Compound_common_name	Compound_synonyms	Chemical_formula	Smiles	Links	EC	Reaction_equation	Pathway
dTDP-4-dehydro-6-deoxy-D-glucose	TDP-4-keto-6-deoxy-D-glucose*TDP-4-oxo-6-deoxy-D-glucose*dTDP-4-oxo-6-deoxy-D-glucose	C16 H24 N2 O15 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(=O)C(O3)C)))		RXN-5461	dTDP-4-dehydro-6-deoxy-D-glucose + NADPH  =  dTDP-alpha-L-rhamnose + NADP+	dTDP-L-rhamnose biosynthesis
dTDP-4-dehydro-6-deoxy-D-glucose	TDP-4-keto-6-deoxy-D-glucose*TDP-4-oxo-6-deoxy-D-glucose*dTDP-4-oxo-6-deoxy-D-glucose	C16 H24 N2 O15 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(=O)C(O3)C)))		4.2.1.46	dTDP-D-glucose  =  H2O + dTDP-4-dehydro-6-deoxy-D-glucose	dTDP-L-rhamnose biosynthesis
(S)-2,3-Epoxysqualene	oxidosqualene*2,3-epoxisqualene*2,3-EDSQ*Squalene 2,3-epoxide*Squalene 2,3-oxide*(S)-Squalene-2,3-epoxide	C30 H50 O1 	CC(CCC1(C(O1)(C)C))=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C	CAS:9029-62-3	5.4.99.8	(S)-2,3-Epoxysqualene  =  cycloartenol	sterol biosynthesis
(S)-2,3-Epoxysqualene	oxidosqualene*2,3-epoxisqualene*2,3-EDSQ*Squalene 2,3-epoxide*Squalene 2,3-oxide*(S)-Squalene-2,3-epoxide	C30 H50 O1 	CC(CCC1(C(O1)(C)C))=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C	CAS:9029-62-3	5.4.99.-	(S)-2,3-Epoxysqualene  =  lupeol	lupeol biosynthesis
(S)-2,3-Epoxysqualene	oxidosqualene*2,3-epoxisqualene*2,3-EDSQ*Squalene 2,3-epoxide*Squalene 2,3-oxide*(S)-Squalene-2,3-epoxide	C30 H50 O1 	CC(CCC1(C(O1)(C)C))=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C	CAS:9029-62-3	1.14.99.7	O2 + reduced acceptor + squalene  =  (S)-2,3-Epoxysqualene + H2O + acceptor	sterol biosynthesis
1-18:3-2-16:3-monogalactosyldiacylglycerol		C43 H70 O10 	C1(OC(CO)C(O)C(O)C(O)1)OCC(OC(=O)CCCCCC=CCC=CCC=CCC)COC(=O)CCCCCCCC=CCC=CCC=CCC		1.14.99.-	1-18:2-2-16:2-monogalactosyldiacylglycerol  =  1-18:3-2-16:3-monogalactosyldiacylglycerol	glycolipid desaturation pathway
acetoacetate	3-ketobutyrate*3-oxobutanate*oxobutyrate*acetoacetic acid*3-oxobutyric acid*3-oxobutanoic acid*diacetic acid*β-ketobutyric acid	C4 H6 O3 	C(O)(=O)CC(=O)C	LIGAND-CPD:C00164*CAS:541-50-4	4.1.3.4	3-hydroxy-3-methyl-glutaryl-CoA  =  acetoacetate + acetyl-CoA	leucine degradation
acetoacetate	3-ketobutyrate*3-oxobutanate*oxobutyrate*acetoacetic acid*3-oxobutyric acid*3-oxobutanoic acid*diacetic acid*β-ketobutyric acid	C4 H6 O3 	C(O)(=O)CC(=O)C	LIGAND-CPD:C00164*CAS:541-50-4	3.7.1.2	H2O + 4-fumaryl-acetoacetate  =  fumarate + acetoacetate	tyrosine degradation
acetoacetate	3-ketobutyrate*3-oxobutanate*oxobutyrate*acetoacetic acid*3-oxobutyric acid*3-oxobutanoic acid*diacetic acid*β-ketobutyric acid	C4 H6 O3 	C(O)(=O)CC(=O)C	LIGAND-CPD:C00164*CAS:541-50-4	3.7.1.2	H2O + 4-fumaryl-acetoacetate  =  fumarate + acetoacetate	phenylalanine degradation
H-protein-(lipoyl)lysine		C8 H13 O1 |Apo-GcvH|1 S2 	C1(CC(SS1)CCCCC(=O)[Apo-GcvH])		1.4.4.2	H-protein-(lipoyl)lysine + glycine  =  CO2 + S-aminomethyldihydrolipoyl-GcvH-protein	glycine degradation
uroporphyrinogen-III		C40 H44 N4 O16 	C(=O)(O)CCc5(c4(Cc1(nc(c(CCC(O)=O)c1CC(=O)O)Cc2(nc(c(CC(O)=O)c2CCC(O)=O)Cc3(nc(c(c3CC(O)=O)CCC(=O)O)Cc(n4)c5CC(O)=O)))))	CAS:1976-85-8	4.1.1.37	uroporphyrinogen-III  =  4 CO2 + coproporphyrinogen III	chlorophyllide a biosynthesis
uroporphyrinogen-III		C40 H44 N4 O16 	C(=O)(O)CCc5(c4(Cc1(nc(c(CCC(O)=O)c1CC(=O)O)Cc2(nc(c(CC(O)=O)c2CCC(O)=O)Cc3(nc(c(c3CC(O)=O)CCC(=O)O)Cc(n4)c5CC(O)=O)))))	CAS:1976-85-8	4.1.1.37	uroporphyrinogen-III  =  4 CO2 + coproporphyrinogen III	biosynthesis of proto- and siroheme
uroporphyrinogen-III		C40 H44 N4 O16 	C(=O)(O)CCc5(c4(Cc1(nc(c(CCC(O)=O)c1CC(=O)O)Cc2(nc(c(CC(O)=O)c2CCC(O)=O)Cc3(nc(c(c3CC(O)=O)CCC(=O)O)Cc(n4)c5CC(O)=O)))))	CAS:1976-85-8	2.1.1.-	uroporphyrinogen-III + 2 S-adenosyl-L-methionine  =  2 S-adenosyl-homocysteine + dihydrosirohydrochlorin	biosynthesis of proto- and siroheme
uroporphyrinogen-III		C40 H44 N4 O16 	C(=O)(O)CCc5(c4(Cc1(nc(c(CCC(O)=O)c1CC(=O)O)Cc2(nc(c(CC(O)=O)c2CCC(O)=O)Cc3(nc(c(c3CC(O)=O)CCC(=O)O)Cc(n4)c5CC(O)=O)))))	CAS:1976-85-8	4.2.1.75	hydroxymethylbilane  =  uroporphyrinogen-III + H2O	chlorophyllide a biosynthesis
uroporphyrinogen-III		C40 H44 N4 O16 	C(=O)(O)CCc5(c4(Cc1(nc(c(CCC(O)=O)c1CC(=O)O)Cc2(nc(c(CC(O)=O)c2CCC(O)=O)Cc3(nc(c(c3CC(O)=O)CCC(=O)O)Cc(n4)c5CC(O)=O)))))	CAS:1976-85-8	4.2.1.75	hydroxymethylbilane  =  uroporphyrinogen-III + H2O	biosynthesis of proto- and siroheme
4-methylthiobutylhydroximate	4-methylthiobutylhydroxamic-acid	C5 H11 N1 O1 S2 	C(SC)CCC(S)=NO		2.4.1.-	4-methylthiobutylhydroximate + UDP-D-glucose  =  3-methylthiopropyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from homomethionine
4-methylthiobutylhydroximate	4-methylthiobutylhydroxamic-acid	C5 H11 N1 O1 S2 	C(SC)CCC(S)=NO		RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
2-keto-3-methyl-valerate	2-oxo-3-methylvalerate*(S)-2-oxo-3-methylpentanoate*(S)-3-methyl-2-oxopentanoate*2-oxo-3-methylpentanoate*3-methyl-2-oxopentanoate*α-keto-β-methyl-valerate	C6 H10 O3 	CC(CC)C(=O)C(=O)O	CAS:1460-34-0	2.6.1.42	2-keto-3-methyl-valerate + L-glutamate  =  L-isoleucine + alpha-ketoglutarate	isoleucine biosynthesis
2-keto-3-methyl-valerate	2-oxo-3-methylvalerate*(S)-2-oxo-3-methylpentanoate*(S)-3-methyl-2-oxopentanoate*2-oxo-3-methylpentanoate*3-methyl-2-oxopentanoate*α-keto-β-methyl-valerate	C6 H10 O3 	CC(CC)C(=O)C(=O)O	CAS:1460-34-0	2.6.1.42	2-keto-3-methyl-valerate + L-glutamate  =  L-isoleucine + alpha-ketoglutarate	isoleucine degradation
2-keto-3-methyl-valerate	2-oxo-3-methylvalerate*(S)-2-oxo-3-methylpentanoate*(S)-3-methyl-2-oxopentanoate*2-oxo-3-methylpentanoate*3-methyl-2-oxopentanoate*α-keto-β-methyl-valerate	C6 H10 O3 	CC(CC)C(=O)C(=O)O	CAS:1460-34-0	2KETO-3METHYLVALERATE-RXN	2-keto-3-methyl-valerate + NAD+ + coenzyme A  =  2-methylbutyryl-CoA + NADH + CO2	isoleucine degradation
2-keto-3-methyl-valerate	2-oxo-3-methylvalerate*(S)-2-oxo-3-methylpentanoate*(S)-3-methyl-2-oxopentanoate*2-oxo-3-methylpentanoate*3-methyl-2-oxopentanoate*α-keto-β-methyl-valerate	C6 H10 O3 	CC(CC)C(=O)C(=O)O	CAS:1460-34-0	4.2.1.9	2,3-dihydroxy-3-methylvalerate  =  2-keto-3-methyl-valerate + H2O	isoleucine biosynthesis
9,10,18-trihydroxystearate		C18 H36 O5 	C(O)(=O)CCCCCCCC(O)C(O)CCCCCCCCO		RXN-1065	9,10-epoxy-18-hydroxystearate + H2O  =  9,10,18-trihydroxystearate	cutin biosynthesis
an alkane					RXN-1022	an alkane  =  a secondary alcohol	epicuticular wax biosynthesis
an alkane					RXN-4443	an alkane  =  a fatty alcohol	fatty acid omega-oxidation
an alkane					4.1.99.5	a fatty aldehyde  =  an alkane + CO	epicuticular wax biosynthesis
allantoin		C4 H6 N4 O3 	C1(NC(N)=O)(C(=O)NC(N1)=O)	LIGAND-CPD:C01551*LIGAND:C01551*CAS:97-59-6	3.5.2.5	H2O + allantoin  =  allantoate	ureide biosynthesis
allantoin		C4 H6 N4 O3 	C1(NC(N)=O)(C(=O)NC(N1)=O)	LIGAND-CPD:C01551*LIGAND:C01551*CAS:97-59-6	3.5.2.5	H2O + allantoin  =  allantoate	ureide degradation
allantoin		C4 H6 N4 O3 	C1(NC(N)=O)(C(=O)NC(N1)=O)	LIGAND-CPD:C01551*LIGAND:C01551*CAS:97-59-6	1.7.3.3	urate + O2  =  allantoin + CO2 + H2O2	purine degradation
allantoin		C4 H6 N4 O3 	C1(NC(N)=O)(C(=O)NC(N1)=O)	LIGAND-CPD:C01551*LIGAND:C01551*CAS:97-59-6	1.7.3.3	urate + H2O2  =  allantoin + CO2	ureide biosynthesis
APS	adenylyl-sulfate*adenosine phosphosulfate*adenosine 5'-sulphatophosphate	C10 H14 N5 O10 P1 S1 	C(OP(=O)(O)OS(=O)(O)=O)[CH]1(O[CH](C(O)C1O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:485-84-7	1.8.99.2	reduced acceptor + APS  =  AMP + acceptor + SO3-2	sulfate assimilation
APS	adenylyl-sulfate*adenosine phosphosulfate*adenosine 5'-sulphatophosphate	C10 H14 N5 O10 P1 S1 	C(OP(=O)(O)OS(=O)(O)=O)[CH]1(O[CH](C(O)C1O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:485-84-7	2.7.7.4	SO42- + ATP  =  APS + pyrophosphate	sulfate assimilation
ethanol	absolute alcohol*alcohol*EtOH*eth*ethyl alcohol*grain alcohol	C2 H6 O1 	C(C)[OH]	CAS:64-17-5	1.1.1.1	acetaldehyde + NADH  =  ethanol + NAD+	sucrose degradation to ethanol and lactate (anaerobic)
coumaryl-alcohol		C9 H10 O2 	C(O)C=Cc1(ccc(O)cc1)		1.1.1.195	coumaraldehyde + NADPH  =  coumaryl-alcohol + NADP+	lignin biosynthesis
D-xylose	xylose*α-D-xylose	C5 H10 O5 	C1(C(O)C(O)C(O)C(O1)O)	LIGAND:C00181*CAS:58-86-6	5.3.1.5	D-xylose  =  xylulose	xylose degradation
Short-glucans					2.4.1.25	Short-glucans + Short-glucans  =  Long-linear-glucans + beta-D-glucose	starch degradation
Short-glucans					3.2.1.1	Long-linear-glucans  =  Short-glucans	starch degradation
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.11.1.6	2 H2O2  =  2 H2O + O2	removal of superoxide radicals
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.11.1.11	2 L-ascorbate + H2O2  =  2 monodehydroascorbate + 2 H2O	ascorbate glutathione cycle
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.7.3.3	urate + H2O2  =  allantoin + CO2	ureide biosynthesis
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.7.3.3	urate + O2  =  allantoin + CO2 + H2O2	purine degradation
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.4.3.6	1,3-diaminopropane + H2O + O2  =  3-aminopropionaldehyde + NH3 + H2O2	beta-alanine biosynthesis I
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.5.3.11	spermine + O2 + H2O  =  1-(3-aminopropyl)-4-aminobutanal + 1,3-diaminopropane + H2O2	beta-alanine biosynthesis I
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	RXN-4444	a fatty alcohol + O2  =  a fatty aldehyde + H2O2	fatty acid omega-oxidation
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	RXN-4465	a omega-hydroxy fatty acid + O2  =  a omega-oxo fatty acid + H2O2	fatty acid omega-oxidation
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.4.3.10	O2 + H2O + putrescine  =  NH3 + H2O2 + 4-amino-butyraldehyde	arginine degradation I
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.15.1.1	2 O2- + 2 H+  =  H2O2 + O2	removal of superoxide radicals
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.4.3.6	tryptamine + H2O + O2  =  NH3 + indole acetaldehyde + H2O2	IAA biosynthesis I
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.1.3.15	glycolate + O2  =  glyoxylate + H2O2	photorespiration
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	PNPOXI-RXN	O2 + pyridoxine-5'-phosphate  =  H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	AMACETOXID-RXN	aminoacetone + H2O + O2  =  NH3 + methylglyoxal + H2O2	threonine degradation
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.4.3.-	O2 + L-aspartate  =  H2O2 + iminoaspartate	NAD biosynthesis I (from aspartate)
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.3.3.1	O2 + dihydroorotate  =  H2O2 + orotate	de novo biosynthesis of pyrimidine ribonucleotides
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.4.3.5	O2 + H2O + pyridoxamine 5'-phosphate  =  NH3 + H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	chlorophyllide a biosynthesis
H2O2	hydroperoxide*perhydrol*hydrogen peroxide	H2 O2 	OO	LIGAND-CPD:C00027*CAS:7722-84-1	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	biosynthesis of proto- and siroheme
limonene	(-)-(4<i>S</i>)-limonene	C10 H16 	CC1(=CCC(C(=C)C)CC1)		4.2.3.16	geranyl-PP  =  limonene + pyrophosphate	monoterpene biosynthesis
(-)-(4S)-alpha-terpineol		C10 H18 O1 	CC1(=CCC(C(C)(C)O)CC1)		RXN-5102	(-)-(4S)-alpha-terpineol  =  1,8-cineole	monoterpene biosynthesis
(-)-(4S)-alpha-terpineol		C10 H18 O1 	CC1(=CCC(C(C)(C)O)CC1)		RXN-5101	geranyl-PP + H2O  =  (-)-(4S)-alpha-terpineol + pyrophosphate	monoterpene biosynthesis
myrcene		C10 H16 	C=CC(=C)CCC=C(C)C		4.2.3.15	geranyl-PP  =  myrcene + pyrophosphate + myrcene	monoterpene biosynthesis
(E)-beta-ocimene		C10 H16 	CC(C=C)=CCC=C(C)C		RXN-5109	geranyl-PP  =  (E)-beta-ocimene + pyrophosphate	monoterpene biosynthesis
D-carnitine	S-(+)-3-hydroxy-4-trimethylaminobutyrate*carnitine (D-form)	C7 H15 N1 O3 	C([N+1](C)(C)C)C(O)CC([O-1])=O	CAS:541-14-0	6.3.2.-	coenzyme A + D-carnitine  =  D-carnitinyl-CoA + H2O	carnitine degradation
dethiobiotin	Desthiobiotin*DTB	C10 H18 N2 O3 	C(=O)(O)CCCCCC1(C(C)NC(N1)=O)	LIGAND-CPD:C01909*CAS:533-48-2	2.8.1.6	dethiobiotin + sulfur donor  =  9-mercaptodethiobiotin	biotin biosynthesis II
dethiobiotin	Desthiobiotin*DTB	C10 H18 N2 O3 	C(=O)(O)CCCCCC1(C(C)NC(N1)=O)	LIGAND-CPD:C01909*CAS:533-48-2	6.3.3.3	CO2 + 7,8-diaminononanoate + ATP  =  dethiobiotin + phosphate + ADP	biotin biosynthesis II
glutathione	gamma-L-glutamyl-L-cysteinyl-glycine*glutathione reduced*glutathione red*GSH*reduced glutathione*red. glutathione	C10 H17 N3 O6 S1 	C(=O)(O)C(N)CCC(=O)NC(CS)C(=O)NCC(O)=O	CAS:70-18-8	1.8.5.1	L-dehydro-ascorbate + 2 glutathione  =  glutathione disulfide + L-ascorbate	ascorbate glutathione cycle
glutathione	gamma-L-glutamyl-L-cysteinyl-glycine*glutathione reduced*glutathione red*GSH*reduced glutathione*red. glutathione	C10 H17 N3 O6 S1 	C(=O)(O)C(N)CCC(=O)NC(CS)C(=O)NCC(O)=O	CAS:70-18-8	S-GSH-RXN	polysulfide + glutathione  =  polysulfide-glutathione complex	sulfur oxidation
glutathione	gamma-L-glutamyl-L-cysteinyl-glycine*glutathione reduced*glutathione red*GSH*reduced glutathione*red. glutathione	C10 H17 N3 O6 S1 	C(=O)(O)C(N)CCC(=O)NC(CS)C(=O)NCC(O)=O	CAS:70-18-8	1.8.1.7	glutathione disulfide + NADPH + H+  =  2 glutathione + NADP+	ascorbate glutathione cycle
glutathione	gamma-L-glutamyl-L-cysteinyl-glycine*glutathione reduced*glutathione red*GSH*reduced glutathione*red. glutathione	C10 H17 N3 O6 S1 	C(=O)(O)C(N)CCC(=O)NC(CS)C(=O)NCC(O)=O	CAS:70-18-8	6.3.2.3	glycine + L-gamma-glutamylcysteine + ATP  =  glutathione + phosphate + ADP	glutathione biosynthesis
glutathione	gamma-L-glutamyl-L-cysteinyl-glycine*glutathione reduced*glutathione red*GSH*reduced glutathione*red. glutathione	C10 H17 N3 O6 S1 	C(=O)(O)C(N)CCC(=O)NC(CS)C(=O)NCC(O)=O	CAS:70-18-8	3.1.2.6	S-lactoyl-glutathione + H2O  =  glutathione + D-lactate	threonine degradation
glutathione	gamma-L-glutamyl-L-cysteinyl-glycine*glutathione reduced*glutathione red*GSH*reduced glutathione*red. glutathione	C10 H17 N3 O6 S1 	C(=O)(O)C(N)CCC(=O)NC(CS)C(=O)NCC(O)=O	CAS:70-18-8	3.1.2.6	S-lactoyl-glutathione + H2O  =  glutathione + D-lactate	methylglyoxal degradation
glutathione	gamma-L-glutamyl-L-cysteinyl-glycine*glutathione reduced*glutathione red*GSH*reduced glutathione*red. glutathione	C10 H17 N3 O6 S1 	C(=O)(O)C(N)CCC(=O)NC(CS)C(=O)NCC(O)=O	CAS:70-18-8	4.4.1.5	methylglyoxal + glutathione  =  S-lactoyl-glutathione	threonine degradation
glutathione	gamma-L-glutamyl-L-cysteinyl-glycine*glutathione reduced*glutathione red*GSH*reduced glutathione*red. glutathione	C10 H17 N3 O6 S1 	C(=O)(O)C(N)CCC(=O)NC(CS)C(=O)NCC(O)=O	CAS:70-18-8	4.4.1.5	methylglyoxal + glutathione  =  S-lactoyl-glutathione	methylglyoxal degradation
3-ureidopropionate	3-Ureidopropanoate*&beta;-Ureidopropionic acid*N-Carbamoyl-&beta;-alanine	C4 H8 N2 O3 	C(CC(=O)O)NC(N)=O		3.5.1.6	H2O + 3-ureidopropionate  =  NH3 + CO2 + beta-alanine	beta-alanine biosynthesis III
3-ureidopropionate	3-Ureidopropanoate*&beta;-Ureidopropionic acid*N-Carbamoyl-&beta;-alanine	C4 H8 N2 O3 	C(CC(=O)O)NC(N)=O		3.5.2.2	H2O + dihydrouracil  =  3-ureidopropionate	beta-alanine biosynthesis III
methylglyoxal	oxopropanal*acetylformaldehyde*pyruvic aldehyde*pyruvaldehyde*methyl-glyoxal*2-oxo-propanal	C3 H4 O2 	C(=O)C(C)=O	CAS:78-98-8	AMACETOXID-RXN	aminoacetone + H2O + O2  =  NH3 + methylglyoxal + H2O2	threonine degradation
methylglyoxal	oxopropanal*acetylformaldehyde*pyruvic aldehyde*pyruvaldehyde*methyl-glyoxal*2-oxo-propanal	C3 H4 O2 	C(=O)C(C)=O	CAS:78-98-8	4.4.1.5	methylglyoxal + glutathione  =  S-lactoyl-glutathione	threonine degradation
methylglyoxal	oxopropanal*acetylformaldehyde*pyruvic aldehyde*pyruvaldehyde*methyl-glyoxal*2-oxo-propanal	C3 H4 O2 	C(=O)C(C)=O	CAS:78-98-8	4.4.1.5	methylglyoxal + glutathione  =  S-lactoyl-glutathione	methylglyoxal degradation
caffeate	caffeic acid	C9 H8 O4 	C(O)(=O)C=Cc1(cc(O)c(O)cc1)		6.2.1.12	caffeate + coenzyme A + ATP  =  caffeoyl-CoA + AMP + pyrophosphate	suberin biosynthesis
caffeate	caffeic acid	C9 H8 O4 	C(O)(=O)C=Cc1(cc(O)c(O)cc1)		2.1.1.68	caffeate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + ferulate	phenylpropanoid biosynthesis
caffeate	caffeic acid	C9 H8 O4 	C(O)(=O)C=Cc1(cc(O)c(O)cc1)		2.1.1.68	caffeate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + ferulate	suberin biosynthesis
caffeate	caffeic acid	C9 H8 O4 	C(O)(=O)C=Cc1(cc(O)c(O)cc1)		RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	phenylpropanoid biosynthesis
caffeate	caffeic acid	C9 H8 O4 	C(O)(=O)C=Cc1(cc(O)c(O)cc1)		RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	suberin biosynthesis
SO42-	SO<SUB>4</SUB><SUP>-2</SUP>*sulfate*SO<SUB>4</SUB><SUP>--</SUP>	O4 S1 	O=S([O-1])([O-1])=O	CAS:14808-79-8	2.7.7.4	SO42- + ATP  =  APS + pyrophosphate	sulfate assimilation
SO42-	SO<SUB>4</SUB><SUP>-2</SUP>*sulfate*SO<SUB>4</SUB><SUP>--</SUP>	O4 S1 	O=S([O-1])([O-1])=O	CAS:14808-79-8	SO3OXTFER-RXN	SO3-2 + 2 oxidized cytochrome c + H2O  =  SO42- + 2 reduced cytochrome c + 2 H+	sulfur oxidation
1,4-alpha-D-glucan	1,4-&alpha;-D-glucan*amylose*&beta;-amylase*(1,4-&alpha;-D-glucosyl)<sub>(n)</sub>*(1,4-&alpha;-D-glucosyl)<sub>(n+1)</sub>*(1,4-&alpha;-D-glucosyl)<sub>(n-1)</sub>				2.4.1.18	1,4-alpha-D-glucan  =  Starch	starch biosynthesis
1,4-alpha-D-glucan	1,4-&alpha;-D-glucan*amylose*&beta;-amylase*(1,4-&alpha;-D-glucosyl)<sub>(n)</sub>*(1,4-&alpha;-D-glucosyl)<sub>(n+1)</sub>*(1,4-&alpha;-D-glucosyl)<sub>(n-1)</sub>				2.4.1.21	(1,4-alpha-D-glucosyl)(n) + ADP-D-glucose  =  ADP + (1,4-alpha-D-glucosyl)(n+1)	starch biosynthesis
nicotinamide mononucleotide	&beta;-nicotinamide D-ribonucleotide*nicotinamide ribonucleotide*nicotinamide nucleotide*NMN*nicotinamide D-ribonucleotide	C11 H16 N2 O8 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH](O)1)[n+1]2(cc(C(N)=O)ccc2))	CAS:1094-61-7	3.2.2.14	H2O + nicotinamide mononucleotide  =  D-ribose-5-phosphate + nicotinamide	pyridine nucleotide cycling
nicotinamide mononucleotide	&beta;-nicotinamide D-ribonucleotide*nicotinamide ribonucleotide*nicotinamide nucleotide*NMN*nicotinamide D-ribonucleotide	C11 H16 N2 O8 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH](O)1)[n+1]2(cc(C(N)=O)ccc2))	CAS:1094-61-7	3.5.1.42	nicotinamide mononucleotide + H2O  =  NH3 + nicotinate nucleotide	pyridine nucleotide cycling
nicotinamide mononucleotide	&beta;-nicotinamide D-ribonucleotide*nicotinamide ribonucleotide*nicotinamide nucleotide*NMN*nicotinamide D-ribonucleotide	C11 H16 N2 O8 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH](O)1)[n+1]2(cc(C(N)=O)ccc2))	CAS:1094-61-7	3.6.1.22	H2O + NAD+  =  nicotinamide mononucleotide + AMP	pyridine nucleotide cycling
L-1-phosphatidyl-ethanolamine	O-(1-&beta;-acyl-2-acyl-sn-glycero-3-phospho)-ethanolamine*PtdEtn*phosphatidylethanolamine*1-phosphatidylethanolamine*L-1-phosphotidylethanolamine	C7 H12 N1 O8 R2 P1 			RXN-1382	L-1-phosphatidyl-ethanolamine + L-serine  =  L-1-phosphatidylserine + ethanolamine	phospholipid biosynthesis
L-1-phosphatidyl-ethanolamine	O-(1-&beta;-acyl-2-acyl-sn-glycero-3-phospho)-ethanolamine*PtdEtn*phosphatidylethanolamine*1-phosphatidylethanolamine*L-1-phosphotidylethanolamine	C7 H12 N1 O8 R2 P1 			2.7.8.1	1,2-diacylglycerol + CDP-ethanolamine  =  L-1-phosphatidyl-ethanolamine + CMP	phospholipid biosynthesis
L-1-phosphatidyl-ethanolamine	O-(1-&beta;-acyl-2-acyl-sn-glycero-3-phospho)-ethanolamine*PtdEtn*phosphatidylethanolamine*1-phosphatidylethanolamine*L-1-phosphotidylethanolamine	C7 H12 N1 O8 R2 P1 			4.1.1.65	L-1-phosphatidylserine  =  L-1-phosphatidyl-ethanolamine + CO2	phospholipid biosynthesis
p-aminobenzoate	para-aminobenzoic acid*p-aminobenzoic acid*para-aminobenzoate*4-aminobenzoate*4-aminobenzoic acid	C7 H7 N1 O2 	C(=O)(O)c1(ccc(N)cc1)		2.5.1.15	p-aminobenzoate + 2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate  =  7,8-dihydropteroate + pyrophosphate	tetrahydrofolate biosynthesis I
p-aminobenzoate	para-aminobenzoic acid*p-aminobenzoic acid*para-aminobenzoate*4-aminobenzoate*4-aminobenzoic acid	C7 H7 N1 O2 	C(=O)(O)c1(ccc(N)cc1)		2.5.1.15	p-aminobenzoate + 2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate  =  7,8-dihydropteroate + pyrophosphate	tetrahydrofolate biosynthesis II
p-aminobenzoate	para-aminobenzoic acid*p-aminobenzoic acid*para-aminobenzoate*4-aminobenzoate*4-aminobenzoic acid	C7 H7 N1 O2 	C(=O)(O)c1(ccc(N)cc1)		RXN-6142	p-aminobenzoate + UDP-D-glucose  =  p-aminobenzoate-beta-D-glucopyranosyl ester + UDP	tetrahydrofolate biosynthesis I
p-aminobenzoate	para-aminobenzoic acid*p-aminobenzoic acid*para-aminobenzoate*4-aminobenzoate*4-aminobenzoic acid	C7 H7 N1 O2 	C(=O)(O)c1(ccc(N)cc1)		4.1.3.38	4-amino-4-deoxychorismate  =  p-aminobenzoate + pyruvate	tetrahydrofolate biosynthesis I
p-aminobenzoate	para-aminobenzoic acid*p-aminobenzoic acid*para-aminobenzoate*4-aminobenzoate*4-aminobenzoic acid	C7 H7 N1 O2 	C(=O)(O)c1(ccc(N)cc1)		4.1.3.38	4-amino-4-deoxychorismate  =  p-aminobenzoate + pyruvate	tetrahydrofolate biosynthesis II
mannose	mannopyranoside*mannopyranose*D-mannose	C6 H12 O6 	C(=O)C(O)C(O)C(O)C(O)CO	LIGAND:C00159*CAS:3458-28-4	2.7.1.7	mannose + ATP  =  mannose-6-phosphate + ADP	mannitol degradation
mannose	mannopyranoside*mannopyranose*D-mannose	C6 H12 O6 	C(=O)C(O)C(O)C(O)C(O)CO	LIGAND:C00159*CAS:3458-28-4	1.1.1.255	NAD+ + mannitol  =  NADH + mannose	mannitol degradation
terpinolene		C10 H16 	CC1(=CCC(=C(C)C)CC1)		RXN-5108	geranyl-PP  =  terpinolene + pyrophosphate	monoterpene biosynthesis
(-)-(1S,5S)-beta-pinene		C10 H16 	CC1(C2(CC1C(=C)CC2))(C)		4.2.3.14	geranyl-PP  =  (-)-(1S,5S)-beta-pinene + pyrophosphate	monoterpene biosynthesis
2-aminomuconate semialdehyde	2-Aminomuconate 6-semialdehyde*2-aminomuconic semialdehyde	C6 H7 N1 O3 	[CH](=O)C=CC=C(N)C(O)=O		1.2.1.32	H2O + NAD+ + 2-aminomuconate semialdehyde  =  NADH + 2-amino-muconate	tryptophan degradation
2-aminomuconate semialdehyde	2-Aminomuconate 6-semialdehyde*2-aminomuconic semialdehyde	C6 H7 N1 O3 	[CH](=O)C=CC=C(N)C(O)=O		4.1.1.45	2-amino-3-carboxymuconate semialdehyde  =  CO2 + 2-aminomuconate semialdehyde	tryptophan degradation
(-)-(1S,5S)-alpha-pinene		C10 H16 	CC1(C2(CC1C(C)=CC2))(C)		4.2.3.14	geranyl-PP  =  (-)-(1S,5S)-alpha-pinene + pyrophosphate	monoterpene biosynthesis
(-)-(1S)-sabinene		C10 H16 	C=C2(C1(C(C(C)C)(C1)CC2))		RXN-5103	geranyl-PP  =  (-)-(1S)-sabinene + pyrophosphate	monoterpene biosynthesis
2-dehydropantoate	ketopantoate*2-keto-pantoate	C6 H10 O4 	C(O)(=O)C(=O)C(C)(C)CO		2.1.2.11	H2O + 2-keto-isovalerate + 5,10-methylene-THF  =  2-dehydropantoate + tetrahydrofolate	pantothenate biosynthesis
2-dehydropantoate	ketopantoate*2-keto-pantoate	C6 H10 O4 	C(O)(=O)C(=O)C(C)(C)CO		1.1.1.169	2-dehydropantoate + NADPH  =  L-pantoate + NADP+	pantothenate biosynthesis
alpha-D-glucose	&alpha;-glucose*D-glucose*glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C1(C(O)C(O)C(O)C(O1)CO)(O)		2.7.1.1	alpha-D-glucose + ATP  =  alpha-D-glucose-6-phosphate + ADP	sucrose degradation
alpha-D-glucose	&alpha;-glucose*D-glucose*glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C1(C(O)C(O)C(O)C(O1)CO)(O)		3.2.1.20	maltose + H2O  =  2 alpha-D-glucose	starch degradation
alpha-D-glucose	&alpha;-glucose*D-glucose*glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C1(C(O)C(O)C(O)C(O1)CO)(O)		3.2.1.26	sucrose + H2O  =  alpha-D-glucose + fructose	sucrose degradation
GA8	gibberellin A<sub>8</sub>*gibberellin A8*GA8	C19 H24 O7 	C=C1(C2(CC5(C1)([CH](CC2)C34(OC(=O)C(C(O)C(O)C3)(C)[CH]4C5C(=O)O)))(O))		1.14.11.-	GA8 + alpha-ketoglutarate + O2  =  GA8-catabolite + succinate + CO2 + H2O	gibberellin inactivation
GA8	gibberellin A<sub>8</sub>*gibberellin A8*GA8	C19 H24 O7 	C=C1(C2(CC5(C1)([CH](CC2)C34(OC(=O)C(C(O)C(O)C3)(C)[CH]4C5C(=O)O)))(O))		1.14.11.13	GA1 + alpha-ketoglutarate + O2  =  GA8 + succinate + CO2	gibberellin inactivation
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	6.1.1.19	tRNAarg + L-arginine + ATP  =  L-arginyl-tRNAarg + pyrophosphate + AMP	tRNA charging pathway
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	3.5.3.1	H2O + L-arginine  =  urea + L-ornithine	arginine degradation II
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis III
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	4.1.1.19	L-arginine  =  CO2 + agmatine	arginine degradation I
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	4.1.1.19	L-arginine  =  CO2 + agmatine	spermine biosynthesis I
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis II
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis I
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis II (acetyl cycle)
L-arginine	2-amino-5-guanidinovaleric acid*R*arginine*arg	C6 H14 N4 O2 	C(NC(N)=N)CC[CH](N)C(O)=O	CAS:74-79-3*CAS:7004-12-8	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis III
UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine	UDP-3-O-(3-hydroxytetradecanoyl)-N-acetylglucosamine	C31 H53 N3 O19 P2 	CCCCCCCCCCCC(O)CC(=O)OC1(C(NC(=O)C)C(OC(C1O)CO)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3)))		UDPACYLGLCNACDEACETYL-RXN	UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine + H2O  =  UDP-3-O-(3-hydroxymyristoyl)glucosamine + acetate	lipid-A-precursor biosynthesis
UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine	UDP-3-O-(3-hydroxytetradecanoyl)-N-acetylglucosamine	C31 H53 N3 O19 P2 	CCCCCCCCCCCC(O)CC(=O)OC1(C(NC(=O)C)C(OC(C1O)CO)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3)))		2.3.1.129	(R)-3-hydroxymyristoyl-ACP + UDP-N-acetyl-D-glucosamine  =  UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine + acyl carrier protein	lipid-A-precursor biosynthesis
N-acetyl-L-glutamate	N-acetyl-glutamate*N-acetylglutamic acid*<i>N</i>-acetylglutamic acid*acetyl-glu*<i>N</i>-acetyl-glutamate*acetyl-glutamate*<i>N</i>-acetyl L-glutamic acid	C7 H11 N1 O5 	CC(=O)NC(C(O)=O)CCC(O)=O	LIGAND:C00624*CAS:1188-37-0	2.7.2.8	N-acetyl-L-glutamate + ATP  =  N-acetylglutamyl-phosphate + ADP	arginine biosynthesis
N-acetyl-L-glutamate	N-acetyl-glutamate*N-acetylglutamic acid*<i>N</i>-acetylglutamic acid*acetyl-glu*<i>N</i>-acetyl-glutamate*acetyl-glutamate*<i>N</i>-acetyl L-glutamic acid	C7 H11 N1 O5 	CC(=O)NC(C(O)=O)CCC(O)=O	LIGAND:C00624*CAS:1188-37-0	2.7.2.8	N-acetyl-L-glutamate + ATP  =  N-acetylglutamyl-phosphate + ADP	arginine biosynthesis II (acetyl cycle)
N-acetyl-L-glutamate	N-acetyl-glutamate*N-acetylglutamic acid*<i>N</i>-acetylglutamic acid*acetyl-glu*<i>N</i>-acetyl-glutamate*acetyl-glutamate*<i>N</i>-acetyl L-glutamic acid	C7 H11 N1 O5 	CC(=O)NC(C(O)=O)CCC(O)=O	LIGAND:C00624*CAS:1188-37-0	2.3.1.35	L-glutamate + N-alpha-acetylornithine  =  N-acetyl-L-glutamate + L-ornithine	arginine biosynthesis II (acetyl cycle)
N-acetyl-L-glutamate	N-acetyl-glutamate*N-acetylglutamic acid*<i>N</i>-acetylglutamic acid*acetyl-glu*<i>N</i>-acetyl-glutamate*acetyl-glutamate*<i>N</i>-acetyl L-glutamic acid	C7 H11 N1 O5 	CC(=O)NC(C(O)=O)CCC(O)=O	LIGAND:C00624*CAS:1188-37-0	2.3.1.1	L-glutamate + acetyl-CoA  =  N-acetyl-L-glutamate + coenzyme A	arginine biosynthesis
N-acetyl-L-glutamate	N-acetyl-glutamate*N-acetylglutamic acid*<i>N</i>-acetylglutamic acid*acetyl-glu*<i>N</i>-acetyl-glutamate*acetyl-glutamate*<i>N</i>-acetyl L-glutamic acid	C7 H11 N1 O5 	CC(=O)NC(C(O)=O)CCC(O)=O	LIGAND:C00624*CAS:1188-37-0	2.3.1.1	L-glutamate + acetyl-CoA  =  N-acetyl-L-glutamate + coenzyme A	arginine biosynthesis II (acetyl cycle)
Mg2+	magnesium*Mg<SUP>+2</SUP>*Mg<SUP>++</SUP>*magnesium ion	MG1 	[Mg+2]	LIGAND-CPD:C00305	6.6.1.1	ATP + protoporphyrin IX + Mg2+ + H2O  =  Mg-protoporphyrin + H+ + phosphate + ADP	chlorophyllide a biosynthesis
a lysophosphatidylcholine	a lysolecithin*a lyso-phosphatidylcholine	C9 H20 N1 O7 R21 P1 	C([N+1](C)(C)C)COP(=O)(O)OCC(O)COC([R2])=O		3.1.1.4	a phosphatidylcholine + H2O  =  linolenate + a lysophosphatidylcholine	jasmonic acid biosynthesis
xylulose	D-xylulose*D-threo-pentulose	C5 H10 O5 	C(O)C(O)C(O)C(=O)CO	CAS:551-84-8	2.7.1.17	xylulose + ATP  =  D-xylulose-5-phosphate + ADP	xylose degradation
xylulose	D-xylulose*D-threo-pentulose	C5 H10 O5 	C(O)C(O)C(O)C(=O)CO	CAS:551-84-8	5.3.1.5	D-xylose  =  xylulose	xylose degradation
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose degradation
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose degradation to ethanol and lactate (anaerobic)
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	colanic acid building blocks biosynthesis
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	galactose degradation II
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	galactose degradation I
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose biosynthesis
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	UDP-glucose conversion
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.23	N-acetyl-glucosamine-1-phosphate + UTP  =  UDP-N-acetyl-D-glucosamine + pyrophosphate	UDP-N-acetyl-D-glucosamine biosynthesis
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.10	alpha-D-galactose-1-phosphate + UTP  =  UDP-galactose + pyrophosphate	galactose degradation I
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	RXN0-724	UTP + reduced flavodoxin  =  dUTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	6.3.4.2	L-glutamine + H2O + UTP + ATP  =  CTP + phosphate + ADP + L-glutamate	de novo biosynthesis of pyrimidine ribonucleotides
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	RXN-3	alpha-D-galacturonate 1-phosphate + UTP  =  UDP-D-galacturonate + pyrophosphate	UDP-D-galacturonate biosynthesis II (from D-galacturonate)
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.7.44	alpha-D-glucuronate 1-phosphate + UTP  =  UDP-D-glucuronate + pyrophosphate	inositol oxidation pathway
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	RXN-7401	beta-L-arabinose 1-phosphate + UTP  =  UDP-L-arabinose + pyrophosphate	UDP-L-arabinose biosynthesis II (from L-arabinose)
UTP	uridine-triphosphate*uridine-5'-triphosphate	C9 H15 N2 O15 P3 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:63-39-8	2.7.4.6	UDP + ATP  =  UTP + ADP	de novo biosynthesis of pyrimidine ribonucleotides
24-methylenelophenol	cpd-4101*cdp-4101*4&alpha;-methyl-5&alpha;-ergosta-7,24-dien-3&beta;-ol	C29 H48 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC=3)C(C)C(O)CC4)(C))))		2.1.1.143	24-methylenelophenol + S-adenosyl-L-methionine  =  24-ethylidenelophenol + S-adenosyl-homocysteine	sterol biosynthesis
24-methylenelophenol	cpd-4101*cdp-4101*4&alpha;-methyl-5&alpha;-ergosta-7,24-dien-3&beta;-ol	C29 H48 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC=3)C(C)C(O)CC4)(C))))		2.1.1.-	24-methylenelophenol + S-adenosyl-homocysteine  =  episterol + S-adenosyl-L-methionine	sterol biosynthesis
24-methylenelophenol	cpd-4101*cdp-4101*4&alpha;-methyl-5&alpha;-ergosta-7,24-dien-3&beta;-ol	C29 H48 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC=3)C(C)C(O)CC4)(C))))		5.3.3.5	4alpha-methylfecosterol  =  24-methylenelophenol	sterol biosynthesis
4-coumarate	p-coumarate*trans-4-hydroxycinnamate*p-coumaric acid*4-Hydroxycinnamic acid*4-Hydroxycinnamate*coumarate	C9 H8 O3 	C(O)(=O)C=Cc1(ccc(O)cc1)	CAS:7400-08-0	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	flavonoid biosynthesis
4-coumarate	p-coumarate*trans-4-hydroxycinnamate*p-coumaric acid*4-Hydroxycinnamic acid*4-Hydroxycinnamate*coumarate	C9 H8 O3 	C(O)(=O)C=Cc1(ccc(O)cc1)	CAS:7400-08-0	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	lignin biosynthesis
4-coumarate	p-coumarate*trans-4-hydroxycinnamate*p-coumaric acid*4-Hydroxycinnamic acid*4-Hydroxycinnamate*coumarate	C9 H8 O3 	C(O)(=O)C=Cc1(ccc(O)cc1)	CAS:7400-08-0	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	phenylpropanoid biosynthesis
4-coumarate	p-coumarate*trans-4-hydroxycinnamate*p-coumaric acid*4-Hydroxycinnamic acid*4-Hydroxycinnamate*coumarate	C9 H8 O3 	C(O)(=O)C=Cc1(ccc(O)cc1)	CAS:7400-08-0	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	suberin biosynthesis
4-coumarate	p-coumarate*trans-4-hydroxycinnamate*p-coumaric acid*4-Hydroxycinnamic acid*4-Hydroxycinnamate*coumarate	C9 H8 O3 	C(O)(=O)C=Cc1(ccc(O)cc1)	CAS:7400-08-0	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	phenylpropanoid biosynthesis, initial reactions
4-coumarate	p-coumarate*trans-4-hydroxycinnamate*p-coumaric acid*4-Hydroxycinnamic acid*4-Hydroxycinnamate*coumarate	C9 H8 O3 	C(O)(=O)C=Cc1(ccc(O)cc1)	CAS:7400-08-0	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	suberin biosynthesis
L-aspartyl-tRNAasp	L-ASPARTYL-TRNA(ASP)				6.1.1.12	tRNAasp + L-aspartate + ATP  =  L-aspartyl-tRNAasp + pyrophosphate + AMP	tRNA charging pathway
a 2(R)-hydroperoxy fatty acid		C2 H3 O4 R1 			RXN-4141	a 2(R)-hydroperoxy fatty acid  =  a 2(R)-hydroxy fatty acid	fatty acid alpha-oxidation
a 2(R)-hydroperoxy fatty acid		C2 H3 O4 R1 			RXN-4122	a 2(R)-hydroperoxy fatty acid  =  a fatty aldehyde + CO2 + H2O	fatty acid alpha-oxidation
a 2(R)-hydroperoxy fatty acid		C2 H3 O4 R1 			1.13.11.-	a fatty acid + O2  =  a 2(R)-hydroperoxy fatty acid	fatty acid alpha-oxidation
3-hydroxy-isobutyrate	3-Hydroxy-2-methylpropanoate*3-Hydroxyisobutyric acid*3-OH-iso-but*3-OH-isobutyrate	C4 H8 O3 	C(O)(=O)C(C)CO	CAS:2068-83-9	1.1.1.31	NAD+ + 3-hydroxy-isobutyrate  =  NADH + methylmalonate-semialdehyde	valine degradation
3-hydroxy-isobutyrate	3-Hydroxy-2-methylpropanoate*3-Hydroxyisobutyric acid*3-OH-iso-but*3-OH-isobutyrate	C4 H8 O3 	C(O)(=O)C(C)CO	CAS:2068-83-9	3.1.2.4	H2O + 3-hydroxy-isobutyryl-CoA  =  3-hydroxy-isobutyrate + coenzyme A	valine degradation
ferricytochrome c	cytochrome-c-oxidized*cytochrome c ox	C42 H53 N8 O6 S2 FE1 	CC1(C8(N2(C(C=1C(C)SCC(N)C(=O)NC)C=c5(n4([Fe+3]62([N+1]3(C(C(C)=C(CCC(O)=O)C=3C=c4c(c5C)CCC(O)=O)=Cc7(c(C)c(c(n67)C=8)C(C)SCC(N)C(=O)NC))))))))	LIGAND-CPD:C00125*CAS:9007-43-6	1.10.2.2	2 ferricytochrome c + a ubiquinol  =  2 ferrocytochrome c + a ubiquinone	aerobic respiration
ferricytochrome c	cytochrome-c-oxidized*cytochrome c ox	C42 H53 N8 O6 S2 FE1 	CC1(C8(N2(C(C=1C(C)SCC(N)C(=O)NC)C=c5(n4([Fe+3]62([N+1]3(C(C(C)=C(CCC(O)=O)C=3C=c4c(c5C)CCC(O)=O)=Cc7(c(C)c(c(n67)C=8)C(C)SCC(N)C(=O)NC))))))))	LIGAND-CPD:C00125*CAS:9007-43-6	1.3.2.3	2 ferricytochrome c + L-galactono-1,4-lactone  =  2 ferrocytochrome c + L-ascorbate	ascorbate biosynthesis
ferricytochrome c	cytochrome-c-oxidized*cytochrome c ox	C42 H53 N8 O6 S2 FE1 	CC1(C8(N2(C(C=1C(C)SCC(N)C(=O)NC)C=c5(n4([Fe+3]62([N+1]3(C(C(C)=C(CCC(O)=O)C=3C=c4c(c5C)CCC(O)=O)=Cc7(c(C)c(c(n67)C=8)C(C)SCC(N)C(=O)NC))))))))	LIGAND-CPD:C00125*CAS:9007-43-6	1.9.3.1	O2 + 4 ferrocytochrome c  =  2 H2O + 4 ferricytochrome c	aerobic respiration
16-hydroxypalmitate		C16 H32 O3 	C(O)(=O)CCCCCCCCCCCCCCCO		RXN-1062	16-hydroxypalmitate + NADPH + O2  =  10,16-dihydroxypalmitate + NADP+ + H2O	cutin biosynthesis
16-hydroxypalmitate		C16 H32 O3 	C(O)(=O)CCCCCCCCCCCCCCCO		1.14.13.-	palmitate + NADPH + O2  =  16-hydroxypalmitate + NADP+ + H2O	cutin biosynthesis
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	sucrose degradation to ethanol and lactate (anaerobic)
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis I
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis II
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	gluconeogenesis
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glyceraldehyde 3-phosphate degradation
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	1.2.1.9	H2O + NADP+ + D-glyceraldehyde-3-phosphate  =  3-phosphoglycerate + NADPH	glycolysis I
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	2.2.1.2	D-glyceraldehyde-3-phosphate + D-sedoheptulose-7-phosphate  =  D-fructose-6-phosphate + D-erythrose-4-phosphate	non-oxidative branch of the pentose phosphate pathway
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	5.3.1.1	D-glyceraldehyde-3-phosphate  =  dihydroxy-acetone-phosphate	Calvin cycle
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	5.3.1.1	D-glyceraldehyde-3-phosphate  =  dihydroxy-acetone-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	5.3.1.1	D-glyceraldehyde-3-phosphate  =  dihydroxy-acetone-phosphate	glycolysis I
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	5.3.1.1	D-glyceraldehyde-3-phosphate  =  dihydroxy-acetone-phosphate	glycolysis II
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.3.37	pyruvate + D-glyceraldehyde-3-phosphate  =  1-deoxy-D-xylulose 5-phosphate + CO2	thiamin biosynthesis
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.3.37	pyruvate + D-glyceraldehyde-3-phosphate  =  1-deoxy-D-xylulose 5-phosphate + CO2	isopentenyl diphosphate biosynthesis -- mevalonate-independent
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	1.2.1.59	NAD(P)H + 1,3-diphosphateglycerate  =  NAD(P)+ + D-glyceraldehyde-3-phosphate + phosphate	Calvin cycle
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.2.4	deoxyribose-5-phosphate  =  acetaldehyde + D-glyceraldehyde-3-phosphate	(deoxy)ribose phosphate degradation
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	RXN0-2381	indole-3-glycerol-phosphate  =  indole + D-glyceraldehyde-3-phosphate	tryptophan biosynthesis
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	2TRANSKETO-RXN	D-erythrose-4-phosphate + D-xylulose-5-phosphate  =  D-fructose-6-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	2TRANSKETO-RXN	D-erythrose-4-phosphate + D-xylulose-5-phosphate  =  D-fructose-6-phosphate + D-glyceraldehyde-3-phosphate	non-oxidative branch of the pentose phosphate pathway
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.2.14	2-keto-3-deoxy-6-phospho-gluconate  =  D-glyceraldehyde-3-phosphate + pyruvate	beta-D-glucuronide degradation
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	(deoxy)ribose phosphate degradation
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	ribose degradation
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	non-oxidative branch of the pentose phosphate pathway
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	glycolysis I
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	glycolysis II
D-glyceraldehyde-3-phosphate	3-phosphoglyceraldehyde*D-glyceraldehyde-3-P*glyceraldehyde-3-phosphate*gap*glyceraldehyde-phosphate*glyceraldehyde-P*glyceraldehyde-3-P*(2<i>R</i>)-2-hydroxy-3-(phosphonooxy)-propanal	C3 H7 O6 P1 	C(=O)[CH](O)COP(O)(=O)O	CAS:142-10-9	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	gluconeogenesis
ferrocytochrome c	cytochrome-c-reduced*cytochrome c red	C42 H53 N8 O6 S2 FE1 	CC1(C8(N2(C(C=1C(C)SCC(N)C(=O)NC)C=c5(n4([Fe+2]62([N+1]3(C(C(C)=C(CCC(O)=O)C=3C=c4c(c5C)CCC(O)=O)=Cc7(c(C)c(c(n67)C=8)C(C)SCC(N)C(=O)NC))))))))	LIGAND-CPD:C00126*CAS:9007-43-6	1.9.3.1	O2 + 4 ferrocytochrome c  =  2 H2O + 4 ferricytochrome c	aerobic respiration
ferrocytochrome c	cytochrome-c-reduced*cytochrome c red	C42 H53 N8 O6 S2 FE1 	CC1(C8(N2(C(C=1C(C)SCC(N)C(=O)NC)C=c5(n4([Fe+2]62([N+1]3(C(C(C)=C(CCC(O)=O)C=3C=c4c(c5C)CCC(O)=O)=Cc7(c(C)c(c(n67)C=8)C(C)SCC(N)C(=O)NC))))))))	LIGAND-CPD:C00126*CAS:9007-43-6	1.3.2.3	2 ferricytochrome c + L-galactono-1,4-lactone  =  2 ferrocytochrome c + L-ascorbate	ascorbate biosynthesis
ferrocytochrome c	cytochrome-c-reduced*cytochrome c red	C42 H53 N8 O6 S2 FE1 	CC1(C8(N2(C(C=1C(C)SCC(N)C(=O)NC)C=c5(n4([Fe+2]62([N+1]3(C(C(C)=C(CCC(O)=O)C=3C=c4c(c5C)CCC(O)=O)=Cc7(c(C)c(c(n67)C=8)C(C)SCC(N)C(=O)NC))))))))	LIGAND-CPD:C00126*CAS:9007-43-6	1.10.2.2	2 ferricytochrome c + a ubiquinol  =  2 ferrocytochrome c + a ubiquinone	aerobic respiration
a fatty aldehyde		C2 H3 O1 R1 			4.1.99.5	a fatty aldehyde  =  an alkane + CO	epicuticular wax biosynthesis
a fatty aldehyde		C2 H3 O1 R1 			1.1.1.2	NAD(P)H + a fatty aldehyde  =  NAD(P)+ + a primary alcohol	epicuticular wax biosynthesis
a fatty aldehyde		C2 H3 O1 R1 			1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid omega-oxidation
a fatty aldehyde		C2 H3 O1 R1 			1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid alpha-oxidation
a fatty aldehyde		C2 H3 O1 R1 			RXN-4444	a fatty alcohol + O2  =  a fatty aldehyde + H2O2	fatty acid omega-oxidation
a fatty aldehyde		C2 H3 O1 R1 			RXN-4122	a 2(R)-hydroperoxy fatty acid  =  a fatty aldehyde + CO2 + H2O	fatty acid alpha-oxidation
a fatty aldehyde		C2 H3 O1 R1 			1.2.1.50	NAD(P)H + very-long-chain-fatty-acyl-CoA  =  NAD(P)+ + a fatty aldehyde	epicuticular wax biosynthesis
inosine	hypoxanthine-ribose*iso-prinosine*riboxine	C10 H12 N4 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00294*LIGAND:C00294*CAS:58-63-9	2.7.1.73	inosine + ATP  =  IMP + ADP	salvage pathways of purine nucleosides
inosine	hypoxanthine-ribose*iso-prinosine*riboxine	C10 H12 N4 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00294*LIGAND:C00294*CAS:58-63-9	3.2.2.2	inosine + H2O  =  hypoxanthine + D-ribose	purine degradation
inosine	hypoxanthine-ribose*iso-prinosine*riboxine	C10 H12 N4 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00294*LIGAND:C00294*CAS:58-63-9	3.2.2.2	inosine + H2O  =  hypoxanthine + D-ribose	salvage pathways of purine nucleosides
inosine	hypoxanthine-ribose*iso-prinosine*riboxine	C10 H12 N4 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00294*LIGAND:C00294*CAS:58-63-9	3.1.3.5	IMP + H2O  =  inosine + phosphate	purine degradation
inosine	hypoxanthine-ribose*iso-prinosine*riboxine	C10 H12 N4 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00294*LIGAND:C00294*CAS:58-63-9	3.1.3.5	IMP + H2O  =  inosine + phosphate	salvage pathways of purine nucleosides
N-succinyl-2-amino-6-ketopimelate	<i>N</i>-succinyl-L-2-amino-6-oxoheptanedioate*succinyl-&epsilon;-keto-&alpha;-aminopimelate	C11 H15 N1 O8 	C(O)(=O)C(=O)CCCC(C(=O)O)NC(=O)CCC(=O)O		2.6.1.17	L-glutamate + N-succinyl-2-amino-6-ketopimelate  =  alpha-ketoglutarate + N-succinyl-L,L-2,6-diaminopimelate	lysine biosynthesis
N-succinyl-2-amino-6-ketopimelate	<i>N</i>-succinyl-L-2-amino-6-oxoheptanedioate*succinyl-&epsilon;-keto-&alpha;-aminopimelate	C11 H15 N1 O8 	C(O)(=O)C(=O)CCCC(C(=O)O)NC(=O)CCC(=O)O		2.3.1.117	H2O + L-2,3,4,5-tetrahydrodipicolinate + succinyl-CoA  =  N-succinyl-2-amino-6-ketopimelate + coenzyme A	lysine biosynthesis
D-myo-inositol (1,4,5,6)-tetrakisphosphate	inositol (1,4,5,6)-tetra<i>kis</i>phosphate*1D-<i>myo</i>-inositol (1,4,5,6)-tetra<i>kis</i>phosphate*Ins(1,4,5,6)P<sub>4</sub>*I(1,4,5,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(O)		2.7.1.-	D-myo-inositol (1,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
D-myo-inositol (1,4,5,6)-tetrakisphosphate	inositol (1,4,5,6)-tetra<i>kis</i>phosphate*1D-<i>myo</i>-inositol (1,4,5,6)-tetra<i>kis</i>phosphate*Ins(1,4,5,6)P<sub>4</sub>*I(1,4,5,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(O)		2.7.1.-	D-myo-inositol (1,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,2,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
D-myo-inositol (1,4,5,6)-tetrakisphosphate	inositol (1,4,5,6)-tetra<i>kis</i>phosphate*1D-<i>myo</i>-inositol (1,4,5,6)-tetra<i>kis</i>phosphate*Ins(1,4,5,6)P<sub>4</sub>*I(1,4,5,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(O)		2.7.1.151	inositol 1,4,5-trisphosphate + ATP  =  D-myo-inositol (1,4,5,6)-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
sinapaldehyde		C11 H12 O4 	C(=O)C=Cc1(cc(OC)c(O)c(c1)OC)		1.1.1.195	sinapaldehyde + NADPH  =  sinapyl-alcohol + NADP+	lignin biosynthesis
sinapaldehyde		C11 H12 O4 	C(=O)C=Cc1(cc(OC)c(O)c(c1)OC)		RXN-92	sinapaldehyde + UDP-D-glucose  =  sinapaldehyde glucoside + UDP	monolignol glucosides biosynthesis
sinapaldehyde		C11 H12 O4 	C(=O)C=Cc1(cc(OC)c(O)c(c1)OC)		2.1.1.68	5-hydroxy-coniferaldehyde + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + sinapaldehyde	lignin biosynthesis
CMP	5'-cytidylic acid*cytidine-5'-monophosphate*cytidylate*cytidylic acid*C*cytidine-P*cytidine-monophosphate*cytidine-phosphate*cytidine-5'-phosphate	C9 H14 N3 O8 P1 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)O))	LIGAND-CPD:C00055*CAS:84-52-6*CAS:63-37-6*PUBCHEM:6131	2.7.8.2	1,2-diacylglycerol + CDP-choline  =  a phosphatidylcholine + CMP	choline biosynthesis III
CMP	5'-cytidylic acid*cytidine-5'-monophosphate*cytidylate*cytidylic acid*C*cytidine-P*cytidine-monophosphate*cytidine-phosphate*cytidine-5'-phosphate	C9 H14 N3 O8 P1 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)O))	LIGAND-CPD:C00055*CAS:84-52-6*CAS:63-37-6*PUBCHEM:6131	6.3.2.5	D-4'-phosphopantothenate + L-cysteine + CTP  =  R-4'-phosphopantothenoyl-L-cysteine + pyrophosphate + CMP	coenzyme A biosynthesis
CMP	5'-cytidylic acid*cytidine-5'-monophosphate*cytidylate*cytidylic acid*C*cytidine-P*cytidine-monophosphate*cytidine-phosphate*cytidine-5'-phosphate	C9 H14 N3 O8 P1 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)O))	LIGAND-CPD:C00055*CAS:84-52-6*CAS:63-37-6*PUBCHEM:6131	2.-.-.-	lipid IV(A) + CMP-3-deoxy-D-manno-octulosonate  =  (KDO)-lipid IV(A) + CMP	lipid-A-precursor biosynthesis
CMP	5'-cytidylic acid*cytidine-5'-monophosphate*cytidylate*cytidylic acid*C*cytidine-P*cytidine-monophosphate*cytidine-phosphate*cytidine-5'-phosphate	C9 H14 N3 O8 P1 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)O))	LIGAND-CPD:C00055*CAS:84-52-6*CAS:63-37-6*PUBCHEM:6131	2.7.8.2	1,2-diacylglycerol + CDP-choline  =  a phosphatidylcholine + CMP	phospholipid biosynthesis
CMP	5'-cytidylic acid*cytidine-5'-monophosphate*cytidylate*cytidylic acid*C*cytidine-P*cytidine-monophosphate*cytidine-phosphate*cytidine-5'-phosphate	C9 H14 N3 O8 P1 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)O))	LIGAND-CPD:C00055*CAS:84-52-6*CAS:63-37-6*PUBCHEM:6131	2.7.8.1	1,2-diacylglycerol + CDP-ethanolamine  =  L-1-phosphatidyl-ethanolamine + CMP	phospholipid biosynthesis
CMP	5'-cytidylic acid*cytidine-5'-monophosphate*cytidylate*cytidylic acid*C*cytidine-P*cytidine-monophosphate*cytidine-phosphate*cytidine-5'-phosphate	C9 H14 N3 O8 P1 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)O))	LIGAND-CPD:C00055*CAS:84-52-6*CAS:63-37-6*PUBCHEM:6131	RXN0-302	4-diphosphocytidyl-2-C-methylerythritol 2-phosphate  =  2-C-methyl-D-erythritol-2,4-cyclodiphosphate + CMP	isopentenyl diphosphate biosynthesis -- mevalonate-independent
CMP	5'-cytidylic acid*cytidine-5'-monophosphate*cytidylate*cytidylic acid*C*cytidine-P*cytidine-monophosphate*cytidine-phosphate*cytidine-5'-phosphate	C9 H14 N3 O8 P1 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)O))	LIGAND-CPD:C00055*CAS:84-52-6*CAS:63-37-6*PUBCHEM:6131	2.7.8.5	CDP-diacylglycerol + glycerol-3-phosphate  =  L-1-phosphatidylglycerol-phosphate + CMP	phospholipid biosynthesis
CMP	5'-cytidylic acid*cytidine-5'-monophosphate*cytidylate*cytidylic acid*C*cytidine-P*cytidine-monophosphate*cytidine-phosphate*cytidine-5'-phosphate	C9 H14 N3 O8 P1 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)O))	LIGAND-CPD:C00055*CAS:84-52-6*CAS:63-37-6*PUBCHEM:6131	2.7.8.11	CDP-diacylglycerol + myo-inositol  =  L-1-phosphatidyl-inositol + CMP	phospholipid biosynthesis
saccharopine	N6-(L-1,3-dicarboxypropyl)-L-lysine*&epsilon;-N-(L-glutar-2-yl)-L-lysine	C11 H20 N2 O6 	C(=O)(O)C(CCC(O)=O)NCCCCC(N)C(=O)O	CAS:997-68-2	1.5.1.9	H2O + NAD+ + saccharopine  =  NADH + allysine + L-glutamate	lysine degradation II
saccharopine	N6-(L-1,3-dicarboxypropyl)-L-lysine*&epsilon;-N-(L-glutar-2-yl)-L-lysine	C11 H20 N2 O6 	C(=O)(O)C(CCC(O)=O)NCCCCC(N)C(=O)O	CAS:997-68-2	1.5.1.8	NADPH + alpha-ketoglutarate + L-lysine  =  H2O + NADP+ + saccharopine	lysine degradation II
tRNAgln	TRNA(GLN)				6.1.1.18	tRNAgln + L-glutamine + ATP  =  L-glutaminyl-tRNAgln + pyrophosphate + AMP	tRNA charging pathway
L-asparagine	asparagine*&alpha;-aminosuccinamic acid*(-)-asparagine*(S)-2,4-diamino-4-oxobutanoic acid*(S)-asparagine*2,4-diamino-4-oxobutanoic acid, (S)-*2-aminosuccinamic acid, L-*agedoite*altheine*asparagine acid*aspartic acid beta-amide*butanoic acid, 2,4-diamino-4-oxo-, (S)-*L-2,4-diamino-4-oxobutanoic acid*L-asparatamine*L-&beta;-asparagine	C4 H8 N2 O3 	C(N)(=O)CC(N)C(O)=O	LIGAND:C00152*CAS:70-47-3*CAS:7006-34-0	6.1.1.22	tRNAasn + L-asparagine + ATP  =  L-asparaginyl-tRNAasn + pyrophosphate + AMP	tRNA charging pathway
L-asparagine	asparagine*&alpha;-aminosuccinamic acid*(-)-asparagine*(S)-2,4-diamino-4-oxobutanoic acid*(S)-asparagine*2,4-diamino-4-oxobutanoic acid, (S)-*2-aminosuccinamic acid, L-*agedoite*altheine*asparagine acid*aspartic acid beta-amide*butanoic acid, 2,4-diamino-4-oxo-, (S)-*L-2,4-diamino-4-oxobutanoic acid*L-asparatamine*L-&beta;-asparagine	C4 H8 N2 O3 	C(N)(=O)CC(N)C(O)=O	LIGAND:C00152*CAS:70-47-3*CAS:7006-34-0	3.5.1.1	L-asparagine + H2O  =  NH3 + L-aspartate	asparagine degradation I
L-asparagine	asparagine*&alpha;-aminosuccinamic acid*(-)-asparagine*(S)-2,4-diamino-4-oxobutanoic acid*(S)-asparagine*2,4-diamino-4-oxobutanoic acid, (S)-*2-aminosuccinamic acid, L-*agedoite*altheine*asparagine acid*aspartic acid beta-amide*butanoic acid, 2,4-diamino-4-oxo-, (S)-*L-2,4-diamino-4-oxobutanoic acid*L-asparatamine*L-&beta;-asparagine	C4 H8 N2 O3 	C(N)(=O)CC(N)C(O)=O	LIGAND:C00152*CAS:70-47-3*CAS:7006-34-0	6.3.5.4	H2O + L-glutamine + L-aspartate + ATP  =  L-glutamate + L-asparagine + pyrophosphate + AMP	asparagine biosynthesis
benzyl-desulfoglucosinolate		C14 H19 N1 O6 S1 	C(O)C1(C(OC(O)C(O)C(O)1)SC(=NO)cc2(ccccc2))		2.8.2.-	benzyl-desulfoglucosinolate + PAPS  =  benzyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from phenylalanine
benzyl-desulfoglucosinolate		C14 H19 N1 O6 S1 	C(O)C1(C(OC(O)C(O)C(O)1)SC(=NO)cc2(ccccc2))		2.4.1.-	phenylacetothiohydroximate + UDP-D-glucose  =  benzyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from phenylalanine
N-formylkynurenine	<i>N</i>-Formyl-L-kynurenine	C11 H12 N2 O4 	C(=O)(O)C(N)CC(=O)c1(c(NC=O)cccc1)	CAS:1022-31-7	3.5.1.9	N-formylkynurenine + H2O  =  kynurenine + formate	NAD biosynthesis II (from tryptophan)
N-formylkynurenine	<i>N</i>-Formyl-L-kynurenine	C11 H12 N2 O4 	C(=O)(O)C(N)CC(=O)c1(c(NC=O)cccc1)	CAS:1022-31-7	3.5.1.9	N-formylkynurenine + H2O  =  kynurenine + formate	tryptophan degradation
N-formylkynurenine	<i>N</i>-Formyl-L-kynurenine	C11 H12 N2 O4 	C(=O)(O)C(N)CC(=O)c1(c(NC=O)cccc1)	CAS:1022-31-7	1.13.11.11	O2 + L-tryptophan  =  N-formylkynurenine	NAD biosynthesis II (from tryptophan)
N-formylkynurenine	<i>N</i>-Formyl-L-kynurenine	C11 H12 N2 O4 	C(=O)(O)C(N)CC(=O)c1(c(NC=O)cccc1)	CAS:1022-31-7	1.13.11.11	O2 + L-tryptophan  =  N-formylkynurenine	tryptophan degradation
deamido-NAD	NaADN*deamido-NAD<sup>+</sup>*deamidonicotinamide adenine dinucleoetide*nicotinate adenine dinucleotide*NAAD	C21 H27 N6 O15 P2 	C(O)(=O)c1(c[n+1](ccc1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(=O)(O)OP(O)(=O)OC[CH]3(O[CH]([CH](O)[CH]3O)n4(c5(c(nc4)c(N)ncn5)))))	CAS:6450-77-7	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis II (from tryptophan)
deamido-NAD	NaADN*deamido-NAD<sup>+</sup>*deamidonicotinamide adenine dinucleoetide*nicotinate adenine dinucleotide*NAAD	C21 H27 N6 O15 P2 	C(O)(=O)c1(c[n+1](ccc1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(=O)(O)OP(O)(=O)OC[CH]3(O[CH]([CH](O)[CH]3O)n4(c5(c(nc4)c(N)ncn5)))))	CAS:6450-77-7	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis I (from aspartate)
deamido-NAD	NaADN*deamido-NAD<sup>+</sup>*deamidonicotinamide adenine dinucleoetide*nicotinate adenine dinucleotide*NAAD	C21 H27 N6 O15 P2 	C(O)(=O)c1(c[n+1](ccc1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(=O)(O)OP(O)(=O)OC[CH]3(O[CH]([CH](O)[CH]3O)n4(c5(c(nc4)c(N)ncn5)))))	CAS:6450-77-7	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	pyridine nucleotide cycling
deamido-NAD	NaADN*deamido-NAD<sup>+</sup>*deamidonicotinamide adenine dinucleoetide*nicotinate adenine dinucleotide*NAAD	C21 H27 N6 O15 P2 	C(O)(=O)c1(c[n+1](ccc1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(=O)(O)OP(O)(=O)OC[CH]3(O[CH]([CH](O)[CH]3O)n4(c5(c(nc4)c(N)ncn5)))))	CAS:6450-77-7	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	NAD biosynthesis I (from aspartate)
deamido-NAD	NaADN*deamido-NAD<sup>+</sup>*deamidonicotinamide adenine dinucleoetide*nicotinate adenine dinucleotide*NAAD	C21 H27 N6 O15 P2 	C(O)(=O)c1(c[n+1](ccc1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(=O)(O)OP(O)(=O)OC[CH]3(O[CH]([CH](O)[CH]3O)n4(c5(c(nc4)c(N)ncn5)))))	CAS:6450-77-7	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	pyridine nucleotide cycling
deamido-NAD	NaADN*deamido-NAD<sup>+</sup>*deamidonicotinamide adenine dinucleoetide*nicotinate adenine dinucleotide*NAAD	C21 H27 N6 O15 P2 	C(O)(=O)c1(c[n+1](ccc1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(=O)(O)OP(O)(=O)OC[CH]3(O[CH]([CH](O)[CH]3O)n4(c5(c(nc4)c(N)ncn5)))))	CAS:6450-77-7	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	NAD biosynthesis II (from tryptophan)
deamido-NAD	NaADN*deamido-NAD<sup>+</sup>*deamidonicotinamide adenine dinucleoetide*nicotinate adenine dinucleotide*NAAD	C21 H27 N6 O15 P2 	C(O)(=O)c1(c[n+1](ccc1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(=O)(O)OP(O)(=O)OC[CH]3(O[CH]([CH](O)[CH]3O)n4(c5(c(nc4)c(N)ncn5)))))	CAS:6450-77-7	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	NAD biosynthesis I (from aspartate)
deamido-NAD	NaADN*deamido-NAD<sup>+</sup>*deamidonicotinamide adenine dinucleoetide*nicotinate adenine dinucleotide*NAAD	C21 H27 N6 O15 P2 	C(O)(=O)c1(c[n+1](ccc1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(=O)(O)OP(O)(=O)OC[CH]3(O[CH]([CH](O)[CH]3O)n4(c5(c(nc4)c(N)ncn5)))))	CAS:6450-77-7	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	pyridine nucleotide cycling
131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester		C35 H32 N4 O5 MG1 	Cc6(c(C(=O)CC(=O)OC)c1(n7([Mg]35(n4(c(C=C2(C(C)=C(C(C=1)=N23)CCC(O)=O))c(C)c(C=C)c4C=C8(N5=C(C=c67)C(C=C)=C(C)8))))))		1.14.13.81	131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  divinyl protochlorophyllide a + NADP+ + 2 H2O	chlorophyllide a biosynthesis
131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester		C35 H32 N4 O5 MG1 	Cc6(c(C(=O)CC(=O)OC)c1(n7([Mg]35(n4(c(C=C2(C(C)=C(C(C=1)=N23)CCC(O)=O))c(C)c(C=C)c4C=C8(N5=C(C=c67)C(C=C)=C(C)8))))))		1.14.13.81	131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + 2 H2O	chlorophyllide a biosynthesis
tRNAala	TRNA(ALA)				6.1.1.7	tRNAala + L-alanine + ATP  =  L-alanyl-tRNAala + pyrophosphate + AMP	tRNA charging pathway
GA8-catabolite	gibberellin A<sub>8</sub>-catabolite*gibberellin A8-catabolite*GA8-catabolite	C19 H22 O7 	CC1([CH]4(C(=CC(=O)C(O)1)[CH]3(C2(CC(C(=C)C2)(O)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA8 + alpha-ketoglutarate + O2  =  GA8-catabolite + succinate + CO2 + H2O	gibberellin inactivation
histidinol	histidol*histidinol*L-histidinol	C6 H11 N3 O1 	c1(c(nc[nH]1)CC(N)CO)	CAS:501-28-0	1.1.1.23	histidinol + NAD+  =  histidinal + NADH	histidine biosynthesis
histidinol	histidol*histidinol*L-histidinol	C6 H11 N3 O1 	c1(c(nc[nH]1)CC(N)CO)	CAS:501-28-0	3.1.3.15	L-histidinol-phosphate + H2O  =  histidinol + phosphate	histidine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	flavonoid biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	lignin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	formylTHF biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.22	tRNAasn + L-asparagine + ATP  =  L-asparaginyl-tRNAasn + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.19	tRNAarg + L-arginine + ATP  =  L-arginyl-tRNAarg + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.7	tRNAala + L-alanine + ATP  =  L-alanyl-tRNAala + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.19	D-ribulose-5-phosphate + ATP  =  D-ribulose-1,5-bisphosphate + ADP	Calvin cycle
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.15	L-proline + tRNApro + ATP  =  L-prolyl-tRNApro + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.14	tRNAgly + glycine + ATP  =  glycyl-tRNAgly + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.9	tRNAval + L-valine + ATP  =  L-valyl-tRNAval + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.10	tRNAmet + L-methionine + ATP  =  L-methionyl-tRNAmet + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.4	L-leucine + tRNAleu + ATP  =  L-leucyl-tRNAleu + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.5	tRNAile + L-isoleucine + ATP  =  L-isoleucyl-tRNAile + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	sucrose degradation to ethanol and lactate (anaerobic)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	sucrose degradation to ethanol and lactate (anaerobic)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.2	mevalonate-5P + ATP  =  mevalonate-5-PP + ADP	mevalonate pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.11	tRNAser + L-serine + ATP  =  L-seryl-tRNAser + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	glycine degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	carbon monoxide dehydrogenase pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.23	NAD+ + ATP  =  NADP+ + ADP	NAD/NADH phosphorylation and dephosphorylation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	colanic acid building blocks biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	galactose degradation II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	galactose degradation I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.71	shikimate + ATP  =  shikimate-3-phosphate + ADP	chorismate biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	glutamine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	ammonia assimilation cycle
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	nitrate assimilation pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.30	glycerol + ATP  =  glycerol-3-phosphate + ADP	glycerol degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	SAM cycle
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	ethylene biosynthesis from methionine
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	adenosylmethionine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine salvage pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine degradation I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.20	tRNAphe + L-phenylalanine + ATP  =  L-phenylalanyl-tRNAphe + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.3	tRNAthr + L-threonine + ATP  =  L-threonyl-tRNAthr + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.7.4	SO42- + ATP  =  APS + pyrophosphate	sulfate assimilation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	Calvin cycle
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	sucrose degradation to ethanol and lactate (anaerobic)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glycolysis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glycolysis II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	gluconeogenesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glyceraldehyde 3-phosphate degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.4	L-aspartate + ATP  =  L-aspartyl-4-phosphate + ADP	homoserine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.4	L-aspartate + ATP  =  L-aspartyl-4-phosphate + ADP	lysine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.15	D-ribose + ATP  =  D-ribose-5-phosphate + ADP	ribose degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	gluconeogenesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	glyceraldehyde 3-phosphate degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.7.27	alpha-D-glucose-1-phosphate + ATP  =  ADP-D-glucose + pyrophosphate	starch biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.6.1	ATP + D-ribose-5-phosphate  =  PRPP + AMP	PRPP biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.4	fructose + ATP  =  D-fructose-6-phosphate + ADP	sucrose degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.4	fructose + ATP  =  D-fructose-6-phosphate + ADP	sucrose degradation to ethanol and lactate (anaerobic)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.7	hydroxymethylpyrimidine phosphate + ATP  =  4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate + ADP	thiamin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.39	homoserine + ATP  =  O-phospho-L-homoserine + ADP	threonine biosynthesis from homoserine
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.39	homoserine + ATP  =  O-phospho-L-homoserine + ADP	methionine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.1	L-tyrosine + tRNAtyr + ATP  =  L-tyrosyl-tRNAtyr + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.2	tRNAtrp + L-tryptophan + ATP  =  L-tryptophanyl-tRNAtrp + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis II (from tryptophan)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis I (from aspartate)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	pyridine nucleotide cycling
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.12	ATP + gluconate  =  6-phospho-D-gluconate + ADP	superpathway of gluconate degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	4.1.1.33	mevalonate-5-PP + ATP  =  phosphate + CO2 + delta3-isopentenyl-PP + ADP	mevalonate pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.3	AMP + ATP  =  ADP + ADP	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	4.1.1.21	5-aminoimidazole ribonucleotide + ATP + CO2 + H2O  =  phosphate + phosphoribosyl-carboxy-aminoimidazole + ADP	de novo biosynthesis of purine nucleotides II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.4.2.11	nicotinate + H2O + PRPP + ATP  =  nicotinate nucleotide + pyrophosphate + phosphate + ADP	pyridine nucleotide cycling
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.8	N-acetyl-L-glutamate + ATP  =  N-acetylglutamyl-phosphate + ADP	arginine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.8	N-acetyl-L-glutamate + ATP  =  N-acetylglutamyl-phosphate + ADP	arginine biosynthesis II (acetyl cycle)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	superpathway of glyoxylate cycle
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	gluconeogenesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.8	GMP + ATP  =  GDP + ADP	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.-	ATP + UMP  =  ADP + UDP	de novo biosynthesis of pyrimidine ribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.33	pantothenate + ATP  =  D-4'-phosphopantothenate + ADP	coenzyme A biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.16	tRNAcys + L-cysteine + ATP  =  L-cysteinyl-tRNAcys + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.20	adenosine + ATP  =  AMP + ADP	salvage pathways of purine nucleosides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.6.5	GTP + ATP  =  guanosine 3'-diphosphate 5'-triphosphate + AMP	ppGpp biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.9	dTMP + ATP  =  dTDP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.6	tRNAlys + L-lysine + ATP  =  L-lysyl-tRNAlys + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.50	ATP + 4-methyl-5-(beta-hydroxyethyl)thiazole  =  ADP + 4-methyl-5-(beta-hydroxyethyl)thiazole phosphate	thiamin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.21	tRNAhis + L-histidine + ATP  =  L-histidyl-tRNAhis + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.12	tRNAasp + L-aspartate + ATP  =  L-aspartyl-tRNAasp + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.6	GDP + ATP  =  GTP + ADP	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis II (acetyl cycle)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis III
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.2	carbamoyl-phosphate + ADP  =  NH3 + CO2 + ATP	citrulline degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.2	L-cysteine + L-glutamate + ATP  =  L-gamma-glutamylcysteine + phosphate + ADP	glutathione biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.26	riboflavin + ATP  =  FMN + ADP	riboflavin and FMN and FAD biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.1	beta-alanine + L-pantoate + ATP  =  pantothenate + pyrophosphate + AMP	pantothenate biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	chlorophyllide a biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	biosynthesis of proto- and siroheme
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.36	mevalonate + ATP  =  mevalonate-5P + ADP	mevalonate pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.3.3	CO2 + 7,8-diaminononanoate + ATP  =  dethiobiotin + phosphate + ADP	biotin biosynthesis II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	ATP + pyridoxine  =  ADP + pyridoxine-5'-phosphate	pyridoxal 5'-phosphate salvage pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.3	glycine + L-gamma-glutamylcysteine + ATP  =  glutathione + phosphate + ADP	glutathione biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.3.2	N5-formyl-H4F + ATP  =  5,10-methenyl-THF + ADP + phosphate	formylTHF biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.7.2	FMN + ATP  =  FAD + pyrophosphate	riboflavin and FMN and FAD biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	NAD biosynthesis I (from aspartate)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	pyridine nucleotide cycling
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	NAD biosynthesis II (from tryptophan)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	NAD biosynthesis I (from aspartate)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	pyridine nucleotide cycling
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.4.1.2	HCO3- + H+ + acetyl-CoA + ATP  =  malonyl-CoA + phosphate + ADP	fatty acid biosynthesis - initial steps
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.6	dADP + ATP  =  dATP + ADP	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.6	dGDP + ATP  =  dGTP + ADP	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	RXN0-745	ATP + reduced flavodoxin  =  dATP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	RXN0-742	5-aminoimidazole ribonucleotide + ATP + H2O + CO2  =  N5-carboxyaminoimidazole ribonucleotide + ADP + phosphate	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	salvage pathways of purine nucleosides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.1.2.-	5-phospho-ribosyl-glycineamide + formate + ATP  =  phosphate + 5'-phosphoribosyl-N-formylglycineamide + ADP	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.6	CTP + ADP  =  CDP + ATP	de novo biosynthesis of pyrimidine ribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.6	UDP + ATP  =  UTP + ADP	de novo biosynthesis of pyrimidine ribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.6.3	6-hydroxymethyl-dehydropterin + ATP  =  2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate + AMP	tetrahydrofolate biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.6.3	6-hydroxymethyl-dehydropterin + ATP  =  2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate + AMP	tetrahydrofolate biosynthesis II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.2.1	acetylphosphate + ADP  =  acetate + ATP	carbon monoxide dehydrogenase pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  AMP + pyrophosphate + O-succinylbenzoyl-CoA	menaquinone biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.31	glycerate + ATP  =  3-phosphoglycerate + ADP	photorespiration
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.7	mannose + ATP  =  mannose-6-phosphate + ADP	mannitol degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.12	caffeate + coenzyme A + ATP  =  caffeoyl-CoA + AMP + pyrophosphate	suberin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.12	ferulate + coenzyme A + ATP  =  feruloyl-CoA + AMP + pyrophosphate	suberin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	PROPIONYL-COA-CARBOXYLASE-RXN	propionyl-CoA + H2O + ATP + CO2  =  D-methylmalonyl-CoA + phosphate + ADP	methionine degradation I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle variation I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle -- aerobic respiration
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.3	coenzyme A + a fatty acid + ATP  =  acyl-CoA + pyrophosphate + AMP	fatty acid beta-oxidation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	isoleucine degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	valine degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.4.1.4	HCO3- + 3-methylcrotonyl-CoA + ATP  =  phosphate + trans-3-methylglutaconyl-CoA + ADP	leucine degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.-.-	4-diphosphocytidyl-2-C-methylerythritol + ATP  =  4-diphosphocytidyl-2-C-methylerythritol 2-phosphate + ADP	isopentenyl diphosphate biosynthesis -- mevalonate-independent
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.49	ATP + hydroxymethylpyrimidine  =  ADP + hydroxymethylpyrimidine phosphate	thiamin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.16	thiamine-phosphate + ATP  =  thiamin diphosphate + ADP	thiamin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.89	thiamine + ATP  =  thiamine-phosphate + ADP	thiamin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.6	dTDP + ATP  =  dTTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.6	dUDP + ATP  =  dUTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.4.6	dCDP + ATP  =  dCTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.45	2-dehydro-3-deoxy-D-gluconate + ATP  =  2-keto-3-deoxy-6-phospho-gluconate + ADP	beta-D-glucuronide degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.130	lipid A disaccharide + ATP  =  lipid IV(A) + ADP	lipid-A-precursor biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	GDPPYPHOSKIN-RXN	ATP + GDP  =  AMP + guanosine 5'-diphosphate,3'-diphosphate	ppGpp biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.24	dephospho-CoA + ATP  =  coenzyme A + ADP	coenzyme A biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.7.3	pantetheine 4'-phosphate + ATP  =  dephospho-CoA + pyrophosphate	coenzyme A biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.35	ATP + pyridoxal  =  ADP + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	PYRAMKIN-RXN	ATP + pyridoxamine  =  ADP + pyridoxamine 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.17	xylulose + ATP  =  D-xylulose-5-phosphate + ADP	xylose degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.5.1.-	dimethylallyl-pyrophosphate + ATP  =  isopentenyladenosine-5'-triphosphate + pyrophosphate	trans-zeatin biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.1	alpha-D-glucose + ATP  =  alpha-D-glucose-6-phosphate + ADP	sucrose degradation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.82	ethanolamine + ATP  =  phosphoryl-ethanolamine + ADP	choline biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.2.17	tetrahydrofolate + L-glutamate + ATP  =  THF-L-glutamate + ADP + phosphate	tetrahydrofolate biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.100	5-methylthioribose + ATP  =  5-methylthioribose-1-phosphate + ADP	methionine salvage pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	arginine biosynthesis III
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	proline biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.6.1.1	ATP + protoporphyrin IX + Mg2+ + H2O  =  Mg-protoporphyrin + H+ + phosphate + ADP	chlorophyllide a biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.5.4	H2O + L-glutamine + L-aspartate + ATP  =  L-glutamate + L-asparagine + pyrophosphate + AMP	asparagine biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.2	L-glutamine + H2O + UTP + ATP  =  CTP + phosphate + ADP + L-glutamate	de novo biosynthesis of pyrimidine ribonucleotides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.1.1.18	tRNAgln + L-glutamine + ATP  =  L-glutaminyl-tRNAgln + pyrophosphate + AMP	tRNA charging pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.17	coenzyme A + propionate + ATP  =  propionyl-CoA + pyrophosphate + AMP	beta-alanine biosynthesis II
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	D-myo-inositol (1,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,2,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.151	inositol 1,4,5-trisphosphate + ATP  =  D-myo-inositol (1,4,5,6)-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	D-myo-inositol (1,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-independent phytate biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	D-myo-inositol (1,3,4,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,2,3,4,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	D-myo-inositol (1,2,3,4,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.-	1D-myo-inositol 1,3,4,5-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.133	D-myo-inositol (1,3,4)-trisphosphate + ATP  =  D-myo-inositol (1,3,4,6)-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.140	D-myo-inositol (1,3,4,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.139	D-myo-inositol (1,3,4)-trisphosphate + ATP  =  1D-myo-inositol 1,3,4,5-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.64	myo-inositol + ATP  =  D-myo-inositol (3)-monophosphate + ADP	lipid-independent phytate biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	RXN-7202	D-myo-inositol (3)-monophosphate + ATP  =  D-myo-inositol (3,4)-bisphosphate + ADP	lipid-independent phytate biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.134	D-myo-inositol (3,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-independent phytate biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	RXN-7203	D-myo-inositol (3,4)-bisphosphate + ATP  =  D-myo-inositol (3,4,6)-trisphosphate + ADP	lipid-independent phytate biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	RXN-7204	D-myo-inositol (3,4,6)-trisphosphate + ATP  =  D-myo-inositol (3,4,5,6)-tetrakisphosphate + ADP	lipid-independent phytate biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.44	galacturonate + ATP  =  alpha-D-galacturonate 1-phosphate + ADP	UDP-D-galacturonate biosynthesis II (from D-galacturonate)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.43	glucuronate + ATP  =  alpha-D-glucuronate 1-phosphate + ADP	inositol oxidation pathway
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.46	L-arabinose + ATP  =  beta-L-arabinose 1-phosphate + ADP	UDP-L-arabinose biosynthesis II (from L-arabinose)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.52	L-fucose + ATP  =  beta-L-fucose 1-phosphate + ADP	GDP-L-fucose biosynthesis II (from L-fucose)
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  4-(2'-carboxyphenyl)-4-oxobutyryl-CoA + AMP + pyrophosphate	phylloquinone biosynthesis
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.86	NADH + ATP  =  NADPH + ADP	NAD/NADH phosphorylation and dephosphorylation
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.73	inosine + ATP  =  IMP + ADP	salvage pathways of purine nucleosides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.7.1.73	guanosine + ATP  =  GMP + ADP	salvage pathways of purine nucleosides
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	6.3.4.3	10-formyl-H4PteGlun + ADP + phosphate  =  THF polyglutamate + ATP + formate	tetrahydrofolate biosynthesis I
ATP	adenylpyrophosphate*adenosine-triphosphate*adenosine-5'-triphosphate	C10 H16 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00002*CAS:56-65-5	2.4.2.17	ATP + PRPP  =  phosphoribosyl-ATP + pyrophosphate	histidine biosynthesis
D-myo-inositol (1,2,3,4,6)-pentakisphosphate	Ins(1,2,3,4,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,2,3,4,6)-penta<i>kis</i>phosphate*inositol (1,2,3,4,6)-penta<i>kis</i>phosphate	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,2,3,4,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
D-myo-inositol (1,2,3,4,6)-pentakisphosphate	Ins(1,2,3,4,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,2,3,4,6)-penta<i>kis</i>phosphate*inositol (1,2,3,4,6)-penta<i>kis</i>phosphate	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,3,4,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,2,3,4,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.15	UDP-D-glucose + alpha-D-glucose-6-phosphate  =  UDP + trehalose 6-phosphate	trehalose biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	5.1.3.2	UDP-D-glucose  =  UDP-galactose	colanic acid building blocks biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	5.1.3.2	UDP-D-glucose  =  UDP-galactose	galactose degradation II
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	5.1.3.2	UDP-D-glucose  =  UDP-galactose	galactose degradation I
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	5.1.3.2	UDP-D-glucose  =  UDP-galactose	UDP-glucose conversion
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose degradation
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose degradation to ethanol and lactate (anaerobic)
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	galactose degradation I
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.14	D-fructose-6-phosphate + UDP-D-glucose  =  sucrose-6'-phosphate + UDP	sucrose biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	UDP-D-xylose biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	colanic acid building blocks biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	galactose degradation I
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.121	indole-3-acetate + UDP-D-glucose  =  indole-3-acetyl-beta-1-D-glucose + UDP	IAA conjugate biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.12	UDP-D-glucose + (1,4-beta-D-glucosyl)(n)  =  UDP + (1,4-beta-D-glucosyl)(n+1)	cellulose biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	3.13.1.1	UDP-D-glucose + SO3-2  =  UDP-sulfoquinovose + H2O	sulfolipid biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	indolylmethylthiohydroximate + UDP-D-glucose  =  indolylmethyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from tryptophan
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	4-methylthiobutylhydroximate + UDP-D-glucose  =  3-methylthiopropyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from homomethionine
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	trans-zeatin-O-glucoside + UDP-D-glucose  =  trans-zeatin-O-glucoside-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	cis-zeatin + UDP-D-glucose  =  cis-zeatin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	kinetin + UDP-D-glucose  =  kinetin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	benzyladenine + UDP-D-glucose  =  benzyladenine-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	isopentenyladenine + UDP-D-glucose  =  isopentenyladenine-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-7-N-dihydrozeatin + UDP	cytokinins 7-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	trans-zeatin + UDP-D-glucose  =  trans-zeatin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	cis-zeatin + UDP-D-glucose  =  cis-zeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	kinetin + UDP-D-glucose  =  kinetin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	benzyladenine + UDP-D-glucose  =  benzyladenine-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	isopentenyladenine + UDP-D-glucose  =  isopentenyladenine-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	trans-zeatin + UDP-D-glucose  =  trans-zeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	pelargonidin + UDP-D-glucose  =  pelargonidin-3-glucoside + UDP	anthocyanin biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	RXN1F-775	cyanidin + UDP-D-glucose  =  cyanidin-3-glucoside + UDP	anthocyanin biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.91	kaempferol + UDP-D-glucose  =  kaempferol-3-glucoside + UDP	flavonol biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.91	quercetin + UDP-D-glucose  =  quercetin-3-glucoside + UDP	flavonol biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	dihydrozeatin-9-N-glucoside + UDP-D-glucose  =  dihydrozeatin-9-N-glucoside-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.203	trans-zeatin + UDP-D-glucose  =  trans-zeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.-	phenylacetothiohydroximate + UDP-D-glucose  =  benzyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from phenylalanine
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.12	UDP-D-glucose + alpha-D-galactose-1-phosphate  =  alpha-D-glucose-1-phosphate + UDP-galactose	colanic acid building blocks biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.12	UDP-D-glucose + alpha-D-galactose-1-phosphate  =  alpha-D-glucose-1-phosphate + UDP-galactose	galactose degradation II
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.120	sinapate + UDP-D-glucose  =  1-O-sinapoyl-beta-D-glucose + UDP	sinapate ester biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	RXN1F-444	kaempferol-3-glucoside-7-rhamnoside + UDP-D-glucose  =  kaempferol-3-O-gentiobioside-7-O-rhamnoside + UDP	flavonol biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	RXN-6142	p-aminobenzoate + UDP-D-glucose  =  p-aminobenzoate-beta-D-glucopyranosyl ester + UDP	tetrahydrofolate biosynthesis I
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.215	cis-zeatin + UDP-D-glucose  =  cis-zeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.117	dolichyl-phosphate + UDP-D-glucose  =  dolichyl beta-D-glucosyl phosphate + UDP	dolichyl-diphosphooligosaccharide biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	RXN-95	dihydroconiferyl alcohol + UDP-D-glucose  =  dihydroconiferyl alcohol glucoside + UDP	monolignol glucosides biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	RXN-92	sinapaldehyde + UDP-D-glucose  =  sinapaldehyde glucoside + UDP	monolignol glucosides biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	RXN-91	coniferyl aldehyde + UDP-D-glucose  =  coniferaldehyde glucoside + UDP	monolignol glucosides biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.111	sinapyl-alcohol + UDP-D-glucose  =  syringin + UDP	monolignol glucosides biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.4.1.111	coniferyl alcohol + UDP-D-glucose  =  coniferin + UDP	coniferin metabolism
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	RXN-5482	UDP-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+ + H2O	UDP-L-rhamnose biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	4.2.1.76	UDP-D-glucose  =  H2O + UDP-4-dehydro-6-deoxy-D-glucose	UDP-L-rhamnose biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose degradation
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose degradation to ethanol and lactate (anaerobic)
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	colanic acid building blocks biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	galactose degradation II
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	galactose degradation I
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose biosynthesis
UDP-D-glucose	UDPG*UDP-glucose	C15 H24 N2 O17 P2 	C1(OC(CO)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	LIGAND-CPD:C00029*CAS:133-89-1	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	UDP-glucose conversion
24-ethylidenelophenol	(Z)-24-ethylidenelophenol*citrostadienol	C30 H50 O1 	CC=C(C(C)C)CC[CH](C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C)([CH](CC=3)C(C)C(O)CC4))))		2.1.1.-	24-ethylidenelophenol  =  avenasterol	sterol biosynthesis
24-ethylidenelophenol	(Z)-24-ethylidenelophenol*citrostadienol	C30 H50 O1 	CC=C(C(C)C)CC[CH](C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C)([CH](CC=3)C(C)C(O)CC4))))		2.1.1.143	24-methylenelophenol + S-adenosyl-L-methionine  =  24-ethylidenelophenol + S-adenosyl-homocysteine	sterol biosynthesis
episterol		C28 H46 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC=3)CC(O)CC4)(C))))		1.3.3.-	episterol  =  5-dehydro episterol	sterol biosynthesis
episterol		C28 H46 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC=3)CC(O)CC4)(C))))		2.1.1.-	24-methylenelophenol + S-adenosyl-homocysteine  =  episterol + S-adenosyl-L-methionine	sterol biosynthesis
avenasterol		C29 H48 O1 	CC(C)C(=CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC=3)CC(O)CC4)(C))))		1.3.3.-	avenasterol  =  5-dehydroavenasterol	sterol biosynthesis
avenasterol		C29 H48 O1 	CC(C)C(=CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC=3)CC(O)CC4)(C))))		2.1.1.-	24-ethylidenelophenol  =  avenasterol	sterol biosynthesis
5-dehydroavenasterol		C29 H46 O1 	CC(C)C(=CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC=3)CC(O)CC4)(C))))		1.3.1.21	5-dehydroavenasterol + 2 NADPH  =  isofucosterol + 2 NADP+	sterol biosynthesis
5-dehydroavenasterol		C29 H46 O1 	CC(C)C(=CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC=3)CC(O)CC4)(C))))		1.3.3.-	avenasterol  =  5-dehydroavenasterol	sterol biosynthesis
isofucosterol		C29 H48 O1 	CC(C)C(=CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4221	isofucosterol  =  delta24-25-sitosterol	sterol biosynthesis
isofucosterol		C29 H48 O1 	CC(C)C(=CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		1.3.1.21	5-dehydroavenasterol + 2 NADPH  =  isofucosterol + 2 NADP+	sterol biosynthesis
solanyl pyrophosphate		C45 H76 O7 P2 	CC(=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(O)(=O)O)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C		RXN-2761	homogentisate + solanyl pyrophosphate  =  2-methyl-6-solanyl-1,4-benzoquinone + CO2 + pyrophosphate	plastoquinone biosynthesis
L-1-phosphatidylserine	O-sn-phosphatidyl-L-serine*phosphatidyl-serine*3-O-sn-phosphatidyl-L-serine*phosphatidyl-L-serine*1-phosphatidyl-serine	C8 H12 N1 O10 R2 P1 			4.1.1.65	L-1-phosphatidylserine  =  L-1-phosphatidyl-ethanolamine + CO2	phospholipid biosynthesis
L-1-phosphatidylserine	O-sn-phosphatidyl-L-serine*phosphatidyl-serine*3-O-sn-phosphatidyl-L-serine*phosphatidyl-L-serine*1-phosphatidyl-serine	C8 H12 N1 O10 R2 P1 			RXN-1382	L-1-phosphatidyl-ethanolamine + L-serine  =  L-1-phosphatidylserine + ethanolamine	phospholipid biosynthesis
dihydrosterculate	dihydrosterculic acid	C19 H36 O2 	CCCCCCCCC1(C(C1)CCCCCCCC(O)=O)		RXN-7422	dihydrosterculate  =  sterculate	cyclopropane and cyclopropene fatty acid biosynthesis
dihydrosterculate	dihydrosterculic acid	C19 H36 O2 	CCCCCCCCC1(C(C1)CCCCCCCC(O)=O)		2.1.1.79	oleate + S-adenosyl-L-methionine  =  dihydrosterculate + S-adenosyl-homocysteine	cyclopropane and cyclopropene fatty acid biosynthesis
reduced flavodoxin	dihydro flavodoxin				RXN0-746	GTP + reduced flavodoxin  =  dGTP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
reduced flavodoxin	dihydro flavodoxin				RXN0-745	ATP + reduced flavodoxin  =  dATP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
reduced flavodoxin	dihydro flavodoxin				RXN0-723	CTP + reduced flavodoxin  =  dCTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
reduced flavodoxin	dihydro flavodoxin				RXN0-724	UTP + reduced flavodoxin  =  dUTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
GA29	gibberellin A<sub>29</sub>*gibberellin A29*GA29	C19 H24 O6 	C=C1(C2(CC5(C1)([CH](CC2)C34(OC(=O)C(CC(O)C3)(C)[CH]4C5C(=O)O)))(O))		1.14.11.-	GA29 + alpha-ketoglutarate + O2  =  GA29-catabolite + succinate + CO2 + H2O	gibberellin inactivation
GA29	gibberellin A<sub>29</sub>*gibberellin A29*GA29	C19 H24 O6 	C=C1(C2(CC5(C1)([CH](CC2)C34(OC(=O)C(CC(O)C3)(C)[CH]4C5C(=O)O)))(O))		1.14.11.-	GA20 + alpha-ketoglutarate + O2  =  GA29 + succinate + CO2	gibberellin inactivation
L-phosphatidate	phosphatidate  (E.coli)*L-phosphatidate*A 3-SN-phosphatidate*diacyl-glycerol-3p*diacyl-glycerol-p*1,2-diacyl-sn-glycerol-3-phosphate*phosphatidic acid*1,2-diacylglycerol-3-phosphate*phosphatidate*diacylglycerol-3-phosphate	C5 H7 O8 R2 P1 		LIGAND-CPD:C00416	2.7.7.41	CTP + L-phosphatidate  =  CDP-diacylglycerol + pyrophosphate	phospholipid biosynthesis
L-phosphatidate	phosphatidate  (E.coli)*L-phosphatidate*A 3-SN-phosphatidate*diacyl-glycerol-3p*diacyl-glycerol-p*1,2-diacyl-sn-glycerol-3-phosphate*phosphatidic acid*1,2-diacylglycerol-3-phosphate*phosphatidate*diacylglycerol-3-phosphate	C5 H7 O8 R2 P1 		LIGAND-CPD:C00416	3.1.3.4	H2O + L-phosphatidate  =  phosphate + 1,2-diacylglycerol	triacylglycerol biosynthesis
L-phosphatidate	phosphatidate  (E.coli)*L-phosphatidate*A 3-SN-phosphatidate*diacyl-glycerol-3p*diacyl-glycerol-p*1,2-diacyl-sn-glycerol-3-phosphate*phosphatidic acid*1,2-diacylglycerol-3-phosphate*phosphatidate*diacylglycerol-3-phosphate	C5 H7 O8 R2 P1 		LIGAND-CPD:C00416	3.1.3.4	H2O + L-phosphatidate  =  phosphate + 1,2-diacylglycerol	phospholipid biosynthesis
L-phosphatidate	phosphatidate  (E.coli)*L-phosphatidate*A 3-SN-phosphatidate*diacyl-glycerol-3p*diacyl-glycerol-p*1,2-diacyl-sn-glycerol-3-phosphate*phosphatidic acid*1,2-diacylglycerol-3-phosphate*phosphatidate*diacylglycerol-3-phosphate	C5 H7 O8 R2 P1 		LIGAND-CPD:C00416	3.1.4.4	a phosphatidylcholine + H2O  =  L-phosphatidate + choline	choline biosynthesis III
L-phosphatidate	phosphatidate  (E.coli)*L-phosphatidate*A 3-SN-phosphatidate*diacyl-glycerol-3p*diacyl-glycerol-p*1,2-diacyl-sn-glycerol-3-phosphate*phosphatidic acid*1,2-diacylglycerol-3-phosphate*phosphatidate*diacylglycerol-3-phosphate	C5 H7 O8 R2 P1 		LIGAND-CPD:C00416	3.1.4.4	a phosphatidylcholine + H2O  =  L-phosphatidate + choline	lipases pathway
L-phosphatidate	phosphatidate  (E.coli)*L-phosphatidate*A 3-SN-phosphatidate*diacyl-glycerol-3p*diacyl-glycerol-p*1,2-diacyl-sn-glycerol-3-phosphate*phosphatidic acid*1,2-diacylglycerol-3-phosphate*phosphatidate*diacylglycerol-3-phosphate	C5 H7 O8 R2 P1 		LIGAND-CPD:C00416	2.3.1.51	fatty-acyl-CoA + 1-acyl-sn-glycerol-3P  =  L-phosphatidate + coenzyme A	triacylglycerol biosynthesis
D-ribulose-1,5-bisphosphate	ribulose 1,5-bisphosphate*D-ribulose-1,5-diphosphate*D-ribulose-1,5-P<SUB>2</SUB>	C5 H12 O11 P2 	C(OP(=O)(O)O)C(O)C(O)C(=O)COP(O)(O)=O	CAS:14689-84-0	4.1.1.39	H2O + CO2 + D-ribulose-1,5-bisphosphate  =  2 3-phosphoglycerate	Calvin cycle
D-ribulose-1,5-bisphosphate	ribulose 1,5-bisphosphate*D-ribulose-1,5-diphosphate*D-ribulose-1,5-P<SUB>2</SUB>	C5 H12 O11 P2 	C(OP(=O)(O)O)C(O)C(O)C(=O)COP(O)(O)=O	CAS:14689-84-0	4.1.1.-	D-ribulose-1,5-bisphosphate + O2  =  2-phosphoglycolate + 3-phosphoglycerate + 2 H+	photorespiration
D-ribulose-1,5-bisphosphate	ribulose 1,5-bisphosphate*D-ribulose-1,5-diphosphate*D-ribulose-1,5-P<SUB>2</SUB>	C5 H12 O11 P2 	C(OP(=O)(O)O)C(O)C(O)C(=O)COP(O)(O)=O	CAS:14689-84-0	2.7.1.19	D-ribulose-5-phosphate + ATP  =  D-ribulose-1,5-bisphosphate + ADP	Calvin cycle
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		2.4.1.83	dolichyl-phosphate + GDP-mannose  =  dolichyl beta-D-mannosyl phosphate + GDP	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		2.7.8.15	dolichyl-phosphate + UDP-N-acetyl-D-glucosamine  =  N-acetylglucosaminyl-diphosphodolichol + UMP	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		2.4.1.117	dolichyl-phosphate + UDP-D-glucose  =  dolichyl beta-D-glucosyl phosphate + UDP	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		2.7.1.108	dolichol + CTP  =  dolichyl-phosphate + CDP	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		RXN-5466	(mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		RXN-5468	(mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		RXN-5469	(mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol   + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		RXN-5472	(glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-glucosyl phosphate  =  (glucosyl)3-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		RXN-5470	(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol   + dolichyl beta-D-glucosyl phosphate  =  glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		RXN-5471	glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-glucosyl phosphate  =  (glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl-phosphate	dolichol-phosphate*Dolychol phosphate	C80 H133 O4 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)O		RXN-5467	(mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	6.1.1.7	tRNAala + L-alanine + ATP  =  L-alanyl-tRNAala + pyrophosphate + AMP	tRNA charging pathway
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	2.3.1.47	L-alanine + 6-carboxyhexanoyl-CoA  =  CO2 + coenzyme A + 8-amino-7-oxononanoate	biotin biosynthesis II
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	2.6.1.2	alpha-ketoglutarate + L-alanine  =  L-glutamate + pyruvate	alanine degradation
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	2.6.1.2	alpha-ketoglutarate + L-alanine  =  L-glutamate + pyruvate	alanine biosynthesis
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	RXN-2944	indole-3-acetate + L-alanine  =  indole-3-acetyl-ala + H2O	IAA conjugate biosynthesis
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	2.6.1.18	malonate semialdehyde + L-alanine  =  beta-alanine + pyruvate	beta-alanine biosynthesis II
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	2.6.1.19	4-aminobutyrate + pyruvate  =  succinate semialdehyde + L-alanine	glutamate degradation II
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	3.5.1.-	indole-3-acetyl-ala + H2O  =  indole-3-acetate + L-alanine	IAA biosynthesis II
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	3.7.1.3	3-hydroxy-L-kynurenine + H2O  =  3-hydroxy-anthranilate + L-alanine	NAD biosynthesis II (from tryptophan)
L-alanine	alanine*L-&alpha;-alanine	C3 H7 N1 O2 	C(O)(=O)C(N)C	LIGAND-CPD:C00041*LIGAND:C00041*CAS:6898-94-8*CAS:56-41-7	3.7.1.3	3-hydroxy-L-kynurenine + H2O  =  3-hydroxy-anthranilate + L-alanine	tryptophan degradation
10-formyl-H4PteGlun		C8 H11 N6 O2 R1 			6.3.4.3	10-formyl-H4PteGlun + ADP + phosphate  =  THF polyglutamate + ATP + formate	tetrahydrofolate biosynthesis I
10-formyl-H4PteGlun		C8 H11 N6 O2 R1 			3.5.4.9	5,10-methenyl-H4PteGlun + H2O  =  10-formyl-H4PteGlun	tetrahydrofolate biosynthesis I
10-formyl-H4PteGlun		C8 H11 N6 O2 R1 			6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis
10-formyl-H4PteGlun		C8 H11 N6 O2 R1 			6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis I
acetylphosphate	acetyl-P	C2 H5 O5 P1 	CC(=O)OP(=O)(O)O	CAS:590-54-5*LIGAND-CPD:c00227	2.3.1.8	phosphate + acetyl-CoA  =  acetylphosphate + coenzyme A	carbon monoxide dehydrogenase pathway
acetylphosphate	acetyl-P	C2 H5 O5 P1 	CC(=O)OP(=O)(O)O	CAS:590-54-5*LIGAND-CPD:c00227	2.7.2.1	acetylphosphate + ADP  =  acetate + ATP	carbon monoxide dehydrogenase pathway
L-glutamyl-tRNAglt	L-glutamyl-tRNA<SUP>glt</SUP>*L-GLUTAMYL-TRNA(GLT)				1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	chlorophyllide a biosynthesis
L-glutamyl-tRNAglt	L-glutamyl-tRNA<SUP>glt</SUP>*L-GLUTAMYL-TRNA(GLT)				1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	biosynthesis of proto- and siroheme
L-glutamyl-tRNAglt	L-glutamyl-tRNA<SUP>glt</SUP>*L-GLUTAMYL-TRNA(GLT)				6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	chlorophyllide a biosynthesis
L-glutamyl-tRNAglt	L-glutamyl-tRNA<SUP>glt</SUP>*L-GLUTAMYL-TRNA(GLT)				6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	biosynthesis of proto- and siroheme
L-glutamyl-tRNAglt	L-glutamyl-tRNA<SUP>glt</SUP>*L-GLUTAMYL-TRNA(GLT)				6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	tRNA charging pathway
crotonobetainyl-CoA		C28 H48 N8 O17 P3 S1 	C(NCCC(=O)NCCSC(=O)C=CC[N+1](C)(C)C)(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC1(OC(C(O)C1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))		1.3.99.-	reduced acceptor + crotonobetainyl-CoA  =  acceptor + gamma-butyrobetainyl-CoA	carnitine degradation
crotonobetainyl-CoA		C28 H48 N8 O17 P3 S1 	C(NCCC(=O)NCCSC(=O)C=CC[N+1](C)(C)C)(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC1(OC(C(O)C1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))		6.3.2.-	coenzyme A + crotono-betaine  =  crotonobetainyl-CoA + H2O	carnitine degradation
crotonobetainyl-CoA		C28 H48 N8 O17 P3 S1 	C(NCCC(=O)NCCSC(=O)C=CC[N+1](C)(C)C)(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC1(OC(C(O)C1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))		4.2.1.-	L-carnitinyl-CoA  =  H2O + crotonobetainyl-CoA	carnitine degradation
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	2.7.1.15	D-ribose + ATP  =  D-ribose-5-phosphate + ADP	ribose degradation
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	RXN-4541	cis-zeatin riboside + H2O  =  cis-zeatin + D-ribose	cis-zeatin biosynthesis
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	3.2.2.7	H2O + adenosine  =  D-ribose + adenine	salvage pathways of purine nucleosides
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	3.2.2.2	inosine + H2O  =  hypoxanthine + D-ribose	purine degradation
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	3.2.2.2	inosine + H2O  =  hypoxanthine + D-ribose	salvage pathways of purine nucleosides
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	3.2.2.1	xanthosine + H2O  =  xanthine + D-ribose	purine degradation
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	3.2.2.1	xanthosine + H2O  =  xanthine + D-ribose	salvage pathways of purine nucleosides
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	3.2.2.1	guanosine + H2O  =  guanine + D-ribose	purine degradation
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	3.2.2.1	guanosine + H2O  =  guanine + D-ribose	salvage pathways of purine nucleosides
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	RXN-4315	isopentenyl adenosine + H2O  =  isopentenyladenine + D-ribose	trans-zeatin biosynthesis
D-ribose	&alpha;-D-ribose*ribose*&alpha;-D-ribose-5	C5 H10 O5 	C(O)C1(C(O)C(O)C(O1)O)	LIGAND-CPD:C00121*LIGAND:C00121*CAS:50-69-1	RXN-4318	trans-zeatin riboside + H2O  =  trans-zeatin + D-ribose	trans-zeatin biosynthesis
D-myo-Inositol (1)-monophosphate	Ins(1)P<sub>1</sub>*1-D-<i>myo</i>-inositol-1-p*Ins(1)P*1D-<i>myo</i>-inositol (1)-monophosphate*Ins1P	C6 H12 O9 P1 	C1(C(O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(O)	LIGAND-CPD:C01177	RXN-7252	D-myo-Inositol (1)-monophosphate + H2O  =  myo-inositol + phosphate	phytate degradation I
D-myo-Inositol (1)-monophosphate	Ins(1)P<sub>1</sub>*1-D-<i>myo</i>-inositol-1-p*Ins(1)P*1D-<i>myo</i>-inositol (1)-monophosphate*Ins1P	C6 H12 O9 P1 	C1(C(O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(O)	LIGAND-CPD:C01177	RXN-7251	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-Inositol (1)-monophosphate + phosphate	phytate degradation I
protoporphyrinogen	protoporphyrinogen IX*protoporphyrinogen	C34 H36 N4 O4 	Cc1(c4(nc(c1C=C)Cc2(nc(c(c(C)2)CCC(=O)O)Cc3(nc(c(C)c3CCC(=O)O)Cc5(c(C)c(C=C)c(C4)n5)))))	CAS:7412-77-3	1.3.3.4	1.5 O2 + protoporphyrinogen  =  3 H2O + protoporphyrin IX	chlorophyllide a biosynthesis
protoporphyrinogen	protoporphyrinogen IX*protoporphyrinogen	C34 H36 N4 O4 	Cc1(c4(nc(c1C=C)Cc2(nc(c(c(C)2)CCC(=O)O)Cc3(nc(c(C)c3CCC(=O)O)Cc5(c(C)c(C=C)c(C4)n5)))))	CAS:7412-77-3	1.3.3.4	1.5 O2 + protoporphyrinogen  =  3 H2O + protoporphyrin IX	biosynthesis of proto- and siroheme
protoporphyrinogen	protoporphyrinogen IX*protoporphyrinogen	C34 H36 N4 O4 	Cc1(c4(nc(c1C=C)Cc2(nc(c(c(C)2)CCC(=O)O)Cc3(nc(c(C)c3CCC(=O)O)Cc5(c(C)c(C=C)c(C4)n5)))))	CAS:7412-77-3	1.-.-.-	NAD(P)+ + coproporphyrinogen III  =  protoporphyrinogen + NAD(P)H + 2 CO2	biosynthesis of proto- and siroheme
protoporphyrinogen	protoporphyrinogen IX*protoporphyrinogen	C34 H36 N4 O4 	Cc1(c4(nc(c1C=C)Cc2(nc(c(c(C)2)CCC(=O)O)Cc3(nc(c(C)c3CCC(=O)O)Cc5(c(C)c(C=C)c(C4)n5)))))	CAS:7412-77-3	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	chlorophyllide a biosynthesis
protoporphyrinogen	protoporphyrinogen IX*protoporphyrinogen	C34 H36 N4 O4 	Cc1(c4(nc(c1C=C)Cc2(nc(c(c(C)2)CCC(=O)O)Cc3(nc(c(C)c3CCC(=O)O)Cc5(c(C)c(C=C)c(C4)n5)))))	CAS:7412-77-3	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	biosynthesis of proto- and siroheme
coumaraldehyde		C9 H8 O2 	C(=O)C=Cc1(ccc(O)cc1)		1.1.1.195	coumaraldehyde + NADPH  =  coumaryl-alcohol + NADP+	lignin biosynthesis
coumaraldehyde		C9 H8 O2 	C(=O)C=Cc1(ccc(O)cc1)		1.2.1.44	coumaroyl-CoA + NADPH  =  coumaraldehyde + NADP+ + coenzyme A	lignin biosynthesis
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	6.1.1.20	tRNAphe + L-phenylalanine + ATP  =  L-phenylalanyl-tRNAphe + pyrophosphate + AMP	tRNA charging pathway
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	phenylpropanoid biosynthesis, initial reactions
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	suberin biosynthesis
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	salicylic acid biosynthesis
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	1.14.16.1	O2 + tetrahydrobiopterin + L-phenylalanine  =  L-tyrosine + 4alpha-hydroxy-5,6,7,8-tetrahydrobiopterin	phenylalanine degradation
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	1.14.13.-	L-phenylalanine + NADPH + O2  =  phenylacetaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from phenylalanine
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	4.2.1.91	L-arogenate  =  CO2 + H2O + L-phenylalanine	phenylalanine biosynthesis I
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	2.6.1.9	phenylpyruvate + L-glutamate  =  L-phenylalanine + alpha-ketoglutarate	phenylalanine biosynthesis II
L-phenylalanine	F*endophenyl*phenylalanine*phe	C9 H11 N1 O2 	C(O)(=O)C(N)Cc1(ccccc1)	LIGAND:C00079*CAS:63-91-2*CAS:3617-44-5	2.6.1.5	phenylpyruvate + L-glutamate  =  L-phenylalanine + alpha-ketoglutarate	phenylalanine biosynthesis II
UDP-D-glucuronate	udp-glcua*UDP-glucuronate*uridine diphosphate glucuronate*uridine diphosphate glucuronic acid	C15 H22 N2 O18 P2 	C1(OC(C(O)=O)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	CAS:2616-64-0	4.1.1.35	UDP-D-glucuronate  =  UDP-D-xylose + CO2	UDP-D-xylose biosynthesis
UDP-D-glucuronate	udp-glcua*UDP-glucuronate*uridine diphosphate glucuronate*uridine diphosphate glucuronic acid	C15 H22 N2 O18 P2 	C1(OC(C(O)=O)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	CAS:2616-64-0	5.1.3.6	UDP-D-glucuronate  =  UDP-D-galacturonate	UDP-D-galacturonate biosynthesis I (from UDP-D-glucuronate)
UDP-D-glucuronate	udp-glcua*UDP-glucuronate*uridine diphosphate glucuronate*uridine diphosphate glucuronic acid	C15 H22 N2 O18 P2 	C1(OC(C(O)=O)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	CAS:2616-64-0	2.7.7.44	alpha-D-glucuronate 1-phosphate + UTP  =  UDP-D-glucuronate + pyrophosphate	inositol oxidation pathway
UDP-D-glucuronate	udp-glcua*UDP-glucuronate*uridine diphosphate glucuronate*uridine diphosphate glucuronic acid	C15 H22 N2 O18 P2 	C1(OC(C(O)=O)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	CAS:2616-64-0	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	UDP-D-xylose biosynthesis
UDP-D-glucuronate	udp-glcua*UDP-glucuronate*uridine diphosphate glucuronate*uridine diphosphate glucuronic acid	C15 H22 N2 O18 P2 	C1(OC(C(O)=O)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	CAS:2616-64-0	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	colanic acid building blocks biosynthesis
UDP-D-glucuronate	udp-glcua*UDP-glucuronate*uridine diphosphate glucuronate*uridine diphosphate glucuronic acid	C15 H22 N2 O18 P2 	C1(OC(C(O)=O)C(O)C(O)C(O)1)OP(=O)(O)OP(O)(=O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3))	CAS:2616-64-0	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	galactose degradation I
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	1.17.4.1	Reduced Thioredoxin + GDP  =  Oxidized Thioredoxin + dGDP + H2O	de novo biosynthesis of purine nucleotides I
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	2.7.4.6	GDP + ATP  =  GTP + ADP	de novo biosynthesis of purine nucleotides I
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	RXN0-748	GDP + reduced glutaredoxin  =  dGDP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	2.7.7.22	mannose-1-phosphate + GDP  =  GDP-mannose + phosphate	colanic acid building blocks biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	2.7.7.22	mannose-1-phosphate + GDP  =  GDP-mannose + phosphate	GDP-D-rhamnose biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	GDPPYPHOSKIN-RXN	ATP + GDP  =  AMP + guanosine 5'-diphosphate,3'-diphosphate	ppGpp biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	2.4.1.132	mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  (mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	RXN-5464	(mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP-mannose  =  (mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	RXN-5465	(mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  (mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	RXN-5463	(mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP-mannose  =  (mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	3.1.7.2	guanosine 5'-diphosphate,3'-diphosphate + H2O  =  pyrophosphate + GDP	ppGpp biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	2.4.1.142	(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	4.1.1.32	oxaloacetate + GTP  =  CO2 + phosphoenolpyruvate + GDP	phenylalanine degradation
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	2.7.4.8	GMP + ATP  =  GDP + ADP	de novo biosynthesis of purine nucleotides I
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	2.4.1.83	dolichyl-phosphate + GDP-mannose  =  dolichyl beta-D-mannosyl phosphate + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides II
GDP	ppG*guanosine-5'-diphosphate*guanosine-diphosphate	C10 H15 N5 O11 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00035*CAS:146-91-8	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides I
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	superpathway of glyoxylate cycle
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	gluconeogenesis
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	4.1.1.31	phosphate + oxaloacetate  =  phosphoenolpyruvate + H2O + CO2	gluconeogenesis
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	4.1.1.32	oxaloacetate + GTP  =  CO2 + phosphoenolpyruvate + GDP	phenylalanine degradation
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	1.1.1.37	malate  =  oxaloacetate	superpathway of glyoxylate cycle
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	1.1.99.16	acceptor + malate  =  reduced acceptor + oxaloacetate	TCA cycle -- aerobic respiration
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	TCA cycle variation I
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	superpathway of glyoxylate cycle
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	glyoxylate cycle
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	phenylalanine degradation
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	TCA cycle -- aerobic respiration
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	gluconeogenesis
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle variation I
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	glyoxylate cycle
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle -- aerobic respiration
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	2.6.1.1	oxaloacetate + L-glutamate  =  L-aspartate + alpha-ketoglutarate	asparagine biosynthesis
oxaloacetate	keto-oxaloacetate*oxaloacetic acid*oxalacetic acid*oxaloacetate*oxalacetate	C4 H4 O5 	C(O)(=O)CC(=O)C(=O)O	LIGAND:C00036*CAS:328-42-7	2.6.1.1	oxaloacetate + L-glutamate  =  L-aspartate + alpha-ketoglutarate	aspartate biosynthesis and degradation
L-leucyl-tRNAleu	L-leucyl-tRNA*L-LEUCYL-TRNA(LEU)				6.1.1.4	L-leucine + tRNAleu + ATP  =  L-leucyl-tRNAleu + pyrophosphate + AMP	tRNA charging pathway
N-alpha-acetylornithine	<i>N</i>-&alpha;-acetylornithine*N-acetylornithine*N2-acetyl-L-ornithine*<i>N<sup>2</sup></i>-acetyl-ornithine*<i>N<sup>2</sup></i>-acetyl-L-ornithine*<i>N</i>-acetylornithine*acetylornithine	C7 H14 N2 O3 	CC(=O)NC(C(O)=O)CCCN	CAS:2185-16-2	2.6.1.11	N-acetylglutamate semialdehyde + L-glutamate  =  N-alpha-acetylornithine + alpha-ketoglutarate	arginine biosynthesis
N-alpha-acetylornithine	<i>N</i>-&alpha;-acetylornithine*N-acetylornithine*N2-acetyl-L-ornithine*<i>N<sup>2</sup></i>-acetyl-ornithine*<i>N<sup>2</sup></i>-acetyl-L-ornithine*<i>N</i>-acetylornithine*acetylornithine	C7 H14 N2 O3 	CC(=O)NC(C(O)=O)CCCN	CAS:2185-16-2	2.6.1.11	N-acetylglutamate semialdehyde + L-glutamate  =  N-alpha-acetylornithine + alpha-ketoglutarate	arginine biosynthesis II (acetyl cycle)
N-alpha-acetylornithine	<i>N</i>-&alpha;-acetylornithine*N-acetylornithine*N2-acetyl-L-ornithine*<i>N<sup>2</sup></i>-acetyl-ornithine*<i>N<sup>2</sup></i>-acetyl-L-ornithine*<i>N</i>-acetylornithine*acetylornithine	C7 H14 N2 O3 	CC(=O)NC(C(O)=O)CCCN	CAS:2185-16-2	2.3.1.35	L-glutamate + N-alpha-acetylornithine  =  N-acetyl-L-glutamate + L-ornithine	arginine biosynthesis II (acetyl cycle)
N-alpha-acetylornithine	<i>N</i>-&alpha;-acetylornithine*N-acetylornithine*N2-acetyl-L-ornithine*<i>N<sup>2</sup></i>-acetyl-ornithine*<i>N<sup>2</sup></i>-acetyl-L-ornithine*<i>N</i>-acetylornithine*acetylornithine	C7 H14 N2 O3 	CC(=O)NC(C(O)=O)CCCN	CAS:2185-16-2	3.5.1.16	N-alpha-acetylornithine + H2O  =  L-ornithine + acetate	arginine biosynthesis
sulfur donor	(S)		S	NCI:403664*CAS:7704-34-9	2.8.1.6	dethiobiotin + sulfur donor  =  9-mercaptodethiobiotin	biotin biosynthesis II
2-keto-4-methyl-pentanoate	4-methyl-2-oxopentanoate*2-oxo-4-methylpentanoate*&alpha;-ketoisocaproate*&alpha;-oxoisocaproate	C6 H10 O3 	CC(C)CC(=O)C(=O)O	CAS:816-66-0	2.6.1.42	2-keto-4-methyl-pentanoate + L-glutamate  =  L-leucine + alpha-ketoglutarate	leucine biosynthesis
2-keto-4-methyl-pentanoate	4-methyl-2-oxopentanoate*2-oxo-4-methylpentanoate*&alpha;-ketoisocaproate*&alpha;-oxoisocaproate	C6 H10 O3 	CC(C)CC(=O)C(=O)O	CAS:816-66-0	2.6.1.42	2-keto-4-methyl-pentanoate + L-glutamate  =  L-leucine + alpha-ketoglutarate	leucine degradation
2-keto-4-methyl-pentanoate	4-methyl-2-oxopentanoate*2-oxo-4-methylpentanoate*&alpha;-ketoisocaproate*&alpha;-oxoisocaproate	C6 H10 O3 	CC(C)CC(=O)C(=O)O	CAS:816-66-0	2KETO-4METHYL-PENTANOATE-DEHYDROG-RXN	2-keto-4-methyl-pentanoate + coenzyme A + NAD+  =  isovaleryl-CoA + CO2 + NADH	leucine degradation
2-keto-4-methyl-pentanoate	4-methyl-2-oxopentanoate*2-oxo-4-methylpentanoate*&alpha;-ketoisocaproate*&alpha;-oxoisocaproate	C6 H10 O3 	CC(C)CC(=O)C(=O)O	CAS:816-66-0	1.1.1.85	2-D-threo-hydroxy-3-carboxy-isocaproate + NAD+  =  2-keto-4-methyl-pentanoate + NADH + CO2	leucine biosynthesis
14-beta-D-glucosyln1	1,4-&beta;-D-glucan*(1,4-&beta;-D-glucosyl)(N)			CAS:9004-34-6	2.4.1.12	UDP-D-glucose + (1,4-beta-D-glucosyl)(n)  =  UDP + (1,4-beta-D-glucosyl)(n+1)	cellulose biosynthesis
D-myo-inositol (3,4,6)-trisphosphate	1D-<i>myo</i>-inositol (3,4,6)-trisphosphate*Ins(3,4,6)P<sub>3</sub>*I(3,4,6)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7204	D-myo-inositol (3,4,6)-trisphosphate + ATP  =  D-myo-inositol (3,4,5,6)-tetrakisphosphate + ADP	lipid-independent phytate biosynthesis
D-myo-inositol (3,4,6)-trisphosphate	1D-<i>myo</i>-inositol (3,4,6)-trisphosphate*Ins(3,4,6)P<sub>3</sub>*I(3,4,6)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7203	D-myo-inositol (3,4)-bisphosphate + ATP  =  D-myo-inositol (3,4,6)-trisphosphate + ADP	lipid-independent phytate biosynthesis
phosphoribosyl-carboxy-aminoimidazole	1-(5-phosphoribosyl)-4-carboxy-5-aminoimidazole*5'-P-ribosyl-4-carboxy-5-aminoimidazole*5'-phosphoribosyl-4-carboxy-5-aminoimidazole*5-phosphoribosyl-4-carboxy-5-aminoimidazole*1-(5'-phosphoribosyl)-5-amino-4-imidazole carboxylate*1-(5'-phosphoribosyl)-4-carboxy-5-aminoimidazole*CAIR	C9 H14 N3 O9 P1 	C(OP(O)(=O)O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c(N)c(nc2)C(=O)O))		6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides II
phosphoribosyl-carboxy-aminoimidazole	1-(5-phosphoribosyl)-4-carboxy-5-aminoimidazole*5'-P-ribosyl-4-carboxy-5-aminoimidazole*5'-phosphoribosyl-4-carboxy-5-aminoimidazole*5-phosphoribosyl-4-carboxy-5-aminoimidazole*1-(5'-phosphoribosyl)-5-amino-4-imidazole carboxylate*1-(5'-phosphoribosyl)-4-carboxy-5-aminoimidazole*CAIR	C9 H14 N3 O9 P1 	C(OP(O)(=O)O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c(N)c(nc2)C(=O)O))		6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides I
phosphoribosyl-carboxy-aminoimidazole	1-(5-phosphoribosyl)-4-carboxy-5-aminoimidazole*5'-P-ribosyl-4-carboxy-5-aminoimidazole*5'-phosphoribosyl-4-carboxy-5-aminoimidazole*5-phosphoribosyl-4-carboxy-5-aminoimidazole*1-(5'-phosphoribosyl)-5-amino-4-imidazole carboxylate*1-(5'-phosphoribosyl)-4-carboxy-5-aminoimidazole*CAIR	C9 H14 N3 O9 P1 	C(OP(O)(=O)O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c(N)c(nc2)C(=O)O))		RXN0-743	N5-carboxyaminoimidazole ribonucleotide  =  phosphoribosyl-carboxy-aminoimidazole	de novo biosynthesis of purine nucleotides I
phosphoribosyl-carboxy-aminoimidazole	1-(5-phosphoribosyl)-4-carboxy-5-aminoimidazole*5'-P-ribosyl-4-carboxy-5-aminoimidazole*5'-phosphoribosyl-4-carboxy-5-aminoimidazole*5-phosphoribosyl-4-carboxy-5-aminoimidazole*1-(5'-phosphoribosyl)-5-amino-4-imidazole carboxylate*1-(5'-phosphoribosyl)-4-carboxy-5-aminoimidazole*CAIR	C9 H14 N3 O9 P1 	C(OP(O)(=O)O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c(N)c(nc2)C(=O)O))		4.1.1.21	5-aminoimidazole ribonucleotide + ATP + CO2 + H2O  =  phosphate + phosphoribosyl-carboxy-aminoimidazole + ADP	de novo biosynthesis of purine nucleotides II
lipid A disaccharide	2,3-bis-(3-hydroxytetradecanoyl)-D-glucosaminyl-(&beta;-D-1,6)-2,3-bis-(3-hydroxytetradecanoyl)-D-glucosaminyl-&beta;-phosphate*2,3-bis(3-hydroxymyristoyl)-D-glucosaminyl-1,6-&beta;-D-2,3-bis(3-hydroxymyristoyl)-&beta;-D-glucosaminyl 1-phosphate*2'-3'-diacyl-GlcN(&beta;-1'-6)2,3-diacyl-GlcN-1-P*2,3,2',3'-tetrakis(3-hydroxymyristoyl)-D-glucosaminyl-1,6-&beta;-D-glucosamine 1-phosphate*2,3-bis(3-hydroxytetradecanoyl)-D-glucosaminyl-1,6-&beta;-D-2,3-bis(3-hydroxytetradecanoyl)-&beta;-D-glucosaminyl 1-phosphate	C68 H129 N2 O20 P1 	CCCCCCCCCCCC(O)CC(=O)NC1(C(OP(=O)(O)O)OC(C(O)C1OC(=O)CC(O)CCCCCCCCCCC)COC2(C(NC(=O)CC(O)CCCCCCCCCCC)C(C(O)C(O2)CO)OC(=O)CC(O)CCCCCCCCCCC))		2.7.1.130	lipid A disaccharide + ATP  =  lipid IV(A) + ADP	lipid-A-precursor biosynthesis
lipid A disaccharide	2,3-bis-(3-hydroxytetradecanoyl)-D-glucosaminyl-(&beta;-D-1,6)-2,3-bis-(3-hydroxytetradecanoyl)-D-glucosaminyl-&beta;-phosphate*2,3-bis(3-hydroxymyristoyl)-D-glucosaminyl-1,6-&beta;-D-2,3-bis(3-hydroxymyristoyl)-&beta;-D-glucosaminyl 1-phosphate*2'-3'-diacyl-GlcN(&beta;-1'-6)2,3-diacyl-GlcN-1-P*2,3,2',3'-tetrakis(3-hydroxymyristoyl)-D-glucosaminyl-1,6-&beta;-D-glucosamine 1-phosphate*2,3-bis(3-hydroxytetradecanoyl)-D-glucosaminyl-1,6-&beta;-D-2,3-bis(3-hydroxytetradecanoyl)-&beta;-D-glucosaminyl 1-phosphate	C68 H129 N2 O20 P1 	CCCCCCCCCCCC(O)CC(=O)NC1(C(OP(=O)(O)O)OC(C(O)C1OC(=O)CC(O)CCCCCCCCCCC)COC2(C(NC(=O)CC(O)CCCCCCCCCCC)C(C(O)C(O2)CO)OC(=O)CC(O)CCCCCCCCCCC))		2.4.1.182	2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate + UDP-2,3-bis(3-hydroxymyristoyl)glucosamine  =  lipid A disaccharide + UDP	lipid-A-precursor biosynthesis
24-methyldesmosterol		C28 H46 O1 	CC(C)=C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-708	24-methyldesmosterol  =  campesterol	sterol biosynthesis
24-methyldesmosterol		C28 H46 O1 	CC(C)=C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4222	24-methylenecholesterol  =  24-methyldesmosterol	sterol biosynthesis
ThiS protein	B4407*ThiS				THIAZOLSYN2-RXN	L-tyrosine + 1-deoxy-D-xylulose 5-phosphate + ThiS-COSH  =  4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-hydroxybenzyl alcohol + C1 of tyrosine + ThiS protein	thiamin biosynthesis
4alpha-hydroxy-5,6,7,8-tetrahydrobiopterin		C9 H15 N5 O4 	C[CH](O)[CH](O)C1(NC2(O)(C(NC1)=NC(N)=NC2=O))		1.14.16.1	O2 + tetrahydrobiopterin + L-phenylalanine  =  L-tyrosine + 4alpha-hydroxy-5,6,7,8-tetrahydrobiopterin	phenylalanine degradation
delta24-25-sitosterol		C29 H48 O1 	CC(C)=C(CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4224	delta24-25-sitosterol  =  sitosterol	sterol biosynthesis
delta24-25-sitosterol		C29 H48 O1 	CC(C)=C(CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4221	isofucosterol  =  delta24-25-sitosterol	sterol biosynthesis
sitosterol		C29 H50 O1 	CC(C)C(CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4243	sitosterol  =  stigmasterol	sterol biosynthesis
sitosterol		C29 H50 O1 	CC(C)C(CC)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4224	delta24-25-sitosterol  =  sitosterol	sterol biosynthesis
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis III
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	spermine biosynthesis II
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	spermine biosynthesis I
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis II
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis I
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		2.5.1.22	spermidine + S-adenosylmethioninamine  =  spermine + 5'-methylthioadenosine	spermine biosynthesis II
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		2.5.1.22	spermidine + S-adenosylmethioninamine  =  spermine + 5'-methylthioadenosine	spermine biosynthesis I
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		4.1.1.50	S-adenosyl-L-methionine  =  CO2 + S-adenosylmethioninamine	polyamine biosynthesis III
S-adenosylmethioninamine	decarboxylated AdoMet*(5-deoxy-5-adenosyl)(3-aminopropyl) methylsulfonium salt*decarboxylated SAM*S-Adenosyl-L-methioninamine*decarboxylated S-adenosylmethionine*dAdoMet*S-methyl-s-adenosyl homocysteamine	C14 H23 N6 O3 S1 	C(N)CC[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))		4.1.1.50	S-adenosyl-L-methionine  =  CO2 + S-adenosylmethioninamine	polyamine biosynthesis I
benzyl-glucosinolate	glucotropaeolin	C14 H19 N1 O9 S2 	C1(OC(C(CO)C(O)C(O)1)SC(=NOS(=O)(O)=O)cc2(ccccc2))(O)		2.8.2.-	benzyl-desulfoglucosinolate + PAPS  =  benzyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from phenylalanine
GA29-catabolite	gibberellin A<sub>29</sub>-catabolite*gibberellin A29-catabolite*GA29-catabolite	C19 H22 O6 	CC1([CH]4(C(=CC(=O)C1)[CH]3(C2(CC(C(=C)C2)(O)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA29 + alpha-ketoglutarate + O2  =  GA29-catabolite + succinate + CO2 + H2O	gibberellin inactivation
indole-3-acetyl-leu	indole-3-acetyl-leucine	C16 H20 N2 O3 	C(=O)(NC(C(O)=O)CC(C)C)Cc2(c[nH]c1(ccccc12))		3.5.1.-	indole-3-acetyl-leu + H2O  =  indole-3-acetate + L-leucine	IAA biosynthesis II
indole-3-acetyl-leu	indole-3-acetyl-leucine	C16 H20 N2 O3 	C(=O)(NC(C(O)=O)CC(C)C)Cc2(c[nH]c1(ccccc12))		RXN-2945	indole-3-acetate + L-leucine  =  indole-3-acetyl-leu + H2O	IAA conjugate biosynthesis
UDP-N-acetyl-D-glucosamine	uridine diphosphate <i>N</i>-acetylglucosamine*UDP-<i>N</i>-acetyl-glucosamine*UDP-acetyl-D-glucosamine*UDP-GlcNAc*UDP-N-acetyl-glucosamine*uridine diphosphate N-acetylglucosamine*N-[2-[[[5-[(2,4-dioxo-1H-pyrimidin-1-yl)]-3,4-dihydroxy-tetrahydrofuran-2-yl]methoxy-hydroxy-phosphinoyl]oxy-hydroxy-phosphinoyl]oxy-4,5-dihydroxy-6-(hydroxymethyl)tetrahydropyran-3-yl]acetamide	C17 H27 N3 O17 P2 	C(C1(OC(C(O)C(O)1)n2(c(=O)[nH]c(=O)cc2)))OP(O)(=O)OP(O)(=O)OC3(C(NC(=O)C)C(O)C(O)C(O3)CO)	CAS:528-04-1	2.7.8.15	dolichyl-phosphate + UDP-N-acetyl-D-glucosamine  =  N-acetylglucosaminyl-diphosphodolichol + UMP	dolichyl-diphosphooligosaccharide biosynthesis
UDP-N-acetyl-D-glucosamine	uridine diphosphate <i>N</i>-acetylglucosamine*UDP-<i>N</i>-acetyl-glucosamine*UDP-acetyl-D-glucosamine*UDP-GlcNAc*UDP-N-acetyl-glucosamine*uridine diphosphate N-acetylglucosamine*N-[2-[[[5-[(2,4-dioxo-1H-pyrimidin-1-yl)]-3,4-dihydroxy-tetrahydrofuran-2-yl]methoxy-hydroxy-phosphinoyl]oxy-hydroxy-phosphinoyl]oxy-4,5-dihydroxy-6-(hydroxymethyl)tetrahydropyran-3-yl]acetamide	C17 H27 N3 O17 P2 	C(C1(OC(C(O)C(O)1)n2(c(=O)[nH]c(=O)cc2)))OP(O)(=O)OP(O)(=O)OC3(C(NC(=O)C)C(O)C(O)C(O3)CO)	CAS:528-04-1	2.4.1.141	N-acetylglucosaminyl-diphosphodolichol + UDP-N-acetyl-D-glucosamine  =  (N-acetylglucosaminyl)2-diphosphodolichol + UDP	dolichyl-diphosphooligosaccharide biosynthesis
UDP-N-acetyl-D-glucosamine	uridine diphosphate <i>N</i>-acetylglucosamine*UDP-<i>N</i>-acetyl-glucosamine*UDP-acetyl-D-glucosamine*UDP-GlcNAc*UDP-N-acetyl-glucosamine*uridine diphosphate N-acetylglucosamine*N-[2-[[[5-[(2,4-dioxo-1H-pyrimidin-1-yl)]-3,4-dihydroxy-tetrahydrofuran-2-yl]methoxy-hydroxy-phosphinoyl]oxy-hydroxy-phosphinoyl]oxy-4,5-dihydroxy-6-(hydroxymethyl)tetrahydropyran-3-yl]acetamide	C17 H27 N3 O17 P2 	C(C1(OC(C(O)C(O)1)n2(c(=O)[nH]c(=O)cc2)))OP(O)(=O)OP(O)(=O)OC3(C(NC(=O)C)C(O)C(O)C(O3)CO)	CAS:528-04-1	2.3.1.129	(R)-3-hydroxymyristoyl-ACP + UDP-N-acetyl-D-glucosamine  =  UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine + acyl carrier protein	lipid-A-precursor biosynthesis
UDP-N-acetyl-D-glucosamine	uridine diphosphate <i>N</i>-acetylglucosamine*UDP-<i>N</i>-acetyl-glucosamine*UDP-acetyl-D-glucosamine*UDP-GlcNAc*UDP-N-acetyl-glucosamine*uridine diphosphate N-acetylglucosamine*N-[2-[[[5-[(2,4-dioxo-1H-pyrimidin-1-yl)]-3,4-dihydroxy-tetrahydrofuran-2-yl]methoxy-hydroxy-phosphinoyl]oxy-hydroxy-phosphinoyl]oxy-4,5-dihydroxy-6-(hydroxymethyl)tetrahydropyran-3-yl]acetamide	C17 H27 N3 O17 P2 	C(C1(OC(C(O)C(O)1)n2(c(=O)[nH]c(=O)cc2)))OP(O)(=O)OP(O)(=O)OC3(C(NC(=O)C)C(O)C(O)C(O3)CO)	CAS:528-04-1	2.7.7.23	N-acetyl-glucosamine-1-phosphate + UTP  =  UDP-N-acetyl-D-glucosamine + pyrophosphate	UDP-N-acetyl-D-glucosamine biosynthesis
biotin	vitamin H*coenzyme R*<I>d</I>-biotin	C10 H16 N2 O3 S1 	C1(SC([CH]2([CH]1NC(N2)=O))CCCCC(O)=O)	LIGAND-CPD:C00120*LIGAND:C00120*CAS:58-85-5	RXN-5985	9-mercaptodethiobiotin  =  biotin	biotin biosynthesis II
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	glutamine biosynthesis
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	ammonia assimilation cycle
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	nitrate assimilation pathway
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	2.7.2.2	carbamoyl-phosphate + ADP  =  NH3 + CO2 + ATP	citrulline degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	NAD biosynthesis I (from aspartate)
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	pyridine nucleotide cycling
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	salvage pathways of purine nucleosides
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	de novo biosynthesis of purine nucleotides I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.15	H2O + guanosine  =  NH3 + xanthosine	purine degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.15	H2O + guanosine  =  NH3 + xanthosine	salvage pathways of purine nucleosides
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.3	H2O + guanine  =  NH3 + xanthine	purine degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.3	H2O + guanine  =  NH3 + xanthine	salvage pathways of purine nucleosides
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	1.4.1.3	NH3 + NAD(P)H + alpha-ketoglutarate  =  NAD(P)+ + H2O + L-glutamate	arginine biosynthesis III
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.5.7	acrylonitrile + 2 H2O  =  acrylate + NH3	acrylonitrile degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	1.4.1.2	H2O + NAD+ + L-glutamate  =  NH3 + NADH + alpha-ketoglutarate	glutamate degradation I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	1.4.3.6	1,3-diaminopropane + H2O + O2  =  3-aminopropionaldehyde + NH3 + H2O2	beta-alanine biosynthesis I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.5	H2O + cytidine  =  NH3 + uridine	(deoxy)ribose phosphate degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	1.4.3.10	O2 + H2O + putrescine  =  NH3 + H2O2 + 4-amino-butyraldehyde	arginine degradation I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.4	acrylamide + H2O  =  NH3 + acrylate + H+	acrylonitrile degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.4	nicotinamide + H2O  =  NH3 + nicotinate	aldoxime degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	1.4.3.6	tryptamine + H2O + O2  =  NH3 + indole acetaldehyde + H2O2	IAA biosynthesis I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.5.1	3-indoleacetonitrile + 2 H2O  =  NH3 + indole-3-acetate	IAA biosynthesis I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.3.1.19	L-threonine  =  2-oxobutanoate + NH3	isoleucine biosynthesis
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.3.9	2 H2O + 2 allantoate  =  2 NH3 + O2 + 2 CO2 + 2 ureidoglycine	ureide degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.13	H2O + dCTP  =  NH3 + dUTP	de novo biosynthesis of pyrimidine deoxyribonucleotides
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.3.19	H2O + (S)-ureidoglycolate  =  2 NH3 + CO2 + glyoxylate	ureide degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.4.1.1	cystathionine + H2O  =  NH3 + 2-oxobutanoate + L-cysteine	homocysteine and cysteine interconversion
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	AMACETOXID-RXN	aminoacetone + H2O + O2  =  NH3 + methylglyoxal + H2O2	threonine degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	1.7.7.-	NO2- + reduced ferredoxin  =  NH3 + H2O + oxidized ferredoxin	nitrate assimilation pathway
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	photorespiration
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.42	nicotinamide mononucleotide + H2O  =  NH3 + nicotinate nucleotide	pyridine nucleotide cycling
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.19	nicotinamide + H2O  =  NH3 + nicotinate	pyridine nucleotide cycling
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.26	H2O + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate  =  5-amino-6-(5'-phosphoribosylamino)uracil + NH3	riboflavin and FMN and FAD biosynthesis
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.6	H2O + 3-ureidopropionate  =  NH3 + CO2 + beta-alanine	beta-alanine biosynthesis III
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.3.12	H2O + agmatine  =  NH3 + N-carbamoylputrescine	polyamine biosynthesis III
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.3.12	H2O + agmatine  =  NH3 + N-carbamoylputrescine	arginine degradation I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	2.5.1.61	H2O + 4 porphobilinogen  =  4 NH3 + hydroxymethylbilane	chlorophyllide a biosynthesis
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	2.5.1.61	H2O + 4 porphobilinogen  =  4 NH3 + hydroxymethylbilane	biosynthesis of proto- and siroheme
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.1	L-asparagine + H2O  =  NH3 + L-aspartate	asparagine degradation I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	polyamine biosynthesis III
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	arginine degradation I
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	phenylpropanoid biosynthesis, initial reactions
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	suberin biosynthesis
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	salicylic acid biosynthesis
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	1.4.3.5	O2 + H2O + pyridoxamine 5'-phosphate  =  NH3 + H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.5	H2O + deoxycytidine  =  NH3 + deoxyuridine	(deoxy)ribose phosphate degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.6	AMP + H2O  =  IMP + NH3	purine degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.4.6	AMP + H2O  =  IMP + NH3	salvage pathways of purine nucleosides
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	3.5.1.5	H2O + urea  =  2 NH3 + CO2	ureide degradation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	homocysteine and cysteine interconversion
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	methionine biosynthesis
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	sulfate assimilation
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	4.4.1.11	L-methionine + H2O  =  NH3 + 2-oxobutanoate + methanethiol	methionine degradation II
NH3	NH<SUB>3</SUB>*ammonia	H3 N1 	[NH3]	CAS:7664-41-7	2.1.2.10	S-aminomethyldihydrolipoyl-GcvH-protein + tetrahydrofolate  =  NH3 + dihydrolipoyl-GcvH-protein + 5,10-methylene-THF	glycine degradation
tRNAarg	TRNA(ARG)				6.1.1.19	tRNAarg + L-arginine + ATP  =  L-arginyl-tRNAarg + pyrophosphate + AMP	tRNA charging pathway
phenylacetothiohydroximate	phenylacetothiohydroxamic acid	C8 H9 N1 O1 S1 	C(S)(=NO)Cc1(ccccc1)		2.4.1.-	phenylacetothiohydroximate + UDP-D-glucose  =  benzyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from phenylalanine
phenylacetothiohydroximate	phenylacetothiohydroxamic acid	C8 H9 N1 O1 S1 	C(S)(=NO)Cc1(ccccc1)		RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate	2,5-diamino-6-hydroxy-4-(5-phosphoribosylamino)pyrimidine	C9 H16 N5 O8 P1 	c1(=O)(c(N)c(nc([nH]1)N)NC2(OC(C(O)C2O)COP(O)(O)=O))		3.5.4.26	H2O + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate  =  5-amino-6-(5'-phosphoribosylamino)uracil + NH3	riboflavin and FMN and FAD biosynthesis
2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate	2,5-diamino-6-hydroxy-4-(5-phosphoribosylamino)pyrimidine	C9 H16 N5 O8 P1 	c1(=O)(c(N)c(nc([nH]1)N)NC2(OC(C(O)C2O)COP(O)(O)=O))		3.5.4.25	3 H2O + GTP  =  pyrophosphate + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate + formate	riboflavin and FMN and FAD biosynthesis
acrylamide		C3 H5 N1 O1 	C(=O)(N)C=C	NCI:7785	3.5.1.4	acrylamide + H2O  =  NH3 + acrylate + H+	acrylonitrile degradation
acrylamide		C3 H5 N1 O1 	C(=O)(N)C=C	NCI:7785	4.2.1.84	acrylonitrile + H2O  =  acrylamide	acrylonitrile degradation
L-arabinose		C5 H10 O5 	C1(C(O)C(O)C(O)C(O1)O)		2.7.1.46	L-arabinose + ATP  =  beta-L-arabinose 1-phosphate + ADP	UDP-L-arabinose biosynthesis II (from L-arabinose)
10,16-dihydroxypalmitate		C16 H32 O4 	C(O)CCCCCC(O)CCCCCCCCC(O)=O		RXN-1062	16-hydroxypalmitate + NADPH + O2  =  10,16-dihydroxypalmitate + NADP+ + H2O	cutin biosynthesis
NH(4)OH	ammonium hydroxide	N1 O1 	[NH3+1]O		2-AMINOMUCONATE-REDUCTASE-RXN	2-amino-muconate + 2 H2O + NADH  =  NH(4)OH + alpha-ketoadipate + NAD+	tryptophan degradation
N-methylethanolamine phosphate	P-MME	C3 H10 N1 O4 P1 	C(NC)COP(O)(O)=O		2.1.1.103	N-methylethanolamine phosphate + S-adenosyl-L-methionine  =  N-dimethylethanolamine phosphate + S-adenosyl-homocysteine	choline biosynthesis I
N-methylethanolamine phosphate	P-MME	C3 H10 N1 O4 P1 	C(NC)COP(O)(O)=O		2.1.1.103	phosphoryl-ethanolamine + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + N-methylethanolamine phosphate	choline biosynthesis I
3,4-dihydroxy-2-butanone-4-P	3,4-dihydroxy-2-butanone-4-phosphate	C4 H9 O6 P1 	CC(=O)C(O)COP(O)(O)=O		LUMAZINESYN-RXN	5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + 3,4-dihydroxy-2-butanone-4-P  =  6,7-dimethyl-8-(1-D-ribityl)lumazine + phosphate + O2	riboflavin and FMN and FAD biosynthesis
3,4-dihydroxy-2-butanone-4-P	3,4-dihydroxy-2-butanone-4-phosphate	C4 H9 O6 P1 	CC(=O)C(O)COP(O)(O)=O		DIOHBUTANONEPSYN-RXN	D-ribulose-5-phosphate  =  3,4-dihydroxy-2-butanone-4-P + formate	riboflavin and FMN and FAD biosynthesis
thymidine	deoxythymidine	C10 H14 N2 O5 	C(O)C1(OC(CC(O)1)n2(c(=O)[nH]c(=O)c(C)c2))	LIGAND:C00214*CAS:50-89-5	2.4.2.4	phosphate + thymidine  =  deoxyribose-1-phosphate + thymine	(deoxy)ribose phosphate degradation
2-acylglycerol	2-Glyceride*2-Monoacylglycerol	C4 H7 O4 R1 			RXN-1603	2-acylglycerol  =  acylglycerol	triacylglycerol degradation
2-acylglycerol	2-Glyceride*2-Monoacylglycerol	C4 H7 O4 R1 			RXN-1602	1,2-diacylglycerol + H2O  =  2-acylglycerol + a fatty acid	triacylglycerol degradation
kynurenine	L-kynurenine	C10 H12 N2 O3 	C(=O)(O)C(N)CC(=O)c1(c(N)cccc1)	CAS:343-65-7	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	NAD biosynthesis II (from tryptophan)
kynurenine	L-kynurenine	C10 H12 N2 O3 	C(=O)(O)C(N)CC(=O)c1(c(N)cccc1)	CAS:343-65-7	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	tryptophan degradation
kynurenine	L-kynurenine	C10 H12 N2 O3 	C(=O)(O)C(N)CC(=O)c1(c(N)cccc1)	CAS:343-65-7	3.5.1.9	N-formylkynurenine + H2O  =  kynurenine + formate	NAD biosynthesis II (from tryptophan)
kynurenine	L-kynurenine	C10 H12 N2 O3 	C(=O)(O)C(N)CC(=O)c1(c(N)cccc1)	CAS:343-65-7	3.5.1.9	N-formylkynurenine + H2O  =  kynurenine + formate	tryptophan degradation
dihydrokaempferol	aromadendrin*(+)-aromadendrin*(+)-Dihydrokaempferol	C15 H12 O6 	c1(cc(ccc1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))	CAS:480-20-6	1.14.13.21	dihydrokaempferol + O2  =  dihydroquercetin + H2O	flavonol biosynthesis
dihydrokaempferol	aromadendrin*(+)-aromadendrin*(+)-Dihydrokaempferol	C15 H12 O6 	c1(cc(ccc1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))	CAS:480-20-6	1.14.13.21	dihydrokaempferol + O2  =  dihydroquercetin + H2O	anthocyanin biosynthesis
dihydrokaempferol	aromadendrin*(+)-aromadendrin*(+)-Dihydrokaempferol	C15 H12 O6 	c1(cc(ccc1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))	CAS:480-20-6	RXN1F-93	dihydrokaempferol + alpha-ketoglutarate + O2  =  kaempferol + succinate + CO2 + H2O	flavonol biosynthesis
dihydrokaempferol	aromadendrin*(+)-aromadendrin*(+)-Dihydrokaempferol	C15 H12 O6 	c1(cc(ccc1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))	CAS:480-20-6	1.1.1.219	NADPH + dihydrokaempferol  =  leucopelargonidin + NADP+	anthocyanin biosynthesis
dihydrokaempferol	aromadendrin*(+)-aromadendrin*(+)-Dihydrokaempferol	C15 H12 O6 	c1(cc(ccc1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))	CAS:480-20-6	1.14.11.9	naringenin + O2 + alpha-ketoglutarate  =  CO2 + succinate + dihydrokaempferol	flavonoid biosynthesis
brassicasterol		C28 H46 O1 	CC(C)C(C)C=CC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4242	campesterol  =  brassicasterol	sterol biosynthesis
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides II
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides I
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	2.6.1.1	oxaloacetate + L-glutamate  =  L-aspartate + alpha-ketoglutarate	asparagine biosynthesis
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	2.6.1.1	oxaloacetate + L-glutamate  =  L-aspartate + alpha-ketoglutarate	aspartate biosynthesis and degradation
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	2.7.2.4	L-aspartate + ATP  =  L-aspartyl-4-phosphate + ADP	homoserine biosynthesis
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	2.7.2.4	L-aspartate + ATP  =  L-aspartyl-4-phosphate + ADP	lysine biosynthesis
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides II
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides I
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.1.1.12	tRNAasp + L-aspartate + ATP  =  L-aspartyl-tRNAasp + pyrophosphate + AMP	tRNA charging pathway
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis II (acetyl cycle)
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis III
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	1.4.3.-	O2 + L-aspartate  =  H2O2 + iminoaspartate	NAD biosynthesis I (from aspartate)
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	2.1.3.2	L-aspartate + carbamoyl-phosphate  =  carbamoyl-L-aspartate + phosphate	de novo biosynthesis of pyrimidine ribonucleotides
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	RXN-2946	indole-3-acetate + L-aspartate  =  indole-3-acetyl-asp + H2O	IAA conjugate biosynthesis
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	6.3.5.4	H2O + L-glutamine + L-aspartate + ATP  =  L-glutamate + L-asparagine + pyrophosphate + AMP	asparagine biosynthesis
L-aspartate	L-aspartic acid*aspartic acid*D*aspartate*asp	C4 H7 N1 O4 	C(O)(=O)[CH](N)CC(O)=O	CAS:56-84-8	3.5.1.1	L-asparagine + H2O  =  NH3 + L-aspartate	asparagine degradation I
stigmasterol		C29 H48 O1 	CC(C)C(CC)C=CC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4243	sitosterol  =  stigmasterol	sterol biosynthesis
2-amino-3-carboxymuconate semialdehyde	2-amino-3-carboxymuconate-6-semialdehyde*ACS	C7 H7 N1 O5 	[CH](=O)C=CC(C(=O)O)=C(N)C(O)=O		4.1.1.45	2-amino-3-carboxymuconate semialdehyde  =  CO2 + 2-aminomuconate semialdehyde	tryptophan degradation
2-amino-3-carboxymuconate semialdehyde	2-amino-3-carboxymuconate-6-semialdehyde*ACS	C7 H7 N1 O5 	[CH](=O)C=CC(C(=O)O)=C(N)C(O)=O		RXN-5721	2-amino-3-carboxymuconate semialdehyde  =  quinolinate + H2O	NAD biosynthesis II (from tryptophan)
2-amino-3-carboxymuconate semialdehyde	2-amino-3-carboxymuconate-6-semialdehyde*ACS	C7 H7 N1 O5 	[CH](=O)C=CC(C(=O)O)=C(N)C(O)=O		1.13.11.6	O2 + 3-hydroxy-anthranilate  =  2-amino-3-carboxymuconate semialdehyde	NAD biosynthesis II (from tryptophan)
2-amino-3-carboxymuconate semialdehyde	2-amino-3-carboxymuconate-6-semialdehyde*ACS	C7 H7 N1 O5 	[CH](=O)C=CC(C(=O)O)=C(N)C(O)=O		1.13.11.6	O2 + 3-hydroxy-anthranilate  =  2-amino-3-carboxymuconate semialdehyde	tryptophan degradation
L-threonyl-tRNAthr	L-THREONYL-TRNA(THR)				6.1.1.3	tRNAthr + L-threonine + ATP  =  L-threonyl-tRNAthr + pyrophosphate + AMP	tRNA charging pathway
glycolaldehyde	2-OH-acetaldehyde*glycolaldehyde*hydroxyacetaldehyde*2-hydroxyethanal	C2 H4 O2 	C(O)C=O	CAS:141-46-8	4.1.2.25	dihydro-neo-pterin  =  glycolaldehyde + 6-hydroxymethyl-dehydropterin	tetrahydrofolate biosynthesis I
glycolaldehyde	2-OH-acetaldehyde*glycolaldehyde*hydroxyacetaldehyde*2-hydroxyethanal	C2 H4 O2 	C(O)C=O	CAS:141-46-8	4.1.2.25	dihydro-neo-pterin  =  glycolaldehyde + 6-hydroxymethyl-dehydropterin	tetrahydrofolate biosynthesis II
acetate	acet*acetic acid*ethanoic acid	C2 H3 O2 	C([O-1])(=O)C	LIGAND-CPD:c00033*CAS:71-50-1	2.7.2.1	acetylphosphate + ADP  =  acetate + ATP	carbon monoxide dehydrogenase pathway
acetate	acet*acetic acid*ethanoic acid	C2 H3 O2 	C([O-1])(=O)C	LIGAND-CPD:c00033*CAS:71-50-1	RXN-1408	indole + acetate  =  indole-3-acetate	IAA biosynthesis I
acetate	acet*acetic acid*ethanoic acid	C2 H3 O2 	C([O-1])(=O)C	LIGAND-CPD:c00033*CAS:71-50-1	3.5.1.16	N-alpha-acetylornithine + H2O  =  L-ornithine + acetate	arginine biosynthesis
acetate	acet*acetic acid*ethanoic acid	C2 H3 O2 	C([O-1])(=O)C	LIGAND-CPD:c00033*CAS:71-50-1	UDPACYLGLCNACDEACETYL-RXN	UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine + H2O  =  UDP-3-O-(3-hydroxymyristoyl)glucosamine + acetate	lipid-A-precursor biosynthesis
acetate	acet*acetic acid*ethanoic acid	C2 H3 O2 	C([O-1])(=O)C	LIGAND-CPD:c00033*CAS:71-50-1	RXN-721	O-acetyl-L-homoserine + L-cysteine  =  cystathionine + acetate	homocysteine and cysteine interconversion
acetate	acet*acetic acid*ethanoic acid	C2 H3 O2 	C([O-1])(=O)C	LIGAND-CPD:c00033*CAS:71-50-1	RXN-744	3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate + 3 O2  =  (+)-7-isojasmonate + 3 acetate	jasmonic acid biosynthesis
acetate	acet*acetic acid*ethanoic acid	C2 H3 O2 	C([O-1])(=O)C	LIGAND-CPD:c00033*CAS:71-50-1	4.2.99.8	O-acetyl-L-serine + H2S  =  L-cysteine + acetate	cysteine biosynthesis
acetate	acet*acetic acid*ethanoic acid	C2 H3 O2 	C([O-1])(=O)C	LIGAND-CPD:c00033*CAS:71-50-1	4.2.99.8	O-acetyl-L-serine + H2S  =  L-cysteine + acetate	sulfate assimilation
4-coumaroylshikimate	trans-5-O-(4-Coumaroyl)shikimate*trans-(p-coumaroyl)-shikimate	C16 H16 O7 	C(=O)(O)C1(CC(C(O)C(C=1)O)OC(=O)C=CC2(=CC=C(O)C=C2))		1.14.13.36	4-coumaroylshikimate + NADPH + O2  =  caffeoylshikimate + NADP+ + H2O	lignin biosynthesis
4-coumaroylshikimate	trans-5-O-(4-Coumaroyl)shikimate*trans-(p-coumaroyl)-shikimate	C16 H16 O7 	C(=O)(O)C1(CC(C(O)C(C=1)O)OC(=O)C=CC2(=CC=C(O)C=C2))		2.3.1.133	shikimate + coumaroyl-CoA  =  4-coumaroylshikimate + coenzyme A	lignin biosynthesis
L-glutamate gamma-semialdehyde	glutamic &gamma;-semialdehyde*L-glutamate-5-semialdehyde*glutamate-semialdehyde	C5 H9 N1 O3 	C(=O)(O)C(N)CCC=O		SPONTPRO-RXN	L-glutamate gamma-semialdehyde  =  H2O + L-delta1-pyrroline-5-carboxylate	proline biosynthesis
L-glutamate gamma-semialdehyde	glutamic &gamma;-semialdehyde*L-glutamate-5-semialdehyde*glutamate-semialdehyde	C5 H9 N1 O3 	C(=O)(O)C(N)CCC=O		SPONTPRO-RXN	L-glutamate gamma-semialdehyde  =  H2O + L-delta1-pyrroline-5-carboxylate	arginine degradation II
L-glutamate gamma-semialdehyde	glutamic &gamma;-semialdehyde*L-glutamate-5-semialdehyde*glutamate-semialdehyde	C5 H9 N1 O3 	C(=O)(O)C(N)CCC=O		PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	arginine biosynthesis III
L-glutamate gamma-semialdehyde	glutamic &gamma;-semialdehyde*L-glutamate-5-semialdehyde*glutamate-semialdehyde	C5 H9 N1 O3 	C(=O)(O)C(N)CCC=O		PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	proline biosynthesis
L-glutamate gamma-semialdehyde	glutamic &gamma;-semialdehyde*L-glutamate-5-semialdehyde*glutamate-semialdehyde	C5 H9 N1 O3 	C(=O)(O)C(N)CCC=O		2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	arginine biosynthesis III
L-glutamate gamma-semialdehyde	glutamic &gamma;-semialdehyde*L-glutamate-5-semialdehyde*glutamate-semialdehyde	C5 H9 N1 O3 	C(=O)(O)C(N)CCC=O		2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	proline biosynthesis
L-glutamate gamma-semialdehyde	glutamic &gamma;-semialdehyde*L-glutamate-5-semialdehyde*glutamate-semialdehyde	C5 H9 N1 O3 	C(=O)(O)C(N)CCC=O		2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	arginine degradation II
L-aspartyl-4-phosphate	4-phospho-L-aspartate*L-4-aspartyl phosphate*L-&beta;-aspartyl-P*L-&beta;-aspartyl-phosphate*L-aspartyl-4-P*L-aspartyl-&beta;-phosphate	C4 H8 N1 O7 P1 	C(=O)(OP(=O)(O)O)CC(N)C(O)=O	CAS:22138-53-0	2.7.2.4	L-aspartate + ATP  =  L-aspartyl-4-phosphate + ADP	homoserine biosynthesis
L-aspartyl-4-phosphate	4-phospho-L-aspartate*L-4-aspartyl phosphate*L-&beta;-aspartyl-P*L-&beta;-aspartyl-phosphate*L-aspartyl-4-P*L-aspartyl-&beta;-phosphate	C4 H8 N1 O7 P1 	C(=O)(OP(=O)(O)O)CC(N)C(O)=O	CAS:22138-53-0	2.7.2.4	L-aspartate + ATP  =  L-aspartyl-4-phosphate + ADP	lysine biosynthesis
L-aspartyl-4-phosphate	4-phospho-L-aspartate*L-4-aspartyl phosphate*L-&beta;-aspartyl-P*L-&beta;-aspartyl-phosphate*L-aspartyl-4-P*L-aspartyl-&beta;-phosphate	C4 H8 N1 O7 P1 	C(=O)(OP(=O)(O)O)CC(N)C(O)=O	CAS:22138-53-0	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	homoserine biosynthesis
L-aspartyl-4-phosphate	4-phospho-L-aspartate*L-4-aspartyl phosphate*L-&beta;-aspartyl-P*L-&beta;-aspartyl-phosphate*L-aspartyl-4-P*L-aspartyl-&beta;-phosphate	C4 H8 N1 O7 P1 	C(=O)(OP(=O)(O)O)CC(N)C(O)=O	CAS:22138-53-0	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	lysine biosynthesis
ThiS-COSH	B4407*ThiS				THIAZOLSYN2-RXN	L-tyrosine + 1-deoxy-D-xylulose 5-phosphate + ThiS-COSH  =  4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-hydroxybenzyl alcohol + C1 of tyrosine + ThiS protein	thiamin biosynthesis
indole carboxyl hydro-thiazole		C12 H10 N2 O2 S1 	C1(=NC(CS1)C(=O)O)c2(c3(c([nH]c2)cccc3))		RXN1F-16	NADP+ + indole carboxyl hydro-thiazole  =  indole carboxyl thiazole + NADPH	camalexin biosynthesis
indole carboxyl hydro-thiazole		C12 H10 N2 O2 S1 	C1(=NC(CS1)C(=O)O)c2(c3(c([nH]c2)cccc3))		RXN1F-15	indole carboxyl tetrahydro-thiazole  =  indole carboxyl hydro-thiazole	camalexin biosynthesis
reduced glutaredoxin	Grx*B0849*GrxA				RXN0-748	GDP + reduced glutaredoxin  =  dGDP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
reduced glutaredoxin	Grx*B0849*GrxA				RXN0-747	ADP + reduced glutaredoxin  =  dADP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
reduced glutaredoxin	Grx*B0849*GrxA				1.17.4.-	UDP + reduced glutaredoxin  =  dUDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
reduced glutaredoxin	Grx*B0849*GrxA				1.17.4.-	CDP + reduced glutaredoxin  =  dCDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
L-pantoate	pantoate*(R)-pantoate	C6 H12 O4 	C(O)C(C)(C)C(O)C(=O)O		1.1.1.169	2-dehydropantoate + NADPH  =  L-pantoate + NADP+	pantothenate biosynthesis
L-pantoate	pantoate*(R)-pantoate	C6 H12 O4 	C(O)C(C)(C)C(O)C(=O)O		6.3.2.1	beta-alanine + L-pantoate + ATP  =  pantothenate + pyrophosphate + AMP	pantothenate biosynthesis
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	homocysteine and cysteine interconversion
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	methionine biosynthesis
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	sulfate assimilation
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	4.4.1.1	cystathionine + H2O  =  NH3 + 2-oxobutanoate + L-cysteine	homocysteine and cysteine interconversion
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	CYSTATHIONASE-RXN	cystathionine + H2O  =  L-cysteine + homoserine	methionine degradation I
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	RXN-721	O-acetyl-L-homoserine + L-cysteine  =  cystathionine + acetate	homocysteine and cysteine interconversion
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	4.2.99.-	L-cysteine + O-phospho-L-homoserine  =  cystathionine + phosphate	methionine biosynthesis
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	4.2.99.-	L-cysteine + O-phospho-L-homoserine  =  cystathionine + phosphate	sulfate assimilation
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	4.2.1.22	homocysteine + L-serine  =  H2O + cystathionine	homocysteine and cysteine interconversion
cystathionine	L-cystathionine	C7 H14 N2 O4 S1 	C(CC(N)C(O)=O)SCC(N)C(=O)O	LIGAND:C00542*CAS:56-88-2	4.2.1.22	homocysteine + L-serine  =  H2O + cystathionine	methionine degradation I
AICAR	Z-nucleotide*aminoimidazole carboxamide ribonucleotide*AICA ribonucleotide*5'-phosphoribosyl-5-amino-4-imidazole carboxamide*5-amino-4-imidazolecarboxamide ribotide*5'-P-ribosyl-5-amino-4-imidazole carboxamide	C9 H15 N4 O8 P1 	C(OP(=O)(O)O)[CH]1(O[CH]([CH](O)[CH](O)1)n2(c(N)c(C(=O)N)nc2))	CAS:3031-94-5	2.1.2.3	N10-formyl-THF + AICAR  =  tetrahydrofolate + phosphoribosyl-formamido-carboxamide	de novo biosynthesis of purine nucleotides II
AICAR	Z-nucleotide*aminoimidazole carboxamide ribonucleotide*AICA ribonucleotide*5'-phosphoribosyl-5-amino-4-imidazole carboxamide*5-amino-4-imidazolecarboxamide ribotide*5'-P-ribosyl-5-amino-4-imidazole carboxamide	C9 H15 N4 O8 P1 	C(OP(=O)(O)O)[CH]1(O[CH]([CH](O)[CH](O)1)n2(c(N)c(C(=O)N)nc2))	CAS:3031-94-5	2.1.2.3	N10-formyl-THF + AICAR  =  tetrahydrofolate + phosphoribosyl-formamido-carboxamide	de novo biosynthesis of purine nucleotides I
AICAR	Z-nucleotide*aminoimidazole carboxamide ribonucleotide*AICA ribonucleotide*5'-phosphoribosyl-5-amino-4-imidazole carboxamide*5-amino-4-imidazolecarboxamide ribotide*5'-P-ribosyl-5-amino-4-imidazole carboxamide	C9 H15 N4 O8 P1 	C(OP(=O)(O)O)[CH]1(O[CH]([CH](O)[CH](O)1)n2(c(N)c(C(=O)N)nc2))	CAS:3031-94-5	2.4.2.-	phosphoribulosylformimino-AICAR-P + L-glutamine  =  D-erythro-imidazole-glycerol-phosphate + AICAR + L-glutamate	histidine biosynthesis
AICAR	Z-nucleotide*aminoimidazole carboxamide ribonucleotide*AICA ribonucleotide*5'-phosphoribosyl-5-amino-4-imidazole carboxamide*5-amino-4-imidazolecarboxamide ribotide*5'-P-ribosyl-5-amino-4-imidazole carboxamide	C9 H15 N4 O8 P1 	C(OP(=O)(O)O)[CH]1(O[CH]([CH](O)[CH](O)1)n2(c(N)c(C(=O)N)nc2))	CAS:3031-94-5	4.3.2.2	5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole  =  fumarate + AICAR	de novo biosynthesis of purine nucleotides II
AICAR	Z-nucleotide*aminoimidazole carboxamide ribonucleotide*AICA ribonucleotide*5'-phosphoribosyl-5-amino-4-imidazole carboxamide*5-amino-4-imidazolecarboxamide ribotide*5'-P-ribosyl-5-amino-4-imidazole carboxamide	C9 H15 N4 O8 P1 	C(OP(=O)(O)O)[CH]1(O[CH]([CH](O)[CH](O)1)n2(c(N)c(C(=O)N)nc2))	CAS:3031-94-5	4.3.2.2	5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole  =  fumarate + AICAR	de novo biosynthesis of purine nucleotides I
succinate-semialdehyde-thiamine PPi	Succinate semialdehyde-thiamin diphosphate anion*succinate-semialdehyde-thiamine pyrophosphate*succinate-semialdehyde-thiamin pyrophosphate*succinate-semialdehyde-thiamin PPi	C16 H25 N4 O10 P2 S1 	c1(c(c(N)nc(n1)C)C[n+1]2(c(C)c(sc2)CCOP(=O)(O)OP(O)(=O)OC(O)CCC(=O)O))	LIGAND-CPD:C05816	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	phylloquinone biosynthesis
succinate-semialdehyde-thiamine PPi	Succinate semialdehyde-thiamin diphosphate anion*succinate-semialdehyde-thiamine pyrophosphate*succinate-semialdehyde-thiamin pyrophosphate*succinate-semialdehyde-thiamin PPi	C16 H25 N4 O10 P2 S1 	c1(c(c(N)nc(n1)C)C[n+1]2(c(C)c(sc2)CCOP(=O)(O)OP(O)(=O)OC(O)CCC(=O)O))	LIGAND-CPD:C05816	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	menaquinone biosynthesis
succinate-semialdehyde-thiamine PPi	Succinate semialdehyde-thiamin diphosphate anion*succinate-semialdehyde-thiamine pyrophosphate*succinate-semialdehyde-thiamin pyrophosphate*succinate-semialdehyde-thiamin PPi	C16 H25 N4 O10 P2 S1 	c1(c(c(N)nc(n1)C)C[n+1]2(c(C)c(sc2)CCOP(=O)(O)OP(O)(=O)OC(O)CCC(=O)O))	LIGAND-CPD:C05816	4.1.1.71	alpha-ketoglutarate + thiamin diphosphate  =  succinate-semialdehyde-thiamine PPi + CO2	menaquinone biosynthesis
trans-2-hexenal		C6 H10 O1 	CCCC=CC=O	CAS:6728-26-3	RXN-1348	trans-2-hexenal  =  trans-2-hexenol	lipoxygenase pathway
trans-2-hexenal		C6 H10 O1 	CCCC=CC=O	CAS:6728-26-3	RXN-1346	cis-3-hexenal  =  trans-2-hexenal	lipoxygenase pathway
coniferyl aldehyde	4-hydroxy-3-methoxycinnamic aldehyde*4-hydroxy-3-methoxycinnamaldehyde*4-hydroxy-3-methoxycinnamic aldehyde *coniferaldehyde	C10 H10 O3 	C(=O)C=Cc1(cc(OC)c(O)cc1)	CAS:458-36-6	1.1.1.195	coniferyl aldehyde + NADPH  =  coniferyl alcohol + NADP+	lignin biosynthesis
coniferyl aldehyde	4-hydroxy-3-methoxycinnamic aldehyde*4-hydroxy-3-methoxycinnamaldehyde*4-hydroxy-3-methoxycinnamic aldehyde *coniferaldehyde	C10 H10 O3 	C(=O)C=Cc1(cc(OC)c(O)cc1)	CAS:458-36-6	RXN-1142	coniferyl aldehyde + NADPH + O2  =  5-hydroxy-coniferaldehyde + NADP+ + H2O	lignin biosynthesis
coniferyl aldehyde	4-hydroxy-3-methoxycinnamic aldehyde*4-hydroxy-3-methoxycinnamaldehyde*4-hydroxy-3-methoxycinnamic aldehyde *coniferaldehyde	C10 H10 O3 	C(=O)C=Cc1(cc(OC)c(O)cc1)	CAS:458-36-6	RXN-91	coniferyl aldehyde + UDP-D-glucose  =  coniferaldehyde glucoside + UDP	monolignol glucosides biosynthesis
coniferyl aldehyde	4-hydroxy-3-methoxycinnamic aldehyde*4-hydroxy-3-methoxycinnamaldehyde*4-hydroxy-3-methoxycinnamic aldehyde *coniferaldehyde	C10 H10 O3 	C(=O)C=Cc1(cc(OC)c(O)cc1)	CAS:458-36-6	1.2.1.44	feruloyl-CoA + NADPH  =  coniferyl aldehyde + NADP+ + coenzyme A	lignin biosynthesis
L-asparaginyl-tRNAasn	L-ASPARAGINYL-TRNA(ASN)				6.1.1.22	tRNAasn + L-asparagine + ATP  =  L-asparaginyl-tRNAasn + pyrophosphate + AMP	tRNA charging pathway
2,3-dimethyl-6-phytyl-1,4-benzoquinone		C28 H48 O2 	CC(CCCC(C)C)CCCC(C)CCCC(C)=CCc1(c(O)c(C)c(C)c(c1)O)		RXN-2543	2,3-dimethyl-6-phytyl-1,4-benzoquinone  =  gamma-tocopherol	vitamin E biosynthesis
2,3-dimethyl-6-phytyl-1,4-benzoquinone		C28 H48 O2 	CC(CCCC(C)C)CCCC(C)CCCC(C)=CCc1(c(O)c(C)c(C)c(c1)O)		2.1.1.-	2-methyl-6-phytyl-1,4-benzoquinone + S-adenosyl-L-methionine  =  2,3-dimethyl-6-phytyl-1,4-benzoquinone + S-adenosyl-homocysteine	vitamin E biosynthesis
e-	e*electron				1.17.4.3	2-C-methyl-D-erythritol-2,4-cyclodiphosphate + e- + H+  =  1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
e-	e*electron				RXN-924	2 NAD(P)+ + 2 H+ + 4 e-  =  2 NAD(P)H	photosynthesis, light reaction
e-	e*electron				PSII-RXN	2 H2O  =  4 H+ + 4 e- + O2	photosynthesis, light reaction
caffeoyl-CoA		C30 H42 N7 O19 P3 S1 	C(CC(=O)NCCSC(=O)C=Cc1(cc(O)c(O)cc1))NC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))		2.1.1.104	caffeoyl-CoA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + feruloyl-CoA	lignin biosynthesis
caffeoyl-CoA		C30 H42 N7 O19 P3 S1 	C(CC(=O)NCCSC(=O)C=Cc1(cc(O)c(O)cc1))NC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))		2.1.1.104	caffeoyl-CoA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + feruloyl-CoA	suberin biosynthesis
caffeoyl-CoA		C30 H42 N7 O19 P3 S1 	C(CC(=O)NCCSC(=O)C=Cc1(cc(O)c(O)cc1))NC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))		6.2.1.12	caffeate + coenzyme A + ATP  =  caffeoyl-CoA + AMP + pyrophosphate	suberin biosynthesis
caffeoyl-CoA		C30 H42 N7 O19 P3 S1 	C(CC(=O)NCCSC(=O)C=Cc1(cc(O)c(O)cc1))NC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))		2.3.1.133	caffeoylshikimate + coenzyme A  =  caffeoyl-CoA + shikimate	lignin biosynthesis
caffeoyl-CoA		C30 H42 N7 O19 P3 S1 	C(CC(=O)NCCSC(=O)C=Cc1(cc(O)c(O)cc1))NC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))		2.3.1.133	caffeoylquinate + coenzyme A  =  caffeoyl-CoA + quinate	lignin biosynthesis
hydroxycinnamoyl-CoA		C30 H44 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)c1(ccccc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		RXN-2003	hydroxycinnamoyl-CoA + NADP+  =  oxocinnamoyl-CoA + NADPH	salicylic acid biosynthesis
hydroxycinnamoyl-CoA		C30 H44 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)c1(ccccc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		RXN-2002	(E)-cinnamoyl-CoA + H2O  =  hydroxycinnamoyl-CoA	salicylic acid biosynthesis
a secondary alcohol					RXN-1023	a secondary alcohol  =  a ketone + methyl-ethyl-ketone	epicuticular wax biosynthesis
a secondary alcohol					RXN-1022	an alkane  =  a secondary alcohol	epicuticular wax biosynthesis
coniferin	coniferyl alcohol-4-O-&beta;-D-glucopyranoside	C16 H22 O8 	C(O)C=Cc1(cc(OC)c(cc1)OC2(C(O)C(O)C(O)C(O2)CO))		3.2.1.126	H2O + coniferin  =  coniferyl alcohol + beta-D-glucose	coniferin metabolism
coniferin	coniferyl alcohol-4-O-&beta;-D-glucopyranoside	C16 H22 O8 	C(O)C=Cc1(cc(OC)c(cc1)OC2(C(O)C(O)C(O)C(O2)CO))		2.4.1.111	coniferyl alcohol + UDP-D-glucose  =  coniferin + UDP	coniferin metabolism
4-aminobutyrate	GABA*4-aminobutyric acid*4-aminobutanoate*4-NH3-but*4-NH2-but*gamma-aminobutyrate*&gamma;-aminobutyrate*4-amino-n-butyric acid*gamma-amino-n-butyric acid	C4 H9 N1 O2 	C(=O)(O)CCCN	CAS:56-12-2	2.6.1.19	alpha-ketoglutarate + 4-aminobutyrate  =  L-glutamate + succinate semialdehyde	glutamate degradation II
4-aminobutyrate	GABA*4-aminobutyric acid*4-aminobutanoate*4-NH3-but*4-NH2-but*gamma-aminobutyrate*&gamma;-aminobutyrate*4-amino-n-butyric acid*gamma-amino-n-butyric acid	C4 H9 N1 O2 	C(=O)(O)CCCN	CAS:56-12-2	2.6.1.19	alpha-ketoglutarate + 4-aminobutyrate  =  L-glutamate + succinate semialdehyde	arginine degradation I
4-aminobutyrate	GABA*4-aminobutyric acid*4-aminobutanoate*4-NH3-but*4-NH2-but*gamma-aminobutyrate*&gamma;-aminobutyrate*4-amino-n-butyric acid*gamma-amino-n-butyric acid	C4 H9 N1 O2 	C(=O)(O)CCCN	CAS:56-12-2	2.6.1.19	4-aminobutyrate + pyruvate  =  succinate semialdehyde + L-alanine	glutamate degradation II
4-aminobutyrate	GABA*4-aminobutyric acid*4-aminobutanoate*4-NH3-but*4-NH2-but*gamma-aminobutyrate*&gamma;-aminobutyrate*4-amino-n-butyric acid*gamma-amino-n-butyric acid	C4 H9 N1 O2 	C(=O)(O)CCCN	CAS:56-12-2	1.2.1.19	4-amino-butyraldehyde + NAD+ + H2O  =  4-aminobutyrate + NADH	arginine degradation I
4-aminobutyrate	GABA*4-aminobutyric acid*4-aminobutanoate*4-NH3-but*4-NH2-but*gamma-aminobutyrate*&gamma;-aminobutyrate*4-amino-n-butyric acid*gamma-amino-n-butyric acid	C4 H9 N1 O2 	C(=O)(O)CCCN	CAS:56-12-2	4.1.1.15	L-glutamate  =  CO2 + 4-aminobutyrate	glutamate degradation II
3-hydroxypropyl-glucosinolate		C10 H19 N1 O10 S2 	C(O)CCC(=NOS(O)(=O)=O)SC1(C(CO)C(O)C(O)C(O1)O)		RXN-2224	3-hydroxypropyl-glucosinolate  =  3-benzoyloxypropyl-glucosinolate	glucosinolate biosynthesis from homomethionine
3-hydroxypropyl-glucosinolate		C10 H19 N1 O10 S2 	C(O)CCC(=NOS(O)(=O)=O)SC1(C(CO)C(O)C(O)C(O1)O)		RXN-2223	3-methylsulfinylpropyl-glucosinolate  =  3-hydroxypropyl-glucosinolate	glucosinolate biosynthesis from homomethionine
sulfoquinovosyldiacylglycerol	SQDG*SL	C11 H16 O12 R2 S1 			RXN-1224	UDP-sulfoquinovose + 1,2-diacylglycerol  =  sulfoquinovosyldiacylglycerol + UDP	sulfolipid biosynthesis
4-fumaryl-acetoacetate		C8 H8 O6 	C(=O)(O)C=CC(=O)CC(=O)CC(O)=O		3.7.1.2	H2O + 4-fumaryl-acetoacetate  =  fumarate + acetoacetate	tyrosine degradation
4-fumaryl-acetoacetate		C8 H8 O6 	C(=O)(O)C=CC(=O)CC(=O)CC(O)=O		3.7.1.2	H2O + 4-fumaryl-acetoacetate  =  fumarate + acetoacetate	phenylalanine degradation
4-fumaryl-acetoacetate		C8 H8 O6 	C(=O)(O)C=CC(=O)CC(=O)CC(O)=O		5.2.1.2	4-maleyl-acetoacetate  =  4-fumaryl-acetoacetate	tyrosine degradation
4-fumaryl-acetoacetate		C8 H8 O6 	C(=O)(O)C=CC(=O)CC(=O)CC(O)=O		5.2.1.2	4-maleyl-acetoacetate  =  4-fumaryl-acetoacetate	phenylalanine degradation
3-hydroxy-propionate	3-Hydroxypropanoate*&beta;-hydroxypropionate*3-Hydroxypropanoic acid*3-Hydropropionic acid*Hydracrylic acid	C3 H6 O3 	C(O)(=O)CCO	CAS:96-26-4*CAS:503-66-2	1.1.1.59	NAD+ + 3-hydroxy-propionate  =  NADH + malonate semialdehyde	beta-alanine biosynthesis II
3-hydroxy-propionate	3-Hydroxypropanoate*&beta;-hydroxypropionate*3-Hydroxypropanoic acid*3-Hydropropionic acid*Hydracrylic acid	C3 H6 O3 	C(O)(=O)CCO	CAS:96-26-4*CAS:503-66-2	3.1.2.4	3-hydroxypropionyl-CoA + H2O  =  3-hydroxy-propionate + coenzyme A	beta-alanine biosynthesis II
myo-inositol	chiro-inositol*mesoinositol*inositol	C6 H12 O6 	C1(O)(C(O)C(O)C(O)C(O)C1O)	LIGAND:C00137*CAS:6917-35-7	2.7.8.11	CDP-diacylglycerol + myo-inositol  =  L-1-phosphatidyl-inositol + CMP	phospholipid biosynthesis
myo-inositol	chiro-inositol*mesoinositol*inositol	C6 H12 O6 	C1(O)(C(O)C(O)C(O)C(O)C1O)	LIGAND:C00137*CAS:6917-35-7	2.7.1.64	myo-inositol + ATP  =  D-myo-inositol (3)-monophosphate + ADP	lipid-independent phytate biosynthesis
myo-inositol	chiro-inositol*mesoinositol*inositol	C6 H12 O6 	C1(O)(C(O)C(O)C(O)C(O)C1O)	LIGAND:C00137*CAS:6917-35-7	1.13.99.1	O2 + myo-inositol  ->  H2O + glucuronate	inositol oxidation pathway
myo-inositol	chiro-inositol*mesoinositol*inositol	C6 H12 O6 	C1(O)(C(O)C(O)C(O)C(O)C1O)	LIGAND:C00137*CAS:6917-35-7	RXN-7253	D-myo-inositol (2) monophosphate + H2O  =  myo-inositol + phosphate	phytate degradation I
myo-inositol	chiro-inositol*mesoinositol*inositol	C6 H12 O6 	C1(O)(C(O)C(O)C(O)C(O)C1O)	LIGAND:C00137*CAS:6917-35-7	RXN-7252	D-myo-Inositol (1)-monophosphate + H2O  =  myo-inositol + phosphate	phytate degradation I
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	2.7.7.41	CTP + L-phosphatidate  =  CDP-diacylglycerol + pyrophosphate	phospholipid biosynthesis
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	2.7.7.38	3-deoxy-D-manno-octulosonate + CTP  =  CMP-3-deoxy-D-manno-octulosonate + pyrophosphate	lipid-A-precursor biosynthesis
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	2.7.7.15	phosphoryl-choline + CTP  =  CDP-choline + pyrophosphate	choline biosynthesis III
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	RXN0-277	2-C-methyl-D-erythritol-4-phosphate + CTP  =  4-diphosphocytidyl-2-C-methylerythritol + pyrophosphate	isopentenyl diphosphate biosynthesis -- mevalonate-independent
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	RXN0-723	CTP + reduced flavodoxin  =  dCTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	6.3.2.5	D-4'-phosphopantothenate + L-cysteine + CTP  =  R-4'-phosphopantothenoyl-L-cysteine + pyrophosphate + CMP	coenzyme A biosynthesis
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	2.7.1.108	dolichol + CTP  =  dolichyl-phosphate + CDP	dolichyl-diphosphooligosaccharide biosynthesis
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	2.7.4.6	CTP + ADP  =  CDP + ATP	de novo biosynthesis of pyrimidine ribonucleotides
CTP	cytidine-triphosphate*cytidine-5'-triphosphate	C9 H16 N3 O14 P3 	c1(n(c(=O)nc(c1)N)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	LIGAND-CPD:C00063*CAS:65-47-4	6.3.4.2	L-glutamine + H2O + UTP + ATP  =  CTP + phosphate + ADP + L-glutamate	de novo biosynthesis of pyrimidine ribonucleotides
guanosine	nucleoside Q	C10 H13 N5 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00387*CAS:118-00-3	2.7.1.73	guanosine + ATP  =  GMP + ADP	salvage pathways of purine nucleosides
guanosine	nucleoside Q	C10 H13 N5 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00387*CAS:118-00-3	3.5.4.15	H2O + guanosine  =  NH3 + xanthosine	purine degradation
guanosine	nucleoside Q	C10 H13 N5 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00387*CAS:118-00-3	3.5.4.15	H2O + guanosine  =  NH3 + xanthosine	salvage pathways of purine nucleosides
guanosine	nucleoside Q	C10 H13 N5 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00387*CAS:118-00-3	3.2.2.1	guanosine + H2O  =  guanine + D-ribose	purine degradation
guanosine	nucleoside Q	C10 H13 N5 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00387*CAS:118-00-3	3.2.2.1	guanosine + H2O  =  guanine + D-ribose	salvage pathways of purine nucleosides
guanosine	nucleoside Q	C10 H13 N5 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00387*CAS:118-00-3	3.1.3.5	GMP + H2O  =  guanosine + phosphate	purine degradation
guanosine	nucleoside Q	C10 H13 N5 O5 	C(O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00387*CAS:118-00-3	3.1.3.5	GMP + H2O  =  guanosine + phosphate	salvage pathways of purine nucleosides
12-oxo-trans-10-dodecenoate	traumatin	C12 H20 O3 	C(=O)(O)CCCCCCCCC=CC=O		RXN-1349	12-oxo-cis-9-dodecenoate  =  12-oxo-trans-10-dodecenoate	lipoxygenase pathway
tRNAlys	TRNA(LYS)				6.1.1.6	tRNAlys + L-lysine + ATP  =  L-lysyl-tRNAlys + pyrophosphate + AMP	tRNA charging pathway
9,10-epoxy-18-hydroxystearate		C18 H34 O4 	C(O)CCCCCCCC1(C(O1)CCCCCCCC(O)=O)		RXN-1065	9,10-epoxy-18-hydroxystearate + H2O  =  9,10,18-trihydroxystearate	cutin biosynthesis
9,10-epoxy-18-hydroxystearate		C18 H34 O4 	C(O)CCCCCCCC1(C(O1)CCCCCCCC(O)=O)		RXN-1064	18-hydroxyoleate + NADPH + O2  =  9,10-epoxy-18-hydroxystearate + NADP+ + H2O	cutin biosynthesis
D-erythrose-4-phosphate	erythrose-4P*threose 4-phosphate*erythrose-4-phosphate*erythrose-4-P*D-erythrose-4-P	C4 H9 O7 P1 	C(=O)C(O)C(O)COP(O)(=O)O	CAS:585-18-2	2TRANSKETO-RXN	D-erythrose-4-phosphate + D-xylulose-5-phosphate  =  D-fructose-6-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-erythrose-4-phosphate	erythrose-4P*threose 4-phosphate*erythrose-4-phosphate*erythrose-4-P*D-erythrose-4-P	C4 H9 O7 P1 	C(=O)C(O)C(O)COP(O)(=O)O	CAS:585-18-2	2TRANSKETO-RXN	D-erythrose-4-phosphate + D-xylulose-5-phosphate  =  D-fructose-6-phosphate + D-glyceraldehyde-3-phosphate	non-oxidative branch of the pentose phosphate pathway
D-erythrose-4-phosphate	erythrose-4P*threose 4-phosphate*erythrose-4-phosphate*erythrose-4-P*D-erythrose-4-P	C4 H9 O7 P1 	C(=O)C(O)C(O)COP(O)(=O)O	CAS:585-18-2	4.1.2.-	dihydroxy-acetone-phosphate + D-erythrose-4-phosphate  =  D-sedoheptulose-1,7-bisphosphate	Calvin cycle
D-erythrose-4-phosphate	erythrose-4P*threose 4-phosphate*erythrose-4-phosphate*erythrose-4-P*D-erythrose-4-P	C4 H9 O7 P1 	C(=O)C(O)C(O)COP(O)(=O)O	CAS:585-18-2	4.1.2.15	phosphoenolpyruvate + D-erythrose-4-phosphate + H2O  =  3-deoxy-D-arabino-heptulosonate-7-phosphate + phosphate	chorismate biosynthesis
D-erythrose-4-phosphate	erythrose-4P*threose 4-phosphate*erythrose-4-phosphate*erythrose-4-P*D-erythrose-4-P	C4 H9 O7 P1 	C(=O)C(O)C(O)COP(O)(=O)O	CAS:585-18-2	2.2.1.2	D-glyceraldehyde-3-phosphate + D-sedoheptulose-7-phosphate  =  D-fructose-6-phosphate + D-erythrose-4-phosphate	non-oxidative branch of the pentose phosphate pathway
allantoate		C4 H8 N4 O4 	C(C(O)=O)(NC(N)=O)NC(N)=O	CAS:99-16-1	3.5.3.4	H2O + allantoate  =  (S)-ureidoglycolate + urea	ureide degradation
allantoate		C4 H8 N4 O4 	C(C(O)=O)(NC(N)=O)NC(N)=O	CAS:99-16-1	3.5.3.9	2 H2O + 2 allantoate  =  2 NH3 + O2 + 2 CO2 + 2 ureidoglycine	ureide degradation
allantoate		C4 H8 N4 O4 	C(C(O)=O)(NC(N)=O)NC(N)=O	CAS:99-16-1	3.5.2.5	H2O + allantoin  =  allantoate	ureide biosynthesis
allantoate		C4 H8 N4 O4 	C(C(O)=O)(NC(N)=O)NC(N)=O	CAS:99-16-1	3.5.2.5	H2O + allantoin  =  allantoate	ureide degradation
triacylglycerol	Triglyceride	C6 H5 O6 R12 R31 	C(OC(=O)[R3])C(OC([R1])=O)COC([R1])=O		3.1.1.3	H2O + triacylglycerol  =  a fatty acid + 1,2-diacylglycerol	triacylglycerol degradation
triacylglycerol	Triglyceride	C6 H5 O6 R12 R31 	C(OC(=O)[R3])C(OC([R1])=O)COC([R1])=O		RXN-1641	a phosphatidylcholine + 1,2-diacylglycerol  =  triacylglycerol + 1-acyl-sn-glycero-3-phosphocholine	triacylglycerol biosynthesis
triacylglycerol	Triglyceride	C6 H5 O6 R12 R31 	C(OC(=O)[R3])C(OC([R1])=O)COC([R1])=O		2.3.1.20	acyl-CoA + 1,2-diacylglycerol  =  triacylglycerol + coenzyme A	triacylglycerol biosynthesis
3-cyanopyridine		C6 H4 N2 	C(#N)C1(=CC=CN=C1)	NCI:17558*CAS:100-54-9	4.2.1.84	3-cyanopyridine + H2O  =  nicotinamide	aldoxime degradation
3-cyanopyridine		C6 H4 N2 	C(#N)C1(=CC=CN=C1)	NCI:17558*CAS:100-54-9	4.2.1.-	E-pyridine-3-aldoxime  =  3-cyanopyridine + H2O	aldoxime degradation
5-hydroxy-coniferaldehyde		C10 H10 O4 	C(=O)C=Cc1(cc(OC)c(O)c(c1)O)		2.1.1.68	5-hydroxy-coniferaldehyde + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + sinapaldehyde	lignin biosynthesis
5-hydroxy-coniferaldehyde		C10 H10 O4 	C(=O)C=Cc1(cc(OC)c(O)c(c1)O)		RXN-1142	coniferyl aldehyde + NADPH + O2  =  5-hydroxy-coniferaldehyde + NADP+ + H2O	lignin biosynthesis
apigenin	4',5,7-Trihydroxyflavone	C15 H10 O5 	c1(ccc(O)cc1)C2(Oc3(c(C(C=2)=O)c(O)cc(c3)O))	CAS:520-36-5	1.14.13.21	apigenin + NADPH + O2  =  luteolin + NADP+ + H2O	luteolin biosynthesis
apigenin	4',5,7-Trihydroxyflavone	C15 H10 O5 	c1(ccc(O)cc1)C2(Oc3(c(C(C=2)=O)c(O)cc(c3)O))	CAS:520-36-5	1.14.11.22	naringenin + alpha-ketoglutarate + O2  =  apigenin + succinate + CO2 + H2O	luteolin biosynthesis
apigenin	4',5,7-Trihydroxyflavone	C15 H10 O5 	c1(ccc(O)cc1)C2(Oc3(c(C(C=2)=O)c(O)cc(c3)O))	CAS:520-36-5	RXN-7650	naringenin + NADPH + O2  =  apigenin + NADP+ + 2 H2O	luteolin biosynthesis
a primary alcohol	1-Alcohol	H1 O1 R1 			1.1.1.2	NAD(P)H + a fatty aldehyde  =  NAD(P)+ + a primary alcohol	epicuticular wax biosynthesis
ubiquinone-8	ubiquinone(9)*coenzyme-Q<SUB>8</SUB>*Q-<i>9</i>	C49 H74 O4 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1(C(=O)C(OC)=C(OC)C(=O)C=1C)	LIGAND-CPD:C00399*CAS:1339-63-5	1.6.5.3	ubiquinol-8 + NAD+  =  ubiquinone-8 + NADH	NAD/NADH phosphorylation and dephosphorylation
beta-ketoacyl-CoA	&beta;-ketoacyl-CoA*RCOCH2CO-CoA*3-oxoacyl-CoA*3-ketoacyl-CoA*beta-ketoacyl-CoA	C24 H37 N7 O18 R1 P3 S1 			2.3.1.16	coenzyme A + beta-ketoacyl-CoA  =  acyl-CoA + acetyl-CoA	fatty acid beta-oxidation
beta-ketoacyl-CoA	&beta;-ketoacyl-CoA*RCOCH2CO-CoA*3-oxoacyl-CoA*3-ketoacyl-CoA*beta-ketoacyl-CoA	C24 H37 N7 O18 R1 P3 S1 			1.1.1.36	beta-ketoacyl-CoA + NADPH  =  3-hydroxyacyl-CoA + NADP+	very long chain fatty acid biosynthesis
beta-ketoacyl-CoA	&beta;-ketoacyl-CoA*RCOCH2CO-CoA*3-oxoacyl-CoA*3-ketoacyl-CoA*beta-ketoacyl-CoA	C24 H37 N7 O18 R1 P3 S1 			2.3.1.-	fatty-acyl-CoA + malonyl-CoA  =  beta-ketoacyl-CoA + CO2 + coenzyme A	very long chain fatty acid biosynthesis
beta-ketoacyl-CoA	&beta;-ketoacyl-CoA*RCOCH2CO-CoA*3-oxoacyl-CoA*3-ketoacyl-CoA*beta-ketoacyl-CoA	C24 H37 N7 O18 R1 P3 S1 			1.1.1.35	NAD+ + L-3-hydroxyacyl-CoA  =  NADH + beta-ketoacyl-CoA	fatty acid beta-oxidation
L-cysteinyl-tRNAcys	L-CYSTEINYL-TRNA(CYS)				6.1.1.16	tRNAcys + L-cysteine + ATP  =  L-cysteinyl-tRNAcys + pyrophosphate + AMP	tRNA charging pathway
tRNAphe	TRNA(PHE)				6.1.1.20	tRNAphe + L-phenylalanine + ATP  =  L-phenylalanyl-tRNAphe + pyrophosphate + AMP	tRNA charging pathway
citrulline	N<sup>&gamma;</sup>-carbamylornithine*&alpha;-amino-&gamma;-ureidovaleric acid*&gamma;ureidonorvaline*N<sup>5</sup>-(Aminocarbonyl)-L-ornithine*L-citrulline	C6 H13 N3 O3 	C(O)(=O)C(N)CCCNC(=O)N	LIGAND:C00327*CAS:372-75-8	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis
citrulline	N<sup>&gamma;</sup>-carbamylornithine*&alpha;-amino-&gamma;-ureidovaleric acid*&gamma;ureidonorvaline*N<sup>5</sup>-(Aminocarbonyl)-L-ornithine*L-citrulline	C6 H13 N3 O3 	C(O)(=O)C(N)CCCNC(=O)N	LIGAND:C00327*CAS:372-75-8	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis II (acetyl cycle)
citrulline	N<sup>&gamma;</sup>-carbamylornithine*&alpha;-amino-&gamma;-ureidovaleric acid*&gamma;ureidonorvaline*N<sup>5</sup>-(Aminocarbonyl)-L-ornithine*L-citrulline	C6 H13 N3 O3 	C(O)(=O)C(N)CCCNC(=O)N	LIGAND:C00327*CAS:372-75-8	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis III
citrulline	N<sup>&gamma;</sup>-carbamylornithine*&alpha;-amino-&gamma;-ureidovaleric acid*&gamma;ureidonorvaline*N<sup>5</sup>-(Aminocarbonyl)-L-ornithine*L-citrulline	C6 H13 N3 O3 	C(O)(=O)C(N)CCCNC(=O)N	LIGAND:C00327*CAS:372-75-8	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis
citrulline	N<sup>&gamma;</sup>-carbamylornithine*&alpha;-amino-&gamma;-ureidovaleric acid*&gamma;ureidonorvaline*N<sup>5</sup>-(Aminocarbonyl)-L-ornithine*L-citrulline	C6 H13 N3 O3 	C(O)(=O)C(N)CCCNC(=O)N	LIGAND:C00327*CAS:372-75-8	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis II (acetyl cycle)
citrulline	N<sup>&gamma;</sup>-carbamylornithine*&alpha;-amino-&gamma;-ureidovaleric acid*&gamma;ureidonorvaline*N<sup>5</sup>-(Aminocarbonyl)-L-ornithine*L-citrulline	C6 H13 N3 O3 	C(O)(=O)C(N)CCCNC(=O)N	LIGAND:C00327*CAS:372-75-8	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis III
citrulline	N<sup>&gamma;</sup>-carbamylornithine*&alpha;-amino-&gamma;-ureidovaleric acid*&gamma;ureidonorvaline*N<sup>5</sup>-(Aminocarbonyl)-L-ornithine*L-citrulline	C6 H13 N3 O3 	C(O)(=O)C(N)CCCNC(=O)N	LIGAND:C00327*CAS:372-75-8	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	citrulline degradation
fatty-acyl-CoA	fatty acyl CoA-*acyl-CoA	C22 H35 N7 O17 R1 P3 S1 			2.3.1.51	fatty-acyl-CoA + 1-acyl-sn-glycerol-3P  =  L-phosphatidate + coenzyme A	triacylglycerol biosynthesis
fatty-acyl-CoA	fatty acyl CoA-*acyl-CoA	C22 H35 N7 O17 R1 P3 S1 			2.3.1.15	fatty-acyl-CoA + glycerol-3-phosphate  =  1-acyl-sn-glycerol-3P + coenzyme A	triacylglycerol biosynthesis
fatty-acyl-CoA	fatty acyl CoA-*acyl-CoA	C22 H35 N7 O17 R1 P3 S1 			RXN-1026	fatty-acyl-CoA + malonyl-CoA  =  very-long-chain-fatty-acyl-CoA + CO2	epicuticular wax biosynthesis
fatty-acyl-CoA	fatty acyl CoA-*acyl-CoA	C22 H35 N7 O17 R1 P3 S1 			2.3.1.-	fatty-acyl-CoA + malonyl-CoA  =  beta-ketoacyl-CoA + CO2 + coenzyme A	very long chain fatty acid biosynthesis
fatty-acyl-CoA	fatty acyl CoA-*acyl-CoA	C22 H35 N7 O17 R1 P3 S1 			1.3.1.38	trans-delta2-enoyl-CoA + NADPH  =  acyln+2-CoA + NADP+	very long chain fatty acid biosynthesis
L-lysine	K*lysine*L-lys*lys*2,6-diaminohexanoic acid*lysine acid	C6 H14 N2 O2 	C(N)CCCC(N)C(O)=O	LIGAND-CPD:C00047*CAS:56-87-1	6.1.1.6	tRNAlys + L-lysine + ATP  =  L-lysyl-tRNAlys + pyrophosphate + AMP	tRNA charging pathway
L-lysine	K*lysine*L-lys*lys*2,6-diaminohexanoic acid*lysine acid	C6 H14 N2 O2 	C(N)CCCC(N)C(O)=O	LIGAND-CPD:C00047*CAS:56-87-1	4.1.1.18	L-lysine  =  CO2 + cadaverine	lysine degradation I
L-lysine	K*lysine*L-lys*lys*2,6-diaminohexanoic acid*lysine acid	C6 H14 N2 O2 	C(N)CCCC(N)C(O)=O	LIGAND-CPD:C00047*CAS:56-87-1	1.5.1.8	NADPH + alpha-ketoglutarate + L-lysine  =  H2O + NADP+ + saccharopine	lysine degradation II
L-lysine	K*lysine*L-lys*lys*2,6-diaminohexanoic acid*lysine acid	C6 H14 N2 O2 	C(N)CCCC(N)C(O)=O	LIGAND-CPD:C00047*CAS:56-87-1	4.1.1.20	meso-diaminopimelate  =  CO2 + L-lysine	lysine biosynthesis
indole-3-acetyl-ala	indole-3-acetyl-alanine	C13 H14 N2 O3 	C(O)(=O)C(C)NC(=O)Cc2(c[nH]c1(ccccc12))		3.5.1.-	indole-3-acetyl-ala + H2O  =  indole-3-acetate + L-alanine	IAA biosynthesis II
indole-3-acetyl-ala	indole-3-acetyl-alanine	C13 H14 N2 O3 	C(O)(=O)C(C)NC(=O)Cc2(c[nH]c1(ccccc12))		RXN-2944	indole-3-acetate + L-alanine  =  indole-3-acetyl-ala + H2O	IAA conjugate biosynthesis
N-feruloyltyramine		C18 H19 N1 O4 	C(Cc1(ccc(O)cc1))NC(=O)C=Cc2(cc(OC)c(O)cc2)		2.3.1.110	feruloyl-CoA + tyramine  =  N-feruloyltyramine + coenzyme A	suberin biosynthesis
naringenin	pelargidanon*salipurpol*naringetol*4;,5',7-trihydroxyflavanone*4',5,7-Trihydroxyflavanone*flavanone naringenin	C15 H12 O5 	c1(cc(ccc1O)[CH]2(Oc3(c(C(C2)=O)c(O)cc(c3)O)))	CAS:480-41-1	1.14.11.9	naringenin + O2 + alpha-ketoglutarate  =  CO2 + succinate + dihydrokaempferol	flavonoid biosynthesis
naringenin	pelargidanon*salipurpol*naringetol*4;,5',7-trihydroxyflavanone*4',5,7-Trihydroxyflavanone*flavanone naringenin	C15 H12 O5 	c1(cc(ccc1O)[CH]2(Oc3(c(C(C2)=O)c(O)cc(c3)O)))	CAS:480-41-1	1.14.11.22	naringenin + alpha-ketoglutarate + O2  =  apigenin + succinate + CO2 + H2O	luteolin biosynthesis
naringenin	pelargidanon*salipurpol*naringetol*4;,5',7-trihydroxyflavanone*4',5,7-Trihydroxyflavanone*flavanone naringenin	C15 H12 O5 	c1(cc(ccc1O)[CH]2(Oc3(c(C(C2)=O)c(O)cc(c3)O)))	CAS:480-41-1	1.14.13.21	naringenin + NADPH + O2  =  eriodictyol + NADP+ + H2O	luteolin biosynthesis
naringenin	pelargidanon*salipurpol*naringetol*4;,5',7-trihydroxyflavanone*4',5,7-Trihydroxyflavanone*flavanone naringenin	C15 H12 O5 	c1(cc(ccc1O)[CH]2(Oc3(c(C(C2)=O)c(O)cc(c3)O)))	CAS:480-41-1	RXN-7650	naringenin + NADPH + O2  =  apigenin + NADP+ + 2 H2O	luteolin biosynthesis
naringenin	pelargidanon*salipurpol*naringetol*4;,5',7-trihydroxyflavanone*4',5,7-Trihydroxyflavanone*flavanone naringenin	C15 H12 O5 	c1(cc(ccc1O)[CH]2(Oc3(c(C(C2)=O)c(O)cc(c3)O)))	CAS:480-41-1	5.5.1.6	naringenin chalcone  =  naringenin	flavonoid biosynthesis
4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate	4-amino-2-methyl-5-diphosphomethylpyrimidine*2-methyl-4-amino-5-hydroxymethylpyrimidine diphosphate*HMP-PP*4-amino-5-hydroxymethyl-2-methylpyrimidine-PP	C6 H11 N3 O7 P2 	c1(c(c(N)nc(C)n1)COP(O)(=O)OP(O)(=O)O)	CAS:841-01-0	2.5.1.3	4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate  =  thiamine-phosphate + pyrophosphate	thiamin biosynthesis
4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate	4-amino-2-methyl-5-diphosphomethylpyrimidine*2-methyl-4-amino-5-hydroxymethylpyrimidine diphosphate*HMP-PP*4-amino-5-hydroxymethyl-2-methylpyrimidine-PP	C6 H11 N3 O7 P2 	c1(c(c(N)nc(C)n1)COP(O)(=O)OP(O)(=O)O)	CAS:841-01-0	2.7.4.7	hydroxymethylpyrimidine phosphate + ATP  =  4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate + ADP	thiamin biosynthesis
L-methylmalonyl-CoA	(R)-methylmalonyl-CoA*methylmalonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.4.99.2	L-methylmalonyl-CoA  =  succinyl-CoA	isoleucine degradation
L-methylmalonyl-CoA	(R)-methylmalonyl-CoA*methylmalonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.4.99.2	L-methylmalonyl-CoA  =  succinyl-CoA	valine degradation
L-methylmalonyl-CoA	(R)-methylmalonyl-CoA*methylmalonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.4.99.2	L-methylmalonyl-CoA  =  succinyl-CoA	methionine degradation I
L-methylmalonyl-CoA	(R)-methylmalonyl-CoA*methylmalonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.1.99.1	D-methylmalonyl-CoA  =  L-methylmalonyl-CoA	isoleucine degradation
L-methylmalonyl-CoA	(R)-methylmalonyl-CoA*methylmalonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.1.99.1	D-methylmalonyl-CoA  =  L-methylmalonyl-CoA	valine degradation
L-methylmalonyl-CoA	(R)-methylmalonyl-CoA*methylmalonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.1.99.1	D-methylmalonyl-CoA  =  L-methylmalonyl-CoA	methionine degradation I
5-methylthioribose-1-phosphate	S5-methyl-5-thio-D-ribose-1-phosphate*5-methylthio-5-deoxy-D-ribose-1-phosphate*5-methylthio-D-ribose-1-phosphate*5-MTR-1-P*1-phosphomethylthioribose*1-phospho-5-S-methylthioribose*1-PMTR*1-phospho-5-S-methylthio-&alpha;-D-ribofuranoside	C6 H13 O7 P1 S1 	C1(OC(CSC)C(O)C(O)1)(OP(O)(=O)O)		5.3.1.23	5-methylthioribose-1-phosphate  =  5-methylthioribulose-1-phosphate	methionine salvage pathway
5-methylthioribose-1-phosphate	S5-methyl-5-thio-D-ribose-1-phosphate*5-methylthio-5-deoxy-D-ribose-1-phosphate*5-methylthio-D-ribose-1-phosphate*5-MTR-1-P*1-phosphomethylthioribose*1-phospho-5-S-methylthioribose*1-PMTR*1-phospho-5-S-methylthio-&alpha;-D-ribofuranoside	C6 H13 O7 P1 S1 	C1(OC(CSC)C(O)C(O)1)(OP(O)(=O)O)		2.7.1.100	5-methylthioribose + ATP  =  5-methylthioribose-1-phosphate + ADP	methionine salvage pathway
propionyl-CoA	propanoyl-CoA*propionyl-coenzyme A	C24 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC)	CAS:317-66-8	PROPIONYL-COA-CARBOXYLASE-RXN	propionyl-CoA + H2O + ATP + CO2  =  D-methylmalonyl-CoA + phosphate + ADP	methionine degradation I
propionyl-CoA	propanoyl-CoA*propionyl-coenzyme A	C24 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC)	CAS:317-66-8	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	isoleucine degradation
propionyl-CoA	propanoyl-CoA*propionyl-coenzyme A	C24 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC)	CAS:317-66-8	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	valine degradation
propionyl-CoA	propanoyl-CoA*propionyl-coenzyme A	C24 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC)	CAS:317-66-8	6.2.1.17	coenzyme A + propionate + ATP  =  propionyl-CoA + pyrophosphate + AMP	beta-alanine biosynthesis II
propionyl-CoA	propanoyl-CoA*propionyl-coenzyme A	C24 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC)	CAS:317-66-8	1.3.99.3	FAD + propionyl-CoA  =  FADH2 + acrylyl-CoA	beta-alanine biosynthesis II
propionyl-CoA	propanoyl-CoA*propionyl-coenzyme A	C24 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC)	CAS:317-66-8	1.2.1.27	NAD+ + coenzyme A + methylmalonate-semialdehyde  =  NADH + CO2 + propionyl-CoA	valine degradation
propionyl-CoA	propanoyl-CoA*propionyl-coenzyme A	C24 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC)	CAS:317-66-8	ALPHA-KETOBUTYRATE-DEHYDROG-RXN	2-oxobutanoate + coenzyme A + NAD+  =  propionyl-CoA + CO2 + NADH	methionine degradation I
propionyl-CoA	propanoyl-CoA*propionyl-coenzyme A	C24 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC)	CAS:317-66-8	2.3.1.16	2-methylaceto-acetyl-CoA + coenzyme A  =  propionyl-CoA + acetyl-CoA	isoleucine degradation
oxocinnamoyl-CoA		C30 H42 N7 O18 P3 S1 	CC(C(O)C(=O)NCCC(=O)NCCSC(=O)CC(=O)c1(ccccc1))(C)COP(O)(=O)OP(O)(=O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(=O)O)n3(c4(c(nc3)c(N)ncn4)))		RXN-2006	oxocinnamoyl-CoA + coenzyme A  =  benzoyl-CoA + acetyl-CoA	salicylic acid biosynthesis
oxocinnamoyl-CoA		C30 H42 N7 O18 P3 S1 	CC(C(O)C(=O)NCCC(=O)NCCSC(=O)CC(=O)c1(ccccc1))(C)COP(O)(=O)OP(O)(=O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(=O)O)n3(c4(c(nc3)c(N)ncn4)))		RXN-2003	hydroxycinnamoyl-CoA + NADP+  =  oxocinnamoyl-CoA + NADPH	salicylic acid biosynthesis
3-phospho-serine	O-phospho-L-serine*serine phosphate*phosphorylserine*seryl phosphate*3-P-serine*serine-3-p*serine-3-phosphate*phosphoserine*P-serine*3-phospho-1-serine*P-ser*3-phosphoserine	C3 H8 N1 O6 P1 	C(C(N)C(O)=O)OP(O)(=O)O	CAS:17885-08-4	3.1.3.3	3-phospho-serine + H2O  =  L-serine + phosphate	serine biosynthesis
3-phospho-serine	O-phospho-L-serine*serine phosphate*phosphorylserine*seryl phosphate*3-P-serine*serine-3-p*serine-3-phosphate*phosphoserine*P-serine*3-phospho-1-serine*P-ser*3-phosphoserine	C3 H8 N1 O6 P1 	C(C(N)C(O)=O)OP(O)(=O)O	CAS:17885-08-4	3.1.3.3	3-phospho-serine + H2O  =  L-serine + phosphate	glycine biosynthesis
3-phospho-serine	O-phospho-L-serine*serine phosphate*phosphorylserine*seryl phosphate*3-P-serine*serine-3-p*serine-3-phosphate*phosphoserine*P-serine*3-phospho-1-serine*P-ser*3-phosphoserine	C3 H8 N1 O6 P1 	C(C(N)C(O)=O)OP(O)(=O)O	CAS:17885-08-4	2.6.1.52	3-phospho-hydroxypyruvate + L-glutamate  =  3-phospho-serine + alpha-ketoglutarate	serine biosynthesis
malonyl-ACP	B1094*AcpP*malonyl-[acyl-carrier protein]*malonyl-S-ACP*malonyl-acyl-carrier-protein	C3 H2 O3 ACP1 S1 		SWISSPROT:P02901	3-OXOACYL-ACP-COA-SYNTHIII-RXN	acetyl-CoA + malonyl-ACP  =  acetoacetyl-ACP + coenzyme A + CO2	fatty acid biosynthesis - initial steps
malonyl-ACP	B1094*AcpP*malonyl-[acyl-carrier protein]*malonyl-S-ACP*malonyl-acyl-carrier-protein	C3 H2 O3 ACP1 S1 		SWISSPROT:P02901	2.3.1.41	acyl-ACP + malonyl-ACP  =  acyl carrier protein + beta-ketoacyl-ACP + CO2	fatty acid elongation -- saturated
malonyl-ACP	B1094*AcpP*malonyl-[acyl-carrier protein]*malonyl-S-ACP*malonyl-acyl-carrier-protein	C3 H2 O3 ACP1 S1 		SWISSPROT:P02901	2.3.1.39	acyl carrier protein + malonyl-CoA  =  malonyl-ACP + coenzyme A	fatty acid biosynthesis - initial steps
glycerol	1,2,3-trihydroxypropane*glycerin*1,2,3-trihydroxypropanol	C3 H8 O3 	C(O)C(O)CO	LIGAND:C00116*CAS:56-81-5	2.7.1.30	glycerol + ATP  =  glycerol-3-phosphate + ADP	glycerol degradation
glycerol	1,2,3-trihydroxypropane*glycerin*1,2,3-trihydroxypropanol	C3 H8 O3 	C(O)C(O)CO	LIGAND:C00116*CAS:56-81-5	3.1.1.23	H2O + acylglycerol  =  a fatty acid + glycerol	triacylglycerol degradation
imidazole acetol-phosphate	imidazole acetol-P*3-(imidazol-4-yl)-2-oxopropyl phosphate	C6 H9 N2 O5 P1 	c1(c(nc[nH]1)CC(=O)COP(=O)(O)O)	CAS:99979-59-6	2.6.1.9	imidazole acetol-phosphate + L-glutamate  =  L-histidinol-phosphate + alpha-ketoglutarate	histidine biosynthesis
imidazole acetol-phosphate	imidazole acetol-P*3-(imidazol-4-yl)-2-oxopropyl phosphate	C6 H9 N2 O5 P1 	c1(c(nc[nH]1)CC(=O)COP(=O)(O)O)	CAS:99979-59-6	4.2.1.19	D-erythro-imidazole-glycerol-phosphate  =  imidazole acetol-phosphate + H2O	histidine biosynthesis
palmitate	palmitic acid*hexadecanoate	C16 H32 O2 	C(=O)(O)CCCCCCCCCCCCCCC	CAS:57-10-3	1.14.13.-	palmitate + NADPH + O2  =  16-hydroxypalmitate + NADP+ + H2O	cutin biosynthesis
L-fucose	fucose*6-deoxy-L-galactose*L-galactomethylose	C6 H12 O5 	C1(C(O)C(O)C(O)C(C)O1)(O)	LIGAND:C01019*CAS:6696-41-9	2.7.1.52	L-fucose + ATP  =  beta-L-fucose 1-phosphate + ADP	GDP-L-fucose biosynthesis II (from L-fucose)
succinyl-CoA	suc-coa*succ-coenzyme-A*succ-S-coenzyme-A*succinyl-S-coenzyme-A*succ-S-CoA*succinylcoenzyme-A*succ-CoA*suc-co-A*succinyl-S-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)	CAS:604-98-8	2.3.1.117	H2O + L-2,3,4,5-tetrahydrodipicolinate + succinyl-CoA  =  N-succinyl-2-amino-6-ketopimelate + coenzyme A	lysine biosynthesis
succinyl-CoA	suc-coa*succ-coenzyme-A*succ-S-coenzyme-A*succinyl-S-coenzyme-A*succ-S-CoA*succinylcoenzyme-A*succ-CoA*suc-co-A*succinyl-S-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)	CAS:604-98-8	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle variation I
succinyl-CoA	suc-coa*succ-coenzyme-A*succ-S-coenzyme-A*succinyl-S-coenzyme-A*succ-S-CoA*succinylcoenzyme-A*succ-CoA*suc-co-A*succinyl-S-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)	CAS:604-98-8	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle -- aerobic respiration
succinyl-CoA	suc-coa*succ-coenzyme-A*succ-S-coenzyme-A*succinyl-S-coenzyme-A*succ-S-CoA*succinylcoenzyme-A*succ-CoA*suc-co-A*succinyl-S-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)	CAS:604-98-8	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle variation I
succinyl-CoA	suc-coa*succ-coenzyme-A*succ-S-coenzyme-A*succinyl-S-coenzyme-A*succ-S-CoA*succinylcoenzyme-A*succ-CoA*suc-co-A*succinyl-S-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)	CAS:604-98-8	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle -- aerobic respiration
succinyl-CoA	suc-coa*succ-coenzyme-A*succ-S-coenzyme-A*succinyl-S-coenzyme-A*succ-S-CoA*succinylcoenzyme-A*succ-CoA*suc-co-A*succinyl-S-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)	CAS:604-98-8	5.4.99.2	L-methylmalonyl-CoA  =  succinyl-CoA	isoleucine degradation
succinyl-CoA	suc-coa*succ-coenzyme-A*succ-S-coenzyme-A*succinyl-S-coenzyme-A*succ-S-CoA*succinylcoenzyme-A*succ-CoA*suc-co-A*succinyl-S-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)	CAS:604-98-8	5.4.99.2	L-methylmalonyl-CoA  =  succinyl-CoA	valine degradation
succinyl-CoA	suc-coa*succ-coenzyme-A*succ-S-coenzyme-A*succinyl-S-coenzyme-A*succ-S-CoA*succinylcoenzyme-A*succ-CoA*suc-co-A*succinyl-S-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC(O)=O)	CAS:604-98-8	5.4.99.2	L-methylmalonyl-CoA  =  succinyl-CoA	methionine degradation I
D-myo-inositol (1,3,4)-trisphosphate	Ins(1,3,4)P<sub>3</sub>*1-D-<i>myo</i>-inositol (1,3,4)-trisphosphate*inositol 1,3,4-trisphosphate	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.133	D-myo-inositol (1,3,4)-trisphosphate + ATP  =  D-myo-inositol (1,3,4,6)-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
D-myo-inositol (1,3,4)-trisphosphate	Ins(1,3,4)P<sub>3</sub>*1-D-<i>myo</i>-inositol (1,3,4)-trisphosphate*inositol 1,3,4-trisphosphate	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.139	D-myo-inositol (1,3,4)-trisphosphate + ATP  =  1D-myo-inositol 1,3,4,5-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
mono-beta-D-galactosyldiacylglycerol	D-GALACTOSYLDIACYLGLYCEROL*monogalactosyl-diacylgycerol*3-&beta;-D-galactosyl-1,2-diacylglycerol*diasylglycerol*monogalactosyldiglyceride*monogalactosyl-diacylglycerol*MGDG*Gal&beta;1->3acyl2Gro	C11 H16 O10 R2 			RXN-1225	mono-beta-D-galactosyldiacylglycerol + UDP-galactose  =  alpha-D-galactosyl-beta-D-galactosyldiacylglycerol + UDP	glycolipid biosynthesis
mono-beta-D-galactosyldiacylglycerol	D-GALACTOSYLDIACYLGLYCEROL*monogalactosyl-diacylgycerol*3-&beta;-D-galactosyl-1,2-diacylglycerol*diasylglycerol*monogalactosyldiglyceride*monogalactosyl-diacylglycerol*MGDG*Gal&beta;1->3acyl2Gro	C11 H16 O10 R2 			2.4.1.184	2 mono-beta-D-galactosyldiacylglycerol  =  alpha-D-galactosyl-beta-D-galactosyldiacylglycerol + 1,2-diacylglycerol	glycolipid biosynthesis
mono-beta-D-galactosyldiacylglycerol	D-GALACTOSYLDIACYLGLYCEROL*monogalactosyl-diacylgycerol*3-&beta;-D-galactosyl-1,2-diacylglycerol*diasylglycerol*monogalactosyldiglyceride*monogalactosyl-diacylglycerol*MGDG*Gal&beta;1->3acyl2Gro	C11 H16 O10 R2 			2.4.1.46	1,2-diacylglycerol + UDP-galactose  =  mono-beta-D-galactosyldiacylglycerol + UDP	glycolipid biosynthesis
5-hydroxy-ferulic-acid	5-hydroxy ferulate	C10 H10 O5 	C(O)(=O)C=Cc1(cc(OC)c(O)c(O)c1)		2.1.1.68	5-hydroxy-ferulic-acid + S-adenosyl-L-methionine  =  sinapate + S-adenosyl-homocysteine	phenylpropanoid biosynthesis
5-hydroxy-ferulic-acid	5-hydroxy ferulate	C10 H10 O5 	C(O)(=O)C=Cc1(cc(OC)c(O)c(O)c1)		RXN-1121	ferulate + NADPH + O2  =  5-hydroxy-ferulic-acid + H2O + NADP+	phenylpropanoid biosynthesis
S-aminomethyldihydrolipoyl-GcvH-protein	B2904*Gcv*GcvH*S-aminomethyl-dihydrolipoylprotein*S-aminomethyldihydrolipoyl-GcvH				2.1.2.10	S-aminomethyldihydrolipoyl-GcvH-protein + tetrahydrofolate  =  NH3 + dihydrolipoyl-GcvH-protein + 5,10-methylene-THF	glycine degradation
S-aminomethyldihydrolipoyl-GcvH-protein	B2904*Gcv*GcvH*S-aminomethyl-dihydrolipoylprotein*S-aminomethyldihydrolipoyl-GcvH				1.4.4.2	H-protein-(lipoyl)lysine + glycine  =  CO2 + S-aminomethyldihydrolipoyl-GcvH-protein	glycine degradation
6-carboxyhexanoyl-CoA	6-carboxyhexanoyl-CoA*pimeloyl-CoA	C28 H46 N7 O19 P3 S1 	C(O)(=O)CCCCCC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(O)(=O)OCC1(OC(C(O)C1OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C01063	2.3.1.47	L-alanine + 6-carboxyhexanoyl-CoA  =  CO2 + coenzyme A + 8-amino-7-oxononanoate	biotin biosynthesis II
indole-3-glycerol-phosphate	indole-3-glycerol-P*1-(indol-3-yl)glycerol-3-P*1-(indol-3-yl)glycerol-3-phosphate*indoleglycerol phosphate	C11 H14 N1 O6 P1 	C(OP(=O)(O)O)C(O)C(O)c1(c2(c([nH]c1)cccc2))		RXN0-2381	indole-3-glycerol-phosphate  =  indole + D-glyceraldehyde-3-phosphate	tryptophan biosynthesis
indole-3-glycerol-phosphate	indole-3-glycerol-P*1-(indol-3-yl)glycerol-3-P*1-(indol-3-yl)glycerol-3-phosphate*indoleglycerol phosphate	C11 H14 N1 O6 P1 	C(OP(=O)(O)O)C(O)C(O)c1(c2(c([nH]c1)cccc2))		RXN-1407	indole-3-glycerol-phosphate  =  indole + glycerol-3-phosphate	IAA biosynthesis I
indole-3-glycerol-phosphate	indole-3-glycerol-P*1-(indol-3-yl)glycerol-3-P*1-(indol-3-yl)glycerol-3-phosphate*indoleglycerol phosphate	C11 H14 N1 O6 P1 	C(OP(=O)(O)O)C(O)C(O)c1(c2(c([nH]c1)cccc2))		4.1.1.48	1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-phosphate  =  indole-3-glycerol-phosphate + CO2 + H2O	tryptophan biosynthesis
beta-D-glucose	&beta;-glucose*&beta;-D-glucopyranose*glucose*dextrose*glc*glc-ring*D-glucose-ring*D-glucose*glucoside*beta-D-glucopyranose*beta-glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00031*CAS:50-99-7	3.2.1.126	H2O + coniferin  =  coniferyl alcohol + beta-D-glucose	coniferin metabolism
beta-D-glucose	&beta;-glucose*&beta;-D-glucopyranose*glucose*dextrose*glc*glc-ring*D-glucose-ring*D-glucose*glucoside*beta-D-glucopyranose*beta-glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00031*CAS:50-99-7	2.3.1.91	1-O-sinapoyl-beta-D-glucose + choline  =  O-sinapoylcholine + beta-D-glucose	sinapate ester biosynthesis
beta-D-glucose	&beta;-glucose*&beta;-D-glucopyranose*glucose*dextrose*glc*glc-ring*D-glucose-ring*D-glucose*glucoside*beta-D-glucopyranose*beta-glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00031*CAS:50-99-7	2.3.1.92	1-O-sinapoyl-beta-D-glucose + malate  =  sinapoyl-(S)-malate + beta-D-glucose	sinapate ester biosynthesis
beta-D-glucose	&beta;-glucose*&beta;-D-glucopyranose*glucose*dextrose*glc*glc-ring*D-glucose-ring*D-glucose*glucoside*beta-D-glucopyranose*beta-glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00031*CAS:50-99-7	2.3.1.103	2 1-O-sinapoyl-beta-D-glucose  =  1,2-bis-O-sinapoyl-beta-D-glucoside + beta-D-glucose	sinapate ester biosynthesis
beta-D-glucose	&beta;-glucose*&beta;-D-glucopyranose*glucose*dextrose*glc*glc-ring*D-glucose-ring*D-glucose*glucoside*beta-D-glucopyranose*beta-glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00031*CAS:50-99-7	2.4.1.25	Short-glucans + Short-glucans  =  Long-linear-glucans + beta-D-glucose	starch degradation
beta-D-glucose	&beta;-glucose*&beta;-D-glucopyranose*glucose*dextrose*glc*glc-ring*D-glucose-ring*D-glucose*glucoside*beta-D-glucopyranose*beta-glucose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00031*CAS:50-99-7	RXN-1444	indolylmethyl-glucosinolate + H2O  =  indolylmethyl glucosinolate aglycone + beta-D-glucose	glucosinolate biosynthesis from tryptophan
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	3.5.3.11	H2O + agmatine  =  urea + putrescine	spermine biosynthesis I
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	3.5.3.11	H2O + agmatine  =  urea + putrescine	polyamine biosynthesis II
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	3.5.3.11	H2O + agmatine  =  urea + putrescine	polyamine biosynthesis I
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	3.5.3.12	H2O + agmatine  =  NH3 + N-carbamoylputrescine	polyamine biosynthesis III
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	3.5.3.12	H2O + agmatine  =  NH3 + N-carbamoylputrescine	arginine degradation I
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis III
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	4.1.1.19	L-arginine  =  CO2 + agmatine	arginine degradation I
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	4.1.1.19	L-arginine  =  CO2 + agmatine	spermine biosynthesis I
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis II
agmatine		C5 H14 N4 	C(NC(N)=N)CCCN	CAS:306-60-5	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis I
L-gamma-glutamylcysteine	&gamma;-glutamylcysteine*&gamma;-L-glutamyl-L-cysteine	C8 H14 N2 O5 S1 	C(O)(=O)C(N)CCC(=O)NC(CS)C(O)=O	CAS:686-58-8	6.3.2.3	glycine + L-gamma-glutamylcysteine + ATP  =  glutathione + phosphate + ADP	glutathione biosynthesis
L-gamma-glutamylcysteine	&gamma;-glutamylcysteine*&gamma;-L-glutamyl-L-cysteine	C8 H14 N2 O5 S1 	C(O)(=O)C(N)CCC(=O)NC(CS)C(O)=O	CAS:686-58-8	6.3.2.2	L-cysteine + L-glutamate + ATP  =  L-gamma-glutamylcysteine + phosphate + ADP	glutathione biosynthesis
divinyl protochlorophyllide a	divinylprotochlorophyllide*divinyl protochlrophyllide a	C35 H32 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)C=C)5))=Cc7(n6c(c(c7C)CCC(=O)O)=C8[CH](C(=O)9)C(=O)OC)))))))		1.3.1.75	divinyl protochlorophyllide a + NADPH  =  monovinyl protochlorophyllide a + NADP+	chlorophyllide a biosynthesis
divinyl protochlorophyllide a	divinylprotochlorophyllide*divinyl protochlrophyllide a	C35 H32 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)C=C)5))=Cc7(n6c(c(c7C)CCC(=O)O)=C8[CH](C(=O)9)C(=O)OC)))))))		1.14.13.81	131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  divinyl protochlorophyllide a + NADP+ + 2 H2O	chlorophyllide a biosynthesis
THF polyglutamate	THF(glu)<sub>n</sub>*H<sub>4</sub>PteGlu<sub>n</sub>*tetrahydropteroylpolyglutamate*THF	C7 H11 N6 O1 R1 			6.3.4.3	10-formyl-H4PteGlun + ADP + phosphate  =  THF polyglutamate + ATP + formate	tetrahydrofolate biosynthesis I
THF polyglutamate	THF(glu)<sub>n</sub>*H<sub>4</sub>PteGlu<sub>n</sub>*tetrahydropteroylpolyglutamate*THF	C7 H11 N6 O1 R1 			6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	formylTHF biosynthesis I
THF polyglutamate	THF(glu)<sub>n</sub>*H<sub>4</sub>PteGlu<sub>n</sub>*tetrahydropteroylpolyglutamate*THF	C7 H11 N6 O1 R1 			6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis I
THF polyglutamate	THF(glu)<sub>n</sub>*H<sub>4</sub>PteGlu<sub>n</sub>*tetrahydropteroylpolyglutamate*THF	C7 H11 N6 O1 R1 			6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis II
dTDP	TDP*thymidine 5'-(trihydrogen diphosphate) (9CI)*deoxy-TDP*thymidine-5'-diphosphate*thymidine-diphosphate	C10 H16 N2 O11 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(O)(O)=O))	CAS:491-97-4	2.7.4.6	dTDP + ATP  =  dTTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dTDP	TDP*thymidine 5'-(trihydrogen diphosphate) (9CI)*deoxy-TDP*thymidine-5'-diphosphate*thymidine-diphosphate	C10 H16 N2 O11 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(O)(O)=O))	CAS:491-97-4	RXN1F-443	kaempferol-3-glucoside + dTDP-alpha-L-rhamnose  =  kaempferol-3-glucoside-7-rhamnoside + dTDP	flavonol biosynthesis
dTDP	TDP*thymidine 5'-(trihydrogen diphosphate) (9CI)*deoxy-TDP*thymidine-5'-diphosphate*thymidine-diphosphate	C10 H16 N2 O11 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(O)(O)=O))	CAS:491-97-4	RXN1F-474	kaempferol + dTDP-alpha-L-rhamnose  =  kaempferol-3-rhamnoside + dTDP	flavonol biosynthesis
dTDP	TDP*thymidine 5'-(trihydrogen diphosphate) (9CI)*deoxy-TDP*thymidine-5'-diphosphate*thymidine-diphosphate	C10 H16 N2 O11 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(O)(O)=O))	CAS:491-97-4	RXN1F-475	kaempferol-3-rhamnoside + dTDP-alpha-L-rhamnose  =  kaempferol-3-rhamnoside-7-rhamnoside + dTDP	flavonol biosynthesis
dTDP	TDP*thymidine 5'-(trihydrogen diphosphate) (9CI)*deoxy-TDP*thymidine-5'-diphosphate*thymidine-diphosphate	C10 H16 N2 O11 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(O)(O)=O))	CAS:491-97-4	2.7.4.9	dTMP + ATP  =  dTDP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	formylTHF biosynthesis
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	formylTHF biosynthesis I
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	de novo biosynthesis of pyrimidine deoxyribonucleotides
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis I
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis I
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis II
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	formylTHF biosynthesis
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	formylTHF biosynthesis I
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	tetrahydrofolate biosynthesis I
7,8-dihydrofolate	H2PteGlu*FH2*H<sub>2</sub>PteGlu<sub>1</sub>*dihydrofolate*DHF	C19 H21 N7 O6 	C(C1(=Nc2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:4033-27-6	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	tetrahydrofolate biosynthesis II
5-amino-6-(5'-phosphoribosylamino)uracil	5-amino-6-(ribosylamino)-2,4-(1H,3H)-pyrimidinedione 5'-phosphate	C9 H15 N4 O9 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)Nc2(c(N)c(=O)[nH]c([nH]2)=O))	LIGAND-CPD:C01268	1.1.1.193	5-amino-6-(5'-phosphoribosylamino)uracil + NADPH  =  5-amino-6-(5'-phosphoribitylamino)uracil + NADP+	riboflavin and FMN and FAD biosynthesis
5-amino-6-(5'-phosphoribosylamino)uracil	5-amino-6-(ribosylamino)-2,4-(1H,3H)-pyrimidinedione 5'-phosphate	C9 H15 N4 O9 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)Nc2(c(N)c(=O)[nH]c([nH]2)=O))	LIGAND-CPD:C01268	3.5.4.26	H2O + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate  =  5-amino-6-(5'-phosphoribosylamino)uracil + NH3	riboflavin and FMN and FAD biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.7	PRPP + adenine  =  AMP + pyrophosphate	salvage pathways of purine nucleosides
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.17	ATP + PRPP  =  phosphoribosyl-ATP + pyrophosphate	histidine biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.10	PRPP + orotate  =  orotidine-5'-phosphate + pyrophosphate	de novo biosynthesis of pyrimidine ribonucleotides
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis II (from tryptophan)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis I (from aspartate)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.1.90	D-fructose-6-phosphate + pyrophosphate  =  phosphate + fructose-1,6-bisphosphate	glycolysis I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	3.6.1.1	H2O + pyrophosphate  =  2 phosphate	UDP-glucose conversion
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.8	PRPP + hypoxanthine  =  pyrophosphate + IMP	salvage pathways of purine nucleosides
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.-	chlorophyllide b + phytyl pyrophosphate  =  chlorophyll b + pyrophosphate	chlorophyll cycle
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.-	chlorophyllide a + geranylgeranyl-PP  =  geranylgeranyl-chlorophyll a + pyrophosphate	chlorophyll a biosynthesis II
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-7568	1,4-dihydroxy-2-naphthoate + phytyl pyrophosphate  =  demethylphylloquinone + CO2 + pyrophosphate	phylloquinone biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  4-(2'-carboxyphenyl)-4-oxobutyryl-CoA + AMP + pyrophosphate	phylloquinone biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.30	beta-L-fucose 1-phosphate + GTP  =  guanosine diphosphate fucose + pyrophosphate	GDP-L-fucose biosynthesis II (from L-fucose)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-7401	beta-L-arabinose 1-phosphate + UTP  =  UDP-L-arabinose + pyrophosphate	UDP-L-arabinose biosynthesis II (from L-arabinose)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.44	alpha-D-glucuronate 1-phosphate + UTP  =  UDP-D-glucuronate + pyrophosphate	inositol oxidation pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-3	alpha-D-galacturonate 1-phosphate + UTP  =  UDP-D-galacturonate + pyrophosphate	UDP-D-galacturonate biosynthesis II (from D-galacturonate)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.2.1.17	coenzyme A + propionate + ATP  =  propionyl-CoA + pyrophosphate + AMP	beta-alanine biosynthesis II
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.8	a tRNA + dimethylallyl-pyrophosphate  =  prenyl-tRNA + pyrophosphate	cis-zeatin biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	4.2.3.14	geranyl-PP  =  (-)-(1S,5S)-alpha-pinene + pyrophosphate	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	4.2.3.15	geranyl-PP  =  myrcene + pyrophosphate + myrcene	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-5109	geranyl-PP  =  (E)-beta-ocimene + pyrophosphate	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	4.2.3.16	geranyl-PP  =  limonene + pyrophosphate	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-5108	geranyl-PP  =  terpinolene + pyrophosphate	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	4.2.3.14	geranyl-PP  =  (-)-(1S,5S)-beta-pinene + pyrophosphate	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-5103	geranyl-PP  =  (-)-(1S)-sabinene + pyrophosphate	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-5101	geranyl-PP + H2O  =  (-)-(4S)-alpha-terpineol + pyrophosphate	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-5123	geranyl-PP  =  (Z)-beta-ocimene + pyrophosphate	monoterpene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.-	dimethylallyl-pyrophosphate + ATP  =  isopentenyladenosine-5'-triphosphate + pyrophosphate	trans-zeatin biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.-	dimethylallyl-pyrophosphate + ADP  =  isopentenyladenosine-5'-diphosphate + pyrophosphate	trans-zeatin biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.27	dimethylallyl-pyrophosphate + AMP  =  isopentenyladenosine-5'-monophosphate + pyrophosphate	trans-zeatin biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.21	presqualene diphosphate + NAD(P)H  =  squalene + NAD(P)+ + pyrophosphate	sterol biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-2761	homogentisate + solanyl pyrophosphate  =  2-methyl-6-solanyl-1,4-benzoquinone + CO2 + pyrophosphate	plastoquinone biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.5.4	H2O + L-glutamine + L-aspartate + ATP  =  L-glutamate + L-asparagine + pyrophosphate + AMP	asparagine biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.3	pantetheine 4'-phosphate + ATP  =  dephospho-CoA + pyrophosphate	coenzyme A biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.2.5	D-4'-phosphopantothenate + L-cysteine + CTP  =  R-4'-phosphopantothenoyl-L-cysteine + pyrophosphate + CMP	coenzyme A biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	3.1.7.2	guanosine 5'-diphosphate,3'-diphosphate + H2O  =  pyrophosphate + GDP	ppGpp biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.3	4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate  =  thiamine-phosphate + pyrophosphate	thiamin biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN0-277	2-C-methyl-D-erythritol-4-phosphate + CTP  =  4-diphosphocytidyl-2-C-methylerythritol + pyrophosphate	isopentenyl diphosphate biosynthesis -- mevalonate-independent
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.2.1.3	coenzyme A + a fatty acid + ATP  =  acyl-CoA + pyrophosphate + AMP	fatty acid beta-oxidation
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.2.1.12	ferulate + coenzyme A + ATP  =  feruloyl-CoA + AMP + pyrophosphate	suberin biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.2.1.12	caffeate + coenzyme A + ATP  =  caffeoyl-CoA + AMP + pyrophosphate	suberin biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	UPPSYN-RXN	cis,trans-polyisoprenyln-PP + delta3-isopentenyl-PP  =  pyrophosphate + cis,trans-polyisoprenyln+1-PP	polyisoprenoid biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.-	trans-polyisoprenyln-PP + delta3-isopentenyl-PP  =  trans-polyisoprenyln+1-PP + pyrophosphate	polyisoprenoid biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.1	dimethylallyl-pyrophosphate + delta3-isopentenyl-PP  =  pyrophosphate + geranyl-PP	polyisoprenoid biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.1	dimethylallyl-pyrophosphate + delta3-isopentenyl-PP  =  pyrophosphate + geranyl-PP	mevalonate pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.13	mannose-1-phosphate + GTP  =  GDP-mannose + pyrophosphate	ascorbate biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	DMK-RXN	1,4-dihydroxy-2-naphthoate + octaprenyl diphosphate  =  demethylmenaquinone-8 + pyrophosphate + CO2	menaquinone biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  AMP + pyrophosphate + O-succinylbenzoyl-CoA	menaquinone biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	3.6.1.-	dihydroneopterin triphosphate + H2O  =  dihydroneopterin phosphate + pyrophosphate	tetrahydrofolate biosynthesis I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	3.6.1.-	dihydroneopterin triphosphate + H2O  =  dihydroneopterin phosphate + pyrophosphate	tetrahydrofolate biosynthesis II
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	salvage pathways of purine nucleosides
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	de novo biosynthesis of purine nucleotides I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	NAD biosynthesis II (from tryptophan)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	NAD biosynthesis I (from aspartate)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	pyridine nucleotide cycling
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	NAD biosynthesis I (from aspartate)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	pyridine nucleotide cycling
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.2	FMN + ATP  =  FAD + pyrophosphate	riboflavin and FMN and FAD biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.32	2 geranylgeranyl-PP  =  phytoene + 2 pyrophosphate	carotenoid biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.10	alpha-D-galactose-1-phosphate + UTP  =  UDP-galactose + pyrophosphate	galactose degradation I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	chlorophyllide a biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	biosynthesis of proto- and siroheme
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.2.1	beta-alanine + L-pantoate + ATP  =  pantothenate + pyrophosphate + AMP	pantothenate biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.21	2 trans, trans-farnesyl diphosphate  =  presqualene diphosphate + pyrophosphate	sterol biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis II (acetyl cycle)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis III
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.-	protoheme + trans, trans-farnesyl diphosphate + H2O  =  heme O + pyrophosphate	biosynthesis of proto- and siroheme
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.12	tRNAasp + L-aspartate + ATP  =  L-aspartyl-tRNAasp + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	3.6.1.23	H2O + dUTP  =  pyrophosphate + dUMP	de novo biosynthesis of pyrimidine deoxyribonucleotides
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.21	tRNAhis + L-histidine + ATP  =  L-histidyl-tRNAhis + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.6	tRNAlys + L-lysine + ATP  =  L-lysyl-tRNAlys + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.16	tRNAcys + L-cysteine + ATP  =  L-cysteinyl-tRNAcys + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.62	chlorophyllide a + phytyl pyrophosphate  =  chlorophyll a + pyrophosphate	chlorophyll cycle
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.62	chlorophyllide a + phytyl pyrophosphate  =  chlorophyll a + pyrophosphate	chlorophyll a biosynthesis I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides II
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.15	phosphoryl-choline + CTP  =  CDP-choline + pyrophosphate	choline biosynthesis III
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	3.5.4.25	3 H2O + GTP  =  pyrophosphate + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate + formate	riboflavin and FMN and FAD biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.11	nicotinate + H2O + PRPP + ATP  =  nicotinate nucleotide + pyrophosphate + phosphate + ADP	pyridine nucleotide cycling
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	RXN-2541	homogentisate + phytyl pyrophosphate  =  2-methyl-6-phytyl-1,4-benzoquinone + CO2 + pyrophosphate	vitamin E biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis II (from tryptophan)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis I (from aspartate)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	pyridine nucleotide cycling
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.2	tRNAtrp + L-tryptophan + ATP  =  L-tryptophanyl-tRNAtrp + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.1	L-tyrosine + tRNAtyr + ATP  =  L-tyrosyl-tRNAtyr + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	3.6.1.31	phosphoribosyl-ATP + H2O  =  phosphoribosyl-AMP + pyrophosphate	histidine biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.38	3-deoxy-D-manno-octulosonate + CTP  =  CMP-3-deoxy-D-manno-octulosonate + pyrophosphate	lipid-A-precursor biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.27	alpha-D-glucose-1-phosphate + ATP  =  ADP-D-glucose + pyrophosphate	starch biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.29	delta3-isopentenyl-PP + trans, trans-farnesyl diphosphate  =  geranylgeranyl-PP + pyrophosphate	ent-kaurene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.4	SO42- + ATP  =  APS + pyrophosphate	sulfate assimilation
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.-	guanine + PRPP  =  pyrophosphate + GMP	salvage pathways of purine nucleosides
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.3	tRNAthr + L-threonine + ATP  =  L-threonyl-tRNAthr + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.20	tRNAphe + L-phenylalanine + ATP  =  L-phenylalanyl-tRNAphe + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	SAM cycle
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	ethylene biosynthesis from methionine
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	adenosylmethionine biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine salvage pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine degradation I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.41	CTP + L-phosphatidate  =  CDP-diacylglycerol + pyrophosphate	phospholipid biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.4.2.18	anthranilate + PRPP  =  N-(5'-phosphoribosyl)-anthranilate + pyrophosphate	tryptophan biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	4.2.3.19	ent-copalyl diphosphate  =  pyrophosphate + ent-kaur-16-ene	ent-kaurene biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.10	geranyl-PP + delta3-isopentenyl-PP  =  pyrophosphate + trans, trans-farnesyl diphosphate	polyisoprenoid biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.10	geranyl-PP + delta3-isopentenyl-PP  =  pyrophosphate + trans, trans-farnesyl diphosphate	mevalonate pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.11	tRNAser + L-serine + ATP  =  L-seryl-tRNAser + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.18	tRNAgln + L-glutamine + ATP  =  L-glutaminyl-tRNAgln + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.5	tRNAile + L-isoleucine + ATP  =  L-isoleucyl-tRNAile + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.4	L-leucine + tRNAleu + ATP  =  L-leucyl-tRNAleu + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.10	tRNAmet + L-methionine + ATP  =  L-methionyl-tRNAmet + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.9	tRNAval + L-valine + ATP  =  L-valyl-tRNAval + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.23	N-acetyl-glucosamine-1-phosphate + UTP  =  UDP-N-acetyl-D-glucosamine + pyrophosphate	UDP-N-acetyl-D-glucosamine biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose degradation
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose degradation to ethanol and lactate (anaerobic)
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	colanic acid building blocks biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	galactose degradation II
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	galactose degradation I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	UDP-glucose conversion
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.14	tRNAgly + glycine + ATP  =  glycyl-tRNAgly + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.15	L-proline + tRNApro + ATP  =  L-prolyl-tRNApro + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.15	p-aminobenzoate + 2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate  =  7,8-dihydropteroate + pyrophosphate	tetrahydrofolate biosynthesis I
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	2.5.1.15	p-aminobenzoate + 2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate  =  7,8-dihydropteroate + pyrophosphate	tetrahydrofolate biosynthesis II
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.7	tRNAala + L-alanine + ATP  =  L-alanyl-tRNAala + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.19	tRNAarg + L-arginine + ATP  =  L-arginyl-tRNAarg + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.1.1.22	tRNAasn + L-asparagine + ATP  =  L-asparaginyl-tRNAasn + pyrophosphate + AMP	tRNA charging pathway
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	flavonoid biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	lignin biosynthesis
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides II
pyrophosphate	diphosphate*PPi*PP*pyrophosphate	H4 O7 P2 	O(P(O)(O)=O)P(O)(=O)O	LIGAND-CPD:C00013*CAS:09/03/2466*CAS:2466-09-3	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides I
methanol	MetOH*carbinol*MeOH*methyl alcohol*wood alcohol	C1 H4 O1 	CO	CAS:67-56-1	3.1.1.11	methylesterified 1,4-alpha-D-galacturonosyl + H2O  =  1,4-alpha-D-galacturonosyl + methanol	homogalacturonan degradation
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.8	L-glutamine + chorismate  =  4-amino-4-deoxychorismate + L-glutamate	tetrahydrofolate biosynthesis I
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.8	L-glutamine + chorismate  =  4-amino-4-deoxychorismate + L-glutamate	tetrahydrofolate biosynthesis II
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis II (from tryptophan)
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis I (from aspartate)
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	pyridine nucleotide cycling
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	4.1.3.27	chorismate + L-glutamine  =  anthranilate + pyruvate + L-glutamate	tryptophan biosynthesis
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	RXN-2948	indole-3-acetate + L-glutamine  =  indole-3-acetyl-gln + H2O	IAA conjugate biosynthesis
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides II
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides I
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides II
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides I
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.5.4	H2O + L-glutamine + L-aspartate + ATP  =  L-glutamate + L-asparagine + pyrophosphate + AMP	asparagine biosynthesis
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.4.2	L-glutamine + H2O + UTP + ATP  =  CTP + phosphate + ADP + L-glutamate	de novo biosynthesis of pyrimidine ribonucleotides
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.1.1.18	tRNAgln + L-glutamine + ATP  =  L-glutaminyl-tRNAgln + pyrophosphate + AMP	tRNA charging pathway
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	2.6.1.16	D-fructose-6-phosphate + L-glutamine  =  D-glucosamine-6-phosphate + L-glutamate	UDP-N-acetyl-D-glucosamine biosynthesis
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides II
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides I
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	2.4.2.-	phosphoribulosylformimino-AICAR-P + L-glutamine  =  D-erythro-imidazole-glycerol-phosphate + AICAR + L-glutamate	histidine biosynthesis
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	glutamine biosynthesis
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	ammonia assimilation cycle
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	nitrate assimilation pathway
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	ammonia assimilation cycle
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	glutamate biosynthesis I
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	ammonia assimilation cycle
L-glutamine	Q*proglumide*glum*gln*glutamine*glumin*2-aminoglutaramic acid*glutamic acid 5-amide	C5 H10 N2 O3 	C(N)(=O)CCC(N)C(O)=O	LIGAND:C00064*CAS:6899-04-3	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	glutamate biosynthesis II
chlorophyll a	chlorophyll a	C55 H72 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(c(C)c(c(n67)=C8[CH](C(=O)9)C(=O)OC)CCC(=O)OCC=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C)))))))		RXN-7679	7-hydroxy-chlorophyll a + H2O + NADP+  =  chlorophyll a + O2 + NADPH	chlorophyll cycle
chlorophyll a	chlorophyll a	C55 H72 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(c(C)c(c(n67)=C8[CH](C(=O)9)C(=O)OC)CCC(=O)OCC=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C)))))))		1.3.1.-	tetrahydrogeranylgeranyl-chlorophyll a + NADPH  =  chlorophyll a + NADP+	chlorophyll a biosynthesis II
chlorophyll a	chlorophyll a	C55 H72 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(c(C)c(c(n67)=C8[CH](C(=O)9)C(=O)OC)CCC(=O)OCC=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C)))))))		2.5.1.62	chlorophyllide a + phytyl pyrophosphate  =  chlorophyll a + pyrophosphate	chlorophyll cycle
chlorophyll a	chlorophyll a	C55 H72 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(c(C)c(c(n67)=C8[CH](C(=O)9)C(=O)OC)CCC(=O)OCC=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C)))))))		2.5.1.62	chlorophyllide a + phytyl pyrophosphate  =  chlorophyll a + pyrophosphate	chlorophyll a biosynthesis I
chlorophyll b	chlorophyll b	C55 H70 N4 O6 MG1 	Cc5(c9(c8(n4([Mg]36(n1(c(c(C)c(C=C)c1=Cc2(c(C=O)c(CC)c(n23)=Cc45))=Cc7(c(C)c(c(n67)=C8[CH](C(=O)9)C(=O)OC)CCC(=O)OCC=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C)))))))		RXN-7678	chlorophyll b + 2 H2O + NADP+  =  7-hydroxy-chlorophyll a + O2 + NADPH	chlorophyll cycle
chlorophyll b	chlorophyll b	C55 H70 N4 O6 MG1 	Cc5(c9(c8(n4([Mg]36(n1(c(c(C)c(C=C)c1=Cc2(c(C=O)c(CC)c(n23)=Cc45))=Cc7(c(C)c(c(n67)=C8[CH](C(=O)9)C(=O)OC)CCC(=O)OCC=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C)))))))		2.5.1.-	chlorophyllide b + phytyl pyrophosphate  =  chlorophyll b + pyrophosphate	chlorophyll cycle
presqualene diphosphate		C30 H52 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=C[CH]1(C([CH]1COP(O)(=O)OP(O)(=O)O)(C)CCC=C(C)CCC=C(C)C)		2.5.1.21	presqualene diphosphate + NAD(P)H  =  squalene + NAD(P)+ + pyrophosphate	sterol biosynthesis
presqualene diphosphate		C30 H52 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=C[CH]1(C([CH]1COP(O)(=O)OP(O)(=O)O)(C)CCC=C(C)CCC=C(C)C)		2.5.1.21	2 trans, trans-farnesyl diphosphate  =  presqualene diphosphate + pyrophosphate	sterol biosynthesis
H2S	hydrogen sulfide	H2 S1 	[SH2]		4.2.99.8	O-acetyl-L-serine + H2S  =  L-cysteine + acetate	cysteine biosynthesis
H2S	hydrogen sulfide	H2 S1 	[SH2]		4.2.99.8	O-acetyl-L-serine + H2S  =  L-cysteine + acetate	sulfate assimilation
H2S	hydrogen sulfide	H2 S1 	[SH2]		1.8.7.1	3 reduced ferredoxin + SO3-2  =  H2O + oxidized ferredoxin + H2S	sulfate assimilation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	formylTHF biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.9	imidazole acetol-phosphate + L-glutamate  =  L-histidinol-phosphate + alpha-ketoglutarate	histidine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.5	phenylpyruvate + L-glutamate  =  L-phenylalanine + alpha-ketoglutarate	phenylalanine biosynthesis II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	glutamine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	ammonia assimilation cycle
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	nitrate assimilation pathway
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	4.1.1.15	L-glutamate  =  CO2 + 4-aminobutyrate	glutamate degradation II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	ammonia assimilation cycle
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	glutamate biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.3.1.1	L-glutamate + acetyl-CoA  =  N-acetyl-L-glutamate + coenzyme A	arginine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.3.1.1	L-glutamate + acetyl-CoA  =  N-acetyl-L-glutamate + coenzyme A	arginine biosynthesis II (acetyl cycle)
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.3.1.35	L-glutamate + N-alpha-acetylornithine  =  N-acetyl-L-glutamate + L-ornithine	arginine biosynthesis II (acetyl cycle)
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.42	2-keto-3-methyl-valerate + L-glutamate  =  L-isoleucine + alpha-ketoglutarate	isoleucine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.42	2-keto-3-methyl-valerate + L-glutamate  =  L-isoleucine + alpha-ketoglutarate	isoleucine degradation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.2	L-cysteine + L-glutamate + ATP  =  L-gamma-glutamylcysteine + phosphate + ADP	glutathione biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	chlorophyllide a biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	biosynthesis of proto- and siroheme
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	tRNA charging pathway
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	ammonia assimilation cycle
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	glutamate biosynthesis II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.9	phenylpyruvate + L-glutamate  =  L-phenylalanine + alpha-ketoglutarate	phenylalanine biosynthesis II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.42	2-keto-4-methyl-pentanoate + L-glutamate  =  L-leucine + alpha-ketoglutarate	leucine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.42	2-keto-4-methyl-pentanoate + L-glutamate  =  L-leucine + alpha-ketoglutarate	leucine degradation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	pantothenate biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	valine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	valine degradation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.57	p-hydroxyphenylpyruvate + L-glutamate  =  L-tyrosine + alpha-ketoglutarate	tyrosine biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	RXN-2947	indole-3-acetate + L-glutamate  =  indole-3-acetyl-glu + H2O	IAA conjugate biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.2.17	tetrahydrofolate + L-glutamate + ATP  =  THF-L-glutamate + ADP + phosphate	tetrahydrofolate biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.57	prephenate + L-glutamate  =  L-arogenate + alpha-ketoglutarate	tyrosine biosynthesis II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.57	prephenate + L-glutamate  =  L-arogenate + alpha-ketoglutarate	phenylalanine biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	arginine biosynthesis III
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	proline biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	1.4.1.2	H2O + NAD+ + L-glutamate  =  NH3 + NADH + alpha-ketoglutarate	glutamate degradation I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	1.4.1.3	NH3 + NAD(P)H + alpha-ketoglutarate  =  NAD(P)+ + H2O + L-glutamate	arginine biosynthesis III
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	1.5.1.12	L-delta1-pyrroline-5-carboxylate + NAD(P)+ + H2O  =  L-glutamate + NAD(P)H + H+	proline degradation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	1.5.1.9	H2O + NAD+ + saccharopine  =  NADH + allysine + L-glutamate	lysine degradation II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.39	alpha-ketoglutarate + alpha-aminoadipate  =  L-glutamate + alpha-ketoadipate	lysine degradation II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.4	H2O + L-glutamine + L-aspartate + ATP  =  L-glutamate + L-asparagine + pyrophosphate + AMP	asparagine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.2	alpha-ketoglutarate + L-alanine  =  L-glutamate + pyruvate	alanine degradation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.2	alpha-ketoglutarate + L-alanine  =  L-glutamate + pyruvate	alanine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.27	alpha-ketoglutarate + L-tryptophan  =  L-glutamate + indole-3-pyruvate	IAA biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.4	L-glutamate + glyoxylate  =  alpha-ketoglutarate + glycine	photorespiration
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	RXN-974	L-serine + alpha-ketoglutarate  =  hydroxypyruvate + L-glutamate	photorespiration
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.19	alpha-ketoglutarate + 4-aminobutyrate  =  L-glutamate + succinate semialdehyde	glutamate degradation II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.19	alpha-ketoglutarate + 4-aminobutyrate  =  L-glutamate + succinate semialdehyde	arginine degradation I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.5	L-tyrosine + alpha-ketoglutarate  =  L-glutamate + p-hydroxyphenylpyruvate	tyrosine degradation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.5	L-tyrosine + alpha-ketoglutarate  =  L-glutamate + p-hydroxyphenylpyruvate	phenylalanine degradation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.17	L-glutamate + N-succinyl-2-amino-6-ketopimelate  =  alpha-ketoglutarate + N-succinyl-L,L-2,6-diaminopimelate	lysine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	arginine biosynthesis III
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	proline biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	arginine degradation II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.8	L-glutamine + chorismate  =  4-amino-4-deoxychorismate + L-glutamate	tetrahydrofolate biosynthesis I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.8	L-glutamine + chorismate  =  4-amino-4-deoxychorismate + L-glutamate	tetrahydrofolate biosynthesis II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.16	D-fructose-6-phosphate + L-glutamine  =  D-glucosamine-6-phosphate + L-glutamate	UDP-N-acetyl-D-glucosamine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.52	3-phospho-hydroxypyruvate + L-glutamate  =  3-phospho-serine + alpha-ketoglutarate	serine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.4.2.-	phosphoribulosylformimino-AICAR-P + L-glutamine  =  D-erythro-imidazole-glycerol-phosphate + AICAR + L-glutamate	histidine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis II (from tryptophan)
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis I (from aspartate)
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	pyridine nucleotide cycling
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.1	oxaloacetate + L-glutamate  =  L-aspartate + alpha-ketoglutarate	asparagine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.1	oxaloacetate + L-glutamate  =  L-aspartate + alpha-ketoglutarate	aspartate biosynthesis and degradation
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.11	N-acetylglutamate semialdehyde + L-glutamate  =  N-alpha-acetylornithine + alpha-ketoglutarate	arginine biosynthesis
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	2.6.1.11	N-acetylglutamate semialdehyde + L-glutamate  =  N-alpha-acetylornithine + alpha-ketoglutarate	arginine biosynthesis II (acetyl cycle)
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.4.2	L-glutamine + H2O + UTP + ATP  =  CTP + phosphate + ADP + L-glutamate	de novo biosynthesis of pyrimidine ribonucleotides
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides II
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides I
L-glutamate	1-amino-propane-1,3-dicarboxylic acid*glutacid*glutaminic acid*L-glutamic acid*&alpha;-aminoglutaric acid*E*glt*glu*glut*glutamate*L-glu*2-aminopentanedioic acid	C5 H9 N1 O4 	C(=O)(O)CCC(N)C(O)=O	LIGAND-CPD:C00025*CAS:56-86-0	4.1.3.27	chorismate + L-glutamine  =  anthranilate + pyruvate + L-glutamate	tryptophan biosynthesis
N-(5'-phosphoribosyl)-anthranilate	N-(5-phospho-&beta;-D-ribosyl)-anthranilate*5-phosphoribosyl-anthranilate*5-P-ribosyl-anthranilate*5'-phosphoribosyl-anthranilate*5'-P-ribosyl-anthranilate*N-(5-phosphoribosyl)-anthranilate	C12 H16 N1 O9 P1 	[CH]1([CH](O)[CH](O)[CH](O1)COP(O)(O)=O)Nc2(c(C(O)=O)cccc2)		5.3.1.24	N-(5'-phosphoribosyl)-anthranilate  =  1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-phosphate	tryptophan biosynthesis
N-(5'-phosphoribosyl)-anthranilate	N-(5-phospho-&beta;-D-ribosyl)-anthranilate*5-phosphoribosyl-anthranilate*5-P-ribosyl-anthranilate*5'-phosphoribosyl-anthranilate*5'-P-ribosyl-anthranilate*N-(5-phosphoribosyl)-anthranilate	C12 H16 N1 O9 P1 	[CH]1([CH](O)[CH](O)[CH](O1)COP(O)(O)=O)Nc2(c(C(O)=O)cccc2)		2.4.2.18	anthranilate + PRPP  =  N-(5'-phosphoribosyl)-anthranilate + pyrophosphate	tryptophan biosynthesis
alpha-aminoadipate	L-&alpha;-aminoadipate*L-&alpha;-aminoadipic acid*L-2-aminoadipic acid*L-2-aminoadipate	C6 H11 N1 O4 	C(O)(=O)C(N)CCCC(=O)O	CAS:542-32-5	2.6.1.39	alpha-ketoglutarate + alpha-aminoadipate  =  L-glutamate + alpha-ketoadipate	lysine degradation II
alpha-aminoadipate	L-&alpha;-aminoadipate*L-&alpha;-aminoadipic acid*L-2-aminoadipic acid*L-2-aminoadipate	C6 H11 N1 O4 	C(O)(=O)C(N)CCCC(=O)O	CAS:542-32-5	ALLYSINE-DEHYDROG-RXN	H2O + allysine + NAD+  =  alpha-aminoadipate + NADH	lysine degradation II
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	6.1.1.14	tRNAgly + glycine + ATP  =  glycyl-tRNAgly + pyrophosphate + AMP	tRNA charging pathway
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis I
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	photorespiration
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	glycine biosynthesis
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides II
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides I
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	6.3.2.3	glycine + L-gamma-glutamylcysteine + ATP  =  glutathione + phosphate + ADP	glutathione biosynthesis
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis I
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	photorespiration
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	2.6.1.4	L-glutamate + glyoxylate  =  alpha-ketoglutarate + glycine	photorespiration
glycine	G*aminoacetic acid*gly	C2 H5 N1 O2 	C(=O)(O)CN	LIGAND:C00037*CAS:56-40-6	1.4.4.2	H-protein-(lipoyl)lysine + glycine  =  CO2 + S-aminomethyldihydrolipoyl-GcvH-protein	glycine degradation
(mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol  	{&alpha;-D-mannosyl-(1->3)-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C108 H180 N2 O27 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)CO)OC4(OC(CO)C(O)C(O)C(O)4))))		RXN-5463	(mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP-mannose  =  (mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol  	{&alpha;-D-mannosyl-(1->3)-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C108 H180 N2 O27 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)CO)OC4(OC(CO)C(O)C(O)C(O)4))))		2.4.1.132	mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  (mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol  	{&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C114 H190 N2 O32 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC4(OC(COC3(OC(CO)C(O)C(O)C(O)3))C(O)C(C(O)4)OC5(OC(CO)C(O)C(O)C(O)5))))		RXN-5464	(mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP-mannose  =  (mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol  	{&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C114 H190 N2 O32 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC4(OC(COC3(OC(CO)C(O)C(O)C(O)3))C(O)C(C(O)4)OC5(OC(CO)C(O)C(O)C(O)5))))		RXN-5463	(mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP-mannose  =  (mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C120 H200 N2 O37 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC4(OC(CO)C(O)C(O)C(O)4))OC5(C(C(O)C(O)C(O5)CO)OC6(OC(CO)C(O)C(O)C(O)6)))))		RXN-5465	(mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  (mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C120 H200 N2 O37 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC4(OC(CO)C(O)C(O)C(O)4))OC5(C(C(O)C(O)C(O5)CO)OC6(OC(CO)C(O)C(O)C(O)6)))))		RXN-5464	(mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP-mannose  =  (mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C126 H210 N2 O42 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC4(OC(CO)C(O)C(O)C(O)4))OC5(C(C(O)C(O)C(O5)CO)OC6(C(C(O)C(O)C(O6)CO)OC7(OC(CO)C(O)C(O)C(O)7))))))		RXN-5466	(mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C126 H210 N2 O42 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC4(OC(CO)C(O)C(O)C(O)4))OC5(C(C(O)C(O)C(O5)CO)OC6(C(C(O)C(O)C(O6)CO)OC7(OC(CO)C(O)C(O)C(O)7))))))		RXN-5465	(mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  (mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
ent-kaur-16-en-19-al		C20 H30 O1 	C=C1(C2(CC3(C1)([CH](CC2)C4(C)([CH](CC3)C(C)(C=O)CCC4))))		1.14.13.78	ent-kaur-16-en-19-al + NADPH + H+ + O2  =  ent-kaurenoate + NADP+ + H2O	GA12 biosynthesis
ent-kaur-16-en-19-al		C20 H30 O1 	C=C1(C2(CC3(C1)([CH](CC2)C4(C)([CH](CC3)C(C)(C=O)CCC4))))		1.14.13.78	ent-kaur-16-en-19-ol + NADPH + H+ + O2  =  ent-kaur-16-en-19-al + NADP+ + 2 H2O	GA12 biosynthesis
(mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->3)-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C132 H220 N2 O47 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC4(C(O)C(C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5)))OC6(C(C(O)C(O)C(O6)CO)OC7(C(C(O)C(O)C(O7)CO)OC8(OC(CO)C(O)C(O)C(O)8))))))		RXN-5467	(mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->3)-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C132 H220 N2 O47 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC4(C(O)C(C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5)))OC6(C(C(O)C(O)C(O6)CO)OC7(C(C(O)C(O)C(O7)CO)OC8(OC(CO)C(O)C(O)C(O)8))))))		RXN-5466	(mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C138 H230 N2 O52 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC6(OC(COC3(C(O)C(C(O)C(O3)CO)OC4(C(C(O)C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5))))C(O)C(C(O)6)OC7(C(C(O)C(O)C(O7)CO)OC8(C(C(O)C(O)C(O8)CO)OC9(OC(CO)C(O)C(O)C(O)9))))))		RXN-5468	(mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C138 H230 N2 O52 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC6(OC(COC3(C(O)C(C(O)C(O3)CO)OC4(C(C(O)C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5))))C(O)C(C(O)6)OC7(C(C(O)C(O)C(O7)CO)OC8(C(C(O)C(O)C(O8)CO)OC9(OC(CO)C(O)C(O)C(O)9))))))		RXN-5467	(mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C144 H240 N2 O57 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC7(OC(COC3(C(O)C(C(O)C(O3)COC4(OC(CO)C(O)C(O)C(O)4))OC5(C(C(O)C(O)C(O5)CO)OC6(OC(CO)C(O)C(O)C(O)6))))C(O)C(C(O)7)OC8(C(C(O)C(O)C(O8)CO)OC9(C(C(O)C(O)C(O9)CO)OC10(OC(CO)C(O)C(O)C(O)10))))))		RXN-5469	(mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol   + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C144 H240 N2 O57 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC7(OC(COC3(C(O)C(C(O)C(O3)COC4(OC(CO)C(O)C(O)C(O)4))OC5(C(C(O)C(O)C(O5)CO)OC6(OC(CO)C(O)C(O)C(O)6))))C(O)C(C(O)7)OC8(C(C(O)C(O)C(O8)CO)OC9(C(C(O)C(O)C(O9)CO)OC10(OC(CO)C(O)C(O)C(O)10))))))		RXN-5468	(mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol  	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C150 H250 N2 O62 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC8(OC(COC5(OC(COC3(C(C(O)C(O)C(O3)CO)OC4(OC(CO)C(O)C(O)C(O)4)))C(O)C(C(O)5)OC6(C(C(O)C(O)C(O6)CO)OC7(OC(CO)C(O)C(O)C(O)7))))C(O)C(C(O)8)OC9(C(C(O)C(O)C(O9)CO)OC10(C(C(O)C(O)C(O10)CO)OC11(OC(CO)C(O)C(O)C(O)11))))))		RXN-5470	(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol   + dolichyl beta-D-glucosyl phosphate  =  glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol  	{&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C150 H250 N2 O62 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC8(OC(COC5(OC(COC3(C(C(O)C(O)C(O3)CO)OC4(OC(CO)C(O)C(O)C(O)4)))C(O)C(C(O)5)OC6(C(C(O)C(O)C(O6)CO)OC7(OC(CO)C(O)C(O)C(O)7))))C(O)C(C(O)8)OC9(C(C(O)C(O)C(O9)CO)OC10(C(C(O)C(O)C(O10)CO)OC11(OC(CO)C(O)C(O)C(O)11))))))		RXN-5469	(mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol   + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-glucosyl-(1->3)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C156 H260 N2 O67 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC6(OC(COC4(C(C(O)C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5)))C(O)C(C(O)6)OC7(C(C(O)C(O)C(O7)CO)OC8(OC(CO)C(O)C(O)C(O)8))))OC9(C(C(O)C(O)C(O9)CO)OC10(C(C(O)C(O)C(O10)CO)OC11(C(O)C(C(O)C(O11)CO)OC12(OC(CO)C(O)C(O)C(O)12)))))))		RXN-5471	glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-glucosyl phosphate  =  (glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-glucosyl-(1->3)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C156 H260 N2 O67 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC6(OC(COC4(C(C(O)C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5)))C(O)C(C(O)6)OC7(C(C(O)C(O)C(O7)CO)OC8(OC(CO)C(O)C(O)C(O)8))))OC9(C(C(O)C(O)C(O9)CO)OC10(C(C(O)C(O)C(O10)CO)OC11(C(O)C(C(O)C(O11)CO)OC12(OC(CO)C(O)C(O)C(O)12)))))))		RXN-5470	(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol   + dolichyl beta-D-glucosyl phosphate  =  glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
3-hydroxyacyl-CoA		C24 H39 N7 O18 R1 P3 S1 			4.2.1.17	3-hydroxyacyl-CoA  =  trans-delta2-enoyl-CoA + H2O	very long chain fatty acid biosynthesis
3-hydroxyacyl-CoA		C24 H39 N7 O18 R1 P3 S1 			1.1.1.36	beta-ketoacyl-CoA + NADPH  =  3-hydroxyacyl-CoA + NADP+	very long chain fatty acid biosynthesis
4-maleyl-acetoacetate		C8 H8 O6 	C(=O)(O)C=CC(=O)CC(=O)CC(O)=O		5.2.1.2	4-maleyl-acetoacetate  =  4-fumaryl-acetoacetate	tyrosine degradation
4-maleyl-acetoacetate		C8 H8 O6 	C(=O)(O)C=CC(=O)CC(=O)CC(O)=O		5.2.1.2	4-maleyl-acetoacetate  =  4-fumaryl-acetoacetate	phenylalanine degradation
4-maleyl-acetoacetate		C8 H8 O6 	C(=O)(O)C=CC(=O)CC(=O)CC(O)=O		1.13.11.5	O2 + homogentisate  =  4-maleyl-acetoacetate	tyrosine degradation
4-maleyl-acetoacetate		C8 H8 O6 	C(=O)(O)C=CC(=O)CC(=O)CC(O)=O		1.13.11.5	O2 + homogentisate  =  4-maleyl-acetoacetate	phenylalanine degradation
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	3.2.2.16	H2O + 5'-methylthioadenosine  =  5-methylthioribose + adenine	methionine salvage pathway
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	4.4.1.14	S-adenosyl-L-methionine  =  5'-methylthioadenosine + 1-aminocyclopropane-1-carboxylate	ethylene biosynthesis from methionine
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	4.4.1.14	S-adenosyl-L-methionine  =  5'-methylthioadenosine + 1-aminocyclopropane-1-carboxylate	methionine salvage pathway
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	2.5.1.22	spermidine + S-adenosylmethioninamine  =  spermine + 5'-methylthioadenosine	spermine biosynthesis II
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	2.5.1.22	spermidine + S-adenosylmethioninamine  =  spermine + 5'-methylthioadenosine	spermine biosynthesis I
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis III
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	spermine biosynthesis II
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	spermine biosynthesis I
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis II
5'-methylthioadenosine	Methylthioadenosine*5'-Deoxy-5'-(methylthio)adenosine*5'-S-methyl-5'-thioadenosine*MTA*S-methyl-adenosine	C11 H15 N5 O3 S1 	C1(OC(CSC)C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3))	CAS:2457-80-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis I
methacrylyl-CoA	Methylacrylyl-CoA*2-Methylprop-2-enoyl-CoA*methacrylyl-coenzyme A	C25 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(O)=O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)=C)	CAS:6008-91-9	4.2.1.17	methacrylyl-CoA + H2O  =  3-hydroxy-isobutyryl-CoA	valine degradation
methacrylyl-CoA	Methylacrylyl-CoA*2-Methylprop-2-enoyl-CoA*methacrylyl-coenzyme A	C25 H40 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(O)=O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)=C)	CAS:6008-91-9	1.3.99.12	isobutyryl-CoA + FAD  =  methacrylyl-CoA + FADH2	valine degradation
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	2.7.4.8	GMP + ATP  =  GDP + ADP	de novo biosynthesis of purine nucleotides I
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	3.1.3.5	GMP + H2O  =  guanosine + phosphate	purine degradation
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	3.1.3.5	GMP + H2O  =  guanosine + phosphate	salvage pathways of purine nucleosides
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	2.7.1.73	guanosine + ATP  =  GMP + ADP	salvage pathways of purine nucleosides
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	RXN-1883	GDP-L-galactose + 2 H2O  =  L-galactose + GMP + phosphate	ascorbate biosynthesis
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	salvage pathways of purine nucleosides
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	de novo biosynthesis of purine nucleotides I
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	2.4.2.-	guanine + PRPP  =  pyrophosphate + GMP	salvage pathways of purine nucleosides
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides II
GMP	guanylate*G*guanylic acid*guanosine-phosphate*guanosine-5'-phosphate*guanosine-monophosphate*guanosine monophosphate*guanosine-5'-monophosphate	C10 H14 N5 O8 P1 	C(OP(=O)(O)O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00144*CAS:85-32-5	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides I
dihydroquercetin	dihydro quercetin*taxifolin	C15 H12 O7 	c1(cc(cc(O)c1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))		1.1.1.219	dihydroquercetin + NADPH  =  leucocyanidin + NADP+	anthocyanin biosynthesis
dihydroquercetin	dihydro quercetin*taxifolin	C15 H12 O7 	c1(cc(cc(O)c1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))		RXN-527	dihydroquercetin + alpha-ketoglutarate + O2  =  quercetin + succinate + CO2 + H2O	flavonol biosynthesis
dihydroquercetin	dihydro quercetin*taxifolin	C15 H12 O7 	c1(cc(cc(O)c1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))		1.14.13.21	dihydrokaempferol + O2  =  dihydroquercetin + H2O	flavonol biosynthesis
dihydroquercetin	dihydro quercetin*taxifolin	C15 H12 O7 	c1(cc(cc(O)c1O)C2(C(O)C(=O)c3(c(O2)cc(O)cc3O)))		1.14.13.21	dihydrokaempferol + O2  =  dihydroquercetin + H2O	anthocyanin biosynthesis
GA110	gibberellin A<sub>110</sub>*gibberellin A110*GA110	C20 H28 O5 	CC1([CH]4(C(CC(O)C1)(C)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA110 + succinate + CO2	gibberellin inactivation
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	IAA biosynthesis I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	glucosinolate biosynthesis from tryptophan
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis II (acetyl cycle)
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	phenylpropanoid biosynthesis, initial reactions
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	suberin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.86	2-acetolactate + NADPH  =  2,3-dihydroxy-isovalerate + NADP+	valine biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-1121	ferulate + NADPH + O2  =  5-hydroxy-ferulic-acid + H2O + NADP+	phenylpropanoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	chlorophyllide a biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	biosynthesis of proto- and siroheme
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN1F-10	monovinyl protochlorophyllide a + NADPH  =  NADP+ + chlorophyllide a	chlorophyllide a biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.75	divinyl protochlorophyllide a + NADPH  =  monovinyl protochlorophyllide a + NADP+	chlorophyllide a biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	carotenoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	xanthophyll cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.193	5-amino-6-(5'-phosphoribosylamino)uracil + NADPH  =  5-amino-6-(5'-phosphoribitylamino)uracil + NADP+	riboflavin and FMN and FAD biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.195	coniferyl aldehyde + NADPH  =  coniferyl alcohol + NADP+	lignin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.36	4-coumaroylquinate + NADPH + O2  =  caffeoylquinate + NADP+ + H2O	lignin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.36	4-coumaroylshikimate + NADPH + O2  =  caffeoylshikimate + NADP+ + H2O	lignin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-1142	coniferyl aldehyde + NADPH + O2  =  5-hydroxy-coniferaldehyde + NADP+ + H2O	lignin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.195	sinapaldehyde + NADPH  =  sinapyl-alcohol + NADP+	lignin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.195	coumaraldehyde + NADPH  =  coumaryl-alcohol + NADP+	lignin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.44	feruloyl-CoA + NADPH  =  coniferyl aldehyde + NADP+ + coenzyme A	lignin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.44	coumaroyl-CoA + NADPH  =  coumaraldehyde + NADP+ + coenzyme A	lignin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.-	benzoate + NADPH + O2  =  salicylate + NADP+ + H2O	salicylic acid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.-.-.-	GDP-4-dehydro-6-L-deoxygalactose + NADPH  =  guanosine diphosphate fucose + NADP+	colanic acid building blocks biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	suberin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	cutin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	phenylpropanoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	suberin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.86	2-aceto-2-hydroxy-butyrate + NADPH  =  2,3-dihydroxy-3-methylvalerate + NADP+	isoleucine biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-1405	tryptamine + O2 + NADPH  =  N-hydroxyl-tryptamine + H2O + NADP+	IAA biosynthesis I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.-	homomethionine + NADPH + O2  =  4-methylthiobutanaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from homomethionine
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-1064	18-hydroxyoleate + NADPH + O2  =  9,10-epoxy-18-hydroxystearate + NADP+ + H2O	cutin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-1062	16-hydroxypalmitate + NADPH + O2  =  10,16-dihydroxypalmitate + NADP+ + H2O	cutin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.-	palmitate + NADPH + O2  =  16-hydroxypalmitate + NADP+ + H2O	cutin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	NAD biosynthesis II (from tryptophan)
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	tryptophan degradation
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.21	5-dehydroavenasterol + 2 NADPH  =  isofucosterol + 2 NADP+	sterol biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.21	5-dehydro episterol + 2 NADPH  =  24-methylenecholesterol + 2 NADP+	sterol biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.70	(4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol + 2 NADPH  =  4alpha-methylfecosterol + 2 NADP+	sterol biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.70	3 NADPH + 3 O2 + obtusifoliol + 3 H+  =  4 H2O + 3 NADP+ + formate + (4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol	sterol biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.219	dihydroquercetin + NADPH  =  leucocyanidin + NADP+	anthocyanin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.6.5.4	2 monodehydroascorbate + NADPH  =  2 L-ascorbate + NADP+	ascorbate glutathione cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.-	L-phenylalanine + NADPH + O2  =  phenylacetaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from phenylalanine
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-5461	dTDP-4-dehydro-6-deoxy-D-glucose + NADPH  =  dTDP-alpha-L-rhamnose + NADP+	dTDP-L-rhamnose biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.79	GA12-aldehyde + NADPH + O2  =  GA12 + NADP+ + H2O	GA12 biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.79	ent-7-alpha-hydroxykaurenoate + NADPH + H+ + O2  =  GA12-aldehyde + NADP+ + 2 H2O	GA12 biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	arginine biosynthesis III
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	proline biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.78	ent-kaur-16-ene + O2 + NADPH  =  H2O + NADP+ + ent-kaur-16-en-19-ol	GA12 biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	carotenoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	xanthophyll cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-4308	isopentenyladenosine-5'-monophosphate + NADPH + H2O  =  trans-zeatin riboside monophosphate + NADP+	trans-zeatin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-4306	isopentenyladenosine-5'-diphosphate + NADPH + H2O  =  trans-zeatin riboside diphosphate + NADP+	trans-zeatin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-4304	isopentenyladenosine-5'-triphosphate + NADPH + H2O  =  trans-zeatin riboside triphosphate + NADP+	trans-zeatin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis III
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis II
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.99.-	22alpha-hydroxy-campest-4-en-3-one + NADPH  =  22alpha-hydroxy-5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis II
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	2.3.1.170	coumaroyl-CoA + 3 malonyl-CoA + NADPH  =  isoliquiritigenin + 4 coenzyme A + 3 CO2 + NADP+ + H2O	flavonoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-5962	zeinoxanthin + NADPH + O2  =  lutein + NADP+ + H2O	carotenoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-5961	alpha-carotene + NADPH + O2  =  zeinoxanthin + NADP+ + H2O	carotenoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.79	ent-kaurenoate + O2 + NADPH  =  ent-7-alpha-hydroxykaurenoate + H2O + NADP+	GA12 biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.78	ent-kaur-16-en-19-ol + NADPH + H+ + O2  =  ent-kaur-16-en-19-al + NADP+ + 2 H2O	GA12 biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.78	ent-kaur-16-en-19-al + NADPH + H+ + O2  =  ent-kaurenoate + NADP+ + H2O	GA12 biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.81	Mg-protoporphyrin monomethyl ester + NADPH + H+ + O2  =  131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + H2O	chlorophyllide a biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.81	131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + 2 H2O	chlorophyllide a biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.81	131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  divinyl protochlorophyllide a + NADP+ + 2 H2O	chlorophyllide a biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-7653	eriodictyol + NADPH + O2  =  luteolin + NADP+ + 2 H2O	luteolin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.21	naringenin + NADPH + O2  =  eriodictyol + NADP+ + H2O	luteolin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.14.13.21	apigenin + NADPH + O2  =  luteolin + NADP+ + H2O	luteolin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-7650	naringenin + NADPH + O2  =  apigenin + NADP+ + 2 H2O	luteolin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	3.1.3.-	NADPH + H2O  =  NADH + phosphate	NAD/NADH phosphorylation and dephosphorylation
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.6.1.1	NAD+ + NADPH  =  NADH + NADP+	NAD/NADH phosphorylation and dephosphorylation
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.38	trans-delta2-enoyl-CoA + NADPH  =  acyln+2-CoA + NADP+	very long chain fatty acid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.36	beta-ketoacyl-CoA + NADPH  =  3-hydroxyacyl-CoA + NADP+	very long chain fatty acid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-5482	UDP-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+ + H2O	UDP-L-rhamnose biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-5481	UDP-4-dehydro-6-deoxy-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+	UDP-L-rhamnose biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.-	tetrahydrogeranylgeranyl-chlorophyll a + NADPH  =  chlorophyll a + NADP+	chlorophyll a biosynthesis II
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.-	dihydrogeranylgeranyl-chlorophyll a + NADPH  =  tetrahydrogeranylgeranyl-chlorophyll a + NADP+	chlorophyll a biosynthesis II
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.-	geranylgeranyl-chlorophyll a + NADPH  =  dihydrogeranylgeranyl-chlorophyll a + NADP+	chlorophyll a biosynthesis II
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-7677	7-hydroxy-chlorophyllide a + O2 + NADPH  =  chlorophyllide b + 2 H2O + NADP+	chlorophyll cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-7676	chlorophyllide a + O2 + NADPH  =  7-hydroxy-chlorophyllide a + H2O + NADP+	chlorophyll cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-7678	chlorophyll b + 2 H2O + NADP+  =  7-hydroxy-chlorophyll a + O2 + NADPH	chlorophyll cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-7679	7-hydroxy-chlorophyll a + H2O + NADP+  =  chlorophyll a + O2 + NADPH	chlorophyll cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	2.7.1.86	NADH + ATP  =  NADPH + ADP	NAD/NADH phosphorylation and dephosphorylation
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.8.1.7	glutathione disulfide + NADPH + H+  =  2 glutathione + NADP+	ascorbate glutathione cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	carotenoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	xanthophyll cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	carotenoid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	xanthophyll cycle
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.43	L-arogenate + NADP+  =  L-tyrosine + NADPH + CO2	tyrosine biosynthesis II
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.5.1.8	NADPH + alpha-ketoglutarate + L-lysine  =  H2O + NADP+ + saccharopine	lysine degradation II
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.224	NADPH + mannose-6-phosphate  =  NADP+ + mannitol-1-phosphate	mannitol biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.2	NADPH + uracil  =  NADP+ + dihydrouracil	beta-alanine biosynthesis III
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.219	NADPH + dihydrokaempferol  =  leucopelargonidin + NADP+	anthocyanin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN1F-16	NADP+ + indole carboxyl hydro-thiazole  =  indole carboxyl thiazole + NADPH	camalexin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.10	NADPH + trans-delta2-enoyl-acyl-ACP  =  acyl-ACP + NADP+	fatty acid elongation -- saturated
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.16	succinate semialdehyde + NADP+ + H2O  =  NADPH + succinate	arginine degradation I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.25	NADPH + 3-dehydro-shikimate  =  NADP+ + shikimate	chorismate biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.-	18-hydroxyoleate + NADP+  =  18-oxooleate + NADPH	suberin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.-	18-oxooleate + NADP+ + H2O  =  octadec-9-ene-1,18-dioic-acid + NADPH	suberin biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.187	NADPH + GDP-4-dehydro-6-deoxy-D-mannose  =  NADP+ + GDP-D-rhamnose	GDP-D-rhamnose biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	TCA cycle variation I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	gluconeogenesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	RXN-2003	hydroxycinnamoyl-CoA + NADP+  =  oxocinnamoyl-CoA + NADPH	salicylic acid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.43	NADPH + CO2  =  NADP+ + formate	carbon monoxide dehydrogenase pathway
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	formylTHF biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	formylTHF biosynthesis I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	carbon monoxide dehydrogenase pathway
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.267	1-deoxy-D-xylulose 5-phosphate + NADPH  =  2-C-methyl-D-erythritol-4-phosphate + NADP+	isopentenyl diphosphate biosynthesis -- mevalonate-independent
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	formylTHF biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	formylTHF biosynthesis I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	tetrahydrofolate biosynthesis I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	tetrahydrofolate biosynthesis II
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.9	H2O + NADP+ + D-glyceraldehyde-3-phosphate  =  3-phosphoglycerate + NADPH	glycolysis I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.271	NADPH + GDP-4-dehydro-6-deoxy-D-mannose  =  NADP+ + guanosine diphosphate fucose	GDP-L-fucose biosynthesis I (from GDP-D-mannose)
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.100	NADPH + beta-ketoacyl-ACP  =  D-3-hydroxy-acyl-ACP + NADP+	fatty acid elongation -- saturated
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.34	2 NADPH + 3-hydroxy-3-methyl-glutaryl-CoA  =  2 NADP+ + coenzyme A + mevalonate	mevalonate pathway
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.3	NADPH + L-aspartate-semialdehyde  =  NADP+ + homoserine	homoserine biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	homoserine biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	lysine biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.169	2-dehydropantoate + NADPH  =  L-pantoate + NADP+	pantothenate biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.3.1.42	NADPH + 12-oxo-cis-10,15-phytodienoate  =  NADP+ + 3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate	jasmonic acid biosynthesis
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle variation I
NADPH	Nicotinamide adenine dinucleotide phosphate - reduced*NADPH+H+*NADPH2*NADPH<SUB>2</SUB>*dihydrotriphosphopyridine nucleotide*dihydrotriphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide phosphate*dihydronicotinamide adenine dinucleotide phosphate reduced*NADP-reduced*NADP-red*NADPH<SUP>+</SUP>H<SUP>+</SUP>*TPNH*dihydronicotinamide adenine dinucleotide-P*NADP(H)	C21 H30 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)N5(C=C(C(N)=O)CC=C5))	LIGAND-CPD:C00005*CAS:2646-71-1	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle -- aerobic respiration
GA97	gibberellin A<sub>97</sub>*gibberellin A97*GA97	C20 H28 O6 	CC1([CH]4(C(CC(O)C1)(C)[CH]3(C2(CC(C(=C)C2)(O)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA97 + succinate + CO2	gibberellin inactivation
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	4.1.3.27	chorismate + L-glutamine  =  anthranilate + pyruvate + L-glutamate	tryptophan biosynthesis
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	5.4.4.2	chorismate  =  isochorismate	phylloquinone biosynthesis
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	5.4.4.2	chorismate  =  isochorismate	salicylic acid biosynthesis
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	5.4.4.2	chorismate  =  isochorismate	menaquinone biosynthesis
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	5.4.99.5	chorismate  =  prephenate	tyrosine biosynthesis II
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	5.4.99.5	chorismate  =  prephenate	phenylalanine biosynthesis I
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	5.4.99.5	chorismate  =  prephenate	tyrosine biosynthesis I
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	5.4.99.5	chorismate  =  prephenate	phenylalanine biosynthesis II
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	6.3.5.8	L-glutamine + chorismate  =  4-amino-4-deoxychorismate + L-glutamate	tetrahydrofolate biosynthesis I
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	6.3.5.8	L-glutamine + chorismate  =  4-amino-4-deoxychorismate + L-glutamate	tetrahydrofolate biosynthesis II
chorismate	chorismic acid	C10 H10 O6 	C=C(C(O)=O)OC1(C(O)C=CC(=C1)C(O)=O)	LIGAND-CPD:C00251*CAS:55508-12-8*LIGAND:C00251*CAS:617-12-9	4.2.3.5	5-enolpyruvyl-shikimate-3-phosphate  =  phosphate + chorismate	chorismate biosynthesis
2-amino-muconate	2-Aminomuconate	C6 H7 N1 O4 	C(O)(=O)C(N)=CC=CC(O)=O		2-AMINOMUCONATE-REDUCTASE-RXN	2-amino-muconate + 2 H2O + NADH  =  NH(4)OH + alpha-ketoadipate + NAD+	tryptophan degradation
2-amino-muconate	2-Aminomuconate	C6 H7 N1 O4 	C(O)(=O)C(N)=CC=CC(O)=O		1.2.1.32	H2O + NAD+ + 2-aminomuconate semialdehyde  =  NADH + 2-amino-muconate	tryptophan degradation
NAD(P)+	NAD(P)*NAD(P)+				1.-.-.-	NAD(P)+ + coproporphyrinogen III  =  protoporphyrinogen + NAD(P)H + 2 CO2	biosynthesis of proto- and siroheme
NAD(P)+	NAD(P)*NAD(P)+				1.2.1.59	NAD(P)H + 1,3-diphosphateglycerate  =  NAD(P)+ + D-glyceraldehyde-3-phosphate + phosphate	Calvin cycle
NAD(P)+	NAD(P)*NAD(P)+				1.1.1.51	campesterol + NAD(P)+  =  campest-4-en-3-one + NAD(P)H	brassinosteroid biosynthesis III
NAD(P)+	NAD(P)*NAD(P)+				1.2.1.3	3-aminopropionaldehyde + NAD(P)+ + H2O  =  beta-alanine + NAD(P)H	beta-alanine biosynthesis I
NAD(P)+	NAD(P)*NAD(P)+				1.5.1.12	L-delta1-pyrroline-5-carboxylate + NAD(P)+ + H2O  =  L-glutamate + NAD(P)H + H+	proline degradation
NAD(P)+	NAD(P)*NAD(P)+				RXN-924	2 NAD(P)+ + 2 H+ + 4 e-  =  2 NAD(P)H	photosynthesis, light reaction
NAD(P)+	NAD(P)*NAD(P)+				1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	proline biosynthesis
NAD(P)+	NAD(P)*NAD(P)+				1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	arginine degradation II
NAD(P)+	NAD(P)*NAD(P)+				1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis
NAD(P)+	NAD(P)*NAD(P)+				1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis I
NAD(P)+	NAD(P)*NAD(P)+				1.3.1.26	L-2,3-dihydrodipicolinate + NAD(P)H + H+  =  L-2,3,4,5-tetrahydrodipicolinate + NAD(P)+	lysine biosynthesis
NAD(P)+	NAD(P)*NAD(P)+				1.1.1.49	beta-D-glucose-6-phosphate + NAD(P)+  =  D-glucono-delta-lactone-6-phosphate + NAD(P)H	oxidative branch of the pentose phosphate pathway
NAD(P)+	NAD(P)*NAD(P)+				1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	superpathway of gluconate degradation
NAD(P)+	NAD(P)*NAD(P)+				1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	oxidative branch of the pentose phosphate pathway
NAD(P)+	NAD(P)*NAD(P)+				1.4.1.3	NH3 + NAD(P)H + alpha-ketoglutarate  =  NAD(P)+ + H2O + L-glutamate	arginine biosynthesis III
NAD(P)+	NAD(P)*NAD(P)+				1.2.1.16	succinate semialdehyde + NAD(P)H  =  4-hydroxybutyrate + NAD(P)+	glutamate degradation II
NAD(P)+	NAD(P)*NAD(P)+				2.5.1.21	presqualene diphosphate + NAD(P)H  =  squalene + NAD(P)+ + pyrophosphate	sterol biosynthesis
NAD(P)+	NAD(P)*NAD(P)+				1.2.1.50	NAD(P)H + very-long-chain-fatty-acyl-CoA  =  NAD(P)+ + a fatty aldehyde	epicuticular wax biosynthesis
NAD(P)+	NAD(P)*NAD(P)+				1.1.1.2	NAD(P)H + a fatty aldehyde  =  NAD(P)+ + a primary alcohol	epicuticular wax biosynthesis
2-oxo-4-methylthiobutanoic acid	2-keto-4-methylthiobutyrate*4-methylthio-2-oxobutanoate*&alpha;-keto-4-methylthiobutyrate*4-methylthio-2-ketobutyrate*4-methylthio-2-ketobutanoate*4-methylthio-2-oxobutyrate*2-ketomethiobutyrate*KMTB*&alpha;-ketomethiobutyrate*2-keto-4-methylthiobutyric acid*&alpha;-ketomethiobutyric acid*&alpha;-keto-&gamma;-methylthiobutyrate*&alpha;-keto-&gamma;-methylthiobutyric acid	C5 H8 O3 S1 	C(SC)CC(=O)C(=O)O		2.3.3.-	2-oxo-4-methylthiobutanoic acid + acetyl-CoA + H2O  =  2-(2'-methylthio)ethylmalic-acid + coenzyme A	homomethionine biosynthesis
2-oxo-4-methylthiobutanoic acid	2-keto-4-methylthiobutyrate*4-methylthio-2-oxobutanoate*&alpha;-keto-4-methylthiobutyrate*4-methylthio-2-ketobutyrate*4-methylthio-2-ketobutanoate*4-methylthio-2-oxobutyrate*2-ketomethiobutyrate*KMTB*&alpha;-ketomethiobutyrate*2-keto-4-methylthiobutyric acid*&alpha;-ketomethiobutyric acid*&alpha;-keto-&gamma;-methylthiobutyrate*&alpha;-keto-&gamma;-methylthiobutyric acid	C5 H8 O3 S1 	C(SC)CC(=O)C(=O)O		2.6.1.5	2-oxo-4-methylthiobutanoic acid + an amino acid  =  L-methionine + keto acid	methionine salvage pathway
2-oxo-4-methylthiobutanoic acid	2-keto-4-methylthiobutyrate*4-methylthio-2-oxobutanoate*&alpha;-keto-4-methylthiobutyrate*4-methylthio-2-ketobutyrate*4-methylthio-2-ketobutanoate*4-methylthio-2-oxobutyrate*2-ketomethiobutyrate*KMTB*&alpha;-ketomethiobutyrate*2-keto-4-methylthiobutyric acid*&alpha;-ketomethiobutyric acid*&alpha;-keto-&gamma;-methylthiobutyrate*&alpha;-keto-&gamma;-methylthiobutyric acid	C5 H8 O3 S1 	C(SC)CC(=O)C(=O)O		R147-RXN	1,2-dihydroxy-3-keto-5-methylthiopentene + O2  =  2-oxo-4-methylthiobutanoic acid + formate	methionine salvage pathway
2-oxo-4-methylthiobutanoic acid	2-keto-4-methylthiobutyrate*4-methylthio-2-oxobutanoate*&alpha;-keto-4-methylthiobutyrate*4-methylthio-2-ketobutyrate*4-methylthio-2-ketobutanoate*4-methylthio-2-oxobutyrate*2-ketomethiobutyrate*KMTB*&alpha;-ketomethiobutyrate*2-keto-4-methylthiobutyric acid*&alpha;-ketomethiobutyric acid*&alpha;-keto-&gamma;-methylthiobutyrate*&alpha;-keto-&gamma;-methylthiobutyric acid	C5 H8 O3 S1 	C(SC)CC(=O)C(=O)O		2.6.1.-	L-methionine + a 2-oxo acid  =  2-oxo-4-methylthiobutanoic acid + an amino acid	homomethionine biosynthesis
cis-aconitate		C6 H6 O6 	C(=O)(O)CC(C(=O)O)=CC(O)=O	CAS:585-84-2	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	TCA cycle variation I
cis-aconitate		C6 H6 O6 	C(=O)(O)CC(C(=O)O)=CC(O)=O	CAS:585-84-2	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	glyoxylate cycle
cis-aconitate		C6 H6 O6 	C(=O)(O)CC(C(=O)O)=CC(O)=O	CAS:585-84-2	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	TCA cycle -- aerobic respiration
cis-aconitate		C6 H6 O6 	C(=O)(O)CC(C(=O)O)=CC(O)=O	CAS:585-84-2	4.2.1.3	citrate  =  cis-aconitate + H2O	TCA cycle variation I
cis-aconitate		C6 H6 O6 	C(=O)(O)CC(C(=O)O)=CC(O)=O	CAS:585-84-2	4.2.1.3	citrate  =  cis-aconitate + H2O	glyoxylate cycle
cis-aconitate		C6 H6 O6 	C(=O)(O)CC(C(=O)O)=CC(O)=O	CAS:585-84-2	4.2.1.3	citrate  =  cis-aconitate + H2O	TCA cycle -- aerobic respiration
kaempferol-3-glucoside-7-rhamnoside	kaempferol-3-O-glucopyranoside-7-O-rhamnopyranoside	C27 H30 O15 	C1(OC(CO)C(O)C(O)C(O)1)Oc2(c(=O)c4(c(oc2c3(ccc(O)cc3))cc(cc(O)4)OC5(C(O)C(O)C(O)C(C)O5)))		RXN1F-444	kaempferol-3-glucoside-7-rhamnoside + UDP-D-glucose  =  kaempferol-3-O-gentiobioside-7-O-rhamnoside + UDP	flavonol biosynthesis
kaempferol-3-glucoside-7-rhamnoside	kaempferol-3-O-glucopyranoside-7-O-rhamnopyranoside	C27 H30 O15 	C1(OC(CO)C(O)C(O)C(O)1)Oc2(c(=O)c4(c(oc2c3(ccc(O)cc3))cc(cc(O)4)OC5(C(O)C(O)C(O)C(C)O5)))		RXN1F-443	kaempferol-3-glucoside + dTDP-alpha-L-rhamnose  =  kaempferol-3-glucoside-7-rhamnoside + dTDP	flavonol biosynthesis
2-(2'-methylthio)ethylmalic-acid		C7 H12 O5 S1 	C(SC)CC(O)(C(O)=O)CC(=O)O		5.4.4.-	2-(2'-methylthio)ethylmalic-acid  =  3-(2'-methylthio)ethylmalic-acid	homomethionine biosynthesis
2-(2'-methylthio)ethylmalic-acid		C7 H12 O5 S1 	C(SC)CC(O)(C(O)=O)CC(=O)O		2.3.3.-	2-oxo-4-methylthiobutanoic acid + acetyl-CoA + H2O  =  2-(2'-methylthio)ethylmalic-acid + coenzyme A	homomethionine biosynthesis
(glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-glucosyl-(1->3)-&alpha;-D-glucosyl-(1->3)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C162 H270 N2 O72 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC6(OC(COC4(C(C(O)C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5)))C(O)C(C(O)6)OC7(C(C(O)C(O)C(O7)CO)OC8(OC(CO)C(O)C(O)C(O)8))))OC9(C(C(O)C(O)C(O9)CO)OC10(C(C(O)C(O)C(O10)CO)OC11(C(O)C(C(O)C(O11)CO)OC12(C(O)C(C(O)C(O12)CO)OC13(OC(CO)C(O)C(O)C(O)13))))))))		RXN-5472	(glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-glucosyl phosphate  =  (glucosyl)3-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
(glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol	{&alpha;-D-glucosyl-(1->3)-&alpha;-D-glucosyl-(1->3)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C162 H270 N2 O72 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC6(OC(COC4(C(C(O)C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5)))C(O)C(C(O)6)OC7(C(C(O)C(O)C(O7)CO)OC8(OC(CO)C(O)C(O)C(O)8))))OC9(C(C(O)C(O)C(O9)CO)OC10(C(C(O)C(O)C(O10)CO)OC11(C(O)C(C(O)C(O11)CO)OC12(C(O)C(C(O)C(O12)CO)OC13(OC(CO)C(O)C(O)C(O)13))))))))		RXN-5471	glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-glucosyl phosphate  =  (glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	6.1.1.16	tRNAcys + L-cysteine + ATP  =  L-cysteinyl-tRNAcys + pyrophosphate + AMP	tRNA charging pathway
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	6.3.2.2	L-cysteine + L-glutamate + ATP  =  L-gamma-glutamylcysteine + phosphate + ADP	glutathione biosynthesis
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	4.2.99.-	L-cysteine + O-phospho-L-homoserine  =  cystathionine + phosphate	methionine biosynthesis
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	4.2.99.-	L-cysteine + O-phospho-L-homoserine  =  cystathionine + phosphate	sulfate assimilation
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	RXN-721	O-acetyl-L-homoserine + L-cysteine  =  cystathionine + acetate	homocysteine and cysteine interconversion
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	6.3.2.5	D-4'-phosphopantothenate + L-cysteine + CTP  =  R-4'-phosphopantothenoyl-L-cysteine + pyrophosphate + CMP	coenzyme A biosynthesis
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	RXN1F-13	indole-3-carboxaldehyde + L-cysteine  =  indole-S-cysteine-adduct	camalexin biosynthesis
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	CYSTATHIONASE-RXN	cystathionine + H2O  =  L-cysteine + homoserine	methionine degradation I
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	4.4.1.1	cystathionine + H2O  =  NH3 + 2-oxobutanoate + L-cysteine	homocysteine and cysteine interconversion
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	4.2.99.8	O-acetyl-L-serine + H2S  =  L-cysteine + acetate	cysteine biosynthesis
L-cysteine	C*carbocysteine*cysteine*Cys	C3 H7 N1 O2 S1 	C(S)C(N)C(O)=O	LIGAND-CPD:C00097*CAS:4371-52-2*CAS:52-90-4	4.2.99.8	O-acetyl-L-serine + H2S  =  L-cysteine + acetate	sulfate assimilation
2-propenyl-glucosinolate	sinigrin	C10 H17 N1 O9 S2 	C1(OC(C(CO)C(O)C(O)1)SC(CC=C)=NOS(O)(=O)=O)(O)		RXN-2222	3-methylsulfinylpropyl-glucosinolate  =  2-propenyl-glucosinolate	glucosinolate biosynthesis from homomethionine
crotonyl-CoA	crotonyl-S-CoA*crotonyl-coenzyme A*crotonoyl-CoA*2-butenoyl-CoA*trans-but-2-enoyl-CoA*but-2-enoyl-CoA*trans-butyr-2-enoyl-CoA	C25 H40 N7 O17 P3 S1 	C1(OC(C(C(O)1)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=CC)(n2(c3(c(nc2)c(N)ncn3)))	UM-BBD-CPD:c0032*LIGAND-CPD:c00877*CAS:102680-35-3*CAS:992-67-6	4.2.1.55	H2O + crotonyl-CoA  =  3-hydroxybutyryl-CoA	lysine degradation II
crotonyl-CoA	crotonyl-S-CoA*crotonyl-coenzyme A*crotonoyl-CoA*2-butenoyl-CoA*trans-but-2-enoyl-CoA*but-2-enoyl-CoA*trans-butyr-2-enoyl-CoA	C25 H40 N7 O17 P3 S1 	C1(OC(C(C(O)1)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=CC)(n2(c3(c(nc2)c(N)ncn3)))	UM-BBD-CPD:c0032*LIGAND-CPD:c00877*CAS:102680-35-3*CAS:992-67-6	4.2.1.55	H2O + crotonyl-CoA  =  3-hydroxybutyryl-CoA	tryptophan degradation
crotonyl-CoA	crotonyl-S-CoA*crotonyl-coenzyme A*crotonoyl-CoA*2-butenoyl-CoA*trans-but-2-enoyl-CoA*but-2-enoyl-CoA*trans-butyr-2-enoyl-CoA	C25 H40 N7 O17 P3 S1 	C1(OC(C(C(O)1)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=CC)(n2(c3(c(nc2)c(N)ncn3)))	UM-BBD-CPD:c0032*LIGAND-CPD:c00877*CAS:102680-35-3*CAS:992-67-6	4.1.1.70	glutaconyl-CoA  =  CO2 + crotonyl-CoA	lysine degradation II
crotonyl-CoA	crotonyl-S-CoA*crotonyl-coenzyme A*crotonoyl-CoA*2-butenoyl-CoA*trans-but-2-enoyl-CoA*but-2-enoyl-CoA*trans-butyr-2-enoyl-CoA	C25 H40 N7 O17 P3 S1 	C1(OC(C(C(O)1)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=CC)(n2(c3(c(nc2)c(N)ncn3)))	UM-BBD-CPD:c0032*LIGAND-CPD:c00877*CAS:102680-35-3*CAS:992-67-6	4.1.1.70	glutaconyl-CoA  =  CO2 + crotonyl-CoA	tryptophan degradation
N-hydroxyl-tryptamine		C10 H12 N2 O1 	c1(c(CCNO)c2(c([nH]1)cccc2))		RXN-1406	N-hydroxyl-tryptamine  =  indole-3-acetaldoxime	IAA biosynthesis I
N-hydroxyl-tryptamine		C10 H12 N2 O1 	c1(c(CCNO)c2(c([nH]1)cccc2))		RXN-1405	tryptamine + O2 + NADPH  =  N-hydroxyl-tryptamine + H2O + NADP+	IAA biosynthesis I
ferricytochrome b1	oxidized cytochrome <i>b</i><sub>1</sub>*cytochrome <i>b</i><sub>1</sub> oxidized				1.2.2.1	ferricytochrome b1 + formate  =  ferrocytochrome b1 + CO2	glycine degradation
1-deoxy-D-xylulose 5-phosphate	DXP*deoxyxylulose-5-phosphate*D-1-deoxyxylulose-5-P*1-deoxy-D-threo-pentulose 5-phosphate*DOXP	C5 H11 O7 P1 	C(OP(=O)(O)O)C(O)C(O)C(C)=O		THIAZOLSYN2-RXN	L-tyrosine + 1-deoxy-D-xylulose 5-phosphate + ThiS-COSH  =  4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-hydroxybenzyl alcohol + C1 of tyrosine + ThiS protein	thiamin biosynthesis
1-deoxy-D-xylulose 5-phosphate	DXP*deoxyxylulose-5-phosphate*D-1-deoxyxylulose-5-P*1-deoxy-D-threo-pentulose 5-phosphate*DOXP	C5 H11 O7 P1 	C(OP(=O)(O)O)C(O)C(O)C(C)=O		1.1.1.267	1-deoxy-D-xylulose 5-phosphate + NADPH  =  2-C-methyl-D-erythritol-4-phosphate + NADP+	isopentenyl diphosphate biosynthesis -- mevalonate-independent
1-deoxy-D-xylulose 5-phosphate	DXP*deoxyxylulose-5-phosphate*D-1-deoxyxylulose-5-P*1-deoxy-D-threo-pentulose 5-phosphate*DOXP	C5 H11 O7 P1 	C(OP(=O)(O)O)C(O)C(O)C(C)=O		4.1.3.37	pyruvate + D-glyceraldehyde-3-phosphate  =  1-deoxy-D-xylulose 5-phosphate + CO2	thiamin biosynthesis
1-deoxy-D-xylulose 5-phosphate	DXP*deoxyxylulose-5-phosphate*D-1-deoxyxylulose-5-P*1-deoxy-D-threo-pentulose 5-phosphate*DOXP	C5 H11 O7 P1 	C(OP(=O)(O)O)C(O)C(O)C(C)=O		4.1.3.37	pyruvate + D-glyceraldehyde-3-phosphate  =  1-deoxy-D-xylulose 5-phosphate + CO2	isopentenyl diphosphate biosynthesis -- mevalonate-independent
a phosphatidylcholine	acyl-glycerophosphocholine*a choline phosphatide*a 1,2-diacyl-sn-glycero-3-phosphocholine*a phosphatidyl-N-trimethylethanolamine*a lecithin	C10 H19 N1 O8 R21 R11 P1 	C([N+1](C)(C)C)COP(=O)(O)OCC(OC(=O)[R1])COC([R2])=O	LIGAND-CPD:C00157*CAS:8002-43-5	3.1.1.4	a phosphatidylcholine + H2O  =  1-acylglycerophosphocholine + a carboxylate	lipases pathway
a phosphatidylcholine	acyl-glycerophosphocholine*a choline phosphatide*a 1,2-diacyl-sn-glycero-3-phosphocholine*a phosphatidyl-N-trimethylethanolamine*a lecithin	C10 H19 N1 O8 R21 R11 P1 	C([N+1](C)(C)C)COP(=O)(O)OCC(OC(=O)[R1])COC([R2])=O	LIGAND-CPD:C00157*CAS:8002-43-5	3.1.1.4	a phosphatidylcholine + H2O  =  linolenate + a lysophosphatidylcholine	jasmonic acid biosynthesis
a phosphatidylcholine	acyl-glycerophosphocholine*a choline phosphatide*a 1,2-diacyl-sn-glycero-3-phosphocholine*a phosphatidyl-N-trimethylethanolamine*a lecithin	C10 H19 N1 O8 R21 R11 P1 	C([N+1](C)(C)C)COP(=O)(O)OCC(OC(=O)[R1])COC([R2])=O	LIGAND-CPD:C00157*CAS:8002-43-5	RXN-1641	a phosphatidylcholine + 1,2-diacylglycerol  =  triacylglycerol + 1-acyl-sn-glycero-3-phosphocholine	triacylglycerol biosynthesis
a phosphatidylcholine	acyl-glycerophosphocholine*a choline phosphatide*a 1,2-diacyl-sn-glycero-3-phosphocholine*a phosphatidyl-N-trimethylethanolamine*a lecithin	C10 H19 N1 O8 R21 R11 P1 	C([N+1](C)(C)C)COP(=O)(O)OCC(OC(=O)[R1])COC([R2])=O	LIGAND-CPD:C00157*CAS:8002-43-5	3.1.4.4	a phosphatidylcholine + H2O  =  L-phosphatidate + choline	choline biosynthesis III
a phosphatidylcholine	acyl-glycerophosphocholine*a choline phosphatide*a 1,2-diacyl-sn-glycero-3-phosphocholine*a phosphatidyl-N-trimethylethanolamine*a lecithin	C10 H19 N1 O8 R21 R11 P1 	C([N+1](C)(C)C)COP(=O)(O)OCC(OC(=O)[R1])COC([R2])=O	LIGAND-CPD:C00157*CAS:8002-43-5	3.1.4.4	a phosphatidylcholine + H2O  =  L-phosphatidate + choline	lipases pathway
a phosphatidylcholine	acyl-glycerophosphocholine*a choline phosphatide*a 1,2-diacyl-sn-glycero-3-phosphocholine*a phosphatidyl-N-trimethylethanolamine*a lecithin	C10 H19 N1 O8 R21 R11 P1 	C([N+1](C)(C)C)COP(=O)(O)OCC(OC(=O)[R1])COC([R2])=O	LIGAND-CPD:C00157*CAS:8002-43-5	2.7.8.2	1,2-diacylglycerol + CDP-choline  =  a phosphatidylcholine + CMP	choline biosynthesis III
a phosphatidylcholine	acyl-glycerophosphocholine*a choline phosphatide*a 1,2-diacyl-sn-glycero-3-phosphocholine*a phosphatidyl-N-trimethylethanolamine*a lecithin	C10 H19 N1 O8 R21 R11 P1 	C([N+1](C)(C)C)COP(=O)(O)OCC(OC(=O)[R1])COC([R2])=O	LIGAND-CPD:C00157*CAS:8002-43-5	2.7.8.2	1,2-diacylglycerol + CDP-choline  =  a phosphatidylcholine + CMP	phospholipid biosynthesis
GA51	gibberellin A<sub>51</sub>*gibberellin A51*GA51	C19 H24 O5 	C=C1(C2(CC5(C1)([CH](CC2)C34(OC(=O)C(CC(O)C3)(C)[CH]4C5C(=O)O))))		1.14.11.-	GA51 + alpha-ketoglutarate + O2  =  GA51-catabolite + succinate + CO2 + H2O	gibberellin inactivation
GA51	gibberellin A<sub>51</sub>*gibberellin A51*GA51	C19 H24 O5 	C=C1(C2(CC5(C1)([CH](CC2)C34(OC(=O)C(CC(O)C3)(C)[CH]4C5C(=O)O))))		1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA51 + succinate + CO2	gibberellin inactivation
homogentisate		C8 H8 O4 	C(O)(=O)Cc1(c(O)ccc(O)c1)		RXN-2541	homogentisate + phytyl pyrophosphate  =  2-methyl-6-phytyl-1,4-benzoquinone + CO2 + pyrophosphate	vitamin E biosynthesis
homogentisate		C8 H8 O4 	C(O)(=O)Cc1(c(O)ccc(O)c1)		1.13.11.5	O2 + homogentisate  =  4-maleyl-acetoacetate	tyrosine degradation
homogentisate		C8 H8 O4 	C(O)(=O)Cc1(c(O)ccc(O)c1)		1.13.11.5	O2 + homogentisate  =  4-maleyl-acetoacetate	phenylalanine degradation
homogentisate		C8 H8 O4 	C(O)(=O)Cc1(c(O)ccc(O)c1)		RXN-2761	homogentisate + solanyl pyrophosphate  =  2-methyl-6-solanyl-1,4-benzoquinone + CO2 + pyrophosphate	plastoquinone biosynthesis
homogentisate		C8 H8 O4 	C(O)(=O)Cc1(c(O)ccc(O)c1)		1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	vitamin E biosynthesis
homogentisate		C8 H8 O4 	C(O)(=O)Cc1(c(O)ccc(O)c1)		1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	tyrosine degradation
homogentisate		C8 H8 O4 	C(O)(=O)Cc1(c(O)ccc(O)c1)		1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	plastoquinone biosynthesis
homogentisate		C8 H8 O4 	C(O)(=O)Cc1(c(O)ccc(O)c1)		1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	phenylalanine degradation
L-proline	2-pyrrolidinecarboxylic acid*P*proline*prol*pro	C5 H9 N1 O2 	C(=O)(O)[CH]1(CCCN1)	LIGAND:C00148*CAS:147-85-3	6.1.1.15	L-proline + tRNApro + ATP  =  L-prolyl-tRNApro + pyrophosphate + AMP	tRNA charging pathway
L-proline	2-pyrrolidinecarboxylic acid*P*proline*prol*pro	C5 H9 N1 O2 	C(=O)(O)[CH]1(CCCN1)	LIGAND:C00148*CAS:147-85-3	1.5.99.8	L-proline + acceptor  =  L-delta1-pyrroline-5-carboxylate + reduced acceptor	proline degradation
L-proline	2-pyrrolidinecarboxylic acid*P*proline*prol*pro	C5 H9 N1 O2 	C(=O)(O)[CH]1(CCCN1)	LIGAND:C00148*CAS:147-85-3	1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	proline biosynthesis
L-proline	2-pyrrolidinecarboxylic acid*P*proline*prol*pro	C5 H9 N1 O2 	C(=O)(O)[CH]1(CCCN1)	LIGAND:C00148*CAS:147-85-3	1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	arginine degradation II
ubiquinol-8	ubiquinol(8)	C49 H78 O4 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1(C(O)C(OC)=C(OC)C(O)C=1C)	LIGAND-CPD:C00390	1.6.5.3	ubiquinol-8 + NAD+  =  ubiquinone-8 + NADH	NAD/NADH phosphorylation and dephosphorylation
beta-L-fucose 1-phosphate	&beta;-L-fucose 1-phosphate*6-deoxy-L-galactose 1-phosphate	C6 H13 O8 P1 	CC1(OC(OP(O)(O)=O)C(O)C(O)C1O)		2.7.7.30	beta-L-fucose 1-phosphate + GTP  =  guanosine diphosphate fucose + pyrophosphate	GDP-L-fucose biosynthesis II (from L-fucose)
beta-L-fucose 1-phosphate	&beta;-L-fucose 1-phosphate*6-deoxy-L-galactose 1-phosphate	C6 H13 O8 P1 	CC1(OC(OP(O)(O)=O)C(O)C(O)C1O)		2.7.1.52	L-fucose + ATP  =  beta-L-fucose 1-phosphate + ADP	GDP-L-fucose biosynthesis II (from L-fucose)
1-(3-aminopropyl)-4-aminobutanal		C7 H16 N2 O1 	C(N)CCNCCCC=O		RXN-6424	1-(3-aminopropyl)-4-aminobutanal  =  1-(3-aminopropyl)-pyrrolinium + H2O	beta-alanine biosynthesis I
1-(3-aminopropyl)-4-aminobutanal		C7 H16 N2 O1 	C(N)CCNCCCC=O		1.5.3.11	spermine + O2 + H2O  =  1-(3-aminopropyl)-4-aminobutanal + 1,3-diaminopropane + H2O2	beta-alanine biosynthesis I
1,5-diazabicyclononane	1,5-diazabicyclo[4.3.0]nonane	C7 H14 N2 	C1(CCC2(N1CCCN2))		RXN-6425	1-(3-aminopropyl)-pyrrolinium  =  1,5-diazabicyclononane	beta-alanine biosynthesis I
1-(3-aminopropyl)-pyrrolinium		C7 H15 N2 	C(N)CC[N+1]1(CCCC=1)		RXN-6425	1-(3-aminopropyl)-pyrrolinium  =  1,5-diazabicyclononane	beta-alanine biosynthesis I
1-(3-aminopropyl)-pyrrolinium		C7 H15 N2 	C(N)CC[N+1]1(CCCC=1)		RXN-6424	1-(3-aminopropyl)-4-aminobutanal  =  1-(3-aminopropyl)-pyrrolinium + H2O	beta-alanine biosynthesis I
kaempferol-3-O-gentiobioside-7-O-rhamnoside	kaempferol-3-O-[glucopyranosyl(1-6)glucopyranoside]-7-O-rhamnopyranoside	C33 H40 O20 	C1(OC(C(O)C(O)C(O)1)COC2(OC(CO)C(O)C(O)C(O)2))Oc3(c(=O)c5(c(oc3c4(ccc(O)cc4))cc(cc(O)5)OC6(C(O)C(O)C(O)C(C)O6)))		RXN1F-444	kaempferol-3-glucoside-7-rhamnoside + UDP-D-glucose  =  kaempferol-3-O-gentiobioside-7-O-rhamnoside + UDP	flavonol biosynthesis
1-pyrroline		C4 H7 N1 	C1(CCC=N1)		RXN-6423	4-amino-butyraldehyde  =  1-pyrroline + H2O	beta-alanine biosynthesis I
trans-delta2-enoyl-acyl-ACP	trans-2,3-dehydroacyl-[acyl-carrier protein]*trans-2,3-dehydroacyl-ACP*CH3(CH2)xCH=CHCO-S-ACP*&alpha;,&beta;-trans-enoyl-ACP				4.2.1.60	D-3-hydroxy-acyl-ACP  =  trans-delta2-enoyl-acyl-ACP + H2O	fatty acid elongation -- saturated
trans-delta2-enoyl-acyl-ACP	trans-2,3-dehydroacyl-[acyl-carrier protein]*trans-2,3-dehydroacyl-ACP*CH3(CH2)xCH=CHCO-S-ACP*&alpha;,&beta;-trans-enoyl-ACP				1.3.1.10	NADPH + trans-delta2-enoyl-acyl-ACP  =  acyl-ACP + NADP+	fatty acid elongation -- saturated
trans-delta2-enoyl-acyl-ACP	trans-2,3-dehydroacyl-[acyl-carrier protein]*trans-2,3-dehydroacyl-ACP*CH3(CH2)xCH=CHCO-S-ACP*&alpha;,&beta;-trans-enoyl-ACP				1.3.1.9	NADH + trans-delta2-enoyl-acyl-ACP  =  acyl-ACP + NAD+	fatty acid elongation -- saturated
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.6.5.3	ubiquinol-8 + NAD+  =  ubiquinone-8 + NADH	NAD/NADH phosphorylation and dephosphorylation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.1	acetaldehyde + NADH  =  ethanol + NAD+	sucrose degradation to ethanol and lactate (anaerobic)
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.-	3-hydroxybutyryl-CoA + NAD+  =  acetoacetyl-CoA + NADH	lysine degradation II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.-	3-hydroxybutyryl-CoA + NAD+  =  acetoacetyl-CoA + NADH	tryptophan degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	2-AMINOMUCONATE-REDUCTASE-RXN	2-amino-muconate + 2 H2O + NADH  =  NH(4)OH + alpha-ketoadipate + NAD+	tryptophan degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.6.5.3	a ubiquinone + NADH  =  a ubiquinol + NAD+	aerobic respiration
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	2.7.1.86	NADH + ATP  =  NADPH + ADP	NAD/NADH phosphorylation and dephosphorylation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	purine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	salvage pathways of purine nucleosides
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.6.1.1	NAD+ + NADPH  =  NADH + NADP+	NAD/NADH phosphorylation and dephosphorylation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	3.1.3.-	NADPH + H2O  =  NADH + phosphate	NAD/NADH phosphorylation and dephosphorylation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.59	NAD+ + 3-hydroxy-propionate  =  NADH + malonate semialdehyde	beta-alanine biosynthesis II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.4.1.2	H2O + NAD+ + L-glutamate  =  NH3 + NADH + alpha-ketoglutarate	glutamate degradation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.3.1.43	NAD+ + L-arogenate  =  L-tyrosine + CO2 + NADH	tyrosine biosynthesis II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.5.1.9	H2O + NAD+ + saccharopine  =  NADH + allysine + L-glutamate	lysine degradation II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	ALLYSINE-DEHYDROG-RXN	H2O + allysine + NAD+  =  alpha-aminoadipate + NADH	lysine degradation II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	RXN-4466	a omega-oxo fatty acid + H2O + NAD+  =  a dicarboxylate + NADH	fatty acid omega-oxidation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid omega-oxidation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid alpha-oxidation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.145	campesterol + NAD+  =  campest-5-en-3-one + NADH	brassinosteroid biosynthesis III
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.32	H2O + NAD+ + 2-aminomuconate semialdehyde  =  NADH + 2-amino-muconate	tryptophan degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	lysine degradation II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	tryptophan degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.3.1.12	prephenate + NAD+  =  p-hydroxyphenylpyruvate + CO2 + NADH	tyrosine biosynthesis I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.19	4-amino-butyraldehyde + NAD+ + H2O  =  4-aminobutyrate + NADH	arginine degradation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	glutamate degradation II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	arginine degradation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	2KETO-4METHYL-PENTANOATE-DEHYDROG-RXN	2-keto-4-methyl-pentanoate + coenzyme A + NAD+  =  isovaleryl-CoA + CO2 + NADH	leucine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.255	NAD+ + mannitol  =  NADH + mannose	mannitol degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.178	NAD+ + 2-methyl-3-hydroxybutyryl-CoA  =  NADH + 2-methylaceto-acetyl-CoA	isoleucine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	2KETO-3METHYLVALERATE-RXN	2-keto-3-methyl-valerate + NAD+ + coenzyme A  =  2-methylbutyryl-CoA + NADH + CO2	isoleucine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.57	NADH + fructuronate  =  NAD+ + D-mannonate	beta-D-glucuronide degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.23	histidinol + NAD+  =  histidinal + NADH	histidine biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.27	NAD+ + coenzyme A + methylmalonate-semialdehyde  =  NADH + CO2 + propionyl-CoA	valine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.25	NAD+ + coenzyme A + 2-keto-isovalerate  =  NADH + CO2 + isobutyryl-CoA	valine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.35	NAD+ + L-3-hydroxyacyl-CoA  =  NADH + beta-ketoacyl-CoA	fatty acid beta-oxidation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	TCA cycle variation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	superpathway of glycolysis, pyruvate dehydrogenase, TCA, and glyoxylate bypass
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle variation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle -- aerobic respiration
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	ALPHA-KETOBUTYRATE-DEHYDROG-RXN	2-oxobutanoate + coenzyme A + NAD+  =  propionyl-CoA + CO2 + NADH	methionine degradation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.-	L-galactose + NAD+  =  L-galactono-1,4-lactone + NADH	ascorbate biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	TCA cycle variation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	superpathway of glyoxylate cycle
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	glyoxylate cycle
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	phenylalanine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	TCA cycle -- aerobic respiration
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	gluconeogenesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	TCA cycle variation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	gluconeogenesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	DIMETHUROPORDEHYDROG-RXN	dihydrosirohydrochlorin + NAD+  =  sirohydrochlorin + NADH	biosynthesis of proto- and siroheme
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.5.1.15	5,10-methylene-THF + NAD+  =  5,10-methenyl-THF + NADH	glycine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	photorespiration
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.23	histidinal + NAD+ + H2O  =  L-histidine + NADH	histidine biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	ammonia assimilation cycle
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	glutamate biosynthesis II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	purine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	ureide biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.31	NAD+ + 3-hydroxy-isobutyrate  =  NADH + methylmalonate-semialdehyde	valine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.27	NADH + pyruvate  =  NAD+ + lactate	sucrose degradation to ethanol and lactate (anaerobic)
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.3.1.9	NADH + trans-delta2-enoyl-acyl-ACP  =  acyl-ACP + NAD+	fatty acid elongation -- saturated
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	UDP-D-xylose biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	colanic acid building blocks biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	galactose degradation I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	sucrose degradation to ethanol and lactate (anaerobic)
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	gluconeogenesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glyceraldehyde 3-phosphate degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.29	NADH + hydroxypyruvate  =  NAD+ + glycerate	photorespiration
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.95	3-phosphoglycerate + NAD+  =  3-phospho-hydroxypyruvate + NADH	serine biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	purine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	salvage pathways of purine nucleosides
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	ureide biosynthesis
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides II
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides I
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.7.1.1	NO3- + NADH  =  NO2- + H2O + NAD+	nitrate assimilation pathway
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.103	L-threonine + NAD+  =  2-amino-3-oxobutanoate + NADH	threonine degradation
NADH	NADH<sub>2</sub>*NADH2*dihydrodiphosphopyridine nucleotide*diphosphopyridine nucleotide reduced*dihydronicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide reduced*NAD-reduced*NADH+H+*DPNH	C21 H29 N7 O14 P2 	C([CH]1(O[CH]([CH](O)[CH]1O)N2(C=C(C(=O)N)[CH2]C=C2)))OP(=O)(O)OP(=O)(O)OC[CH]3(O[CH]([CH](O)[CH](O)3)n4(c5(c(nc4)c(N)ncn5)))	LIGAND-CPD:C00004*CAS:53-84-9	1.1.1.85	2-D-threo-hydroxy-3-carboxy-isocaproate + NAD+  =  2-keto-4-methyl-pentanoate + NADH + CO2	leucine biosynthesis
nicotinate	3-pyridinecarboxylic acid*nicotinic acid*wampocap*nicolar*nicocap*nicobid*nico-400-*nicamin*niacin*niacine*vitamin B<SUB>3</SUB>	C6 H4 N1 O2 	c1(ccc(C([O-1])=O)cn1)	LIGAND:C00253*CAS:59-67-6	2.4.2.11	nicotinate + H2O + PRPP + ATP  =  nicotinate nucleotide + pyrophosphate + phosphate + ADP	pyridine nucleotide cycling
nicotinate	3-pyridinecarboxylic acid*nicotinic acid*wampocap*nicolar*nicocap*nicobid*nico-400-*nicamin*niacin*niacine*vitamin B<SUB>3</SUB>	C6 H4 N1 O2 	c1(ccc(C([O-1])=O)cn1)	LIGAND:C00253*CAS:59-67-6	3.5.1.4	nicotinamide + H2O  =  NH3 + nicotinate	aldoxime degradation
nicotinate	3-pyridinecarboxylic acid*nicotinic acid*wampocap*nicolar*nicocap*nicobid*nico-400-*nicamin*niacin*niacine*vitamin B<SUB>3</SUB>	C6 H4 N1 O2 	c1(ccc(C([O-1])=O)cn1)	LIGAND:C00253*CAS:59-67-6	3.5.1.19	nicotinamide + H2O  =  NH3 + nicotinate	pyridine nucleotide cycling
tRNAhis	TRNA(HIS)				6.1.1.21	tRNAhis + L-histidine + ATP  =  L-histidyl-tRNAhis + pyrophosphate + AMP	tRNA charging pathway
tRNApro	TRNA(PRO)				6.1.1.15	L-proline + tRNApro + ATP  =  L-prolyl-tRNApro + pyrophosphate + AMP	tRNA charging pathway
Fe2+	Fe<SUP>+2</SUP>*Fe<SUP>++</SUP>*ferrous iron*Fe+2*Fe2+	FE1 	[Fe+2]	LIGAND-CPD:C00023	4.99.1.1	Fe2+ + protoporphyrin IX  =  2 H+ + protoheme	biosynthesis of proto- and siroheme
Fe2+	Fe<SUP>+2</SUP>*Fe<SUP>++</SUP>*ferrous iron*Fe+2*Fe2+	FE1 	[Fe+2]	LIGAND-CPD:C00023	4.99.1.4	sirohydrochlorin + Fe2+  =  siroheme  + 2 H+	biosynthesis of proto- and siroheme
L-valine	V*val*valine	C5 H11 N1 O2 	CC(C)C(N)C(O)=O	LIGAND:C00183*CAS:72-18-4	6.1.1.9	tRNAval + L-valine + ATP  =  L-valyl-tRNAval + pyrophosphate + AMP	tRNA charging pathway
L-valine	V*val*valine	C5 H11 N1 O2 	CC(C)C(N)C(O)=O	LIGAND:C00183*CAS:72-18-4	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	pantothenate biosynthesis
L-valine	V*val*valine	C5 H11 N1 O2 	CC(C)C(N)C(O)=O	LIGAND:C00183*CAS:72-18-4	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	valine biosynthesis
L-valine	V*val*valine	C5 H11 N1 O2 	CC(C)C(N)C(O)=O	LIGAND:C00183*CAS:72-18-4	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	valine degradation
quercetin-3-glucoside	quercetin-3-O-&beta;-D-glucoside	C21 H20 O12 	C(O)C1(OC(C(O)C(O)C1O)Oc3(c(c2(cc(O)c(O)cc2))oc4(c(c3=O)c(O)cc(c4)O)))		2.4.1.91	quercetin + UDP-D-glucose  =  quercetin-3-glucoside + UDP	flavonol biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.12	trehalose 6-phosphate + H2O  =  trehalose + phosphate	trehalose biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.10	H2O + N10-formyl-THF  =  tetrahydrofolate + formate	formylTHF biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.1.1.39	H2O + CO2 + D-ribulose-1,5-bisphosphate  =  2 3-phosphoglycerate	Calvin cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.1.3	H2O + triacylglycerol  =  a fatty acid + 1,2-diacylglycerol	triacylglycerol degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.3.1	O-phospho-L-homoserine + H2O  =  phosphate + L-threonine	threonine biosynthesis from homoserine
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.4.1.11	L-methionine + H2O  =  NH3 + 2-oxobutanoate + methanethiol	methionine degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.7.1.1	NO3- + NADH  =  NO2- + H2O + NAD+	nitrate assimilation pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	ureide biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.3	3-phospho-serine + H2O  =  L-serine + phosphate	serine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.3	3-phospho-serine + H2O  =  L-serine + phosphate	glycine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.18	H2O + N-succinyl-L,L-2,6-diaminopimelate  =  L,L-diaminopimelate + succinate	lysine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.2.6	S-lactoyl-glutathione + H2O  =  glutathione + D-lactate	threonine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.2.6	S-lactoyl-glutathione + H2O  =  glutathione + D-lactate	methylglyoxal degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	SAM cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	ethylene biosynthesis from methionine
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	adenosylmethionine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine salvage pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.1.4	a phosphatidylcholine + H2O  =  1-acylglycerophosphocholine + a carboxylate	lipases pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	homocysteine and cysteine interconversion
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	methionine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	sulfate assimilation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.18	H2O + 2-phosphoglycolate  =  glycolate + phosphate	photorespiration
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	gluconeogenesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	glyceraldehyde 3-phosphate degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.4	H2O + L-phosphatidate  =  phosphate + 1,2-diacylglycerol	triacylglycerol biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.4	H2O + L-phosphatidate  =  phosphate + 1,2-diacylglycerol	phospholipid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.5	H2O + urea  =  2 NH3 + CO2	ureide degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.24	H2O + sucrose-6'-phosphate  =  sucrose + phosphate	sucrose biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.2.4	H2O + 3-hydroxy-isobutyryl-CoA  =  3-hydroxy-isobutyrate + coenzyme A	valine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.31	phosphoribosyl-ATP + H2O  =  phosphoribosyl-AMP + pyrophosphate	histidine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.19	phosphoribosyl-AMP + H2O  =  phosphoribosylformiminoAICAR-phosphate	histidine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	photorespiration
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	glycine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	UDP-D-xylose biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	colanic acid building blocks biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	galactose degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.11	fructose-1,6-bisphosphate + H2O  =  D-fructose-6-phosphate + phosphate	Calvin cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.11	fructose-1,6-bisphosphate + H2O  =  D-fructose-6-phosphate + phosphate	gluconeogenesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.7.1.2	H2O + 4-fumaryl-acetoacetate  =  fumarate + acetoacetate	tyrosine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.7.1.2	H2O + 4-fumaryl-acetoacetate  =  fumarate + acetoacetate	phenylalanine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.9	H2O + NADP+ + D-glyceraldehyde-3-phosphate  =  3-phosphoglycerate + NADPH	glycolysis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.6	AMP + H2O  =  IMP + NH3	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.6	AMP + H2O  =  IMP + NH3	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.5	H2O + deoxycytidine  =  NH3 + deoxyuridine	(deoxy)ribose phosphate degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.4.3.5	O2 + H2O + pyridoxamine 5'-phosphate  =  NH3 + H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.1.1.21	5-aminoimidazole ribonucleotide + ATP + CO2 + H2O  =  phosphate + phosphoribosyl-carboxy-aminoimidazole + ADP	de novo biosynthesis of purine nucleotides II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.4.2.11	nicotinate + H2O + PRPP + ATP  =  nicotinate nucleotide + pyrophosphate + phosphate + ADP	pyridine nucleotide cycling
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.25	3 H2O + GTP  =  pyrophosphate + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate + formate	riboflavin and FMN and FAD biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.10	phosphoribosyl-formamido-carboxamide  =  IMP + H2O	de novo biosynthesis of purine nucleotides II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.10	phosphoribosyl-formamido-carboxamide  =  IMP + H2O	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.1.2.11	H2O + 2-keto-isovalerate + 5,10-methylene-THF  =  2-dehydropantoate + tetrahydrofolate	pantothenate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	polyamine biosynthesis III
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	arginine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.17	methacrylyl-CoA + H2O  =  3-hydroxy-isobutyryl-CoA	valine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.1.31	D-glucono-delta-lactone-6-phosphate + H2O  =  6-phospho-D-gluconate	oxidative branch of the pentose phosphate pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.23	H2O + dUTP  =  pyrophosphate + dUMP	de novo biosynthesis of pyrimidine deoxyribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.1	L-asparagine + H2O  =  NH3 + L-aspartate	asparagine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.5.1.61	H2O + 4 porphobilinogen  =  4 NH3 + hydroxymethylbilane	chlorophyllide a biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.5.1.61	H2O + 4 porphobilinogen  =  4 NH3 + hydroxymethylbilane	biosynthesis of proto- and siroheme
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.3.1.1	S-adenosyl-homocysteine + H2O  =  homocysteine + adenosine	SAM cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.3.1.1	S-adenosyl-homocysteine + H2O  =  homocysteine + adenosine	methionine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.2.3	carbamoyl-L-aspartate  =  dihydroorotate + H2O	de novo biosynthesis of pyrimidine ribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	ureide biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.1	H2O + L-arginine  =  urea + L-ornithine	arginine degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.11	H2O + agmatine  =  urea + putrescine	spermine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.11	H2O + agmatine  =  urea + putrescine	polyamine biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.11	H2O + agmatine  =  urea + putrescine	polyamine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.12	H2O + agmatine  =  NH3 + N-carbamoylputrescine	polyamine biosynthesis III
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.12	H2O + agmatine  =  NH3 + N-carbamoylputrescine	arginine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.1.31	H2O + beta-D-glucuronide  =  glucuronate + an alcohol	beta-D-glucuronide degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.2.2	H2O + dihydrouracil  =  3-ureidopropionate	beta-alanine biosynthesis III
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.6	H2O + 3-ureidopropionate  =  NH3 + CO2 + beta-alanine	beta-alanine biosynthesis III
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.23	histidinal + NAD+ + H2O  =  L-histidine + NADH	histidine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.3.3.-	2-oxo-4-methylthiobutanoic acid + acetyl-CoA + H2O  =  2-(2'-methylthio)ethylmalic-acid + coenzyme A	homomethionine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.26	H2O + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate  =  5-amino-6-(5'-phosphoribosylamino)uracil + NH3	riboflavin and FMN and FAD biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RIBOPHOSPHAT-RXN	5-amino-6-(5'-phosphoribitylamino)uracil + H2O  =  5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + phosphate	riboflavin and FMN and FAD biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-742	5-aminoimidazole ribonucleotide + ATP + H2O + CO2  =  N5-carboxyaminoimidazole ribonucleotide + ADP + phosphate	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.14	H2O + nicotinamide mononucleotide  =  D-ribose-5-phosphate + nicotinamide	pyridine nucleotide cycling
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.5	H2O + NAD+  =  adenosine diphosphate ribose + nicotinamide	pyridine nucleotide cycling
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.19	nicotinamide + H2O  =  NH3 + nicotinate	pyridine nucleotide cycling
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.22	H2O + NAD+  =  nicotinamide mononucleotide + AMP	pyridine nucleotide cycling
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.42	nicotinamide mononucleotide + H2O  =  NH3 + nicotinate nucleotide	pyridine nucleotide cycling
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.99.2	reduced acceptor + CO2  =  acceptor + H2O + CO	carbon monoxide dehydrogenase pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	formylTHF biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	glycine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	formylTHF biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	carbon monoxide dehydrogenase pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2009	salicyloyl-CoA + H2O  =  salicylate + coenzyme A	salicylic acid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2005	benzoyl-CoA + H2O  =  benzoate + coenzyme A	salicylic acid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2002	(E)-cinnamoyl-CoA + H2O  =  hydroxycinnamoyl-CoA	salicylic acid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	TCA cycle variation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	glyoxylate cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	TCA cycle -- aerobic respiration
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1883	GDP-L-galactose + 2 H2O  =  L-galactose + GMP + phosphate	ascorbate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.1.4	a phosphatidylcholine + H2O  =  linolenate + a lysophosphatidylcholine	jasmonic acid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.37	H2O + D-sedoheptulose-1,7-bisphosphate  =  phosphate + D-sedoheptulose-7-phosphate	Calvin cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.1	H2O + pyrophosphate  =  2 phosphate	UDP-glucose conversion
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.3.1.117	H2O + L-2,3,4,5-tetrahydrodipicolinate + succinyl-CoA  =  N-succinyl-2-amino-6-ketopimelate + coenzyme A	lysine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	AMACETOXID-RXN	aminoacetone + H2O + O2  =  NH3 + methylglyoxal + H2O2	threonine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.8.7.1	3 reduced ferredoxin + SO3-2  =  H2O + oxidized ferredoxin + H2S	sulfate assimilation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.4.1.1	cystathionine + H2O  =  NH3 + 2-oxobutanoate + L-cysteine	homocysteine and cysteine interconversion
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.1.1.-	18-oxooleate + NADP+ + H2O  =  octadec-9-ene-1,18-dioic-acid + NADPH	suberin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	PROPIONYL-COA-CARBOXYLASE-RXN	propionyl-CoA + H2O + ATP + CO2  =  D-methylmalonyl-CoA + phosphate + ADP	methionine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	CYSTATHIONASE-RXN	cystathionine + H2O  =  L-cysteine + homoserine	methionine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.17	H2O + trans-delta2-enoyl-CoA  =  L-3-hydroxyacyl-CoA	fatty acid beta-oxidation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.15	L-histidinol-phosphate + H2O  =  histidinol + phosphate	histidine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.16	succinate semialdehyde + NADP+ + H2O  =  NADPH + succinate	arginine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.27	L-1-phosphatidylglycerol-phosphate + H2O  =  L-1-phosphatidyl-glycerol + phosphate	phospholipid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.4	H2O + allantoate  =  (S)-ureidoglycolate + urea	ureide degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.2.5	H2O + allantoin  =  allantoate	ureide biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.2.5	H2O + allantoin  =  allantoate	ureide degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.19	H2O + (S)-ureidoglycolate  =  2 NH3 + CO2 + glyoxylate	ureide degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.4.-	CDP + reduced glutaredoxin  =  dCDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.13	H2O + dCTP  =  NH3 + dUTP	de novo biosynthesis of pyrimidine deoxyribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.3.9	2 H2O + 2 allantoate  =  2 NH3 + O2 + 2 CO2 + 2 ureidoglycine	ureide degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1602	1,2-diacylglycerol + H2O  =  2-acylglycerol + a fatty acid	triacylglycerol degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.1.23	H2O + acylglycerol  =  a fatty acid + glycerol	triacylglycerol degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.4.4	a phosphatidylcholine + H2O  =  L-phosphatidate + choline	choline biosynthesis III
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.4.4	a phosphatidylcholine + H2O  =  L-phosphatidate + choline	lipases pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	UDPACYLGLCNACDEACETYL-RXN	UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine + H2O  =  UDP-3-O-(3-hydroxymyristoyl)glucosamine + acetate	lipid-A-precursor biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	LIPIDXSYNTHESIS-RXN	H2O + UDP-2,3-bis(3-hydroxymyristoyl)glucosamine  =  2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate + UMP	lipid-A-precursor biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.7.2	guanosine 5'-diphosphate,3'-diphosphate + H2O  =  pyrophosphate + GDP	ppGpp biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.40	H2O + guanosine 3'-diphosphate 5'-triphosphate  =  phosphate + guanosine 5'-diphosphate,3'-diphosphate	ppGpp biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.17	tiglyl-CoA + H2O  =  2-methyl-3-hydroxybutyryl-CoA	isoleucine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.1.4	(1-4-beta-D-glucan)(m+n) + H2O  =  (1-4-beta-D-glucan)(m) + (1-4-beta-D-glucan)(n)	cellulose biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	ureide biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.5.1	3-indoleacetonitrile + 2 H2O  =  NH3 + indole-3-acetate	IAA biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.4.3.6	tryptamine + H2O + O2  =  NH3 + indole acetaldehyde + H2O2	IAA biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.84	acrylonitrile + H2O  =  acrylamide	acrylonitrile degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.84	3-cyanopyridine + H2O  =  nicotinamide	aldoxime degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.4	nicotinamide + H2O  =  NH3 + nicotinate	aldoxime degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.4	acrylamide + H2O  =  NH3 + acrylate + H+	acrylonitrile degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	glutamate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	arginine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.4.3.10	O2 + H2O + putrescine  =  NH3 + H2O2 + 4-amino-butyraldehyde	arginine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.19	4-amino-butyraldehyde + NAD+ + H2O  =  4-aminobutyrate + NADH	arginine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.1.11	methylesterified 1,4-alpha-D-galacturonosyl + H2O  =  1,4-alpha-D-galacturonosyl + methanol	homogalacturonan degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1444	indolylmethyl-glucosinolate + H2O  =  indolylmethyl glucosinolate aglycone + beta-D-glucose	glucosinolate biosynthesis from tryptophan
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1065	9,10-epoxy-18-hydroxystearate + H2O  =  9,10,18-trihydroxystearate	cutin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.1.20	maltose + H2O  =  2 alpha-D-glucose	starch degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	PSII-RXN	2 H2O  =  4 H+ + 4 e- + O2	photosynthesis, light reaction
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.5	H2O + cytidine  =  NH3 + uridine	(deoxy)ribose phosphate degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	SULFOXTFER-RXN	polysulfide-glutathione complex + O2 + H2O  =  SO3-2 + polysulfide-glutathione complex + 2 H+	sulfur oxidation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	SO3OXTFER-RXN	SO3-2 + 2 oxidized cytochrome c + H2O  =  SO42- + 2 reduced cytochrome c + 2 H+	sulfur oxidation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2-AMINOMUCONATE-REDUCTASE-RXN	2-amino-muconate + 2 H2O + NADH  =  NH(4)OH + alpha-ketoadipate + NAD+	tryptophan degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.32	H2O + NAD+ + 2-aminomuconate semialdehyde  =  NADH + 2-amino-muconate	tryptophan degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.7.1.3	3-hydroxy-L-kynurenine + H2O  =  3-hydroxy-anthranilate + L-alanine	NAD biosynthesis II (from tryptophan)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.7.1.3	3-hydroxy-L-kynurenine + H2O  =  3-hydroxy-anthranilate + L-alanine	tryptophan degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.9	N-formylkynurenine + H2O  =  kynurenine + formate	NAD biosynthesis II (from tryptophan)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.9	N-formylkynurenine + H2O  =  kynurenine + formate	tryptophan degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4318	trans-zeatin riboside + H2O  =  trans-zeatin + D-ribose	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4317	isopentenyladenine + H2O  =  trans-zeatin + 2 H+	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4315	isopentenyl adenosine + H2O  =  isopentenyladenine + D-ribose	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4316	isopentenyl adenosine + H2O  =  trans-zeatin riboside + 2 H+	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4313	isopentenyladenosine-5'-monophosphate + H2O  =  isopentenyl adenosine + phosphate	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4314	trans-zeatin riboside monophosphate + H2O  =  trans-zeatin riboside + phosphate	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4311	isopentenyladenosine-5'-diphosphate + H2O  =  isopentenyladenosine-5'-monophosphate + phosphate	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4312	trans-zeatin riboside diphosphate + H2O  =  trans-zeatin riboside monophosphate + phosphate	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4310	trans-zeatin riboside triphosphate + H2O  =  trans-zeatin riboside diphosphate + phosphate	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4309	isopentenyladenosine-5'-triphosphate + H2O  =  isopentenyladenosine-5'-diphosphate + phosphate	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.99.12	trans-zeatin riboside + H2O + FAD  =  adenosine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.99.12	cis-zeatin + H2O + FAD  =  3-methyl-4-cis-hydroxy-2-butenal + adenine + FADH2	cytokinins degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.99.12	trans-zeatin + H2O + FAD  =  adenine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.99.12	isopentenyl adenosine + H2O + FAD  =  adenosine + 3-methyl-2-butenal + FADH2	cytokinins degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.99.12	isopentenyladenine + FAD + H2O  =  3-methyl-2-butenal + adenine + FADH2	cytokinins degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-5101	geranyl-PP + H2O  =  (-)-(4S)-alpha-terpineol + pyrophosphate	monoterpene biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.-	indole-3-acetyl-leu + H2O  =  indole-3-acetate + L-leucine	IAA biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.-	indole-3-acetyl-ala + H2O  =  indole-3-acetate + L-alanine	IAA biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid omega-oxidation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid alpha-oxidation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4466	a omega-oxo fatty acid + H2O + NAD+  =  a dicarboxylate + NADH	fatty acid omega-oxidation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.4.11	phosphatidyl-myo-inositol 4,5-biphosphate + H2O  =  1,2-diacylglycerol + inositol 1,4,5-trisphosphate	lipases pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.3.11	spermine + O2 + H2O  =  1-(3-aminopropyl)-4-aminobutanal + 1,3-diaminopropane + H2O2	beta-alanine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.2.1.3	3-aminopropionaldehyde + NAD(P)+ + H2O  =  beta-alanine + NAD(P)H	beta-alanine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.4.3.6	1,3-diaminopropane + H2O + O2  =  3-aminopropionaldehyde + NH3 + H2O2	beta-alanine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.99.6	H2O + acceptor + spermidine  =  reduced acceptor + 4-amino-butyraldehyde + 1,3-diaminopropane	beta-alanine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.1.26	sucrose + H2O  =  alpha-D-glucose + fructose	sucrose degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.22	H2O + mannitol-1-phosphate  =  phosphate + mannitol	mannitol biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.1.49	H2O + O-sinapoylcholine  =  choline + sinapate	sinapate ester biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-5647	phosphoryl-choline + H2O  =  choline + phosphate	choline biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.9	5,10-methenyl-H4PteGlun + H2O  =  10-formyl-H4PteGlun	tetrahydrofolate biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.-	dihydroneopterin triphosphate + H2O  =  dihydroneopterin phosphate + pyrophosphate	tetrahydrofolate biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.-	dihydroneopterin triphosphate + H2O  =  dihydroneopterin phosphate + pyrophosphate	tetrahydrofolate biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.-	dihydroneopterin phosphate + H2O  =  dihydro-neo-pterin + phosphate	tetrahydrofolate biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.6.1.-	dihydroneopterin phosphate + H2O  =  dihydro-neo-pterin + phosphate	tetrahydrofolate biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-6321	5,10-methenyl-THF + H2O  =  N5-formyl-H4F	formylTHF biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis II (from tryptophan)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis I (from aspartate)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	pyridine nucleotide cycling
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	R83-RXN	2-hydroxy-3-keto-5-methylthio-1-phosphopentene + H2O  =  1,2-dihydroxy-3-keto-5-methylthiopentene + phosphate	methionine salvage pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.16	H2O + 5'-methylthioadenosine  =  5-methylthioribose + adenine	methionine salvage pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	ALLYSINE-DEHYDROG-RXN	H2O + allysine + NAD+  =  alpha-aminoadipate + NADH	lysine degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.1.9	H2O + NAD+ + saccharopine  =  NADH + allysine + L-glutamate	lysine degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.1.8	NADPH + alpha-ketoglutarate + L-lysine  =  H2O + NADP+ + saccharopine	lysine degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.4.1.2	H2O + NAD+ + L-glutamate  =  NH3 + NADH + alpha-ketoglutarate	glutamate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.1.16	N-alpha-acetylornithine + H2O  =  L-ornithine + acetate	arginine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.5.7	acrylonitrile + 2 H2O  =  acrylate + NH3	acrylonitrile degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.5.1.12	L-delta1-pyrroline-5-carboxylate + NAD(P)+ + H2O  =  L-glutamate + NAD(P)H + H+	proline degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.17	acrylyl-CoA + H2O  =  3-hydroxypropionyl-CoA	beta-alanine biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN1F-152	beta-carotene + 2 H2O  =  zeaxanthin	carotenoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4308	isopentenyladenosine-5'-monophosphate + NADPH + H2O  =  trans-zeatin riboside monophosphate + NADP+	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4306	isopentenyladenosine-5'-diphosphate + NADPH + H2O  =  trans-zeatin riboside diphosphate + NADP+	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4304	isopentenyladenosine-5'-triphosphate + NADPH + H2O  =  trans-zeatin riboside triphosphate + NADP+	trans-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	carotenoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	xanthophyll cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	carotenoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	xanthophyll cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.6.1.1	ATP + protoporphyrin IX + Mg2+ + H2O  =  Mg-protoporphyrin + H+ + phosphate + ADP	chlorophyllide a biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.5.4	H2O + L-glutamine + L-aspartate + ATP  =  L-glutamate + L-asparagine + pyrophosphate + AMP	asparagine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.4.2	L-glutamine + H2O + UTP + ATP  =  CTP + phosphate + ADP + L-glutamate	de novo biosynthesis of pyrimidine ribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.5.1.-	protoheme + trans, trans-farnesyl diphosphate + H2O  =  heme O + pyrophosphate	biosynthesis of proto- and siroheme
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.2.4	3-hydroxypropionyl-CoA + H2O  =  3-hydroxy-propionate + coenzyme A	beta-alanine biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.4.1.3	NH3 + NAD(P)H + alpha-ketoglutarate  =  NAD(P)+ + H2O + L-glutamate	arginine biosynthesis III
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.8	phytate + H2O  =  D-myo-inositol (1,2,4,5,6)-pentakisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.26	phytate + H2O  =  D-myo-inositol (1,2,3,5,6) pentakisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7242	D-myo-inositol (1,2,3,5,6) pentakisphosphate + H2O  =  D-myo-inositol (1,2,5,6) tetrakisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7243	D-myo-inositol (1,2,4,5,6)-pentakisphosphate + H2O  =  D-myo-inositol (1,2,5,6) tetrakisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7244	D-myo-inositol (1,2,5,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,6) trisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7245	D-myo-inositol (1,2,6) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7246	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7246	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7247	D-myo-inositol (1,2,3,5,6) pentakisphosphate + H2O  =  D-myo-inositol (1,2,3,6) tetrakisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7248	D-myo-inositol (1,2,3,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,3) trisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7249	D-myo-inositol (1,2,3,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,6) trisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7250	D-myo-inositol (1,2,3) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7250	D-myo-inositol (1,2,3) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7252	D-myo-Inositol (1)-monophosphate + H2O  =  myo-inositol + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7253	D-myo-inositol (2) monophosphate + H2O  =  myo-inositol + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7251	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-Inositol (1)-monophosphate + phosphate	phytate degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7305	D-myo-inositol (2,4) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.26	H2O + phytate  =  phosphate + D-myo-inositol (1,2,3,4,5)-pentakisphosphate	phytate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7301	D-myo-inositol (1,2,3,4,5)-pentakisphosphate + H2O  =  D-myo-inositol (1,2,3,4) tetrakisphosphate + phosphate	phytate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7302	D-myo-inositol (1,2,3,4) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,3) trisphosphate + phosphate	phytate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7303	D-myo-inositol (1,2,3,4) tetrakisphosphate + H2O  =  D-myo-inositol (2,3,4) trisphosphate + phosphate	phytate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7304	D-myo-inositol (2,3,4) trisphosphate + H2O  =  D-myo-inositol (2,4) bisphosphate + phosphate	phytate degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.1.126	H2O + coniferin  =  coniferyl alcohol + beta-D-glucose	coniferin metabolism
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.-	NADPH + H2O  =  NADH + phosphate	NAD/NADH phosphorylation and dephosphorylation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.-	H2O + NADP+  =  NAD+ + phosphate	NAD/NADH phosphorylation and dephosphorylation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.5	AMP + H2O  =  adenosine + phosphate	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.1	guanosine + H2O  =  guanine + D-ribose	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.1	guanosine + H2O  =  guanine + D-ribose	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.3	H2O + guanine  =  NH3 + xanthine	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.3	H2O + guanine  =  NH3 + xanthine	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.15	H2O + guanosine  =  NH3 + xanthosine	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.15	H2O + guanosine  =  NH3 + xanthosine	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.5	GMP + H2O  =  guanosine + phosphate	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.5	GMP + H2O  =  guanosine + phosphate	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.1	xanthosine + H2O  =  xanthine + D-ribose	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.1	xanthosine + H2O  =  xanthine + D-ribose	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.2	inosine + H2O  =  hypoxanthine + D-ribose	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.2	inosine + H2O  =  hypoxanthine + D-ribose	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.5	IMP + H2O  =  inosine + phosphate	purine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.1.3.5	IMP + H2O  =  inosine + phosphate	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.2.2.7	H2O + adenosine  =  D-ribose + adenine	salvage pathways of purine nucleosides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4541	cis-zeatin riboside + H2O  =  cis-zeatin + D-ribose	cis-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4542	cis-zeatin riboside monophosphate + H2O  =  cis-zeatin riboside + phosphate	cis-zeatin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7679	7-hydroxy-chlorophyll a + H2O + NADP+  =  chlorophyll a + O2 + NADPH	chlorophyll cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7678	chlorophyll b + 2 H2O + NADP+  =  7-hydroxy-chlorophyll a + O2 + NADPH	chlorophyll cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7676	chlorophyllide a + O2 + NADPH  =  7-hydroxy-chlorophyllide a + H2O + NADP+	chlorophyll cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7677	7-hydroxy-chlorophyllide a + O2 + NADPH  =  chlorophyllide b + 2 H2O + NADP+	chlorophyll cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.76	UDP-D-glucose  =  H2O + UDP-4-dehydro-6-deoxy-D-glucose	UDP-L-rhamnose biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-5482	UDP-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+ + H2O	UDP-L-rhamnose biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.17	3-hydroxyacyl-CoA  =  trans-delta2-enoyl-CoA + H2O	very long chain fatty acid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7650	naringenin + NADPH + O2  =  apigenin + NADP+ + 2 H2O	luteolin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.21	apigenin + NADPH + O2  =  luteolin + NADP+ + H2O	luteolin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.21	naringenin + NADPH + O2  =  eriodictyol + NADP+ + H2O	luteolin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-7653	eriodictyol + NADPH + O2  =  luteolin + NADP+ + 2 H2O	luteolin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.22	naringenin + alpha-ketoglutarate + O2  =  apigenin + succinate + CO2 + H2O	luteolin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.22	eriodictyol + alpha-ketoglutarate + O2  =  luteolin + succinate + CO2 + H2O	luteolin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.81	131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  divinyl protochlorophyllide a + NADP+ + 2 H2O	chlorophyllide a biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.81	131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + 2 H2O	chlorophyllide a biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.81	Mg-protoporphyrin monomethyl ester + NADPH + H+ + O2  =  131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + H2O	chlorophyllide a biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.17.4	L-ascorbate + 1-aminocyclopropane-1-carboxylate + O2  =  2 H2O + ethene + L-dehydro-ascorbate + hydrogen cyanide + CO2	ethylene biosynthesis from methionine
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.-	GA8 + alpha-ketoglutarate + O2  =  GA8-catabolite + succinate + CO2 + H2O	gibberellin inactivation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.-	GA29 + alpha-ketoglutarate + O2  =  GA29-catabolite + succinate + CO2 + H2O	gibberellin inactivation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.-	GA51 + alpha-ketoglutarate + O2  =  GA51-catabolite + succinate + CO2 + H2O	gibberellin inactivation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.-	GA34 + alpha-ketoglutarate + O2  =  GA34-catabolite + succinate + CO2 + H2O	gibberellin inactivation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.-	GA37 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2 + H2O	gibberellin biosynthesis II (early C-3 hydroxylation)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.-	GA15 + O2 + alpha-ketoglutarate  =  GA24 + H2O + CO2 + succinate	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.78	ent-kaur-16-en-19-al + NADPH + H+ + O2  =  ent-kaurenoate + NADP+ + H2O	GA12 biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.78	ent-kaur-16-en-19-ol + NADPH + H+ + O2  =  ent-kaur-16-en-19-al + NADP+ + 2 H2O	GA12 biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.79	ent-kaurenoate + O2 + NADPH  =  ent-7-alpha-hydroxykaurenoate + H2O + NADP+	GA12 biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.13.99.1	O2 + myo-inositol  ->  H2O + glucuronate	inositol oxidation pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-5961	alpha-carotene + NADPH + O2  =  zeinoxanthin + NADP+ + H2O	carotenoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-5962	zeinoxanthin + NADPH + O2  =  lutein + NADP+ + H2O	carotenoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.3.1.170	coumaroyl-CoA + 3 malonyl-CoA + NADPH  =  isoliquiritigenin + 4 coenzyme A + 3 CO2 + NADP+ + H2O	flavonoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.19	leucocyanidin + alpha-ketoglutarate + O2  =  cyanidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.70	3 NADPH + 3 O2 + obtusifoliol + 3 H+  =  4 H2O + 3 NADP+ + formate + (4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol	sterol biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.-.-	campesterol + O2 + reduced acceptor  =  (22alpha)-hydroxy-campesterol + H2O + acceptor	brassinosteroid biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.-.-	campestanol + O2 + reduced acceptor  =  (6alpha)-hydroxycampestanol + H2O + acceptor	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.-.-	6-oxocampestanol + O2 + reduced acceptor  =  cathasterone + H2O + acceptor	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.-.-	cathasterone + O2 + reduced acceptor  =  teasterone + H2O + acceptor	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.-.-	typhasterol + O2 + reduced acceptor  =  castasterone + H2O + acceptor	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.4.3	2-C-methyl-D-erythritol-2,4-cyclodiphosphate + e- + H+  =  1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.3.3.4	1.5 O2 + protoporphyrinogen  =  3 H2O + protoporphyrin IX	chlorophyllide a biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.3.3.4	1.5 O2 + protoporphyrinogen  =  3 H2O + protoporphyrin IX	biosynthesis of proto- and siroheme
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.2.1.-	coenzyme A + L-carnitine  =  L-carnitinyl-CoA + H2O	carnitine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.2.-	coenzyme A + crotono-betaine  =  crotonobetainyl-CoA + H2O	carnitine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.3.2.-	coenzyme A + D-carnitine  =  D-carnitinyl-CoA + H2O	carnitine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	carotenoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	xanthophyll cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.78	ent-kaur-16-ene + O2 + NADPH  =  H2O + NADP+ + ent-kaur-16-en-19-ol	GA12 biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.-	E-pyridine-3-aldoxime  =  3-cyanopyridine + H2O	aldoxime degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.91	L-arogenate  =  CO2 + H2O + L-phenylalanine	phenylalanine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	R145-RXN	5-methylthioribulose-1-phosphate  =  2,3-diketo-5-methylthio-1-phosphopentane + H2O	methionine salvage pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-5721	2-amino-3-carboxymuconate semialdehyde  =  quinolinate + H2O	NAD biosynthesis II (from tryptophan)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-527	dihydroquercetin + alpha-ketoglutarate + O2  =  quercetin + succinate + CO2 + H2O	flavonol biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN1F-93	dihydrokaempferol + alpha-ketoglutarate + O2  =  kaempferol + succinate + CO2 + H2O	flavonol biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.79	ent-7-alpha-hydroxykaurenoate + NADPH + H+ + O2  =  GA12-aldehyde + NADP+ + 2 H2O	GA12 biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.79	GA12-aldehyde + NADPH + O2  =  GA12 + NADP+ + H2O	GA12 biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN1F-143	GA12 + O2  =  GA53 + H2O	gibberellin biosynthesis III (early C-13 hydroxylation)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-6423	4-amino-butyraldehyde  =  1-pyrroline + H2O	beta-alanine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-6424	1-(3-aminopropyl)-4-aminobutanal  =  1-(3-aminopropyl)-pyrrolinium + H2O	beta-alanine biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.-	L-phenylalanine + NADPH + O2  =  phenylacetaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from phenylalanine
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-884	1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + 2 H+  =  dimethylallyl-pyrophosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4122	a 2(R)-hydroperoxy fatty acid  =  a fatty aldehyde + CO2 + H2O	fatty acid alpha-oxidation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.11.1.11	2 L-ascorbate + H2O2  =  2 monodehydroascorbate + 2 H2O	ascorbate glutathione cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.10.3.3	L-ascorbate + O2  =  monodehydroascorbate + 2 H2O	ascorbate glutathione cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2944	indole-3-acetate + L-alanine  =  indole-3-acetyl-ala + H2O	IAA conjugate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2945	indole-3-acetate + L-leucine  =  indole-3-acetyl-leu + H2O	IAA conjugate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2946	indole-3-acetate + L-aspartate  =  indole-3-acetyl-asp + H2O	IAA conjugate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2947	indole-3-acetate + L-glutamate  =  indole-3-acetyl-glu + H2O	IAA conjugate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2948	indole-3-acetate + L-glutamine  =  indole-3-acetyl-gln + H2O	IAA conjugate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.11.19	leucopelargonidin + alpha-ketoglutarate + O2  =  pelargonidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.21	dihydrokaempferol + O2  =  dihydroquercetin + H2O	flavonol biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.21	dihydrokaempferol + O2  =  dihydroquercetin + H2O	anthocyanin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4231	campest-4-en-3-one + O2  =  22alpha-hydroxy-campest-4-en-3-one + H2O	brassinosteroid biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4230	5alpha-campestan-3-one + O2  =  22alpha-hydroxy-5alpha-campestan-3-one + H2O	brassinosteroid biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.99.7	O2 + reduced acceptor + squalene  =  (S)-2,3-Epoxysqualene + H2O + acceptor	sterol biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-773	campestanol + O2  =  6-deoxocathasterone + H2O	brassinosteroid biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-773	campestanol + O2  =  6-deoxocathasterone + H2O	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.-.-	6-deoxocathasterone + O2  =  6-deoxoteasterone + H2O	brassinosteroid biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.-.-	6-deoxocathasterone + O2  =  6-deoxoteasterone + H2O	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-777	6-deoxotyphasterol + O2  =  6-deoxocastasterone + H2O	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-778	6-deoxocastasterone + O2  =  6alpha-hydroxy-castasterone + H2O	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-4241	6-deoxotyphasterol + O2  =  typhasterol + H2O	brassinosteroid biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	NAD biosynthesis II (from tryptophan)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	tryptophan degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.55	H2O + crotonyl-CoA  =  3-hydroxybutyryl-CoA	lysine degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.55	H2O + crotonyl-CoA  =  3-hydroxybutyryl-CoA	tryptophan degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN1F-14	indole-S-cysteine-adduct  =  indole carboxyl tetrahydro-thiazole + H2O	camalexin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.-	palmitate + NADPH + O2  =  16-hydroxypalmitate + NADP+ + H2O	cutin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1062	16-hydroxypalmitate + NADPH + O2  =  10,16-dihydroxypalmitate + NADP+ + H2O	cutin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1064	18-hydroxyoleate + NADPH + O2  =  9,10-epoxy-18-hydroxystearate + NADP+ + H2O	cutin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.-	homomethionine + NADPH + O2  =  4-methylthiobutanaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from homomethionine
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.99.1.6	indole-3-acetaldoxime  =  3-indoleacetonitrile + H2O	IAA biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1405	tryptamine + O2 + NADPH  =  N-hydroxyl-tryptamine + H2O + NADP+	IAA biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.60	D-3-hydroxy-acyl-ACP  =  trans-delta2-enoyl-acyl-ACP + H2O	fatty acid elongation -- saturated
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.9	2,3-dihydroxy-3-methylvalerate  =  2-keto-3-methyl-valerate + H2O	isoleucine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.8	D-mannonate  =  H2O + 2-dehydro-3-deoxy-D-gluconate	beta-D-glucuronide degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	SPONTPRO-RXN	L-glutamate gamma-semialdehyde  =  H2O + L-delta1-pyrroline-5-carboxylate	proline biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	SPONTPRO-RXN	L-glutamate gamma-semialdehyde  =  H2O + L-delta1-pyrroline-5-carboxylate	arginine degradation II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.4.1	Reduced Thioredoxin + UDP  =  Oxidized Thioredoxin + dUDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.4.1	Reduced Thioredoxin + CDP  =  Oxidized Thioredoxin + dCDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.4.-	UDP + reduced glutaredoxin  =  dUDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-724	UTP + reduced flavodoxin  =  dUTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-723	CTP + reduced flavodoxin  =  dCTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.1.2	1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + 2 H+  =  delta3-isopentenyl-PP + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.18	H2O + trans-3-methylglutaconyl-CoA  =  3-hydroxy-3-methyl-glutaryl-CoA	leucine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.9	2,3-dihydroxy-isovalerate  =  2-keto-isovalerate + H2O	valine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.4.1.-	homoserine + H2O  =  2-oxobutanoate + NH4+ + H2O	methionine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.1.2.15	phosphoenolpyruvate + D-erythrose-4-phosphate + H2O  =  3-deoxy-D-arabino-heptulosonate-7-phosphate + phosphate	chorismate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	phenylpropanoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	suberin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	suberin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	cutin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.-	L-carnitinyl-CoA  =  H2O + crotonobetainyl-CoA	carnitine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-2382	indole + L-serine  =  L-tryptophan + H2O	tryptophan biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.92	13(S)-hydroperoxylinolenate  =  H2O + 12,13(S)-epoxylinolenate	jasmonic acid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.92	13(S)-hydroperoxylinolenate  =  H2O + 12,13(S)-epoxylinolenate	lipoxygenase pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.1.1.31	phosphate + oxaloacetate  =  phosphoenolpyruvate + H2O + CO2	gluconeogenesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	O-SUCCINYLBENZOATE-COA-SYN-RXN	2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate  =  O-succinylbenzoate + H2O	phylloquinone biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	O-SUCCINYLBENZOATE-COA-SYN-RXN	2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate  =  O-succinylbenzoate + H2O	menaquinone biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	6.2.1.-	trans-cinnamate + coenzyme A  =  (E)-cinnamoyl-CoA + H2O	salicylic acid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.-	benzoate + NADPH + O2  =  salicylate + NADP+ + H2O	salicylic acid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1142	coniferyl aldehyde + NADPH + O2  =  5-hydroxy-coniferaldehyde + NADP+ + H2O	lignin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.36	4-coumaroylshikimate + NADPH + O2  =  caffeoylshikimate + NADP+ + H2O	lignin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.36	4-coumaroylquinate + NADPH + O2  =  caffeoylquinate + NADP+ + H2O	lignin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.7.7.-	NO2- + reduced ferredoxin  =  NH3 + H2O + oxidized ferredoxin	nitrate assimilation pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.4.1	Reduced Thioredoxin + ADP  =  Oxidized Thioredoxin + dADP + H2O	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-745	ATP + reduced flavodoxin  =  dATP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-746	GTP + reduced flavodoxin  =  dGTP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-747	ADP + reduced glutaredoxin  =  dADP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN0-748	GDP + reduced glutaredoxin  =  dGDP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	carotenoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	xanthophyll cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.75	hydroxymethylbilane  =  uroporphyrinogen-III + H2O	chlorophyllide a biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.75	hydroxymethylbilane  =  uroporphyrinogen-III + H2O	biosynthesis of proto- and siroheme
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	QUINOLINATE-SYNTHA-RXN	iminoaspartate + dihydroxy-acetone-phosphate  =  quinolinate + 2 H2O + phosphate	NAD biosynthesis I (from aspartate)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.3.3.9	acetyl-CoA + H2O + glyoxylate  =  malate + coenzyme A	glyoxylate cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.1.3.5	acetoacetyl-CoA + H2O + acetyl-CoA  =  coenzyme A + 3-hydroxy-3-methyl-glutaryl-CoA	mevalonate pathway
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.13.1.1	UDP-D-glucose + SO3-2  =  UDP-sulfoquinovose + H2O	sulfolipid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	RXN-1121	ferulate + NADPH + O2  =  5-hydroxy-ferulic-acid + H2O + NADP+	phenylpropanoid biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.16	2 H2O + GTP  =  dihydroneopterin triphosphate + formate + H2O	tetrahydrofolate biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	3.5.4.16	2 H2O + GTP  =  dihydroneopterin triphosphate + formate + H2O	tetrahydrofolate biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.10	3-dehydroquinate  =  H2O + 3-dehydro-shikimate	chorismate biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.19	D-erythro-imidazole-glycerol-phosphate  =  imidazole acetol-phosphate + H2O	histidine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.52	pyruvate + L-aspartate-semialdehyde  =  2 H2O + L-2,3-dihydrodipicolinate	lysine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.17.4.1	Reduced Thioredoxin + GDP  =  Oxidized Thioredoxin + dGDP + H2O	de novo biosynthesis of purine nucleotides I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.3	citrate  =  cis-aconitate + H2O	TCA cycle variation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.3	citrate  =  cis-aconitate + H2O	glyoxylate cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.3	citrate  =  cis-aconitate + H2O	TCA cycle -- aerobic respiration
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	phenylpropanoid biosynthesis, initial reactions
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	suberin biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.1.1.48	1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-phosphate  =  indole-3-glycerol-phosphate + CO2 + H2O	tryptophan biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle variation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	glyoxylate cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle -- aerobic respiration
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.1.3.12	2-keto-isovalerate + acetyl-CoA + H2O  =  3-carboxy-3-hydroxy-isocaproate + coenzyme A	leucine biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	sucrose degradation to ethanol and lactate (anaerobic)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glycolysis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glycolysis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	gluconeogenesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glyceraldehyde 3-phosphate degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.2	fumarate + H2O  =  malate	TCA cycle variation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.2	fumarate + H2O  =  malate	superpathway of glyoxylate cycle
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.2	fumarate + H2O  =  malate	phenylalanine degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.2	fumarate + H2O  =  malate	TCA cycle -- aerobic respiration
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.24	2 5-amino-levulinate  =  2 H2O + porphobilinogen	chlorophyllide a biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.24	2 5-amino-levulinate  =  2 H2O + porphobilinogen	biosynthesis of proto- and siroheme
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	GDP-L-fucose biosynthesis I (from GDP-D-mannose)
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	colanic acid building blocks biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	GDP-D-rhamnose biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.46	dTDP-D-glucose  =  H2O + dTDP-4-dehydro-6-deoxy-D-glucose	dTDP-L-rhamnose biosynthesis
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.51	prephenate  =  phenylpyruvate + H2O + CO2	phenylalanine biosynthesis II
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.22	homocysteine + L-serine  =  H2O + cystathionine	homocysteine and cysteine interconversion
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.22	homocysteine + L-serine  =  H2O + cystathionine	methionine degradation I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	IAA biosynthesis I
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	glucosinolate biosynthesis from tryptophan
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.11.1.6	2 H2O2  =  2 H2O + O2	removal of superoxide radicals
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	4.2.1.1	H2O + CO2  =  H2CO3	cyanate degradation
H2O	H20*hydrogen oxide*water	H2 O1 	[OH2]	LIGAND-CPD:C00001*CAS:7732-18-5	1.9.3.1	O2 + 4 ferrocytochrome c  =  2 H2O + 4 ferricytochrome c	aerobic respiration
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle variation I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle -- aerobic respiration
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.42	NADPH + 12-oxo-cis-10,15-phytodienoate  =  NADP+ + 3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate	jasmonic acid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.169	2-dehydropantoate + NADPH  =  L-pantoate + NADP+	pantothenate biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	homoserine biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	lysine biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.3	NADPH + L-aspartate-semialdehyde  =  NADP+ + homoserine	homoserine biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.34	2 NADPH + 3-hydroxy-3-methyl-glutaryl-CoA  =  2 NADP+ + coenzyme A + mevalonate	mevalonate pathway
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.100	NADPH + beta-ketoacyl-ACP  =  D-3-hydroxy-acyl-ACP + NADP+	fatty acid elongation -- saturated
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.271	NADPH + GDP-4-dehydro-6-deoxy-D-mannose  =  NADP+ + guanosine diphosphate fucose	GDP-L-fucose biosynthesis I (from GDP-D-mannose)
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.9	H2O + NADP+ + D-glyceraldehyde-3-phosphate  =  3-phosphoglycerate + NADPH	glycolysis I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	formylTHF biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	formylTHF biosynthesis I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	tetrahydrofolate biosynthesis I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	tetrahydrofolate biosynthesis II
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.267	1-deoxy-D-xylulose 5-phosphate + NADPH  =  2-C-methyl-D-erythritol-4-phosphate + NADP+	isopentenyl diphosphate biosynthesis -- mevalonate-independent
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	formylTHF biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	formylTHF biosynthesis I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	carbon monoxide dehydrogenase pathway
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.43	NADPH + CO2  =  NADP+ + formate	carbon monoxide dehydrogenase pathway
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-2003	hydroxycinnamoyl-CoA + NADP+  =  oxocinnamoyl-CoA + NADPH	salicylic acid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	TCA cycle variation I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	gluconeogenesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.187	NADPH + GDP-4-dehydro-6-deoxy-D-mannose  =  NADP+ + GDP-D-rhamnose	GDP-D-rhamnose biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.-	18-oxooleate + NADP+ + H2O  =  octadec-9-ene-1,18-dioic-acid + NADPH	suberin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.-	18-hydroxyoleate + NADP+  =  18-oxooleate + NADPH	suberin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.25	NADPH + 3-dehydro-shikimate  =  NADP+ + shikimate	chorismate biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.16	succinate semialdehyde + NADP+ + H2O  =  NADPH + succinate	arginine degradation I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.10	NADPH + trans-delta2-enoyl-acyl-ACP  =  acyl-ACP + NADP+	fatty acid elongation -- saturated
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.219	NADPH + dihydrokaempferol  =  leucopelargonidin + NADP+	anthocyanin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.2	NADPH + uracil  =  NADP+ + dihydrouracil	beta-alanine biosynthesis III
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.224	NADPH + mannose-6-phosphate  =  NADP+ + mannitol-1-phosphate	mannitol biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.5.1.8	NADPH + alpha-ketoglutarate + L-lysine  =  H2O + NADP+ + saccharopine	lysine degradation II
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.43	L-arogenate + NADP+  =  L-tyrosine + NADPH + CO2	tyrosine biosynthesis II
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN1F-16	NADP+ + indole carboxyl hydro-thiazole  =  indole carboxyl thiazole + NADPH	camalexin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	carotenoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	xanthophyll cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	carotenoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	xanthophyll cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.8.1.7	glutathione disulfide + NADPH + H+  =  2 glutathione + NADP+	ascorbate glutathione cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	3.1.3.-	H2O + NADP+  =  NAD+ + phosphate	NAD/NADH phosphorylation and dephosphorylation
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-7679	7-hydroxy-chlorophyll a + H2O + NADP+  =  chlorophyll a + O2 + NADPH	chlorophyll cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-7678	chlorophyll b + 2 H2O + NADP+  =  7-hydroxy-chlorophyll a + O2 + NADPH	chlorophyll cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-7676	chlorophyllide a + O2 + NADPH  =  7-hydroxy-chlorophyllide a + H2O + NADP+	chlorophyll cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-7677	7-hydroxy-chlorophyllide a + O2 + NADPH  =  chlorophyllide b + 2 H2O + NADP+	chlorophyll cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.-	geranylgeranyl-chlorophyll a + NADPH  =  dihydrogeranylgeranyl-chlorophyll a + NADP+	chlorophyll a biosynthesis II
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.-	dihydrogeranylgeranyl-chlorophyll a + NADPH  =  tetrahydrogeranylgeranyl-chlorophyll a + NADP+	chlorophyll a biosynthesis II
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.-	tetrahydrogeranylgeranyl-chlorophyll a + NADPH  =  chlorophyll a + NADP+	chlorophyll a biosynthesis II
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-5481	UDP-4-dehydro-6-deoxy-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+	UDP-L-rhamnose biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-5482	UDP-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+ + H2O	UDP-L-rhamnose biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.36	beta-ketoacyl-CoA + NADPH  =  3-hydroxyacyl-CoA + NADP+	very long chain fatty acid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.38	trans-delta2-enoyl-CoA + NADPH  =  acyln+2-CoA + NADP+	very long chain fatty acid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.6.1.1	NAD+ + NADPH  =  NADH + NADP+	NAD/NADH phosphorylation and dephosphorylation
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-7650	naringenin + NADPH + O2  =  apigenin + NADP+ + 2 H2O	luteolin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.21	apigenin + NADPH + O2  =  luteolin + NADP+ + H2O	luteolin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.21	naringenin + NADPH + O2  =  eriodictyol + NADP+ + H2O	luteolin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-7653	eriodictyol + NADPH + O2  =  luteolin + NADP+ + 2 H2O	luteolin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.81	131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  divinyl protochlorophyllide a + NADP+ + 2 H2O	chlorophyllide a biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.81	131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + 2 H2O	chlorophyllide a biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.81	Mg-protoporphyrin monomethyl ester + NADPH + H+ + O2  =  131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + H2O	chlorophyllide a biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.78	ent-kaur-16-en-19-al + NADPH + H+ + O2  =  ent-kaurenoate + NADP+ + H2O	GA12 biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.78	ent-kaur-16-en-19-ol + NADPH + H+ + O2  =  ent-kaur-16-en-19-al + NADP+ + 2 H2O	GA12 biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.79	ent-kaurenoate + O2 + NADPH  =  ent-7-alpha-hydroxykaurenoate + H2O + NADP+	GA12 biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-5961	alpha-carotene + NADPH + O2  =  zeinoxanthin + NADP+ + H2O	carotenoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-5962	zeinoxanthin + NADPH + O2  =  lutein + NADP+ + H2O	carotenoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	2.3.1.170	coumaroyl-CoA + 3 malonyl-CoA + NADPH  =  isoliquiritigenin + 4 coenzyme A + 3 CO2 + NADP+ + H2O	flavonoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.70	3 NADPH + 3 O2 + obtusifoliol + 3 H+  =  4 H2O + 3 NADP+ + formate + (4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol	sterol biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.99.-	22alpha-hydroxy-campest-4-en-3-one + NADPH  =  22alpha-hydroxy-5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis II
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis III
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis II
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-4304	isopentenyladenosine-5'-triphosphate + NADPH + H2O  =  trans-zeatin riboside triphosphate + NADP+	trans-zeatin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-4306	isopentenyladenosine-5'-diphosphate + NADPH + H2O  =  trans-zeatin riboside diphosphate + NADP+	trans-zeatin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-4308	isopentenyladenosine-5'-monophosphate + NADPH + H2O  =  trans-zeatin riboside monophosphate + NADP+	trans-zeatin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN1F-10	monovinyl protochlorophyllide a + NADPH  =  NADP+ + chlorophyllide a	chlorophyllide a biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	carotenoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	xanthophyll cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.78	ent-kaur-16-ene + O2 + NADPH  =  H2O + NADP+ + ent-kaur-16-en-19-ol	GA12 biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	arginine biosynthesis III
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	proline biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.79	ent-7-alpha-hydroxykaurenoate + NADPH + H+ + O2  =  GA12-aldehyde + NADP+ + 2 H2O	GA12 biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.79	GA12-aldehyde + NADPH + O2  =  GA12 + NADP+ + H2O	GA12 biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-5461	dTDP-4-dehydro-6-deoxy-D-glucose + NADPH  =  dTDP-alpha-L-rhamnose + NADP+	dTDP-L-rhamnose biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.-	L-phenylalanine + NADPH + O2  =  phenylacetaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from phenylalanine
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.6.5.4	2 monodehydroascorbate + NADPH  =  2 L-ascorbate + NADP+	ascorbate glutathione cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.219	dihydroquercetin + NADPH  =  leucocyanidin + NADP+	anthocyanin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.70	(4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol + 2 NADPH  =  4alpha-methylfecosterol + 2 NADP+	sterol biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.21	5-dehydro episterol + 2 NADPH  =  24-methylenecholesterol + 2 NADP+	sterol biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.21	5-dehydroavenasterol + 2 NADPH  =  isofucosterol + 2 NADP+	sterol biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	NAD biosynthesis II (from tryptophan)
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	tryptophan degradation
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.-	palmitate + NADPH + O2  =  16-hydroxypalmitate + NADP+ + H2O	cutin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-1062	16-hydroxypalmitate + NADPH + O2  =  10,16-dihydroxypalmitate + NADP+ + H2O	cutin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-1064	18-hydroxyoleate + NADPH + O2  =  9,10-epoxy-18-hydroxystearate + NADP+ + H2O	cutin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.-	homomethionine + NADPH + O2  =  4-methylthiobutanaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from homomethionine
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-1405	tryptamine + O2 + NADPH  =  N-hydroxyl-tryptamine + H2O + NADP+	IAA biosynthesis I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.86	2-aceto-2-hydroxy-butyrate + NADPH  =  2,3-dihydroxy-3-methylvalerate + NADP+	isoleucine biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	phenylpropanoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	suberin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	suberin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	cutin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.-.-.-	GDP-4-dehydro-6-L-deoxygalactose + NADPH  =  guanosine diphosphate fucose + NADP+	colanic acid building blocks biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.-	benzoate + NADPH + O2  =  salicylate + NADP+ + H2O	salicylic acid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.44	coumaroyl-CoA + NADPH  =  coumaraldehyde + NADP+ + coenzyme A	lignin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.44	feruloyl-CoA + NADPH  =  coniferyl aldehyde + NADP+ + coenzyme A	lignin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.195	coumaraldehyde + NADPH  =  coumaryl-alcohol + NADP+	lignin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.195	sinapaldehyde + NADPH  =  sinapyl-alcohol + NADP+	lignin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-1142	coniferyl aldehyde + NADPH + O2  =  5-hydroxy-coniferaldehyde + NADP+ + H2O	lignin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.36	4-coumaroylshikimate + NADPH + O2  =  caffeoylshikimate + NADP+ + H2O	lignin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.36	4-coumaroylquinate + NADPH + O2  =  caffeoylquinate + NADP+ + H2O	lignin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.195	coniferyl aldehyde + NADPH  =  coniferyl alcohol + NADP+	lignin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.193	5-amino-6-(5'-phosphoribosylamino)uracil + NADPH  =  5-amino-6-(5'-phosphoribitylamino)uracil + NADP+	riboflavin and FMN and FAD biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	carotenoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	xanthophyll cycle
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.3.1.75	divinyl protochlorophyllide a + NADPH  =  monovinyl protochlorophyllide a + NADP+	chlorophyllide a biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	chlorophyllide a biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	biosynthesis of proto- and siroheme
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	RXN-1121	ferulate + NADPH + O2  =  5-hydroxy-ferulic-acid + H2O + NADP+	phenylpropanoid biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.1.1.86	2-acetolactate + NADPH  =  2,3-dihydroxy-isovalerate + NADP+	valine biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	phenylpropanoid biosynthesis, initial reactions
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	suberin biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis II (acetyl cycle)
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	2.7.1.23	NAD+ + ATP  =  NADP+ + ADP	NAD/NADH phosphorylation and dephosphorylation
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	IAA biosynthesis I
NADP+	coenzyme II*triphosphopyridine nucleotide*nicotinamide adenine dinucleotide phosphate*NADP-oxidized*NADP-ox*NADP+*TPN*TPN+*TPN-ox*nicotinamide adenine dinucleotide-P*NADP(+)*NADP	C21 H29 N7 O17 P3 	C(C1(OC(C(C(O)1)OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3))))OP(O)(=O)OP(=O)(O)OCC4(OC(C(O)C(O)4)[n+1]5(cc(C(N)=O)ccc5))	LIGAND-CPD:C00006*CAS:53-59-8	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	glucosinolate biosynthesis from tryptophan
urea	bromisovalum*carmol*basodexan*carbamide	C1 H4 N2 O1 	C(N)(N)=O	LIGAND:C00086*CAS:57-13-6	3.5.1.5	H2O + urea  =  2 NH3 + CO2	ureide degradation
urea	bromisovalum*carmol*basodexan*carbamide	C1 H4 N2 O1 	C(N)(N)=O	LIGAND:C00086*CAS:57-13-6	4.3.2.3	(S)-ureidoglycolate  =  urea + glyoxylate	ureide degradation
urea	bromisovalum*carmol*basodexan*carbamide	C1 H4 N2 O1 	C(N)(N)=O	LIGAND:C00086*CAS:57-13-6	3.5.3.4	H2O + allantoate  =  (S)-ureidoglycolate + urea	ureide degradation
urea	bromisovalum*carmol*basodexan*carbamide	C1 H4 N2 O1 	C(N)(N)=O	LIGAND:C00086*CAS:57-13-6	3.5.3.11	H2O + agmatine  =  urea + putrescine	spermine biosynthesis I
urea	bromisovalum*carmol*basodexan*carbamide	C1 H4 N2 O1 	C(N)(N)=O	LIGAND:C00086*CAS:57-13-6	3.5.3.11	H2O + agmatine  =  urea + putrescine	polyamine biosynthesis II
urea	bromisovalum*carmol*basodexan*carbamide	C1 H4 N2 O1 	C(N)(N)=O	LIGAND:C00086*CAS:57-13-6	3.5.3.11	H2O + agmatine  =  urea + putrescine	polyamine biosynthesis I
urea	bromisovalum*carmol*basodexan*carbamide	C1 H4 N2 O1 	C(N)(N)=O	LIGAND:C00086*CAS:57-13-6	3.5.3.1	H2O + L-arginine  =  urea + L-ornithine	arginine degradation II
GA34-catabolite	gibberellin A<sub>34</sub>-catabolite*gibberellin A34-catabolite*GA34-catabolite	C19 H22 O6 	CC1([CH]4(C(=CC(=O)C(O)1)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA34 + alpha-ketoglutarate + O2  =  GA34-catabolite + succinate + CO2 + H2O	gibberellin inactivation
spermine	gerontine*musculamine*neuridine*diaminopropyl-tetramethylenediamine	C10 H26 N4 	C(CCN)NCCCCNCCCN	CAS:71-44-3	1.5.3.11	spermine + O2 + H2O  =  1-(3-aminopropyl)-4-aminobutanal + 1,3-diaminopropane + H2O2	beta-alanine biosynthesis I
spermine	gerontine*musculamine*neuridine*diaminopropyl-tetramethylenediamine	C10 H26 N4 	C(CCN)NCCCCNCCCN	CAS:71-44-3	2.5.1.22	spermidine + S-adenosylmethioninamine  =  spermine + 5'-methylthioadenosine	spermine biosynthesis II
spermine	gerontine*musculamine*neuridine*diaminopropyl-tetramethylenediamine	C10 H26 N4 	C(CCN)NCCCCNCCCN	CAS:71-44-3	2.5.1.22	spermidine + S-adenosylmethioninamine  =  spermine + 5'-methylthioadenosine	spermine biosynthesis I
castasterone		C28 H48 O5 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)C(O)C4)(C))))		RXN-720	castasterone  =  brassinolide	brassinosteroid biosynthesis I
castasterone		C28 H48 O5 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)C(O)C4)(C))))		1.14.-.-	typhasterol + O2 + reduced acceptor  =  castasterone + H2O + acceptor	brassinosteroid biosynthesis I
castasterone		C28 H48 O5 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)C(O)C4)(C))))		RXN-779	6alpha-hydroxy-castasterone  =  castasterone	brassinosteroid biosynthesis I
carbamate		C1 H2 N1 O2 	C([O-1])(N)=O		4.3.99.1	HCO3- + cyanate  =  carbamate + CO2	cyanate degradation
GA44	gibberellin A<sub>44</sub> free alcohol form*GA<sub>44</sub> free alcohol form*gibberellin A<sub>44</sub> open lactone form*GA<sub>44</sub> open lactone form*GA44*gibberellin A44*gibberellin A<sub>44</sub>	C20 H28 O6 	CC1(C(O)=O)([CH]2(C(CO)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA38 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
GA44	gibberellin A<sub>44</sub> free alcohol form*GA<sub>44</sub> free alcohol form*gibberellin A<sub>44</sub> open lactone form*GA<sub>44</sub> open lactone form*GA44*gibberellin A44*gibberellin A<sub>44</sub>	C20 H28 O6 	CC1(C(O)=O)([CH]2(C(CO)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.12	GA44 + alpha-ketoglutarate + O2  =  GA19 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
GA44	gibberellin A<sub>44</sub> free alcohol form*GA<sub>44</sub> free alcohol form*gibberellin A<sub>44</sub> open lactone form*GA<sub>44</sub> open lactone form*GA44*gibberellin A44*gibberellin A<sub>44</sub>	C20 H28 O6 	CC1(C(O)=O)([CH]2(C(CO)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA98 + succinate + CO2	gibberellin inactivation
GA44	gibberellin A<sub>44</sub> free alcohol form*GA<sub>44</sub> free alcohol form*gibberellin A<sub>44</sub> open lactone form*GA<sub>44</sub> open lactone form*GA44*gibberellin A44*gibberellin A<sub>44</sub>	C20 H28 O6 	CC1(C(O)=O)([CH]2(C(CO)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA44 + CO2 + succinate	gibberellin biosynthesis III (early C-13 hydroxylation)
CMP-3-deoxy-D-manno-octulosonate	CMP-2-dehydro-3-deoxy-D-octonate*CMP-KDO	C17 H26 N3 O15 P1 	C(O)(=O)C(=O)CC(O)C(O)C(O)C(O)COP(=O)(O)OCC1(OC(C(O)C(O)1)n2(c(=O)nc(N)cc2))		2.-.-.-	lipid IV(A) + CMP-3-deoxy-D-manno-octulosonate  =  (KDO)-lipid IV(A) + CMP	lipid-A-precursor biosynthesis
CMP-3-deoxy-D-manno-octulosonate	CMP-2-dehydro-3-deoxy-D-octonate*CMP-KDO	C17 H26 N3 O15 P1 	C(O)(=O)C(=O)CC(O)C(O)C(O)C(O)COP(=O)(O)OCC1(OC(C(O)C(O)1)n2(c(=O)nc(N)cc2))		2.7.7.38	3-deoxy-D-manno-octulosonate + CTP  =  CMP-3-deoxy-D-manno-octulosonate + pyrophosphate	lipid-A-precursor biosynthesis
GA51-catabolite	gibberellin A<sub>51</sub>-catabolite*gibberellin A51-catabolite*GA51-catabolite	C19 H22 O5 	CC1([CH]4(C(=CC(=O)C1)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA51 + alpha-ketoglutarate + O2  =  GA51-catabolite + succinate + CO2 + H2O	gibberellin inactivation
alpha-ketoadipate	2-ketoadipate*2-oxoadipate*2-keto-adipate*2-oxohexanedionic acid	C6 H8 O5 	C(=O)(O)C(=O)CCCC(O)=O	CAS:3184-35-8	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	lysine degradation II
alpha-ketoadipate	2-ketoadipate*2-oxoadipate*2-keto-adipate*2-oxohexanedionic acid	C6 H8 O5 	C(=O)(O)C(=O)CCCC(O)=O	CAS:3184-35-8	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	tryptophan degradation
alpha-ketoadipate	2-ketoadipate*2-oxoadipate*2-keto-adipate*2-oxohexanedionic acid	C6 H8 O5 	C(=O)(O)C(=O)CCCC(O)=O	CAS:3184-35-8	2.6.1.39	alpha-ketoglutarate + alpha-aminoadipate  =  L-glutamate + alpha-ketoadipate	lysine degradation II
alpha-ketoadipate	2-ketoadipate*2-oxoadipate*2-keto-adipate*2-oxohexanedionic acid	C6 H8 O5 	C(=O)(O)C(=O)CCCC(O)=O	CAS:3184-35-8	2-AMINOMUCONATE-REDUCTASE-RXN	2-amino-muconate + 2 H2O + NADH  =  NH(4)OH + alpha-ketoadipate + NAD+	tryptophan degradation
dUDP	2'-deoxyuridine-5'-diphosphate*deoxyuridine-diphosphate	C9 H14 N2 O11 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(=O)(O)OP(O)(O)=O))		2.7.4.6	dUDP + ATP  =  dUTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dUDP	2'-deoxyuridine-5'-diphosphate*deoxyuridine-diphosphate	C9 H14 N2 O11 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(=O)(O)OP(O)(O)=O))		1.17.4.1	Reduced Thioredoxin + UDP  =  Oxidized Thioredoxin + dUDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
dUDP	2'-deoxyuridine-5'-diphosphate*deoxyuridine-diphosphate	C9 H14 N2 O11 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(=O)(O)OP(O)(O)=O))		1.17.4.-	UDP + reduced glutaredoxin  =  dUDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
mevalonate-5P	(R)-5-Phosphomevalonic acid*mevalonate-5-phosphate*(R)-5-Phosphomevalonate*(R)-Mevalonic acid 5-phosphate*(R)-5-Phosphomevaloonic acid*mevalonate-5-P*mevalonate-P*P-mevalonate*5-phosphomevalonate	C6 H13 O7 P1 	CC(O)(CC(O)=O)CCOP(O)(O)=O	CAS:73566-35-5	2.7.4.2	mevalonate-5P + ATP  =  mevalonate-5-PP + ADP	mevalonate pathway
mevalonate-5P	(R)-5-Phosphomevalonic acid*mevalonate-5-phosphate*(R)-5-Phosphomevalonate*(R)-Mevalonic acid 5-phosphate*(R)-5-Phosphomevaloonic acid*mevalonate-5-P*mevalonate-P*P-mevalonate*5-phosphomevalonate	C6 H13 O7 P1 	CC(O)(CC(O)=O)CCOP(O)(O)=O	CAS:73566-35-5	2.7.1.36	mevalonate + ATP  =  mevalonate-5P + ADP	mevalonate pathway
O2-	peroxide radical*O<SUB>2</SUB><SUP>(.-)</SUP>*super oxide	O2 	O=[O-1]		1.15.1.1	2 O2- + 2 H+  =  H2O2 + O2	removal of superoxide radicals
H2CO3	carbonic acid	C1 H2 O3 	C(=O)(O)O	CAS:463-79-6	4.2.1.1	H2O + CO2  =  H2CO3	cyanate degradation
maltose	&beta;-maltose*maltitol	C12 H22 O11 	C1(OC(CO)C(O)C(O)C(O)1)OC2(C(CO)OC(O)C(O)C(O)2)	CAS:69-79-4	3.2.1.20	maltose + H2O  =  2 alpha-D-glucose	starch degradation
maltose	&beta;-maltose*maltitol	C12 H22 O11 	C1(OC(CO)C(O)C(O)C(O)1)OC2(C(CO)OC(O)C(O)C(O)2)	CAS:69-79-4	3.2.1.2	Long-linear-glucans  =  maltose	starch degradation
iminoaspartate	&alpha;-iminosuccinate	C4 H5 N1 O4 	C(=O)(O)C(=N)CC(O)=O		QUINOLINATE-SYNTHA-RXN	iminoaspartate + dihydroxy-acetone-phosphate  =  quinolinate + 2 H2O + phosphate	NAD biosynthesis I (from aspartate)
iminoaspartate	&alpha;-iminosuccinate	C4 H5 N1 O4 	C(=O)(O)C(=N)CC(O)=O		1.4.3.-	O2 + L-aspartate  =  H2O2 + iminoaspartate	NAD biosynthesis I (from aspartate)
4-amino-butyraldehyde	4-aminobutanal*&gamma;-aminobutyraldehyde*4-aminobutyraldehyde	C4 H9 N1 O1 	C(=O)CCCN	CAS:4390-05-0	1.2.1.19	4-amino-butyraldehyde + NAD+ + H2O  =  4-aminobutyrate + NADH	arginine degradation I
4-amino-butyraldehyde	4-aminobutanal*&gamma;-aminobutyraldehyde*4-aminobutyraldehyde	C4 H9 N1 O1 	C(=O)CCCN	CAS:4390-05-0	RXN-6423	4-amino-butyraldehyde  =  1-pyrroline + H2O	beta-alanine biosynthesis I
4-amino-butyraldehyde	4-aminobutanal*&gamma;-aminobutyraldehyde*4-aminobutyraldehyde	C4 H9 N1 O1 	C(=O)CCCN	CAS:4390-05-0	1.5.99.6	H2O + acceptor + spermidine  =  reduced acceptor + 4-amino-butyraldehyde + 1,3-diaminopropane	beta-alanine biosynthesis I
4-amino-butyraldehyde	4-aminobutanal*&gamma;-aminobutyraldehyde*4-aminobutyraldehyde	C4 H9 N1 O1 	C(=O)CCCN	CAS:4390-05-0	1.4.3.10	O2 + H2O + putrescine  =  NH3 + H2O2 + 4-amino-butyraldehyde	arginine degradation I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.10	S-aminomethyldihydrolipoyl-GcvH-protein + tetrahydrofolate  =  NH3 + dihydrolipoyl-GcvH-protein + 5,10-methylene-THF	glycine degradation
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	glycine degradation
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	carbon monoxide dehydrogenase pathway
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	formylTHF biosynthesis
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	formylTHF biosynthesis I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	tetrahydrofolate biosynthesis I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	1.5.1.3	NADPH + 7,8-dihydrofolate  =  NADP+ + tetrahydrofolate	tetrahydrofolate biosynthesis II
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	photorespiration
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	6.3.2.17	tetrahydrofolate + L-glutamate + ATP  =  THF-L-glutamate + ADP + phosphate	tetrahydrofolate biosynthesis I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.1.13	homocysteine + 5-methyl-THF  =  L-methionine + tetrahydrofolate	formylTHF biosynthesis
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.1.14	5-methyl-THF + homocysteine  =  tetrahydrofolate + L-methionine	SAM cycle
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.1.14	5-methyl-THF + homocysteine  =  tetrahydrofolate + L-methionine	formylTHF biosynthesis I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.11	H2O + 2-keto-isovalerate + 5,10-methylene-THF  =  2-dehydropantoate + tetrahydrofolate	pantothenate biosynthesis
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.3	N10-formyl-THF + AICAR  =  tetrahydrofolate + phosphoribosyl-formamido-carboxamide	de novo biosynthesis of purine nucleotides II
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.3	N10-formyl-THF + AICAR  =  tetrahydrofolate + phosphoribosyl-formamido-carboxamide	de novo biosynthesis of purine nucleotides I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis I
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	photorespiration
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	glycine biosynthesis
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.1.-	5-methyl-THF + [Co-E]  =  tetrahydrofolate + [Co-E-CH3]	carbon monoxide dehydrogenase pathway
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	3.5.1.10	H2O + N10-formyl-THF  =  tetrahydrofolate + formate	formylTHF biosynthesis
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.2	N10-formyl-THF + 5-phospho-ribosyl-glycineamide  =  tetrahydrofolate + 5'-phosphoribosyl-N-formylglycineamide	de novo biosynthesis of purine nucleotides II
tetrahydrofolate	H4PteGlu*5,6,7,8-tetrahydrofolic acid*tetrahydrofolic acid*(6S)-tetrahydrofolate*H<sub>4</sub>PteGlu<sub>1</sub>*tetrahydropteroyl mono-L-glutamate*tetrahydrafolate*5,6,7,8-tetrahydrofolate*THF*tetra-H-folate*th-folate*FH4*folate-H4*tetrahydropteroylglutamate*H4F	C19 H23 N7 O6 	C2([CH](Nc1(c(=O)[nH]c(N)nc1N2))C[NH]c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	LIGAND-CPD:C00101*CAS:135-16-0*CAS:29347-89-5	2.1.2.2	N10-formyl-THF + 5-phospho-ribosyl-glycineamide  =  tetrahydrofolate + 5'-phosphoribosyl-N-formylglycineamide	de novo biosynthesis of purine nucleotides I
L,L-diaminopimelate	L,L-A2pm*L,L-DAP*L,L-2,6-diaminopimelate*L,L-2,6-diaminoheptanedioate	C7 H14 N2 O4 	C(O)(=O)C(N)CCCC(N)C(=O)O	CAS:14289-34-0	5.1.1.7	L,L-diaminopimelate  =  meso-diaminopimelate	lysine biosynthesis
L,L-diaminopimelate	L,L-A2pm*L,L-DAP*L,L-2,6-diaminopimelate*L,L-2,6-diaminoheptanedioate	C7 H14 N2 O4 	C(O)(=O)C(N)CCCC(N)C(=O)O	CAS:14289-34-0	3.5.1.18	H2O + N-succinyl-L,L-2,6-diaminopimelate  =  L,L-diaminopimelate + succinate	lysine biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	GDP-L-fucose biosynthesis I (from GDP-D-mannose)
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	colanic acid building blocks biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	GDP-D-rhamnose biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	2.4.1.83	dolichyl-phosphate + GDP-mannose  =  dolichyl beta-D-mannosyl phosphate + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	5.1.3.18	GDP-mannose  =  GDP-L-galactose	ascorbate biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	2.4.1.142	(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	RXN-5463	(mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP-mannose  =  (mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	RXN-5465	(mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  (mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	RXN-5464	(mannosyl)3-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP-mannose  =  (mannosyl)4-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	2.4.1.132	mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  (mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP	dolichyl-diphosphooligosaccharide biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	2.7.7.22	mannose-1-phosphate + GDP  =  GDP-mannose + phosphate	colanic acid building blocks biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	2.7.7.22	mannose-1-phosphate + GDP  =  GDP-mannose + phosphate	GDP-D-rhamnose biosynthesis
GDP-mannose	GDP-mannose*guanosine pyrophosphate mannose*guanosine diphosphomannose*guanosine diphosphate mannose*GDP-D-mannose	C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))	CAS:18441-12-8*CAS:3123-67-9	2.7.7.13	mannose-1-phosphate + GTP  =  GDP-mannose + pyrophosphate	ascorbate biosynthesis
homoserine	homo-ser*L-homoserine	C4 H9 N1 O3 	C(O)(=O)[CH](N)CCO	LIGAND:C00263*CAS:498-19-1	1.1.1.3	NADPH + L-aspartate-semialdehyde  =  NADP+ + homoserine	homoserine biosynthesis
homoserine	homo-ser*L-homoserine	C4 H9 N1 O3 	C(O)(=O)[CH](N)CCO	LIGAND:C00263*CAS:498-19-1	2.7.1.39	homoserine + ATP  =  O-phospho-L-homoserine + ADP	threonine biosynthesis from homoserine
homoserine	homo-ser*L-homoserine	C4 H9 N1 O3 	C(O)(=O)[CH](N)CCO	LIGAND:C00263*CAS:498-19-1	2.7.1.39	homoserine + ATP  =  O-phospho-L-homoserine + ADP	methionine biosynthesis
homoserine	homo-ser*L-homoserine	C4 H9 N1 O3 	C(O)(=O)[CH](N)CCO	LIGAND:C00263*CAS:498-19-1	4.4.1.-	homoserine + H2O  =  2-oxobutanoate + NH4+ + H2O	methionine degradation I
homoserine	homo-ser*L-homoserine	C4 H9 N1 O3 	C(O)(=O)[CH](N)CCO	LIGAND:C00263*CAS:498-19-1	CYSTATHIONASE-RXN	cystathionine + H2O  =  L-cysteine + homoserine	methionine degradation I
3-deoxy-D-manno-octulosonate	deoxy-manno-octulosonate*2-dehydro-3-deoxy-D-octonate*KDO	C8 H14 O8 	C(O)(=O)C(=O)CC(O)C(O)C(O)C(O)CO		2.7.7.38	3-deoxy-D-manno-octulosonate + CTP  =  CMP-3-deoxy-D-manno-octulosonate + pyrophosphate	lipid-A-precursor biosynthesis
demethylmenaquinone-8	DMK-8*demethylmenaquinone	C50 H70 O2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1(C(=O)c2(c(C(C=1)=O)cccc2))		ADOMET-DMK-METHYLTRANSFER-RXN	demethylmenaquinone-8 + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + menaquinone-8	menaquinone biosynthesis
demethylmenaquinone-8	DMK-8*demethylmenaquinone	C50 H70 O2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1(C(=O)c2(c(C(C=1)=O)cccc2))		DMK-RXN	1,4-dihydroxy-2-naphthoate + octaprenyl diphosphate  =  demethylmenaquinone-8 + pyrophosphate + CO2	menaquinone biosynthesis
3-deoxy-D-arabino-heptulosonate-7-phosphate	3-deoxy-D-arabino-heptulosonate-7-P*3-deoxy-arabino-heptulosonate 7-phosphate*3-deoxy-arabino-heptulosonate-7-P*2-dehydro-3-deoxy-D-arabino-heptonate 7-phosphate	C7 H13 O10 P1 	C(=O)(O)C(=O)CC(O)C(O)C(O)COP(O)(=O)O	CAS:2627-73-8	4.2.3.4	3-deoxy-D-arabino-heptulosonate-7-phosphate  =  phosphate + 3-dehydroquinate	chorismate biosynthesis
3-deoxy-D-arabino-heptulosonate-7-phosphate	3-deoxy-D-arabino-heptulosonate-7-P*3-deoxy-arabino-heptulosonate 7-phosphate*3-deoxy-arabino-heptulosonate-7-P*2-dehydro-3-deoxy-D-arabino-heptonate 7-phosphate	C7 H13 O10 P1 	C(=O)(O)C(=O)CC(O)C(O)C(O)COP(O)(=O)O	CAS:2627-73-8	4.1.2.15	phosphoenolpyruvate + D-erythrose-4-phosphate + H2O  =  3-deoxy-D-arabino-heptulosonate-7-phosphate + phosphate	chorismate biosynthesis
dTDP-alpha-L-rhamnose	dTDP-6-deoxy-L-mannose*dTDP-L-rhamnose*dTDP-rhamnose	C16 H26 N2 O15 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)C)))		RXN1F-475	kaempferol-3-rhamnoside + dTDP-alpha-L-rhamnose  =  kaempferol-3-rhamnoside-7-rhamnoside + dTDP	flavonol biosynthesis
dTDP-alpha-L-rhamnose	dTDP-6-deoxy-L-mannose*dTDP-L-rhamnose*dTDP-rhamnose	C16 H26 N2 O15 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)C)))		RXN1F-474	kaempferol + dTDP-alpha-L-rhamnose  =  kaempferol-3-rhamnoside + dTDP	flavonol biosynthesis
dTDP-alpha-L-rhamnose	dTDP-6-deoxy-L-mannose*dTDP-L-rhamnose*dTDP-rhamnose	C16 H26 N2 O15 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)C)))		RXN1F-443	kaempferol-3-glucoside + dTDP-alpha-L-rhamnose  =  kaempferol-3-glucoside-7-rhamnoside + dTDP	flavonol biosynthesis
dTDP-alpha-L-rhamnose	dTDP-6-deoxy-L-mannose*dTDP-L-rhamnose*dTDP-rhamnose	C16 H26 N2 O15 P2 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)C)))		RXN-5461	dTDP-4-dehydro-6-deoxy-D-glucose + NADPH  =  dTDP-alpha-L-rhamnose + NADP+	dTDP-L-rhamnose biosynthesis
4-coumaroylquinate	trans-(p-coumaroyl)-quinate*trans-5-O-(4-coumaroyl)quinate	C16 H18 O8 	C(=O)(OC1(C(O)C(O)CC(O)(C1)C(O)=O))C=Cc2(ccc(O)cc2)		1.14.13.36	4-coumaroylquinate + NADPH + O2  =  caffeoylquinate + NADP+ + H2O	lignin biosynthesis
4-coumaroylquinate	trans-(p-coumaroyl)-quinate*trans-5-O-(4-coumaroyl)quinate	C16 H18 O8 	C(=O)(OC1(C(O)C(O)CC(O)(C1)C(O)=O))C=Cc2(ccc(O)cc2)		2.3.1.133	quinate + coumaroyl-CoA  =  4-coumaroylquinate + coenzyme A	lignin biosynthesis
mevalonate-5-PP	mevalonate-diphosphate*(R)-5-Diphosphomevalonate	C6 H14 O10 P2 	CC(CC(=O)O)(O)CCOP(O)(=O)OP(O)(=O)O	CAS:4872-34-8	4.1.1.33	mevalonate-5-PP + ATP  =  phosphate + CO2 + delta3-isopentenyl-PP + ADP	mevalonate pathway
mevalonate-5-PP	mevalonate-diphosphate*(R)-5-Diphosphomevalonate	C6 H14 O10 P2 	CC(CC(=O)O)(O)CCOP(O)(=O)OP(O)(=O)O	CAS:4872-34-8	2.7.4.2	mevalonate-5P + ATP  =  mevalonate-5-PP + ADP	mevalonate pathway
sirohydrochlorin	Precorrin	C42 H46 N4 O16 	CC1(CC(O)=O)(C5(N=C(C1CCC(O)=O)C=C2(NC(C(C(C)2CC(O)=O)CCC(O)=O)=CC3(=NC(C(=C3CC(O)=O)CCC(O)=O)=Cc4(c(c(c(n4)C=5)CC(O)=O)CCC(O)=O)))))	CAS:65207-12-7	4.99.1.4	sirohydrochlorin + Fe2+  =  siroheme  + 2 H+	biosynthesis of proto- and siroheme
sirohydrochlorin	Precorrin	C42 H46 N4 O16 	CC1(CC(O)=O)(C5(N=C(C1CCC(O)=O)C=C2(NC(C(C(C)2CC(O)=O)CCC(O)=O)=CC3(=NC(C(=C3CC(O)=O)CCC(O)=O)=Cc4(c(c(c(n4)C=5)CC(O)=O)CCC(O)=O)))))	CAS:65207-12-7	DIMETHUROPORDEHYDROG-RXN	dihydrosirohydrochlorin + NAD+  =  sirohydrochlorin + NADH	biosynthesis of proto- and siroheme
L-threonine	T*thr*thre*L-thr*threonine*2-amino-3-hydroxybutyric acid	C4 H9 N1 O3 	CC(O)C(N)C(=O)O	LIGAND:C00188*CAS:72-19-5	1.1.1.103	L-threonine + NAD+  =  2-amino-3-oxobutanoate + NADH	threonine degradation
L-threonine	T*thr*thre*L-thr*threonine*2-amino-3-hydroxybutyric acid	C4 H9 N1 O3 	CC(O)C(N)C(=O)O	LIGAND:C00188*CAS:72-19-5	6.1.1.3	tRNAthr + L-threonine + ATP  =  L-threonyl-tRNAthr + pyrophosphate + AMP	tRNA charging pathway
L-threonine	T*thr*thre*L-thr*threonine*2-amino-3-hydroxybutyric acid	C4 H9 N1 O3 	CC(O)C(N)C(=O)O	LIGAND:C00188*CAS:72-19-5	4.3.1.19	L-threonine  =  2-oxobutanoate + NH3	isoleucine biosynthesis
L-threonine	T*thr*thre*L-thr*threonine*2-amino-3-hydroxybutyric acid	C4 H9 N1 O3 	CC(O)C(N)C(=O)O	LIGAND:C00188*CAS:72-19-5	4.2.3.1	O-phospho-L-homoserine + H2O  =  phosphate + L-threonine	threonine biosynthesis from homoserine
isocitrate	isocitric acid*D-isocitrate*threo-D<SUB>s</SUB>-isocitrate*I-CIT	C6 H8 O7 	C(=O)(O)CC(C(=O)O)C(O)C(O)=O	CAS:320-77-4	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle variation I
isocitrate	isocitric acid*D-isocitrate*threo-D<SUB>s</SUB>-isocitrate*I-CIT	C6 H8 O7 	C(=O)(O)CC(C(=O)O)C(O)C(O)=O	CAS:320-77-4	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle -- aerobic respiration
isocitrate	isocitric acid*D-isocitrate*threo-D<SUB>s</SUB>-isocitrate*I-CIT	C6 H8 O7 	C(=O)(O)CC(C(=O)O)C(O)C(O)=O	CAS:320-77-4	4.1.3.1	isocitrate  =  glyoxylate + succinate	glyoxylate cycle
isocitrate	isocitric acid*D-isocitrate*threo-D<SUB>s</SUB>-isocitrate*I-CIT	C6 H8 O7 	C(=O)(O)CC(C(=O)O)C(O)C(O)=O	CAS:320-77-4	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	TCA cycle variation I
isocitrate	isocitric acid*D-isocitrate*threo-D<SUB>s</SUB>-isocitrate*I-CIT	C6 H8 O7 	C(=O)(O)CC(C(=O)O)C(O)C(O)=O	CAS:320-77-4	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	glyoxylate cycle
isocitrate	isocitric acid*D-isocitrate*threo-D<SUB>s</SUB>-isocitrate*I-CIT	C6 H8 O7 	C(=O)(O)CC(C(=O)O)C(O)C(O)=O	CAS:320-77-4	ACONITATEHYDR-RXN	cis-aconitate + H2O  =  isocitrate	TCA cycle -- aerobic respiration
glycyl-tRNAgly	GLYCYL-TRNA(GLY)				6.1.1.14	tRNAgly + glycine + ATP  =  glycyl-tRNAgly + pyrophosphate + AMP	tRNA charging pathway
4-methyl-5-(beta-hydroxyethyl)thiazole	4-methyl-5-(2-hydroxyethyl)-thiazole*THZ*5-(2-Hydroxyethyl)-4-methylthiazole*HET	C6 H9 N1 O1 S1 	Cc1(c(CCO)scn1)	CAS:137-00-8	2.7.1.50	ATP + 4-methyl-5-(beta-hydroxyethyl)thiazole  =  ADP + 4-methyl-5-(beta-hydroxyethyl)thiazole phosphate	thiamin biosynthesis
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	QUINOLINATE-SYNTHA-RXN	iminoaspartate + dihydroxy-acetone-phosphate  =  quinolinate + 2 H2O + phosphate	NAD biosynthesis I (from aspartate)
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	4.1.2.-	dihydroxy-acetone-phosphate + D-erythrose-4-phosphate  =  D-sedoheptulose-1,7-bisphosphate	Calvin cycle
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	1.1.99.5	glycerol-3-phosphate + FAD  =  dihydroxy-acetone-phosphate + FADH2	glycerol degradation
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	5.3.1.1	D-glyceraldehyde-3-phosphate  =  dihydroxy-acetone-phosphate	Calvin cycle
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	5.3.1.1	D-glyceraldehyde-3-phosphate  =  dihydroxy-acetone-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	5.3.1.1	D-glyceraldehyde-3-phosphate  =  dihydroxy-acetone-phosphate	glycolysis I
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	5.3.1.1	D-glyceraldehyde-3-phosphate  =  dihydroxy-acetone-phosphate	glycolysis II
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	glycolysis I
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	glycolysis II
dihydroxy-acetone-phosphate	DHAP*glycerone-phosphate*dihydroxyacetone 3-phosphate*dihydroxyacetone-P*di-OH-acetone-P*dihydroxyacetone-phosphate	C3 H7 O6 P1 	C(O)C(=O)COP(O)(=O)O	CAS:57-04-5	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	gluconeogenesis
1-O-sinapoyl-beta-D-glucose	1-O-sinapoyl &beta;-D-glucoside	C17 H24 O10 	C(O)C1(OC(C(O)C(O)C1O)OC(=O)CCc2(cc(OC)c(O)c(c2)OC))	PUBCHEM:439429*PUBCHEM:439429	2.3.1.92	1-O-sinapoyl-beta-D-glucose + malate  =  sinapoyl-(S)-malate + beta-D-glucose	sinapate ester biosynthesis
1-O-sinapoyl-beta-D-glucose	1-O-sinapoyl &beta;-D-glucoside	C17 H24 O10 	C(O)C1(OC(C(O)C(O)C1O)OC(=O)CCc2(cc(OC)c(O)c(c2)OC))	PUBCHEM:439429*PUBCHEM:439429	2.3.1.91	1-O-sinapoyl-beta-D-glucose + choline  =  O-sinapoylcholine + beta-D-glucose	sinapate ester biosynthesis
1-O-sinapoyl-beta-D-glucose	1-O-sinapoyl &beta;-D-glucoside	C17 H24 O10 	C(O)C1(OC(C(O)C(O)C1O)OC(=O)CCc2(cc(OC)c(O)c(c2)OC))	PUBCHEM:439429*PUBCHEM:439429	2.3.1.103	2 1-O-sinapoyl-beta-D-glucose  =  1,2-bis-O-sinapoyl-beta-D-glucoside + beta-D-glucose	sinapate ester biosynthesis
1-O-sinapoyl-beta-D-glucose	1-O-sinapoyl &beta;-D-glucoside	C17 H24 O10 	C(O)C1(OC(C(O)C(O)C1O)OC(=O)CCc2(cc(OC)c(O)c(c2)OC))	PUBCHEM:439429*PUBCHEM:439429	2.4.1.120	sinapate + UDP-D-glucose  =  1-O-sinapoyl-beta-D-glucose + UDP	sinapate ester biosynthesis
kaempferol-3-glucoside	kaempferol-3-O-D-glucoside	C21 H20 O11 	C(O)C1(OC(C(O)C(O)C1O)Oc3(c(c2(ccc(O)cc2))oc4(c(c3=O)c(O)cc(c4)O)))		RXN1F-443	kaempferol-3-glucoside + dTDP-alpha-L-rhamnose  =  kaempferol-3-glucoside-7-rhamnoside + dTDP	flavonol biosynthesis
kaempferol-3-glucoside	kaempferol-3-O-D-glucoside	C21 H20 O11 	C(O)C1(OC(C(O)C(O)C1O)Oc3(c(c2(ccc(O)cc2))oc4(c(c3=O)c(O)cc(c4)O)))		2.4.1.91	kaempferol + UDP-D-glucose  =  kaempferol-3-glucoside + UDP	flavonol biosynthesis
5-methylthioribulose-1-phosphate	5-methylthio-5-deoxy-D-ribulose-1-phosphate*1-phosphomethylthioribulose*methylthioribulose-1-phosphate*MTRu-1-P*1PMT-ribulose*1-phospho-5-S-methylthioribulose	C6 H13 O7 P1 S1 	C(SC)C(O)C(O)C(=O)COP(O)(=O)O		R145-RXN	5-methylthioribulose-1-phosphate  =  2,3-diketo-5-methylthio-1-phosphopentane + H2O	methionine salvage pathway
5-methylthioribulose-1-phosphate	5-methylthio-5-deoxy-D-ribulose-1-phosphate*1-phosphomethylthioribulose*methylthioribulose-1-phosphate*MTRu-1-P*1PMT-ribulose*1-phospho-5-S-methylthioribulose	C6 H13 O7 P1 S1 	C(SC)C(O)C(O)C(=O)COP(O)(=O)O		5.3.1.23	5-methylthioribose-1-phosphate  =  5-methylthioribulose-1-phosphate	methionine salvage pathway
3-hydroxybutyryl-CoA	3-OH-butyryl-CoA*OH-butyryl-CoA*&beta;-hydroxybutyryl-CoA*&beta;-hydroxybutyryl-S-CoA*D-3-hydroxybutyryl-CoA*hydroxy-butyryl-CoA*beta-hydroxybutyryl-CoA*(R)-3-Hydroxybutanoyl-CoA*(3R)-3-Hydroxybutanoyl-CoA*3-hydroxybutanoyl-CoA	C25 H42 N7 O18 P3 S1 	C1(OC(C(C(O)1)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)C)(n2(c3(c(nc2)c(N)ncn3)))	UM-BBD-CPD:c0030	4.2.1.55	H2O + crotonyl-CoA  =  3-hydroxybutyryl-CoA	lysine degradation II
3-hydroxybutyryl-CoA	3-OH-butyryl-CoA*OH-butyryl-CoA*&beta;-hydroxybutyryl-CoA*&beta;-hydroxybutyryl-S-CoA*D-3-hydroxybutyryl-CoA*hydroxy-butyryl-CoA*beta-hydroxybutyryl-CoA*(R)-3-Hydroxybutanoyl-CoA*(3R)-3-Hydroxybutanoyl-CoA*3-hydroxybutanoyl-CoA	C25 H42 N7 O18 P3 S1 	C1(OC(C(C(O)1)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)C)(n2(c3(c(nc2)c(N)ncn3)))	UM-BBD-CPD:c0030	4.2.1.55	H2O + crotonyl-CoA  =  3-hydroxybutyryl-CoA	tryptophan degradation
3-hydroxybutyryl-CoA	3-OH-butyryl-CoA*OH-butyryl-CoA*&beta;-hydroxybutyryl-CoA*&beta;-hydroxybutyryl-S-CoA*D-3-hydroxybutyryl-CoA*hydroxy-butyryl-CoA*beta-hydroxybutyryl-CoA*(R)-3-Hydroxybutanoyl-CoA*(3R)-3-Hydroxybutanoyl-CoA*3-hydroxybutanoyl-CoA	C25 H42 N7 O18 P3 S1 	C1(OC(C(C(O)1)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)C)(n2(c3(c(nc2)c(N)ncn3)))	UM-BBD-CPD:c0030	1.1.1.-	3-hydroxybutyryl-CoA + NAD+  =  acetoacetyl-CoA + NADH	lysine degradation II
3-hydroxybutyryl-CoA	3-OH-butyryl-CoA*OH-butyryl-CoA*&beta;-hydroxybutyryl-CoA*&beta;-hydroxybutyryl-S-CoA*D-3-hydroxybutyryl-CoA*hydroxy-butyryl-CoA*beta-hydroxybutyryl-CoA*(R)-3-Hydroxybutanoyl-CoA*(3R)-3-Hydroxybutanoyl-CoA*3-hydroxybutanoyl-CoA	C25 H42 N7 O18 P3 S1 	C1(OC(C(C(O)1)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)C)(n2(c3(c(nc2)c(N)ncn3)))	UM-BBD-CPD:c0030	1.1.1.-	3-hydroxybutyryl-CoA + NAD+  =  acetoacetyl-CoA + NADH	tryptophan degradation
3-hydroxy-anthranilate	3-hydroxyanthranilate	C7 H7 N1 O3 	C(O)(=O)c1(c(N)c(O)ccc1)	CAS:548-93-6	1.13.11.6	O2 + 3-hydroxy-anthranilate  =  2-amino-3-carboxymuconate semialdehyde	NAD biosynthesis II (from tryptophan)
3-hydroxy-anthranilate	3-hydroxyanthranilate	C7 H7 N1 O3 	C(O)(=O)c1(c(N)c(O)ccc1)	CAS:548-93-6	1.13.11.6	O2 + 3-hydroxy-anthranilate  =  2-amino-3-carboxymuconate semialdehyde	tryptophan degradation
3-hydroxy-anthranilate	3-hydroxyanthranilate	C7 H7 N1 O3 	C(O)(=O)c1(c(N)c(O)ccc1)	CAS:548-93-6	3.7.1.3	3-hydroxy-L-kynurenine + H2O  =  3-hydroxy-anthranilate + L-alanine	NAD biosynthesis II (from tryptophan)
3-hydroxy-anthranilate	3-hydroxyanthranilate	C7 H7 N1 O3 	C(O)(=O)c1(c(N)c(O)ccc1)	CAS:548-93-6	3.7.1.3	3-hydroxy-L-kynurenine + H2O  =  3-hydroxy-anthranilate + L-alanine	tryptophan degradation
a omega-oxo fatty acid					RXN-4466	a omega-oxo fatty acid + H2O + NAD+  =  a dicarboxylate + NADH	fatty acid omega-oxidation
a omega-oxo fatty acid					RXN-4465	a omega-hydroxy fatty acid + O2  =  a omega-oxo fatty acid + H2O2	fatty acid omega-oxidation
3-methylcrotonyl-CoA	beta-methylcrotonoyl-CoA*3-methylbut-2-enoyl-CoA	C26 H42 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=C(C)C)		6.4.1.4	HCO3- + 3-methylcrotonyl-CoA + ATP  =  phosphate + trans-3-methylglutaconyl-CoA + ADP	leucine degradation
3-methylcrotonyl-CoA	beta-methylcrotonoyl-CoA*3-methylbut-2-enoyl-CoA	C26 H42 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=C(C)C)		1.3.99.10	isovaleryl-CoA + FAD  =  3-methylcrotonyl-CoA + FADH2	leucine degradation
polypeptide				LIGAND-CPD:C00403	RXN-2942	indole-3-acetate + polypeptide  =  indole-3-acetyl-polypeptide	IAA conjugate biosynthesis
L-arogenate	L-arogenic acid*pretyrosine	C10 H13 N1 O5 	C(O)(=O)C(N)CC1(C=CC(O)C=C1)(C(=O)O)	CAS:53078-86-7	4.2.1.91	L-arogenate  =  CO2 + H2O + L-phenylalanine	phenylalanine biosynthesis I
L-arogenate	L-arogenic acid*pretyrosine	C10 H13 N1 O5 	C(O)(=O)C(N)CC1(C=CC(O)C=C1)(C(=O)O)	CAS:53078-86-7	1.3.1.43	NAD+ + L-arogenate  =  L-tyrosine + CO2 + NADH	tyrosine biosynthesis II
L-arogenate	L-arogenic acid*pretyrosine	C10 H13 N1 O5 	C(O)(=O)C(N)CC1(C=CC(O)C=C1)(C(=O)O)	CAS:53078-86-7	1.3.1.43	L-arogenate + NADP+  =  L-tyrosine + NADPH + CO2	tyrosine biosynthesis II
L-arogenate	L-arogenic acid*pretyrosine	C10 H13 N1 O5 	C(O)(=O)C(N)CC1(C=CC(O)C=C1)(C(=O)O)	CAS:53078-86-7	2.6.1.57	prephenate + L-glutamate  =  L-arogenate + alpha-ketoglutarate	tyrosine biosynthesis II
L-arogenate	L-arogenic acid*pretyrosine	C10 H13 N1 O5 	C(O)(=O)C(N)CC1(C=CC(O)C=C1)(C(=O)O)	CAS:53078-86-7	2.6.1.57	prephenate + L-glutamate  =  L-arogenate + alpha-ketoglutarate	phenylalanine biosynthesis I
lactate	lactic acid*L(+)-lactate*(S)-lactate*L-lactate*lactasol*lac*2-hydroxypropanoic acid*2-hydroxypropionic acid	C3 H6 O3 	CC(O)C(O)=O	CAS:598-82-3*CAS:50-21-5	1.1.1.27	NADH + pyruvate  =  NAD+ + lactate	sucrose degradation to ethanol and lactate (anaerobic)
indole-3-acetyl-asp	indole-3-acetyl-aspartic acid*indole-3-acetyl-aspartate	C14 H14 N2 O5 	C(=O)(O)CC(C(=O)O)NC(=O)Cc1(c2(c([nH]c1)cccc2))		RXN-2946	indole-3-acetate + L-aspartate  =  indole-3-acetyl-asp + H2O	IAA conjugate biosynthesis
dADP	deoxyadenosine-diphosphate*2'-deoxyadenosine-5'-diphosphate	C10 H15 N5 O9 P2 	C(OP(O)(=O)OP(O)(=O)O)C1(OC(CC(O)1)n2(c3(c(nc2)c(N)ncn3)))	CAS:2793-06-8	2.7.4.6	dADP + ATP  =  dATP + ADP	de novo biosynthesis of purine nucleotides I
dADP	deoxyadenosine-diphosphate*2'-deoxyadenosine-5'-diphosphate	C10 H15 N5 O9 P2 	C(OP(O)(=O)OP(O)(=O)O)C1(OC(CC(O)1)n2(c3(c(nc2)c(N)ncn3)))	CAS:2793-06-8	1.17.4.1	Reduced Thioredoxin + ADP  =  Oxidized Thioredoxin + dADP + H2O	de novo biosynthesis of purine nucleotides I
dADP	deoxyadenosine-diphosphate*2'-deoxyadenosine-5'-diphosphate	C10 H15 N5 O9 P2 	C(OP(O)(=O)OP(O)(=O)O)C1(OC(CC(O)1)n2(c3(c(nc2)c(N)ncn3)))	CAS:2793-06-8	RXN0-747	ADP + reduced glutaredoxin  =  dADP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
thiamine	thiamin*vitamin B<SUB>1</SUB>	C12 H17 N4 O1 S1 	c1(c(cnc(C)n1)C[n+1]2(c(C)c(sc2)CCO))(N)	CAS:59-43-8	2.7.1.89	thiamine + ATP  =  thiamine-phosphate + ADP	thiamin biosynthesis
kaempferol-3-rhamnoside	kaempferol-3-O-rhamnopyranoside	C21 H20 O10 	C1(OC(C)C(O)C(O)C(O)1)Oc3(c(c2(ccc(O)cc2))oc4(c(c3=O)c(O)cc(O)c4))		RXN1F-475	kaempferol-3-rhamnoside + dTDP-alpha-L-rhamnose  =  kaempferol-3-rhamnoside-7-rhamnoside + dTDP	flavonol biosynthesis
kaempferol-3-rhamnoside	kaempferol-3-O-rhamnopyranoside	C21 H20 O10 	C1(OC(C)C(O)C(O)C(O)1)Oc3(c(c2(ccc(O)cc2))oc4(c(c3=O)c(O)cc(O)c4))		RXN1F-474	kaempferol + dTDP-alpha-L-rhamnose  =  kaempferol-3-rhamnoside + dTDP	flavonol biosynthesis
kaempferol-3-rhamnoside-7-rhamnoside	kaempferol-3-O-rhamnopyranoside-7-O-rhamnopyranoside	C27 H30 O14 	C1(OC(C)C(O)C(O)C(O)1)Oc2(c(=O)c4(c(oc2c3(ccc(O)cc3))cc(cc(O)4)OC5(C(O)C(O)C(O)C(C)O5)))		RXN1F-475	kaempferol-3-rhamnoside + dTDP-alpha-L-rhamnose  =  kaempferol-3-rhamnoside-7-rhamnoside + dTDP	flavonol biosynthesis
ADP-D-glucose	adenosine diphosphate glucose*ADP-glucose	C16 H25 N5 O15 P2 	C1(C(O)C(O)C(O)C(O1)CO)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C(O)2)n3(cnc4(c3c(N)ncn4)))	CAS:2140-58-1	2.4.1.21	(1,4-alpha-D-glucosyl)(n) + ADP-D-glucose  =  ADP + (1,4-alpha-D-glucosyl)(n+1)	starch biosynthesis
ADP-D-glucose	adenosine diphosphate glucose*ADP-glucose	C16 H25 N5 O15 P2 	C1(C(O)C(O)C(O)C(O1)CO)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C(O)2)n3(cnc4(c3c(N)ncn4)))	CAS:2140-58-1	2.7.7.27	alpha-D-glucose-1-phosphate + ATP  =  ADP-D-glucose + pyrophosphate	starch biosynthesis
L-isoleucine	I*ile*iso-leucine	C6 H13 N1 O2 	CC(CC)C(N)C(O)=O	LIGAND:C00407*CAS:7004-09-3	6.1.1.5	tRNAile + L-isoleucine + ATP  =  L-isoleucyl-tRNAile + pyrophosphate + AMP	tRNA charging pathway
L-isoleucine	I*ile*iso-leucine	C6 H13 N1 O2 	CC(CC)C(N)C(O)=O	LIGAND:C00407*CAS:7004-09-3	2.6.1.42	2-keto-3-methyl-valerate + L-glutamate  =  L-isoleucine + alpha-ketoglutarate	isoleucine biosynthesis
L-isoleucine	I*ile*iso-leucine	C6 H13 N1 O2 	CC(CC)C(N)C(O)=O	LIGAND:C00407*CAS:7004-09-3	2.6.1.42	2-keto-3-methyl-valerate + L-glutamate  =  L-isoleucine + alpha-ketoglutarate	isoleucine degradation
D-sedoheptulose-1,7-bisphosphate	sedoheptulose 1,7-bisphosphate*D-sedoheptulose-1,7-diphosphate*D-sedoheptulose-1,7-P<SUB>2</SUB>	C7 H16 O13 P2 	C(OP(=O)(O)O)C(=O)C(O)C(O)C(O)C(O)COP(O)(=O)O		3.1.3.37	H2O + D-sedoheptulose-1,7-bisphosphate  =  phosphate + D-sedoheptulose-7-phosphate	Calvin cycle
D-sedoheptulose-1,7-bisphosphate	sedoheptulose 1,7-bisphosphate*D-sedoheptulose-1,7-diphosphate*D-sedoheptulose-1,7-P<SUB>2</SUB>	C7 H16 O13 P2 	C(OP(=O)(O)O)C(=O)C(O)C(O)C(O)C(O)COP(O)(=O)O		4.1.2.-	dihydroxy-acetone-phosphate + D-erythrose-4-phosphate  =  D-sedoheptulose-1,7-bisphosphate	Calvin cycle
mannitol	D-mannitol*mitobronitol	C6 H14 O6 	C(O)C(O)C(O)C(O)C(O)CO	LIGAND:C00392*CAS:69-65-8	1.1.1.255	NAD+ + mannitol  =  NADH + mannose	mannitol degradation
mannitol	D-mannitol*mitobronitol	C6 H14 O6 	C(O)C(O)C(O)C(O)C(O)CO	LIGAND:C00392*CAS:69-65-8	3.1.3.22	H2O + mannitol-1-phosphate  =  phosphate + mannitol	mannitol biosynthesis
beta-ketoacyl-ACP	3-oxoacyl-[acyl-carrier protein]*acetoacyl-ACP*CH3(CH2)xCOCH2CO-S-ACP				2.3.1.41	acyl-ACP + malonyl-ACP  =  acyl carrier protein + beta-ketoacyl-ACP + CO2	fatty acid elongation -- saturated
beta-ketoacyl-ACP	3-oxoacyl-[acyl-carrier protein]*acetoacyl-ACP*CH3(CH2)xCOCH2CO-S-ACP				1.1.1.100	NADPH + beta-ketoacyl-ACP  =  D-3-hydroxy-acyl-ACP + NADP+	fatty acid elongation -- saturated
UDP-4-dehydro-6-deoxy-D-glucose	UDP-4-keto-6-deoxy-D-glucose*UDP-4-oxo-6-deoxy-D-glucose	C15 H22 N2 O16 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3)))		RXN-5481	UDP-4-dehydro-6-deoxy-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+	UDP-L-rhamnose biosynthesis
UDP-4-dehydro-6-deoxy-D-glucose	UDP-4-keto-6-deoxy-D-glucose*UDP-4-oxo-6-deoxy-D-glucose	C15 H22 N2 O16 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3)))		4.2.1.76	UDP-D-glucose  =  H2O + UDP-4-dehydro-6-deoxy-D-glucose	UDP-L-rhamnose biosynthesis
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis II (acetyl cycle)
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis III
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	citrulline degradation
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	arginine biosynthesis III
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	proline biosynthesis
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	arginine degradation II
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	4.1.1.17	L-ornithine  =  CO2 + putrescine	polyamine biosynthesis III
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	4.1.1.17	L-ornithine  =  CO2 + putrescine	spermine biosynthesis II
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	4.1.1.17	L-ornithine  =  CO2 + putrescine	polyamine biosynthesis I
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	3.5.1.16	N-alpha-acetylornithine + H2O  =  L-ornithine + acetate	arginine biosynthesis
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	3.5.3.1	H2O + L-arginine  =  urea + L-ornithine	arginine degradation II
L-ornithine	2,5-diaminopentanoate*2,5-diaminopentanoic acid*2,5-diaminovaleric acid*ornithine*&alpha;,&delta;-diaminovaleric acid	C5 H12 N2 O2 	C(N)CCC(N)C(O)=O	CAS:70-26-8*CAS:7006-33-9	2.3.1.35	L-glutamate + N-alpha-acetylornithine  =  N-acetyl-L-glutamate + L-ornithine	arginine biosynthesis II (acetyl cycle)
O-acetyl-L-homoserine	acetylhomoserine*<I>O</I>-acetylhomoserine	C6 H11 N1 O4 	C(C)(=O)OCCC(N)C(=O)O		RXN-721	O-acetyl-L-homoserine + L-cysteine  =  cystathionine + acetate	homocysteine and cysteine interconversion
indole carboxyl thiazole		C12 H8 N2 O2 S1 	c2(c(C1(=NC(=CS1)C(=O)[OH]))c3(c([nH]2)cccc3))		RXN1F-17	indole carboxyl thiazole  =  3-thiazol-2'-yl-indole + CO2	camalexin biosynthesis
indole carboxyl thiazole		C12 H8 N2 O2 S1 	c2(c(C1(=NC(=CS1)C(=O)[OH]))c3(c([nH]2)cccc3))		RXN1F-16	NADP+ + indole carboxyl hydro-thiazole  =  indole carboxyl thiazole + NADPH	camalexin biosynthesis
meso-diaminopimelate	meso-2,6-diaminopimelate*meso-A<SUB>2</SUB>pm*meso-diaminoheptanedioate*meso-2,6-diaminoheptanedioate*meso-1-&alpha;,&epsilon;-diaminopimelate*D,L-diaminopimelate*D,L-DAP*D,L-meso-diaminoheptanedioate*M-DAP	C7 H14 N2 O4 	C(O)(=O)C(N)CCCC(N)C(=O)O	CAS:922-54-3	4.1.1.20	meso-diaminopimelate  =  CO2 + L-lysine	lysine biosynthesis
meso-diaminopimelate	meso-2,6-diaminopimelate*meso-A<SUB>2</SUB>pm*meso-diaminoheptanedioate*meso-2,6-diaminoheptanedioate*meso-1-&alpha;,&epsilon;-diaminopimelate*D,L-diaminopimelate*D,L-DAP*D,L-meso-diaminoheptanedioate*M-DAP	C7 H14 N2 O4 	C(O)(=O)C(N)CCCC(N)C(=O)O	CAS:922-54-3	5.1.1.7	L,L-diaminopimelate  =  meso-diaminopimelate	lysine biosynthesis
18-hydroxyoleate	18-hydroxyoctadec-9-enoic acid	C18 H34 O3 	C(O)CCCCCCCC=CCCCCCCCC(=O)O		1.1.1.-	18-hydroxyoleate + NADP+  =  18-oxooleate + NADPH	suberin biosynthesis
18-hydroxyoleate	18-hydroxyoctadec-9-enoic acid	C18 H34 O3 	C(O)CCCCCCCC=CCCCCCCCC(=O)O		RXN-1064	18-hydroxyoleate + NADPH + O2  =  9,10-epoxy-18-hydroxystearate + NADP+ + H2O	cutin biosynthesis
18-hydroxyoleate	18-hydroxyoctadec-9-enoic acid	C18 H34 O3 	C(O)CCCCCCCC=CCCCCCCCC(=O)O		1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	suberin biosynthesis
18-hydroxyoleate	18-hydroxyoctadec-9-enoic acid	C18 H34 O3 	C(O)CCCCCCCC=CCCCCCCCC(=O)O		1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	cutin biosynthesis
acrylate		C3 H4 O2 	C(O)(=O)C=C		3.5.5.7	acrylonitrile + 2 H2O  =  acrylate + NH3	acrylonitrile degradation
acrylate		C3 H4 O2 	C(O)(=O)C=C		3.5.1.4	acrylamide + H2O  =  NH3 + acrylate + H+	acrylonitrile degradation
(-)-jasmonic acid methyl ester	jasmonic acid methyl ester*methyl jasmonate	C13 H20 O3 	CCC=CC[CH]1([CH](CC(=O)OC)CCC(=O)1)		2.1.1.141	(-)-jasmonate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + (-)-jasmonic acid methyl ester	jasmonic acid biosynthesis
phosphoryl-ethanolamine	phosphoethanolamine*ethanolamine phosphate*O-Phosphorylethanolamine*O-Phosphoethanolamine	C2 H8 N1 O4 P1 	C(N)COP(O)(=O)O	CAS:1071-23-4*CAS:1071-23-4	2.1.1.103	phosphoryl-ethanolamine + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + N-methylethanolamine phosphate	choline biosynthesis I
phosphoryl-ethanolamine	phosphoethanolamine*ethanolamine phosphate*O-Phosphorylethanolamine*O-Phosphoethanolamine	C2 H8 N1 O4 P1 	C(N)COP(O)(=O)O	CAS:1071-23-4*CAS:1071-23-4	2.7.1.82	ethanolamine + ATP  =  phosphoryl-ethanolamine + ADP	choline biosynthesis I
C25-allenic-apo-aldehyde		C25 H36 O3 	CC(=CC=CC=C(C)CO)C=CC=C(C)C=C=C1(C(C)(C)CC(O)CC(C)(O)1)		RXN-698	neoxanthin + O2  =  xanthoxin + C25-allenic-apo-aldehyde	abscisic acid biosynthesis
acceptor	oxidized electron acceptor*oxidized donor*A				1.8.99.2	reduced acceptor + APS  =  AMP + acceptor + SO3-2	sulfate assimilation
acceptor	oxidized electron acceptor*oxidized donor*A				1.2.99.2	reduced acceptor + CO2  =  acceptor + H2O + CO	carbon monoxide dehydrogenase pathway
acceptor	oxidized electron acceptor*oxidized donor*A				1.1.99.16	acceptor + malate  =  reduced acceptor + oxaloacetate	TCA cycle -- aerobic respiration
acceptor	oxidized electron acceptor*oxidized donor*A				1.5.99.6	H2O + acceptor + spermidine  =  reduced acceptor + 4-amino-butyraldehyde + 1,3-diaminopropane	beta-alanine biosynthesis I
acceptor	oxidized electron acceptor*oxidized donor*A				1.5.99.8	L-proline + acceptor  =  L-delta1-pyrroline-5-carboxylate + reduced acceptor	proline degradation
acceptor	oxidized electron acceptor*oxidized donor*A				1.14.-.-	campesterol + O2 + reduced acceptor  =  (22alpha)-hydroxy-campesterol + H2O + acceptor	brassinosteroid biosynthesis II
acceptor	oxidized electron acceptor*oxidized donor*A				1.14.-.-	campestanol + O2 + reduced acceptor  =  (6alpha)-hydroxycampestanol + H2O + acceptor	brassinosteroid biosynthesis I
acceptor	oxidized electron acceptor*oxidized donor*A				1.14.-.-	6-oxocampestanol + O2 + reduced acceptor  =  cathasterone + H2O + acceptor	brassinosteroid biosynthesis I
acceptor	oxidized electron acceptor*oxidized donor*A				1.14.-.-	cathasterone + O2 + reduced acceptor  =  teasterone + H2O + acceptor	brassinosteroid biosynthesis I
acceptor	oxidized electron acceptor*oxidized donor*A				1.14.-.-	typhasterol + O2 + reduced acceptor  =  castasterone + H2O + acceptor	brassinosteroid biosynthesis I
acceptor	oxidized electron acceptor*oxidized donor*A				1.14.99.7	O2 + reduced acceptor + squalene  =  (S)-2,3-Epoxysqualene + H2O + acceptor	sterol biosynthesis
acceptor	oxidized electron acceptor*oxidized donor*A				1.3.99.-	reduced acceptor + crotonobetainyl-CoA  =  acceptor + gamma-butyrobetainyl-CoA	carnitine degradation
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	4.2.1.2	fumarate + H2O  =  malate	TCA cycle variation I
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	4.2.1.2	fumarate + H2O  =  malate	superpathway of glyoxylate cycle
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	4.2.1.2	fumarate + H2O  =  malate	phenylalanine degradation
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	4.2.1.2	fumarate + H2O  =  malate	TCA cycle -- aerobic respiration
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	2.3.3.9	acetyl-CoA + H2O + glyoxylate  =  malate + coenzyme A	glyoxylate cycle
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	TCA cycle variation I
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	gluconeogenesis
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	TCA cycle variation I
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	gluconeogenesis
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	TCA cycle variation I
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	superpathway of glyoxylate cycle
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	glyoxylate cycle
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	phenylalanine degradation
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	TCA cycle -- aerobic respiration
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	gluconeogenesis
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.99.16	acceptor + malate  =  reduced acceptor + oxaloacetate	TCA cycle -- aerobic respiration
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	1.1.1.37	malate  =  oxaloacetate	superpathway of glyoxylate cycle
malate	hydroxysuccinic acid*hydroxybutanedioic acid*malic acid*L-mal*mal*L-malate*(S)-malate*DL-malic acid	C4 H6 O5 	C(O)(=O)CC(O)C(O)=O	LIGAND:C00497*CAS:6915-15-7	2.3.1.92	1-O-sinapoyl-beta-D-glucose + malate  =  sinapoyl-(S)-malate + beta-D-glucose	sinapate ester biosynthesis
succinate semialdehyde	succ-S-ald	C4 H6 O3 	C(=O)(O)CC[CH]=O		1.2.1.16	succinate semialdehyde + NADP+ + H2O  =  NADPH + succinate	arginine degradation I
succinate semialdehyde	succ-S-ald	C4 H6 O3 	C(=O)(O)CC[CH]=O		1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	glutamate degradation II
succinate semialdehyde	succ-S-ald	C4 H6 O3 	C(=O)(O)CC[CH]=O		1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	arginine degradation I
succinate semialdehyde	succ-S-ald	C4 H6 O3 	C(=O)(O)CC[CH]=O		1.2.1.16	succinate semialdehyde + NAD(P)H  =  4-hydroxybutyrate + NAD(P)+	glutamate degradation II
succinate semialdehyde	succ-S-ald	C4 H6 O3 	C(=O)(O)CC[CH]=O		2.6.1.19	4-aminobutyrate + pyruvate  =  succinate semialdehyde + L-alanine	glutamate degradation II
succinate semialdehyde	succ-S-ald	C4 H6 O3 	C(=O)(O)CC[CH]=O		2.6.1.19	alpha-ketoglutarate + 4-aminobutyrate  =  L-glutamate + succinate semialdehyde	glutamate degradation II
succinate semialdehyde	succ-S-ald	C4 H6 O3 	C(=O)(O)CC[CH]=O		2.6.1.19	alpha-ketoglutarate + 4-aminobutyrate  =  L-glutamate + succinate semialdehyde	arginine degradation I
6-phospho-D-gluconate	6-p-gluconate*6-phospho-gluconate*6-phosphogluconic acid	C6 H13 O10 P1 	C(OP(O)(O)=O)[CH](O)[CH](O)[CH](O)[CH](O)C(O)=O		1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	superpathway of gluconate degradation
6-phospho-D-gluconate	6-p-gluconate*6-phospho-gluconate*6-phosphogluconic acid	C6 H13 O10 P1 	C(OP(O)(O)=O)[CH](O)[CH](O)[CH](O)[CH](O)C(O)=O		1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	oxidative branch of the pentose phosphate pathway
6-phospho-D-gluconate	6-p-gluconate*6-phospho-gluconate*6-phosphogluconic acid	C6 H13 O10 P1 	C(OP(O)(O)=O)[CH](O)[CH](O)[CH](O)[CH](O)C(O)=O		2.7.1.12	ATP + gluconate  =  6-phospho-D-gluconate + ADP	superpathway of gluconate degradation
6-phospho-D-gluconate	6-p-gluconate*6-phospho-gluconate*6-phosphogluconic acid	C6 H13 O10 P1 	C(OP(O)(O)=O)[CH](O)[CH](O)[CH](O)[CH](O)C(O)=O		3.1.1.31	D-glucono-delta-lactone-6-phosphate + H2O  =  6-phospho-D-gluconate	oxidative branch of the pentose phosphate pathway
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	sucrose degradation to ethanol and lactate (anaerobic)
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis I
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis II
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.4.1.14	D-fructose-6-phosphate + UDP-D-glucose  =  sucrose-6'-phosphate + UDP	sucrose biosynthesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.7.1.90	D-fructose-6-phosphate + pyrophosphate  =  phosphate + fructose-1,6-bisphosphate	glycolysis I
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.6.1.16	D-fructose-6-phosphate + L-glutamine  =  D-glucosamine-6-phosphate + L-glutamate	UDP-N-acetyl-D-glucosamine biosynthesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.9	alpha-D-glucose-6-phosphate  =  D-fructose-6-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2TRANSKETO-RXN	D-erythrose-4-phosphate + D-xylulose-5-phosphate  =  D-fructose-6-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2TRANSKETO-RXN	D-erythrose-4-phosphate + D-xylulose-5-phosphate  =  D-fructose-6-phosphate + D-glyceraldehyde-3-phosphate	non-oxidative branch of the pentose phosphate pathway
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.2.1.2	D-glyceraldehyde-3-phosphate + D-sedoheptulose-7-phosphate  =  D-fructose-6-phosphate + D-erythrose-4-phosphate	non-oxidative branch of the pentose phosphate pathway
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	3.1.3.11	fructose-1,6-bisphosphate + H2O  =  D-fructose-6-phosphate + phosphate	Calvin cycle
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	3.1.3.11	fructose-1,6-bisphosphate + H2O  =  D-fructose-6-phosphate + phosphate	gluconeogenesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.7.1.4	fructose + ATP  =  D-fructose-6-phosphate + ADP	sucrose degradation
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	2.7.1.4	fructose + ATP  =  D-fructose-6-phosphate + ADP	sucrose degradation to ethanol and lactate (anaerobic)
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	starch biosynthesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	sucrose degradation
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	ascorbate biosynthesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	glycolysis I
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	glycolysis II
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	gluconeogenesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	mannitol degradation
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	mannitol biosynthesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	colanic acid building blocks biosynthesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	ascorbate biosynthesis
D-fructose-6-phosphate	fructose-6P*fructose-6-P*fruc6p*fru-6-P*fructose-6-phosphate*A-D-fructose-6-P*D-fructose-6-P	C6 H13 O9 P1 	C(O)C1(OC(C(O)C(O)1)COP(O)(=O)O)(O)	CAS:643-13-0	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	GDP-D-rhamnose biosynthesis
monovinyl protochlorophyllide a	protochlorophyllide*monovinyl protochlrophyllide a	C35 H32 N4 O5 MG1 	C(O)(=O)CCC3(C8(N2([Mg]59(n1(c(c(C=C)c(C)c1=CC=2C(C)=3)=CC4(=N(C(C(=C(C)4)CC)=Cc6(n5c7(c(c(C)6)C(=O)C(C7=8)C(=O)OC)))9))))))	CAS:14751-08-7*LIGAND-CPD:C02880	RXN1F-10	monovinyl protochlorophyllide a + NADPH  =  NADP+ + chlorophyllide a	chlorophyllide a biosynthesis
monovinyl protochlorophyllide a	protochlorophyllide*monovinyl protochlrophyllide a	C35 H32 N4 O5 MG1 	C(O)(=O)CCC3(C8(N2([Mg]59(n1(c(c(C=C)c(C)c1=CC=2C(C)=3)=CC4(=N(C(C(=C(C)4)CC)=Cc6(n5c7(c(c(C)6)C(=O)C(C7=8)C(=O)OC)))9))))))	CAS:14751-08-7*LIGAND-CPD:C02880	1.3.1.75	divinyl protochlorophyllide a + NADPH  =  monovinyl protochlorophyllide a + NADP+	chlorophyllide a biosynthesis
GA25	GA25*gibberellin A25*gibberellin A<sub>25</sub>	C20 H26 O6 	CC1(C(O)=O)([CH]2(C(C(O)=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA25 + alpha-ketoglutarate + O2  =  GA13 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA25	GA25*gibberellin A25*gibberellin A<sub>25</sub>	C20 H26 O6 	CC1(C(O)=O)([CH]2(C(C(O)=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA25 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA17	GA<sub>17</sub>*gibberellin A17*gibberellin A<sub>17</sub>	C20 H26 O7 	CC1(C(O)=O)([CH]2(C(C(O)=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA17 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
5-amino-6-(5'-phosphoribitylamino)uracil	5-amino-6-(5'-phosphoribitylamino)uracil*5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione 5'-phosphate	C9 H17 N4 O9 P1 	C(C(O)C(O)C(O)COP(O)(O)=O)Nc1(c(N)c(=O)[nH]c([nH]1)=O)	LIGAND-CPD:C04454	RIBOPHOSPHAT-RXN	5-amino-6-(5'-phosphoribitylamino)uracil + H2O  =  5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + phosphate	riboflavin and FMN and FAD biosynthesis
5-amino-6-(5'-phosphoribitylamino)uracil	5-amino-6-(5'-phosphoribitylamino)uracil*5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione 5'-phosphate	C9 H17 N4 O9 P1 	C(C(O)C(O)C(O)COP(O)(O)=O)Nc1(c(N)c(=O)[nH]c([nH]1)=O)	LIGAND-CPD:C04454	1.1.1.193	5-amino-6-(5'-phosphoribosylamino)uracil + NADPH  =  5-amino-6-(5'-phosphoribitylamino)uracil + NADP+	riboflavin and FMN and FAD biosynthesis
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides II
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides I
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	purine degradation
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	salvage pathways of purine nucleosides
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	ureide biosynthesis
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides II
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides I
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	3.5.4.10	phosphoribosyl-formamido-carboxamide  =  IMP + H2O	de novo biosynthesis of purine nucleotides II
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	3.5.4.10	phosphoribosyl-formamido-carboxamide  =  IMP + H2O	de novo biosynthesis of purine nucleotides I
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	2.4.2.8	PRPP + hypoxanthine  =  pyrophosphate + IMP	salvage pathways of purine nucleosides
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	3.1.3.5	IMP + H2O  =  inosine + phosphate	purine degradation
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	3.1.3.5	IMP + H2O  =  inosine + phosphate	salvage pathways of purine nucleosides
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	2.7.1.73	inosine + ATP  =  IMP + ADP	salvage pathways of purine nucleosides
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	3.5.4.6	AMP + H2O  =  IMP + NH3	purine degradation
IMP	5'-IMP*inosinate*inosine-5'-phosphate*ribosylhypoxanthine monophosphate*IMP*inosinate*inosine monophosphate*inosine 5'-monophosphate*inosine 5'-phosphate*5'-inosinate*5'-inosinic acid*5'-inosine monophosphate	C10 H13 N4 O8 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]cn3)))	LIGAND-CPD:C00130*CAS:131-99-7	3.5.4.6	AMP + H2O  =  IMP + NH3	salvage pathways of purine nucleosides
benzoyl-CoA		C28 H40 N7 O17 P3 S1 	C(NCCC(=O)NCCSC(=O)c1(ccccc1))(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC2(OC(C(O)C2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))	CAS:102185-37-5	RXN-2008	benzoyl-CoA  =  salicyloyl-CoA	salicylic acid biosynthesis
benzoyl-CoA		C28 H40 N7 O17 P3 S1 	C(NCCC(=O)NCCSC(=O)c1(ccccc1))(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC2(OC(C(O)C2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))	CAS:102185-37-5	RXN-2005	benzoyl-CoA + H2O  =  benzoate + coenzyme A	salicylic acid biosynthesis
benzoyl-CoA		C28 H40 N7 O17 P3 S1 	C(NCCC(=O)NCCSC(=O)c1(ccccc1))(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC2(OC(C(O)C2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))	CAS:102185-37-5	RXN-6724	benzyl alcohol + benzoyl-CoA  =  benzylbenzoate + coenzyme A	volatile benzenoid ester biosynthesis
benzoyl-CoA		C28 H40 N7 O17 P3 S1 	C(NCCC(=O)NCCSC(=O)c1(ccccc1))(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC2(OC(C(O)C2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))	CAS:102185-37-5	RXN-2006	oxocinnamoyl-CoA + coenzyme A  =  benzoyl-CoA + acetyl-CoA	salicylic acid biosynthesis
trans-cinnamate	&beta;-phenylacrylic acid*3-phenyl-2-propenoic acid*cinnamic acid*cinnamate*trans-cinnamic acid*(<i>E</i>)-cinnamate	C9 H8 O2 	C(O)(=O)C=Cc1(ccccc1)	PUBCHEM:444539*LIGAND-CPD:C00423*CAS:140-10-3	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	phenylpropanoid biosynthesis, initial reactions
trans-cinnamate	&beta;-phenylacrylic acid*3-phenyl-2-propenoic acid*cinnamic acid*cinnamate*trans-cinnamic acid*(<i>E</i>)-cinnamate	C9 H8 O2 	C(O)(=O)C=Cc1(ccccc1)	PUBCHEM:444539*LIGAND-CPD:C00423*CAS:140-10-3	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	suberin biosynthesis
trans-cinnamate	&beta;-phenylacrylic acid*3-phenyl-2-propenoic acid*cinnamic acid*cinnamate*trans-cinnamic acid*(<i>E</i>)-cinnamate	C9 H8 O2 	C(O)(=O)C=Cc1(ccccc1)	PUBCHEM:444539*LIGAND-CPD:C00423*CAS:140-10-3	6.2.1.-	trans-cinnamate + coenzyme A  =  (E)-cinnamoyl-CoA + H2O	salicylic acid biosynthesis
trans-cinnamate	&beta;-phenylacrylic acid*3-phenyl-2-propenoic acid*cinnamic acid*cinnamate*trans-cinnamic acid*(<i>E</i>)-cinnamate	C9 H8 O2 	C(O)(=O)C=Cc1(ccccc1)	PUBCHEM:444539*LIGAND-CPD:C00423*CAS:140-10-3	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	phenylpropanoid biosynthesis, initial reactions
trans-cinnamate	&beta;-phenylacrylic acid*3-phenyl-2-propenoic acid*cinnamic acid*cinnamate*trans-cinnamic acid*(<i>E</i>)-cinnamate	C9 H8 O2 	C(O)(=O)C=Cc1(ccccc1)	PUBCHEM:444539*LIGAND-CPD:C00423*CAS:140-10-3	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	suberin biosynthesis
trans-cinnamate	&beta;-phenylacrylic acid*3-phenyl-2-propenoic acid*cinnamic acid*cinnamate*trans-cinnamic acid*(<i>E</i>)-cinnamate	C9 H8 O2 	C(O)(=O)C=Cc1(ccccc1)	PUBCHEM:444539*LIGAND-CPD:C00423*CAS:140-10-3	4.3.1.5	L-phenylalanine  =  NH3 + trans-cinnamate	salicylic acid biosynthesis
menaquinone-8	vitamin K<SUB>2</SUB>*MK-8*menaquinone	C51 H72 O2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1(=C(C)C(=O)c2(c(C(=O)1)cccc2))		ADOMET-DMK-METHYLTRANSFER-RXN	demethylmenaquinone-8 + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + menaquinone-8	menaquinone biosynthesis
L-ascorbate	vitamin C*ascorbate*L-ascorbate (vitamin C)*ascorbic acid	C6 H8 O6 	C1(OC(C(O)CO)C(O)=C(O)1)(=O)	CAS:50-81-7	1.10.3.3	L-ascorbate + O2  =  monodehydroascorbate + 2 H2O	ascorbate glutathione cycle
L-ascorbate	vitamin C*ascorbate*L-ascorbate (vitamin C)*ascorbic acid	C6 H8 O6 	C1(OC(C(O)CO)C(O)=C(O)1)(=O)	CAS:50-81-7	1.11.1.11	2 L-ascorbate + H2O2  =  2 monodehydroascorbate + 2 H2O	ascorbate glutathione cycle
L-ascorbate	vitamin C*ascorbate*L-ascorbate (vitamin C)*ascorbic acid	C6 H8 O6 	C1(OC(C(O)CO)C(O)=C(O)1)(=O)	CAS:50-81-7	1.14.17.4	L-ascorbate + 1-aminocyclopropane-1-carboxylate + O2  =  2 H2O + ethene + L-dehydro-ascorbate + hydrogen cyanide + CO2	ethylene biosynthesis from methionine
L-ascorbate	vitamin C*ascorbate*L-ascorbate (vitamin C)*ascorbic acid	C6 H8 O6 	C1(OC(C(O)CO)C(O)=C(O)1)(=O)	CAS:50-81-7	1.6.5.4	2 monodehydroascorbate + NADPH  =  2 L-ascorbate + NADP+	ascorbate glutathione cycle
L-ascorbate	vitamin C*ascorbate*L-ascorbate (vitamin C)*ascorbic acid	C6 H8 O6 	C1(OC(C(O)CO)C(O)=C(O)1)(=O)	CAS:50-81-7	RXN-3523	2 monodehydroascorbate  =  L-ascorbate + L-dehydro-ascorbate	ascorbate glutathione cycle
L-ascorbate	vitamin C*ascorbate*L-ascorbate (vitamin C)*ascorbic acid	C6 H8 O6 	C1(OC(C(O)CO)C(O)=C(O)1)(=O)	CAS:50-81-7	1.3.2.3	2 ferricytochrome c + L-galactono-1,4-lactone  =  2 ferrocytochrome c + L-ascorbate	ascorbate biosynthesis
L-ascorbate	vitamin C*ascorbate*L-ascorbate (vitamin C)*ascorbic acid	C6 H8 O6 	C1(OC(C(O)CO)C(O)=C(O)1)(=O)	CAS:50-81-7	1.8.5.1	L-dehydro-ascorbate + 2 glutathione  =  glutathione disulfide + L-ascorbate	ascorbate glutathione cycle
tRNAser	TRNA(SER)				6.1.1.11	tRNAser + L-serine + ATP  =  L-seryl-tRNAser + pyrophosphate + AMP	tRNA charging pathway
guanine		C5 H5 N5 O1 	c12([nH]cnc(c(=O)[nH]c(N)n1)2)	LIGAND-CPD:C00242*CAS:73-40-5	2.4.2.-	guanine + PRPP  =  pyrophosphate + GMP	salvage pathways of purine nucleosides
guanine		C5 H5 N5 O1 	c12([nH]cnc(c(=O)[nH]c(N)n1)2)	LIGAND-CPD:C00242*CAS:73-40-5	3.5.4.3	H2O + guanine  =  NH3 + xanthine	purine degradation
guanine		C5 H5 N5 O1 	c12([nH]cnc(c(=O)[nH]c(N)n1)2)	LIGAND-CPD:C00242*CAS:73-40-5	3.5.4.3	H2O + guanine  =  NH3 + xanthine	salvage pathways of purine nucleosides
guanine		C5 H5 N5 O1 	c12([nH]cnc(c(=O)[nH]c(N)n1)2)	LIGAND-CPD:C00242*CAS:73-40-5	3.2.2.1	guanosine + H2O  =  guanine + D-ribose	purine degradation
guanine		C5 H5 N5 O1 	c12([nH]cnc(c(=O)[nH]c(N)n1)2)	LIGAND-CPD:C00242*CAS:73-40-5	3.2.2.1	guanosine + H2O  =  guanine + D-ribose	salvage pathways of purine nucleosides
allysine	2-aminoadipate semialdehyde*2-aminoadipate-6-semialdehyde	C6 H11 N1 O3 	C(=O)(O)C(N)CCCC=O	CAS:1962-83-0	ALLYSINE-DEHYDROG-RXN	H2O + allysine + NAD+  =  alpha-aminoadipate + NADH	lysine degradation II
allysine	2-aminoadipate semialdehyde*2-aminoadipate-6-semialdehyde	C6 H11 N1 O3 	C(=O)(O)C(N)CCCC=O	CAS:1962-83-0	1.5.1.9	H2O + NAD+ + saccharopine  =  NADH + allysine + L-glutamate	lysine degradation II
5-aminoimidazole ribonucleotide	5-aminoimidazole ribotide*AIR*1-(5'-phosphoribosyl)-5-aminoimidazole*5'-phosphoribosyl-5-aminoimidazole	C8 H14 N3 O7 P1 	c1(c(N)n(cn1)C2(OC(C(O)C2O)COP(O)(O)=O))		4.1.1.21	5-aminoimidazole ribonucleotide + ATP + CO2 + H2O  =  phosphate + phosphoribosyl-carboxy-aminoimidazole + ADP	de novo biosynthesis of purine nucleotides II
5-aminoimidazole ribonucleotide	5-aminoimidazole ribotide*AIR*1-(5'-phosphoribosyl)-5-aminoimidazole*5'-phosphoribosyl-5-aminoimidazole	C8 H14 N3 O7 P1 	c1(c(N)n(cn1)C2(OC(C(O)C2O)COP(O)(O)=O))		RXN0-742	5-aminoimidazole ribonucleotide + ATP + H2O + CO2  =  N5-carboxyaminoimidazole ribonucleotide + ADP + phosphate	de novo biosynthesis of purine nucleotides I
5-aminoimidazole ribonucleotide	5-aminoimidazole ribotide*AIR*1-(5'-phosphoribosyl)-5-aminoimidazole*5'-phosphoribosyl-5-aminoimidazole	C8 H14 N3 O7 P1 	c1(c(N)n(cn1)C2(OC(C(O)C2O)COP(O)(O)=O))		PYRIMSYN1-RXN	5-aminoimidazole ribonucleotide  =  hydroxymethylpyrimidine phosphate	thiamin biosynthesis
5-aminoimidazole ribonucleotide	5-aminoimidazole ribotide*AIR*1-(5'-phosphoribosyl)-5-aminoimidazole*5'-phosphoribosyl-5-aminoimidazole	C8 H14 N3 O7 P1 	c1(c(N)n(cn1)C2(OC(C(O)C2O)COP(O)(O)=O))		6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides II
5-aminoimidazole ribonucleotide	5-aminoimidazole ribotide*AIR*1-(5'-phosphoribosyl)-5-aminoimidazole*5'-phosphoribosyl-5-aminoimidazole	C8 H14 N3 O7 P1 	c1(c(N)n(cn1)C2(OC(C(O)C2O)COP(O)(O)=O))		6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides I
dihydro-neo-pterin	2-amino-4-hydroxy-6-(D-erythro-1,2,3-trihydroxypropyl)-7,8-dihydropteridine*dihydro-neo-pterin*2-amino-4-hydroxy-6-(D-erythro)-trihydroxypropyldihydropteridin	C9 H13 N5 O4 	C(O)C(O)C(O)C1(=Nc2(c(NC1)nc(N)[nH]c2=O))		4.1.2.25	dihydro-neo-pterin  =  glycolaldehyde + 6-hydroxymethyl-dehydropterin	tetrahydrofolate biosynthesis I
dihydro-neo-pterin	2-amino-4-hydroxy-6-(D-erythro-1,2,3-trihydroxypropyl)-7,8-dihydropteridine*dihydro-neo-pterin*2-amino-4-hydroxy-6-(D-erythro)-trihydroxypropyldihydropteridin	C9 H13 N5 O4 	C(O)C(O)C(O)C1(=Nc2(c(NC1)nc(N)[nH]c2=O))		4.1.2.25	dihydro-neo-pterin  =  glycolaldehyde + 6-hydroxymethyl-dehydropterin	tetrahydrofolate biosynthesis II
dihydro-neo-pterin	2-amino-4-hydroxy-6-(D-erythro-1,2,3-trihydroxypropyl)-7,8-dihydropteridine*dihydro-neo-pterin*2-amino-4-hydroxy-6-(D-erythro)-trihydroxypropyldihydropteridin	C9 H13 N5 O4 	C(O)C(O)C(O)C1(=Nc2(c(NC1)nc(N)[nH]c2=O))		3.6.1.-	dihydroneopterin phosphate + H2O  =  dihydro-neo-pterin + phosphate	tetrahydrofolate biosynthesis I
dihydro-neo-pterin	2-amino-4-hydroxy-6-(D-erythro-1,2,3-trihydroxypropyl)-7,8-dihydropteridine*dihydro-neo-pterin*2-amino-4-hydroxy-6-(D-erythro)-trihydroxypropyldihydropteridin	C9 H13 N5 O4 	C(O)C(O)C(O)C1(=Nc2(c(NC1)nc(N)[nH]c2=O))		3.6.1.-	dihydroneopterin phosphate + H2O  =  dihydro-neo-pterin + phosphate	tetrahydrofolate biosynthesis II
L-carnitine	&gamma;-Trimethyl-hydroxybutyrobetaine*3-hydroxy-4-trimethylammoniobutanoate*R-(-)-3-hydroxy-4-trimethylaminobutyrate*vitamin B T*bicarnesine*(S)-carnitine*L-&gamma;-trimethyl-&beta;-hydroxybutyrobetaine*vitamin BT*3-carboxy-2-hydroxy-N,N,N-trimethyl-1-propanaminium	C7 H15 N1 O3 	C([N+1](C)(C)C)C(O)CC([O-1])=O	CAS:541-15-1	6.2.1.-	coenzyme A + L-carnitine  =  L-carnitinyl-CoA + H2O	carnitine degradation
kaempferol		C15 H10 O6 	c1(O)(ccc(cc1)C2(=C(O)C(=O)c3(c(O2)cc(O)cc3O)))		2.4.1.91	kaempferol + UDP-D-glucose  =  kaempferol-3-glucoside + UDP	flavonol biosynthesis
kaempferol		C15 H10 O6 	c1(O)(ccc(cc1)C2(=C(O)C(=O)c3(c(O2)cc(O)cc3O)))		RXN1F-474	kaempferol + dTDP-alpha-L-rhamnose  =  kaempferol-3-rhamnoside + dTDP	flavonol biosynthesis
kaempferol		C15 H10 O6 	c1(O)(ccc(cc1)C2(=C(O)C(=O)c3(c(O2)cc(O)cc3O)))		RXN1F-93	dihydrokaempferol + alpha-ketoglutarate + O2  =  kaempferol + succinate + CO2 + H2O	flavonol biosynthesis
(S)-ureidoglycolate	(-)-ureidoglycolate*ureidoglycolate	C3 H6 N2 O4 	C(C(=O)O)(O)NC(N)=O	CAS:2017665	3.5.3.19	H2O + (S)-ureidoglycolate  =  2 NH3 + CO2 + glyoxylate	ureide degradation
(S)-ureidoglycolate	(-)-ureidoglycolate*ureidoglycolate	C3 H6 N2 O4 	C(C(=O)O)(O)NC(N)=O	CAS:2017665	4.3.2.3	(S)-ureidoglycolate  =  urea + glyoxylate	ureide degradation
(S)-ureidoglycolate	(-)-ureidoglycolate*ureidoglycolate	C3 H6 N2 O4 	C(C(=O)O)(O)NC(N)=O	CAS:2017665	3.5.3.4	H2O + allantoate  =  (S)-ureidoglycolate + urea	ureide degradation
xanthoxin		C15 H20 O3 	CC(=CC=O)C=CC12(C(C)(O1)CC(=O)CC(C)(C)2)		RXN-699	xanthoxin  =  abscisic acid aldehyde	abscisic acid biosynthesis
xanthoxin		C15 H20 O3 	CC(=CC=O)C=CC12(C(C)(O1)CC(=O)CC(C)(C)2)		RXN-698	neoxanthin + O2  =  xanthoxin + C25-allenic-apo-aldehyde	abscisic acid biosynthesis
dihydroneopterin phosphate	dihydroneopterin-p*2-Amino-4-hydroxy-6-(erythro-1,2,3-trihydroxypropyl)dihydropteridine phosphate	C9 H14 N5 O7 P1 	C2(C(C(O)C(O)COP(O)(O)=O)=Nc1(c(=O)[nH]c(N)nc1N2))		3.6.1.-	dihydroneopterin phosphate + H2O  =  dihydro-neo-pterin + phosphate	tetrahydrofolate biosynthesis I
dihydroneopterin phosphate	dihydroneopterin-p*2-Amino-4-hydroxy-6-(erythro-1,2,3-trihydroxypropyl)dihydropteridine phosphate	C9 H14 N5 O7 P1 	C2(C(C(O)C(O)COP(O)(O)=O)=Nc1(c(=O)[nH]c(N)nc1N2))		3.6.1.-	dihydroneopterin phosphate + H2O  =  dihydro-neo-pterin + phosphate	tetrahydrofolate biosynthesis II
dihydroneopterin phosphate	dihydroneopterin-p*2-Amino-4-hydroxy-6-(erythro-1,2,3-trihydroxypropyl)dihydropteridine phosphate	C9 H14 N5 O7 P1 	C2(C(C(O)C(O)COP(O)(O)=O)=Nc1(c(=O)[nH]c(N)nc1N2))		3.6.1.-	dihydroneopterin triphosphate + H2O  =  dihydroneopterin phosphate + pyrophosphate	tetrahydrofolate biosynthesis I
dihydroneopterin phosphate	dihydroneopterin-p*2-Amino-4-hydroxy-6-(erythro-1,2,3-trihydroxypropyl)dihydropteridine phosphate	C9 H14 N5 O7 P1 	C2(C(C(O)C(O)COP(O)(O)=O)=Nc1(c(=O)[nH]c(N)nc1N2))		3.6.1.-	dihydroneopterin triphosphate + H2O  =  dihydroneopterin phosphate + pyrophosphate	tetrahydrofolate biosynthesis II
4-methyl-5-(beta-hydroxyethyl)thiazole phosphate	4-4-methyl-5-(2-phosphonooxyethyl)-thiazole*4-methyl-5-(2-phosphoethyl)-thiazole*THZ-P*4-Methyl-5-(2-phosphono-oxyethyl)-thiazole	C6 H10 N1 O4 P1 S1 	Cc1(c(scn1)CCOP(O)(=O)O)		2.5.1.3	4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate  =  thiamine-phosphate + pyrophosphate	thiamin biosynthesis
4-methyl-5-(beta-hydroxyethyl)thiazole phosphate	4-4-methyl-5-(2-phosphonooxyethyl)-thiazole*4-methyl-5-(2-phosphoethyl)-thiazole*THZ-P*4-Methyl-5-(2-phosphono-oxyethyl)-thiazole	C6 H10 N1 O4 P1 S1 	Cc1(c(scn1)CCOP(O)(=O)O)		THIAZOLSYN2-RXN	L-tyrosine + 1-deoxy-D-xylulose 5-phosphate + ThiS-COSH  =  4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-hydroxybenzyl alcohol + C1 of tyrosine + ThiS protein	thiamin biosynthesis
4-methyl-5-(beta-hydroxyethyl)thiazole phosphate	4-4-methyl-5-(2-phosphonooxyethyl)-thiazole*4-methyl-5-(2-phosphoethyl)-thiazole*THZ-P*4-Methyl-5-(2-phosphono-oxyethyl)-thiazole	C6 H10 N1 O4 P1 S1 	Cc1(c(scn1)CCOP(O)(=O)O)		2.7.1.50	ATP + 4-methyl-5-(beta-hydroxyethyl)thiazole  =  ADP + 4-methyl-5-(beta-hydroxyethyl)thiazole phosphate	thiamin biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.11	N-acetylglutamate semialdehyde + L-glutamate  =  N-alpha-acetylornithine + alpha-ketoglutarate	arginine biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.11	N-acetylglutamate semialdehyde + L-glutamate  =  N-alpha-acetylornithine + alpha-ketoglutarate	arginine biosynthesis II (acetyl cycle)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.1	oxaloacetate + L-glutamate  =  L-aspartate + alpha-ketoglutarate	asparagine biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.1	oxaloacetate + L-glutamate  =  L-aspartate + alpha-ketoglutarate	aspartate biosynthesis and degradation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	4.1.1.71	alpha-ketoglutarate + thiamin diphosphate  =  succinate-semialdehyde-thiamine PPi + CO2	menaquinone biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.52	3-phospho-hydroxypyruvate + L-glutamate  =  3-phospho-serine + alpha-ketoglutarate	serine biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	arginine biosynthesis III
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	proline biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.13	L-ornithine + alpha-ketoglutarate  =  L-glutamate + L-glutamate gamma-semialdehyde	arginine degradation II
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.17	L-glutamate + N-succinyl-2-amino-6-ketopimelate  =  alpha-ketoglutarate + N-succinyl-L,L-2,6-diaminopimelate	lysine biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle variation I
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle -- aerobic respiration
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.5	L-tyrosine + alpha-ketoglutarate  =  L-glutamate + p-hydroxyphenylpyruvate	tyrosine degradation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.5	L-tyrosine + alpha-ketoglutarate  =  L-glutamate + p-hydroxyphenylpyruvate	phenylalanine degradation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.19	alpha-ketoglutarate + 4-aminobutyrate  =  L-glutamate + succinate semialdehyde	glutamate degradation II
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.19	alpha-ketoglutarate + 4-aminobutyrate  =  L-glutamate + succinate semialdehyde	arginine degradation I
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	RXN-974	L-serine + alpha-ketoglutarate  =  hydroxypyruvate + L-glutamate	photorespiration
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.4	L-glutamate + glyoxylate  =  alpha-ketoglutarate + glycine	photorespiration
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.27	alpha-ketoglutarate + L-tryptophan  =  L-glutamate + indole-3-pyruvate	IAA biosynthesis I
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.2	alpha-ketoglutarate + L-alanine  =  L-glutamate + pyruvate	alanine degradation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.2	alpha-ketoglutarate + L-alanine  =  L-glutamate + pyruvate	alanine biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.9	naringenin + O2 + alpha-ketoglutarate  =  CO2 + succinate + dihydrokaempferol	flavonoid biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.19	leucopelargonidin + alpha-ketoglutarate + O2  =  pelargonidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.19	leucocyanidin + alpha-ketoglutarate + O2  =  cyanidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA4 + alpha-ketoglutarate + O2  =  GA34 + succinate + CO2	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA25 + alpha-ketoglutarate + O2  =  GA13 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA15 + alpha-ketoglutarate + O2  =  GA37 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA38 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA17 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA25 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.15	GA20 + alpha-ketoglutarate + O2  =  GA1 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.12	GA44 + alpha-ketoglutarate + O2  =  GA19 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA4 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	RXN1F-93	dihydrokaempferol + alpha-ketoglutarate + O2  =  kaempferol + succinate + CO2 + H2O	flavonol biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	RXN-527	dihydroquercetin + alpha-ketoglutarate + O2  =  quercetin + succinate + CO2 + H2O	flavonol biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.39	alpha-ketoglutarate + alpha-aminoadipate  =  L-glutamate + alpha-ketoadipate	lysine degradation II
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA15 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA15 + O2 + alpha-ketoglutarate  =  GA24 + H2O + CO2 + succinate	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA9 + succinate + 2 CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA36 + O2 + alpha-ketoglutarate  =  GA4 + succinate + 2 CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA14 + O2 + alpha-ketoglutarate  =  GA37 + CO2 + succinate	gibberellin biosynthesis II (early C-3 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA37 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2 + H2O	gibberellin biosynthesis II (early C-3 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA14 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA44 + CO2 + succinate	gibberellin biosynthesis III (early C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA20 + succinate + 2 CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA98 + succinate + CO2	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA97 + succinate + CO2	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA110 + succinate + CO2	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA34 + alpha-ketoglutarate + O2  =  GA34-catabolite + succinate + CO2 + H2O	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA51 + alpha-ketoglutarate + O2  =  GA51-catabolite + succinate + CO2 + H2O	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA51 + succinate + CO2	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA29 + alpha-ketoglutarate + O2  =  GA29-catabolite + succinate + CO2 + H2O	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.13	GA1 + alpha-ketoglutarate + O2  =  GA8 + succinate + CO2	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA8 + alpha-ketoglutarate + O2  =  GA8-catabolite + succinate + CO2 + H2O	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.-	GA20 + alpha-ketoglutarate + O2  =  GA29 + succinate + CO2	gibberellin inactivation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.22	eriodictyol + alpha-ketoglutarate + O2  =  luteolin + succinate + CO2 + H2O	luteolin biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.14.11.22	naringenin + alpha-ketoglutarate + O2  =  apigenin + succinate + CO2 + H2O	luteolin biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.4.1.3	NH3 + NAD(P)H + alpha-ketoglutarate  =  NAD(P)+ + H2O + L-glutamate	arginine biosynthesis III
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.4.1.2	H2O + NAD+ + L-glutamate  =  NH3 + NADH + alpha-ketoglutarate	glutamate degradation I
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.57	prephenate + L-glutamate  =  L-arogenate + alpha-ketoglutarate	tyrosine biosynthesis II
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.57	prephenate + L-glutamate  =  L-arogenate + alpha-ketoglutarate	phenylalanine biosynthesis I
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.5.1.8	NADPH + alpha-ketoglutarate + L-lysine  =  H2O + NADP+ + saccharopine	lysine degradation II
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.57	p-hydroxyphenylpyruvate + L-glutamate  =  L-tyrosine + alpha-ketoglutarate	tyrosine biosynthesis I
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	pantothenate biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	valine biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	valine degradation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.42	2-keto-4-methyl-pentanoate + L-glutamate  =  L-leucine + alpha-ketoglutarate	leucine biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.42	2-keto-4-methyl-pentanoate + L-glutamate  =  L-leucine + alpha-ketoglutarate	leucine degradation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.9	phenylpyruvate + L-glutamate  =  L-phenylalanine + alpha-ketoglutarate	phenylalanine biosynthesis II
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	ammonia assimilation cycle
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	glutamate biosynthesis II
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.42	2-keto-3-methyl-valerate + L-glutamate  =  L-isoleucine + alpha-ketoglutarate	isoleucine biosynthesis
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.42	2-keto-3-methyl-valerate + L-glutamate  =  L-isoleucine + alpha-ketoglutarate	isoleucine degradation
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	ammonia assimilation cycle
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	glutamate biosynthesis I
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.5	phenylpyruvate + L-glutamate  =  L-phenylalanine + alpha-ketoglutarate	phenylalanine biosynthesis II
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle variation I
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle -- aerobic respiration
alpha-ketoglutarate	ketoglutarate*&alpha;-ketoglutarate*2-oxoglutaric acid*&alpha;-ketoglutaric acid*&alpha;-oxoglutarate*2-oxoglutarate*2-ketoglutaric acid*2-ketoglutarate*2-oxopentanedionic acid*2-oxopentanedionate	C5 H6 O5 	C(O)(=O)C(=O)CCC(=O)O	LIGAND-CPD:C00026*CAS:328-50-7	2.6.1.9	imidazole acetol-phosphate + L-glutamate  =  L-histidinol-phosphate + alpha-ketoglutarate	histidine biosynthesis
GA12	GA12*gibberellin A12*gibberellin A<sub>12</sub>	C20 H28 O4 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		RXN1F-143	GA12 + O2  =  GA53 + H2O	gibberellin biosynthesis III (early C-13 hydroxylation)
GA12	GA12*gibberellin A12*gibberellin A<sub>12</sub>	C20 H28 O4 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA15 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA12	GA12*gibberellin A12*gibberellin A<sub>12</sub>	C20 H28 O4 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA14 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
GA12	GA12*gibberellin A12*gibberellin A<sub>12</sub>	C20 H28 O4 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA110 + succinate + CO2	gibberellin inactivation
GA12	GA12*gibberellin A12*gibberellin A<sub>12</sub>	C20 H28 O4 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.13.79	GA12-aldehyde + NADPH + O2  =  GA12 + NADP+ + H2O	GA12 biosynthesis
GA19	GA<sub>19</sub>*gibberellin A19*gibberellin A<sub>19</sub>	C20 H26 O6 	CC1(C(O)=O)([CH]2(C(C=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA17 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
GA19	GA<sub>19</sub>*gibberellin A19*gibberellin A<sub>19</sub>	C20 H26 O6 	CC1(C(O)=O)([CH]2(C(C=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA20 + succinate + 2 CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
GA19	GA<sub>19</sub>*gibberellin A19*gibberellin A<sub>19</sub>	C20 H26 O6 	CC1(C(O)=O)([CH]2(C(C=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.12	GA44 + alpha-ketoglutarate + O2  =  GA19 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
GA15	gibberellin A<sub>15</sub> (open lactone form)*GA<sub>15</sub> (open lactone form)*gibberellin A15*gibberellin A<sub>15</sub>	C20 H28 O5 	CC1(C(O)=O)([CH]2(C(CO)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA15 + alpha-ketoglutarate + O2  =  GA37 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
GA15	gibberellin A<sub>15</sub> (open lactone form)*GA<sub>15</sub> (open lactone form)*gibberellin A15*gibberellin A<sub>15</sub>	C20 H28 O5 	CC1(C(O)=O)([CH]2(C(CO)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA15 + O2 + alpha-ketoglutarate  =  GA24 + H2O + CO2 + succinate	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA15	gibberellin A<sub>15</sub> (open lactone form)*GA<sub>15</sub> (open lactone form)*gibberellin A15*gibberellin A<sub>15</sub>	C20 H28 O5 	CC1(C(O)=O)([CH]2(C(CO)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA15 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
zeta-carotene		C40 H60 	CC(C)=CCCC(C)=CCCC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)CCC=C(C)CCC=C(C)C		1.14.99.30	zeta-carotene  =  lycopene	carotenoid biosynthesis
zeta-carotene		C40 H60 	CC(C)=CCCC(C)=CCCC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)CCC=C(C)CCC=C(C)C		RXN1F-145	phytoene  =  zeta-carotene	carotenoid biosynthesis
cis-delta3-enoyl-CoA	RCH=CHCH2CO-CoA				5.3.3.8	cis-delta3-enoyl-CoA  =  trans-delta2-enoyl-CoA	fatty acid beta-oxidation
unknown					1.14.14.-	unknown  =  indole-3-carboxaldehyde	camalexin biosynthesis
xanthosine	9 &beta;-D-ribofuranosylxanthine	C10 H12 N4 O6 	c1(c2(c([nH]c([nH]1)=O)n(cn2)[CH]3([CH](O)[CH](O)[CH](O3)CO)))(=O)	LIGAND-CPD:C01762*LIGAND:C01762*CAS:146-80-5	XANTHOSINEPHOSPHORY-RXN	xanthosine + phosphate  =  ribose-1-phosphate + xanthine	ureide biosynthesis
xanthosine	9 &beta;-D-ribofuranosylxanthine	C10 H12 N4 O6 	c1(c2(c([nH]c([nH]1)=O)n(cn2)[CH]3([CH](O)[CH](O)[CH](O3)CO)))(=O)	LIGAND-CPD:C01762*LIGAND:C01762*CAS:146-80-5	3.2.2.1	xanthosine + H2O  =  xanthine + D-ribose	purine degradation
xanthosine	9 &beta;-D-ribofuranosylxanthine	C10 H12 N4 O6 	c1(c2(c([nH]c([nH]1)=O)n(cn2)[CH]3([CH](O)[CH](O)[CH](O3)CO)))(=O)	LIGAND-CPD:C01762*LIGAND:C01762*CAS:146-80-5	3.2.2.1	xanthosine + H2O  =  xanthine + D-ribose	salvage pathways of purine nucleosides
xanthosine	9 &beta;-D-ribofuranosylxanthine	C10 H12 N4 O6 	c1(c2(c([nH]c([nH]1)=O)n(cn2)[CH]3([CH](O)[CH](O)[CH](O3)CO)))(=O)	LIGAND-CPD:C01762*LIGAND:C01762*CAS:146-80-5	3.5.4.15	H2O + guanosine  =  NH3 + xanthosine	purine degradation
xanthosine	9 &beta;-D-ribofuranosylxanthine	C10 H12 N4 O6 	c1(c2(c([nH]c([nH]1)=O)n(cn2)[CH]3([CH](O)[CH](O)[CH](O3)CO)))(=O)	LIGAND-CPD:C01762*LIGAND:C01762*CAS:146-80-5	3.5.4.15	H2O + guanosine  =  NH3 + xanthosine	salvage pathways of purine nucleosides
xanthosine	9 &beta;-D-ribofuranosylxanthine	C10 H12 N4 O6 	c1(c2(c([nH]c([nH]1)=O)n(cn2)[CH]3([CH](O)[CH](O)[CH](O3)CO)))(=O)	LIGAND-CPD:C01762*LIGAND:C01762*CAS:146-80-5	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	purine degradation
xanthosine	9 &beta;-D-ribofuranosylxanthine	C10 H12 N4 O6 	c1(c2(c([nH]c([nH]1)=O)n(cn2)[CH]3([CH](O)[CH](O)[CH](O3)CO)))(=O)	LIGAND-CPD:C01762*LIGAND:C01762*CAS:146-80-5	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	salvage pathways of purine nucleosides
xanthosine	9 &beta;-D-ribofuranosylxanthine	C10 H12 N4 O6 	c1(c2(c([nH]c([nH]1)=O)n(cn2)[CH]3([CH](O)[CH](O)[CH](O3)CO)))(=O)	LIGAND-CPD:C01762*LIGAND:C01762*CAS:146-80-5	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	ureide biosynthesis
2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate	(1<i>S</i>,6<i>R</i>)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate	C11 H12 O6 	C(=O)(O)CCC(=O)C1(C(C(O)=O)C(O)C=CC=1)	LIGAND-CPD:C05817	O-SUCCINYLBENZOATE-COA-SYN-RXN	2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate  =  O-succinylbenzoate + H2O	phylloquinone biosynthesis
2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate	(1<i>S</i>,6<i>R</i>)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate	C11 H12 O6 	C(=O)(O)CCC(=O)C1(C(C(O)=O)C(O)C=CC=1)	LIGAND-CPD:C05817	O-SUCCINYLBENZOATE-COA-SYN-RXN	2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate  =  O-succinylbenzoate + H2O	menaquinone biosynthesis
2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate	(1<i>S</i>,6<i>R</i>)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate	C11 H12 O6 	C(=O)(O)CCC(=O)C1(C(C(O)=O)C(O)C=CC=1)	LIGAND-CPD:C05817	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	phylloquinone biosynthesis
2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate	(1<i>S</i>,6<i>R</i>)-6-hydroxy-2-succinylcyclohexa-2,4-diene-1-carboxylate	C11 H12 O6 	C(=O)(O)CCC(=O)C1(C(C(O)=O)C(O)C=CC=1)	LIGAND-CPD:C05817	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	menaquinone biosynthesis
phytoene	7,7',8,8',11,11',12,12'-octahydro-&psi;,&psi;-caro	C40 H64 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CC=CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C	CAS:540-04-5	RXN1F-145	phytoene  =  zeta-carotene	carotenoid biosynthesis
phytoene	7,7',8,8',11,11',12,12'-octahydro-&psi;,&psi;-caro	C40 H64 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CC=CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C	CAS:540-04-5	2.5.1.32	2 geranylgeranyl-PP  =  phytoene + 2 pyrophosphate	carotenoid biosynthesis
shikimate	shikimic acid	C7 H10 O5 	C(=O)(O)C1(=[CH][CH](O)[CH](O)[CH](O)[CH2]1)	LIGAND:C00493*CAS:138-59-0	2.7.1.71	shikimate + ATP  =  shikimate-3-phosphate + ADP	chorismate biosynthesis
shikimate	shikimic acid	C7 H10 O5 	C(=O)(O)C1(=[CH][CH](O)[CH](O)[CH](O)[CH2]1)	LIGAND:C00493*CAS:138-59-0	2.3.1.133	shikimate + coumaroyl-CoA  =  4-coumaroylshikimate + coenzyme A	lignin biosynthesis
shikimate	shikimic acid	C7 H10 O5 	C(=O)(O)C1(=[CH][CH](O)[CH](O)[CH](O)[CH2]1)	LIGAND:C00493*CAS:138-59-0	1.1.1.25	NADPH + 3-dehydro-shikimate  =  NADP+ + shikimate	chorismate biosynthesis
shikimate	shikimic acid	C7 H10 O5 	C(=O)(O)C1(=[CH][CH](O)[CH](O)[CH](O)[CH2]1)	LIGAND:C00493*CAS:138-59-0	2.3.1.133	caffeoylshikimate + coenzyme A  =  caffeoyl-CoA + shikimate	lignin biosynthesis
UDP-L-rhamnose	UDP-rhamnose	C15 H24 N2 O16 P2 	CC1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3)))		RXN-5482	UDP-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+ + H2O	UDP-L-rhamnose biosynthesis
UDP-L-rhamnose	UDP-rhamnose	C15 H24 N2 O16 P2 	CC1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3)))		RXN-5481	UDP-4-dehydro-6-deoxy-D-glucose + NADPH  =  UDP-L-rhamnose + NADP+	UDP-L-rhamnose biosynthesis
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides II
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides I
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	3.5.4.25	3 H2O + GTP  =  pyrophosphate + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate + formate	riboflavin and FMN and FAD biosynthesis
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	2.7.6.5	GTP + ATP  =  guanosine 3'-diphosphate 5'-triphosphate + AMP	ppGpp biosynthesis
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	3.5.4.16	2 H2O + GTP  =  dihydroneopterin triphosphate + formate + H2O	tetrahydrofolate biosynthesis I
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	3.5.4.16	2 H2O + GTP  =  dihydroneopterin triphosphate + formate + H2O	tetrahydrofolate biosynthesis II
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	RXN0-746	GTP + reduced flavodoxin  =  dGTP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	2.7.7.13	mannose-1-phosphate + GTP  =  GDP-mannose + pyrophosphate	ascorbate biosynthesis
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	4.1.1.32	oxaloacetate + GTP  =  CO2 + phosphoenolpyruvate + GDP	phenylalanine degradation
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	2.7.7.30	beta-L-fucose 1-phosphate + GTP  =  guanosine diphosphate fucose + pyrophosphate	GDP-L-fucose biosynthesis II (from L-fucose)
GTP	guanylyl imidodiphosphate*guanosine 5'-triphosphate*guanosine-triphosphate	C10 H16 N5 O14 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C00044*LIGAND-CPD:c00044*CAS:86-01-1	2.7.4.6	GDP + ATP  =  GTP + ADP	de novo biosynthesis of purine nucleotides I
phosphoribosyl-AMP	N1-(5-phospho-D-ribosyl)-AMP*5-phosphoribosyl-AMP*N-(5-phospho-D-ribosyl)-AMP*N-(5'-phospho-D-ribosyl)-AMP	C15 H23 N5 O14 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n3(c2(ncn(c(=N)c2nc3)C4(OC(C(O)C(O)4)COP(O)(=O)O))))		3.5.4.19	phosphoribosyl-AMP + H2O  =  phosphoribosylformiminoAICAR-phosphate	histidine biosynthesis
phosphoribosyl-AMP	N1-(5-phospho-D-ribosyl)-AMP*5-phosphoribosyl-AMP*N-(5-phospho-D-ribosyl)-AMP*N-(5'-phospho-D-ribosyl)-AMP	C15 H23 N5 O14 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n3(c2(ncn(c(=N)c2nc3)C4(OC(C(O)C(O)4)COP(O)(=O)O))))		3.6.1.31	phosphoribosyl-ATP + H2O  =  phosphoribosyl-AMP + pyrophosphate	histidine biosynthesis
salicyloyl-CoA		C28 H40 N7 O18 P3 S1 	C(NCCC(=O)NCCSC(=O)c1(c(O)cccc1))(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC2(OC(C(O)C2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))		RXN-2009	salicyloyl-CoA + H2O  =  salicylate + coenzyme A	salicylic acid biosynthesis
salicyloyl-CoA		C28 H40 N7 O18 P3 S1 	C(NCCC(=O)NCCSC(=O)c1(c(O)cccc1))(=O)C(O)C(C)(C)COP(O)(=O)OP(=O)(O)OCC2(OC(C(O)C2OP(=O)(O)O)n3(c4(c(nc3)c(N)ncn4)))		RXN-2008	benzoyl-CoA  =  salicyloyl-CoA	salicylic acid biosynthesis
L-methionyl-tRNAmet	L-METHIONYL-TRNA*L-METHIONYL-TRNA(MET)				6.1.1.10	tRNAmet + L-methionine + ATP  =  L-methionyl-tRNAmet + pyrophosphate + AMP	tRNA charging pathway
nicotinate nucleotide	nicotinate dinucleotide*&beta;-nicotinate-D-nucleotide*NaMN*nicotinic acid nucleotide*nicotinic acid mononucleotide*nicotinic acid ribonucleotide*nicotinate-D-ribonucleotide*nicotinate ribonucleotide*nicotinate mononucleotide*deamido-nicotinamide mononucleotide*deamido-NMN*Beta-nicotinate D-ribonucleotide	C11 H15 N1 O9 P1 	[CH]2([n+1]1(cc(C(=O)O)ccc1))(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O)	CAS:321-02-8	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis II (from tryptophan)
nicotinate nucleotide	nicotinate dinucleotide*&beta;-nicotinate-D-nucleotide*NaMN*nicotinic acid nucleotide*nicotinic acid mononucleotide*nicotinic acid ribonucleotide*nicotinate-D-ribonucleotide*nicotinate ribonucleotide*nicotinate mononucleotide*deamido-nicotinamide mononucleotide*deamido-NMN*Beta-nicotinate D-ribonucleotide	C11 H15 N1 O9 P1 	[CH]2([n+1]1(cc(C(=O)O)ccc1))(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O)	CAS:321-02-8	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis I (from aspartate)
nicotinate nucleotide	nicotinate dinucleotide*&beta;-nicotinate-D-nucleotide*NaMN*nicotinic acid nucleotide*nicotinic acid mononucleotide*nicotinic acid ribonucleotide*nicotinate-D-ribonucleotide*nicotinate ribonucleotide*nicotinate mononucleotide*deamido-nicotinamide mononucleotide*deamido-NMN*Beta-nicotinate D-ribonucleotide	C11 H15 N1 O9 P1 	[CH]2([n+1]1(cc(C(=O)O)ccc1))(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O)	CAS:321-02-8	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	NAD biosynthesis II (from tryptophan)
nicotinate nucleotide	nicotinate dinucleotide*&beta;-nicotinate-D-nucleotide*NaMN*nicotinic acid nucleotide*nicotinic acid mononucleotide*nicotinic acid ribonucleotide*nicotinate-D-ribonucleotide*nicotinate ribonucleotide*nicotinate mononucleotide*deamido-nicotinamide mononucleotide*deamido-NMN*Beta-nicotinate D-ribonucleotide	C11 H15 N1 O9 P1 	[CH]2([n+1]1(cc(C(=O)O)ccc1))(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O)	CAS:321-02-8	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	NAD biosynthesis I (from aspartate)
nicotinate nucleotide	nicotinate dinucleotide*&beta;-nicotinate-D-nucleotide*NaMN*nicotinic acid nucleotide*nicotinic acid mononucleotide*nicotinic acid ribonucleotide*nicotinate-D-ribonucleotide*nicotinate ribonucleotide*nicotinate mononucleotide*deamido-nicotinamide mononucleotide*deamido-NMN*Beta-nicotinate D-ribonucleotide	C11 H15 N1 O9 P1 	[CH]2([n+1]1(cc(C(=O)O)ccc1))(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O)	CAS:321-02-8	2.7.7.18	ATP + nicotinate nucleotide  =  pyrophosphate + deamido-NAD	pyridine nucleotide cycling
nicotinate nucleotide	nicotinate dinucleotide*&beta;-nicotinate-D-nucleotide*NaMN*nicotinic acid nucleotide*nicotinic acid mononucleotide*nicotinic acid ribonucleotide*nicotinate-D-ribonucleotide*nicotinate ribonucleotide*nicotinate mononucleotide*deamido-nicotinamide mononucleotide*deamido-NMN*Beta-nicotinate D-ribonucleotide	C11 H15 N1 O9 P1 	[CH]2([n+1]1(cc(C(=O)O)ccc1))(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O)	CAS:321-02-8	3.5.1.42	nicotinamide mononucleotide + H2O  =  NH3 + nicotinate nucleotide	pyridine nucleotide cycling
nicotinate nucleotide	nicotinate dinucleotide*&beta;-nicotinate-D-nucleotide*NaMN*nicotinic acid nucleotide*nicotinic acid mononucleotide*nicotinic acid ribonucleotide*nicotinate-D-ribonucleotide*nicotinate ribonucleotide*nicotinate mononucleotide*deamido-nicotinamide mononucleotide*deamido-NMN*Beta-nicotinate D-ribonucleotide	C11 H15 N1 O9 P1 	[CH]2([n+1]1(cc(C(=O)O)ccc1))(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O)	CAS:321-02-8	2.4.2.11	nicotinate + H2O + PRPP + ATP  =  nicotinate nucleotide + pyrophosphate + phosphate + ADP	pyridine nucleotide cycling
O-succinylbenzoyl-CoA	2-Succinylbenzoyl-CoA*Succinylbenzoyl-CoA	C32 H44 N7 O20 P3 S1 	c1(c2(c(ncn1)n(cn2)C3(OC(C(C(O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)c4(c(cccc4)C(=O)CCC(=O)O))))(N)		4.1.3.36	O-succinylbenzoyl-CoA  =  coenzyme A + 1,4-dihydroxy-2-naphthoate	menaquinone biosynthesis
O-succinylbenzoyl-CoA	2-Succinylbenzoyl-CoA*Succinylbenzoyl-CoA	C32 H44 N7 O20 P3 S1 	c1(c2(c(ncn1)n(cn2)C3(OC(C(C(O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)c4(c(cccc4)C(=O)CCC(=O)O))))(N)		6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  AMP + pyrophosphate + O-succinylbenzoyl-CoA	menaquinone biosynthesis
2-methyl-6-phytyl-1,4-benzoquinone		C27 H46 O2 	CC(CCCC(C)CCCC(C)C)CCCC(C)=CCc1(c(O)c(C)cc(O)c1)		RXN-2561	2-methyl-6-phytyl-1,4-benzoquinone  =  delta-tocopherol	vitamin E biosynthesis
2-methyl-6-phytyl-1,4-benzoquinone		C27 H46 O2 	CC(CCCC(C)CCCC(C)C)CCCC(C)=CCc1(c(O)c(C)cc(O)c1)		2.1.1.-	2-methyl-6-phytyl-1,4-benzoquinone + S-adenosyl-L-methionine  =  2,3-dimethyl-6-phytyl-1,4-benzoquinone + S-adenosyl-homocysteine	vitamin E biosynthesis
2-methyl-6-phytyl-1,4-benzoquinone		C27 H46 O2 	CC(CCCC(C)CCCC(C)C)CCCC(C)=CCc1(c(O)c(C)cc(O)c1)		RXN-2541	homogentisate + phytyl pyrophosphate  =  2-methyl-6-phytyl-1,4-benzoquinone + CO2 + pyrophosphate	vitamin E biosynthesis
1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-phosphate	1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-P*1-(2-carboxyphenylamino)-1-deoxy-D-ribulose-5-phosphate*1-(2-carboxyphenylamino)-1-deoxy-D-ribulose-5-P	C12 H16 N1 O9 P1 	C(OP(O)(O)=O)C(O)C(O)C(=O)CNc1(c(C(O)=O)cccc1)		4.1.1.48	1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-phosphate  =  indole-3-glycerol-phosphate + CO2 + H2O	tryptophan biosynthesis
1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-phosphate	1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-P*1-(2-carboxyphenylamino)-1-deoxy-D-ribulose-5-phosphate*1-(2-carboxyphenylamino)-1-deoxy-D-ribulose-5-P	C12 H16 N1 O9 P1 	C(OP(O)(O)=O)C(O)C(O)C(=O)CNc1(c(C(O)=O)cccc1)		5.3.1.24	N-(5'-phosphoribosyl)-anthranilate  =  1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-phosphate	tryptophan biosynthesis
1-methoxy-3-indolylmethyl-glucosinolate	neoglucobrassicin	C17 H22 N2 O10 S2 	C(O)C1(C(OC(O)C(O)C1O)SC(=NOS(O)(=O)=O)Cc2(cn(OC)c3(c2cccc3)))		RXN-2161	indolylmethyl-glucosinolate  =  1-methoxy-3-indolylmethyl-glucosinolate	glucosinolate biosynthesis from tryptophan
dTMP	T*thymidylic acid*thymidine monophosphate*deoxythymidylate*TMP*thymidine-5'-monophosphate*thymidine-phosphate*thymidine-5'-phosphate*Deoxythymidine 5'-phosphate*5'-Thymidylic acid*Deoxythymidylic acid*Thymidylate	C10 H15 N2 O8 P1 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(O)(O)=O))	LIGAND-CPD:C00364*CAS:365-07-1	2.7.4.9	dTMP + ATP  =  dTDP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dTMP	T*thymidylic acid*thymidine monophosphate*deoxythymidylate*TMP*thymidine-5'-monophosphate*thymidine-phosphate*thymidine-5'-phosphate*Deoxythymidine 5'-phosphate*5'-Thymidylic acid*Deoxythymidylic acid*Thymidylate	C10 H15 N2 O8 P1 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(O)(O)=O))	LIGAND-CPD:C00364*CAS:365-07-1	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	formylTHF biosynthesis
dTMP	T*thymidylic acid*thymidine monophosphate*deoxythymidylate*TMP*thymidine-5'-monophosphate*thymidine-phosphate*thymidine-5'-phosphate*Deoxythymidine 5'-phosphate*5'-Thymidylic acid*Deoxythymidylic acid*Thymidylate	C10 H15 N2 O8 P1 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(O)(O)=O))	LIGAND-CPD:C00364*CAS:365-07-1	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	formylTHF biosynthesis I
dTMP	T*thymidylic acid*thymidine monophosphate*deoxythymidylate*TMP*thymidine-5'-monophosphate*thymidine-phosphate*thymidine-5'-phosphate*Deoxythymidine 5'-phosphate*5'-Thymidylic acid*Deoxythymidylic acid*Thymidylate	C10 H15 N2 O8 P1 	Cc1(cn(c(=O)[nH]c1=O)C2(OC(C(C2)O)COP(O)(O)=O))	LIGAND-CPD:C00364*CAS:365-07-1	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	de novo biosynthesis of pyrimidine deoxyribonucleotides
siroheme 		C42 H44 N4 O16 FE1 	C(O)(=O)CC8(C7(=Cc1(n2(c(c(CCC(=O)O)c1CC(=O)O)C=c4(n3([Fe]62(N5(C(=Cc3c(CCC(=O)O)c4CC(=O)O)C(CC(=O)O)(C)[CH](CCC(=O)O)C5=CC(=N67)[CH]8CCC(=O)O))))))))(C)		4.99.1.4	sirohydrochlorin + Fe2+  =  siroheme  + 2 H+	biosynthesis of proto- and siroheme
abscisic acid aldehyde	ABA aldehyde	C15 H20 O3 	CC(=CC=O)C=CC1(O)(C(C)=CC(=O)CC(C)1C)		RXN-700	abscisic acid aldehyde  =  abscisate	abscisic acid biosynthesis
abscisic acid aldehyde	ABA aldehyde	C15 H20 O3 	CC(=CC=O)C=CC1(O)(C(C)=CC(=O)CC(C)1C)		RXN-699	xanthoxin  =  abscisic acid aldehyde	abscisic acid biosynthesis
abscisate	abscisic acid*ABA	C15 H20 O3 	CC(=CC=O)C=CC1(O)(C(C)=CC(=O)CC(C)1C)		RXN-700	abscisic acid aldehyde  =  abscisate	abscisic acid biosynthesis
GA53	GA53*gibberellin A53*gibberellin A<sub>53</sub>	C20 H28 O5 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA44 + CO2 + succinate	gibberellin biosynthesis III (early C-13 hydroxylation)
GA53	GA53*gibberellin A53*gibberellin A<sub>53</sub>	C20 H28 O5 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA97 + succinate + CO2	gibberellin inactivation
GA53	GA53*gibberellin A53*gibberellin A<sub>53</sub>	C20 H28 O5 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C(O)=O)(CC(O)(CC3)C(C4)=C))))		RXN1F-143	GA12 + O2  =  GA53 + H2O	gibberellin biosynthesis III (early C-13 hydroxylation)
24-methylenecycloartenol	24(28)-methylenecycloartenol	C31 H52 O1 	CC(C)C(=C)CCC(C)C1(C5(C)(C(C)(CC1)C2(C4(C3([CH](CC2)C(C)(C)C(O)CC3)(C4))(CC5))))		2.1.1.-	24-methylenecycloartenol + S-adenosyl-homocysteine  =  cycloeucalenol + S-adenosyl-L-methionine	sterol biosynthesis
24-methylenecycloartenol	24(28)-methylenecycloartenol	C31 H52 O1 	CC(C)C(=C)CCC(C)C1(C5(C)(C(C)(CC1)C2(C4(C3([CH](CC2)C(C)(C)C(O)CC3)(C4))(CC5))))		2.1.1.41	cycloartenol + S-adenosyl-L-methionine  =  24-methylenecycloartenol + S-adenosyl-homocysteine	sterol biosynthesis
brassinolide		C28 H48 O6 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)OC3)CC(O)C(O)C4)(C))))		RXN-720	castasterone  =  brassinolide	brassinosteroid biosynthesis I
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		RXN-4231	campest-4-en-3-one + O2  =  22alpha-hydroxy-campest-4-en-3-one + H2O	brassinosteroid biosynthesis II
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis III
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis II
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis I
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		5.3.3.1	campest-5-en-3-one  =  campest-4-en-3-one	brassinosteroid biosynthesis III
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		1.1.1.51	campesterol + NAD(P)+  =  campest-4-en-3-one + NAD(P)H	brassinosteroid biosynthesis III
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		1.1.1.145	campest-4-en-3beta-ol  =  campest-4-en-3-one	brassinosteroid biosynthesis III
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		1.1.1.145	campest-4-en-3beta-ol  =  campest-4-en-3-one	brassinosteroid biosynthesis II
campest-4-en-3-one	methylcholestenone*(24<i>R</i>)-24-methyl-cholest-4-en-3-one*3-dehydro-&Delta;<sup>4-5</sup>-campesterol	C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		1.1.1.145	campest-4-en-3beta-ol  =  campest-4-en-3-one	brassinosteroid biosynthesis I
5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione	4-(1-D-Ribitylamino)-5-aminouracil*4-(1-D-ribitylamino)-5-amino-2,6-dihydroxypyrimidine *4-(1-D-ribitylamino)-5-aminouracil	C9 H16 N4 O6 	C(O)C(O)C(O)C(O)CNc1(c(N)c(=O)[nH]c([nH]1)=O)		LUMAZINESYN-RXN	5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + 3,4-dihydroxy-2-butanone-4-P  =  6,7-dimethyl-8-(1-D-ribityl)lumazine + phosphate + O2	riboflavin and FMN and FAD biosynthesis
5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione	4-(1-D-Ribitylamino)-5-aminouracil*4-(1-D-ribitylamino)-5-amino-2,6-dihydroxypyrimidine *4-(1-D-ribitylamino)-5-aminouracil	C9 H16 N4 O6 	C(O)C(O)C(O)C(O)CNc1(c(N)c(=O)[nH]c([nH]1)=O)		RIBOPHOSPHAT-RXN	5-amino-6-(5'-phosphoribitylamino)uracil + H2O  =  5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + phosphate	riboflavin and FMN and FAD biosynthesis
5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione	4-(1-D-Ribitylamino)-5-aminouracil*4-(1-D-ribitylamino)-5-amino-2,6-dihydroxypyrimidine *4-(1-D-ribitylamino)-5-aminouracil	C9 H16 N4 O6 	C(O)C(O)C(O)C(O)CNc1(c(N)c(=O)[nH]c([nH]1)=O)		2.5.1.9	2 6,7-dimethyl-8-(1-D-ribityl)lumazine  =  5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + riboflavin	riboflavin and FMN and FAD biosynthesis
protoporphyrin IX	protoporphyrin	C34 H34 N4 O4 	Cc5(c(CCC(=O)O)c4(C=C1(N=C(C(C)=C1CCC(=O)O)C=c2(nc(c(c2C)C=C)=CC3(=NC(C(=C3C)C=C)=Cc(n4)5)))))	CAS:553-12-8	4.99.1.1	Fe2+ + protoporphyrin IX  =  2 H+ + protoheme	biosynthesis of proto- and siroheme
protoporphyrin IX	protoporphyrin	C34 H34 N4 O4 	Cc5(c(CCC(=O)O)c4(C=C1(N=C(C(C)=C1CCC(=O)O)C=c2(nc(c(c2C)C=C)=CC3(=NC(C(=C3C)C=C)=Cc(n4)5)))))	CAS:553-12-8	6.6.1.1	ATP + protoporphyrin IX + Mg2+ + H2O  =  Mg-protoporphyrin + H+ + phosphate + ADP	chlorophyllide a biosynthesis
protoporphyrin IX	protoporphyrin	C34 H34 N4 O4 	Cc5(c(CCC(=O)O)c4(C=C1(N=C(C(C)=C1CCC(=O)O)C=c2(nc(c(c2C)C=C)=CC3(=NC(C(=C3C)C=C)=Cc(n4)5)))))	CAS:553-12-8	1.3.3.4	1.5 O2 + protoporphyrinogen  =  3 H2O + protoporphyrin IX	chlorophyllide a biosynthesis
protoporphyrin IX	protoporphyrin	C34 H34 N4 O4 	Cc5(c(CCC(=O)O)c4(C=C1(N=C(C(C)=C1CCC(=O)O)C=c2(nc(c(c2C)C=C)=CC3(=NC(C(=C3C)C=C)=Cc(n4)5)))))	CAS:553-12-8	1.3.3.4	1.5 O2 + protoporphyrinogen  =  3 H2O + protoporphyrin IX	biosynthesis of proto- and siroheme
131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester	13<SUP>1</SUP>-hydroxy-Mg-protoporphyrin IX 13-monomethyl ester	C35 H34 N4 O5 MG1 	Cc6(c(C(O)CC(=O)OC)c1(n7([Mg]35(n4(c(C=C2(C(C)=C(C(C=1)=N23)CCC(O)=O))c(C)c(C=C)c4C=C8(N5=C(C=c67)C(C=C)=C(C)8))))))		1.14.13.81	131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + 2 H2O	chlorophyllide a biosynthesis
131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester	13<SUP>1</SUP>-hydroxy-Mg-protoporphyrin IX 13-monomethyl ester	C35 H34 N4 O5 MG1 	Cc6(c(C(O)CC(=O)OC)c1(n7([Mg]35(n4(c(C=C2(C(C)=C(C(C=1)=N23)CCC(O)=O))c(C)c(C=C)c4C=C8(N5=C(C=c67)C(C=C)=C(C)8))))))		1.14.13.81	Mg-protoporphyrin monomethyl ester + NADPH + H+ + O2  =  131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + H2O	chlorophyllide a biosynthesis
gamma-tocopherol		C28 H48 O2 	Cc2(c1(OC(C)(CCc1cc(O)c(C)2)CCCC(C)CCCC(C)CCCC(C)C))		2.1.1.95	gamma-tocopherol + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + alpha-tocopherol	vitamin E biosynthesis
gamma-tocopherol		C28 H48 O2 	Cc2(c1(OC(C)(CCc1cc(O)c(C)2)CCCC(C)CCCC(C)CCCC(C)C))		RXN-2543	2,3-dimethyl-6-phytyl-1,4-benzoquinone  =  gamma-tocopherol	vitamin E biosynthesis
quinolinate	2,3-pyridinedicarboxylic acid*2,3-pyridinedicarboxylate*quinolinic acid*pyridine-2,3-dicarboxylic acid*pyridine-2,3-dicarboxylate	C7 H5 N1 O4 	C(O)(=O)c1(c(C(=O)O)cccn1)	CAS:89-00-9	RXN-5721	2-amino-3-carboxymuconate semialdehyde  =  quinolinate + H2O	NAD biosynthesis II (from tryptophan)
quinolinate	2,3-pyridinedicarboxylic acid*2,3-pyridinedicarboxylate*quinolinic acid*pyridine-2,3-dicarboxylic acid*pyridine-2,3-dicarboxylate	C7 H5 N1 O4 	C(O)(=O)c1(c(C(=O)O)cccn1)	CAS:89-00-9	QUINOLINATE-SYNTHA-RXN	iminoaspartate + dihydroxy-acetone-phosphate  =  quinolinate + 2 H2O + phosphate	NAD biosynthesis I (from aspartate)
quinolinate	2,3-pyridinedicarboxylic acid*2,3-pyridinedicarboxylate*quinolinic acid*pyridine-2,3-dicarboxylic acid*pyridine-2,3-dicarboxylate	C7 H5 N1 O4 	C(O)(=O)c1(c(C(=O)O)cccn1)	CAS:89-00-9	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis II (from tryptophan)
quinolinate	2,3-pyridinedicarboxylic acid*2,3-pyridinedicarboxylate*quinolinic acid*pyridine-2,3-dicarboxylic acid*pyridine-2,3-dicarboxylate	C7 H5 N1 O4 	C(O)(=O)c1(c(C(=O)O)cccn1)	CAS:89-00-9	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis I (from aspartate)
deoxyuridine	2-Deoxyuridine	C9 H12 N2 O5 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)CO))	LIGAND:C00526*CAS:951-78-0	URA-PHOSPH-RXN	phosphate + deoxyuridine  =  deoxyribose-1-phosphate + uracil	(deoxy)ribose phosphate degradation
deoxyuridine	2-Deoxyuridine	C9 H12 N2 O5 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)CO))	LIGAND:C00526*CAS:951-78-0	3.5.4.5	H2O + deoxycytidine  =  NH3 + deoxyuridine	(deoxy)ribose phosphate degradation
trans-2-hexenol		C6 H12 O1 	CCCC=CCO		RXN-1348	trans-2-hexenal  =  trans-2-hexenol	lipoxygenase pathway
uracil		C4 H4 N2 O2 	c1(=O)(cc[nH]c([nH]1)=O)	LIGAND:C00106*CAS:66-22-8	1.3.1.2	NADPH + uracil  =  NADP+ + dihydrouracil	beta-alanine biosynthesis III
uracil		C4 H4 N2 O2 	c1(=O)(cc[nH]c([nH]1)=O)	LIGAND:C00106*CAS:66-22-8	2.4.2.3	phosphate + uridine  =  ribose-1-phosphate + uracil	(deoxy)ribose phosphate degradation
uracil		C4 H4 N2 O2 	c1(=O)(cc[nH]c([nH]1)=O)	LIGAND:C00106*CAS:66-22-8	URA-PHOSPH-RXN	phosphate + deoxyuridine  =  deoxyribose-1-phosphate + uracil	(deoxy)ribose phosphate degradation
tRNAtyr	TRNA(TYR)				6.1.1.1	L-tyrosine + tRNAtyr + ATP  =  L-tyrosyl-tRNAtyr + pyrophosphate + AMP	tRNA charging pathway
3-dehydro-shikimate	3-dehydroshikimic acid*5-dehydroshikimic acid*5-dehydroshikimate	C7 H8 O5 	C(=O)(O)C1(=[CH]C(=O)[CH](O)[CH]([CH2]1)O)	CAS:2922-42-1	1.1.1.25	NADPH + 3-dehydro-shikimate  =  NADP+ + shikimate	chorismate biosynthesis
3-dehydro-shikimate	3-dehydroshikimic acid*5-dehydroshikimic acid*5-dehydroshikimate	C7 H8 O5 	C(=O)(O)C1(=[CH]C(=O)[CH](O)[CH]([CH2]1)O)	CAS:2922-42-1	4.2.1.10	3-dehydroquinate  =  H2O + 3-dehydro-shikimate	chorismate biosynthesis
campest-5-en-3-one		C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(=O)CC4)(C))))		5.3.3.1	campest-5-en-3-one  =  campest-4-en-3-one	brassinosteroid biosynthesis III
campest-5-en-3-one		C28 H46 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(=O)CC4)(C))))		1.1.1.145	campesterol + NAD+  =  campest-5-en-3-one + NADH	brassinosteroid biosynthesis III
(22alpha)-hydroxy-campesterol	(22<i>S</i>)-22-hydroxy-campesterol	C28 H48 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4226	(22alpha)-hydroxy-campesterol  =  22alpha-hydroxy-campest-4-en-3-one	brassinosteroid biosynthesis II
(22alpha)-hydroxy-campesterol	(22<i>S</i>)-22-hydroxy-campesterol	C28 H48 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		1.14.-.-	campesterol + O2 + reduced acceptor  =  (22alpha)-hydroxy-campesterol + H2O + acceptor	brassinosteroid biosynthesis II
22alpha-hydroxy-campest-4-en-3-one	(22<i>S</i>)-22-hydroxy-campest-4-en-3-one*(22<i>S</i>,24<i>R</i>)-22-hydroxy-ergost-4-en-3-one	C28 H46 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		1.3.99.-	22alpha-hydroxy-campest-4-en-3-one + NADPH  =  22alpha-hydroxy-5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis II
22alpha-hydroxy-campest-4-en-3-one	(22<i>S</i>)-22-hydroxy-campest-4-en-3-one*(22<i>S</i>,24<i>R</i>)-22-hydroxy-ergost-4-en-3-one	C28 H46 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		RXN-4226	(22alpha)-hydroxy-campesterol  =  22alpha-hydroxy-campest-4-en-3-one	brassinosteroid biosynthesis II
22alpha-hydroxy-campest-4-en-3-one	(22<i>S</i>)-22-hydroxy-campest-4-en-3-one*(22<i>S</i>,24<i>R</i>)-22-hydroxy-ergost-4-en-3-one	C28 H46 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(=O)CC4)(C))))		RXN-4231	campest-4-en-3-one + O2  =  22alpha-hydroxy-campest-4-en-3-one + H2O	brassinosteroid biosynthesis II
sucrose	saccharose*sugar*Glc(&alpha;1<->2&beta;)Fru*&alpha;-D-glucopyranosyl &beta;-D-fructofuranoside	C12 H22 O11 	C(O)C1(C(O)C(O)C(O1)CO)OC2(OC(CO)C(O)C(O)C2O)	LIGAND:C00089*CAS:57-50-1*NCI:406942	3.2.1.26	sucrose + H2O  =  alpha-D-glucose + fructose	sucrose degradation
sucrose	saccharose*sugar*Glc(&alpha;1<->2&beta;)Fru*&alpha;-D-glucopyranosyl &beta;-D-fructofuranoside	C12 H22 O11 	C(O)C1(C(O)C(O)C(O1)CO)OC2(OC(CO)C(O)C(O)C2O)	LIGAND:C00089*CAS:57-50-1*NCI:406942	3.1.3.24	H2O + sucrose-6'-phosphate  =  sucrose + phosphate	sucrose biosynthesis
sucrose	saccharose*sugar*Glc(&alpha;1<->2&beta;)Fru*&alpha;-D-glucopyranosyl &beta;-D-fructofuranoside	C12 H22 O11 	C(O)C1(C(O)C(O)C(O1)CO)OC2(OC(CO)C(O)C(O)C2O)	LIGAND:C00089*CAS:57-50-1*NCI:406942	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose degradation
sucrose	saccharose*sugar*Glc(&alpha;1<->2&beta;)Fru*&alpha;-D-glucopyranosyl &beta;-D-fructofuranoside	C12 H22 O11 	C(O)C1(C(O)C(O)C(O1)CO)OC2(OC(CO)C(O)C(O)C2O)	LIGAND:C00089*CAS:57-50-1*NCI:406942	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose degradation to ethanol and lactate (anaerobic)
sucrose	saccharose*sugar*Glc(&alpha;1<->2&beta;)Fru*&alpha;-D-glucopyranosyl &beta;-D-fructofuranoside	C12 H22 O11 	C(O)C1(C(O)C(O)C(O1)CO)OC2(OC(CO)C(O)C(O)C2O)	LIGAND:C00089*CAS:57-50-1*NCI:406942	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	galactose degradation I
sucrose	saccharose*sugar*Glc(&alpha;1<->2&beta;)Fru*&alpha;-D-glucopyranosyl &beta;-D-fructofuranoside	C12 H22 O11 	C(O)C1(C(O)C(O)C(O1)CO)OC2(OC(CO)C(O)C(O)C2O)	LIGAND:C00089*CAS:57-50-1*NCI:406942	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose biosynthesis
22alpha-hydroxy-5alpha-campestan-3-one	(22<i>S</i>)-22-hydroxy-5&alpha;-campestan-3-one*(22<i>S</i>,24<i>R</i>)-22-hydroxy-5&alpha;-ergostan-3-one	C28 H48 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		RXN-4228	22alpha-hydroxy-5alpha-campestan-3-one  =  6-deoxocathasterone	brassinosteroid biosynthesis II
22alpha-hydroxy-5alpha-campestan-3-one	(22<i>S</i>)-22-hydroxy-5&alpha;-campestan-3-one*(22<i>S</i>,24<i>R</i>)-22-hydroxy-5&alpha;-ergostan-3-one	C28 H48 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		1.3.99.-	22alpha-hydroxy-campest-4-en-3-one + NADPH  =  22alpha-hydroxy-5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis II
22alpha-hydroxy-5alpha-campestan-3-one	(22<i>S</i>)-22-hydroxy-5&alpha;-campestan-3-one*(22<i>S</i>,24<i>R</i>)-22-hydroxy-5&alpha;-ergostan-3-one	C28 H48 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		RXN-4230	5alpha-campestan-3-one + O2  =  22alpha-hydroxy-5alpha-campestan-3-one + H2O	brassinosteroid biosynthesis II
alpha-D-galactose	&alpha;-galactose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O)O1)		2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	colanic acid building blocks biosynthesis
alpha-D-galactose	&alpha;-galactose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O)O1)		2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	galactose degradation II
alpha-D-galactose	&alpha;-galactose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O)O1)		2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	galactose degradation I
alpha-D-galactose	&alpha;-galactose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O)O1)		5.1.3.3	beta-D-galactose  =  alpha-D-galactose	galactose degradation II
guanosine 3'-diphosphate 5'-triphosphate	guanosine pentaphosphate*pppGpp*guanosine 5'-triphosphate,3'-diphosphate	C10 H18 N5 O20 P5 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1OP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))		3.6.1.40	H2O + guanosine 3'-diphosphate 5'-triphosphate  =  phosphate + guanosine 5'-diphosphate,3'-diphosphate	ppGpp biosynthesis
guanosine 3'-diphosphate 5'-triphosphate	guanosine pentaphosphate*pppGpp*guanosine 5'-triphosphate,3'-diphosphate	C10 H18 N5 O20 P5 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1OP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))		2.7.6.5	GTP + ATP  =  guanosine 3'-diphosphate 5'-triphosphate + AMP	ppGpp biosynthesis
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	6.1.1.10	tRNAmet + L-methionine + ATP  =  L-methionyl-tRNAmet + pyrophosphate + AMP	tRNA charging pathway
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	4.4.1.11	L-methionine + H2O  =  NH3 + 2-oxobutanoate + methanethiol	methionine degradation II
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	SAM cycle
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	ethylene biosynthesis from methionine
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	adenosylmethionine biosynthesis
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine salvage pathway
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine degradation I
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.6.1.-	L-methionine + a 2-oxo acid  =  2-oxo-4-methylthiobutanoic acid + an amino acid	homomethionine biosynthesis
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.1.1.13	homocysteine + 5-methyl-THF  =  L-methionine + tetrahydrofolate	formylTHF biosynthesis
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.6.1.5	2-oxo-4-methylthiobutanoic acid + an amino acid  =  L-methionine + keto acid	methionine salvage pathway
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.1.1.14	5-methyl-THF + homocysteine  =  tetrahydrofolate + L-methionine	SAM cycle
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.1.1.14	5-methyl-THF + homocysteine  =  tetrahydrofolate + L-methionine	formylTHF biosynthesis I
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.1.1.-	S-Methyl-L-methionine + homocysteine  =  2 L-methionine	methionine biosynthesis
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.1.1.14	5-methyltetrahydropteroyltri-L-glutamate + homocysteine  =  tetrahydropteroyltri-L-glutamate + L-methionine	methionine biosynthesis
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.1.1.14	5-methyltetrahydropteroyltri-L-glutamate + homocysteine  =  tetrahydropteroyltri-L-glutamate + L-methionine	sulfate assimilation
L-methionine	M*met*methionine	C5 H11 N1 O2 S1 	C(SC)CC(N)C(O)=O	LIGAND-CPD:C00073*LIGAND:C00073*CAS:63-68-3*CAS:7005-18-7	2.1.1.10	homocysteine + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + L-methionine	methionine biosynthesis
urate	8-hydroxyxanthine*2,6,8-trihydroxypurine*trioxopurine*2,6,8-trioxypurine*purine-2,6,8-(1H,3H,9H)-trione*uric acid	C5 H3 N4 O3 	c2(=O)([nH]c([O-1])nc1([nH]c(=O)[nH]c12))	LIGAND-CPD:C00366*CAS:69-93-2	1.7.3.3	urate + H2O2  =  allantoin + CO2	ureide biosynthesis
urate	8-hydroxyxanthine*2,6,8-trihydroxypurine*trioxopurine*2,6,8-trioxypurine*purine-2,6,8-(1H,3H,9H)-trione*uric acid	C5 H3 N4 O3 	c2(=O)([nH]c([O-1])nc1([nH]c(=O)[nH]c12))	LIGAND-CPD:C00366*CAS:69-93-2	1.7.3.3	urate + O2  =  allantoin + CO2 + H2O2	purine degradation
urate	8-hydroxyxanthine*2,6,8-trihydroxypurine*trioxopurine*2,6,8-trioxypurine*purine-2,6,8-(1H,3H,9H)-trione*uric acid	C5 H3 N4 O3 	c2(=O)([nH]c([O-1])nc1([nH]c(=O)[nH]c12))	LIGAND-CPD:C00366*CAS:69-93-2	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	purine degradation
urate	8-hydroxyxanthine*2,6,8-trihydroxypurine*trioxopurine*2,6,8-trioxypurine*purine-2,6,8-(1H,3H,9H)-trione*uric acid	C5 H3 N4 O3 	c2(=O)([nH]c([O-1])nc1([nH]c(=O)[nH]c12))	LIGAND-CPD:C00366*CAS:69-93-2	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	ureide biosynthesis
cis-3-hexenal		C6 H10 O1 	C(=O)CC=CCC	CAS:6789-80-6	RXN-1346	cis-3-hexenal  =  trans-2-hexenal	lipoxygenase pathway
cis-3-hexenal		C6 H10 O1 	C(=O)CC=CCC	CAS:6789-80-6	RXN-1347	cis-3-hexenal  =  cis-3-hexenol	lipoxygenase pathway
cis-3-hexenal		C6 H10 O1 	C(=O)CC=CCC	CAS:6789-80-6	RXN-1345	13(S)-hydroperoxylinolenate  =  12-oxo-cis-9-dodecenoate + cis-3-hexenal	lipoxygenase pathway
pyridoxine-5'-phosphate	pyridoxine-phosphate*pyridoxine-5P*pyridoxine-P	C8 H12 N1 O6 P1 	c1(c(c(CO)c(O)c(C)n1)COP(=O)(O)O)		PNPOXI-RXN	O2 + pyridoxine-5'-phosphate  =  H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
pyridoxine-5'-phosphate	pyridoxine-phosphate*pyridoxine-5P*pyridoxine-P	C8 H12 N1 O6 P1 	c1(c(c(CO)c(O)c(C)n1)COP(=O)(O)O)		2.7.1.-	ATP + pyridoxine  =  ADP + pyridoxine-5'-phosphate	pyridoxal 5'-phosphate salvage pathway
O-succinylbenzoate	2-succinylbenzoate*succinylbenzoate	C11 H10 O5 	C(=O)(O)CCC(=O)c1(c(C(O)=O)cccc1)	LIGAND-CPD:C02730	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  AMP + pyrophosphate + O-succinylbenzoyl-CoA	menaquinone biosynthesis
O-succinylbenzoate	2-succinylbenzoate*succinylbenzoate	C11 H10 O5 	C(=O)(O)CCC(=O)c1(c(C(O)=O)cccc1)	LIGAND-CPD:C02730	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  4-(2'-carboxyphenyl)-4-oxobutyryl-CoA + AMP + pyrophosphate	phylloquinone biosynthesis
O-succinylbenzoate	2-succinylbenzoate*succinylbenzoate	C11 H10 O5 	C(=O)(O)CCC(=O)c1(c(C(O)=O)cccc1)	LIGAND-CPD:C02730	O-SUCCINYLBENZOATE-COA-SYN-RXN	2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate  =  O-succinylbenzoate + H2O	phylloquinone biosynthesis
O-succinylbenzoate	2-succinylbenzoate*succinylbenzoate	C11 H10 O5 	C(=O)(O)CCC(=O)c1(c(C(O)=O)cccc1)	LIGAND-CPD:C02730	O-SUCCINYLBENZOATE-COA-SYN-RXN	2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate  =  O-succinylbenzoate + H2O	menaquinone biosynthesis
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	glycine degradation
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis I
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	carbon monoxide dehydrogenase pathway
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	2.1.2.-	5-phospho-ribosyl-glycineamide + formate + ATP  =  phosphate + 5'-phosphoribosyl-N-formylglycineamide + ADP	de novo biosynthesis of purine nucleotides I
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	1.2.1.43	NADPH + CO2  =  NADP+ + formate	carbon monoxide dehydrogenase pathway
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	1.2.2.1	ferricytochrome b1 + formate  =  ferrocytochrome b1 + CO2	glycine degradation
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	1.14.13.70	3 NADPH + 3 O2 + obtusifoliol + 3 H+  =  4 H2O + 3 NADP+ + formate + (4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol	sterol biosynthesis
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	R147-RXN	1,2-dihydroxy-3-keto-5-methylthiopentene + O2  =  2-oxo-4-methylthiobutanoic acid + formate	methionine salvage pathway
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	6.3.4.3	10-formyl-H4PteGlun + ADP + phosphate  =  THF polyglutamate + ATP + formate	tetrahydrofolate biosynthesis I
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	3.5.1.9	N-formylkynurenine + H2O  =  kynurenine + formate	NAD biosynthesis II (from tryptophan)
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	3.5.1.9	N-formylkynurenine + H2O  =  kynurenine + formate	tryptophan degradation
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	3.5.4.16	2 H2O + GTP  =  dihydroneopterin triphosphate + formate + H2O	tetrahydrofolate biosynthesis I
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	3.5.4.16	2 H2O + GTP  =  dihydroneopterin triphosphate + formate + H2O	tetrahydrofolate biosynthesis II
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	3.5.4.25	3 H2O + GTP  =  pyrophosphate + 2,5-diamino-6-(ribosylamino)-4-(3H)-pyrimidinone 5'-phosphate + formate	riboflavin and FMN and FAD biosynthesis
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	DIOHBUTANONEPSYN-RXN	D-ribulose-5-phosphate  =  3,4-dihydroxy-2-butanone-4-P + formate	riboflavin and FMN and FAD biosynthesis
formate	formic acid	C1 H2 O2 	[CH](=O)O	CAS:64-18-6	3.5.1.10	H2O + N10-formyl-THF  =  tetrahydrofolate + formate	formylTHF biosynthesis
pyridoxamine 5'-phosphate	pyridoxamine phosphate	C8 H13 N2 O5 P1 	C(N)c1(c(COP(O)(=O)O)cnc(C)c(O)1)		1.4.3.5	O2 + H2O + pyridoxamine 5'-phosphate  =  NH3 + H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
pyridoxamine 5'-phosphate	pyridoxamine phosphate	C8 H13 N2 O5 P1 	C(N)c1(c(COP(O)(=O)O)cnc(C)c(O)1)		PYRAMKIN-RXN	ATP + pyridoxamine  =  ADP + pyridoxamine 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	starch biosynthesis
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	sucrose degradation
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	ascorbate biosynthesis
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	glycolysis I
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	glycolysis II
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.3.1.9	beta-D-glucose-6-phosphate  =  D-fructose-6-phosphate	gluconeogenesis
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	1.1.1.49	beta-D-glucose-6-phosphate + NAD(P)+  =  D-glucono-delta-lactone-6-phosphate + NAD(P)H	oxidative branch of the pentose phosphate pathway
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.5.1.4	beta-D-glucose-6-phosphate  =  D-myo-inositol (3)-monophosphate	lipid-independent phytate biosynthesis
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.1.3.15	beta-D-glucose-6-phosphate  =  alpha-D-glucose-6-phosphate	starch biosynthesis
beta-D-glucose-6-phosphate	D-glucose-6-P*glucose-6-P*glucose-6-phosphate*&beta;-D-glucose-6-P*D-glucose-6-phosphate	C6 H13 O9 P1 	C1(O)(OC(C(O)C(O)C1O)COP(O)(O)=O)	LIGAND:C00092*CAS:56-73-5	5.1.3.15	beta-D-glucose-6-phosphate  =  alpha-D-glucose-6-phosphate	sucrose degradation
2-methyl-3-hydroxybutyryl-CoA	(2S,3S)-3-hydroxy-2-methylbutanoyl-CoA*(2S,3S)-3-hydroxy-2-methylbutyryl-CoA*(S)-3-hydroxy-2-methylbutyryl-CoA*3-hydroxy-2-methylbutyryl-CoA	C26 H44 N7 O18 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)C)		1.1.1.178	NAD+ + 2-methyl-3-hydroxybutyryl-CoA  =  NADH + 2-methylaceto-acetyl-CoA	isoleucine degradation
2-methyl-3-hydroxybutyryl-CoA	(2S,3S)-3-hydroxy-2-methylbutanoyl-CoA*(2S,3S)-3-hydroxy-2-methylbutyryl-CoA*(S)-3-hydroxy-2-methylbutyryl-CoA*3-hydroxy-2-methylbutyryl-CoA	C26 H44 N7 O18 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)C)		4.2.1.17	tiglyl-CoA + H2O  =  2-methyl-3-hydroxybutyryl-CoA	isoleucine degradation
lipid IV(A)	2,3,2',3'-tetrakis(3-hydroxymyristoyl)-D-glucosaminyl-1,6-&beta;-D-glucosamine 1,4'-bisphosphate*2,3,2',3'-tetrakis-(3-hydroxytetradecanoyl)-D-glucosaminyl-1,6-&beta;-D-glucosamine-1,4'-bisphosphate	C68 H130 N2 O23 P2 	CCCCCCCCCCCC(O)CC(=O)NC1(C(OP(=O)(O)O)OC(C(O)C1OC(=O)CC(O)CCCCCCCCCCC)COC2(C(NC(=O)CC(O)CCCCCCCCCCC)C(C(C(O2)CO)OP(O)(O)=O)OC(=O)CC(O)CCCCCCCCCCC))		2.-.-.-	lipid IV(A) + CMP-3-deoxy-D-manno-octulosonate  =  (KDO)-lipid IV(A) + CMP	lipid-A-precursor biosynthesis
lipid IV(A)	2,3,2',3'-tetrakis(3-hydroxymyristoyl)-D-glucosaminyl-1,6-&beta;-D-glucosamine 1,4'-bisphosphate*2,3,2',3'-tetrakis-(3-hydroxytetradecanoyl)-D-glucosaminyl-1,6-&beta;-D-glucosamine-1,4'-bisphosphate	C68 H130 N2 O23 P2 	CCCCCCCCCCCC(O)CC(=O)NC1(C(OP(=O)(O)O)OC(C(O)C1OC(=O)CC(O)CCCCCCCCCCC)COC2(C(NC(=O)CC(O)CCCCCCCCCCC)C(C(C(O2)CO)OP(O)(O)=O)OC(=O)CC(O)CCCCCCCCCCC))		2.7.1.130	lipid A disaccharide + ATP  =  lipid IV(A) + ADP	lipid-A-precursor biosynthesis
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis III
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	spermine biosynthesis II
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	spermine biosynthesis I
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis II
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis I
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	1.4.3.10	O2 + H2O + putrescine  =  NH3 + H2O2 + 4-amino-butyraldehyde	arginine degradation I
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	4.1.1.17	L-ornithine  =  CO2 + putrescine	polyamine biosynthesis III
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	4.1.1.17	L-ornithine  =  CO2 + putrescine	spermine biosynthesis II
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	4.1.1.17	L-ornithine  =  CO2 + putrescine	polyamine biosynthesis I
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	3.5.3.11	H2O + agmatine  =  urea + putrescine	spermine biosynthesis I
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	3.5.3.11	H2O + agmatine  =  urea + putrescine	polyamine biosynthesis II
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	3.5.3.11	H2O + agmatine  =  urea + putrescine	polyamine biosynthesis I
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	polyamine biosynthesis III
putrescine	1,4-diaminobutane*1,4-butanediamine*tetramethylenediamine*putrescine	C4 H12 N2 	C(N)CCCN	CAS:110-60-1	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	arginine degradation I
dCDP	2'-deoxycytidine diphosphate*2'-deoxycytidine-5'-diphosphate*deoxycytidine-diphosphate	C9 H15 N3 O10 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C2)COP(O)(=O)OP(O)(O)=O))	CAS:800-73-7	1.17.4.-	CDP + reduced glutaredoxin  =  dCDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
dCDP	2'-deoxycytidine diphosphate*2'-deoxycytidine-5'-diphosphate*deoxycytidine-diphosphate	C9 H15 N3 O10 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C2)COP(O)(=O)OP(O)(O)=O))	CAS:800-73-7	2.7.4.6	dCDP + ATP  =  dCTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dCDP	2'-deoxycytidine diphosphate*2'-deoxycytidine-5'-diphosphate*deoxycytidine-diphosphate	C9 H15 N3 O10 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C2)COP(O)(=O)OP(O)(O)=O))	CAS:800-73-7	1.17.4.1	Reduced Thioredoxin + CDP  =  Oxidized Thioredoxin + dCDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
deoxycytidine	d-cytidine*2'-deoxycytidine	C9 H13 N3 O4 	c1(n(c(=O)nc(c1)N)C2(OC(C(C2)O)CO))	LIGAND:C00881*CAS:951-77-9	3.5.4.5	H2O + deoxycytidine  =  NH3 + deoxyuridine	(deoxy)ribose phosphate degradation
a fatty acid	a long chain fatty acid*free fatty acid*a fatty acid anion*fatty acid*A LONG-CHAIN CARBOXYLIC ACID*A LONG-CHAIN ACID ANION*A LONG-CHAIN FATTY ACID ANION*a long-chain carboxylate*RCH2CH2COOH	C2 H3 O2 R1 			6.2.1.3	coenzyme A + a fatty acid + ATP  =  acyl-CoA + pyrophosphate + AMP	fatty acid beta-oxidation
a fatty acid	a long chain fatty acid*free fatty acid*a fatty acid anion*fatty acid*A LONG-CHAIN CARBOXYLIC ACID*A LONG-CHAIN ACID ANION*A LONG-CHAIN FATTY ACID ANION*a long-chain carboxylate*RCH2CH2COOH	C2 H3 O2 R1 			1.13.11.-	a fatty acid + O2  =  a 2(R)-hydroperoxy fatty acid	fatty acid alpha-oxidation
a fatty acid	a long chain fatty acid*free fatty acid*a fatty acid anion*fatty acid*A LONG-CHAIN CARBOXYLIC ACID*A LONG-CHAIN ACID ANION*A LONG-CHAIN FATTY ACID ANION*a long-chain carboxylate*RCH2CH2COOH	C2 H3 O2 R1 			RXN-4464	a fatty acid  =  a omega-hydroxy fatty acid	fatty acid omega-oxidation
a fatty acid	a long chain fatty acid*free fatty acid*a fatty acid anion*fatty acid*A LONG-CHAIN CARBOXYLIC ACID*A LONG-CHAIN ACID ANION*A LONG-CHAIN FATTY ACID ANION*a long-chain carboxylate*RCH2CH2COOH	C2 H3 O2 R1 			1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid omega-oxidation
a fatty acid	a long chain fatty acid*free fatty acid*a fatty acid anion*fatty acid*A LONG-CHAIN CARBOXYLIC ACID*A LONG-CHAIN ACID ANION*A LONG-CHAIN FATTY ACID ANION*a long-chain carboxylate*RCH2CH2COOH	C2 H3 O2 R1 			1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid alpha-oxidation
a fatty acid	a long chain fatty acid*free fatty acid*a fatty acid anion*fatty acid*A LONG-CHAIN CARBOXYLIC ACID*A LONG-CHAIN ACID ANION*A LONG-CHAIN FATTY ACID ANION*a long-chain carboxylate*RCH2CH2COOH	C2 H3 O2 R1 			3.1.1.23	H2O + acylglycerol  =  a fatty acid + glycerol	triacylglycerol degradation
a fatty acid	a long chain fatty acid*free fatty acid*a fatty acid anion*fatty acid*A LONG-CHAIN CARBOXYLIC ACID*A LONG-CHAIN ACID ANION*A LONG-CHAIN FATTY ACID ANION*a long-chain carboxylate*RCH2CH2COOH	C2 H3 O2 R1 			RXN-1602	1,2-diacylglycerol + H2O  =  2-acylglycerol + a fatty acid	triacylglycerol degradation
a fatty acid	a long chain fatty acid*free fatty acid*a fatty acid anion*fatty acid*A LONG-CHAIN CARBOXYLIC ACID*A LONG-CHAIN ACID ANION*A LONG-CHAIN FATTY ACID ANION*a long-chain carboxylate*RCH2CH2COOH	C2 H3 O2 R1 			3.1.1.3	H2O + triacylglycerol  =  a fatty acid + 1,2-diacylglycerol	triacylglycerol degradation
luteolin	3',4',5,7-tetrahydroxyflavone*3',4',5,7-tetrahydroxyflavone*5,7,3',4'-tetrahydroxyflavone	C15 H10 O6 	c1(ccc(O)c(c1)O)C3(=CC(=O)c2(c(O)cc(O)cc2O3))	CAS:491-70-3	1.14.11.22	eriodictyol + alpha-ketoglutarate + O2  =  luteolin + succinate + CO2 + H2O	luteolin biosynthesis
luteolin	3',4',5,7-tetrahydroxyflavone*3',4',5,7-tetrahydroxyflavone*5,7,3',4'-tetrahydroxyflavone	C15 H10 O6 	c1(ccc(O)c(c1)O)C3(=CC(=O)c2(c(O)cc(O)cc2O3))	CAS:491-70-3	RXN-7653	eriodictyol + NADPH + O2  =  luteolin + NADP+ + 2 H2O	luteolin biosynthesis
luteolin	3',4',5,7-tetrahydroxyflavone*3',4',5,7-tetrahydroxyflavone*5,7,3',4'-tetrahydroxyflavone	C15 H10 O6 	c1(ccc(O)c(c1)O)C3(=CC(=O)c2(c(O)cc(O)cc2O3))	CAS:491-70-3	1.14.13.21	apigenin + NADPH + O2  =  luteolin + NADP+ + H2O	luteolin biosynthesis
delta-tocopherol		C27 H46 O2 	CC(C)CCCC(C)CCCC(C)CCCC1(C)(OC2(C(CC1)=CC(O)=CC=2C))		2.1.1.95	delta-tocopherol + S-adenosyl-L-methionine  =  beta-tocopherol + S-adenosyl-homocysteine	vitamin E biosynthesis
delta-tocopherol		C27 H46 O2 	CC(C)CCCC(C)CCCC(C)CCCC1(C)(OC2(C(CC1)=CC(O)=CC=2C))		RXN-2561	2-methyl-6-phytyl-1,4-benzoquinone  =  delta-tocopherol	vitamin E biosynthesis
an alcohol	alcohol*ROH	H1 O1 R1 			3.2.1.31	H2O + beta-D-glucuronide  =  glucuronate + an alcohol	beta-D-glucuronide degradation
8-amino-7-oxononanoate	7-KAP*7-keto-8-aminopelargonate*KAPA	C9 H17 N1 O3 	CC(N)C(=O)CCCCCC(=O)O	LIGAND-CPD:C01092	2.6.1.62	S-adenosyl-L-methionine + 8-amino-7-oxononanoate  =  S-adenosyl-4-methylthio-2-oxobutanoate + 7,8-diaminononanoate	biotin biosynthesis II
8-amino-7-oxononanoate	7-KAP*7-keto-8-aminopelargonate*KAPA	C9 H17 N1 O3 	CC(N)C(=O)CCCCCC(=O)O	LIGAND-CPD:C01092	2.3.1.47	L-alanine + 6-carboxyhexanoyl-CoA  =  CO2 + coenzyme A + 8-amino-7-oxononanoate	biotin biosynthesis II
Mg-protoporphyrin	Mg-protoporphyrin IX*Mg-protoporphyrin*magnesium protoporphyrin	C34 H32 N4 O4 MG1 	Cc8(c4(n7([Mg]35(n1(c(c(C)c(C=C)c1=Cc2(c(C)c(c(n23)=C4)C=C))=Cc6(n5c(c(c6C)CCC(=O)O)=Cc7c8CCC(=O)O))))))		2.1.1.11	Mg-protoporphyrin + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + Mg-protoporphyrin monomethyl ester	chlorophyllide a biosynthesis
Mg-protoporphyrin	Mg-protoporphyrin IX*Mg-protoporphyrin*magnesium protoporphyrin	C34 H32 N4 O4 MG1 	Cc8(c4(n7([Mg]35(n1(c(c(C)c(C=C)c1=Cc2(c(C)c(c(n23)=C4)C=C))=Cc6(n5c(c(c6C)CCC(=O)O)=Cc7c8CCC(=O)O))))))		6.6.1.1	ATP + protoporphyrin IX + Mg2+ + H2O  =  Mg-protoporphyrin + H+ + phosphate + ADP	chlorophyllide a biosynthesis
(R)-3-hydroxymyristoyl-ACP	B1094*AcpP*3-hydroxytetradecanoyl-ACP				2.3.1.129	(R)-3-hydroxymyristoyl-ACP + UDP-N-acetyl-D-glucosamine  =  UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine + acyl carrier protein	lipid-A-precursor biosynthesis
(R)-3-hydroxymyristoyl-ACP	B1094*AcpP*3-hydroxytetradecanoyl-ACP				2.3.1.-	UDP-3-O-(3-hydroxymyristoyl)glucosamine + (R)-3-hydroxymyristoyl-ACP  =  UDP-2,3-bis(3-hydroxymyristoyl)glucosamine + acyl carrier protein	lipid-A-precursor biosynthesis
benzylacetate		C9 H10 O2 	C(OC(C)=O)c1(ccccc1)		2.3.1.84	benzyl alcohol + acetyl-CoA  =  benzylacetate + coenzyme A	volatile benzenoid ester biosynthesis
a ketone					RXN-1023	a secondary alcohol  =  a ketone + methyl-ethyl-ketone	epicuticular wax biosynthesis
(Z)-beta-ocimene		C10 H16 	C=CC(C)=CCC=C(C)C		RXN-5123	geranyl-PP  =  (Z)-beta-ocimene + pyrophosphate	monoterpene biosynthesis
naringenin chalcone	2'44'6-tetrahydroxychalcone	C15 H11 O5 	c1(c(o)c(c(O)cc(O)1)C(=O)C=Cc2(ccc(O)cc2))	CAS:520-36-5	5.5.1.6	naringenin chalcone  =  naringenin	flavonoid biosynthesis
naringenin chalcone	2'44'6-tetrahydroxychalcone	C15 H11 O5 	c1(c(o)c(c(O)cc(O)1)C(=O)C=Cc2(ccc(O)cc2))	CAS:520-36-5	2.3.1.74	coumaroyl-CoA + 3 malonyl-CoA  =  naringenin chalcone + 3 CO2 + 4 coenzyme A	flavonoid biosynthesis
dUMP	U*deoxyurdine-phosphate*2'-deoxyuridine-5-monophosphate*deoxyuridine-phosphate*2'-deoxyuridine-5'-phosphate*2'-deoxyuridylic acid*2'-deoxy-5'-uridylic acid	C9 H13 N2 O8 P1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(O)(O)=O))	CAS:964-26-1	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	formylTHF biosynthesis
dUMP	U*deoxyurdine-phosphate*2'-deoxyuridine-5-monophosphate*deoxyuridine-phosphate*2'-deoxyuridine-5'-phosphate*2'-deoxyuridylic acid*2'-deoxy-5'-uridylic acid	C9 H13 N2 O8 P1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(O)(O)=O))	CAS:964-26-1	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	formylTHF biosynthesis I
dUMP	U*deoxyurdine-phosphate*2'-deoxyuridine-5-monophosphate*deoxyuridine-phosphate*2'-deoxyuridine-5'-phosphate*2'-deoxyuridylic acid*2'-deoxy-5'-uridylic acid	C9 H13 N2 O8 P1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(O)(O)=O))	CAS:964-26-1	2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	de novo biosynthesis of pyrimidine deoxyribonucleotides
dUMP	U*deoxyurdine-phosphate*2'-deoxyuridine-5-monophosphate*deoxyuridine-phosphate*2'-deoxyuridine-5'-phosphate*2'-deoxyuridylic acid*2'-deoxy-5'-uridylic acid	C9 H13 N2 O8 P1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(O)(O)=O))	CAS:964-26-1	3.6.1.23	H2O + dUTP  =  pyrophosphate + dUMP	de novo biosynthesis of pyrimidine deoxyribonucleotides
NO3-	NO<SUB>3</SUB>*nitrate	N1 O3 	[N+1]([O-1])([O-1])=O	CAS:14797-55-8	1.7.1.1	NO3- + NADH  =  NO2- + H2O + NAD+	nitrate assimilation pathway
delta2-enoyl-CoA	RCH=CHCO-CoA*2,3-dehydroacyl-CoA				1.3.99.3	acyl-CoA + FAD  =  FADH2 + delta2-enoyl-CoA	fatty acid beta-oxidation
methyl-ethyl-ketone					RXN-1023	a secondary alcohol  =  a ketone + methyl-ethyl-ketone	epicuticular wax biosynthesis
prenyl-tRNA					RXN-4544	prenyl-tRNA  =  cis-prenyl-tRNA	cis-zeatin biosynthesis
prenyl-tRNA					2.5.1.8	a tRNA + dimethylallyl-pyrophosphate  =  prenyl-tRNA + pyrophosphate	cis-zeatin biosynthesis
2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate	2-amino-7,8-dihydro-4-hydroxy-6-(diphosphooxymethyl)-pteridine*dihydropterin-CH2OH-diphosphate*dihydropterin-CH2OH-pp	C7 H11 N5 O8 P2 	C2(C(COP(O)(=O)OP(O)(=O)O)=Nc1(c(O)nc(N)nc1N2))		2.5.1.15	p-aminobenzoate + 2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate  =  7,8-dihydropteroate + pyrophosphate	tetrahydrofolate biosynthesis I
2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate	2-amino-7,8-dihydro-4-hydroxy-6-(diphosphooxymethyl)-pteridine*dihydropterin-CH2OH-diphosphate*dihydropterin-CH2OH-pp	C7 H11 N5 O8 P2 	C2(C(COP(O)(=O)OP(O)(=O)O)=Nc1(c(O)nc(N)nc1N2))		2.5.1.15	p-aminobenzoate + 2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate  =  7,8-dihydropteroate + pyrophosphate	tetrahydrofolate biosynthesis II
2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate	2-amino-7,8-dihydro-4-hydroxy-6-(diphosphooxymethyl)-pteridine*dihydropterin-CH2OH-diphosphate*dihydropterin-CH2OH-pp	C7 H11 N5 O8 P2 	C2(C(COP(O)(=O)OP(O)(=O)O)=Nc1(c(O)nc(N)nc1N2))		2.7.6.3	6-hydroxymethyl-dehydropterin + ATP  =  2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate + AMP	tetrahydrofolate biosynthesis I
2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate	2-amino-7,8-dihydro-4-hydroxy-6-(diphosphooxymethyl)-pteridine*dihydropterin-CH2OH-diphosphate*dihydropterin-CH2OH-pp	C7 H11 N5 O8 P2 	C2(C(COP(O)(=O)OP(O)(=O)O)=Nc1(c(O)nc(N)nc1N2))		2.7.6.3	6-hydroxymethyl-dehydropterin + ATP  =  2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate + AMP	tetrahydrofolate biosynthesis II
L-glutaminyl-tRNAgln	L-GLUTAMINYL-TRNA(GLN)				6.1.1.18	tRNAgln + L-glutamine + ATP  =  L-glutaminyl-tRNAgln + pyrophosphate + AMP	tRNA charging pathway
octaprenyl diphosphate	octaprenyl pyrophosphate*OPP*farnesylfarnesylgeraniol*all-trans-octaprenyl diphosphate	C40 H68 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(O)(O)=O		DMK-RXN	1,4-dihydroxy-2-naphthoate + octaprenyl diphosphate  =  demethylmenaquinone-8 + pyrophosphate + CO2	menaquinone biosynthesis
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	salvage pathways of purine nucleosides
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	de novo biosynthesis of purine nucleotides I
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	purine degradation
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	salvage pathways of purine nucleosides
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	ureide biosynthesis
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides II
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides I
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	purine degradation
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	salvage pathways of purine nucleosides
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	ureide biosynthesis
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides II
xanthosine-5-phosphate	(9-D-ribosylxanthine)-5'-phosphate*XMP*xanthosine-5-phosphate*xanthosine-5'-phosphate*xanthosine-5-P*xanthosine-5'-P	C10 H13 N4 O9 P1 	C(OP(O)(O)=O)[CH]1(O[CH]([CH](O)[CH]1O)n2(c3(c(nc2)c(=O)[nH]c([nH]3)=O)))	LIGAND-CPD:C00655*CAS:523-98-8	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides I
pyridoxine	vitamin B<SUB>6</SUB>*2-methyl-3-hydroxy-4,5-bis(hydroxy-methyl) pyridine	C8 H11 N1 O3 	C(O)c1(c(CO)cnc(C)c(O)1)	CAS:65-23-6	2.7.1.-	ATP + pyridoxine  =  ADP + pyridoxine-5'-phosphate	pyridoxal 5'-phosphate salvage pathway
gluconate	D-gluconate*D-gluconoate*gluconic acid*D-gluconic acid*dextronic acid*aldonic acid*maltonic acid	C6 H12 O7 	C(O)(=O)[CH](O)[CH](O)[CH](O)[CH](O)CO	CAS:526-95-4	2.7.1.12	ATP + gluconate  =  6-phospho-D-gluconate + ADP	superpathway of gluconate degradation
D-mannonate	mannonate	C6 H12 O7 	C(=O)(O)[CH](O)[CH](O)[CH](O)[CH](O)CO		1.1.1.57	NADH + fructuronate  =  NAD+ + D-mannonate	beta-D-glucuronide degradation
D-mannonate	mannonate	C6 H12 O7 	C(=O)(O)[CH](O)[CH](O)[CH](O)[CH](O)CO		4.2.1.8	D-mannonate  =  H2O + 2-dehydro-3-deoxy-D-gluconate	beta-D-glucuronide degradation
3-thiazol-2'-yl-indole	Camalexin	C11 H8 N2 S1 	C1(N=C(SC=1)c3(c[nH]c2(ccccc23)))		RXN1F-17	indole carboxyl thiazole  =  3-thiazol-2'-yl-indole + CO2	camalexin biosynthesis
L-alanyl-tRNAala	L-ALANYL-TRNA(ALA)				6.1.1.7	tRNAala + L-alanine + ATP  =  L-alanyl-tRNAala + pyrophosphate + AMP	tRNA charging pathway
a dicarboxylate					RXN-4466	a omega-oxo fatty acid + H2O + NAD+  =  a dicarboxylate + NADH	fatty acid omega-oxidation
GA98	gibberellin A<sub>98</sub>*gibberellin A98*GA98	C20 H28 O7 	CC1([CH]4(C(CC(O)C1)(CO)[CH]3(C2(CC(C(=C)C2)(O)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA98 + succinate + CO2	gibberellin inactivation
L-tryptophan	W*tryptacin*trofan*trp*tryptophan*2-amino-3-indolylpropanic acid	C11 H12 N2 O2 	c1(c(CC(N)C(=O)O)c2(c([nH]1)cccc2))	LIGAND:C00078*CAS:6912-86-3*CAS:73-22-3	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	IAA biosynthesis I
L-tryptophan	W*tryptacin*trofan*trp*tryptophan*2-amino-3-indolylpropanic acid	C11 H12 N2 O2 	c1(c(CC(N)C(=O)O)c2(c([nH]1)cccc2))	LIGAND:C00078*CAS:6912-86-3*CAS:73-22-3	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	glucosinolate biosynthesis from tryptophan
L-tryptophan	W*tryptacin*trofan*trp*tryptophan*2-amino-3-indolylpropanic acid	C11 H12 N2 O2 	c1(c(CC(N)C(=O)O)c2(c([nH]1)cccc2))	LIGAND:C00078*CAS:6912-86-3*CAS:73-22-3	6.1.1.2	tRNAtrp + L-tryptophan + ATP  =  L-tryptophanyl-tRNAtrp + pyrophosphate + AMP	tRNA charging pathway
L-tryptophan	W*tryptacin*trofan*trp*tryptophan*2-amino-3-indolylpropanic acid	C11 H12 N2 O2 	c1(c(CC(N)C(=O)O)c2(c([nH]1)cccc2))	LIGAND:C00078*CAS:6912-86-3*CAS:73-22-3	4.1.1.28	L-tryptophan  =  CO2 + tryptamine	IAA biosynthesis I
L-tryptophan	W*tryptacin*trofan*trp*tryptophan*2-amino-3-indolylpropanic acid	C11 H12 N2 O2 	c1(c(CC(N)C(=O)O)c2(c([nH]1)cccc2))	LIGAND:C00078*CAS:6912-86-3*CAS:73-22-3	2.6.1.27	alpha-ketoglutarate + L-tryptophan  =  L-glutamate + indole-3-pyruvate	IAA biosynthesis I
L-tryptophan	W*tryptacin*trofan*trp*tryptophan*2-amino-3-indolylpropanic acid	C11 H12 N2 O2 	c1(c(CC(N)C(=O)O)c2(c([nH]1)cccc2))	LIGAND:C00078*CAS:6912-86-3*CAS:73-22-3	1.13.11.11	O2 + L-tryptophan  =  N-formylkynurenine	NAD biosynthesis II (from tryptophan)
L-tryptophan	W*tryptacin*trofan*trp*tryptophan*2-amino-3-indolylpropanic acid	C11 H12 N2 O2 	c1(c(CC(N)C(=O)O)c2(c([nH]1)cccc2))	LIGAND:C00078*CAS:6912-86-3*CAS:73-22-3	1.13.11.11	O2 + L-tryptophan  =  N-formylkynurenine	tryptophan degradation
L-tryptophan	W*tryptacin*trofan*trp*tryptophan*2-amino-3-indolylpropanic acid	C11 H12 N2 O2 	c1(c(CC(N)C(=O)O)c2(c([nH]1)cccc2))	LIGAND:C00078*CAS:6912-86-3*CAS:73-22-3	RXN0-2382	indole + L-serine  =  L-tryptophan + H2O	tryptophan biosynthesis
pantetheine 4'-phosphate	phosphopantotheine*pantotheine-4'-phosphate*4'-phosphopantetheine*phosphopantetheine	C11 H23 N2 O7 P1 S1 	CC(C)(COP(O)(=O)O)C(O)C(=O)NCCC(=O)NCCS		2.7.7.3	pantetheine 4'-phosphate + ATP  =  dephospho-CoA + pyrophosphate	coenzyme A biosynthesis
pantetheine 4'-phosphate	phosphopantotheine*pantotheine-4'-phosphate*4'-phosphopantetheine*phosphopantetheine	C11 H23 N2 O7 P1 S1 	CC(C)(COP(O)(=O)O)C(O)C(=O)NCCC(=O)NCCS		4.1.1.36	R-4'-phosphopantothenoyl-L-cysteine  =  pantetheine 4'-phosphate + CO2	coenzyme A biosynthesis
UDP-sulfoquinovose		C15 H24 N2 O19 P2 S1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(OC(CS(=O)(O)=O)C(O)C(O)C3O)))		RXN-1224	UDP-sulfoquinovose + 1,2-diacylglycerol  =  sulfoquinovosyldiacylglycerol + UDP	sulfolipid biosynthesis
UDP-sulfoquinovose		C15 H24 N2 O19 P2 S1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(OC(CS(=O)(O)=O)C(O)C(O)C3O)))		3.13.1.1	UDP-D-glucose + SO3-2  =  UDP-sulfoquinovose + H2O	sulfolipid biosynthesis
Long-linear-glucans					3.2.1.2	Long-linear-glucans  =  maltose	starch degradation
Long-linear-glucans					2.4.1.1	Long-linear-glucans + phosphate  =  alpha-D-glucose-1-phosphate	starch degradation
Long-linear-glucans					3.2.1.1	Long-linear-glucans  =  Short-glucans	starch degradation
Long-linear-glucans					3.2.1.41	Large-branched-glucans  =  Long-linear-glucans	starch degradation
Long-linear-glucans					2.4.1.25	Short-glucans + Short-glucans  =  Long-linear-glucans + beta-D-glucose	starch degradation
cycloeucalenol		C30 H50 O1 	CC(C)C(=C)CCC(C)C1(C5(C)(C(C)(CC1)C2(C4(C3([CH](CC2)C(C)C(O)CC3)(C4))(CC5))))	CAS:469-39-6*LIGAND-CPD:C02141	5.5.1.9	cycloeucalenol  =  obtusifoliol	sterol biosynthesis
cycloeucalenol		C30 H50 O1 	CC(C)C(=C)CCC(C)C1(C5(C)(C(C)(CC1)C2(C4(C3([CH](CC2)C(C)C(O)CC3)(C4))(CC5))))	CAS:469-39-6*LIGAND-CPD:C02141	2.1.1.-	24-methylenecycloartenol + S-adenosyl-homocysteine  =  cycloeucalenol + S-adenosyl-L-methionine	sterol biosynthesis
THF-L-glutamate	tetrahydrofolate glutamate	C24 H29 N8 O9 	C(=O)(O)C(CCC(O)=O)NC(=O)CCC(C(=O)O)NC(=O)c1(ccc(cc1)NC[CH]2(Nc3(c(NC2)nc(N)nc3=O)))		6.3.2.17	tetrahydrofolate + L-glutamate + ATP  =  THF-L-glutamate + ADP + phosphate	tetrahydrofolate biosynthesis I
4-hydroxybutyrate	4-Hydroxybutanoate*4-OH-but*4-Hydroxybutanoic acid*4-Hydroxybutyric acid	C4 H8 O3 	C(O)(=O)CCCO	CAS:591-81-1	1.2.1.16	succinate semialdehyde + NAD(P)H  =  4-hydroxybutyrate + NAD(P)+	glutamate degradation II
UDP-3-O-(3-hydroxymyristoyl)glucosamine	UDP-3-O-(3-hydroxytetradecanoyl)glucosamine	C29 H51 N3 O18 P2 	CCCCCCCCCCCC(O)CC(=O)OC1(C(N)C(OC(C1O)CO)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3)))		2.3.1.-	UDP-3-O-(3-hydroxymyristoyl)glucosamine + (R)-3-hydroxymyristoyl-ACP  =  UDP-2,3-bis(3-hydroxymyristoyl)glucosamine + acyl carrier protein	lipid-A-precursor biosynthesis
UDP-3-O-(3-hydroxymyristoyl)glucosamine	UDP-3-O-(3-hydroxytetradecanoyl)glucosamine	C29 H51 N3 O18 P2 	CCCCCCCCCCCC(O)CC(=O)OC1(C(N)C(OC(C1O)CO)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c(=O)[nH]c(=O)cc3)))		UDPACYLGLCNACDEACETYL-RXN	UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine + H2O  =  UDP-3-O-(3-hydroxymyristoyl)glucosamine + acetate	lipid-A-precursor biosynthesis
5,10-methenyl-H4PteGlun		C8 H10 N6 O1 R1 			3.5.4.9	5,10-methenyl-H4PteGlun + H2O  =  10-formyl-H4PteGlun	tetrahydrofolate biosynthesis I
isoliquiritigenin	42'4'-trihydroxychalcone	C15 H12 O4 	C(c1(ccc(O)cc1))=CC(=O)c2(c(O)cc(O)cc2)		2.3.1.170	coumaroyl-CoA + 3 malonyl-CoA + NADPH  =  isoliquiritigenin + 4 coenzyme A + 3 CO2 + NADP+ + H2O	flavonoid biosynthesis
3-carboxy-3-hydroxy-isocaproate	3-hydroxy-4-methyl-3-carboxypentanoate*3-carboxy-3-hydroxy-4-methylpentanoate*3-isopropylmalate*&alpha;-isopropylmalate	C7 H12 O5 	C(=O)(O)CC(O)(C(=O)O)C(C)C		4.1.3.12	2-keto-isovalerate + acetyl-CoA + H2O  =  3-carboxy-3-hydroxy-isocaproate + coenzyme A	leucine biosynthesis
3-carboxy-3-hydroxy-isocaproate	3-hydroxy-4-methyl-3-carboxypentanoate*3-carboxy-3-hydroxy-4-methylpentanoate*3-isopropylmalate*&alpha;-isopropylmalate	C7 H12 O5 	C(=O)(O)CC(O)(C(=O)O)C(C)C		4.2.1.33	3-carboxy-3-hydroxy-isocaproate  =  2-D-threo-hydroxy-3-carboxy-isocaproate	leucine biosynthesis
2-acetolactate	(S)-2-hydroxy-2-methyl-3-oxobutanoate*&alpha;-acetolactate	C5 H8 O4 	CC(=O)C(C)(O)C(O)=O		1.1.1.86	2-acetolactate + NADPH  =  2,3-dihydroxy-isovalerate + NADP+	valine biosynthesis
2-acetolactate	(S)-2-hydroxy-2-methyl-3-oxobutanoate*&alpha;-acetolactate	C5 H8 O4 	CC(=O)C(C)(O)C(O)=O		2.2.1.6	2 pyruvate  =  2-acetolactate + CO2	valine biosynthesis
ent-kaur-16-en-19-ol		C20 H32 O1 	C=C1(C2(CC3(C1)(C(CC2)C4(C)(C(CC3)C(C)(CO)CCC4))))		1.14.13.78	ent-kaur-16-en-19-ol + NADPH + H+ + O2  =  ent-kaur-16-en-19-al + NADP+ + 2 H2O	GA12 biosynthesis
ent-kaur-16-en-19-ol		C20 H32 O1 	C=C1(C2(CC3(C1)(C(CC2)C4(C)(C(CC3)C(C)(CO)CCC4))))		1.14.13.78	ent-kaur-16-ene + O2 + NADPH  =  H2O + NADP+ + ent-kaur-16-en-19-ol	GA12 biosynthesis
coproporphyrinogen III	coproporphyrinogen	C36 H44 N4 O8 	Cc5(c(CCC(=O)O)c4(Cc1(nc(c(C)c1CCC(=O)O)Cc2(nc(c(c2C)CCC(=O)O)Cc3(c(C)c(c(n3)Cc(n4)5)CCC(O)=O)))))	CAS:2624-63-7	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	chlorophyllide a biosynthesis
coproporphyrinogen III	coproporphyrinogen	C36 H44 N4 O8 	Cc5(c(CCC(=O)O)c4(Cc1(nc(c(C)c1CCC(=O)O)Cc2(nc(c(c2C)CCC(=O)O)Cc3(c(C)c(c(n3)Cc(n4)5)CCC(O)=O)))))	CAS:2624-63-7	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	biosynthesis of proto- and siroheme
coproporphyrinogen III	coproporphyrinogen	C36 H44 N4 O8 	Cc5(c(CCC(=O)O)c4(Cc1(nc(c(C)c1CCC(=O)O)Cc2(nc(c(c2C)CCC(=O)O)Cc3(c(C)c(c(n3)Cc(n4)5)CCC(O)=O)))))	CAS:2624-63-7	1.-.-.-	NAD(P)+ + coproporphyrinogen III  =  protoporphyrinogen + NAD(P)H + 2 CO2	biosynthesis of proto- and siroheme
coproporphyrinogen III	coproporphyrinogen	C36 H44 N4 O8 	Cc5(c(CCC(=O)O)c4(Cc1(nc(c(C)c1CCC(=O)O)Cc2(nc(c(c2C)CCC(=O)O)Cc3(c(C)c(c(n3)Cc(n4)5)CCC(O)=O)))))	CAS:2624-63-7	4.1.1.37	uroporphyrinogen-III  =  4 CO2 + coproporphyrinogen III	chlorophyllide a biosynthesis
coproporphyrinogen III	coproporphyrinogen	C36 H44 N4 O8 	Cc5(c(CCC(=O)O)c4(Cc1(nc(c(C)c1CCC(=O)O)Cc2(nc(c(c2C)CCC(=O)O)Cc3(c(C)c(c(n3)Cc(n4)5)CCC(O)=O)))))	CAS:2624-63-7	4.1.1.37	uroporphyrinogen-III  =  4 CO2 + coproporphyrinogen III	biosynthesis of proto- and siroheme
5'-phosphoribosyl-N-formylglycineamide	5'-P-ribosyl-N-formylglycineamide*5'-phosphoribosyl-N-formylglycinamide*5'-phosphoribosyl-N-formylglycineamide*FGAR*5-phosphoribosyl-N-formalglycineamide*5'-phosphoribosyl-formylglycinamide	C8 H15 N2 O9 P1 	C(=O)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides II
5'-phosphoribosyl-N-formylglycineamide	5'-P-ribosyl-N-formylglycineamide*5'-phosphoribosyl-N-formylglycinamide*5'-phosphoribosyl-N-formylglycineamide*FGAR*5-phosphoribosyl-N-formalglycineamide*5'-phosphoribosyl-formylglycinamide	C8 H15 N2 O9 P1 	C(=O)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides I
5'-phosphoribosyl-N-formylglycineamide	5'-P-ribosyl-N-formylglycineamide*5'-phosphoribosyl-N-formylglycinamide*5'-phosphoribosyl-N-formylglycineamide*FGAR*5-phosphoribosyl-N-formalglycineamide*5'-phosphoribosyl-formylglycinamide	C8 H15 N2 O9 P1 	C(=O)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		2.1.2.-	5-phospho-ribosyl-glycineamide + formate + ATP  =  phosphate + 5'-phosphoribosyl-N-formylglycineamide + ADP	de novo biosynthesis of purine nucleotides I
5'-phosphoribosyl-N-formylglycineamide	5'-P-ribosyl-N-formylglycineamide*5'-phosphoribosyl-N-formylglycinamide*5'-phosphoribosyl-N-formylglycineamide*FGAR*5-phosphoribosyl-N-formalglycineamide*5'-phosphoribosyl-formylglycinamide	C8 H15 N2 O9 P1 	C(=O)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		2.1.2.2	N10-formyl-THF + 5-phospho-ribosyl-glycineamide  =  tetrahydrofolate + 5'-phosphoribosyl-N-formylglycineamide	de novo biosynthesis of purine nucleotides II
5'-phosphoribosyl-N-formylglycineamide	5'-P-ribosyl-N-formylglycineamide*5'-phosphoribosyl-N-formylglycinamide*5'-phosphoribosyl-N-formylglycineamide*FGAR*5-phosphoribosyl-N-formalglycineamide*5'-phosphoribosyl-formylglycinamide	C8 H15 N2 O9 P1 	C(=O)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		2.1.2.2	N10-formyl-THF + 5-phospho-ribosyl-glycineamide  =  tetrahydrofolate + 5'-phosphoribosyl-N-formylglycineamide	de novo biosynthesis of purine nucleotides I
NH4+	ammonium	H4 N1 	[NH4+1]	LIGAND-CPD:C01342*CAS:66701-25-5*CAS:14798-03-9	4.4.1.-	homoserine + H2O  =  2-oxobutanoate + NH4+ + H2O	methionine degradation I
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	formylTHF biosynthesis
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	glycine degradation
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	formylTHF biosynthesis I
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	carbon monoxide dehydrogenase pathway
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	RXN-6321	5,10-methenyl-THF + H2O  =  N5-formyl-H4F	formylTHF biosynthesis I
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	1.5.1.15	5,10-methylene-THF + NAD+  =  5,10-methenyl-THF + NADH	glycine degradation
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	formylTHF biosynthesis
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	formylTHF biosynthesis I
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	carbon monoxide dehydrogenase pathway
5,10-methenyl-THF	5,10-methylenetetrahydrofolate*n5-n10-CH-THF*n5-n10-methenyltetrahydrofolate*CH-THF*5,10-methenyltetrahydrofolate*anhydroleucovorin*methenyl-tetrahydrofolate*methenyl-THF*methenyl-H<sub>4</sub>F	C20 H22 N7 O6 	C3(C1(CN(C=[N+1]1c2(c(=O)[nH]c(N)nc2N3))c4(ccc(cc4)C(=O)NC(C(O)=O)CCC(O)=O)))	CAS:7444-29-3	6.3.3.2	N5-formyl-H4F + ATP  =  5,10-methenyl-THF + ADP + phosphate	formylTHF biosynthesis I
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	2.4.1.46	1,2-diacylglycerol + UDP-galactose  =  mono-beta-D-galactosyldiacylglycerol + UDP	glycolipid biosynthesis
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	RXN-1225	mono-beta-D-galactosyldiacylglycerol + UDP-galactose  =  alpha-D-galactosyl-beta-D-galactosyldiacylglycerol + UDP	glycolipid biosynthesis
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	2.7.7.12	UDP-D-glucose + alpha-D-galactose-1-phosphate  =  alpha-D-glucose-1-phosphate + UDP-galactose	colanic acid building blocks biosynthesis
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	2.7.7.12	UDP-D-glucose + alpha-D-galactose-1-phosphate  =  alpha-D-glucose-1-phosphate + UDP-galactose	galactose degradation II
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	2.7.7.10	alpha-D-galactose-1-phosphate + UTP  =  UDP-galactose + pyrophosphate	galactose degradation I
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	5.1.3.2	UDP-D-glucose  =  UDP-galactose	colanic acid building blocks biosynthesis
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	5.1.3.2	UDP-D-glucose  =  UDP-galactose	galactose degradation II
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	5.1.3.2	UDP-D-glucose  =  UDP-galactose	galactose degradation I
UDP-galactose	UDP-D-galactopyranose*UDP-D-galactose*uridine diphosphate galactose	C15 H24 N2 O17 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)CO)))	CAS:2956-16-3	5.1.3.2	UDP-D-glucose  =  UDP-galactose	UDP-glucose conversion
thiamin diphosphate	thiamine pyrophosphate*Thaimine pyrophosphate*thiamin diphosphate*TPP*thiamin-PPi*thiamin pyrophosphate*thiamine diphosphate*thiamine-PPi*ThPP	C12 H19 N4 O7 P2 S1 	C(c1(c(N)nc(C)nc1))[n+1]2(c(C)c(sc2)CCOP(O)(=O)OP(O)(=O)O)	LIGAND-CPD:C00068*CAS:154-87-0	4.1.1.71	alpha-ketoglutarate + thiamin diphosphate  =  succinate-semialdehyde-thiamine PPi + CO2	menaquinone biosynthesis
thiamin diphosphate	thiamine pyrophosphate*Thaimine pyrophosphate*thiamin diphosphate*TPP*thiamin-PPi*thiamin pyrophosphate*thiamine diphosphate*thiamine-PPi*ThPP	C12 H19 N4 O7 P2 S1 	C(c1(c(N)nc(C)nc1))[n+1]2(c(C)c(sc2)CCOP(O)(=O)OP(O)(=O)O)	LIGAND-CPD:C00068*CAS:154-87-0	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	phylloquinone biosynthesis
thiamin diphosphate	thiamine pyrophosphate*Thaimine pyrophosphate*thiamin diphosphate*TPP*thiamin-PPi*thiamin pyrophosphate*thiamine diphosphate*thiamine-PPi*ThPP	C12 H19 N4 O7 P2 S1 	C(c1(c(N)nc(C)nc1))[n+1]2(c(C)c(sc2)CCOP(O)(=O)OP(O)(=O)O)	LIGAND-CPD:C00068*CAS:154-87-0	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	menaquinone biosynthesis
thiamin diphosphate	thiamine pyrophosphate*Thaimine pyrophosphate*thiamin diphosphate*TPP*thiamin-PPi*thiamin pyrophosphate*thiamine diphosphate*thiamine-PPi*ThPP	C12 H19 N4 O7 P2 S1 	C(c1(c(N)nc(C)nc1))[n+1]2(c(C)c(sc2)CCOP(O)(=O)OP(O)(=O)O)	LIGAND-CPD:C00068*CAS:154-87-0	2.7.4.16	thiamine-phosphate + ATP  =  thiamin diphosphate + ADP	thiamin biosynthesis
5-phospho-ribosyl-glycineamide	5'-phosphoribosylglycinamide*5'-phosphoribosylglycineamide*5'-p-ribosylglycinamide*5'-p-ribosylglycineamide*GAR	C7 H15 N2 O8 P1 	C(CN)(=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(O)(=O)O)		2.1.2.2	N10-formyl-THF + 5-phospho-ribosyl-glycineamide  =  tetrahydrofolate + 5'-phosphoribosyl-N-formylglycineamide	de novo biosynthesis of purine nucleotides II
5-phospho-ribosyl-glycineamide	5'-phosphoribosylglycinamide*5'-phosphoribosylglycineamide*5'-p-ribosylglycinamide*5'-p-ribosylglycineamide*GAR	C7 H15 N2 O8 P1 	C(CN)(=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(O)(=O)O)		2.1.2.2	N10-formyl-THF + 5-phospho-ribosyl-glycineamide  =  tetrahydrofolate + 5'-phosphoribosyl-N-formylglycineamide	de novo biosynthesis of purine nucleotides I
5-phospho-ribosyl-glycineamide	5'-phosphoribosylglycinamide*5'-phosphoribosylglycineamide*5'-p-ribosylglycinamide*5'-p-ribosylglycineamide*GAR	C7 H15 N2 O8 P1 	C(CN)(=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(O)(=O)O)		2.1.2.-	5-phospho-ribosyl-glycineamide + formate + ATP  =  phosphate + 5'-phosphoribosyl-N-formylglycineamide + ADP	de novo biosynthesis of purine nucleotides I
5-phospho-ribosyl-glycineamide	5'-phosphoribosylglycinamide*5'-phosphoribosylglycineamide*5'-p-ribosylglycinamide*5'-p-ribosylglycineamide*GAR	C7 H15 N2 O8 P1 	C(CN)(=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(O)(=O)O)		6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides II
5-phospho-ribosyl-glycineamide	5'-phosphoribosylglycinamide*5'-phosphoribosylglycineamide*5'-p-ribosylglycinamide*5'-p-ribosylglycineamide*GAR	C7 H15 N2 O8 P1 	C(CN)(=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(O)(=O)O)		6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides I
2-methyl-6-solanyl-1,4-benzoquinone		C52 H82 O2 	CC(=CCCC(C)=CCCC(C)=CCC1(C(O)C(C)=CC(C=1)O))CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C		2.1.1.-	2-methyl-6-solanyl-1,4-benzoquinone + S-adenosyl-L-methionine  =  plastoquinone-9 + S-adenosyl-homocysteine	plastoquinone biosynthesis
2-methyl-6-solanyl-1,4-benzoquinone		C52 H82 O2 	CC(=CCCC(C)=CCCC(C)=CCC1(C(O)C(C)=CC(C=1)O))CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C		RXN-2761	homogentisate + solanyl pyrophosphate  =  2-methyl-6-solanyl-1,4-benzoquinone + CO2 + pyrophosphate	plastoquinone biosynthesis
L-1-phosphatidyl-glycerol	3-(3-sn-phosphatidyl)glycerol*3(3-phosphatidyl-)glycerol*1-phosphatidylglycerol*phosphatidylglycerol	C8 H13 O10 R11 R21 P1 	C(OC(=O)[R2])C(OC(=O)[R1])COP(O)(=O)OCC(O)CO		3.1.3.27	L-1-phosphatidylglycerol-phosphate + H2O  =  L-1-phosphatidyl-glycerol + phosphate	phospholipid biosynthesis
alpha-D-galactose-1-phosphate	galactose-1P*galactose-1-P*D-galactose-1-phosphate*galactose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:2255-14-3	2.7.7.10	alpha-D-galactose-1-phosphate + UTP  =  UDP-galactose + pyrophosphate	galactose degradation I
alpha-D-galactose-1-phosphate	galactose-1P*galactose-1-P*D-galactose-1-phosphate*galactose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:2255-14-3	2.7.7.12	UDP-D-glucose + alpha-D-galactose-1-phosphate  =  alpha-D-glucose-1-phosphate + UDP-galactose	colanic acid building blocks biosynthesis
alpha-D-galactose-1-phosphate	galactose-1P*galactose-1-P*D-galactose-1-phosphate*galactose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:2255-14-3	2.7.7.12	UDP-D-glucose + alpha-D-galactose-1-phosphate  =  alpha-D-glucose-1-phosphate + UDP-galactose	galactose degradation II
alpha-D-galactose-1-phosphate	galactose-1P*galactose-1-P*D-galactose-1-phosphate*galactose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:2255-14-3	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	colanic acid building blocks biosynthesis
alpha-D-galactose-1-phosphate	galactose-1P*galactose-1-P*D-galactose-1-phosphate*galactose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:2255-14-3	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	galactose degradation II
alpha-D-galactose-1-phosphate	galactose-1P*galactose-1-P*D-galactose-1-phosphate*galactose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:2255-14-3	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	galactose degradation I
phosphoribosyl-ATP	N1-(5-phospho-D-ribosyl)-ATP*5-phosphoribosyl-ATP*1-(5-phospho-D-ribosyl)-ATP	C15 H25 N5 O20 P4 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n3(c2(ncn(c(=N)c2nc3)C4(OC(C(O)C(O)4)COP(O)(=O)O))))		2.4.2.17	ATP + PRPP  =  phosphoribosyl-ATP + pyrophosphate	histidine biosynthesis
phosphoribosyl-ATP	N1-(5-phospho-D-ribosyl)-ATP*5-phosphoribosyl-ATP*1-(5-phospho-D-ribosyl)-ATP	C15 H25 N5 O20 P4 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n3(c2(ncn(c(=N)c2nc3)C4(OC(C(O)C(O)4)COP(O)(=O)O))))		3.6.1.31	phosphoribosyl-ATP + H2O  =  phosphoribosyl-AMP + pyrophosphate	histidine biosynthesis
indole-3-pyruvate	indole-pyr*indolepyruvic acid*(indol-3-yl)pyruvate*indolepyruvate*3-(indol-3-yl)pyruvate	C11 H9 N1 O3 	C(O)(=O)C(=O)Cc2(c[nH]c1(ccccc12))	CAS:35656-49-6	4.1.1.74	indole-3-pyruvate  =  CO2 + indole acetaldehyde	IAA biosynthesis I
indole-3-pyruvate	indole-pyr*indolepyruvic acid*(indol-3-yl)pyruvate*indolepyruvate*3-(indol-3-yl)pyruvate	C11 H9 N1 O3 	C(O)(=O)C(=O)Cc2(c[nH]c1(ccccc12))	CAS:35656-49-6	2.6.1.27	alpha-ketoglutarate + L-tryptophan  =  L-glutamate + indole-3-pyruvate	IAA biosynthesis I
spermidine		C7 H19 N3 	C(N)CCCNCCCN	CAS:124-20-9	2.5.1.22	spermidine + S-adenosylmethioninamine  =  spermine + 5'-methylthioadenosine	spermine biosynthesis II
spermidine		C7 H19 N3 	C(N)CCCNCCCN	CAS:124-20-9	2.5.1.22	spermidine + S-adenosylmethioninamine  =  spermine + 5'-methylthioadenosine	spermine biosynthesis I
spermidine		C7 H19 N3 	C(N)CCCNCCCN	CAS:124-20-9	1.5.99.6	H2O + acceptor + spermidine  =  reduced acceptor + 4-amino-butyraldehyde + 1,3-diaminopropane	beta-alanine biosynthesis I
spermidine		C7 H19 N3 	C(N)CCCNCCCN	CAS:124-20-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis III
spermidine		C7 H19 N3 	C(N)CCCNCCCN	CAS:124-20-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	spermine biosynthesis II
spermidine		C7 H19 N3 	C(N)CCCNCCCN	CAS:124-20-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	spermine biosynthesis I
spermidine		C7 H19 N3 	C(N)CCCNCCCN	CAS:124-20-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis II
spermidine		C7 H19 N3 	C(N)CCCNCCCN	CAS:124-20-9	2.5.1.16	putrescine + S-adenosylmethioninamine  =  spermidine + 5'-methylthioadenosine	polyamine biosynthesis I
indole-3-acetyl-gln	indole-3-acetyl-glutamine	C15 H17 N3 O4 	C(=O)(NC(C(=O)O)CCC(N)=O)Cc1(c[nH]c2(c1cccc2))		RXN-2948	indole-3-acetate + L-glutamine  =  indole-3-acetyl-gln + H2O	IAA conjugate biosynthesis
3-methyl-2-butenal	3-methylbut-2-enal*3,3-dimethyl-acrylaldehyde*prenal	C5 H8 O1 	C(=O)C=C(C)C	LIGAND-CPD:C07330	1.5.99.12	isopentenyladenine + FAD + H2O  =  3-methyl-2-butenal + adenine + FADH2	cytokinins degradation
3-methyl-2-butenal	3-methylbut-2-enal*3,3-dimethyl-acrylaldehyde*prenal	C5 H8 O1 	C(=O)C=C(C)C	LIGAND-CPD:C07330	1.5.99.12	isopentenyl adenosine + H2O + FAD  =  adenosine + 3-methyl-2-butenal + FADH2	cytokinins degradation
phenylpyruvate	phenylpyruvate*phenylpyruvic acid*alpha-ketohydrocinnamic acid*3-phenyl-2-oxopropanoate*keto-phenylpyruvate	C9 H8 O3 	C(=O)(O)C(=O)Cc1(ccccc1)	CAS:156-06-9	2.6.1.5	phenylpyruvate + L-glutamate  =  L-phenylalanine + alpha-ketoglutarate	phenylalanine biosynthesis II
phenylpyruvate	phenylpyruvate*phenylpyruvic acid*alpha-ketohydrocinnamic acid*3-phenyl-2-oxopropanoate*keto-phenylpyruvate	C9 H8 O3 	C(=O)(O)C(=O)Cc1(ccccc1)	CAS:156-06-9	2.6.1.9	phenylpyruvate + L-glutamate  =  L-phenylalanine + alpha-ketoglutarate	phenylalanine biosynthesis II
phenylpyruvate	phenylpyruvate*phenylpyruvic acid*alpha-ketohydrocinnamic acid*3-phenyl-2-oxopropanoate*keto-phenylpyruvate	C9 H8 O3 	C(=O)(O)C(=O)Cc1(ccccc1)	CAS:156-06-9	4.2.1.51	prephenate  =  phenylpyruvate + H2O + CO2	phenylalanine biosynthesis II
indole-3-acetyl-glu	indole-3-acetyl-glutamate	C15 H16 N2 O5 	C(NC(C(O)=O)CCC(O)=O)(=O)Cc1(c2(c([nH]c1)cccc2))		RXN-2947	indole-3-acetate + L-glutamate  =  indole-3-acetyl-glu + H2O	IAA conjugate biosynthesis
dTTP	thymidine triphosphate*thymidine 5'-triphosphate*TTP	C10 H17 N2 O14 P3 	Cc1(cn(c(=O)[nH]c(=O)1)C2(OC(C(O)C2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:365-08-2	2.7.4.6	dTDP + ATP  =  dTTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.3.99.3	acyl-CoA + FAD  =  FADH2 + delta2-enoyl-CoA	fatty acid beta-oxidation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.3.99.1	succinate + FAD  =  fumarate + FADH2	TCA cycle variation I
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.3.99.12	isobutyryl-CoA + FAD  =  methacrylyl-CoA + FADH2	valine degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.3.99.12	2-methylbutyryl-CoA + FAD  =  tiglyl-CoA + FADH2	isoleucine degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.3.99.10	isovaleryl-CoA + FAD  =  3-methylcrotonyl-CoA + FADH2	leucine degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	GLUTARYL-COA-DEHYDROG-RXN	glutaryl-CoA + FAD  =  glutaconyl-CoA + FADH2	lysine degradation II
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	GLUTARYL-COA-DEHYDROG-RXN	glutaryl-CoA + FAD  =  glutaconyl-CoA + FADH2	tryptophan degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.5.99.12	trans-zeatin riboside + H2O + FAD  =  adenosine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.5.99.12	cis-zeatin + H2O + FAD  =  3-methyl-4-cis-hydroxy-2-butenal + adenine + FADH2	cytokinins degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.5.99.12	trans-zeatin + H2O + FAD  =  adenine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.5.99.12	isopentenyl adenosine + H2O + FAD  =  adenosine + 3-methyl-2-butenal + FADH2	cytokinins degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.5.99.12	isopentenyladenine + FAD + H2O  =  3-methyl-2-butenal + adenine + FADH2	cytokinins degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.1.99.5	glycerol-3-phosphate + FAD  =  dihydroxy-acetone-phosphate + FADH2	glycerol degradation
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	1.3.99.3	FAD + propionyl-CoA  =  FADH2 + acrylyl-CoA	beta-alanine biosynthesis II
FAD	flavin adenine dinucleotide oxidized*flavin adenine dinucleotide*flavitan	C27 H33 N9 O15 P2 	Cc3(cc2(n(c1(c(C(=O)[NH]C(=O)N=1)nc2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH](O)4)n5(c6(c(nc5)c(N)ncn6)))))	LIGAND-CPD:C00016*CAS:146-14-5	2.7.7.2	FMN + ATP  =  FAD + pyrophosphate	riboflavin and FMN and FAD biosynthesis
dihydroorotate	4,5-dihydroorotate*4,5-dihydroorotic acid*hydroorotic acid*(S)-dihydroorotate*di-H-orotate*L-dihydroorotate*5,6-dihydroorotate*L-4,5-dihydroorotate*4-pyrimidinecarboxylic acid*hexahydro-2,6-dioxo-	C5 H6 N2 O4 	C1(=O)(CC(C(O)=O)NC(N1)=O)	CAS:155-54-4	1.3.3.1	O2 + dihydroorotate  =  H2O2 + orotate	de novo biosynthesis of pyrimidine ribonucleotides
dihydroorotate	4,5-dihydroorotate*4,5-dihydroorotic acid*hydroorotic acid*(S)-dihydroorotate*di-H-orotate*L-dihydroorotate*5,6-dihydroorotate*L-4,5-dihydroorotate*4-pyrimidinecarboxylic acid*hexahydro-2,6-dioxo-	C5 H6 N2 O4 	C1(=O)(CC(C(O)=O)NC(N1)=O)	CAS:155-54-4	3.5.2.3	carbamoyl-L-aspartate  =  dihydroorotate + H2O	de novo biosynthesis of pyrimidine ribonucleotides
malonyl-CoA	malonylCoenzyme A	C24 H38 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)=O)	LIGAND-CPD:C00083*CAS:524-14-1	2.3.1.39	acyl carrier protein + malonyl-CoA  =  malonyl-ACP + coenzyme A	fatty acid biosynthesis - initial steps
malonyl-CoA	malonylCoenzyme A	C24 H38 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)=O)	LIGAND-CPD:C00083*CAS:524-14-1	RXN-1026	fatty-acyl-CoA + malonyl-CoA  =  very-long-chain-fatty-acyl-CoA + CO2	epicuticular wax biosynthesis
malonyl-CoA	malonylCoenzyme A	C24 H38 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)=O)	LIGAND-CPD:C00083*CAS:524-14-1	2.3.1.74	coumaroyl-CoA + 3 malonyl-CoA  =  naringenin chalcone + 3 CO2 + 4 coenzyme A	flavonoid biosynthesis
malonyl-CoA	malonylCoenzyme A	C24 H38 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)=O)	LIGAND-CPD:C00083*CAS:524-14-1	2.3.1.170	coumaroyl-CoA + 3 malonyl-CoA + NADPH  =  isoliquiritigenin + 4 coenzyme A + 3 CO2 + NADP+ + H2O	flavonoid biosynthesis
malonyl-CoA	malonylCoenzyme A	C24 H38 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)=O)	LIGAND-CPD:C00083*CAS:524-14-1	2.3.1.-	fatty-acyl-CoA + malonyl-CoA  =  beta-ketoacyl-CoA + CO2 + coenzyme A	very long chain fatty acid biosynthesis
malonyl-CoA	malonylCoenzyme A	C24 H38 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(O)=O)	LIGAND-CPD:C00083*CAS:524-14-1	6.4.1.2	HCO3- + H+ + acetyl-CoA + ATP  =  malonyl-CoA + phosphate + ADP	fatty acid biosynthesis - initial steps
5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	1-(5-phosphoribosyl)-4-(N-succino-carboxamide)-5-aminoimidazole*5'-P-ribosyl-4-(N-succinocarboxamide)-5-aminoimidazole*5'-p-Ribosyl-4-(N-succinocarboxamide)-5-amino imidazole*1-(5'-phosphoribosyl)-4-(N-succino-carboxamide)-5-aminoimidazole*SAICAR	C13 H19 N4 O12 P1 	[CH]1([CH](O)[CH](O)[CH](O1)COP(=O)(O)O)n2(c(N)c(nc2)C(=O)NC(C(O)=O)CC(O)=O)		4.3.2.2	5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole  =  fumarate + AICAR	de novo biosynthesis of purine nucleotides II
5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	1-(5-phosphoribosyl)-4-(N-succino-carboxamide)-5-aminoimidazole*5'-P-ribosyl-4-(N-succinocarboxamide)-5-aminoimidazole*5'-p-Ribosyl-4-(N-succinocarboxamide)-5-amino imidazole*1-(5'-phosphoribosyl)-4-(N-succino-carboxamide)-5-aminoimidazole*SAICAR	C13 H19 N4 O12 P1 	[CH]1([CH](O)[CH](O)[CH](O1)COP(=O)(O)O)n2(c(N)c(nc2)C(=O)NC(C(O)=O)CC(O)=O)		4.3.2.2	5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole  =  fumarate + AICAR	de novo biosynthesis of purine nucleotides I
5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	1-(5-phosphoribosyl)-4-(N-succino-carboxamide)-5-aminoimidazole*5'-P-ribosyl-4-(N-succinocarboxamide)-5-aminoimidazole*5'-p-Ribosyl-4-(N-succinocarboxamide)-5-amino imidazole*1-(5'-phosphoribosyl)-4-(N-succino-carboxamide)-5-aminoimidazole*SAICAR	C13 H19 N4 O12 P1 	[CH]1([CH](O)[CH](O)[CH](O1)COP(=O)(O)O)n2(c(N)c(nc2)C(=O)NC(C(O)=O)CC(O)=O)		6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides II
5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	1-(5-phosphoribosyl)-4-(N-succino-carboxamide)-5-aminoimidazole*5'-P-ribosyl-4-(N-succinocarboxamide)-5-aminoimidazole*5'-p-Ribosyl-4-(N-succinocarboxamide)-5-amino imidazole*1-(5'-phosphoribosyl)-4-(N-succino-carboxamide)-5-aminoimidazole*SAICAR	C13 H19 N4 O12 P1 	[CH]1([CH](O)[CH](O)[CH](O1)COP(=O)(O)O)n2(c(N)c(nc2)C(=O)NC(C(O)=O)CC(O)=O)		6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides I
reduced ferredoxin	reduced ferredoxin*ferredoxin*Fdx				METLENETHFRED-FERRE-RXN	5,10-methylene-THF + reduced ferredoxin  =  5-methyl-THF + oxidized ferredoxin	carbon monoxide dehydrogenase pathway
reduced ferredoxin	reduced ferredoxin*ferredoxin*Fdx				1.7.7.-	NO2- + reduced ferredoxin  =  NH3 + H2O + oxidized ferredoxin	nitrate assimilation pathway
reduced ferredoxin	reduced ferredoxin*ferredoxin*Fdx				1.8.7.1	3 reduced ferredoxin + SO3-2  =  H2O + oxidized ferredoxin + H2S	sulfate assimilation
reduced ferredoxin	reduced ferredoxin*ferredoxin*Fdx				1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	ammonia assimilation cycle
reduced ferredoxin	reduced ferredoxin*ferredoxin*Fdx				1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	glutamate biosynthesis I
tRNAile	TRNA(ILE)				6.1.1.5	tRNAile + L-isoleucine + ATP  =  L-isoleucyl-tRNAile + pyrophosphate + AMP	tRNA charging pathway
salicylate	salicylic acid*o-hydroxybenzoic acid	C7 H6 O3 	C(O)(=O)c1(c(O)cccc1)	CAS:69-72-7	RXN-6723	salicylate + S-adenosyl-L-methionine  =  methylsalicylate + S-adenosyl-homocysteine	volatile benzenoid ester biosynthesis
salicylate	salicylic acid*o-hydroxybenzoic acid	C7 H6 O3 	C(O)(=O)c1(c(O)cccc1)	CAS:69-72-7	RXN-1981	isochorismate  =  salicylate + pyruvate	salicylic acid biosynthesis
salicylate	salicylic acid*o-hydroxybenzoic acid	C7 H6 O3 	C(O)(=O)c1(c(O)cccc1)	CAS:69-72-7	1.14.13.-	benzoate + NADPH + O2  =  salicylate + NADP+ + H2O	salicylic acid biosynthesis
salicylate	salicylic acid*o-hydroxybenzoic acid	C7 H6 O3 	C(O)(=O)c1(c(O)cccc1)	CAS:69-72-7	RXN-2009	salicyloyl-CoA + H2O  =  salicylate + coenzyme A	salicylic acid biosynthesis
beta-alanine	&beta;-alanine*3-aminopropanoate	C3 H7 N1 O2 	C(O)(=O)CCN	LIGAND:C00099*CAS:107-95-9	6.3.2.1	beta-alanine + L-pantoate + ATP  =  pantothenate + pyrophosphate + AMP	pantothenate biosynthesis
beta-alanine	&beta;-alanine*3-aminopropanoate	C3 H7 N1 O2 	C(O)(=O)CCN	LIGAND:C00099*CAS:107-95-9	2.6.1.18	malonate semialdehyde + L-alanine  =  beta-alanine + pyruvate	beta-alanine biosynthesis II
beta-alanine	&beta;-alanine*3-aminopropanoate	C3 H7 N1 O2 	C(O)(=O)CCN	LIGAND:C00099*CAS:107-95-9	1.2.1.3	3-aminopropionaldehyde + NAD(P)+ + H2O  =  beta-alanine + NAD(P)H	beta-alanine biosynthesis I
beta-alanine	&beta;-alanine*3-aminopropanoate	C3 H7 N1 O2 	C(O)(=O)CCN	LIGAND:C00099*CAS:107-95-9	3.5.1.6	H2O + 3-ureidopropionate  =  NH3 + CO2 + beta-alanine	beta-alanine biosynthesis III
L-arginyl-tRNAarg	L-ARGINYL-TRNA(ARG)				6.1.1.19	tRNAarg + L-arginine + ATP  =  L-arginyl-tRNAarg + pyrophosphate + AMP	tRNA charging pathway
D-carnitinyl-CoA		C28 H50 N8 O18 P3 S1 	C([N+1](C)(C)C)C(O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(O)(=O)OCC1(OC(C(O)C1OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3)))		5.-.-.-	D-carnitinyl-CoA  =  L-carnitinyl-CoA	carnitine degradation
D-carnitinyl-CoA		C28 H50 N8 O18 P3 S1 	C([N+1](C)(C)C)C(O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(O)(=O)OCC1(OC(C(O)C1OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3)))		6.3.2.-	coenzyme A + D-carnitine  =  D-carnitinyl-CoA + H2O	carnitine degradation
3-benzoyloxypropyl-glucosinolate	glucomalcommin	C17 H23 N1 O11 S2 	C(=NOS(O)(=O)=O)(SC1(C(CO)C(O)C(O)C(O1)O))CCCOC(=O)c2(ccccc2)		RXN-2224	3-hydroxypropyl-glucosinolate  =  3-benzoyloxypropyl-glucosinolate	glucosinolate biosynthesis from homomethionine
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	flavonoid biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	lignin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	4.1.3.12	2-keto-isovalerate + acetyl-CoA + H2O  =  3-carboxy-3-hydroxy-isocaproate + coenzyme A	leucine biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.16	2-methylaceto-acetyl-CoA + coenzyme A  =  propionyl-CoA + acetyl-CoA	isoleucine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	1.1.1.34	2 NADPH + 3-hydroxy-3-methyl-glutaryl-CoA  =  2 NADP+ + coenzyme A + mevalonate	mevalonate pathway
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle variation I
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	glyoxylate cycle
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle -- aerobic respiration
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	4.1.3.5	acetoacetyl-CoA + H2O + acetyl-CoA  =  coenzyme A + 3-hydroxy-3-methyl-glutaryl-CoA	mevalonate pathway
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.3.9	acetyl-CoA + H2O + glyoxylate  =  malate + coenzyme A	glyoxylate cycle
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	ACETYLSYNCLTH-RXN	CO + [Co-E-CH3] + coenzyme A  =  acetyl-CoA + [Co-E]	carbon monoxide dehydrogenase pathway
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.133	caffeoylquinate + coenzyme A  =  caffeoyl-CoA + quinate	lignin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.133	caffeoylshikimate + coenzyme A  =  caffeoyl-CoA + shikimate	lignin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	RXN-2006	oxocinnamoyl-CoA + coenzyme A  =  benzoyl-CoA + acetyl-CoA	salicylic acid biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.-	trans-cinnamate + coenzyme A  =  (E)-cinnamoyl-CoA + H2O	salicylic acid biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  AMP + pyrophosphate + O-succinylbenzoyl-CoA	menaquinone biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.3.2.-	coenzyme A + crotono-betaine  =  crotonobetainyl-CoA + H2O	carnitine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.-	coenzyme A + L-carnitine  =  L-carnitinyl-CoA + H2O	carnitine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.3.2.-	coenzyme A + D-carnitine  =  D-carnitinyl-CoA + H2O	carnitine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.12	caffeate + coenzyme A + ATP  =  caffeoyl-CoA + AMP + pyrophosphate	suberin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.12	ferulate + coenzyme A + ATP  =  feruloyl-CoA + AMP + pyrophosphate	suberin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	ALPHA-KETOBUTYRATE-DEHYDROG-RXN	2-oxobutanoate + coenzyme A + NAD+  =  propionyl-CoA + CO2 + NADH	methionine degradation I
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle variation I
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle -- aerobic respiration
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	TCA cycle variation I
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	superpathway of glycolysis, pyruvate dehydrogenase, TCA, and glyoxylate bypass
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle variation I
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle -- aerobic respiration
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.3	coenzyme A + a fatty acid + ATP  =  acyl-CoA + pyrophosphate + AMP	fatty acid beta-oxidation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.16	coenzyme A + beta-ketoacyl-CoA  =  acyl-CoA + acetyl-CoA	fatty acid beta-oxidation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	1.2.1.25	NAD+ + coenzyme A + 2-keto-isovalerate  =  NADH + CO2 + isobutyryl-CoA	valine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	1.2.1.27	NAD+ + coenzyme A + methylmalonate-semialdehyde  =  NADH + CO2 + propionyl-CoA	valine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2KETO-3METHYLVALERATE-RXN	2-keto-3-methyl-valerate + NAD+ + coenzyme A  =  2-methylbutyryl-CoA + NADH + CO2	isoleucine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2KETO-4METHYL-PENTANOATE-DEHYDROG-RXN	2-keto-4-methyl-pentanoate + coenzyme A + NAD+  =  isovaleryl-CoA + CO2 + NADH	leucine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	lysine degradation II
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	tryptophan degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.17	coenzyme A + propionate + ATP  =  propionyl-CoA + pyrophosphate + AMP	beta-alanine biosynthesis II
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  4-(2'-carboxyphenyl)-4-oxobutyryl-CoA + AMP + pyrophosphate	phylloquinone biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.-	fatty-acyl-CoA + malonyl-CoA  =  beta-ketoacyl-CoA + CO2 + coenzyme A	very long chain fatty acid biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	RXN-6724	benzyl alcohol + benzoyl-CoA  =  benzylbenzoate + coenzyme A	volatile benzenoid ester biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.84	benzyl alcohol + acetyl-CoA  =  benzylacetate + coenzyme A	volatile benzenoid ester biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	4.1.3.36	4-(2'-carboxyphenyl)-4-oxobutyryl-CoA  =  coenzyme A + 1,4-dihydroxy-2-naphthoate	phylloquinone biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	3.1.2.4	3-hydroxypropionyl-CoA + H2O  =  3-hydroxy-propionate + coenzyme A	beta-alanine biosynthesis II
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.170	coumaroyl-CoA + 3 malonyl-CoA + NADPH  =  isoliquiritigenin + 4 coenzyme A + 3 CO2 + NADP+ + H2O	flavonoid biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.74	coumaroyl-CoA + 3 malonyl-CoA  =  naringenin chalcone + 3 CO2 + 4 coenzyme A	flavonoid biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.7.1.24	dephospho-CoA + ATP  =  coenzyme A + ADP	coenzyme A biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.15	fatty-acyl-CoA + glycerol-3-phosphate  =  1-acyl-sn-glycerol-3P + coenzyme A	triacylglycerol biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.51	fatty-acyl-CoA + 1-acyl-sn-glycerol-3P  =  L-phosphatidate + coenzyme A	triacylglycerol biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.110	feruloyl-CoA + tyramine  =  N-feruloyltyramine + coenzyme A	suberin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.117	H2O + L-2,3,4,5-tetrahydrodipicolinate + succinyl-CoA  =  N-succinyl-2-amino-6-ketopimelate + coenzyme A	lysine biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	GLUCOSAMINE1PACETYL-RXN	glucosamine-1P + acetyl-CoA  =  N-acetyl-glucosamine-1-phosphate + coenzyme A	UDP-N-acetyl-D-glucosamine biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	RXN-2005	benzoyl-CoA + H2O  =  benzoate + coenzyme A	salicylic acid biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	RXN-2009	salicyloyl-CoA + H2O  =  salicylate + coenzyme A	salicylic acid biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	1.2.1.44	coumaroyl-CoA + NADPH  =  coumaraldehyde + NADP+ + coenzyme A	lignin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	1.2.1.44	feruloyl-CoA + NADPH  =  coniferyl aldehyde + NADP+ + coenzyme A	lignin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.133	quinate + coumaroyl-CoA  =  4-coumaroylquinate + coenzyme A	lignin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.133	shikimate + coumaroyl-CoA  =  4-coumaroylshikimate + coenzyme A	lignin biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.8	phosphate + acetyl-CoA  =  acetylphosphate + coenzyme A	carbon monoxide dehydrogenase pathway
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	3-OXOACYL-ACP-COA-SYNTHIII-RXN	acetyl-CoA + malonyl-ACP  =  acetoacetyl-ACP + coenzyme A + CO2	fatty acid biosynthesis - initial steps
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.3.-	2-oxo-4-methylthiobutanoic acid + acetyl-CoA + H2O  =  2-(2'-methylthio)ethylmalic-acid + coenzyme A	homomethionine biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	lysine degradation II
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	tryptophan degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	mevalonate pathway
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.20	acyl-CoA + 1,2-diacylglycerol  =  triacylglycerol + coenzyme A	triacylglycerol biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.1	L-glutamate + acetyl-CoA  =  N-acetyl-L-glutamate + coenzyme A	arginine biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.1	L-glutamate + acetyl-CoA  =  N-acetyl-L-glutamate + coenzyme A	arginine biosynthesis II (acetyl cycle)
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.39	acyl carrier protein + malonyl-CoA  =  malonyl-ACP + coenzyme A	fatty acid biosynthesis - initial steps
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	4.1.3.36	O-succinylbenzoyl-CoA  =  coenzyme A + 1,4-dihydroxy-2-naphthoate	menaquinone biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	3.1.2.4	H2O + 3-hydroxy-isobutyryl-CoA  =  3-hydroxy-isobutyrate + coenzyme A	valine degradation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.30	L-serine + acetyl-CoA  =  O-acetyl-L-serine + coenzyme A	cysteine biosynthesis
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.30	L-serine + acetyl-CoA  =  O-acetyl-L-serine + coenzyme A	sulfate assimilation
coenzyme A	Co-A-SH*CoA*co-A-SH*co-enzyme-A*co-A*HS-CoA	C21 H36 N7 O16 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCS)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)N2(c3(c(N=C2)c(N)ncn3)))	CAS:85-61-0*LIGAND-CPD:C00010	2.3.1.47	L-alanine + 6-carboxyhexanoyl-CoA  =  CO2 + coenzyme A + 8-amino-7-oxononanoate	biotin biosynthesis II
glycolate	hydroxyacetic acid*glycolic acid	C2 H4 O3 	C(=O)(O)CO	LIGAND:C00160*CAS:79-14-1	1.1.3.15	glycolate + O2  =  glyoxylate + H2O2	photorespiration
glycolate	hydroxyacetic acid*glycolic acid	C2 H4 O3 	C(=O)(O)CO	LIGAND:C00160*CAS:79-14-1	3.1.3.18	H2O + 2-phosphoglycolate  =  glycolate + phosphate	photorespiration
ferulate	ferulic acid*Ferulate*3-methoxy-4-hydroxycinnamic acid*caffeic acid 3-methyl ether*4-Hydroxy-3-methoxycinnamic acid*3-Methoxy-4-hydroxy-trans-cinnamate	C10 H10 O4 	C(O)(=O)C=Cc1(cc(OC)c(O)cc1)	CAS:1135-24-6	RXN-1121	ferulate + NADPH + O2  =  5-hydroxy-ferulic-acid + H2O + NADP+	phenylpropanoid biosynthesis
ferulate	ferulic acid*Ferulate*3-methoxy-4-hydroxycinnamic acid*caffeic acid 3-methyl ether*4-Hydroxy-3-methoxycinnamic acid*3-Methoxy-4-hydroxy-trans-cinnamate	C10 H10 O4 	C(O)(=O)C=Cc1(cc(OC)c(O)cc1)	CAS:1135-24-6	6.2.1.12	ferulate + coenzyme A + ATP  =  feruloyl-CoA + AMP + pyrophosphate	suberin biosynthesis
ferulate	ferulic acid*Ferulate*3-methoxy-4-hydroxycinnamic acid*caffeic acid 3-methyl ether*4-Hydroxy-3-methoxycinnamic acid*3-Methoxy-4-hydroxy-trans-cinnamate	C10 H10 O4 	C(O)(=O)C=Cc1(cc(OC)c(O)cc1)	CAS:1135-24-6	2.1.1.68	caffeate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + ferulate	phenylpropanoid biosynthesis
ferulate	ferulic acid*Ferulate*3-methoxy-4-hydroxycinnamic acid*caffeic acid 3-methyl ether*4-Hydroxy-3-methoxycinnamic acid*3-Methoxy-4-hydroxy-trans-cinnamate	C10 H10 O4 	C(O)(=O)C=Cc1(cc(OC)c(O)cc1)	CAS:1135-24-6	2.1.1.68	caffeate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + ferulate	suberin biosynthesis
thiamine-phosphate	thiamin monophosphate*thiamin phosphate*thiamin-P*thiamine-Pi*ThP*thiamine monophosphate	C12 H18 N4 O4 P1 S1 	c1(c(cnc(n1)C)C[n+1]2(c(C)c(sc2)CCOP(=O)(O)O))(N)		2.7.4.16	thiamine-phosphate + ATP  =  thiamin diphosphate + ADP	thiamin biosynthesis
thiamine-phosphate	thiamin monophosphate*thiamin phosphate*thiamin-P*thiamine-Pi*ThP*thiamine monophosphate	C12 H18 N4 O4 P1 S1 	c1(c(cnc(n1)C)C[n+1]2(c(C)c(sc2)CCOP(=O)(O)O))(N)		2.7.1.89	thiamine + ATP  =  thiamine-phosphate + ADP	thiamin biosynthesis
thiamine-phosphate	thiamin monophosphate*thiamin phosphate*thiamin-P*thiamine-Pi*ThP*thiamine monophosphate	C12 H18 N4 O4 P1 S1 	c1(c(cnc(n1)C)C[n+1]2(c(C)c(sc2)CCOP(=O)(O)O))(N)		2.5.1.3	4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate  =  thiamine-phosphate + pyrophosphate	thiamin biosynthesis
pyridoxamine	PM	C8 H12 N2 O2 	C(N)c1(c(CO)cnc(C)c1O)	CAS:85-87-0	PYRAMKIN-RXN	ATP + pyridoxamine  =  ADP + pyridoxamine 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.39	H2O + CO2 + D-ribulose-1,5-bisphosphate  =  2 3-phosphoglycerate	Calvin cycle
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis II (from tryptophan)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis I (from aspartate)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.21	5-aminoimidazole ribonucleotide + ATP + CO2 + H2O  =  phosphate + phosphoribosyl-carboxy-aminoimidazole + ADP	de novo biosynthesis of purine nucleotides II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.7.2.2	carbamoyl-phosphate + ADP  =  NH3 + CO2 + ATP	citrulline degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	6.3.3.3	CO2 + 7,8-diaminononanoate + ATP  =  dethiobiotin + phosphate + ADP	biotin biosynthesis II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN0-742	5-aminoimidazole ribonucleotide + ATP + H2O + CO2  =  N5-carboxyaminoimidazole ribonucleotide + ADP + phosphate	de novo biosynthesis of purine nucleotides I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	PROPIONYL-COA-CARBOXYLASE-RXN	propionyl-CoA + H2O + ATP + CO2  =  D-methylmalonyl-CoA + phosphate + ADP	methionine degradation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.3.1.-	fatty-acyl-CoA + malonyl-CoA  =  beta-ketoacyl-CoA + CO2 + coenzyme A	very long chain fatty acid biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.7.3.3	urate + O2  =  allantoin + CO2 + H2O2	purine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.22	naringenin + alpha-ketoglutarate + O2  =  apigenin + succinate + CO2 + H2O	luteolin biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.22	eriodictyol + alpha-ketoglutarate + O2  =  luteolin + succinate + CO2 + H2O	luteolin biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN-7568	1,4-dihydroxy-2-naphthoate + phytyl pyrophosphate  =  demethylphylloquinone + CO2 + pyrophosphate	phylloquinone biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.17.4	L-ascorbate + 1-aminocyclopropane-1-carboxylate + O2  =  2 H2O + ethene + L-dehydro-ascorbate + hydrogen cyanide + CO2	ethylene biosynthesis from methionine
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA20 + alpha-ketoglutarate + O2  =  GA29 + succinate + CO2	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA8 + alpha-ketoglutarate + O2  =  GA8-catabolite + succinate + CO2 + H2O	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.13	GA1 + alpha-ketoglutarate + O2  =  GA8 + succinate + CO2	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA29 + alpha-ketoglutarate + O2  =  GA29-catabolite + succinate + CO2 + H2O	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA51 + succinate + CO2	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA51 + alpha-ketoglutarate + O2  =  GA51-catabolite + succinate + CO2 + H2O	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA34 + alpha-ketoglutarate + O2  =  GA34-catabolite + succinate + CO2 + H2O	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA110 + succinate + CO2	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA97 + succinate + CO2	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA98 + succinate + CO2	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA17 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA20 + succinate + 2 CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA44 + CO2 + succinate	gibberellin biosynthesis III (early C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA14 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA37 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2 + H2O	gibberellin biosynthesis II (early C-3 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA14 + O2 + alpha-ketoglutarate  =  GA37 + CO2 + succinate	gibberellin biosynthesis II (early C-3 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA36 + O2 + alpha-ketoglutarate  =  GA4 + succinate + 2 CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA25 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA9 + succinate + 2 CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA15 + O2 + alpha-ketoglutarate  =  GA24 + H2O + CO2 + succinate	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA15 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.3.1.170	coumaroyl-CoA + 3 malonyl-CoA + NADPH  =  isoliquiritigenin + 4 coenzyme A + 3 CO2 + NADP+ + H2O	flavonoid biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.7.3.3	urate + H2O2  =  allantoin + CO2	ureide biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.-.-.-	NAD(P)+ + coproporphyrinogen III  =  protoporphyrinogen + NAD(P)H + 2 CO2	biosynthesis of proto- and siroheme
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	superpathway of gluconate degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	oxidative branch of the pentose phosphate pathway
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.19	leucocyanidin + alpha-ketoglutarate + O2  =  cyanidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.2.2.1	ferricytochrome b1 + formate  =  ferrocytochrome b1 + CO2	glycine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.3.1.43	L-arogenate + NADP+  =  L-tyrosine + NADPH + CO2	tyrosine biosynthesis II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.3.1.43	NAD+ + L-arogenate  =  L-tyrosine + CO2 + NADH	tyrosine biosynthesis II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.2.1.91	L-arogenate  =  CO2 + H2O + L-phenylalanine	phenylalanine biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN-527	dihydroquercetin + alpha-ketoglutarate + O2  =  quercetin + succinate + CO2 + H2O	flavonol biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN1F-93	dihydrokaempferol + alpha-ketoglutarate + O2  =  kaempferol + succinate + CO2 + H2O	flavonol biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN-5641	L-serine  =  ethanolamine + CO2	choline biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA4 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.12	GA44 + alpha-ketoglutarate + O2  =  GA19 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.15	GA20 + alpha-ketoglutarate + O2  =  GA1 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA38 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA15 + alpha-ketoglutarate + O2  =  GA37 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA25 + alpha-ketoglutarate + O2  =  GA13 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.-	GA4 + alpha-ketoglutarate + O2  =  GA34 + succinate + CO2	gibberellin inactivation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.1	pyruvate  =  acetaldehyde + CO2	sucrose degradation to ethanol and lactate (anaerobic)
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.13.-	L-phenylalanine + NADPH + O2  =  phenylacetaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from phenylalanine
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN-4122	a 2(R)-hydroperoxy fatty acid  =  a fatty aldehyde + CO2 + H2O	fatty acid alpha-oxidation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.19	leucopelargonidin + alpha-ketoglutarate + O2  =  pelargonidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.3.1.74	coumaroyl-CoA + 3 malonyl-CoA  =  naringenin chalcone + 3 CO2 + 4 coenzyme A	flavonoid biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.11.9	naringenin + O2 + alpha-ketoglutarate  =  CO2 + succinate + dihydrokaempferol	flavonoid biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.45	2-amino-3-carboxymuconate semialdehyde  =  CO2 + 2-aminomuconate semialdehyde	tryptophan degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	lysine degradation II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	tryptophan degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.70	glutaconyl-CoA  =  CO2 + crotonyl-CoA	lysine degradation II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.70	glutaconyl-CoA  =  CO2 + crotonyl-CoA	tryptophan degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN1F-17	indole carboxyl thiazole  =  3-thiazol-2'-yl-indole + CO2	camalexin biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN-1026	fatty-acyl-CoA + malonyl-CoA  =  very-long-chain-fatty-acyl-CoA + CO2	epicuticular wax biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.13.-	homomethionine + NADPH + O2  =  4-methylthiobutanaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from homomethionine
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN-2761	homogentisate + solanyl pyrophosphate  =  2-methyl-6-solanyl-1,4-benzoquinone + CO2 + pyrophosphate	plastoquinone biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.3.1.12	prephenate + NAD+  =  p-hydroxyphenylpyruvate + CO2 + NADH	tyrosine biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2KETO-4METHYL-PENTANOATE-DEHYDROG-RXN	2-keto-4-methyl-pentanoate + coenzyme A + NAD+  =  isovaleryl-CoA + CO2 + NADH	leucine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.74	indole-3-pyruvate  =  CO2 + indole acetaldehyde	IAA biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.28	L-tryptophan  =  CO2 + tryptamine	IAA biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.3.1.41	acyl-ACP + malonyl-ACP  =  acyl carrier protein + beta-ketoacyl-ACP + CO2	fatty acid elongation -- saturated
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.-	3-(2'-methylthio)ethylmalic-acid  =  2-oxo-5-methylthiopentanoic-acid + CO2	homomethionine biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2KETO-3METHYLVALERATE-RXN	2-keto-3-methyl-valerate + NAD+ + coenzyme A  =  2-methylbutyryl-CoA + NADH + CO2	isoleucine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.2.1.6	pyruvate + 2-oxobutanoate  =  2-aceto-2-hydroxy-butyrate + CO2	isoleucine biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.36	R-4'-phosphopantothenoyl-L-cysteine  =  pantetheine 4'-phosphate + CO2	coenzyme A biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	3.5.3.9	2 H2O + 2 allantoate  =  2 NH3 + O2 + 2 CO2 + 2 ureidoglycine	ureide degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	3.5.3.19	H2O + (S)-ureidoglycolate  =  2 NH3 + CO2 + glyoxylate	ureide degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis III
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.19	L-arginine  =  CO2 + agmatine	arginine degradation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.19	L-arginine  =  CO2 + agmatine	spermine biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.19	L-arginine  =  CO2 + agmatine	polyamine biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.17	L-ornithine  =  CO2 + putrescine	polyamine biosynthesis III
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.17	L-ornithine  =  CO2 + putrescine	spermine biosynthesis II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.17	L-ornithine  =  CO2 + putrescine	polyamine biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.2.1.27	NAD+ + coenzyme A + methylmalonate-semialdehyde  =  NADH + CO2 + propionyl-CoA	valine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.2.1.25	NAD+ + coenzyme A + 2-keto-isovalerate  =  NADH + CO2 + isobutyryl-CoA	valine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.32	oxaloacetate + GTP  =  CO2 + phosphoenolpyruvate + GDP	phenylalanine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	TCA cycle variation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	superpathway of glycolysis, pyruvate dehydrogenase, TCA, and glyoxylate bypass
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle variation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle -- aerobic respiration
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	ALPHA-KETOBUTYRATE-DEHYDROG-RXN	2-oxobutanoate + coenzyme A + NAD+  =  propionyl-CoA + CO2 + NADH	methionine degradation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.3.99.1	HCO3- + cyanate  =  carbamate + CO2	cyanate degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	THREOSPON-RXN	2-amino-3-oxobutanoate  =  aminoacetone + CO2	threonine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.31	phosphate + oxaloacetate  =  phosphoenolpyruvate + H2O + CO2	gluconeogenesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	TCA cycle variation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	gluconeogenesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	TCA cycle variation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	gluconeogenesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	DMK-RXN	1,4-dihydroxy-2-naphthoate + octaprenyl diphosphate  =  demethylmenaquinone-8 + pyrophosphate + CO2	menaquinone biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.2.1.43	NADPH + CO2  =  NADP+ + formate	carbon monoxide dehydrogenase pathway
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.2.99.2	reduced acceptor + CO2  =  acceptor + H2O + CO	carbon monoxide dehydrogenase pathway
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	photorespiration
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	3-OXOACYL-ACP-COA-SYNTHIII-RXN	acetyl-CoA + malonyl-ACP  =  acetoacetyl-ACP + coenzyme A + CO2	fatty acid biosynthesis - initial steps
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.18	L-lysine  =  CO2 + cadaverine	lysine degradation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	3.5.1.6	H2O + 3-ureidopropionate  =  NH3 + CO2 + beta-alanine	beta-alanine biosynthesis III
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.65	L-1-phosphatidylserine  =  L-1-phosphatidyl-ethanolamine + CO2	phospholipid biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.20	meso-diaminopimelate  =  CO2 + L-lysine	lysine biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.3.37	pyruvate + D-glyceraldehyde-3-phosphate  =  1-deoxy-D-xylulose 5-phosphate + CO2	thiamin biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.3.37	pyruvate + D-glyceraldehyde-3-phosphate  =  1-deoxy-D-xylulose 5-phosphate + CO2	isopentenyl diphosphate biosynthesis -- mevalonate-independent
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.23	orotidine-5'-phosphate  =  CO2 + UMP	de novo biosynthesis of pyrimidine ribonucleotides
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.50	S-adenosyl-L-methionine  =  CO2 + S-adenosylmethioninamine	polyamine biosynthesis III
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.50	S-adenosyl-L-methionine  =  CO2 + S-adenosylmethioninamine	polyamine biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	polyamine biosynthesis III
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	arginine degradation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	superpathway of glyoxylate cycle
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	gluconeogenesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.37	uroporphyrinogen-III  =  4 CO2 + coproporphyrinogen III	chlorophyllide a biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.37	uroporphyrinogen-III  =  4 CO2 + coproporphyrinogen III	biosynthesis of proto- and siroheme
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.48	1-(o-carboxyphenylamino)-1'-deoxyribulose-5'-phosphate  =  indole-3-glycerol-phosphate + CO2 + H2O	tryptophan biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	RXN-2541	homogentisate + phytyl pyrophosphate  =  2-methyl-6-phytyl-1,4-benzoquinone + CO2 + pyrophosphate	vitamin E biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.33	mevalonate-5-PP + ATP  =  phosphate + CO2 + delta3-isopentenyl-PP + ADP	mevalonate pathway
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.71	alpha-ketoglutarate + thiamin diphosphate  =  succinate-semialdehyde-thiamine PPi + CO2	menaquinone biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.15	L-glutamate  =  CO2 + 4-aminobutyrate	glutamate degradation II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	3.5.1.5	H2O + urea  =  2 NH3 + CO2	ureide degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	chlorophyllide a biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	biosynthesis of proto- and siroheme
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.2.1.6	2 pyruvate  =  2-acetolactate + CO2	valine biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	2.3.1.47	L-alanine + 6-carboxyhexanoyl-CoA  =  CO2 + coenzyme A + 8-amino-7-oxononanoate	biotin biosynthesis II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.4.4.2	H-protein-(lipoyl)lysine + glycine  =  CO2 + S-aminomethyldihydrolipoyl-GcvH-protein	glycine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.2.1.51	prephenate  =  phenylpyruvate + H2O + CO2	phenylalanine biosynthesis II
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.1.1.35	UDP-D-glucuronate  =  UDP-D-xylose + CO2	UDP-D-xylose biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	vitamin E biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	tyrosine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	plastoquinone biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	phenylalanine degradation
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.85	2-D-threo-hydroxy-3-carboxy-isocaproate + NAD+  =  2-keto-4-methyl-pentanoate + NADH + CO2	leucine biosynthesis
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle variation I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.1.1.42	isocitrate + NADP+  =  NADPH + alpha-ketoglutarate + CO2	TCA cycle -- aerobic respiration
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	IAA biosynthesis I
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	glucosinolate biosynthesis from tryptophan
CO2	carbonic anhydride*carbonic acid gas*carbon dioxide	C1 O2 	C(=O)=O	LIGAND-CPD:C00011*CAS:124-38-9	4.2.1.1	H2O + CO2  =  H2CO3	cyanate degradation
7,8-diaminononanoate	7,8-diaminopelargonate*DAPA	C9 H20 N2 O2 	CC(N)C(N)CCCCCC(=O)O	LIGAND-CPD:C01037	6.3.3.3	CO2 + 7,8-diaminononanoate + ATP  =  dethiobiotin + phosphate + ADP	biotin biosynthesis II
7,8-diaminononanoate	7,8-diaminopelargonate*DAPA	C9 H20 N2 O2 	CC(N)C(N)CCCCCC(=O)O	LIGAND-CPD:C01037	2.6.1.62	S-adenosyl-L-methionine + 8-amino-7-oxononanoate  =  S-adenosyl-4-methylthio-2-oxobutanoate + 7,8-diaminononanoate	biotin biosynthesis II
adenosine diphosphate ribose	ADP-D-ribose*ADP-ribose	C15 H23 N5 O14 P2 	C(OP(O)(=O)OP(=O)(O)OC1(OC(CO)C(O)C(O)1))C2(OC(C(O)C(O)2)n3(c4(c(nc3)c(N)ncn4)))	CAS:20762-30-5	3.2.2.5	H2O + NAD+  =  adenosine diphosphate ribose + nicotinamide	pyridine nucleotide cycling
phytyl pyrophosphate	phytyl pyrophosphate*Phytyl PP	C20 H42 O7 P2 	C(OP(O)(=O)OP(O)(=O)O)C=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C		RXN-2541	homogentisate + phytyl pyrophosphate  =  2-methyl-6-phytyl-1,4-benzoquinone + CO2 + pyrophosphate	vitamin E biosynthesis
phytyl pyrophosphate	phytyl pyrophosphate*Phytyl PP	C20 H42 O7 P2 	C(OP(O)(=O)OP(O)(=O)O)C=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C		2.5.1.62	chlorophyllide a + phytyl pyrophosphate  =  chlorophyll a + pyrophosphate	chlorophyll cycle
phytyl pyrophosphate	phytyl pyrophosphate*Phytyl PP	C20 H42 O7 P2 	C(OP(O)(=O)OP(O)(=O)O)C=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C		2.5.1.62	chlorophyllide a + phytyl pyrophosphate  =  chlorophyll a + pyrophosphate	chlorophyll a biosynthesis I
phytyl pyrophosphate	phytyl pyrophosphate*Phytyl PP	C20 H42 O7 P2 	C(OP(O)(=O)OP(O)(=O)O)C=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C		RXN-7568	1,4-dihydroxy-2-naphthoate + phytyl pyrophosphate  =  demethylphylloquinone + CO2 + pyrophosphate	phylloquinone biosynthesis
phytyl pyrophosphate	phytyl pyrophosphate*Phytyl PP	C20 H42 O7 P2 	C(OP(O)(=O)OP(O)(=O)O)C=C(C)CCC[CH](C)CCC[CH](C)CCCC(C)C		2.5.1.-	chlorophyllide b + phytyl pyrophosphate  =  chlorophyll b + pyrophosphate	chlorophyll cycle
ent-copalyl diphosphate	<i>ent</i>-CDP*<i>ent</i>-copalyl diphosphate*<i>ent</i>-CPP*CPP*CDP	C20 H36 O7 P2 	CC(=CCOP(O)(=O)OP(O)(=O)O)CC[CH]1(C(=C)CC[CH]2(C1(C)CCCC(C)(C)2))		4.2.3.19	ent-copalyl diphosphate  =  pyrophosphate + ent-kaur-16-ene	ent-kaurene biosynthesis
ent-copalyl diphosphate	<i>ent</i>-CDP*<i>ent</i>-copalyl diphosphate*<i>ent</i>-CPP*CPP*CDP	C20 H36 O7 P2 	CC(=CCOP(O)(=O)OP(O)(=O)O)CC[CH]1(C(=C)CC[CH]2(C1(C)CCCC(C)(C)2))		5.5.1.13	geranylgeranyl-PP  =  ent-copalyl diphosphate	ent-kaurene biosynthesis
carbamoyl-L-aspartate	carbamyul-L-aspartate*N-carbamoyl-L-aspartate*carbamyul-aspartate*carbamoyl-aspartate*carbamyl-aspartate*carbamyl-L-aspartate	C5 H8 N2 O5 	C(=O)(O)CC(C(O)=O)NC(N)=O	CAS:16649-79-9	2.1.3.2	L-aspartate + carbamoyl-phosphate  =  carbamoyl-L-aspartate + phosphate	de novo biosynthesis of pyrimidine ribonucleotides
carbamoyl-L-aspartate	carbamyul-L-aspartate*N-carbamoyl-L-aspartate*carbamyul-aspartate*carbamoyl-aspartate*carbamyl-aspartate*carbamyl-L-aspartate	C5 H8 N2 O5 	C(=O)(O)CC(C(O)=O)NC(N)=O	CAS:16649-79-9	3.5.2.3	carbamoyl-L-aspartate  =  dihydroorotate + H2O	de novo biosynthesis of pyrimidine ribonucleotides
UDP-L-arabinose	UDP-&beta;-L-arabinose*UDP-arabinose	C14 H22 N2 O16 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)CO3)))		5.1.3.5	UDP-D-xylose  =  UDP-L-arabinose	UDP-L-arabinose biosynthesis I (from UDP-xylose)
UDP-L-arabinose	UDP-&beta;-L-arabinose*UDP-arabinose	C14 H22 N2 O16 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)CO3)))		RXN-7401	beta-L-arabinose 1-phosphate + UTP  =  UDP-L-arabinose + pyrophosphate	UDP-L-arabinose biosynthesis II (from L-arabinose)
p-hydroxyphenylpyruvate	hydroxyphenylpyruvate*4-hydroxyphenylpyruvate	C9 H8 O4 	C(=O)(O)C(=O)Cc1(ccc(O)cc1)	CAS:156-39-8	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	vitamin E biosynthesis
p-hydroxyphenylpyruvate	hydroxyphenylpyruvate*4-hydroxyphenylpyruvate	C9 H8 O4 	C(=O)(O)C(=O)Cc1(ccc(O)cc1)	CAS:156-39-8	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	tyrosine degradation
p-hydroxyphenylpyruvate	hydroxyphenylpyruvate*4-hydroxyphenylpyruvate	C9 H8 O4 	C(=O)(O)C(=O)Cc1(ccc(O)cc1)	CAS:156-39-8	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	plastoquinone biosynthesis
p-hydroxyphenylpyruvate	hydroxyphenylpyruvate*4-hydroxyphenylpyruvate	C9 H8 O4 	C(=O)(O)C(=O)Cc1(ccc(O)cc1)	CAS:156-39-8	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	phenylalanine degradation
p-hydroxyphenylpyruvate	hydroxyphenylpyruvate*4-hydroxyphenylpyruvate	C9 H8 O4 	C(=O)(O)C(=O)Cc1(ccc(O)cc1)	CAS:156-39-8	2.6.1.57	p-hydroxyphenylpyruvate + L-glutamate  =  L-tyrosine + alpha-ketoglutarate	tyrosine biosynthesis I
p-hydroxyphenylpyruvate	hydroxyphenylpyruvate*4-hydroxyphenylpyruvate	C9 H8 O4 	C(=O)(O)C(=O)Cc1(ccc(O)cc1)	CAS:156-39-8	1.3.1.12	prephenate + NAD+  =  p-hydroxyphenylpyruvate + CO2 + NADH	tyrosine biosynthesis I
p-hydroxyphenylpyruvate	hydroxyphenylpyruvate*4-hydroxyphenylpyruvate	C9 H8 O4 	C(=O)(O)C(=O)Cc1(ccc(O)cc1)	CAS:156-39-8	2.6.1.5	L-tyrosine + alpha-ketoglutarate  =  L-glutamate + p-hydroxyphenylpyruvate	tyrosine degradation
p-hydroxyphenylpyruvate	hydroxyphenylpyruvate*4-hydroxyphenylpyruvate	C9 H8 O4 	C(=O)(O)C(=O)Cc1(ccc(O)cc1)	CAS:156-39-8	2.6.1.5	L-tyrosine + alpha-ketoglutarate  =  L-glutamate + p-hydroxyphenylpyruvate	phenylalanine degradation
E-pyridine-3-aldoxime		C6 H6 N2 O1 	C(=NO)C1(C=NC=CC=1)		4.2.1.-	E-pyridine-3-aldoxime  =  3-cyanopyridine + H2O	aldoxime degradation
D-3-hydroxyacyl-CoA	(R)-3-hydroxyacyl-CoA*(R)-hydroxyacyl-CoA*cis-3-hydroxyacyl-CoA*RCHOHCH2CO-CoA*3-OH-acyl-CoA*3-hydroxyacyl-CoA	C24 H39 N7 O18 R1 P3 S1 			5.1.2.3	D-3-hydroxyacyl-CoA  =  L-3-hydroxyacyl-CoA	fatty acid beta-oxidation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	homoserine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	lysine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	sucrose degradation to ethanol and lactate (anaerobic)
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	gluconeogenesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glyceraldehyde 3-phosphate degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	XANTHOSINEPHOSPHORY-RXN	xanthosine + phosphate  =  ribose-1-phosphate + xanthine	ureide biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.3.1.8	phosphate + acetyl-CoA  =  acetylphosphate + coenzyme A	carbon monoxide dehydrogenase pathway
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.1.1.31	phosphate + oxaloacetate  =  phosphoenolpyruvate + H2O + CO2	gluconeogenesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.59	NAD(P)H + 1,3-diphosphateglycerate  =  NAD(P)+ + D-glyceraldehyde-3-phosphate + phosphate	Calvin cycle
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.1.2.15	phosphoenolpyruvate + D-erythrose-4-phosphate + H2O  =  3-deoxy-D-arabino-heptulosonate-7-phosphate + phosphate	chorismate biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.4.1.1	Long-linear-glucans + phosphate  =  alpha-D-glucose-1-phosphate	starch degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.4.2.4	phosphate + thymidine  =  deoxyribose-1-phosphate + thymine	(deoxy)ribose phosphate degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	URA-PHOSPH-RXN	phosphate + deoxyuridine  =  deoxyribose-1-phosphate + uracil	(deoxy)ribose phosphate degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.4.2.3	phosphate + uridine  =  ribose-1-phosphate + uracil	(deoxy)ribose phosphate degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.3	10-formyl-H4PteGlun + ADP + phosphate  =  THF polyglutamate + ATP + formate	tetrahydrofolate biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-4542	cis-zeatin riboside monophosphate + H2O  =  cis-zeatin riboside + phosphate	cis-zeatin biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.5	IMP + H2O  =  inosine + phosphate	purine degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.5	IMP + H2O  =  inosine + phosphate	salvage pathways of purine nucleosides
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.5	GMP + H2O  =  guanosine + phosphate	purine degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.5	GMP + H2O  =  guanosine + phosphate	salvage pathways of purine nucleosides
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.5	AMP + H2O  =  adenosine + phosphate	salvage pathways of purine nucleosides
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.-	H2O + NADP+  =  NAD+ + phosphate	NAD/NADH phosphorylation and dephosphorylation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.-	NADPH + H2O  =  NADH + phosphate	NAD/NADH phosphorylation and dephosphorylation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7304	D-myo-inositol (2,3,4) trisphosphate + H2O  =  D-myo-inositol (2,4) bisphosphate + phosphate	phytate degradation II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7303	D-myo-inositol (1,2,3,4) tetrakisphosphate + H2O  =  D-myo-inositol (2,3,4) trisphosphate + phosphate	phytate degradation II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7302	D-myo-inositol (1,2,3,4) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,3) trisphosphate + phosphate	phytate degradation II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7301	D-myo-inositol (1,2,3,4,5)-pentakisphosphate + H2O  =  D-myo-inositol (1,2,3,4) tetrakisphosphate + phosphate	phytate degradation II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.26	H2O + phytate  =  phosphate + D-myo-inositol (1,2,3,4,5)-pentakisphosphate	phytate degradation II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7305	D-myo-inositol (2,4) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7251	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-Inositol (1)-monophosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7253	D-myo-inositol (2) monophosphate + H2O  =  myo-inositol + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7252	D-myo-Inositol (1)-monophosphate + H2O  =  myo-inositol + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7250	D-myo-inositol (1,2,3) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7250	D-myo-inositol (1,2,3) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7249	D-myo-inositol (1,2,3,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,6) trisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7248	D-myo-inositol (1,2,3,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,3) trisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7247	D-myo-inositol (1,2,3,5,6) pentakisphosphate + H2O  =  D-myo-inositol (1,2,3,6) tetrakisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7246	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7246	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7245	D-myo-inositol (1,2,6) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7244	D-myo-inositol (1,2,5,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,6) trisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7243	D-myo-inositol (1,2,4,5,6)-pentakisphosphate + H2O  =  D-myo-inositol (1,2,5,6) tetrakisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-7242	D-myo-inositol (1,2,3,5,6) pentakisphosphate + H2O  =  D-myo-inositol (1,2,5,6) tetrakisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.26	phytate + H2O  =  D-myo-inositol (1,2,3,5,6) pentakisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.8	phytate + H2O  =  D-myo-inositol (1,2,4,5,6)-pentakisphosphate + phosphate	phytate degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.6.1.1	ATP + protoporphyrin IX + Mg2+ + H2O  =  Mg-protoporphyrin + H+ + phosphate + ADP	chlorophyllide a biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	LUMAZINESYN-RXN	5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + 3,4-dihydroxy-2-butanone-4-P  =  6,7-dimethyl-8-(1-D-ribityl)lumazine + phosphate + O2	riboflavin and FMN and FAD biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	arginine biosynthesis III
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	proline biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	R83-RXN	2-hydroxy-3-keto-5-methylthio-1-phosphopentene + H2O  =  1,2-dihydroxy-3-keto-5-methylthiopentene + phosphate	methionine salvage pathway
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.17	tetrahydrofolate + L-glutamate + ATP  =  THF-L-glutamate + ADP + phosphate	tetrahydrofolate biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-5647	phosphoryl-choline + H2O  =  choline + phosphate	choline biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.22	H2O + mannitol-1-phosphate  =  phosphate + mannitol	mannitol biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-4309	isopentenyladenosine-5'-triphosphate + H2O  =  isopentenyladenosine-5'-diphosphate + phosphate	trans-zeatin biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-4310	trans-zeatin riboside triphosphate + H2O  =  trans-zeatin riboside diphosphate + phosphate	trans-zeatin biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-4312	trans-zeatin riboside diphosphate + H2O  =  trans-zeatin riboside monophosphate + phosphate	trans-zeatin biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-4311	isopentenyladenosine-5'-diphosphate + H2O  =  isopentenyladenosine-5'-monophosphate + phosphate	trans-zeatin biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-4314	trans-zeatin riboside monophosphate + H2O  =  trans-zeatin riboside + phosphate	trans-zeatin biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-4313	isopentenyladenosine-5'-monophosphate + H2O  =  isopentenyl adenosine + phosphate	trans-zeatin biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	purine degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	salvage pathways of purine nucleosides
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	XMPXAN-RXN	xanthosine-5-phosphate + H2O  =  xanthosine + phosphate	ureide biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.6.1.40	H2O + guanosine 3'-diphosphate 5'-triphosphate  =  phosphate + guanosine 5'-diphosphate,3'-diphosphate	ppGpp biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.27	L-1-phosphatidylglycerol-phosphate + H2O  =  L-1-phosphatidyl-glycerol + phosphate	phospholipid biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.4.1.4	HCO3- + 3-methylcrotonyl-CoA + ATP  =  phosphate + trans-3-methylglutaconyl-CoA + ADP	leucine degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.15	L-histidinol-phosphate + H2O  =  histidinol + phosphate	histidine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	isoleucine degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	valine degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle variation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle -- aerobic respiration
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	PROPIONYL-COA-CARBOXYLASE-RXN	propionyl-CoA + H2O + ATP + CO2  =  D-methylmalonyl-CoA + phosphate + ADP	methionine degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.2.99.-	L-cysteine + O-phospho-L-homoserine  =  cystathionine + phosphate	methionine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.2.99.-	L-cysteine + O-phospho-L-homoserine  =  cystathionine + phosphate	sulfate assimilation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.6.1.1	H2O + pyrophosphate  =  2 phosphate	UDP-glucose conversion
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.37	H2O + D-sedoheptulose-1,7-bisphosphate  =  phosphate + D-sedoheptulose-7-phosphate	Calvin cycle
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.7.7.22	mannose-1-phosphate + GDP  =  GDP-mannose + phosphate	colanic acid building blocks biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.7.7.22	mannose-1-phosphate + GDP  =  GDP-mannose + phosphate	GDP-D-rhamnose biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN-1883	GDP-L-galactose + 2 H2O  =  L-galactose + GMP + phosphate	ascorbate biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.7.1.90	D-fructose-6-phosphate + pyrophosphate  =  phosphate + fructose-1,6-bisphosphate	glycolysis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.6.1.-	dihydroneopterin phosphate + H2O  =  dihydro-neo-pterin + phosphate	tetrahydrofolate biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.6.1.-	dihydroneopterin phosphate + H2O  =  dihydro-neo-pterin + phosphate	tetrahydrofolate biosynthesis II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.1.3.2	L-aspartate + carbamoyl-phosphate  =  carbamoyl-L-aspartate + phosphate	de novo biosynthesis of pyrimidine ribonucleotides
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.1.2.-	5-phospho-ribosyl-glycineamide + formate + ATP  =  phosphate + 5'-phosphoribosyl-N-formylglycineamide + ADP	de novo biosynthesis of purine nucleotides I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RXN0-742	5-aminoimidazole ribonucleotide + ATP + H2O + CO2  =  N5-carboxyaminoimidazole ribonucleotide + ADP + phosphate	de novo biosynthesis of purine nucleotides I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.4.1.2	HCO3- + H+ + acetyl-CoA + ATP  =  malonyl-CoA + phosphate + ADP	fatty acid biosynthesis - initial steps
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	RIBOPHOSPHAT-RXN	5-amino-6-(5'-phosphoribitylamino)uracil + H2O  =  5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + phosphate	riboflavin and FMN and FAD biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.3.2	N5-formyl-H4F + ATP  =  5,10-methenyl-THF + ADP + phosphate	formylTHF biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.3	glycine + L-gamma-glutamylcysteine + ATP  =  glutathione + phosphate + ADP	glutathione biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	QUINOLINATE-SYNTHA-RXN	iminoaspartate + dihydroxy-acetone-phosphate  =  quinolinate + 2 H2O + phosphate	NAD biosynthesis I (from aspartate)
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.3.3	CO2 + 7,8-diaminononanoate + ATP  =  dethiobiotin + phosphate + ADP	biotin biosynthesis II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.2.3.4	3-deoxy-D-arabino-heptulosonate-7-phosphate  =  phosphate + 3-dehydroquinate	chorismate biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.2	L-cysteine + L-glutamate + ATP  =  L-gamma-glutamylcysteine + phosphate + ADP	glutathione biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.4.2.11	nicotinate + H2O + PRPP + ATP  =  nicotinate nucleotide + pyrophosphate + phosphate + ADP	pyridine nucleotide cycling
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis II (acetyl cycle)
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.1.1.21	5-aminoimidazole ribonucleotide + ATP + CO2 + H2O  =  phosphate + phosphoribosyl-carboxy-aminoimidazole + ADP	de novo biosynthesis of purine nucleotides II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.1.1.33	mevalonate-5-PP + ATP  =  phosphate + CO2 + delta3-isopentenyl-PP + ADP	mevalonate pathway
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.11	fructose-1,6-bisphosphate + H2O  =  D-fructose-6-phosphate + phosphate	Calvin cycle
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.11	fructose-1,6-bisphosphate + H2O  =  D-fructose-6-phosphate + phosphate	gluconeogenesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.24	H2O + sucrose-6'-phosphate  =  sucrose + phosphate	sucrose biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.5.1.19	shikimate-3-phosphate + phosphoenolpyruvate  =  5-enolpyruvyl-shikimate-3-phosphate + phosphate	chorismate biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.2.3.5	5-enolpyruvyl-shikimate-3-phosphate  =  phosphate + chorismate	chorismate biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.4	H2O + L-phosphatidate  =  phosphate + 1,2-diacylglycerol	triacylglycerol biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.4	H2O + L-phosphatidate  =  phosphate + 1,2-diacylglycerol	phospholipid biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	gluconeogenesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	glyceraldehyde 3-phosphate degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.18	H2O + 2-phosphoglycolate  =  glycolate + phosphate	photorespiration
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis II (acetyl cycle)
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis III
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	citrulline degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	SAM cycle
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	ethylene biosynthesis from methionine
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	adenosylmethionine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine salvage pathway
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine degradation I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	glutamine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	ammonia assimilation cycle
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	nitrate assimilation pathway
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.3	3-phospho-serine + H2O  =  L-serine + phosphate	serine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.3	3-phospho-serine + H2O  =  L-serine + phosphate	glycine biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	glycine degradation
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	carbon monoxide dehydrogenase pathway
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.4.2	L-glutamine + H2O + UTP + ATP  =  CTP + phosphate + ADP + L-glutamate	de novo biosynthesis of pyrimidine ribonucleotides
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	4.2.3.1	O-phospho-L-homoserine + H2O  =  phosphate + L-threonine	threonine biosynthesis from homoserine
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	formylTHF biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis I
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis II
phosphate	inorganic phosphate*phosphate-inorganic*Pi*orthophosphate*PO<SUB>4</SUB><SUP>3-</SUP>*HPO<SUB>4</SUB><SUP>2-</SUP>*HPO<SUB>4</SUB><SUP>-2</SUP>	O4 P1 	P([O-1])([O-1])(=O)[O-1]	LIGAND-CPD:C00009*CAS:14265-44-2	3.1.3.12	trehalose 6-phosphate + H2O  =  trehalose + phosphate	trehalose biosynthesis
6-hydroxymethyl-dehydropterin	dihydropterin-CH2OH*2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine	C7 H9 N5 O2 	C2(C(CO)=Nc1(c(O)nc(N)nc1N2))		2.7.6.3	6-hydroxymethyl-dehydropterin + ATP  =  2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate + AMP	tetrahydrofolate biosynthesis I
6-hydroxymethyl-dehydropterin	dihydropterin-CH2OH*2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine	C7 H9 N5 O2 	C2(C(CO)=Nc1(c(O)nc(N)nc1N2))		2.7.6.3	6-hydroxymethyl-dehydropterin + ATP  =  2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate + AMP	tetrahydrofolate biosynthesis II
6-hydroxymethyl-dehydropterin	dihydropterin-CH2OH*2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine	C7 H9 N5 O2 	C2(C(CO)=Nc1(c(O)nc(N)nc1N2))		4.1.2.25	dihydro-neo-pterin  =  glycolaldehyde + 6-hydroxymethyl-dehydropterin	tetrahydrofolate biosynthesis I
6-hydroxymethyl-dehydropterin	dihydropterin-CH2OH*2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine	C7 H9 N5 O2 	C2(C(CO)=Nc1(c(O)nc(N)nc1N2))		4.1.2.25	dihydro-neo-pterin  =  glycolaldehyde + 6-hydroxymethyl-dehydropterin	tetrahydrofolate biosynthesis II
indole-3-carboxaldehyde		C9 H7 N1 O1 	c1(c([CH]=O)c2(c([nH]1)cccc2))		RXN1F-13	indole-3-carboxaldehyde + L-cysteine  =  indole-S-cysteine-adduct	camalexin biosynthesis
indole-3-carboxaldehyde		C9 H7 N1 O1 	c1(c([CH]=O)c2(c([nH]1)cccc2))		1.14.14.-	unknown  =  indole-3-carboxaldehyde	camalexin biosynthesis
phosphoribosyl-formamido-carboxamide	5'-p-Ribosyl-5-formamido-4-imidazolecarboxamide*5'-phosphoribosyl-5-formamido-4-imidazole carboxamide*5'-p-Ribosyl-5-formamido-4-imidazole carboxamide*5-Phosphoribosyl-5-formamido-4-imid-carboxamide*5-formamido-1-(5-phosphoribosyl)-imidazole-4-carboxamide*FAICAR	C10 H15 N4 O9 P1 	c1(n(cnc(C(N)=O)1)[CH]2(O[CH]([CH](O)[CH]2O)COP(=O)(O)O))(NC=O)		3.5.4.10	phosphoribosyl-formamido-carboxamide  =  IMP + H2O	de novo biosynthesis of purine nucleotides II
phosphoribosyl-formamido-carboxamide	5'-p-Ribosyl-5-formamido-4-imidazolecarboxamide*5'-phosphoribosyl-5-formamido-4-imidazole carboxamide*5'-p-Ribosyl-5-formamido-4-imidazole carboxamide*5-Phosphoribosyl-5-formamido-4-imid-carboxamide*5-formamido-1-(5-phosphoribosyl)-imidazole-4-carboxamide*FAICAR	C10 H15 N4 O9 P1 	c1(n(cnc(C(N)=O)1)[CH]2(O[CH]([CH](O)[CH]2O)COP(=O)(O)O))(NC=O)		3.5.4.10	phosphoribosyl-formamido-carboxamide  =  IMP + H2O	de novo biosynthesis of purine nucleotides I
phosphoribosyl-formamido-carboxamide	5'-p-Ribosyl-5-formamido-4-imidazolecarboxamide*5'-phosphoribosyl-5-formamido-4-imidazole carboxamide*5'-p-Ribosyl-5-formamido-4-imidazole carboxamide*5-Phosphoribosyl-5-formamido-4-imid-carboxamide*5-formamido-1-(5-phosphoribosyl)-imidazole-4-carboxamide*FAICAR	C10 H15 N4 O9 P1 	c1(n(cnc(C(N)=O)1)[CH]2(O[CH]([CH](O)[CH]2O)COP(=O)(O)O))(NC=O)		2.1.2.3	N10-formyl-THF + AICAR  =  tetrahydrofolate + phosphoribosyl-formamido-carboxamide	de novo biosynthesis of purine nucleotides II
phosphoribosyl-formamido-carboxamide	5'-p-Ribosyl-5-formamido-4-imidazolecarboxamide*5'-phosphoribosyl-5-formamido-4-imidazole carboxamide*5'-p-Ribosyl-5-formamido-4-imidazole carboxamide*5-Phosphoribosyl-5-formamido-4-imid-carboxamide*5-formamido-1-(5-phosphoribosyl)-imidazole-4-carboxamide*FAICAR	C10 H15 N4 O9 P1 	c1(n(cnc(C(N)=O)1)[CH]2(O[CH]([CH](O)[CH]2O)COP(=O)(O)O))(NC=O)		2.1.2.3	N10-formyl-THF + AICAR  =  tetrahydrofolate + phosphoribosyl-formamido-carboxamide	de novo biosynthesis of purine nucleotides I
(glucosyl)3-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol	(glucosyl)<sub>3</sub>-(mannosyl)<sub>9</sub>-(<i>N</i>-acetylglucosaminyl)<sub>2</sub>-PP-Dol*{&alpha;-D-glucosyl-(1->2)-&alpha;-D-glucosyl-(1->3)-&alpha;-D-glucosyl-(1->3)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1->3)-[&alpha;-D-mannosyl-(1->2)-&alpha;-D-mannosyl-(1,6)]-&alpha;-D-mannosyl-(1,6)]-&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C168 H280 N2 O77 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(C(O)C(C(O)C(O3)COC6(OC(COC4(C(C(O)C(O)C(O4)CO)OC5(OC(CO)C(O)C(O)C(O)5)))C(O)C(C(O)6)OC7(C(C(O)C(O)C(O7)CO)OC8(OC(CO)C(O)C(O)C(O)8))))OC9(C(C(O)C(O)C(O9)CO)OC10(C(C(O)C(O)C(O10)CO)OC11(C(O)C(C(O)C(O11)CO)OC12(C(O)C(C(O)C(O12)CO)OC13(C(C(O)C(O)C(O13)CO)OC14(OC(CO)C(O)C(O)C(O)14)))))))))	LIGAND-CPD:C04213	RXN-5472	(glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-glucosyl phosphate  =  (glucosyl)3-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
tRNAtrp	TRNA(TRP)				6.1.1.2	tRNAtrp + L-tryptophan + ATP  =  L-tryptophanyl-tRNAtrp + pyrophosphate + AMP	tRNA charging pathway
CDP-diacylglycerol	CDP-diglyceride*CDP-1,2-diglyceride*CDP-1,2-diacylglycerol	C14 H19 N3 O15 R11 R21 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OCC(OC([R1])=O)COC([R2])=O))		2.7.8.11	CDP-diacylglycerol + myo-inositol  =  L-1-phosphatidyl-inositol + CMP	phospholipid biosynthesis
CDP-diacylglycerol	CDP-diglyceride*CDP-1,2-diglyceride*CDP-1,2-diacylglycerol	C14 H19 N3 O15 R11 R21 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OCC(OC([R1])=O)COC([R2])=O))		2.7.8.5	CDP-diacylglycerol + glycerol-3-phosphate  =  L-1-phosphatidylglycerol-phosphate + CMP	phospholipid biosynthesis
CDP-diacylglycerol	CDP-diglyceride*CDP-1,2-diglyceride*CDP-1,2-diacylglycerol	C14 H19 N3 O15 R11 R21 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OCC(OC([R1])=O)COC([R2])=O))		2.7.7.41	CTP + L-phosphatidate  =  CDP-diacylglycerol + pyrophosphate	phospholipid biosynthesis
porphobilinogen		C10 H14 N2 O4 	c1(c(CCC(O)=O)c(CC(O)=O)c(n1)CN)	CAS:487-90-1	2.5.1.61	H2O + 4 porphobilinogen  =  4 NH3 + hydroxymethylbilane	chlorophyllide a biosynthesis
porphobilinogen		C10 H14 N2 O4 	c1(c(CCC(O)=O)c(CC(O)=O)c(n1)CN)	CAS:487-90-1	2.5.1.61	H2O + 4 porphobilinogen  =  4 NH3 + hydroxymethylbilane	biosynthesis of proto- and siroheme
porphobilinogen		C10 H14 N2 O4 	c1(c(CCC(O)=O)c(CC(O)=O)c(n1)CN)	CAS:487-90-1	4.2.1.24	2 5-amino-levulinate  =  2 H2O + porphobilinogen	chlorophyllide a biosynthesis
porphobilinogen		C10 H14 N2 O4 	c1(c(CCC(O)=O)c(CC(O)=O)c(n1)CN)	CAS:487-90-1	4.2.1.24	2 5-amino-levulinate  =  2 H2O + porphobilinogen	biosynthesis of proto- and siroheme
dUTP	deoxy-UTP*2'-deoxyuridine-5'-triphosphate*deoxyuridine-triphosphate	C9 H15 N2 O14 P3 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	CAS:1173-82-6	3.6.1.23	H2O + dUTP  =  pyrophosphate + dUMP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dUTP	deoxy-UTP*2'-deoxyuridine-5'-triphosphate*deoxyuridine-triphosphate	C9 H15 N2 O14 P3 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	CAS:1173-82-6	3.5.4.13	H2O + dCTP  =  NH3 + dUTP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dUTP	deoxy-UTP*2'-deoxyuridine-5'-triphosphate*deoxyuridine-triphosphate	C9 H15 N2 O14 P3 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	CAS:1173-82-6	2.7.4.6	dUDP + ATP  =  dUTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dUTP	deoxy-UTP*2'-deoxyuridine-5'-triphosphate*deoxyuridine-triphosphate	C9 H15 N2 O14 P3 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(C2)O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O))	CAS:1173-82-6	RXN0-724	UTP + reduced flavodoxin  =  dUTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
hypoxanthine		C5 H4 N4 O1 	c12(c(nc[nH]1)c(=O)[nH]cn2)	LIGAND-CPD:C00262*LIGAND:C00262*CAS:68-94-0	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	purine degradation
hypoxanthine		C5 H4 N4 O1 	c12(c(nc[nH]1)c(=O)[nH]cn2)	LIGAND-CPD:C00262*LIGAND:C00262*CAS:68-94-0	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	salvage pathways of purine nucleosides
hypoxanthine		C5 H4 N4 O1 	c12(c(nc[nH]1)c(=O)[nH]cn2)	LIGAND-CPD:C00262*LIGAND:C00262*CAS:68-94-0	3.2.2.2	inosine + H2O  =  hypoxanthine + D-ribose	purine degradation
hypoxanthine		C5 H4 N4 O1 	c12(c(nc[nH]1)c(=O)[nH]cn2)	LIGAND-CPD:C00262*LIGAND:C00262*CAS:68-94-0	3.2.2.2	inosine + H2O  =  hypoxanthine + D-ribose	salvage pathways of purine nucleosides
hypoxanthine		C5 H4 N4 O1 	c12(c(nc[nH]1)c(=O)[nH]cn2)	LIGAND-CPD:C00262*LIGAND:C00262*CAS:68-94-0	2.4.2.8	PRPP + hypoxanthine  =  pyrophosphate + IMP	salvage pathways of purine nucleosides
geranylgeranyl-PP	GGPP*all-trans-geranyl-geranyl-pp*geranylgeranyl-diphosphate	C20 H36 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(O)(O)=O		5.5.1.13	geranylgeranyl-PP  =  ent-copalyl diphosphate	ent-kaurene biosynthesis
geranylgeranyl-PP	GGPP*all-trans-geranyl-geranyl-pp*geranylgeranyl-diphosphate	C20 H36 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(O)(O)=O		2.5.1.32	2 geranylgeranyl-PP  =  phytoene + 2 pyrophosphate	carotenoid biosynthesis
geranylgeranyl-PP	GGPP*all-trans-geranyl-geranyl-pp*geranylgeranyl-diphosphate	C20 H36 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(O)(O)=O		2.5.1.-	chlorophyllide a + geranylgeranyl-PP  =  geranylgeranyl-chlorophyll a + pyrophosphate	chlorophyll a biosynthesis II
geranylgeranyl-PP	GGPP*all-trans-geranyl-geranyl-pp*geranylgeranyl-diphosphate	C20 H36 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(O)(O)=O		2.5.1.29	delta3-isopentenyl-PP + trans, trans-farnesyl diphosphate  =  geranylgeranyl-PP + pyrophosphate	ent-kaurene biosynthesis
UDP-2,3-bis(3-hydroxymyristoyl)glucosamine	UDP-2,3-bis(3-hydroxytetradecanoyl)glucosamine*UDP-2,3-diacyl-glucosamine	C43 H77 N3 O20 P2 	CCCCCCCCCCCC(O)CC(=O)NC3(C(OP(O)(=O)OP(O)(=O)OCC1(OC(C(O)C(O)1)n2(c(=O)[nH]c(=O)cc2)))OC(CO)C(O)C3OC(=O)CC(O)CCCCCCCCCCC)		LIPIDXSYNTHESIS-RXN	H2O + UDP-2,3-bis(3-hydroxymyristoyl)glucosamine  =  2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate + UMP	lipid-A-precursor biosynthesis
UDP-2,3-bis(3-hydroxymyristoyl)glucosamine	UDP-2,3-bis(3-hydroxytetradecanoyl)glucosamine*UDP-2,3-diacyl-glucosamine	C43 H77 N3 O20 P2 	CCCCCCCCCCCC(O)CC(=O)NC3(C(OP(O)(=O)OP(O)(=O)OCC1(OC(C(O)C(O)1)n2(c(=O)[nH]c(=O)cc2)))OC(CO)C(O)C3OC(=O)CC(O)CCCCCCCCCCC)		2.4.1.182	2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate + UDP-2,3-bis(3-hydroxymyristoyl)glucosamine  =  lipid A disaccharide + UDP	lipid-A-precursor biosynthesis
UDP-2,3-bis(3-hydroxymyristoyl)glucosamine	UDP-2,3-bis(3-hydroxytetradecanoyl)glucosamine*UDP-2,3-diacyl-glucosamine	C43 H77 N3 O20 P2 	CCCCCCCCCCCC(O)CC(=O)NC3(C(OP(O)(=O)OP(O)(=O)OCC1(OC(C(O)C(O)1)n2(c(=O)[nH]c(=O)cc2)))OC(CO)C(O)C3OC(=O)CC(O)CCCCCCCCCCC)		2.3.1.-	UDP-3-O-(3-hydroxymyristoyl)glucosamine + (R)-3-hydroxymyristoyl-ACP  =  UDP-2,3-bis(3-hydroxymyristoyl)glucosamine + acyl carrier protein	lipid-A-precursor biosynthesis
L-galactose		C6 H12 O6 	C1(C(O)C(O)C(O)C(O1)CO)(O)		1.1.1.-	L-galactose + NAD+  =  L-galactono-1,4-lactone + NADH	ascorbate biosynthesis
L-galactose		C6 H12 O6 	C1(C(O)C(O)C(O)C(O1)CO)(O)		RXN-1883	GDP-L-galactose + 2 H2O  =  L-galactose + GMP + phosphate	ascorbate biosynthesis
2-oxo-5-methylthiopentanoic-acid		C6 H10 O3 S1 	C(=O)(O)C(=O)CCCSC		2.6.1.-	2-oxo-5-methylthiopentanoic-acid + an amino acid  =  homomethionine + a 2-oxo acid	homomethionine biosynthesis
2-oxo-5-methylthiopentanoic-acid		C6 H10 O3 S1 	C(=O)(O)C(=O)CCCSC		1.1.1.-	3-(2'-methylthio)ethylmalic-acid  =  2-oxo-5-methylthiopentanoic-acid + CO2	homomethionine biosynthesis
a 2-oxo acid	2-oxo acid	C2 H1 O3 R1 			2.6.1.-	L-methionine + a 2-oxo acid  =  2-oxo-4-methylthiobutanoic acid + an amino acid	homomethionine biosynthesis
a 2-oxo acid	2-oxo acid	C2 H1 O3 R1 			2.6.1.-	2-oxo-5-methylthiopentanoic-acid + an amino acid  =  homomethionine + a 2-oxo acid	homomethionine biosynthesis
2,3-dihydroxy-3-methylvalerate	(R)-2,3-Dihydroxy-3-methylpentanoate*(R)-2,3-Dihydroxy-3-methylvalerate*2,3-dihydroxy-3-methylpentanoate	C6 H12 O4 	CC(CC)(O)C(O)C(=O)O		4.2.1.9	2,3-dihydroxy-3-methylvalerate  =  2-keto-3-methyl-valerate + H2O	isoleucine biosynthesis
2,3-dihydroxy-3-methylvalerate	(R)-2,3-Dihydroxy-3-methylpentanoate*(R)-2,3-Dihydroxy-3-methylvalerate*2,3-dihydroxy-3-methylpentanoate	C6 H12 O4 	CC(CC)(O)C(O)C(=O)O		1.1.1.86	2-aceto-2-hydroxy-butyrate + NADPH  =  2,3-dihydroxy-3-methylvalerate + NADP+	isoleucine biosynthesis
tRNAval	TRNA(VAL)				6.1.1.9	tRNAval + L-valine + ATP  =  L-valyl-tRNAval + pyrophosphate + AMP	tRNA charging pathway
trans-delta2-enoyl-CoA	trans-&Delta;<SUP>2</SUP>-enoyl-CoA*trans-2,3-didehydroacyl-CoA*trans-2,3-dehydroacyl-CoA	C24 H37 N7 O17 R1 P3 S1 			4.2.1.17	H2O + trans-delta2-enoyl-CoA  =  L-3-hydroxyacyl-CoA	fatty acid beta-oxidation
trans-delta2-enoyl-CoA	trans-&Delta;<SUP>2</SUP>-enoyl-CoA*trans-2,3-didehydroacyl-CoA*trans-2,3-dehydroacyl-CoA	C24 H37 N7 O17 R1 P3 S1 			1.3.1.38	trans-delta2-enoyl-CoA + NADPH  =  acyln+2-CoA + NADP+	very long chain fatty acid biosynthesis
trans-delta2-enoyl-CoA	trans-&Delta;<SUP>2</SUP>-enoyl-CoA*trans-2,3-didehydroacyl-CoA*trans-2,3-dehydroacyl-CoA	C24 H37 N7 O17 R1 P3 S1 			4.2.1.17	3-hydroxyacyl-CoA  =  trans-delta2-enoyl-CoA + H2O	very long chain fatty acid biosynthesis
trans-delta2-enoyl-CoA	trans-&Delta;<SUP>2</SUP>-enoyl-CoA*trans-2,3-didehydroacyl-CoA*trans-2,3-dehydroacyl-CoA	C24 H37 N7 O17 R1 P3 S1 			5.3.3.8	cis-delta3-enoyl-CoA  =  trans-delta2-enoyl-CoA	fatty acid beta-oxidation
L-lysyl-tRNAlys	L-LYSYL-TRNA(LYS)				6.1.1.6	tRNAlys + L-lysine + ATP  =  L-lysyl-tRNAlys + pyrophosphate + AMP	tRNA charging pathway
2-dehydro-3-deoxy-D-gluconate	2-keto-3-deoxy-D-gluconate*3-deoxy-2-oxo-D-gluconate*2-keto-3-deoxygluconate	C6 H10 O6 	C(=O)(O)C(=O)[CH2][CH](O)[CH](O)CO	CAS:17510-99-5	2.7.1.45	2-dehydro-3-deoxy-D-gluconate + ATP  =  2-keto-3-deoxy-6-phospho-gluconate + ADP	beta-D-glucuronide degradation
2-dehydro-3-deoxy-D-gluconate	2-keto-3-deoxy-D-gluconate*3-deoxy-2-oxo-D-gluconate*2-keto-3-deoxygluconate	C6 H10 O6 	C(=O)(O)C(=O)[CH2][CH](O)[CH](O)CO	CAS:17510-99-5	4.2.1.8	D-mannonate  =  H2O + 2-dehydro-3-deoxy-D-gluconate	beta-D-glucuronide degradation
UDP-D-xylose	udp-xylose*UDP-&alpha;-D-xylose	C14 H22 N2 O16 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)CO3)))	CAS:3616-06-6	4.1.1.35	UDP-D-glucuronate  =  UDP-D-xylose + CO2	UDP-D-xylose biosynthesis
UDP-D-xylose	udp-xylose*UDP-&alpha;-D-xylose	C14 H22 N2 O16 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)CO3)))	CAS:3616-06-6	5.1.3.5	UDP-D-xylose  =  UDP-L-arabinose	UDP-L-arabinose biosynthesis I (from UDP-xylose)
indole acetaldehyde	indole-3-acetaldehyde*2-(indol-3-yl)acetaldehyde	C10 H9 N1 O1 	c1(c(CC=O)c2(c([nH]1)cccc2))	CAS:2591-98-2	1.2.3.7	O2 + 2 indole acetaldehyde  =  2 indole-3-acetate	IAA biosynthesis I
indole acetaldehyde	indole-3-acetaldehyde*2-(indol-3-yl)acetaldehyde	C10 H9 N1 O1 	c1(c(CC=O)c2(c([nH]1)cccc2))	CAS:2591-98-2	4.1.1.74	indole-3-pyruvate  =  CO2 + indole acetaldehyde	IAA biosynthesis I
indole acetaldehyde	indole-3-acetaldehyde*2-(indol-3-yl)acetaldehyde	C10 H9 N1 O1 	c1(c(CC=O)c2(c([nH]1)cccc2))	CAS:2591-98-2	1.4.3.6	tryptamine + H2O + O2  =  NH3 + indole acetaldehyde + H2O2	IAA biosynthesis I
2-methylaceto-acetyl-CoA	2-methyl-3-acetoacetyl-CoA*2-methylacetoacetyl coenzyme A	C26 H42 N7 O18 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(C)=O)	CAS:6712-01-2	2.3.1.16	2-methylaceto-acetyl-CoA + coenzyme A  =  propionyl-CoA + acetyl-CoA	isoleucine degradation
2-methylaceto-acetyl-CoA	2-methyl-3-acetoacetyl-CoA*2-methylacetoacetyl coenzyme A	C26 H42 N7 O18 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(C)=O)	CAS:6712-01-2	1.1.1.178	NAD+ + 2-methyl-3-hydroxybutyryl-CoA  =  NADH + 2-methylaceto-acetyl-CoA	isoleucine degradation
L-aspartate-semialdehyde	L-aspartic 4-semialdehyde*L-aspartate-4-semialdehyde*L-aspartate &beta;-semialdehyde	C4 H7 N1 O3 	[CH](=O)CC(N)C(O)=O	CAS:15106-57-7	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	homoserine biosynthesis
L-aspartate-semialdehyde	L-aspartic 4-semialdehyde*L-aspartate-4-semialdehyde*L-aspartate &beta;-semialdehyde	C4 H7 N1 O3 	[CH](=O)CC(N)C(O)=O	CAS:15106-57-7	1.2.1.11	NADPH + L-aspartyl-4-phosphate  =  NADP+ + phosphate + L-aspartate-semialdehyde	lysine biosynthesis
L-aspartate-semialdehyde	L-aspartic 4-semialdehyde*L-aspartate-4-semialdehyde*L-aspartate &beta;-semialdehyde	C4 H7 N1 O3 	[CH](=O)CC(N)C(O)=O	CAS:15106-57-7	4.2.1.52	pyruvate + L-aspartate-semialdehyde  =  2 H2O + L-2,3-dihydrodipicolinate	lysine biosynthesis
L-aspartate-semialdehyde	L-aspartic 4-semialdehyde*L-aspartate-4-semialdehyde*L-aspartate &beta;-semialdehyde	C4 H7 N1 O3 	[CH](=O)CC(N)C(O)=O	CAS:15106-57-7	1.1.1.3	NADPH + L-aspartate-semialdehyde  =  NADP+ + homoserine	homoserine biosynthesis
L-carnitinyl-CoA	L-carnityl-CoA	C28 H50 N8 O18 P3 S1 	C([N+1](C)(C)C)C(O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(O)(=O)OCC1(OC(C(O)C1OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3)))		4.2.1.-	L-carnitinyl-CoA  =  H2O + crotonobetainyl-CoA	carnitine degradation
L-carnitinyl-CoA	L-carnityl-CoA	C28 H50 N8 O18 P3 S1 	C([N+1](C)(C)C)C(O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(O)(=O)OCC1(OC(C(O)C1OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3)))		6.2.1.-	coenzyme A + L-carnitine  =  L-carnitinyl-CoA + H2O	carnitine degradation
L-carnitinyl-CoA	L-carnityl-CoA	C28 H50 N8 O18 P3 S1 	C([N+1](C)(C)C)C(O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(O)(=O)OCC1(OC(C(O)C1OP(O)(=O)O)n2(c3(c(nc2)c(N)ncn3)))		5.-.-.-	D-carnitinyl-CoA  =  L-carnitinyl-CoA	carnitine degradation
4-hydroxy-3-indolylmethyl-glucosinolate	4-hydroxyindol-3-ylmethylglucosinolate*4-hydroxyglucobrassicin	C16 H20 N2 O10 S2 	c1(c(c2(c(O)cccc([nH]1)2))CC(=NOS(O)(=O)=O)SC3(C(CO)C(O)C(O)C(O3)O))		RXN-2163	4-hydroxy-3-indolylmethyl-glucosinolate  =  4-methoxy-3-indolylmethyl-glucosinolate	glucosinolate biosynthesis from tryptophan
4-hydroxy-3-indolylmethyl-glucosinolate	4-hydroxyindol-3-ylmethylglucosinolate*4-hydroxyglucobrassicin	C16 H20 N2 O10 S2 	c1(c(c2(c(O)cccc([nH]1)2))CC(=NOS(O)(=O)=O)SC3(C(CO)C(O)C(O)C(O3)O))		RXN-2162	indolylmethyl-glucosinolate  =  4-hydroxy-3-indolylmethyl-glucosinolate	glucosinolate biosynthesis from tryptophan
riboflavin	vitamin B<SUB>2</SUB>	C17 H20 N4 O6 	C(O)C(O)C(O)C(O)Cn2(c1(c(C(=O)NC(N=1)=O)=nc3(c2cc(C)c(C)c3)))	LIGAND:C00255*CAS:83-88-5	2.7.1.26	riboflavin + ATP  =  FMN + ADP	riboflavin and FMN and FAD biosynthesis
riboflavin	vitamin B<SUB>2</SUB>	C17 H20 N4 O6 	C(O)C(O)C(O)C(O)Cn2(c1(c(C(=O)NC(N=1)=O)=nc3(c2cc(C)c(C)c3)))	LIGAND:C00255*CAS:83-88-5	2.5.1.9	2 6,7-dimethyl-8-(1-D-ribityl)lumazine  =  5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + riboflavin	riboflavin and FMN and FAD biosynthesis
(E)-cinnamoyl-CoA		C30 H42 N7 O17 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccccc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		RXN-2002	(E)-cinnamoyl-CoA + H2O  =  hydroxycinnamoyl-CoA	salicylic acid biosynthesis
(E)-cinnamoyl-CoA		C30 H42 N7 O17 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccccc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		6.2.1.-	trans-cinnamate + coenzyme A  =  (E)-cinnamoyl-CoA + H2O	salicylic acid biosynthesis
dolichol		C80 H132 O1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCO		2.7.1.108	dolichol + CTP  =  dolichyl-phosphate + CDP	dolichyl-diphosphooligosaccharide biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	sucrose degradation to ethanol and lactate (anaerobic)
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis I
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis II
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.2.1.6	2 pyruvate  =  2-acetolactate + CO2	valine biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	gluconeogenesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	glyceraldehyde 3-phosphate degradation
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.2.1.52	pyruvate + L-aspartate-semialdehyde  =  2 H2O + L-2,3-dihydrodipicolinate	lysine biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.1.3.37	pyruvate + D-glyceraldehyde-3-phosphate  =  1-deoxy-D-xylulose 5-phosphate + CO2	thiamin biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.1.3.37	pyruvate + D-glyceraldehyde-3-phosphate  =  1-deoxy-D-xylulose 5-phosphate + CO2	isopentenyl diphosphate biosynthesis -- mevalonate-independent
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	TCA cycle variation I
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	superpathway of glycolysis, pyruvate dehydrogenase, TCA, and glyoxylate bypass
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.2.1.6	pyruvate + 2-oxobutanoate  =  2-aceto-2-hydroxy-butyrate + CO2	isoleucine biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.1.1.1	pyruvate  =  acetaldehyde + CO2	sucrose degradation to ethanol and lactate (anaerobic)
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.6.1.19	4-aminobutyrate + pyruvate  =  succinate semialdehyde + L-alanine	glutamate degradation II
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.6.1.18	malonate semialdehyde + L-alanine  =  beta-alanine + pyruvate	beta-alanine biosynthesis II
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	phylloquinone biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	menaquinone biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.6.1.2	alpha-ketoglutarate + L-alanine  =  L-glutamate + pyruvate	alanine degradation
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	2.6.1.2	alpha-ketoglutarate + L-alanine  =  L-glutamate + pyruvate	alanine biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.1.2.14	2-keto-3-deoxy-6-phospho-gluconate  =  D-glyceraldehyde-3-phosphate + pyruvate	beta-D-glucuronide degradation
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	TCA cycle variation I
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	gluconeogenesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	TCA cycle variation I
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	1.1.1.40	NADP+ + malate  =  NADPH + CO2 + pyruvate	gluconeogenesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	RXN-1981	isochorismate  =  salicylate + pyruvate	salicylic acid biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.1.3.38	4-amino-4-deoxychorismate  =  p-aminobenzoate + pyruvate	tetrahydrofolate biosynthesis I
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.1.3.38	4-amino-4-deoxychorismate  =  p-aminobenzoate + pyruvate	tetrahydrofolate biosynthesis II
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	1.1.1.27	NADH + pyruvate  =  NAD+ + lactate	sucrose degradation to ethanol and lactate (anaerobic)
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	homocysteine and cysteine interconversion
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	methionine biosynthesis
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	sulfate assimilation
pyruvate	&alpha;-ketopropionic acid*BTS*alpha-ketopropionic acid*acetylformic acid*Pyroracemic acid*2-Oxopropanoic acid*2-Oxopropanoate*Pyruvic acid*pyruvic acid*2-oxopropanoate*2-oxopropanoic acid*pyroracemic acid*2-oxo-propionic acid	C3 H4 O3 	C(=O)(O)C(=O)C	LIGAND-CPD:C00022*UM-BBD-CPD:c0159*LIGAND-CPD:c00022*CAS:127-17-3	4.1.3.27	chorismate + L-glutamine  =  anthranilate + pyruvate + L-glutamate	tryptophan biosynthesis
L-phenylalanyl-tRNAphe	L-PHENYLALANYL-TRNA(PHE)				6.1.1.20	tRNAphe + L-phenylalanine + ATP  =  L-phenylalanyl-tRNAphe + pyrophosphate + AMP	tRNA charging pathway
S-adenosyl-4-methylthio-2-oxobutanoate		C15 H20 N5 O6 S1 	C(CC(=O)C(=O)O)[S+1](C)CC1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C04425	2.6.1.62	S-adenosyl-L-methionine + 8-amino-7-oxononanoate  =  S-adenosyl-4-methylthio-2-oxobutanoate + 7,8-diaminononanoate	biotin biosynthesis II
glycerate	(R)-glycerate*D-glycerate	C3 H6 O4 	C(O)C(O)C(O)=O	CAS:6000-40-4	1.1.1.29	NADH + hydroxypyruvate  =  NAD+ + glycerate	photorespiration
glycerate	(R)-glycerate*D-glycerate	C3 H6 O4 	C(O)C(O)C(O)=O	CAS:6000-40-4	2.7.1.31	glycerate + ATP  =  3-phosphoglycerate + ADP	photorespiration
L-tyrosine	Y*tyr*tyrosine	C9 H11 N1 O3 	C(O)(=O)C(N)Cc1(ccc(O)cc1)	LIGAND-CPD:C00082*LIGAND:C00082*CAS:60-18-4	6.1.1.1	L-tyrosine + tRNAtyr + ATP  =  L-tyrosyl-tRNAtyr + pyrophosphate + AMP	tRNA charging pathway
L-tyrosine	Y*tyr*tyrosine	C9 H11 N1 O3 	C(O)(=O)C(N)Cc1(ccc(O)cc1)	LIGAND-CPD:C00082*LIGAND:C00082*CAS:60-18-4	2.6.1.5	L-tyrosine + alpha-ketoglutarate  =  L-glutamate + p-hydroxyphenylpyruvate	tyrosine degradation
L-tyrosine	Y*tyr*tyrosine	C9 H11 N1 O3 	C(O)(=O)C(N)Cc1(ccc(O)cc1)	LIGAND-CPD:C00082*LIGAND:C00082*CAS:60-18-4	2.6.1.5	L-tyrosine + alpha-ketoglutarate  =  L-glutamate + p-hydroxyphenylpyruvate	phenylalanine degradation
L-tyrosine	Y*tyr*tyrosine	C9 H11 N1 O3 	C(O)(=O)C(N)Cc1(ccc(O)cc1)	LIGAND-CPD:C00082*LIGAND:C00082*CAS:60-18-4	THIAZOLSYN2-RXN	L-tyrosine + 1-deoxy-D-xylulose 5-phosphate + ThiS-COSH  =  4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-hydroxybenzyl alcohol + C1 of tyrosine + ThiS protein	thiamin biosynthesis
L-tyrosine	Y*tyr*tyrosine	C9 H11 N1 O3 	C(O)(=O)C(N)Cc1(ccc(O)cc1)	LIGAND-CPD:C00082*LIGAND:C00082*CAS:60-18-4	1.14.16.1	O2 + tetrahydrobiopterin + L-phenylalanine  =  L-tyrosine + 4alpha-hydroxy-5,6,7,8-tetrahydrobiopterin	phenylalanine degradation
L-tyrosine	Y*tyr*tyrosine	C9 H11 N1 O3 	C(O)(=O)C(N)Cc1(ccc(O)cc1)	LIGAND-CPD:C00082*LIGAND:C00082*CAS:60-18-4	1.3.1.43	L-arogenate + NADP+  =  L-tyrosine + NADPH + CO2	tyrosine biosynthesis II
L-tyrosine	Y*tyr*tyrosine	C9 H11 N1 O3 	C(O)(=O)C(N)Cc1(ccc(O)cc1)	LIGAND-CPD:C00082*LIGAND:C00082*CAS:60-18-4	1.3.1.43	NAD+ + L-arogenate  =  L-tyrosine + CO2 + NADH	tyrosine biosynthesis II
L-tyrosine	Y*tyr*tyrosine	C9 H11 N1 O3 	C(O)(=O)C(N)Cc1(ccc(O)cc1)	LIGAND-CPD:C00082*LIGAND:C00082*CAS:60-18-4	2.6.1.57	p-hydroxyphenylpyruvate + L-glutamate  =  L-tyrosine + alpha-ketoglutarate	tyrosine biosynthesis I
pelargonidin-3-glucoside	C21H21CLO5*callistephin*3-(beta-D-glucopyranosyloxy)-55,7-dihydroxy-2-(4-hydroxyphenyl)-1-benzopyrylium chloride	C21 H21 O10 	C1(OC(CO)C(O)C(O)C(O)1)OC3(C(c2(ccc(O)cc2))=Oc4(c(C=3)c(O)cc(c4)O))		2.4.1.-	pelargonidin + UDP-D-glucose  =  pelargonidin-3-glucoside + UDP	anthocyanin biosynthesis
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	2.1.2.2	N10-formyl-THF + 5-phospho-ribosyl-glycineamide  =  tetrahydrofolate + 5'-phosphoribosyl-N-formylglycineamide	de novo biosynthesis of purine nucleotides II
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	2.1.2.2	N10-formyl-THF + 5-phospho-ribosyl-glycineamide  =  tetrahydrofolate + 5'-phosphoribosyl-N-formylglycineamide	de novo biosynthesis of purine nucleotides I
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	3.5.1.10	H2O + N10-formyl-THF  =  tetrahydrofolate + formate	formylTHF biosynthesis
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	2.1.2.3	N10-formyl-THF + AICAR  =  tetrahydrofolate + phosphoribosyl-formamido-carboxamide	de novo biosynthesis of purine nucleotides II
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	2.1.2.3	N10-formyl-THF + AICAR  =  tetrahydrofolate + phosphoribosyl-formamido-carboxamide	de novo biosynthesis of purine nucleotides I
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	formylTHF biosynthesis
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	glycine degradation
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	formylTHF biosynthesis I
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	3.5.4.9	H2O + 5,10-methenyl-THF  =  N10-formyl-THF	carbon monoxide dehydrogenase pathway
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	glycine degradation
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis I
N10-formyl-THF	10-formyl-tetrahydrofolate*n<sup>10</sup>-formyltetrahydrofolate*N<sup>10</sup>-formyl-H<sub>4</sub>F*10-formyl-THF*10-formyl-H<sub>4</sub>PteGlu<sub>1</sub>	C20 H23 N7 O7 	C2(C(Nc1(c(=O)[nH]c(N)nc1N2))CN(C=O)c3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O))	CAS:2800-34-2	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	carbon monoxide dehydrogenase pathway
isochorismate	Isochorismic acid	C10 H10 O6 	C(O)(=O)C1(C(O)C(C=CC=1)OC(=C)C(=O)O)	LIGAND-CPD:C00885*CAS:22642-82-6	RXN-1981	isochorismate  =  salicylate + pyruvate	salicylic acid biosynthesis
isochorismate	Isochorismic acid	C10 H10 O6 	C(O)(=O)C1(C(O)C(C=CC=1)OC(=C)C(=O)O)	LIGAND-CPD:C00885*CAS:22642-82-6	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	phylloquinone biosynthesis
isochorismate	Isochorismic acid	C10 H10 O6 	C(O)(=O)C1(C(O)C(C=CC=1)OC(=C)C(=O)O)	LIGAND-CPD:C00885*CAS:22642-82-6	SHCHCSYNTH-RXN	succinate-semialdehyde-thiamine PPi + isochorismate  =  2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate + thiamin diphosphate + pyruvate	menaquinone biosynthesis
isochorismate	Isochorismic acid	C10 H10 O6 	C(O)(=O)C1(C(O)C(C=CC=1)OC(=C)C(=O)O)	LIGAND-CPD:C00885*CAS:22642-82-6	5.4.4.2	chorismate  =  isochorismate	phylloquinone biosynthesis
isochorismate	Isochorismic acid	C10 H10 O6 	C(O)(=O)C1(C(O)C(C=CC=1)OC(=C)C(=O)O)	LIGAND-CPD:C00885*CAS:22642-82-6	5.4.4.2	chorismate  =  isochorismate	salicylic acid biosynthesis
isochorismate	Isochorismic acid	C10 H10 O6 	C(O)(=O)C1(C(O)C(C=CC=1)OC(=C)C(=O)O)	LIGAND-CPD:C00885*CAS:22642-82-6	5.4.4.2	chorismate  =  isochorismate	menaquinone biosynthesis
pelargonidin	3,5,7-Trihydroxy-2-(4-hydroxyphenil)-1-benzopyrylium chloride*3,4',5,7-tetrahydroxyflavylium chloride*3,5,7-trihydroxy-2-(4-hydroxyphenyl)benzopyrylium chloride*1-Benzopyrylium, 3,5,7-trihydroxy-2-(4-hydroxyphenyl)-, chloride*Flavylium, 3,4',5,7-tetrahydroxy-, chloride*Pelargonidin chloride*Pelargonidol chloride	C15 H11 O5 	c12(c(cc(O)cc(O)1)O=C(C(O)=C2)c3(ccc(O)cc3))	CAS:134-04-3	2.4.1.-	pelargonidin + UDP-D-glucose  =  pelargonidin-3-glucoside + UDP	anthocyanin biosynthesis
pelargonidin	3,5,7-Trihydroxy-2-(4-hydroxyphenil)-1-benzopyrylium chloride*3,4',5,7-tetrahydroxyflavylium chloride*3,5,7-trihydroxy-2-(4-hydroxyphenyl)benzopyrylium chloride*1-Benzopyrylium, 3,5,7-trihydroxy-2-(4-hydroxyphenyl)-, chloride*Flavylium, 3,4',5,7-tetrahydroxy-, chloride*Pelargonidin chloride*Pelargonidol chloride	C15 H11 O5 	c12(c(cc(O)cc(O)1)O=C(C(O)=C2)c3(ccc(O)cc3))	CAS:134-04-3	1.14.11.19	leucopelargonidin + alpha-ketoglutarate + O2  =  pelargonidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
dATP	2'-deoxyadenosine triphosphate*deoxy-ATP*deoxyadenosine-triphosphate*2'-deoxyadenosine-5'-triphosphate	C10 H16 N5 O12 P3 	C(OP(O)(=O)OP(O)(=O)OP(O)(O)=O)C1(OC(CC(O)1)n2(c3(c(nc2)c(N)ncn3)))	CAS:1927-31-7	RXN0-745	ATP + reduced flavodoxin  =  dATP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
dATP	2'-deoxyadenosine triphosphate*deoxy-ATP*deoxyadenosine-triphosphate*2'-deoxyadenosine-5'-triphosphate	C10 H16 N5 O12 P3 	C(OP(O)(=O)OP(O)(=O)OP(O)(O)=O)C1(OC(CC(O)1)n2(c3(c(nc2)c(N)ncn3)))	CAS:1927-31-7	2.7.4.6	dADP + ATP  =  dATP + ADP	de novo biosynthesis of purine nucleotides I
aminoacetone		C3 H7 N1 O1 	C(N)C(C)=O	CAS:298-08-8	AMACETOXID-RXN	aminoacetone + H2O + O2  =  NH3 + methylglyoxal + H2O2	threonine degradation
aminoacetone		C3 H7 N1 O1 	C(N)C(C)=O	CAS:298-08-8	THREOSPON-RXN	2-amino-3-oxobutanoate  =  aminoacetone + CO2	threonine degradation
acetoacetyl-ACP	B1094*AcpP*acetoacetyl-S-ACP	C4 H5 O2 ACP1 S1 		SWISSPROT:P02901	3-OXOACYL-ACP-COA-SYNTHIII-RXN	acetyl-CoA + malonyl-ACP  =  acetoacetyl-ACP + coenzyme A + CO2	fatty acid biosynthesis - initial steps
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		2.5.1.10	geranyl-PP + delta3-isopentenyl-PP  =  pyrophosphate + trans, trans-farnesyl diphosphate	polyisoprenoid biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		2.5.1.10	geranyl-PP + delta3-isopentenyl-PP  =  pyrophosphate + trans, trans-farnesyl diphosphate	mevalonate pathway
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		RXN-5123	geranyl-PP  =  (Z)-beta-ocimene + pyrophosphate	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		RXN-5101	geranyl-PP + H2O  =  (-)-(4S)-alpha-terpineol + pyrophosphate	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		RXN-5103	geranyl-PP  =  (-)-(1S)-sabinene + pyrophosphate	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		4.2.3.14	geranyl-PP  =  (-)-(1S,5S)-beta-pinene + pyrophosphate	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		RXN-5108	geranyl-PP  =  terpinolene + pyrophosphate	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		4.2.3.16	geranyl-PP  =  limonene + pyrophosphate	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		RXN-5109	geranyl-PP  =  (E)-beta-ocimene + pyrophosphate	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		4.2.3.15	geranyl-PP  =  myrcene + pyrophosphate + myrcene	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		4.2.3.14	geranyl-PP  =  (-)-(1S,5S)-alpha-pinene + pyrophosphate	monoterpene biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		2.5.1.1	dimethylallyl-pyrophosphate + delta3-isopentenyl-PP  =  pyrophosphate + geranyl-PP	polyisoprenoid biosynthesis
geranyl-PP	GPP*geranyl-diphosphate*geranyl-pyrophosphate	C10 H20 O7 P2 	C(OP(O)(=O)OP(O)(O)=O)C=C(C)CCC=C(C)C		2.5.1.1	dimethylallyl-pyrophosphate + delta3-isopentenyl-PP  =  pyrophosphate + geranyl-PP	mevalonate pathway
1-acyl-sn-glycero-3-phosphocholine	1-Acyl-sn-glycerol-3-phosphocholine*1-Acylglycero-3-phosphocholine	C9 H20 N1 O7 R1 P1 			RXN-1641	a phosphatidylcholine + 1,2-diacylglycerol  =  triacylglycerol + 1-acyl-sn-glycero-3-phosphocholine	triacylglycerol biosynthesis
CO	carbon monoxide*carbon monooxide	C1 O1 	[C-1]#[O+1]	CAS:630-08-0	ACETYLSYNCLTH-RXN	CO + [Co-E-CH3] + coenzyme A  =  acetyl-CoA + [Co-E]	carbon monoxide dehydrogenase pathway
CO	carbon monoxide*carbon monooxide	C1 O1 	[C-1]#[O+1]	CAS:630-08-0	1.2.99.2	reduced acceptor + CO2  =  acceptor + H2O + CO	carbon monoxide dehydrogenase pathway
CO	carbon monoxide*carbon monooxide	C1 O1 	[C-1]#[O+1]	CAS:630-08-0	4.1.99.5	a fatty aldehyde  =  an alkane + CO	epicuticular wax biosynthesis
cis,trans-polyisoprenyln-PP					UPPSYN-RXN	cis,trans-polyisoprenyln-PP + delta3-isopentenyl-PP  =  pyrophosphate + cis,trans-polyisoprenyln+1-PP	polyisoprenoid biosynthesis
dolichyl beta-D-glucosyl phosphate		C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)OC1(OC(CO)C(O)C(O)C(O)1)		RXN-5471	glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-glucosyl phosphate  =  (glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl beta-D-glucosyl phosphate		C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)OC1(OC(CO)C(O)C(O)C(O)1)		RXN-5470	(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol   + dolichyl beta-D-glucosyl phosphate  =  glucosyl-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl beta-D-glucosyl phosphate		C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)OC1(OC(CO)C(O)C(O)C(O)1)		RXN-5472	(glucosyl)2(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-glucosyl phosphate  =  (glucosyl)3-(mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl beta-D-glucosyl phosphate		C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(O)(=O)OC1(OC(CO)C(O)C(O)C(O)1)		2.4.1.117	dolichyl-phosphate + UDP-D-glucose  =  dolichyl beta-D-glucosyl phosphate + UDP	dolichyl-diphosphooligosaccharide biosynthesis
coumaroyl-CoA	p-coumaryl-CoA*4-coumaroyl-CoA	C30 H42 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccc(O)cc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		2.3.1.133	shikimate + coumaroyl-CoA  =  4-coumaroylshikimate + coenzyme A	lignin biosynthesis
coumaroyl-CoA	p-coumaryl-CoA*4-coumaroyl-CoA	C30 H42 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccc(O)cc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		2.3.1.133	quinate + coumaroyl-CoA  =  4-coumaroylquinate + coenzyme A	lignin biosynthesis
coumaroyl-CoA	p-coumaryl-CoA*4-coumaroyl-CoA	C30 H42 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccc(O)cc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		1.2.1.44	coumaroyl-CoA + NADPH  =  coumaraldehyde + NADP+ + coenzyme A	lignin biosynthesis
coumaroyl-CoA	p-coumaryl-CoA*4-coumaroyl-CoA	C30 H42 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccc(O)cc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		2.3.1.74	coumaroyl-CoA + 3 malonyl-CoA  =  naringenin chalcone + 3 CO2 + 4 coenzyme A	flavonoid biosynthesis
coumaroyl-CoA	p-coumaryl-CoA*4-coumaroyl-CoA	C30 H42 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccc(O)cc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		2.3.1.170	coumaroyl-CoA + 3 malonyl-CoA + NADPH  =  isoliquiritigenin + 4 coenzyme A + 3 CO2 + NADP+ + H2O	flavonoid biosynthesis
coumaroyl-CoA	p-coumaryl-CoA*4-coumaroyl-CoA	C30 H42 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccc(O)cc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	flavonoid biosynthesis
coumaroyl-CoA	p-coumaryl-CoA*4-coumaroyl-CoA	C30 H42 N7 O18 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc1(ccc(O)cc1))COP(=O)(O)OP(=O)(O)OC[CH]2(O[CH]([CH](O)[CH]2OP(O)(O)=O)n3(c4(c(nc3)c(N)ncn4)))		6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	lignin biosynthesis
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	2.5.1.19	shikimate-3-phosphate + phosphoenolpyruvate  =  5-enolpyruvyl-shikimate-3-phosphate + phosphate	chorismate biosynthesis
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.1.1.32	oxaloacetate + GTP  =  CO2 + phosphoenolpyruvate + GDP	phenylalanine degradation
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.1.2.15	phosphoenolpyruvate + D-erythrose-4-phosphate + H2O  =  3-deoxy-D-arabino-heptulosonate-7-phosphate + phosphate	chorismate biosynthesis
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.1.1.31	phosphate + oxaloacetate  =  phosphoenolpyruvate + H2O + CO2	gluconeogenesis
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	superpathway of glyoxylate cycle
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	gluconeogenesis
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	gluconeogenesis
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	glyceraldehyde 3-phosphate degradation
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	sucrose degradation to ethanol and lactate (anaerobic)
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glycolysis I
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glycolysis II
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	gluconeogenesis
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glyceraldehyde 3-phosphate degradation
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	sucrose degradation to ethanol and lactate (anaerobic)
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis I
phosphoenolpyruvate	P-enol-pyruvate*P-enol-pyr*PEP	C3 H5 O6 P1 	C=C(C(=O)O)OP(O)(=O)O	LIGAND-CPD:c00074*CAS:73-89-2	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis II
tyramine	tyrosamine*4-(2-Aminoethyl)phenol*p-Hydroxyphenethylamine*2-(p-Hydroxyphenyl)ethylamine	C8 H11 N1 O1 	C(N)Cc1(ccc(O)cc1)		2.3.1.110	feruloyl-CoA + tyramine  =  N-feruloyltyramine + coenzyme A	suberin biosynthesis
phosphoribosylformiminoAICAR-phosphate	phosphoribosyl-formimino-aicar-P*phosphoribosylformiminoAICAR-P*5-(5-phospho-D-ribosyl-aminoformimino)-1-(5-phosphoribosyl)-imidazole4-carboxamide*5-(5'-phospho-D-ribosyl-aminoformimino)-1-(5-phosphoribosyl)-imidazole-4-carboxamide*N-5-phosphoribosyl-formimino-5-amino-imidazole-4-carboxamide ribonucleotide*N-(5'-phospho-D-ribosylformimino)-5-amino-1-(5''-phosphoribosyl)-4-imidazolecarboxamide	C15 H25 N5 O15 P2 	C(OP(=O)(O)O)[CH]1(O[CH]([CH](O)[CH]1O)NC=Nc2(n(cnc2C(=O)N)[CH]3(O[CH]([CH](O)[CH](O)3)COP(=O)(O)O)))		5.3.1.16	phosphoribosylformiminoAICAR-phosphate  =  phosphoribulosylformimino-AICAR-P	histidine biosynthesis
phosphoribosylformiminoAICAR-phosphate	phosphoribosyl-formimino-aicar-P*phosphoribosylformiminoAICAR-P*5-(5-phospho-D-ribosyl-aminoformimino)-1-(5-phosphoribosyl)-imidazole4-carboxamide*5-(5'-phospho-D-ribosyl-aminoformimino)-1-(5-phosphoribosyl)-imidazole-4-carboxamide*N-5-phosphoribosyl-formimino-5-amino-imidazole-4-carboxamide ribonucleotide*N-(5'-phospho-D-ribosylformimino)-5-amino-1-(5''-phosphoribosyl)-4-imidazolecarboxamide	C15 H25 N5 O15 P2 	C(OP(=O)(O)O)[CH]1(O[CH]([CH](O)[CH]1O)NC=Nc2(n(cnc2C(=O)N)[CH]3(O[CH]([CH](O)[CH](O)3)COP(=O)(O)O)))		3.5.4.19	phosphoribosyl-AMP + H2O  =  phosphoribosylformiminoAICAR-phosphate	histidine biosynthesis
D-myo-inositol (1,2,3,5,6) pentakisphosphate	1D-<i>myo</i>-inositol (1,2,3,5,6) penta<i>kis</i>phosphate*Ins(1,2,3,5,6)P<sub>5</sub>*I(1,2,3,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		RXN-7242	D-myo-inositol (1,2,3,5,6) pentakisphosphate + H2O  =  D-myo-inositol (1,2,5,6) tetrakisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,3,5,6) pentakisphosphate	1D-<i>myo</i>-inositol (1,2,3,5,6) penta<i>kis</i>phosphate*Ins(1,2,3,5,6)P<sub>5</sub>*I(1,2,3,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		RXN-7247	D-myo-inositol (1,2,3,5,6) pentakisphosphate + H2O  =  D-myo-inositol (1,2,3,6) tetrakisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,3,5,6) pentakisphosphate	1D-<i>myo</i>-inositol (1,2,3,5,6) penta<i>kis</i>phosphate*Ins(1,2,3,5,6)P<sub>5</sub>*I(1,2,3,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		3.1.3.26	phytate + H2O  =  D-myo-inositol (1,2,3,5,6) pentakisphosphate + phosphate	phytate degradation I
isopentenyladenosine-5'-triphosphate	iPTP*isopentenyladenosine riboside-5'-triphosphate*iPRTP	C15 H24 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(ncn3)NCC=C(C)C)))		RXN-4309	isopentenyladenosine-5'-triphosphate + H2O  =  isopentenyladenosine-5'-diphosphate + phosphate	trans-zeatin biosynthesis
isopentenyladenosine-5'-triphosphate	iPTP*isopentenyladenosine riboside-5'-triphosphate*iPRTP	C15 H24 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(ncn3)NCC=C(C)C)))		RXN-4304	isopentenyladenosine-5'-triphosphate + NADPH + H2O  =  trans-zeatin riboside triphosphate + NADP+	trans-zeatin biosynthesis
isopentenyladenosine-5'-triphosphate	iPTP*isopentenyladenosine riboside-5'-triphosphate*iPRTP	C15 H24 N5 O13 P3 	C(OP(O)(=O)OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(ncn3)NCC=C(C)C)))		2.5.1.-	dimethylallyl-pyrophosphate + ATP  =  isopentenyladenosine-5'-triphosphate + pyrophosphate	trans-zeatin biosynthesis
tetrahydrobiopterin	phenylalanine hydroxylase cofactor*5,6,7,8-erythro-tetrahydrobiopterin*5,6,7,8-tetrahydrobiopterin*5,6,7,8-tetra-H-biopterin*tetra-H-biopterin*tetra-hydro-biopterin	C9 H15 N5 O3 	C1(C(C(O)C(C)O)Nc2(c(N1)nc(N)[nH]c(=O)2))	CAS:17528-72-2	1.14.16.1	O2 + tetrahydrobiopterin + L-phenylalanine  =  L-tyrosine + 4alpha-hydroxy-5,6,7,8-tetrahydrobiopterin	phenylalanine degradation
D-myo-inositol (1,2,5,6) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,5,6) tetra<i>kis</i>phosphate*Ins(1,2,5,6)P<sub>4</sub>*I(1,2,5,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(O)		RXN-7244	D-myo-inositol (1,2,5,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,6) trisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,5,6) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,5,6) tetra<i>kis</i>phosphate*Ins(1,2,5,6)P<sub>4</sub>*I(1,2,5,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(O)		RXN-7243	D-myo-inositol (1,2,4,5,6)-pentakisphosphate + H2O  =  D-myo-inositol (1,2,5,6) tetrakisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,5,6) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,5,6) tetra<i>kis</i>phosphate*Ins(1,2,5,6)P<sub>4</sub>*I(1,2,5,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(O)		RXN-7242	D-myo-inositol (1,2,3,5,6) pentakisphosphate + H2O  =  D-myo-inositol (1,2,5,6) tetrakisphosphate + phosphate	phytate degradation I
adenosine	adenine-D-ribose	C10 H13 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(N)ncn3))	LIGAND-CPD:C00212*LIGAND:C00212*CAS:58-61-7	2.7.1.20	adenosine + ATP  =  AMP + ADP	salvage pathways of purine nucleosides
adenosine	adenine-D-ribose	C10 H13 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(N)ncn3))	LIGAND-CPD:C00212*LIGAND:C00212*CAS:58-61-7	3.2.2.7	H2O + adenosine  =  D-ribose + adenine	salvage pathways of purine nucleosides
adenosine	adenine-D-ribose	C10 H13 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(N)ncn3))	LIGAND-CPD:C00212*LIGAND:C00212*CAS:58-61-7	3.1.3.5	AMP + H2O  =  adenosine + phosphate	salvage pathways of purine nucleosides
adenosine	adenine-D-ribose	C10 H13 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(N)ncn3))	LIGAND-CPD:C00212*LIGAND:C00212*CAS:58-61-7	1.5.99.12	isopentenyl adenosine + H2O + FAD  =  adenosine + 3-methyl-2-butenal + FADH2	cytokinins degradation
adenosine	adenine-D-ribose	C10 H13 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(N)ncn3))	LIGAND-CPD:C00212*LIGAND:C00212*CAS:58-61-7	1.5.99.12	trans-zeatin riboside + H2O + FAD  =  adenosine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
adenosine	adenine-D-ribose	C10 H13 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(N)ncn3))	LIGAND-CPD:C00212*LIGAND:C00212*CAS:58-61-7	3.3.1.1	S-adenosyl-homocysteine + H2O  =  homocysteine + adenosine	SAM cycle
adenosine	adenine-D-ribose	C10 H13 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(N)ncn3))	LIGAND-CPD:C00212*LIGAND:C00212*CAS:58-61-7	3.3.1.1	S-adenosyl-homocysteine + H2O  =  homocysteine + adenosine	methionine degradation I
trans-zeatin riboside triphosphate	ZTP*zeatin triphosphate*tZRTP	C15 H24 N5 O14 P3 	C1(C(O)C(O)C(O1)COP(=O)(O)OP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4310	trans-zeatin riboside triphosphate + H2O  =  trans-zeatin riboside diphosphate + phosphate	trans-zeatin biosynthesis
trans-zeatin riboside triphosphate	ZTP*zeatin triphosphate*tZRTP	C15 H24 N5 O14 P3 	C1(C(O)C(O)C(O1)COP(=O)(O)OP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4304	isopentenyladenosine-5'-triphosphate + NADPH + H2O  =  trans-zeatin riboside triphosphate + NADP+	trans-zeatin biosynthesis
D-myo-inositol (1,2,3,6) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,3,6) tetra<i>kis</i>phosphate*Ins(1,2,3,6)P<sub>4</sub>*I(1,2,3,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7248	D-myo-inositol (1,2,3,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,3) trisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,3,6) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,3,6) tetra<i>kis</i>phosphate*Ins(1,2,3,6)P<sub>4</sub>*I(1,2,3,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7249	D-myo-inositol (1,2,3,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,6) trisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,3,6) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,3,6) tetra<i>kis</i>phosphate*Ins(1,2,3,6)P<sub>4</sub>*I(1,2,3,6)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7247	D-myo-inositol (1,2,3,5,6) pentakisphosphate + H2O  =  D-myo-inositol (1,2,3,6) tetrakisphosphate + phosphate	phytate degradation I
isopentenyladenosine-5'-diphosphate	iPDP*isopentenyladenosine riboside-5'-diphosphate*iPRDP	C15 H23 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(ncn3)NCC=C(C)C)))		RXN-4311	isopentenyladenosine-5'-diphosphate + H2O  =  isopentenyladenosine-5'-monophosphate + phosphate	trans-zeatin biosynthesis
isopentenyladenosine-5'-diphosphate	iPDP*isopentenyladenosine riboside-5'-diphosphate*iPRDP	C15 H23 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(ncn3)NCC=C(C)C)))		RXN-4306	isopentenyladenosine-5'-diphosphate + NADPH + H2O  =  trans-zeatin riboside diphosphate + NADP+	trans-zeatin biosynthesis
isopentenyladenosine-5'-diphosphate	iPDP*isopentenyladenosine riboside-5'-diphosphate*iPRDP	C15 H23 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(ncn3)NCC=C(C)C)))		2.5.1.-	dimethylallyl-pyrophosphate + ADP  =  isopentenyladenosine-5'-diphosphate + pyrophosphate	trans-zeatin biosynthesis
isopentenyladenosine-5'-diphosphate	iPDP*isopentenyladenosine riboside-5'-diphosphate*iPRDP	C15 H23 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(ncn3)NCC=C(C)C)))		RXN-4309	isopentenyladenosine-5'-triphosphate + H2O  =  isopentenyladenosine-5'-diphosphate + phosphate	trans-zeatin biosynthesis
lycopene		C40 H56 	CC(C)=CCCC(C)=CC=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC=C(C)CCC=C(C)C		RXN1F-150	lycopene  =  gamma-carotene	carotenoid biosynthesis
lycopene		C40 H56 	CC(C)=CCCC(C)=CC=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC=C(C)CCC=C(C)C		RXN1F-147	lycopene  =  delta-carotene	carotenoid biosynthesis
lycopene		C40 H56 	CC(C)=CCCC(C)=CC=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC=C(C)CCC=C(C)C		1.14.99.30	zeta-carotene  =  lycopene	carotenoid biosynthesis
uridine		C9 H12 N2 O6 	c1(n(c(=O)[nH]c(c1)=O)C2(C(O)C(O)C(O2)CO))	LIGAND:C00299*CAS:58-96-8	2.4.2.3	phosphate + uridine  =  ribose-1-phosphate + uracil	(deoxy)ribose phosphate degradation
uridine		C9 H12 N2 O6 	c1(n(c(=O)[nH]c(c1)=O)C2(C(O)C(O)C(O2)CO))	LIGAND:C00299*CAS:58-96-8	3.5.4.5	H2O + cytidine  =  NH3 + uridine	(deoxy)ribose phosphate degradation
D-myo-inositol (1,2,6) trisphosphate	1D-<i>myo</i>-inositol (1,2,6) trisphosphate*Ins(1,2,6)P<sub>3</sub>*I(1,2,6)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)1)(O)		RXN-7245	D-myo-inositol (1,2,6) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,6) trisphosphate	1D-<i>myo</i>-inositol (1,2,6) trisphosphate*Ins(1,2,6)P<sub>3</sub>*I(1,2,6)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)1)(O)		RXN-7249	D-myo-inositol (1,2,3,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,6) trisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,6) trisphosphate	1D-<i>myo</i>-inositol (1,2,6) trisphosphate*Ins(1,2,6)P<sub>3</sub>*I(1,2,6)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)1)(O)		RXN-7244	D-myo-inositol (1,2,5,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,6) trisphosphate + phosphate	phytate degradation I
trans-zeatin riboside diphosphate	ZDP*zeatin diphosphate*tZRDP	C15 H23 N5 O11 P2 	C1(C(O)C(O)C(O1)COP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4312	trans-zeatin riboside diphosphate + H2O  =  trans-zeatin riboside monophosphate + phosphate	trans-zeatin biosynthesis
trans-zeatin riboside diphosphate	ZDP*zeatin diphosphate*tZRDP	C15 H23 N5 O11 P2 	C1(C(O)C(O)C(O1)COP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4306	isopentenyladenosine-5'-diphosphate + NADPH + H2O  =  trans-zeatin riboside diphosphate + NADP+	trans-zeatin biosynthesis
trans-zeatin riboside diphosphate	ZDP*zeatin diphosphate*tZRDP	C15 H23 N5 O11 P2 	C1(C(O)C(O)C(O1)COP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4310	trans-zeatin riboside triphosphate + H2O  =  trans-zeatin riboside diphosphate + phosphate	trans-zeatin biosynthesis
delta-carotene		C40 H56 	CC(C)=CCCC(C)=CC=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC1(C(C)(C)CCC=C(C)1)		RXN1F-148	delta-carotene  =  alpha-carotene	carotenoid biosynthesis
delta-carotene		C40 H56 	CC(C)=CCCC(C)=CC=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC1(C(C)(C)CCC=C(C)1)		RXN1F-147	lycopene  =  delta-carotene	carotenoid biosynthesis
D-myo-inositol (1,2,3) trisphosphate	1D-<i>myo</i>-inositol (1,2,3) trisphosphate*Ins(1,2,3)P<sub>3</sub>*I(1,2,3)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7250	D-myo-inositol (1,2,3) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation II
D-myo-inositol (1,2,3) trisphosphate	1D-<i>myo</i>-inositol (1,2,3) trisphosphate*Ins(1,2,3)P<sub>3</sub>*I(1,2,3)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7250	D-myo-inositol (1,2,3) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,3) trisphosphate	1D-<i>myo</i>-inositol (1,2,3) trisphosphate*Ins(1,2,3)P<sub>3</sub>*I(1,2,3)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7302	D-myo-inositol (1,2,3,4) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,3) trisphosphate + phosphate	phytate degradation II
D-myo-inositol (1,2,3) trisphosphate	1D-<i>myo</i>-inositol (1,2,3) trisphosphate*Ins(1,2,3)P<sub>3</sub>*I(1,2,3)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7248	D-myo-inositol (1,2,3,6) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,3) trisphosphate + phosphate	phytate degradation I
isopentenyladenosine-5'-monophosphate	iPMP*isopentenyladenosine riboside-5'-monophosphate*iPRMP	C15 H22 N5 O7 P1 	C1(C(O)C(O)C(O1)COP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)C))		RXN-4313	isopentenyladenosine-5'-monophosphate + H2O  =  isopentenyl adenosine + phosphate	trans-zeatin biosynthesis
isopentenyladenosine-5'-monophosphate	iPMP*isopentenyladenosine riboside-5'-monophosphate*iPRMP	C15 H22 N5 O7 P1 	C1(C(O)C(O)C(O1)COP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)C))		RXN-4308	isopentenyladenosine-5'-monophosphate + NADPH + H2O  =  trans-zeatin riboside monophosphate + NADP+	trans-zeatin biosynthesis
isopentenyladenosine-5'-monophosphate	iPMP*isopentenyladenosine riboside-5'-monophosphate*iPRMP	C15 H22 N5 O7 P1 	C1(C(O)C(O)C(O1)COP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)C))		2.5.1.27	dimethylallyl-pyrophosphate + AMP  =  isopentenyladenosine-5'-monophosphate + pyrophosphate	trans-zeatin biosynthesis
isopentenyladenosine-5'-monophosphate	iPMP*isopentenyladenosine riboside-5'-monophosphate*iPRMP	C15 H22 N5 O7 P1 	C1(C(O)C(O)C(O1)COP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)C))		RXN-4311	isopentenyladenosine-5'-diphosphate + H2O  =  isopentenyladenosine-5'-monophosphate + phosphate	trans-zeatin biosynthesis
D-myo-inositol (2) monophosphate	1D-<i>myo</i>-inositol (2) monophosphate*Ins(2)P<sub>1</sub>*Ins(2)P*Ins2P	C6 H12 O9 P1 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C(O)1)(O)		RXN-7253	D-myo-inositol (2) monophosphate + H2O  =  myo-inositol + phosphate	phytate degradation I
D-myo-inositol (2) monophosphate	1D-<i>myo</i>-inositol (2) monophosphate*Ins(2)P<sub>1</sub>*Ins(2)P*Ins2P	C6 H12 O9 P1 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C(O)1)(O)		RXN-7305	D-myo-inositol (2,4) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation II
D-myo-inositol (2) monophosphate	1D-<i>myo</i>-inositol (2) monophosphate*Ins(2)P<sub>1</sub>*Ins(2)P*Ins2P	C6 H12 O9 P1 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C(O)1)(O)		RXN-7246	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation II
D-myo-inositol (2) monophosphate	1D-<i>myo</i>-inositol (2) monophosphate*Ins(2)P<sub>1</sub>*Ins(2)P*Ins2P	C6 H12 O9 P1 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C(O)1)(O)		RXN-7246	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation I
trans-zeatin riboside monophosphate	ZMP*tZRMP	C15 H22 N5 O8 P1 	C1(C(O)C(O)C(O1)COP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4314	trans-zeatin riboside monophosphate + H2O  =  trans-zeatin riboside + phosphate	trans-zeatin biosynthesis
trans-zeatin riboside monophosphate	ZMP*tZRMP	C15 H22 N5 O8 P1 	C1(C(O)C(O)C(O1)COP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4308	isopentenyladenosine-5'-monophosphate + NADPH + H2O  =  trans-zeatin riboside monophosphate + NADP+	trans-zeatin biosynthesis
trans-zeatin riboside monophosphate	ZMP*tZRMP	C15 H22 N5 O8 P1 	C1(C(O)C(O)C(O1)COP(O)(O)=O)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4312	trans-zeatin riboside diphosphate + H2O  =  trans-zeatin riboside monophosphate + phosphate	trans-zeatin biosynthesis
D-myo-inositol (1,2) bisphosphate	1D-<i>myo</i>-inositol (1,2) bisphosphate*1D-<i>myo</i>-inositol (1,2) biphosphate*Ins(1,2)P<sub>2</sub>*D-<i>myo</i>-inositol (1,2) biphosphate*I(1,2)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(O)		RXN-7246	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation II
D-myo-inositol (1,2) bisphosphate	1D-<i>myo</i>-inositol (1,2) bisphosphate*1D-<i>myo</i>-inositol (1,2) biphosphate*Ins(1,2)P<sub>2</sub>*D-<i>myo</i>-inositol (1,2) biphosphate*I(1,2)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(O)		RXN-7246	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation I
D-myo-inositol (1,2) bisphosphate	1D-<i>myo</i>-inositol (1,2) bisphosphate*1D-<i>myo</i>-inositol (1,2) biphosphate*Ins(1,2)P<sub>2</sub>*D-<i>myo</i>-inositol (1,2) biphosphate*I(1,2)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(O)		RXN-7251	D-myo-inositol (1,2) bisphosphate + H2O  =  D-myo-Inositol (1)-monophosphate + phosphate	phytate degradation I
D-myo-inositol (1,2) bisphosphate	1D-<i>myo</i>-inositol (1,2) bisphosphate*1D-<i>myo</i>-inositol (1,2) biphosphate*Ins(1,2)P<sub>2</sub>*D-<i>myo</i>-inositol (1,2) biphosphate*I(1,2)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(O)		RXN-7250	D-myo-inositol (1,2,3) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation II
D-myo-inositol (1,2) bisphosphate	1D-<i>myo</i>-inositol (1,2) bisphosphate*1D-<i>myo</i>-inositol (1,2) biphosphate*Ins(1,2)P<sub>2</sub>*D-<i>myo</i>-inositol (1,2) biphosphate*I(1,2)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(O)		RXN-7250	D-myo-inositol (1,2,3) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2) bisphosphate	1D-<i>myo</i>-inositol (1,2) bisphosphate*1D-<i>myo</i>-inositol (1,2) biphosphate*Ins(1,2)P<sub>2</sub>*D-<i>myo</i>-inositol (1,2) biphosphate*I(1,2)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(O)1)(O)		RXN-7245	D-myo-inositol (1,2,6) trisphosphate + H2O  =  D-myo-inositol (1,2) bisphosphate + phosphate	phytate degradation I
2-keto-3-deoxy-6-phospho-gluconate	2-dehydro-3-deoxy-D-gluconate-6-phosphate*2-dehydro-3-deoxy-6-phospho-D-gluconate*6-phospho-2-dehydro-3-deoxy-D-gluconate*2-keto-3-deoxy-6-phosphogluconate*2-keto-3-deoxy-6-P-gluconate*6-p-2-k-3-deo-gluconate*6-phospho-2-keto-3-deoxygluconate*6-phospho-2-dehydro-3-deoxygluconate*2-keto-3-deoxygluconate-6-P	C6 H11 O9 P1 	C(OP(O)(O)=O)[CH](O)[CH](O)[CH2]C(=O)C(=O)O	CAS:27244-54-8	4.1.2.14	2-keto-3-deoxy-6-phospho-gluconate  =  D-glyceraldehyde-3-phosphate + pyruvate	beta-D-glucuronide degradation
2-keto-3-deoxy-6-phospho-gluconate	2-dehydro-3-deoxy-D-gluconate-6-phosphate*2-dehydro-3-deoxy-6-phospho-D-gluconate*6-phospho-2-dehydro-3-deoxy-D-gluconate*2-keto-3-deoxy-6-phosphogluconate*2-keto-3-deoxy-6-P-gluconate*6-p-2-k-3-deo-gluconate*6-phospho-2-keto-3-deoxygluconate*6-phospho-2-dehydro-3-deoxygluconate*2-keto-3-deoxygluconate-6-P	C6 H11 O9 P1 	C(OP(O)(O)=O)[CH](O)[CH](O)[CH2]C(=O)C(=O)O	CAS:27244-54-8	2.7.1.45	2-dehydro-3-deoxy-D-gluconate + ATP  =  2-keto-3-deoxy-6-phospho-gluconate + ADP	beta-D-glucuronide degradation
isopentenyl adenosine	iPA	C15 H21 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(ncn3)NCC=C(C)C))		RXN-4315	isopentenyl adenosine + H2O  =  isopentenyladenine + D-ribose	trans-zeatin biosynthesis
isopentenyl adenosine	iPA	C15 H21 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(ncn3)NCC=C(C)C))		RXN-4316	isopentenyl adenosine + H2O  =  trans-zeatin riboside + 2 H+	trans-zeatin biosynthesis
isopentenyl adenosine	iPA	C15 H21 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(ncn3)NCC=C(C)C))		1.5.99.12	isopentenyl adenosine + H2O + FAD  =  adenosine + 3-methyl-2-butenal + FADH2	cytokinins degradation
isopentenyl adenosine	iPA	C15 H21 N5 O4 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(ncn3)NCC=C(C)C))		RXN-4313	isopentenyladenosine-5'-monophosphate + H2O  =  isopentenyl adenosine + phosphate	trans-zeatin biosynthesis
alpha-carotene		C40 H56 	CC1(C(=C(C)CCC1)C=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CCC=C(C)2))(C)		RXN-5961	alpha-carotene + NADPH + O2  =  zeinoxanthin + NADP+ + H2O	carotenoid biosynthesis
alpha-carotene		C40 H56 	CC1(C(=C(C)CCC1)C=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CCC=C(C)2))(C)		RXN1F-148	delta-carotene  =  alpha-carotene	carotenoid biosynthesis
trans-zeatin riboside	ZR*zeatin riboside	C15 H21 N5 O5 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4318	trans-zeatin riboside + H2O  =  trans-zeatin + D-ribose	trans-zeatin biosynthesis
trans-zeatin riboside	ZR*zeatin riboside	C15 H21 N5 O5 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		1.5.99.12	trans-zeatin riboside + H2O + FAD  =  adenosine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
trans-zeatin riboside	ZR*zeatin riboside	C15 H21 N5 O5 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4316	isopentenyl adenosine + H2O  =  trans-zeatin riboside + 2 H+	trans-zeatin biosynthesis
trans-zeatin riboside	ZR*zeatin riboside	C15 H21 N5 O5 	C1(C(O)C(O)C(O1)CO)n2(c3(c(nc2)c(ncn3)NCC=C(C)CO))		RXN-4314	trans-zeatin riboside monophosphate + H2O  =  trans-zeatin riboside + phosphate	trans-zeatin biosynthesis
lutein		C40 H56 O2 	CC1(C(=C(C)CC(O)C1)C=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CC(O)C=C(C)2))(C)		RXN-5962	zeinoxanthin + NADPH + O2  =  lutein + NADP+ + H2O	carotenoid biosynthesis
isopentenyladenine	N<sup>6</sup>-&Delta;2-isopentenyladenine*iP	C10 H12 N5 	c2(ncnc1(c(ncn1)2))(NCC=C(C)C)	CAS:2365-40-4*NCI:|106958|	RXN-4317	isopentenyladenine + H2O  =  trans-zeatin + 2 H+	trans-zeatin biosynthesis
isopentenyladenine	N<sup>6</sup>-&Delta;2-isopentenyladenine*iP	C10 H12 N5 	c2(ncnc1(c(ncn1)2))(NCC=C(C)C)	CAS:2365-40-4*NCI:|106958|	2.4.1.-	isopentenyladenine + UDP-D-glucose  =  isopentenyladenine-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
isopentenyladenine	N<sup>6</sup>-&Delta;2-isopentenyladenine*iP	C10 H12 N5 	c2(ncnc1(c(ncn1)2))(NCC=C(C)C)	CAS:2365-40-4*NCI:|106958|	2.4.1.-	isopentenyladenine + UDP-D-glucose  =  isopentenyladenine-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
isopentenyladenine	N<sup>6</sup>-&Delta;2-isopentenyladenine*iP	C10 H12 N5 	c2(ncnc1(c(ncn1)2))(NCC=C(C)C)	CAS:2365-40-4*NCI:|106958|	1.5.99.12	isopentenyladenine + FAD + H2O  =  3-methyl-2-butenal + adenine + FADH2	cytokinins degradation
isopentenyladenine	N<sup>6</sup>-&Delta;2-isopentenyladenine*iP	C10 H12 N5 	c2(ncnc1(c(ncn1)2))(NCC=C(C)C)	CAS:2365-40-4*NCI:|106958|	RXN-4315	isopentenyl adenosine + H2O  =  isopentenyladenine + D-ribose	trans-zeatin biosynthesis
D-myo-inositol (3)-monophosphate	1-L-<i>myo</i>-inositol-1-p*L-<i>myo</i>-inositol 1-phosphate*inositol 1-phosphate*<i>myo</i>-inositol 1-phosphate*1D-<i>myo</i>-inositol 3-phosphate*Ins(3)P<sub>1</sub>*1D-<i>myo</i>-inositol 3-monophosphate*<i>myo</i>-inositol 1-monophosphate*Ins3P*1L-<i>myo</i>-inositol 1-phosphate	C6 H12 O9 P1 	C1(C(O)C(O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7202	D-myo-inositol (3)-monophosphate + ATP  =  D-myo-inositol (3,4)-bisphosphate + ADP	lipid-independent phytate biosynthesis
D-myo-inositol (3)-monophosphate	1-L-<i>myo</i>-inositol-1-p*L-<i>myo</i>-inositol 1-phosphate*inositol 1-phosphate*<i>myo</i>-inositol 1-phosphate*1D-<i>myo</i>-inositol 3-phosphate*Ins(3)P<sub>1</sub>*1D-<i>myo</i>-inositol 3-monophosphate*<i>myo</i>-inositol 1-monophosphate*Ins3P*1L-<i>myo</i>-inositol 1-phosphate	C6 H12 O9 P1 	C1(C(O)C(O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		2.7.1.64	myo-inositol + ATP  =  D-myo-inositol (3)-monophosphate + ADP	lipid-independent phytate biosynthesis
D-myo-inositol (3)-monophosphate	1-L-<i>myo</i>-inositol-1-p*L-<i>myo</i>-inositol 1-phosphate*inositol 1-phosphate*<i>myo</i>-inositol 1-phosphate*1D-<i>myo</i>-inositol 3-phosphate*Ins(3)P<sub>1</sub>*1D-<i>myo</i>-inositol 3-monophosphate*<i>myo</i>-inositol 1-monophosphate*Ins3P*1L-<i>myo</i>-inositol 1-phosphate	C6 H12 O9 P1 	C1(C(O)C(O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		5.5.1.4	beta-D-glucose-6-phosphate  =  D-myo-inositol (3)-monophosphate	lipid-independent phytate biosynthesis
methylesterified 1,4-alpha-D-galacturonosyl	methylesterified homogalacturonan	C19 H28 O19 	C1(OC(C(=O)O)C(O)C(O)C(O)1)OC2(C(O)C(O)C(OC2C(=O)OC)OC3(C(C(O)=O)OC(O)C(O)C(O)3))		3.1.1.11	methylesterified 1,4-alpha-D-galacturonosyl + H2O  =  1,4-alpha-D-galacturonosyl + methanol	homogalacturonan degradation
dihydrouracil	5,6-dihydrouracil*DI-H-uracil*4,5-dihydrouracil	C4 H6 N2 O2 	C1(NC(=O)NC(=O)C1)	CAS:504-07-4	3.5.2.2	H2O + dihydrouracil  =  3-ureidopropionate	beta-alanine biosynthesis III
dihydrouracil	5,6-dihydrouracil*DI-H-uracil*4,5-dihydrouracil	C4 H6 N2 O2 	C1(NC(=O)NC(=O)C1)	CAS:504-07-4	1.3.1.2	NADPH + uracil  =  NADP+ + dihydrouracil	beta-alanine biosynthesis III
homomethionine		C6 H13 N1 O2 S1 	C(O)(=O)C(N)CCCSC		1.14.13.-	homomethionine + NADPH + O2  =  4-methylthiobutanaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from homomethionine
homomethionine		C6 H13 N1 O2 S1 	C(O)(=O)C(N)CCCSC		2.6.1.-	2-oxo-5-methylthiopentanoic-acid + an amino acid  =  homomethionine + a 2-oxo acid	homomethionine biosynthesis
1,3-diaminopropane	Trimethylenediamine*1,3-Propanediamine*Propane-1,3-diamine*1,3-DAP	C3 H10 N2 	C(N)CCN	CAS:109-76-2	1.4.3.6	1,3-diaminopropane + H2O + O2  =  3-aminopropionaldehyde + NH3 + H2O2	beta-alanine biosynthesis I
1,3-diaminopropane	Trimethylenediamine*1,3-Propanediamine*Propane-1,3-diamine*1,3-DAP	C3 H10 N2 	C(N)CCN	CAS:109-76-2	1.5.99.6	H2O + acceptor + spermidine  =  reduced acceptor + 4-amino-butyraldehyde + 1,3-diaminopropane	beta-alanine biosynthesis I
1,3-diaminopropane	Trimethylenediamine*1,3-Propanediamine*Propane-1,3-diamine*1,3-DAP	C3 H10 N2 	C(N)CCN	CAS:109-76-2	1.5.3.11	spermine + O2 + H2O  =  1-(3-aminopropyl)-4-aminobutanal + 1,3-diaminopropane + H2O2	beta-alanine biosynthesis I
trehalose	&alpha;,&alpha;-trehalose	C12 H22 O11 	C1(OC(CO)C(O)C(O)C(O)1)OC2(C(O)C(O)C(O)C(O2)CO)	CAS:99-20-7	3.1.3.12	trehalose 6-phosphate + H2O  =  trehalose + phosphate	trehalose biosynthesis
phytate	phytic acid*<i>myo</i>-inositol hexakisphosphate*1D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*Inositol 1,2,3,4,5,6-hexakisphosphate*InsP<sub>6</sub>	C6 H12 O24 P6 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		3.1.3.8	phytate + H2O  =  D-myo-inositol (1,2,4,5,6)-pentakisphosphate + phosphate	phytate degradation I
phytate	phytic acid*<i>myo</i>-inositol hexakisphosphate*1D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*Inositol 1,2,3,4,5,6-hexakisphosphate*InsP<sub>6</sub>	C6 H12 O24 P6 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		3.1.3.26	phytate + H2O  =  D-myo-inositol (1,2,3,5,6) pentakisphosphate + phosphate	phytate degradation I
phytate	phytic acid*<i>myo</i>-inositol hexakisphosphate*1D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*Inositol 1,2,3,4,5,6-hexakisphosphate*InsP<sub>6</sub>	C6 H12 O24 P6 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		3.1.3.26	H2O + phytate  =  phosphate + D-myo-inositol (1,2,3,4,5)-pentakisphosphate	phytate degradation II
phytate	phytic acid*<i>myo</i>-inositol hexakisphosphate*1D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*Inositol 1,2,3,4,5,6-hexakisphosphate*InsP<sub>6</sub>	C6 H12 O24 P6 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,2,3,4,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
phytate	phytic acid*<i>myo</i>-inositol hexakisphosphate*1D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*Inositol 1,2,3,4,5,6-hexakisphosphate*InsP<sub>6</sub>	C6 H12 O24 P6 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-independent phytate biosynthesis
phytate	phytic acid*<i>myo</i>-inositol hexakisphosphate*1D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*Inositol 1,2,3,4,5,6-hexakisphosphate*InsP<sub>6</sub>	C6 H12 O24 P6 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
phytate	phytic acid*<i>myo</i>-inositol hexakisphosphate*1D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*D-<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*<i>myo</i>-Inositol 1,2,3,4,5,6-hexakisphosphate*Inositol 1,2,3,4,5,6-hexakisphosphate*InsP<sub>6</sub>	C6 H12 O24 P6 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
dolichyl beta-D-mannosyl phosphate	dolichol monophosphate mannose*beta-D-mannopyranose, 1-ester with dolichol dihydrogen phosphate*D-mannose, ester with dolichol dihydrogen phosphate*mannosyl phosphoryl dolichol*mannolipid*dolichyl mannosyl phosphate*dolichyl mannopyranosyl phosphate*dolichol, beta-D-mannopyranose deriv.*dolichyl phosphate D-mannose*dolichyl D-mannosyl phosphate	C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OC1(C(O)C(O)C(O)C(O1)CO)	PUBCHEM:41482*CAS:41482	RXN-5467	(mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl beta-D-mannosyl phosphate	dolichol monophosphate mannose*beta-D-mannopyranose, 1-ester with dolichol dihydrogen phosphate*D-mannose, ester with dolichol dihydrogen phosphate*mannosyl phosphoryl dolichol*mannolipid*dolichyl mannosyl phosphate*dolichyl mannopyranosyl phosphate*dolichol, beta-D-mannopyranose deriv.*dolichyl phosphate D-mannose*dolichyl D-mannosyl phosphate	C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OC1(C(O)C(O)C(O)C(O1)CO)	PUBCHEM:41482*CAS:41482	RXN-5469	(mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)9-(N-acetylglucosaminyl)2-diphosphodolichol   + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl beta-D-mannosyl phosphate	dolichol monophosphate mannose*beta-D-mannopyranose, 1-ester with dolichol dihydrogen phosphate*D-mannose, ester with dolichol dihydrogen phosphate*mannosyl phosphoryl dolichol*mannolipid*dolichyl mannosyl phosphate*dolichyl mannopyranosyl phosphate*dolichol, beta-D-mannopyranose deriv.*dolichyl phosphate D-mannose*dolichyl D-mannosyl phosphate	C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OC1(C(O)C(O)C(O)C(O1)CO)	PUBCHEM:41482*CAS:41482	RXN-5468	(mannosyl)7-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)8-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl beta-D-mannosyl phosphate	dolichol monophosphate mannose*beta-D-mannopyranose, 1-ester with dolichol dihydrogen phosphate*D-mannose, ester with dolichol dihydrogen phosphate*mannosyl phosphoryl dolichol*mannolipid*dolichyl mannosyl phosphate*dolichyl mannopyranosyl phosphate*dolichol, beta-D-mannopyranose deriv.*dolichyl phosphate D-mannose*dolichyl D-mannosyl phosphate	C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OC1(C(O)C(O)C(O)C(O1)CO)	PUBCHEM:41482*CAS:41482	RXN-5466	(mannosyl)5-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl beta-D-mannosyl phosphate  =  (mannosyl)6-(N-acetylglucosaminyl)2-diphosphodolichol + dolichyl-phosphate	dolichyl-diphosphooligosaccharide biosynthesis
dolichyl beta-D-mannosyl phosphate	dolichol monophosphate mannose*beta-D-mannopyranose, 1-ester with dolichol dihydrogen phosphate*D-mannose, ester with dolichol dihydrogen phosphate*mannosyl phosphoryl dolichol*mannolipid*dolichyl mannosyl phosphate*dolichyl mannopyranosyl phosphate*dolichol, beta-D-mannopyranose deriv.*dolichyl phosphate D-mannose*dolichyl D-mannosyl phosphate	C86 H143 O9 P1 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OC1(C(O)C(O)C(O)C(O1)CO)	PUBCHEM:41482*CAS:41482	2.4.1.83	dolichyl-phosphate + GDP-mannose  =  dolichyl beta-D-mannosyl phosphate + GDP	dolichyl-diphosphooligosaccharide biosynthesis
alpha-D-galactosyl-beta-D-galactosyldiacylglycerol	digalactosyldiacylglycerol*DGDG	C17 H26 O15 R2 			2.4.1.184	2 mono-beta-D-galactosyldiacylglycerol  =  alpha-D-galactosyl-beta-D-galactosyldiacylglycerol + 1,2-diacylglycerol	glycolipid biosynthesis
alpha-D-galactosyl-beta-D-galactosyldiacylglycerol	digalactosyldiacylglycerol*DGDG	C17 H26 O15 R2 			RXN-1225	mono-beta-D-galactosyldiacylglycerol + UDP-galactose  =  alpha-D-galactosyl-beta-D-galactosyldiacylglycerol + UDP	glycolipid biosynthesis
monodehydroascorbate		C6 H7 O6 	C(O)C(O)c1(c(O)c(O)c([O-1])o1)		1.6.5.4	2 monodehydroascorbate + NADPH  =  2 L-ascorbate + NADP+	ascorbate glutathione cycle
monodehydroascorbate		C6 H7 O6 	C(O)C(O)c1(c(O)c(O)c([O-1])o1)		RXN-3523	2 monodehydroascorbate  =  L-ascorbate + L-dehydro-ascorbate	ascorbate glutathione cycle
monodehydroascorbate		C6 H7 O6 	C(O)C(O)c1(c(O)c(O)c([O-1])o1)		1.10.3.3	L-ascorbate + O2  =  monodehydroascorbate + 2 H2O	ascorbate glutathione cycle
monodehydroascorbate		C6 H7 O6 	C(O)C(O)c1(c(O)c(O)c([O-1])o1)		1.11.1.11	2 L-ascorbate + H2O2  =  2 monodehydroascorbate + 2 H2O	ascorbate glutathione cycle
3-hydroxy-L-kynurenine	L-3-hydroxykynurenine*3-hydroxy-kynurenine	C10 H12 N2 O4 	C(=O)(O)C(N)CC(=O)c1(c(N)c(O)ccc1)	CAS:606-14-4	3.7.1.3	3-hydroxy-L-kynurenine + H2O  =  3-hydroxy-anthranilate + L-alanine	NAD biosynthesis II (from tryptophan)
3-hydroxy-L-kynurenine	L-3-hydroxykynurenine*3-hydroxy-kynurenine	C10 H12 N2 O4 	C(=O)(O)C(N)CC(=O)c1(c(N)c(O)ccc1)	CAS:606-14-4	3.7.1.3	3-hydroxy-L-kynurenine + H2O  =  3-hydroxy-anthranilate + L-alanine	tryptophan degradation
3-hydroxy-L-kynurenine	L-3-hydroxykynurenine*3-hydroxy-kynurenine	C10 H12 N2 O4 	C(=O)(O)C(N)CC(=O)c1(c(N)c(O)ccc1)	CAS:606-14-4	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	NAD biosynthesis II (from tryptophan)
3-hydroxy-L-kynurenine	L-3-hydroxykynurenine*3-hydroxy-kynurenine	C10 H12 N2 O4 	C(=O)(O)C(N)CC(=O)c1(c(N)c(O)ccc1)	CAS:606-14-4	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	tryptophan degradation
D-myo-inositol (3,4,5,6)-tetrakisphosphate	Ins(3,4,5,6)P<sub>4</sub>*Inositol 3,4,5,6-tetra<i>kis</i>phosphate*1D-<i>myo</i>-inositol 3,4,5,6-tetra<i>kis</i>phosphate*I(3,4,5,6)P<sub>4</sub>	C6 H16 O18 P4 	C1(C(OP(O)(=O)O)C(OP(O)(=O)O)C(OP(O)(=O)O)C(C(O)1)OP(O)(=O)O)(O)		2.7.1.134	D-myo-inositol (3,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-independent phytate biosynthesis
D-myo-inositol (3,4,5,6)-tetrakisphosphate	Ins(3,4,5,6)P<sub>4</sub>*Inositol 3,4,5,6-tetra<i>kis</i>phosphate*1D-<i>myo</i>-inositol 3,4,5,6-tetra<i>kis</i>phosphate*I(3,4,5,6)P<sub>4</sub>	C6 H16 O18 P4 	C1(C(OP(O)(=O)O)C(OP(O)(=O)O)C(OP(O)(=O)O)C(C(O)1)OP(O)(=O)O)(O)		RXN-7204	D-myo-inositol (3,4,6)-trisphosphate + ATP  =  D-myo-inositol (3,4,5,6)-tetrakisphosphate + ADP	lipid-independent phytate biosynthesis
dGDP	2'-deoxyguanosine-5'-diphosphate*deoxyguanosine-diphosphate	C10 H15 N5 O10 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(CC1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	CAS:102783-74-4	2.7.4.6	dGDP + ATP  =  dGTP + ADP	de novo biosynthesis of purine nucleotides I
dGDP	2'-deoxyguanosine-5'-diphosphate*deoxyguanosine-diphosphate	C10 H15 N5 O10 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(CC1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	CAS:102783-74-4	RXN0-748	GDP + reduced glutaredoxin  =  dGDP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
dGDP	2'-deoxyguanosine-5'-diphosphate*deoxyguanosine-diphosphate	C10 H15 N5 O10 P2 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(CC1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	CAS:102783-74-4	1.17.4.1	Reduced Thioredoxin + GDP  =  Oxidized Thioredoxin + dGDP + H2O	de novo biosynthesis of purine nucleotides I
isovaleryl-CoA	3-methylbutyryl-CoA*3-methylbutanoyl-CoA*isovaleryl-coenzyme A*iso-valeryl-CoA	C26 H44 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(C)C)	CAS:6244-91-3	1.3.99.10	isovaleryl-CoA + FAD  =  3-methylcrotonyl-CoA + FADH2	leucine degradation
isovaleryl-CoA	3-methylbutyryl-CoA*3-methylbutanoyl-CoA*isovaleryl-coenzyme A*iso-valeryl-CoA	C26 H44 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(C)C)	CAS:6244-91-3	2KETO-4METHYL-PENTANOATE-DEHYDROG-RXN	2-keto-4-methyl-pentanoate + coenzyme A + NAD+  =  isovaleryl-CoA + CO2 + NADH	leucine degradation
3-indoleacetonitrile	indole-3-ylacetonitrile*indole-3-acetonitrile*(indole-3-yl)acetonitrile	C10 H8 N2 	c1(c(CC#N)c2(c([nH]1)cccc2))		3.5.5.1	3-indoleacetonitrile + 2 H2O  =  NH3 + indole-3-acetate	IAA biosynthesis I
3-indoleacetonitrile	indole-3-ylacetonitrile*indole-3-acetonitrile*(indole-3-yl)acetonitrile	C10 H8 N2 	c1(c(CC#N)c2(c([nH]1)cccc2))		4.99.1.6	indole-3-acetaldoxime  =  3-indoleacetonitrile + H2O	IAA biosynthesis I
GA24	GA24*gibberellin A24*gibberellin A<sub>24</sub>	C20 H26 O5 	CC1(C(O)=O)([CH]2(C(C=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA9 + succinate + 2 CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA24	GA24*gibberellin A24*gibberellin A<sub>24</sub>	C20 H26 O5 	CC1(C(O)=O)([CH]2(C(C=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA24	GA24*gibberellin A24*gibberellin A<sub>24</sub>	C20 H26 O5 	CC1(C(O)=O)([CH]2(C(C=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA25 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA24	GA24*gibberellin A24*gibberellin A<sub>24</sub>	C20 H26 O5 	CC1(C(O)=O)([CH]2(C(C=O)(CCC1)[CH]3(C4(C2C(O)=O)(CC(CC3)C(C4)=C))))		1.14.11.-	GA15 + O2 + alpha-ketoglutarate  =  GA24 + H2O + CO2 + succinate	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
trans-zeatin	zeatin*cytokinin*(2E)-2-methyl-4-(1H-purin-6-ylamino)-2-buten-1-ol*<i>t</i>-zeatin	C10 H12 N5 O1 	c2(ncnc1(c(ncn1)2))(NCC=C(C)CO)		2.4.1.-	trans-zeatin + UDP-D-glucose  =  trans-zeatin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
trans-zeatin	zeatin*cytokinin*(2E)-2-methyl-4-(1H-purin-6-ylamino)-2-buten-1-ol*<i>t</i>-zeatin	C10 H12 N5 O1 	c2(ncnc1(c(ncn1)2))(NCC=C(C)CO)		2.4.1.-	trans-zeatin + UDP-D-glucose  =  trans-zeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
trans-zeatin	zeatin*cytokinin*(2E)-2-methyl-4-(1H-purin-6-ylamino)-2-buten-1-ol*<i>t</i>-zeatin	C10 H12 N5 O1 	c2(ncnc1(c(ncn1)2))(NCC=C(C)CO)		1.5.99.12	trans-zeatin + H2O + FAD  =  adenine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
trans-zeatin	zeatin*cytokinin*(2E)-2-methyl-4-(1H-purin-6-ylamino)-2-buten-1-ol*<i>t</i>-zeatin	C10 H12 N5 O1 	c2(ncnc1(c(ncn1)2))(NCC=C(C)CO)		2.4.1.203	trans-zeatin + UDP-D-glucose  =  trans-zeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
trans-zeatin	zeatin*cytokinin*(2E)-2-methyl-4-(1H-purin-6-ylamino)-2-buten-1-ol*<i>t</i>-zeatin	C10 H12 N5 O1 	c2(ncnc1(c(ncn1)2))(NCC=C(C)CO)		RXN-4317	isopentenyladenine + H2O  =  trans-zeatin + 2 H+	trans-zeatin biosynthesis
trans-zeatin	zeatin*cytokinin*(2E)-2-methyl-4-(1H-purin-6-ylamino)-2-buten-1-ol*<i>t</i>-zeatin	C10 H12 N5 O1 	c2(ncnc1(c(ncn1)2))(NCC=C(C)CO)		RXN-4318	trans-zeatin riboside + H2O  =  trans-zeatin + D-ribose	trans-zeatin biosynthesis
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	2.5.1.8	a tRNA + dimethylallyl-pyrophosphate  =  prenyl-tRNA + pyrophosphate	cis-zeatin biosynthesis
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	2.5.1.27	dimethylallyl-pyrophosphate + AMP  =  isopentenyladenosine-5'-monophosphate + pyrophosphate	trans-zeatin biosynthesis
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	2.5.1.-	dimethylallyl-pyrophosphate + ADP  =  isopentenyladenosine-5'-diphosphate + pyrophosphate	trans-zeatin biosynthesis
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	2.5.1.-	dimethylallyl-pyrophosphate + ATP  =  isopentenyladenosine-5'-triphosphate + pyrophosphate	trans-zeatin biosynthesis
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	2.5.1.1	dimethylallyl-pyrophosphate + delta3-isopentenyl-PP  =  pyrophosphate + geranyl-PP	polyisoprenoid biosynthesis
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	2.5.1.1	dimethylallyl-pyrophosphate + delta3-isopentenyl-PP  =  pyrophosphate + geranyl-PP	mevalonate pathway
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	5.3.3.2	delta3-isopentenyl-PP  =  dimethylallyl-pyrophosphate	polyisoprenoid biosynthesis
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	5.3.3.2	delta3-isopentenyl-PP  =  dimethylallyl-pyrophosphate	mevalonate pathway
dimethylallyl-pyrophosphate	&delta;2-isopentenyl-diphosphate*&delta;-prenyl diphosphate*DMAPP*prenyl-diphosphate*delta-prenyl diphosphate*delta2-isopentenyl-diphosphate*2-isopentenyl diphosphate*prenyl diphosphate*DMAPP*DPP*dimethylallyl-diphosphate*di-CH3-allyl-PPi*dimethylallyl-PP*dimethylallyl-PPi*DMPP	C5 H12 O7 P2 	C(C=C(C)C)OP(O)(=O)OP(O)(=O)O	CAS:358-71-4*LIGAND-CPD:C00235*CAS:358-72-5*CAS:358-71-4*LIGAND-CPD:C02742	RXN0-884	1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + 2 H+  =  dimethylallyl-pyrophosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
guanosine 5'-diphosphate,3'-diphosphate	guanosine tetraphosphate*ppGpp*guanosine 3',5'-bispyrophosphate*guanosine 3',5'-bis(diphosphate)*Guanosine 3'-diphosphate 5'-diphosphate	C10 H17 N5 O17 P4 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1OP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C01228	3.1.7.2	guanosine 5'-diphosphate,3'-diphosphate + H2O  =  pyrophosphate + GDP	ppGpp biosynthesis
guanosine 5'-diphosphate,3'-diphosphate	guanosine tetraphosphate*ppGpp*guanosine 3',5'-bispyrophosphate*guanosine 3',5'-bis(diphosphate)*Guanosine 3'-diphosphate 5'-diphosphate	C10 H17 N5 O17 P4 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1OP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C01228	3.6.1.40	H2O + guanosine 3'-diphosphate 5'-triphosphate  =  phosphate + guanosine 5'-diphosphate,3'-diphosphate	ppGpp biosynthesis
guanosine 5'-diphosphate,3'-diphosphate	guanosine tetraphosphate*ppGpp*guanosine 3',5'-bispyrophosphate*guanosine 3',5'-bis(diphosphate)*Guanosine 3'-diphosphate 5'-diphosphate	C10 H17 N5 O17 P4 	C(OP(=O)(O)OP(O)(O)=O)C1(OC(C(O)C1OP(=O)(O)OP(O)(O)=O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	LIGAND-CPD:C01228	GDPPYPHOSKIN-RXN	ATP + GDP  =  AMP + guanosine 5'-diphosphate,3'-diphosphate	ppGpp biosynthesis
gamma-carotene		C40 H56 	CC(C)=CCCC(C)=CC=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC1(C(C)(C)CCCC(C)=1)		RXN1F-151	gamma-carotene  =  beta-carotene	carotenoid biosynthesis
gamma-carotene		C40 H56 	CC(C)=CCCC(C)=CC=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC1(C(C)(C)CCCC(C)=1)		RXN1F-150	lycopene  =  gamma-carotene	carotenoid biosynthesis
a omega-hydroxy fatty acid					RXN-4465	a omega-hydroxy fatty acid + O2  =  a omega-oxo fatty acid + H2O2	fatty acid omega-oxidation
a omega-hydroxy fatty acid					RXN-4464	a fatty acid  =  a omega-hydroxy fatty acid	fatty acid omega-oxidation
glutaryl-CoA	glutaryl-coenzyme A	C26 H42 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(O)=O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCCC(O)=O)		GLUTARYL-COA-DEHYDROG-RXN	glutaryl-CoA + FAD  =  glutaconyl-CoA + FADH2	lysine degradation II
glutaryl-CoA	glutaryl-coenzyme A	C26 H42 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(O)=O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCCC(O)=O)		GLUTARYL-COA-DEHYDROG-RXN	glutaryl-CoA + FAD  =  glutaconyl-CoA + FADH2	tryptophan degradation
glutaryl-CoA	glutaryl-coenzyme A	C26 H42 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(O)=O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCCC(O)=O)		2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	lysine degradation II
glutaryl-CoA	glutaryl-coenzyme A	C26 H42 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(O)=O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCCC(O)=O)		2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	tryptophan degradation
ent-kaur-16-ene	<i>ent</i>-kaurene	C20 H32 	CC3(C)(CCCC4(C)([CH]1(C2(CC(CC1)C(C2)=C)(CC[CH]34))))		1.14.13.78	ent-kaur-16-ene + O2 + NADPH  =  H2O + NADP+ + ent-kaur-16-en-19-ol	GA12 biosynthesis
ent-kaur-16-ene	<i>ent</i>-kaurene	C20 H32 	CC3(C)(CCCC4(C)([CH]1(C2(CC(CC1)C(C2)=C)(CC[CH]34))))		4.2.3.19	ent-copalyl diphosphate  =  pyrophosphate + ent-kaur-16-ene	ent-kaurene biosynthesis
beta-carotene		C40 H56 	CC(C=CC=C(C)C=CC1(C(C)(C)CCCC(C)=1))=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CCCC(C)=2)	CAS:7235-40-7	RXN1F-152	beta-carotene + 2 H2O  =  zeaxanthin	carotenoid biosynthesis
beta-carotene		C40 H56 	CC(C=CC=C(C)C=CC1(C(C)(C)CCCC(C)=1))=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CCCC(C)=2)	CAS:7235-40-7	RXN1F-151	gamma-carotene  =  beta-carotene	carotenoid biosynthesis
DNA					2.1.1.37	DNA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + DNA CONTAINING 5-METHYLCYTOSINE	methionine degradation I
3-(2'-methylthio)ethylmalic-acid		C7 H12 O5 S1 	C(SC)CC(C(O)=O)C(O)C(=O)O		1.1.1.-	3-(2'-methylthio)ethylmalic-acid  =  2-oxo-5-methylthiopentanoic-acid + CO2	homomethionine biosynthesis
3-(2'-methylthio)ethylmalic-acid		C7 H12 O5 S1 	C(SC)CC(C(O)=O)C(O)C(=O)O		5.4.4.-	2-(2'-methylthio)ethylmalic-acid  =  3-(2'-methylthio)ethylmalic-acid	homomethionine biosynthesis
trans-polyisoprenyln-PP					2.5.1.-	trans-polyisoprenyln-PP + delta3-isopentenyl-PP  =  trans-polyisoprenyln+1-PP + pyrophosphate	polyisoprenoid biosynthesis
2-amino-3-oxobutanoate	2-amino-acetoacetate*2-amino-3-ketobutyrate*2-amino-3-oxobutyrate*&alpha;-amino-&beta;-ketobutyrate*L-2-amino-3-oxobutanoate	C4 H7 N1 O3 	C(O)(=O)C(N)C(=O)C		THREOSPON-RXN	2-amino-3-oxobutanoate  =  aminoacetone + CO2	threonine degradation
2-amino-3-oxobutanoate	2-amino-acetoacetate*2-amino-3-ketobutyrate*2-amino-3-oxobutyrate*&alpha;-amino-&beta;-ketobutyrate*L-2-amino-3-oxobutanoate	C4 H7 N1 O3 	C(O)(=O)C(N)C(=O)C		1.1.1.103	L-threonine + NAD+  =  2-amino-3-oxobutanoate + NADH	threonine degradation
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	glycolysis I
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	glycolysis II
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	4.1.2.13	fructose-1,6-bisphosphate  =  dihydroxy-acetone-phosphate + D-glyceraldehyde-3-phosphate	gluconeogenesis
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	3.1.3.11	fructose-1,6-bisphosphate + H2O  =  D-fructose-6-phosphate + phosphate	Calvin cycle
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	3.1.3.11	fructose-1,6-bisphosphate + H2O  =  D-fructose-6-phosphate + phosphate	gluconeogenesis
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	2.7.1.90	D-fructose-6-phosphate + pyrophosphate  =  phosphate + fructose-1,6-bisphosphate	glycolysis I
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	sucrose degradation to ethanol and lactate (anaerobic)
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis I
fructose-1,6-bisphosphate	fructose-1,6-biphosphate*fructose-1,6-diphosphate*&alpha;-D-fructose-1,6-diphosphate*D-fructose-1,6-diphosphate*D-fructose-1,6-bisphosphate	C6 H14 O12 P2 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)(O)COP(O)(=O)O)	CAS:488-69-7	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis II
6,7-dimethyl-8-(1-D-ribityl)lumazine		C13 H18 N4 O6 	CC1(N(CC(O)C(O)C(O)CO)C2(C(=NC(C)=1)C(=O)NC(N=2)=O))		2.5.1.9	2 6,7-dimethyl-8-(1-D-ribityl)lumazine  =  5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + riboflavin	riboflavin and FMN and FAD biosynthesis
6,7-dimethyl-8-(1-D-ribityl)lumazine		C13 H18 N4 O6 	CC1(N(CC(O)C(O)C(O)CO)C2(C(=NC(C)=1)C(=O)NC(N=2)=O))		LUMAZINESYN-RXN	5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + 3,4-dihydroxy-2-butanone-4-P  =  6,7-dimethyl-8-(1-D-ribityl)lumazine + phosphate + O2	riboflavin and FMN and FAD biosynthesis
3-methylsulfinylpropyl-glucosinolate	glucoiberin	C11 H21 N1 O10 S3 	C1(OC(C(CO)C(O)C(O)1)SC(=NOS(O)(=O)=O)CCCS(=O)C)(O)		RXN-2222	3-methylsulfinylpropyl-glucosinolate  =  2-propenyl-glucosinolate	glucosinolate biosynthesis from homomethionine
3-methylsulfinylpropyl-glucosinolate	glucoiberin	C11 H21 N1 O10 S3 	C1(OC(C(CO)C(O)C(O)1)SC(=NOS(O)(=O)=O)CCCS(=O)C)(O)		RXN-2223	3-methylsulfinylpropyl-glucosinolate  =  3-hydroxypropyl-glucosinolate	glucosinolate biosynthesis from homomethionine
3-methylsulfinylpropyl-glucosinolate	glucoiberin	C11 H21 N1 O10 S3 	C1(OC(C(CO)C(O)C(O)1)SC(=NOS(O)(=O)=O)CCCS(=O)C)(O)		RXN-2221	3-methylthiopropyl-glucosinolate  =  3-methylsulfinylpropyl-glucosinolate	glucosinolate biosynthesis from homomethionine
2-aceto-2-hydroxy-butyrate	&alpha;-aceto-&alpha;-hydroxybutyrate	C6 H10 O4 	CC(=O)C(O)(C(O)=O)CC	CAS:3142-65-2	1.1.1.86	2-aceto-2-hydroxy-butyrate + NADPH  =  2,3-dihydroxy-3-methylvalerate + NADP+	isoleucine biosynthesis
2-aceto-2-hydroxy-butyrate	&alpha;-aceto-&alpha;-hydroxybutyrate	C6 H10 O4 	CC(=O)C(O)(C(O)=O)CC	CAS:3142-65-2	2.2.1.6	pyruvate + 2-oxobutanoate  =  2-aceto-2-hydroxy-butyrate + CO2	isoleucine biosynthesis
3-hydroxypropionyl-CoA	3-hydroxypropionyl-coenzyme A*3-Hydroxypropanoyl-CoA*3-Hydroxypropanoyl coenzymeA	C24 H40 N7 O18 P3 S1 	c1(c2(c(ncn1)n(cn2)C3(OC(C(C(O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCO)))(N)		3.1.2.4	3-hydroxypropionyl-CoA + H2O  =  3-hydroxy-propionate + coenzyme A	beta-alanine biosynthesis II
3-hydroxypropionyl-CoA	3-hydroxypropionyl-coenzyme A*3-Hydroxypropanoyl-CoA*3-Hydroxypropanoyl coenzymeA	C24 H40 N7 O18 P3 S1 	c1(c2(c(ncn1)n(cn2)C3(OC(C(C(O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCO)))(N)		4.2.1.17	acrylyl-CoA + H2O  =  3-hydroxypropionyl-CoA	beta-alanine biosynthesis II
zeaxanthin		C40 H56 O2 	CC(C=CC=C(C)C=CC1(C(C)(C)CC(O)CC(C)=1))=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CC(O)CC(C)=2)		RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	carotenoid biosynthesis
zeaxanthin		C40 H56 O2 	CC(C=CC=C(C)C=CC1(C(C)(C)CC(O)CC(C)=1))=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CC(O)CC(C)=2)		RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	xanthophyll cycle
zeaxanthin		C40 H56 O2 	CC(C=CC=C(C)C=CC1(C(C)(C)CC(O)CC(C)=1))=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CC(O)CC(C)=2)		RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	carotenoid biosynthesis
zeaxanthin		C40 H56 O2 	CC(C=CC=C(C)C=CC1(C(C)(C)CC(O)CC(C)=1))=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CC(O)CC(C)=2)		RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	xanthophyll cycle
zeaxanthin		C40 H56 O2 	CC(C=CC=C(C)C=CC1(C(C)(C)CC(O)CC(C)=1))=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CC(O)CC(C)=2)		RXN1F-152	beta-carotene + 2 H2O  =  zeaxanthin	carotenoid biosynthesis
antheraxanthin		C40 H56 O3 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC3(C(C)(C)CC(O)CC(C)=3)		RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	carotenoid biosynthesis
antheraxanthin		C40 H56 O3 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC3(C(C)(C)CC(O)CC(C)=3)		RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	xanthophyll cycle
antheraxanthin		C40 H56 O3 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC3(C(C)(C)CC(O)CC(C)=3)		RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	carotenoid biosynthesis
antheraxanthin		C40 H56 O3 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC3(C(C)(C)CC(O)CC(C)=3)		RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	xanthophyll cycle
antheraxanthin		C40 H56 O3 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC3(C(C)(C)CC(O)CC(C)=3)		RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	carotenoid biosynthesis
antheraxanthin		C40 H56 O3 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC3(C(C)(C)CC(O)CC(C)=3)		RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	xanthophyll cycle
antheraxanthin		C40 H56 O3 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC3(C(C)(C)CC(O)CC(C)=3)		RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	carotenoid biosynthesis
antheraxanthin		C40 H56 O3 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC3(C(C)(C)CC(O)CC(C)=3)		RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	xanthophyll cycle
a fatty alcohol					RXN-4444	a fatty alcohol + O2  =  a fatty aldehyde + H2O2	fatty acid omega-oxidation
a fatty alcohol					RXN-4443	an alkane  =  a fatty alcohol	fatty acid omega-oxidation
ent-kaurenoate	<i>ent</i>-kaur-16-en-19-oate*ent-kaurenoic acid	C20 H30 O2 	CC3(C(O)=O)(CCCC4(C)([CH]1(C2(CC(CC1)C(C2)=C)(CC[CH]34))))		1.14.13.79	ent-kaurenoate + O2 + NADPH  =  ent-7-alpha-hydroxykaurenoate + H2O + NADP+	GA12 biosynthesis
ent-kaurenoate	<i>ent</i>-kaur-16-en-19-oate*ent-kaurenoic acid	C20 H30 O2 	CC3(C(O)=O)(CCCC4(C)([CH]1(C2(CC(CC1)C(C2)=C)(CC[CH]34))))		1.14.13.78	ent-kaur-16-en-19-al + NADPH + H+ + O2  =  ent-kaurenoate + NADP+ + H2O	GA12 biosynthesis
violaxanthin		C40 H56 O4 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC34(C(C)(O3)CC(O)CC(C)(C)4)		RXN1F-155	violaxanthin  =  neoxanthin	carotenoid biosynthesis
violaxanthin		C40 H56 O4 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC34(C(C)(O3)CC(O)CC(C)(C)4)		RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	carotenoid biosynthesis
violaxanthin		C40 H56 O4 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC34(C(C)(O3)CC(O)CC(C)(C)4)		RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	xanthophyll cycle
violaxanthin		C40 H56 O4 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC34(C(C)(O3)CC(O)CC(C)(C)4)		RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	carotenoid biosynthesis
violaxanthin		C40 H56 O4 	CC(C=CC=C(C)C=CC12(C(C)(O1)CC(O)CC(C)(C)2))=CC=CC=C(C)C=CC=C(C)C=CC34(C(C)(O3)CC(O)CC(C)(C)4)		RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	xanthophyll cycle
GA9	GA9*gibberellin A9*gibberellin A<sub>9</sub>	C19 H24 O4 	C=C5(C1(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCCC(C)3C(O4)=O)))(C5)))		1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA4 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA9	GA9*gibberellin A9*gibberellin A<sub>9</sub>	C19 H24 O4 	C=C5(C1(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCCC(C)3C(O4)=O)))(C5)))		1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA51 + succinate + CO2	gibberellin inactivation
GA9	GA9*gibberellin A9*gibberellin A<sub>9</sub>	C19 H24 O4 	C=C5(C1(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCCC(C)3C(O4)=O)))(C5)))		1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA9 + succinate + 2 CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
neoxanthin		C40 H56 O4 	CC(C=CC=C(C)C=C=C1(C(C)(C)CC(O)CC(C)(O)1))=CC=CC=C(C)C=CC=C(C)C=CC23(C(C)(O2)CC(O)CC(C)(C)3)		RXN-698	neoxanthin + O2  =  xanthoxin + C25-allenic-apo-aldehyde	abscisic acid biosynthesis
neoxanthin		C40 H56 O4 	CC(C=CC=C(C)C=C=C1(C(C)(C)CC(O)CC(C)(O)1))=CC=CC=C(C)C=CC=C(C)C=CC23(C(C)(O2)CC(O)CC(C)(C)3)		RXN1F-155	violaxanthin  =  neoxanthin	carotenoid biosynthesis
benzyl alcohol	&alpha;-hydroxytoluene*benzenemethanol*phenylmethanol*phenylcarbinol*hydroxymethylbenzene	C7 H8 O1 	C(O)c1(ccccc1)	CAS:100-51-6	2.3.1.84	benzyl alcohol + acetyl-CoA  =  benzylacetate + coenzyme A	volatile benzenoid ester biosynthesis
benzyl alcohol	&alpha;-hydroxytoluene*benzenemethanol*phenylmethanol*phenylcarbinol*hydroxymethylbenzene	C7 H8 O1 	C(O)c1(ccccc1)	CAS:100-51-6	RXN-6724	benzyl alcohol + benzoyl-CoA  =  benzylbenzoate + coenzyme A	volatile benzenoid ester biosynthesis
ent-7-alpha-hydroxykaurenoate	ent-7-&alpha;-hydroxykaurenoic acid*<i>ent</i>-7&alpha;-hydroxykaur-16-en-19-oate*ent-7-alpha-hydroxykaurenoic acid*7-hydroxy-kaurenoic acid	C20 H30 O3 	CC3(C(O)=O)(CCCC4(C)([CH]1(C2(CC(CC1)C(C2)=C)(C(O)C[CH]34))))		1.14.13.79	ent-7-alpha-hydroxykaurenoate + NADPH + H+ + O2  =  GA12-aldehyde + NADP+ + 2 H2O	GA12 biosynthesis
ent-7-alpha-hydroxykaurenoate	ent-7-&alpha;-hydroxykaurenoic acid*<i>ent</i>-7&alpha;-hydroxykaur-16-en-19-oate*ent-7-alpha-hydroxykaurenoic acid*7-hydroxy-kaurenoic acid	C20 H30 O3 	CC3(C(O)=O)(CCCC4(C)([CH]1(C2(CC(CC1)C(C2)=C)(C(O)C[CH]34))))		1.14.13.79	ent-kaurenoate + O2 + NADPH  =  ent-7-alpha-hydroxykaurenoate + H2O + NADP+	GA12 biosynthesis
GA4	GA4*gibberellin A4*gibberellin A<sub>4</sub>	C19 H24 O5 	C=C5(C1(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCC(O)C(C)3C(O4)=O)))(C5)))		1.14.11.-	GA4 + alpha-ketoglutarate + O2  =  GA34 + succinate + CO2	gibberellin inactivation
GA4	GA4*gibberellin A4*gibberellin A<sub>4</sub>	C19 H24 O5 	C=C5(C1(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCC(O)C(C)3C(O4)=O)))(C5)))		1.14.11.-	GA36 + O2 + alpha-ketoglutarate  =  GA4 + succinate + 2 CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
GA4	GA4*gibberellin A4*gibberellin A<sub>4</sub>	C19 H24 O5 	C=C5(C1(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCC(O)C(C)3C(O4)=O)))(C5)))		1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA4 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
GA12-aldehyde	GA12-aldehyde*gibberellin A12-aldehyde*gibberellin A<sub>12</sub>-aldehyde	C20 H28 O3 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C=O)(CC(CC3)C(C4)=C))))		1.14.13.79	GA12-aldehyde + NADPH + O2  =  GA12 + NADP+ + H2O	GA12 biosynthesis
GA12-aldehyde	GA12-aldehyde*gibberellin A12-aldehyde*gibberellin A<sub>12</sub>-aldehyde	C20 H28 O3 	CC1(C(O)=O)([CH]2(C(C)(CCC1)[CH]3(C4(C2C=O)(CC(CC3)C(C4)=C))))		1.14.13.79	ent-7-alpha-hydroxykaurenoate + NADPH + H+ + O2  =  GA12-aldehyde + NADP+ + 2 H2O	GA12 biosynthesis
4alpha-methylfecosterol	4&alpha;-methyl-5&alpha;-ergosta-8,24-dien-3&beta;-ol	C29 H48 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(=C(CC2)C4([CH](CC3)C(C)C(O)CC4)(C))))		5.3.3.5	4alpha-methylfecosterol  =  24-methylenelophenol	sterol biosynthesis
4alpha-methylfecosterol	4&alpha;-methyl-5&alpha;-ergosta-8,24-dien-3&beta;-ol	C29 H48 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(=C(CC2)C4([CH](CC3)C(C)C(O)CC4)(C))))		1.3.1.70	(4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol + 2 NADPH  =  4alpha-methylfecosterol + 2 NADP+	sterol biosynthesis
GA1	GA1*gibberellin A<sub>1</sub>*gibberellin A1	C19 H24 O6 	C=C5(C1(O)(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCC(O)C(C)3C(O4)=O)))(C5)))		1.14.11.13	GA1 + alpha-ketoglutarate + O2  =  GA8 + succinate + CO2	gibberellin inactivation
GA1	GA1*gibberellin A<sub>1</sub>*gibberellin A1	C19 H24 O6 	C=C5(C1(O)(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCC(O)C(C)3C(O4)=O)))(C5)))		1.14.11.15	GA20 + alpha-ketoglutarate + O2  =  GA1 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
hydrogen cyanide	cyanide*hydrocyanic acid	C1 H1 N1 	[CH]#N	LIGAND-CPD:C01326*CAS:57-12-5	1.14.17.4	L-ascorbate + 1-aminocyclopropane-1-carboxylate + O2  =  2 H2O + ethene + L-dehydro-ascorbate + hydrogen cyanide + CO2	ethylene biosynthesis from methionine
beta-L-arabinose 1-phosphate	&beta;-L-arabinose 1-P	C5 H11 O8 P1 	C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)		RXN-7401	beta-L-arabinose 1-phosphate + UTP  =  UDP-L-arabinose + pyrophosphate	UDP-L-arabinose biosynthesis II (from L-arabinose)
beta-L-arabinose 1-phosphate	&beta;-L-arabinose 1-P	C5 H11 O8 P1 	C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)		2.7.1.46	L-arabinose + ATP  =  beta-L-arabinose 1-phosphate + ADP	UDP-L-arabinose biosynthesis II (from L-arabinose)
5-phospho-beta-D-ribosyl-amine	5-phospho-&beta;-D-ribosyl-amine*5-P-&beta;-D-ribosyl-amine*PRA*5-phosphoribosylamine	C5 H12 N1 O7 P1 	C(OP(O)(=O)O)[CH]1([CH](O)[CH](O)[CH](O1)N)		6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides II
5-phospho-beta-D-ribosyl-amine	5-phospho-&beta;-D-ribosyl-amine*5-P-&beta;-D-ribosyl-amine*PRA*5-phosphoribosylamine	C5 H12 N1 O7 P1 	C(OP(O)(=O)O)[CH]1([CH](O)[CH](O)[CH](O1)N)		6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides I
5-phospho-beta-D-ribosyl-amine	5-phospho-&beta;-D-ribosyl-amine*5-P-&beta;-D-ribosyl-amine*PRA*5-phosphoribosylamine	C5 H12 N1 O7 P1 	C(OP(O)(=O)O)[CH]1([CH](O)[CH](O)[CH](O1)N)		2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides II
5-phospho-beta-D-ribosyl-amine	5-phospho-&beta;-D-ribosyl-amine*5-P-&beta;-D-ribosyl-amine*PRA*5-phosphoribosylamine	C5 H12 N1 O7 P1 	C(OP(O)(=O)O)[CH]1([CH](O)[CH](O)[CH](O1)N)		2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides I
2-hydroxy-3-keto-5-methylthio-1-phosphopentene	1-phosphoryloxyl-2-hydroxy-3-keto-5-methylthiopentene	C6 H11 O6 P1 S1 	C(OP(O)(O)=O)=C(O)C(=O)CCSC		R83-RXN	2-hydroxy-3-keto-5-methylthio-1-phosphopentene + H2O  =  1,2-dihydroxy-3-keto-5-methylthiopentene + phosphate	methionine salvage pathway
2-hydroxy-3-keto-5-methylthio-1-phosphopentene	1-phosphoryloxyl-2-hydroxy-3-keto-5-methylthiopentene	C6 H11 O6 P1 S1 	C(OP(O)(O)=O)=C(O)C(=O)CCSC		R82-RXN	2,3-diketo-5-methylthio-1-phosphopentane  =  2-hydroxy-3-keto-5-methylthio-1-phosphopentene	methionine salvage pathway
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	2.5.1.10	geranyl-PP + delta3-isopentenyl-PP  =  pyrophosphate + trans, trans-farnesyl diphosphate	polyisoprenoid biosynthesis
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	2.5.1.10	geranyl-PP + delta3-isopentenyl-PP  =  pyrophosphate + trans, trans-farnesyl diphosphate	mevalonate pathway
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	2.5.1.29	delta3-isopentenyl-PP + trans, trans-farnesyl diphosphate  =  geranylgeranyl-PP + pyrophosphate	ent-kaurene biosynthesis
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	2.5.1.-	trans-polyisoprenyln-PP + delta3-isopentenyl-PP  =  trans-polyisoprenyln+1-PP + pyrophosphate	polyisoprenoid biosynthesis
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	UPPSYN-RXN	cis,trans-polyisoprenyln-PP + delta3-isopentenyl-PP  =  pyrophosphate + cis,trans-polyisoprenyln+1-PP	polyisoprenoid biosynthesis
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	2.5.1.1	dimethylallyl-pyrophosphate + delta3-isopentenyl-PP  =  pyrophosphate + geranyl-PP	polyisoprenoid biosynthesis
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	2.5.1.1	dimethylallyl-pyrophosphate + delta3-isopentenyl-PP  =  pyrophosphate + geranyl-PP	mevalonate pathway
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	5.3.3.2	delta3-isopentenyl-PP  =  dimethylallyl-pyrophosphate	polyisoprenoid biosynthesis
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	5.3.3.2	delta3-isopentenyl-PP  =  dimethylallyl-pyrophosphate	mevalonate pathway
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	1.17.1.2	1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + 2 H+  =  delta3-isopentenyl-PP + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
delta3-isopentenyl-PP	isopentenyl-pp*isopentenyl diphosphate*IPP*delta(3)-isopentenyl-PP*isopentenyl pyrophosphate	C5 H12 O7 P2 	CC(=C)CCOP(O)(=O)OP(O)(=O)O	LIGAND-CPD:C00129*CAS:358-71-4	4.1.1.33	mevalonate-5-PP + ATP  =  phosphate + CO2 + delta3-isopentenyl-PP + ADP	mevalonate pathway
L-galactono-1,4-lactone	L-galactono-&gamma;-lactone	C6 H10 O6 	C1(OC(C(O)CO)C(O)C(O)1)(=O)	CAS:1668-08-2	1.3.2.3	2 ferricytochrome c + L-galactono-1,4-lactone  =  2 ferrocytochrome c + L-ascorbate	ascorbate biosynthesis
L-galactono-1,4-lactone	L-galactono-&gamma;-lactone	C6 H10 O6 	C1(OC(C(O)CO)C(O)C(O)1)(=O)	CAS:1668-08-2	1.1.1.-	L-galactose + NAD+  =  L-galactono-1,4-lactone + NADH	ascorbate biosynthesis
1,4-dihydroxy-2-naphthoate	DHNA	C11 H8 O4 	C(=O)(O)c1(c(O)c2(c(c(O)c1)cccc2))	LIGAND-CPD:C03657	DMK-RXN	1,4-dihydroxy-2-naphthoate + octaprenyl diphosphate  =  demethylmenaquinone-8 + pyrophosphate + CO2	menaquinone biosynthesis
1,4-dihydroxy-2-naphthoate	DHNA	C11 H8 O4 	C(=O)(O)c1(c(O)c2(c(c(O)c1)cccc2))	LIGAND-CPD:C03657	RXN-7568	1,4-dihydroxy-2-naphthoate + phytyl pyrophosphate  =  demethylphylloquinone + CO2 + pyrophosphate	phylloquinone biosynthesis
1,4-dihydroxy-2-naphthoate	DHNA	C11 H8 O4 	C(=O)(O)c1(c(O)c2(c(c(O)c1)cccc2))	LIGAND-CPD:C03657	4.1.3.36	4-(2'-carboxyphenyl)-4-oxobutyryl-CoA  =  coenzyme A + 1,4-dihydroxy-2-naphthoate	phylloquinone biosynthesis
1,4-dihydroxy-2-naphthoate	DHNA	C11 H8 O4 	C(=O)(O)c1(c(O)c2(c(c(O)c1)cccc2))	LIGAND-CPD:C03657	4.1.3.36	O-succinylbenzoyl-CoA  =  coenzyme A + 1,4-dihydroxy-2-naphthoate	menaquinone biosynthesis
dihydrozeatin	2-Methyl-4-(1H-purin-6-ylamino)butan-1-ol*N6-(4-Hydroxyisopentanyl)adenine	C10 H15 N5 O1 	C[CH](CO)CCNc2(c1(c([nH]cn1)ncn2))	CAS:23599-75-9	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-7-N-dihydrozeatin + UDP	cytokinins 7-N-glucoside biosynthesis
dihydrozeatin	2-Methyl-4-(1H-purin-6-ylamino)butan-1-ol*N6-(4-Hydroxyisopentanyl)adenine	C10 H15 N5 O1 	C[CH](CO)CCNc2(c1(c([nH]cn1)ncn2))	CAS:23599-75-9	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
dihydrozeatin	2-Methyl-4-(1H-purin-6-ylamino)butan-1-ol*N6-(4-Hydroxyisopentanyl)adenine	C10 H15 N5 O1 	C[CH](CO)CCNc2(c1(c([nH]cn1)ncn2))	CAS:23599-75-9	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
N-acetylglucosaminyl-diphosphodolichol	<i>N</i>-acetyl-D-glucosaminyldiphosphodolichol	C88 H147 N1 O12 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(O)C(O1)CO)		2.4.1.141	N-acetylglucosaminyl-diphosphodolichol + UDP-N-acetyl-D-glucosamine  =  (N-acetylglucosaminyl)2-diphosphodolichol + UDP	dolichyl-diphosphooligosaccharide biosynthesis
N-acetylglucosaminyl-diphosphodolichol	<i>N</i>-acetyl-D-glucosaminyldiphosphodolichol	C88 H147 N1 O12 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(O)C(O1)CO)		2.7.8.15	dolichyl-phosphate + UDP-N-acetyl-D-glucosamine  =  N-acetylglucosaminyl-diphosphodolichol + UMP	dolichyl-diphosphooligosaccharide biosynthesis
sinapoyl-(S)-malate		C15 H16 O9 	C(=O)(O)C=Cc1(cc(OC)c(c(c1)OC)OC(=O)C(O)CC(O)=O)	PUBCHEM:439836	2.3.1.92	1-O-sinapoyl-beta-D-glucose + malate  =  sinapoyl-(S)-malate + beta-D-glucose	sinapate ester biosynthesis
an amino acid	amino acid*L-amino acid	C2 H4 N1 O2 R1 			2.6.1.-	2-oxo-5-methylthiopentanoic-acid + an amino acid  =  homomethionine + a 2-oxo acid	homomethionine biosynthesis
an amino acid	amino acid*L-amino acid	C2 H4 N1 O2 R1 			2.6.1.5	2-oxo-4-methylthiobutanoic acid + an amino acid  =  L-methionine + keto acid	methionine salvage pathway
an amino acid	amino acid*L-amino acid	C2 H4 N1 O2 R1 			2.6.1.-	L-methionine + a 2-oxo acid  =  2-oxo-4-methylthiobutanoic acid + an amino acid	homomethionine biosynthesis
GA20	GA20*gibberellin A20*gibberellin A<sub>20</sub>	C19 H24 O5 	C=C5(C1(O)(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCCC(C)3C(O4)=O)))(C5)))		1.14.11.15	GA20 + alpha-ketoglutarate + O2  =  GA1 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
GA20	GA20*gibberellin A20*gibberellin A<sub>20</sub>	C19 H24 O5 	C=C5(C1(O)(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCCC(C)3C(O4)=O)))(C5)))		1.14.11.-	GA20 + alpha-ketoglutarate + O2  =  GA29 + succinate + CO2	gibberellin inactivation
GA20	GA20*gibberellin A20*gibberellin A<sub>20</sub>	C19 H24 O5 	C=C5(C1(O)(CC2(C(C(O)=O)[CH]3(C4([CH](CC1)2)(CCCC(C)3C(O4)=O)))(C5)))		1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA20 + succinate + 2 CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
cis-3-hexenol		C6 H12 O1 	C(O)CC=CCC	NCI:74451*CAS:928-96-1	RXN-1347	cis-3-hexenal  =  cis-3-hexenol	lipoxygenase pathway
ribose-1-phosphate	D-ribose-1-phosphate*&alpha;-D-ribose-1P*&alpha;-D-ribofuranose 1-phosphate*&alpha;-D-ribose-1-phosphate	C5 H11 O8 P1 	C(O)[CH]1(O[CH](OP(O)(O)=O)[CH](O)[CH](O)1)	CAS:14075-00-4	5.4.2.7	ribose-1-phosphate  =  D-ribose-5-phosphate	(deoxy)ribose phosphate degradation
ribose-1-phosphate	D-ribose-1-phosphate*&alpha;-D-ribose-1P*&alpha;-D-ribofuranose 1-phosphate*&alpha;-D-ribose-1-phosphate	C5 H11 O8 P1 	C(O)[CH]1(O[CH](OP(O)(O)=O)[CH](O)[CH](O)1)	CAS:14075-00-4	2.4.2.3	phosphate + uridine  =  ribose-1-phosphate + uracil	(deoxy)ribose phosphate degradation
ribose-1-phosphate	D-ribose-1-phosphate*&alpha;-D-ribose-1P*&alpha;-D-ribofuranose 1-phosphate*&alpha;-D-ribose-1-phosphate	C5 H11 O8 P1 	C(O)[CH]1(O[CH](OP(O)(O)=O)[CH](O)[CH](O)1)	CAS:14075-00-4	XANTHOSINEPHOSPHORY-RXN	xanthosine + phosphate  =  ribose-1-phosphate + xanthine	ureide biosynthesis
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	1.2.1.59	NAD(P)H + 1,3-diphosphateglycerate  =  NAD(P)+ + D-glyceraldehyde-3-phosphate + phosphate	Calvin cycle
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	sucrose degradation to ethanol and lactate (anaerobic)
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis I
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis II
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	gluconeogenesis
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glyceraldehyde 3-phosphate degradation
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	Calvin cycle
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	sucrose degradation to ethanol and lactate (anaerobic)
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glycolysis I
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glycolysis II
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	gluconeogenesis
1,3-diphosphateglycerate	glycerate 1,3-diphosphate*3-phospho-D-glyceroyl-phosphate*3-phosphoglyceroyl-P*P-glyceroyl-P*phosphoglyceroyl-P*3-phosphoglyceroyl-phosphate*3-P-glyceroyl-P*DPG*13-DPG*glycerate 1,3-bisphosphate*1,3-biphosphoglycerate	C3 H8 O10 P2 	C(OP(O)(O)=O)(=O)C(O)COP(O)(O)=O	CAS:1981-49-3	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glyceraldehyde 3-phosphate degradation
quinate	quinic acid	C7 H12 O6 	C(=O)(O)C1([CH2][CH](O)[CH](O)[CH](O)[CH2]1)(O)	LIGAND:C00296*CAS:77-95-2	2.3.1.133	quinate + coumaroyl-CoA  =  4-coumaroylquinate + coenzyme A	lignin biosynthesis
quinate	quinic acid	C7 H12 O6 	C(=O)(O)C1([CH2][CH](O)[CH](O)[CH](O)[CH2]1)(O)	LIGAND:C00296*CAS:77-95-2	2.3.1.133	caffeoylquinate + coenzyme A  =  caffeoyl-CoA + quinate	lignin biosynthesis
nicotinamide	6-aminonicotinamide*vitamin PP*niacinamide	C6 H6 N2 O1 	c1(ccc(cn1)C(N)=O)	LIGAND:C00153*CAS:98-92-0	3.5.1.19	nicotinamide + H2O  =  NH3 + nicotinate	pyridine nucleotide cycling
nicotinamide	6-aminonicotinamide*vitamin PP*niacinamide	C6 H6 N2 O1 	c1(ccc(cn1)C(N)=O)	LIGAND:C00153*CAS:98-92-0	3.5.1.4	nicotinamide + H2O  =  NH3 + nicotinate	aldoxime degradation
nicotinamide	6-aminonicotinamide*vitamin PP*niacinamide	C6 H6 N2 O1 	c1(ccc(cn1)C(N)=O)	LIGAND:C00153*CAS:98-92-0	4.2.1.84	3-cyanopyridine + H2O  =  nicotinamide	aldoxime degradation
nicotinamide	6-aminonicotinamide*vitamin PP*niacinamide	C6 H6 N2 O1 	c1(ccc(cn1)C(N)=O)	LIGAND:C00153*CAS:98-92-0	3.2.2.5	H2O + NAD+  =  adenosine diphosphate ribose + nicotinamide	pyridine nucleotide cycling
nicotinamide	6-aminonicotinamide*vitamin PP*niacinamide	C6 H6 N2 O1 	c1(ccc(cn1)C(N)=O)	LIGAND:C00153*CAS:98-92-0	3.2.2.14	H2O + nicotinamide mononucleotide  =  D-ribose-5-phosphate + nicotinamide	pyridine nucleotide cycling
glutaconyl-CoA	glutaconyl-coenzyme A*pent-2-enoyl-CoA*glutaconyl-1-CoA*4-carboxybut-2-enoyl-CoA	C26 H40 N7 O19 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=CCC(=O)O)COP(O)(=O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	CAS:6712-05-6	4.1.1.70	glutaconyl-CoA  =  CO2 + crotonyl-CoA	lysine degradation II
glutaconyl-CoA	glutaconyl-coenzyme A*pent-2-enoyl-CoA*glutaconyl-1-CoA*4-carboxybut-2-enoyl-CoA	C26 H40 N7 O19 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=CCC(=O)O)COP(O)(=O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	CAS:6712-05-6	4.1.1.70	glutaconyl-CoA  =  CO2 + crotonyl-CoA	tryptophan degradation
glutaconyl-CoA	glutaconyl-coenzyme A*pent-2-enoyl-CoA*glutaconyl-1-CoA*4-carboxybut-2-enoyl-CoA	C26 H40 N7 O19 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=CCC(=O)O)COP(O)(=O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	CAS:6712-05-6	GLUTARYL-COA-DEHYDROG-RXN	glutaryl-CoA + FAD  =  glutaconyl-CoA + FADH2	lysine degradation II
glutaconyl-CoA	glutaconyl-coenzyme A*pent-2-enoyl-CoA*glutaconyl-1-CoA*4-carboxybut-2-enoyl-CoA	C26 H40 N7 O19 P3 S1 	CC(C)(C(O)C(=O)NCCC(=O)NCCSC(=O)C=CCC(=O)O)COP(O)(=O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	CAS:6712-05-6	GLUTARYL-COA-DEHYDROG-RXN	glutaryl-CoA + FAD  =  glutaconyl-CoA + FADH2	tryptophan degradation
L-arginino-succinate	<i>N</i>-(L-arginino)-succinate*N-(L-arginino)-succinate*arginino-succinate	C10 H18 N4 O6 	C(=O)(O)C(N)CCCNC(=N)NC(C(O)=O)CC(O)=O	CAS:92117-83-4	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis
L-arginino-succinate	<i>N</i>-(L-arginino)-succinate*N-(L-arginino)-succinate*arginino-succinate	C10 H18 N4 O6 	C(=O)(O)C(N)CCCNC(=N)NC(C(O)=O)CC(O)=O	CAS:92117-83-4	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis II (acetyl cycle)
L-arginino-succinate	<i>N</i>-(L-arginino)-succinate*N-(L-arginino)-succinate*arginino-succinate	C10 H18 N4 O6 	C(=O)(O)C(N)CCCNC(=N)NC(C(O)=O)CC(O)=O	CAS:92117-83-4	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis III
L-arginino-succinate	<i>N</i>-(L-arginino)-succinate*N-(L-arginino)-succinate*arginino-succinate	C10 H18 N4 O6 	C(=O)(O)C(N)CCCNC(=N)NC(C(O)=O)CC(O)=O	CAS:92117-83-4	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis
L-arginino-succinate	<i>N</i>-(L-arginino)-succinate*N-(L-arginino)-succinate*arginino-succinate	C10 H18 N4 O6 	C(=O)(O)C(N)CCCNC(=N)NC(C(O)=O)CC(O)=O	CAS:92117-83-4	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis II (acetyl cycle)
L-arginino-succinate	<i>N</i>-(L-arginino)-succinate*N-(L-arginino)-succinate*arginino-succinate	C10 H18 N4 O6 	C(=O)(O)C(N)CCCNC(=N)NC(C(O)=O)CC(O)=O	CAS:92117-83-4	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis III
L-histidyl-tRNAhis	L-HISTIDYL-TRNA(HIS)				6.1.1.21	tRNAhis + L-histidine + ATP  =  L-histidyl-tRNAhis + pyrophosphate + AMP	tRNA charging pathway
L-prolyl-tRNApro	L-PROLYL-TRNA(PRO)				6.1.1.15	L-proline + tRNApro + ATP  =  L-prolyl-tRNApro + pyrophosphate + AMP	tRNA charging pathway
D-myo-inositol (1,2,3,4) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,3,4) tetra<i>kis</i>phosphate*<i>myo</i>-inositol (1,2,3,4) tetra<i>kis</i>phosphate*Ins(1,2,3,4)P<sub>4</sub>*I(1,2,3,4)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		RXN-7302	D-myo-inositol (1,2,3,4) tetrakisphosphate + H2O  =  D-myo-inositol (1,2,3) trisphosphate + phosphate	phytate degradation II
D-myo-inositol (1,2,3,4) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,3,4) tetra<i>kis</i>phosphate*<i>myo</i>-inositol (1,2,3,4) tetra<i>kis</i>phosphate*Ins(1,2,3,4)P<sub>4</sub>*I(1,2,3,4)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		RXN-7303	D-myo-inositol (1,2,3,4) tetrakisphosphate + H2O  =  D-myo-inositol (2,3,4) trisphosphate + phosphate	phytate degradation II
D-myo-inositol (1,2,3,4) tetrakisphosphate	1D-<i>myo</i>-inositol (1,2,3,4) tetra<i>kis</i>phosphate*<i>myo</i>-inositol (1,2,3,4) tetra<i>kis</i>phosphate*Ins(1,2,3,4)P<sub>4</sub>*I(1,2,3,4)P<sub>4</sub>	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		RXN-7301	D-myo-inositol (1,2,3,4,5)-pentakisphosphate + H2O  =  D-myo-inositol (1,2,3,4) tetrakisphosphate + phosphate	phytate degradation II
D-myo-inositol (2,3,4) trisphosphate	1D-<i>myo</i>-inositol (2,3,4) trisphosphate*<i>myo</i>-inositol (2,3,4) trisphosphate*Ins(2,3,4)P<sub>3</sub>*I(2,3,4)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		RXN-7304	D-myo-inositol (2,3,4) trisphosphate + H2O  =  D-myo-inositol (2,4) bisphosphate + phosphate	phytate degradation II
D-myo-inositol (2,3,4) trisphosphate	1D-<i>myo</i>-inositol (2,3,4) trisphosphate*<i>myo</i>-inositol (2,3,4) trisphosphate*Ins(2,3,4)P<sub>3</sub>*I(2,3,4)P<sub>3</sub>	C6 H12 O15 P3 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)		RXN-7303	D-myo-inositol (1,2,3,4) tetrakisphosphate + H2O  =  D-myo-inositol (2,3,4) trisphosphate + phosphate	phytate degradation II
NAD(P)H					1.1.1.2	NAD(P)H + a fatty aldehyde  =  NAD(P)+ + a primary alcohol	epicuticular wax biosynthesis
NAD(P)H					1.2.1.50	NAD(P)H + very-long-chain-fatty-acyl-CoA  =  NAD(P)+ + a fatty aldehyde	epicuticular wax biosynthesis
NAD(P)H					2.5.1.21	presqualene diphosphate + NAD(P)H  =  squalene + NAD(P)+ + pyrophosphate	sterol biosynthesis
NAD(P)H					1.2.1.16	succinate semialdehyde + NAD(P)H  =  4-hydroxybutyrate + NAD(P)+	glutamate degradation II
NAD(P)H					1.4.1.3	NH3 + NAD(P)H + alpha-ketoglutarate  =  NAD(P)+ + H2O + L-glutamate	arginine biosynthesis III
NAD(P)H					1.-.-.-	NAD(P)+ + coproporphyrinogen III  =  protoporphyrinogen + NAD(P)H + 2 CO2	biosynthesis of proto- and siroheme
NAD(P)H					1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	superpathway of gluconate degradation
NAD(P)H					1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	oxidative branch of the pentose phosphate pathway
NAD(P)H					1.1.1.49	beta-D-glucose-6-phosphate + NAD(P)+  =  D-glucono-delta-lactone-6-phosphate + NAD(P)H	oxidative branch of the pentose phosphate pathway
NAD(P)H					1.3.1.26	L-2,3-dihydrodipicolinate + NAD(P)H + H+  =  L-2,3,4,5-tetrahydrodipicolinate + NAD(P)+	lysine biosynthesis
NAD(P)H					1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis
NAD(P)H					1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis I
NAD(P)H					1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	proline biosynthesis
NAD(P)H					1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	arginine degradation II
NAD(P)H					RXN-924	2 NAD(P)+ + 2 H+ + 4 e-  =  2 NAD(P)H	photosynthesis, light reaction
NAD(P)H					1.5.1.12	L-delta1-pyrroline-5-carboxylate + NAD(P)+ + H2O  =  L-glutamate + NAD(P)H + H+	proline degradation
NAD(P)H					1.2.1.3	3-aminopropionaldehyde + NAD(P)+ + H2O  =  beta-alanine + NAD(P)H	beta-alanine biosynthesis I
NAD(P)H					1.1.1.51	campesterol + NAD(P)+  =  campest-4-en-3-one + NAD(P)H	brassinosteroid biosynthesis III
NAD(P)H					1.2.1.59	NAD(P)H + 1,3-diphosphateglycerate  =  NAD(P)+ + D-glyceraldehyde-3-phosphate + phosphate	Calvin cycle
D-myo-inositol (2,4) bisphosphate	1D-<i>myo</i>-inositol (2,4) bisphosphate*<i>myo</i>-inositol (2,4) bisphosphate*Ins(2,4)P<sub>2</sub>*I(2,4)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C1OP(O)([O-1])=O)(O)		RXN-7305	D-myo-inositol (2,4) bisphosphate + H2O  =  D-myo-inositol (2) monophosphate + phosphate	phytate degradation II
D-myo-inositol (2,4) bisphosphate	1D-<i>myo</i>-inositol (2,4) bisphosphate*<i>myo</i>-inositol (2,4) bisphosphate*Ins(2,4)P<sub>2</sub>*I(2,4)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C1OP(O)([O-1])=O)(O)		RXN-7304	D-myo-inositol (2,3,4) trisphosphate + H2O  =  D-myo-inositol (2,4) bisphosphate + phosphate	phytate degradation II
tRNAasp	TRNA(ASP)				6.1.1.12	tRNAasp + L-aspartate + ATP  =  L-aspartyl-tRNAasp + pyrophosphate + AMP	tRNA charging pathway
1,4-alpha-D-galacturonosyl	1,4-&alpha;-poly-D-galacturonate*homogalacturonan	C18 H26 O19 	C1(OC(C(=O)O)C(O)C(O)C(O)1)OC2(C(O)C(O)C(OC2C(O)=O)OC3(C(C(O)=O)OC(O)C(O)C(O)3))		3.1.1.11	methylesterified 1,4-alpha-D-galacturonosyl + H2O  =  1,4-alpha-D-galacturonosyl + methanol	homogalacturonan degradation
1,4-alpha-D-galacturonosyl	1,4-&alpha;-poly-D-galacturonate*homogalacturonan	C18 H26 O19 	C1(OC(C(=O)O)C(O)C(O)C(O)1)OC2(C(O)C(O)C(OC2C(O)=O)OC3(C(C(O)=O)OC(O)C(O)C(O)3))		3.2.1.15	1,4-alpha-D-galacturonosyl  =  1,4-alpha-D-galacturonosyl	homogalacturonan degradation
Starch					3.2.1.1	Starch  =  Large-branched-glucans	starch degradation
Starch					2.4.1.18	1,4-alpha-D-glucan  =  Starch	starch biosynthesis
deoxyribose-1-phosphate	2-deoxy-D-ribose-1-phosphate*2-deoxy-&alpha;-D-ribose 1-phosphate	C5 H11 O7 P1 	[CH]1(O[CH](CO)[CH](O)[CH2]1)(OP(O)(O)=O)	CAS:17210-42-3	5.4.2.7	deoxyribose-1-phosphate  =  deoxyribose-5-phosphate	(deoxy)ribose phosphate degradation
deoxyribose-1-phosphate	2-deoxy-D-ribose-1-phosphate*2-deoxy-&alpha;-D-ribose 1-phosphate	C5 H11 O7 P1 	[CH]1(O[CH](CO)[CH](O)[CH2]1)(OP(O)(O)=O)	CAS:17210-42-3	2.4.2.4	phosphate + thymidine  =  deoxyribose-1-phosphate + thymine	(deoxy)ribose phosphate degradation
deoxyribose-1-phosphate	2-deoxy-D-ribose-1-phosphate*2-deoxy-&alpha;-D-ribose 1-phosphate	C5 H11 O7 P1 	[CH]1(O[CH](CO)[CH](O)[CH2]1)(OP(O)(O)=O)	CAS:17210-42-3	URA-PHOSPH-RXN	phosphate + deoxyuridine  =  deoxyribose-1-phosphate + uracil	(deoxy)ribose phosphate degradation
O-acetyl-L-serine	O3-acetyl-L-serine*acetylserine*O-acetylserine	C5 H9 N1 O4 	C([CH](N)C(O)=O)OC(C)=O	CAS:66638-22-0	4.2.99.8	O-acetyl-L-serine + H2S  =  L-cysteine + acetate	cysteine biosynthesis
O-acetyl-L-serine	O3-acetyl-L-serine*acetylserine*O-acetylserine	C5 H9 N1 O4 	C([CH](N)C(O)=O)OC(C)=O	CAS:66638-22-0	4.2.99.8	O-acetyl-L-serine + H2S  =  L-cysteine + acetate	sulfate assimilation
O-acetyl-L-serine	O3-acetyl-L-serine*acetylserine*O-acetylserine	C5 H9 N1 O4 	C([CH](N)C(O)=O)OC(C)=O	CAS:66638-22-0	2.3.1.30	L-serine + acetyl-CoA  =  O-acetyl-L-serine + coenzyme A	cysteine biosynthesis
O-acetyl-L-serine	O3-acetyl-L-serine*acetylserine*O-acetylserine	C5 H9 N1 O4 	C([CH](N)C(O)=O)OC(C)=O	CAS:66638-22-0	2.3.1.30	L-serine + acetyl-CoA  =  O-acetyl-L-serine + coenzyme A	sulfate assimilation
4-methoxy-3-indolylmethyl-glucosinolate	4-methoxyindol-3-ylmethylglucosinolate*4-methyoxyglucobrassicin	C17 H22 N2 O10 S2 	c1(c(c2(c(OC)cccc([nH]1)2))CC(=NOS(O)(=O)=O)SC3(C(CO)C(O)C(O)C(O3)O))		RXN-2163	4-hydroxy-3-indolylmethyl-glucosinolate  =  4-methoxy-3-indolylmethyl-glucosinolate	glucosinolate biosynthesis from tryptophan
GDP-D-rhamnose	GDP-6-deoxy-D-mannose	C16 H25 N5 O15 P2 	CC1(OC(C(O)C(O)C1O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		1.1.1.187	NADPH + GDP-4-dehydro-6-deoxy-D-mannose  =  NADP+ + GDP-D-rhamnose	GDP-D-rhamnose biosynthesis
Oxidized Thioredoxin					1.17.4.1	Reduced Thioredoxin + UDP  =  Oxidized Thioredoxin + dUDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
Oxidized Thioredoxin					1.17.4.1	Reduced Thioredoxin + CDP  =  Oxidized Thioredoxin + dCDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
Oxidized Thioredoxin					1.17.4.1	Reduced Thioredoxin + ADP  =  Oxidized Thioredoxin + dADP + H2O	de novo biosynthesis of purine nucleotides I
Oxidized Thioredoxin					1.17.4.1	Reduced Thioredoxin + GDP  =  Oxidized Thioredoxin + dGDP + H2O	de novo biosynthesis of purine nucleotides I
PAPS	3'-phosphoadenylyl-sulfate*phosphoadenosine phosphosulfate*3'-phosphoadenosine-5'-phosphosulfate*5-phosphoadenosine 3-phosphosulfate	C10 H15 N5 O13 P2 S1 	[CH]1(O[CH](C(C(O)1)OP(=O)(O)O)COP(O)(=O)OS(O)(=O)=O)n2(c3(c(nc2)c(N)ncn3))	CAS:482-67-7	2.8.2.-	indolylmethyl-desulfoglucosinolate + PAPS  =  indolylmethyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from tryptophan
PAPS	3'-phosphoadenylyl-sulfate*phosphoadenosine phosphosulfate*3'-phosphoadenosine-5'-phosphosulfate*5-phosphoadenosine 3-phosphosulfate	C10 H15 N5 O13 P2 S1 	[CH]1(O[CH](C(C(O)1)OP(=O)(O)O)COP(O)(=O)OS(O)(=O)=O)n2(c3(c(nc2)c(N)ncn3))	CAS:482-67-7	2.8.2.-	3-methylthiopropyl-desulfoglucosinolate + PAPS  =  3-methylthiopropyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from homomethionine
PAPS	3'-phosphoadenylyl-sulfate*phosphoadenosine phosphosulfate*3'-phosphoadenosine-5'-phosphosulfate*5-phosphoadenosine 3-phosphosulfate	C10 H15 N5 O13 P2 S1 	[CH]1(O[CH](C(C(O)1)OP(=O)(O)O)COP(O)(=O)OS(O)(=O)=O)n2(c3(c(nc2)c(N)ncn3))	CAS:482-67-7	2.8.2.-	benzyl-desulfoglucosinolate + PAPS  =  benzyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from phenylalanine
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose degradation
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose degradation to ethanol and lactate (anaerobic)
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	colanic acid building blocks biosynthesis
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	galactose degradation II
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	galactose degradation I
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	sucrose biosynthesis
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.9	alpha-D-glucose-1-phosphate + UTP  =  UDP-D-glucose + pyrophosphate	UDP-glucose conversion
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	5.4.2.2	alpha-D-glucose-1-phosphate  =  alpha-D-glucose-6-phosphate	starch biosynthesis
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	5.4.2.2	alpha-D-glucose-1-phosphate  =  alpha-D-glucose-6-phosphate	sucrose degradation
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	5.4.2.2	alpha-D-glucose-1-phosphate  =  alpha-D-glucose-6-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.27	alpha-D-glucose-1-phosphate + ATP  =  ADP-D-glucose + pyrophosphate	starch biosynthesis
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.12	UDP-D-glucose + alpha-D-galactose-1-phosphate  =  alpha-D-glucose-1-phosphate + UDP-galactose	colanic acid building blocks biosynthesis
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.7.7.12	UDP-D-glucose + alpha-D-galactose-1-phosphate  =  alpha-D-glucose-1-phosphate + UDP-galactose	galactose degradation II
alpha-D-glucose-1-phosphate	glucose 1-phosphate*cori ester*D-glucose 1-phosphate*glucose-1P*&alpha;-glucose-1-phosphate*D-glucose-&alpha;-1-phosphate*&alpha;-D-glucose-1-P*D-glucose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(O)=O)C(O)C(O)C1O)	CAS:59-56-3*LIGAND-CPD:C00103	2.4.1.1	Long-linear-glucans + phosphate  =  alpha-D-glucose-1-phosphate	starch degradation
L-1-phosphatidyl-inositol	1-Phosphatidyl-D-myo-inositol*1-phosphatidylinositol*L-1-phosphatidylinositol*phosphatidyl-inositol*1-Phosphatidyl-1D-myo-inositol*Phosphatidyl-1D-myo-inositol*(3-Phosphatidyl)-1-D-inositol	C11 H17 O13 R2 P1 			2.7.8.11	CDP-diacylglycerol + myo-inositol  =  L-1-phosphatidyl-inositol + CMP	phospholipid biosynthesis
D-myo-inositol (1,2,3,4,5)-pentakisphosphate	1-<i>myo</i>-inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*<i>myo</i>-inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*1L-<i>myo</i>-inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*1D-<i>myo</i>-inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*I(1,2,3,4,5)P<sub>5</sub>*Ins(1,2,3,4,5)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)	LIGAND-CPD:C04579	RXN-7301	D-myo-inositol (1,2,3,4,5)-pentakisphosphate + H2O  =  D-myo-inositol (1,2,3,4) tetrakisphosphate + phosphate	phytate degradation II
D-myo-inositol (1,2,3,4,5)-pentakisphosphate	1-<i>myo</i>-inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*<i>myo</i>-inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*1L-<i>myo</i>-inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*1D-<i>myo</i>-inositol (1,2,3,4,5)-penta<i>kis</i>phosphate*I(1,2,3,4,5)P<sub>5</sub>*Ins(1,2,3,4,5)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)1)(OP(O)([O-1])=O)	LIGAND-CPD:C04579	3.1.3.26	H2O + phytate  =  phosphate + D-myo-inositol (1,2,3,4,5)-pentakisphosphate	phytate degradation II
D-glucono-delta-lactone-6-phosphate	6-phosphogluconolactone*D-6-phosphoglucono-&delta;-lactone*D-6-P-glucono-&delta;-lactone*D-glucono-1,5-lactone-6-phosphate*6-phospho-D-glucono-1,5-lactone*D-6-phospho-glucono-&delta;-lactone	C6 H11 O9 P1 	C(OP(O)(=O)O)[CH]1([CH](O)[CH](O)[CH](O)C(=O)O1)	CAS:2641-81-8	3.1.1.31	D-glucono-delta-lactone-6-phosphate + H2O  =  6-phospho-D-gluconate	oxidative branch of the pentose phosphate pathway
D-glucono-delta-lactone-6-phosphate	6-phosphogluconolactone*D-6-phosphoglucono-&delta;-lactone*D-6-P-glucono-&delta;-lactone*D-glucono-1,5-lactone-6-phosphate*6-phospho-D-glucono-1,5-lactone*D-6-phospho-glucono-&delta;-lactone	C6 H11 O9 P1 	C(OP(O)(=O)O)[CH]1([CH](O)[CH](O)[CH](O)C(=O)O1)	CAS:2641-81-8	1.1.1.49	beta-D-glucose-6-phosphate + NAD(P)+  =  D-glucono-delta-lactone-6-phosphate + NAD(P)H	oxidative branch of the pentose phosphate pathway
2,3-dihydroxy-isovalerate	2,3-dihydroxy-3-methylbutanoate*(R)-2,3-dihydroxy-3-methylbutanoate*&alpha;,&beta;-dihydroxy-isovalerate	C5 H10 O4 	CC(C)(O)C(O)C(O)=O		4.2.1.9	2,3-dihydroxy-isovalerate  =  2-keto-isovalerate + H2O	valine biosynthesis
2,3-dihydroxy-isovalerate	2,3-dihydroxy-3-methylbutanoate*(R)-2,3-dihydroxy-3-methylbutanoate*&alpha;,&beta;-dihydroxy-isovalerate	C5 H10 O4 	CC(C)(O)C(O)C(O)=O		1.1.1.86	2-acetolactate + NADPH  =  2,3-dihydroxy-isovalerate + NADP+	valine biosynthesis
alpha-D-galacturonate 1-phosphate	1-phospho-&alpha;-D-galacturonate*D-galacturonate-1-P*galacturonate-1-phosphate*galacturonate-1-P*D-galacturonate 1-phosphate	C6 H11 O10 P1 	C1(C(O)C(O)C(O)C(O1)C(=O)O)(OP(O)(=O)O)		RXN-3	alpha-D-galacturonate 1-phosphate + UTP  =  UDP-D-galacturonate + pyrophosphate	UDP-D-galacturonate biosynthesis II (from D-galacturonate)
alpha-D-galacturonate 1-phosphate	1-phospho-&alpha;-D-galacturonate*D-galacturonate-1-P*galacturonate-1-phosphate*galacturonate-1-P*D-galacturonate 1-phosphate	C6 H11 O10 P1 	C1(C(O)C(O)C(O)C(O1)C(=O)O)(OP(O)(=O)O)		2.7.1.44	galacturonate + ATP  =  alpha-D-galacturonate 1-phosphate + ADP	UDP-D-galacturonate biosynthesis II (from D-galacturonate)
dCTP	2'-deoxycytidine-5'-triphosphate*deoxycytidine-triphosphate*deoxy-CTP	C9 H16 N3 O13 P3 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:2056-98-6	3.5.4.13	H2O + dCTP  =  NH3 + dUTP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dCTP	2'-deoxycytidine-5'-triphosphate*deoxycytidine-triphosphate*deoxy-CTP	C9 H16 N3 O13 P3 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:2056-98-6	2.7.4.6	dCDP + ATP  =  dCTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
dCTP	2'-deoxycytidine-5'-triphosphate*deoxycytidine-triphosphate*deoxy-CTP	C9 H16 N3 O13 P3 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C2)COP(O)(=O)OP(O)(=O)OP(O)(=O)O))	CAS:2056-98-6	RXN0-723	CTP + reduced flavodoxin  =  dCTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
acylglycerol	Glyceride*Monoglyceride*Monoacylglycerol	C4 H7 O4 R1 			3.1.1.23	H2O + acylglycerol  =  a fatty acid + glycerol	triacylglycerol degradation
acylglycerol	Glyceride*Monoglyceride*Monoacylglycerol	C4 H7 O4 R1 			RXN-1603	2-acylglycerol  =  acylglycerol	triacylglycerol degradation
very-long-chain-fatty-acyl-CoA	acyl-CoA	C22 H35 N7 O17 R1 P3 S1 			1.2.1.50	NAD(P)H + very-long-chain-fatty-acyl-CoA  =  NAD(P)+ + a fatty aldehyde	epicuticular wax biosynthesis
very-long-chain-fatty-acyl-CoA	acyl-CoA	C22 H35 N7 O17 R1 P3 S1 			RXN-1026	fatty-acyl-CoA + malonyl-CoA  =  very-long-chain-fatty-acyl-CoA + CO2	epicuticular wax biosynthesis
D-myo-inositol (1,3,4,6)-tetrakisphosphate	Ins(1,3,4,6)P<sub>4</sub>*inositol (1,3,4,6)-tetra<i>kis</i>phosphate*1D-<i>myo</i> -inositol 1,3,4,6-tetra<i>kis</i>phosphate	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.140	D-myo-inositol (1,3,4,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
D-myo-inositol (1,3,4,6)-tetrakisphosphate	Ins(1,3,4,6)P<sub>4</sub>*inositol (1,3,4,6)-tetra<i>kis</i>phosphate*1D-<i>myo</i> -inositol 1,3,4,6-tetra<i>kis</i>phosphate	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,3,4,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,2,3,4,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
D-myo-inositol (1,3,4,6)-tetrakisphosphate	Ins(1,3,4,6)P<sub>4</sub>*inositol (1,3,4,6)-tetra<i>kis</i>phosphate*1D-<i>myo</i> -inositol 1,3,4,6-tetra<i>kis</i>phosphate	C6 H12 O18 P4 	C1(C(OP(O)([O-1])=O)C(O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.133	D-myo-inositol (1,3,4)-trisphosphate + ATP  =  D-myo-inositol (1,3,4,6)-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
1D-myo-inositol 1,3,4,5-tetrakisphosphate	1D-<i>myo</i>-inositol (1,3,4,5)-tetra<i>kis</i>phosphate*inositol (1,3,4,5)-tetra<i>kis</i>phosphate*Ins(1,3,4,5)P<sub>4</sub>*D-myo-inositol 1,3,4,5-tetrakisphosphate*inositol 1,3,4,5-tetrakisphosphate	C6 H16 O18 P4 	C1(C(O)C(OP(O)(=O)O)C(OP(O)(=O)O)C(C(O)1)OP(=O)(O)O)(OP(O)(=O)O)		2.7.1.-	1D-myo-inositol 1,3,4,5-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
1D-myo-inositol 1,3,4,5-tetrakisphosphate	1D-<i>myo</i>-inositol (1,3,4,5)-tetra<i>kis</i>phosphate*inositol (1,3,4,5)-tetra<i>kis</i>phosphate*Ins(1,3,4,5)P<sub>4</sub>*D-myo-inositol 1,3,4,5-tetrakisphosphate*inositol 1,3,4,5-tetrakisphosphate	C6 H16 O18 P4 	C1(C(O)C(OP(O)(=O)O)C(OP(O)(=O)O)C(C(O)1)OP(=O)(O)O)(OP(O)(=O)O)		2.7.1.139	D-myo-inositol (1,3,4)-trisphosphate + ATP  =  1D-myo-inositol 1,3,4,5-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
adenylo-succinate	N6-(1,2-dicarboxyethyl)-AMP*adenylo-succ	C14 H18 N5 O11 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(ncn3)N[CH](C(O)=O)CC(O)=O)))	CAS:19240-42-7	4.3.2.2	adenylo-succinate  =  fumarate + AMP	de novo biosynthesis of purine nucleotides II
adenylo-succinate	N6-(1,2-dicarboxyethyl)-AMP*adenylo-succ	C14 H18 N5 O11 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(ncn3)N[CH](C(O)=O)CC(O)=O)))	CAS:19240-42-7	4.3.2.2	adenylo-succinate  =  fumarate + AMP	de novo biosynthesis of purine nucleotides I
adenylo-succinate	N6-(1,2-dicarboxyethyl)-AMP*adenylo-succ	C14 H18 N5 O11 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(ncn3)N[CH](C(O)=O)CC(O)=O)))	CAS:19240-42-7	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides II
adenylo-succinate	N6-(1,2-dicarboxyethyl)-AMP*adenylo-succ	C14 H18 N5 O11 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c3(c(nc2)c(ncn3)N[CH](C(O)=O)CC(O)=O)))	CAS:19240-42-7	6.3.4.4	L-aspartate + IMP + GTP  =  adenylo-succinate + phosphate + GDP	de novo biosynthesis of purine nucleotides I
2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate	2,3-diacyl-glucosamine 1-phosphate*2,3-bis(3-hydroxytetradecanoyl)-&beta;-D-glucosaminyl 1-phosphate*2,3-bis(&beta;-hydroxymyristoyl)-&beta;-D-glucosaminyl 1-phosphate*lipid X	C34 H66 N1 O12 P1 	CCCCCCCCCCCC(O)CC(=O)NC1(C(C(O)C(CO)OC1OP(O)(O)=O)OC(=O)CC(O)CCCCCCCCCCC)	LIGAND-CPD:C04824	2.4.1.182	2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate + UDP-2,3-bis(3-hydroxymyristoyl)glucosamine  =  lipid A disaccharide + UDP	lipid-A-precursor biosynthesis
2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate	2,3-diacyl-glucosamine 1-phosphate*2,3-bis(3-hydroxytetradecanoyl)-&beta;-D-glucosaminyl 1-phosphate*2,3-bis(&beta;-hydroxymyristoyl)-&beta;-D-glucosaminyl 1-phosphate*lipid X	C34 H66 N1 O12 P1 	CCCCCCCCCCCC(O)CC(=O)NC1(C(C(O)C(CO)OC1OP(O)(O)=O)OC(=O)CC(O)CCCCCCCCCCC)	LIGAND-CPD:C04824	LIPIDXSYNTHESIS-RXN	H2O + UDP-2,3-bis(3-hydroxymyristoyl)glucosamine  =  2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate + UMP	lipid-A-precursor biosynthesis
prephenate		C10 H10 O6 	C(=O)(O)C(=O)CC1(C(O)=O)(C=C[CH](O)C=C1)	CAS:126-49-8	4.2.1.51	prephenate  =  phenylpyruvate + H2O + CO2	phenylalanine biosynthesis II
prephenate		C10 H10 O6 	C(=O)(O)C(=O)CC1(C(O)=O)(C=C[CH](O)C=C1)	CAS:126-49-8	1.3.1.12	prephenate + NAD+  =  p-hydroxyphenylpyruvate + CO2 + NADH	tyrosine biosynthesis I
prephenate		C10 H10 O6 	C(=O)(O)C(=O)CC1(C(O)=O)(C=C[CH](O)C=C1)	CAS:126-49-8	2.6.1.57	prephenate + L-glutamate  =  L-arogenate + alpha-ketoglutarate	tyrosine biosynthesis II
prephenate		C10 H10 O6 	C(=O)(O)C(=O)CC1(C(O)=O)(C=C[CH](O)C=C1)	CAS:126-49-8	2.6.1.57	prephenate + L-glutamate  =  L-arogenate + alpha-ketoglutarate	phenylalanine biosynthesis I
prephenate		C10 H10 O6 	C(=O)(O)C(=O)CC1(C(O)=O)(C=C[CH](O)C=C1)	CAS:126-49-8	5.4.99.5	chorismate  =  prephenate	tyrosine biosynthesis II
prephenate		C10 H10 O6 	C(=O)(O)C(=O)CC1(C(O)=O)(C=C[CH](O)C=C1)	CAS:126-49-8	5.4.99.5	chorismate  =  prephenate	phenylalanine biosynthesis I
prephenate		C10 H10 O6 	C(=O)(O)C(=O)CC1(C(O)=O)(C=C[CH](O)C=C1)	CAS:126-49-8	5.4.99.5	chorismate  =  prephenate	tyrosine biosynthesis I
prephenate		C10 H10 O6 	C(=O)(O)C(=O)CC1(C(O)=O)(C=C[CH](O)C=C1)	CAS:126-49-8	5.4.99.5	chorismate  =  prephenate	phenylalanine biosynthesis II
glucuronate	D-glucuronate*glucuronic acid*D-glucuronic acid	C6 H10 O7 	C(=O)(O)C1(C(O)C(O)C(O)C(O1)O)	CAS:576-37-4	5.3.1.12	glucuronate  =  fructuronate	beta-D-glucuronide degradation
glucuronate	D-glucuronate*glucuronic acid*D-glucuronic acid	C6 H10 O7 	C(=O)(O)C1(C(O)C(O)C(O)C(O1)O)	CAS:576-37-4	2.7.1.43	glucuronate + ATP  =  alpha-D-glucuronate 1-phosphate + ADP	inositol oxidation pathway
glucuronate	D-glucuronate*glucuronic acid*D-glucuronic acid	C6 H10 O7 	C(=O)(O)C1(C(O)C(O)C(O)C(O1)O)	CAS:576-37-4	1.13.99.1	O2 + myo-inositol  ->  H2O + glucuronate	inositol oxidation pathway
glucuronate	D-glucuronate*glucuronic acid*D-glucuronic acid	C6 H10 O7 	C(=O)(O)C1(C(O)C(O)C(O)C(O1)O)	CAS:576-37-4	3.2.1.31	H2O + beta-D-glucuronide  =  glucuronate + an alcohol	beta-D-glucuronide degradation
glucosamine-1P	&alpha;-D-glucosamine 1P*&alpha;-D-glucosamine 1-phosphate	C6 H14 N1 O8 P1 	[CH]1(O[CH](CO)[CH](O)[CH](O)[CH](N)1)(OP(O)(=O)O)		GLUCOSAMINE1PACETYL-RXN	glucosamine-1P + acetyl-CoA  =  N-acetyl-glucosamine-1-phosphate + coenzyme A	UDP-N-acetyl-D-glucosamine biosynthesis
glucosamine-1P	&alpha;-D-glucosamine 1P*&alpha;-D-glucosamine 1-phosphate	C6 H14 N1 O8 P1 	[CH]1(O[CH](CO)[CH](O)[CH](O)[CH](N)1)(OP(O)(=O)O)		PHOSGLUCOSAMINEMUT-RXN	D-glucosamine-6-phosphate  =  glucosamine-1P	UDP-N-acetyl-D-glucosamine biosynthesis
acyl-ACP	acyl-[acyl carrier protein]*CH3(CH2)xCO-S-ACP				1.3.1.9	NADH + trans-delta2-enoyl-acyl-ACP  =  acyl-ACP + NAD+	fatty acid elongation -- saturated
acyl-ACP	acyl-[acyl carrier protein]*CH3(CH2)xCO-S-ACP				2.3.1.41	acyl-ACP + malonyl-ACP  =  acyl carrier protein + beta-ketoacyl-ACP + CO2	fatty acid elongation -- saturated
acyl-ACP	acyl-[acyl carrier protein]*CH3(CH2)xCO-S-ACP				1.3.1.10	NADPH + trans-delta2-enoyl-acyl-ACP  =  acyl-ACP + NADP+	fatty acid elongation -- saturated
acrylyl-CoA	acryloyl-CoA*acryloyl-coenzyme A*acrylyl-CoA	C24 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=C)	CAS:5776-58-9	4.2.1.17	acrylyl-CoA + H2O  =  3-hydroxypropionyl-CoA	beta-alanine biosynthesis II
acrylyl-CoA	acryloyl-CoA*acryloyl-coenzyme A*acrylyl-CoA	C24 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=C)	CAS:5776-58-9	1.3.99.3	FAD + propionyl-CoA  =  FADH2 + acrylyl-CoA	beta-alanine biosynthesis II
5-phosphoribosyl-n-formylglycineamidine	5'-phosphoribosyl-N-formyl glycineamidine*FGAM*5-phosphoribosyl-N-formylglycineamidine*5'-phosphoribosylformylglycinamidine	C8 H16 N3 O8 P1 	C(=N)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides II
5-phosphoribosyl-n-formylglycineamidine	5'-phosphoribosyl-N-formyl glycineamidine*FGAM*5-phosphoribosyl-N-formylglycineamidine*5'-phosphoribosylformylglycinamidine	C8 H16 N3 O8 P1 	C(=N)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides I
5-phosphoribosyl-n-formylglycineamidine	5'-phosphoribosyl-N-formyl glycineamidine*FGAM*5-phosphoribosyl-N-formylglycineamidine*5'-phosphoribosylformylglycinamidine	C8 H16 N3 O8 P1 	C(=N)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides II
5-phosphoribosyl-n-formylglycineamidine	5'-phosphoribosyl-N-formyl glycineamidine*FGAM*5-phosphoribosyl-N-formylglycineamidine*5'-phosphoribosylformylglycinamidine	C8 H16 N3 O8 P1 	C(=N)(CNC=O)N[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)		6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides I
phosphatidyl-myo-inositol 4,5-biphosphate	1-Phosphatidyl-1D-myo-inositol 4,5-bisphosphate	C11 H19 O19 R2 P3 			3.1.4.11	phosphatidyl-myo-inositol 4,5-biphosphate + H2O  =  1,2-diacylglycerol + inositol 1,4,5-trisphosphate	lipases pathway
acrylonitrile		C3 H3 N1 	C(#N)C=C	NCI:6362*CAS:107-13-1	4.2.1.84	acrylonitrile + H2O  =  acrylamide	acrylonitrile degradation
acrylonitrile		C3 H3 N1 	C(#N)C=C	NCI:6362*CAS:107-13-1	3.5.5.7	acrylonitrile + 2 H2O  =  acrylate + NH3	acrylonitrile degradation
demethylphylloquinone	3-phytyl-1,4-naphtoquinone	C30 H44 O2 	CC(CCCC(C)CCCC(C)C)CCCC(C)=CCC1(C(=O)C2(=C(C(=O)C=1)C=CC=C2))		RXN-7569	demethylphylloquinone + S-adenosyl-L-methionine  =  phylloquinone + S-adenosyl-homocysteine	phylloquinone biosynthesis
demethylphylloquinone	3-phytyl-1,4-naphtoquinone	C30 H44 O2 	CC(CCCC(C)CCCC(C)C)CCCC(C)=CCC1(C(=O)C2(=C(C(=O)C=1)C=CC=C2))		RXN-7568	1,4-dihydroxy-2-naphthoate + phytyl pyrophosphate  =  demethylphylloquinone + CO2 + pyrophosphate	phylloquinone biosynthesis
1,8-cineole	cineole*1,8-epoxy-p-menthane*1,8-oxido-p-menthane*eucalyptol*cajeputol	C10 H18 O1 	CC12(CCC(C(C)(O1)C)CC2)		RXN-5102	(-)-(4S)-alpha-terpineol  =  1,8-cineole	monoterpene biosynthesis
acetoacetyl-CoA	acetoacetyl-S-CoA	C25 H40 N7 O18 P3 S1 	CC(=O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00332*CAS:1420-36-6	1.1.1.-	3-hydroxybutyryl-CoA + NAD+  =  acetoacetyl-CoA + NADH	lysine degradation II
acetoacetyl-CoA	acetoacetyl-S-CoA	C25 H40 N7 O18 P3 S1 	CC(=O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00332*CAS:1420-36-6	1.1.1.-	3-hydroxybutyryl-CoA + NAD+  =  acetoacetyl-CoA + NADH	tryptophan degradation
acetoacetyl-CoA	acetoacetyl-S-CoA	C25 H40 N7 O18 P3 S1 	CC(=O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00332*CAS:1420-36-6	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	lysine degradation II
acetoacetyl-CoA	acetoacetyl-S-CoA	C25 H40 N7 O18 P3 S1 	CC(=O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00332*CAS:1420-36-6	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	tryptophan degradation
acetoacetyl-CoA	acetoacetyl-S-CoA	C25 H40 N7 O18 P3 S1 	CC(=O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00332*CAS:1420-36-6	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	mevalonate pathway
acetoacetyl-CoA	acetoacetyl-S-CoA	C25 H40 N7 O18 P3 S1 	CC(=O)CC(=O)SCCNC(=O)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)[CH]1OP(O)(O)=O)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00332*CAS:1420-36-6	4.1.3.5	acetoacetyl-CoA + H2O + acetyl-CoA  =  coenzyme A + 3-hydroxy-3-methyl-glutaryl-CoA	mevalonate pathway
indolylmethylthiohydroximate	indolylmethylthiohydroximic acid	C10 H10 N2 O1 S1 	C([SH])(=NO)Cc1(c[nH]c2(c1cccc2))		2.4.1.-	indolylmethylthiohydroximate + UDP-D-glucose  =  indolylmethyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from tryptophan
indolylmethylthiohydroximate	indolylmethylthiohydroximic acid	C10 H10 N2 O1 S1 	C([SH])(=NO)Cc1(c[nH]c2(c1cccc2))		RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
indolylmethyl-desulfoglucosinolate		C16 H20 N2 O6 S1 	C(O)C1(C(OC(O)C(O)C(O)1)SC(=NO)Cc2(c3(c([nH]c2)cccc3)))		2.8.2.-	indolylmethyl-desulfoglucosinolate + PAPS  =  indolylmethyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from tryptophan
indolylmethyl-desulfoglucosinolate		C16 H20 N2 O6 S1 	C(O)C1(C(OC(O)C(O)C(O)1)SC(=NO)Cc2(c3(c([nH]c2)cccc3)))		2.4.1.-	indolylmethylthiohydroximate + UDP-D-glucose  =  indolylmethyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from tryptophan
alpha-D-glucuronate 1-phosphate	1-phospho-&alpha;-D-glucuronate	C6 H11 O10 P1 	C1(OC(C(=O)O)C(O)C(O)C(O)1)(OP(O)(=O)O)		2.7.7.44	alpha-D-glucuronate 1-phosphate + UTP  =  UDP-D-glucuronate + pyrophosphate	inositol oxidation pathway
alpha-D-glucuronate 1-phosphate	1-phospho-&alpha;-D-glucuronate	C6 H11 O10 P1 	C1(OC(C(=O)O)C(O)C(O)C(O)1)(OP(O)(=O)O)		2.7.1.43	glucuronate + ATP  =  alpha-D-glucuronate 1-phosphate + ADP	inositol oxidation pathway
indolylmethyl-glucosinolate	3-indolymethyl-glucosinolate*glucobrassicin	C16 H20 N2 O9 S2 	C(SC1(C(CO)C(O)C(O)C(O)O1))(=NOS(O)(=O)=O)Cc2(c[nH]c3(ccccc23))		RXN-1444	indolylmethyl-glucosinolate + H2O  =  indolylmethyl glucosinolate aglycone + beta-D-glucose	glucosinolate biosynthesis from tryptophan
indolylmethyl-glucosinolate	3-indolymethyl-glucosinolate*glucobrassicin	C16 H20 N2 O9 S2 	C(SC1(C(CO)C(O)C(O)C(O)O1))(=NOS(O)(=O)=O)Cc2(c[nH]c3(ccccc23))		RXN-2161	indolylmethyl-glucosinolate  =  1-methoxy-3-indolylmethyl-glucosinolate	glucosinolate biosynthesis from tryptophan
indolylmethyl-glucosinolate	3-indolymethyl-glucosinolate*glucobrassicin	C16 H20 N2 O9 S2 	C(SC1(C(CO)C(O)C(O)C(O)O1))(=NOS(O)(=O)=O)Cc2(c[nH]c3(ccccc23))		RXN-2162	indolylmethyl-glucosinolate  =  4-hydroxy-3-indolylmethyl-glucosinolate	glucosinolate biosynthesis from tryptophan
indolylmethyl-glucosinolate	3-indolymethyl-glucosinolate*glucobrassicin	C16 H20 N2 O9 S2 	C(SC1(C(CO)C(O)C(O)C(O)O1))(=NOS(O)(=O)=O)Cc2(c[nH]c3(ccccc23))		2.8.2.-	indolylmethyl-desulfoglucosinolate + PAPS  =  indolylmethyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from tryptophan
leucopelargonidin	cis 3,4-leucopelargonidin	C15 H14 O6 	c2(O)(cc1(OC(C(O)C(O)c1c(c2)O)c3(ccc(O)cc3)))		1.1.1.219	NADPH + dihydrokaempferol  =  leucopelargonidin + NADP+	anthocyanin biosynthesis
leucopelargonidin	cis 3,4-leucopelargonidin	C15 H14 O6 	c2(O)(cc1(OC(C(O)C(O)c1c(c2)O)c3(ccc(O)cc3)))		1.14.11.19	leucopelargonidin + alpha-ketoglutarate + O2  =  pelargonidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	4.2.1.22	homocysteine + L-serine  =  H2O + cystathionine	homocysteine and cysteine interconversion
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	4.2.1.22	homocysteine + L-serine  =  H2O + cystathionine	methionine degradation I
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	6.1.1.11	tRNAser + L-serine + ATP  =  L-seryl-tRNAser + pyrophosphate + AMP	tRNA charging pathway
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	2.3.1.30	L-serine + acetyl-CoA  =  O-acetyl-L-serine + coenzyme A	cysteine biosynthesis
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	2.3.1.30	L-serine + acetyl-CoA  =  O-acetyl-L-serine + coenzyme A	sulfate assimilation
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	RXN0-2382	indole + L-serine  =  L-tryptophan + H2O	tryptophan biosynthesis
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	RXN-1382	L-1-phosphatidyl-ethanolamine + L-serine  =  L-1-phosphatidylserine + ethanolamine	phospholipid biosynthesis
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	RXN-974	L-serine + alpha-ketoglutarate  =  hydroxypyruvate + L-glutamate	photorespiration
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	RXN-5641	L-serine  =  ethanolamine + CO2	choline biosynthesis I
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis I
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	photorespiration
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	glycine biosynthesis
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	3.1.3.3	3-phospho-serine + H2O  =  L-serine + phosphate	serine biosynthesis
L-serine	S*serine*ser*L-ser	C3 H7 N1 O3 	C(=O)(O)[CH](N)CO	LIGAND-CPD:C00065*LIGAND:C00065*CAS:56-45-1	3.1.3.3	3-phospho-serine + H2O  =  L-serine + phosphate	glycine biosynthesis
phylloquinone	2-methyl-3-phytyl-1,4-naphthoquinone*phytonadione*phytomenadione*3-phytylmenadione*vitamin K<SUB>1</SUB>	C31 H46 O2 	CC1(=C(C(=O)C2(=C(C(=O)1)C=CC=C2))CC=C(C)CCCC(C)CCCC(C)CCCC(C)C)	NCI:270681*CAS:84-80-0	RXN-7569	demethylphylloquinone + S-adenosyl-L-methionine  =  phylloquinone + S-adenosyl-homocysteine	phylloquinone biosynthesis
S-lactoyl-glutathione	S-D-lactoylglutathione*D-lactoylglutathione*(R)-S-lactoylglutathione	C13 H21 N3 O8 S1 	C(O)(=O)C(N)CCC(=O)NC(CSC(=O)C(C)O)C(=O)NCC(=O)O	CAS:25138-66-3	4.4.1.5	methylglyoxal + glutathione  =  S-lactoyl-glutathione	threonine degradation
S-lactoyl-glutathione	S-D-lactoylglutathione*D-lactoylglutathione*(R)-S-lactoylglutathione	C13 H21 N3 O8 S1 	C(O)(=O)C(N)CCC(=O)NC(CSC(=O)C(C)O)C(=O)NCC(=O)O	CAS:25138-66-3	4.4.1.5	methylglyoxal + glutathione  =  S-lactoyl-glutathione	methylglyoxal degradation
S-lactoyl-glutathione	S-D-lactoylglutathione*D-lactoylglutathione*(R)-S-lactoylglutathione	C13 H21 N3 O8 S1 	C(O)(=O)C(N)CCC(=O)NC(CSC(=O)C(C)O)C(=O)NCC(=O)O	CAS:25138-66-3	3.1.2.6	S-lactoyl-glutathione + H2O  =  glutathione + D-lactate	threonine degradation
S-lactoyl-glutathione	S-D-lactoylglutathione*D-lactoylglutathione*(R)-S-lactoylglutathione	C13 H21 N3 O8 S1 	C(O)(=O)C(N)CCC(=O)NC(CSC(=O)C(C)O)C(=O)NCC(=O)O	CAS:25138-66-3	3.1.2.6	S-lactoyl-glutathione + H2O  =  glutathione + D-lactate	methylglyoxal degradation
glyoxylate	glyoxalate*glyox*glyoxylic acid	C2 H2 O3 	C(=O)(O)[CH]=O	CAS:298-12-4	2.6.1.4	L-glutamate + glyoxylate  =  alpha-ketoglutarate + glycine	photorespiration
glyoxylate	glyoxalate*glyox*glyoxylic acid	C2 H2 O3 	C(=O)(O)[CH]=O	CAS:298-12-4	1.1.3.15	glycolate + O2  =  glyoxylate + H2O2	photorespiration
glyoxylate	glyoxalate*glyox*glyoxylic acid	C2 H2 O3 	C(=O)(O)[CH]=O	CAS:298-12-4	4.3.2.3	(S)-ureidoglycolate  =  urea + glyoxylate	ureide degradation
glyoxylate	glyoxalate*glyox*glyoxylic acid	C2 H2 O3 	C(=O)(O)[CH]=O	CAS:298-12-4	3.5.3.19	H2O + (S)-ureidoglycolate  =  2 NH3 + CO2 + glyoxylate	ureide degradation
glyoxylate	glyoxalate*glyox*glyoxylic acid	C2 H2 O3 	C(=O)(O)[CH]=O	CAS:298-12-4	2.3.3.9	acetyl-CoA + H2O + glyoxylate  =  malate + coenzyme A	glyoxylate cycle
glyoxylate	glyoxalate*glyox*glyoxylic acid	C2 H2 O3 	C(=O)(O)[CH]=O	CAS:298-12-4	4.1.3.1	isocitrate  =  glyoxylate + succinate	glyoxylate cycle
FMN	flavin mononucleotide	C17 H21 N4 O9 P1 	C1(c2(c(=NC(=O)N1)n(c3(c(n2)cc(C)c(c3)C))CC(O)C(O)C(O)COP(=O)(O)O))(=O)	LIGAND-CPD:C00061*CAS:146-17-8	2.7.7.2	FMN + ATP  =  FAD + pyrophosphate	riboflavin and FMN and FAD biosynthesis
FMN	flavin mononucleotide	C17 H21 N4 O9 P1 	C1(c2(c(=NC(=O)N1)n(c3(c(n2)cc(C)c(c3)C))CC(O)C(O)C(O)COP(=O)(O)O))(=O)	LIGAND-CPD:C00061*CAS:146-17-8	2.7.1.26	riboflavin + ATP  =  FMN + ADP	riboflavin and FMN and FAD biosynthesis
syringin	sinapyl alcohol-4-O-&beta;-D-glucopyranoside	C17 H24 O9 	C(O)C=Cc1(cc(OC)c(c(c1)OC)OC2(OC(CO)C(O)C(O)C(O)2))		2.4.1.111	sinapyl-alcohol + UDP-D-glucose  =  syringin + UDP	monolignol glucosides biosynthesis
2-phosphoglycolate	2-p-glycolate*phosphoglycolate*Phosphoglycolic acid	C2 H5 O6 P1 	C(C(=O)O)OP(=O)(O)O	LIGAND:C00988	3.1.3.18	H2O + 2-phosphoglycolate  =  glycolate + phosphate	photorespiration
2-phosphoglycolate	2-p-glycolate*phosphoglycolate*Phosphoglycolic acid	C2 H5 O6 P1 	C(C(=O)O)OP(=O)(O)O	LIGAND:C00988	4.1.1.-	D-ribulose-1,5-bisphosphate + O2  =  2-phosphoglycolate + 3-phosphoglycerate + 2 H+	photorespiration
1-aminocyclopropane-1-carboxylate	1-Aminocyclopropane-1-carboxylic acid	C4 H7 N1 O2 	C(O)(=O)C1(CC1)(N)	CAS:22059-21-8	1.14.17.4	L-ascorbate + 1-aminocyclopropane-1-carboxylate + O2  =  2 H2O + ethene + L-dehydro-ascorbate + hydrogen cyanide + CO2	ethylene biosynthesis from methionine
1-aminocyclopropane-1-carboxylate	1-Aminocyclopropane-1-carboxylic acid	C4 H7 N1 O2 	C(O)(=O)C1(CC1)(N)	CAS:22059-21-8	4.4.1.14	S-adenosyl-L-methionine  =  5'-methylthioadenosine + 1-aminocyclopropane-1-carboxylate	ethylene biosynthesis from methionine
1-aminocyclopropane-1-carboxylate	1-Aminocyclopropane-1-carboxylic acid	C4 H7 N1 O2 	C(O)(=O)C1(CC1)(N)	CAS:22059-21-8	4.4.1.14	S-adenosyl-L-methionine  =  5'-methylthioadenosine + 1-aminocyclopropane-1-carboxylate	methionine salvage pathway
2-methylbutyryl-CoA	alpha-methylbutyryl-CoA*&alpha;-methylbutanoyl-CoA*2-methylbutanoyl-CoA	C26 H44 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)CC)		1.3.99.12	2-methylbutyryl-CoA + FAD  =  tiglyl-CoA + FADH2	isoleucine degradation
2-methylbutyryl-CoA	alpha-methylbutyryl-CoA*&alpha;-methylbutanoyl-CoA*2-methylbutanoyl-CoA	C26 H44 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)CC)		2KETO-3METHYLVALERATE-RXN	2-keto-3-methyl-valerate + NAD+ + coenzyme A  =  2-methylbutyryl-CoA + NADH + CO2	isoleucine degradation
cyanate	Cyanic acid*cyanic acid*hydrogen cyanate	C1 H1 N1 O1 	C(#N)O	CAS:420-05-3	4.3.99.1	HCO3- + cyanate  =  carbamate + CO2	cyanate degradation
L-2,3,4,5-tetrahydrodipicolinate	tetrahydrodipicolinate*&Delta;<SUP>1</SUP>-piperideine-2,6-dicarboxylate	C7 H9 N1 O4 	C(O)(=O)C1(=NC(C(=O)O)CCC1)		2.3.1.117	H2O + L-2,3,4,5-tetrahydrodipicolinate + succinyl-CoA  =  N-succinyl-2-amino-6-ketopimelate + coenzyme A	lysine biosynthesis
L-2,3,4,5-tetrahydrodipicolinate	tetrahydrodipicolinate*&Delta;<SUP>1</SUP>-piperideine-2,6-dicarboxylate	C7 H9 N1 O4 	C(O)(=O)C1(=NC(C(=O)O)CCC1)		1.3.1.26	L-2,3-dihydrodipicolinate + NAD(P)H + H+  =  L-2,3,4,5-tetrahydrodipicolinate + NAD(P)+	lysine biosynthesis
tRNAglt	tRNA<SUP>glt</SUP>*TRNA(GLT)				6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	chlorophyllide a biosynthesis
tRNAglt	tRNA<SUP>glt</SUP>*TRNA(GLT)				6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	biosynthesis of proto- and siroheme
tRNAglt	tRNA<SUP>glt</SUP>*TRNA(GLT)				6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	tRNA charging pathway
tRNAglt	tRNA<SUP>glt</SUP>*TRNA(GLT)				1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	chlorophyllide a biosynthesis
tRNAglt	tRNA<SUP>glt</SUP>*TRNA(GLT)				1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	biosynthesis of proto- and siroheme
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.95	gamma-tocopherol + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + alpha-tocopherol	vitamin E biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.103	phosphoryl-ethanolamine + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + N-methylethanolamine phosphate	choline biosynthesis I
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.104	caffeoyl-CoA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + feruloyl-CoA	lignin biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.104	caffeoyl-CoA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + feruloyl-CoA	suberin biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.6.1.62	S-adenosyl-L-methionine + 8-amino-7-oxononanoate  =  S-adenosyl-4-methylthio-2-oxobutanoate + 7,8-diaminononanoate	biotin biosynthesis II
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	4.1.1.50	S-adenosyl-L-methionine  =  CO2 + S-adenosylmethioninamine	polyamine biosynthesis III
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	4.1.1.50	S-adenosyl-L-methionine  =  CO2 + S-adenosylmethioninamine	polyamine biosynthesis I
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.10	homocysteine + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + L-methionine	methionine biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.11	Mg-protoporphyrin + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + Mg-protoporphyrin monomethyl ester	chlorophyllide a biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.95	delta-tocopherol + S-adenosyl-L-methionine  =  beta-tocopherol + S-adenosyl-homocysteine	vitamin E biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.-	2-methyl-6-phytyl-1,4-benzoquinone + S-adenosyl-L-methionine  =  2,3-dimethyl-6-phytyl-1,4-benzoquinone + S-adenosyl-homocysteine	vitamin E biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.68	5-hydroxy-coniferaldehyde + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + sinapaldehyde	lignin biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.-	uroporphyrinogen-III + 2 S-adenosyl-L-methionine  =  2 S-adenosyl-homocysteine + dihydrosirohydrochlorin	biosynthesis of proto- and siroheme
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	ADOMET-DMK-METHYLTRANSFER-RXN	demethylmenaquinone-8 + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + menaquinone-8	menaquinone biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.141	(-)-jasmonate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + (-)-jasmonic acid methyl ester	jasmonic acid biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.68	caffeate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + ferulate	phenylpropanoid biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.68	caffeate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + ferulate	suberin biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.37	DNA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + DNA CONTAINING 5-METHYLCYTOSINE	methionine degradation I
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.-	2-methyl-6-solanyl-1,4-benzoquinone + S-adenosyl-L-methionine  =  plastoquinone-9 + S-adenosyl-homocysteine	plastoquinone biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.41	cycloartenol + S-adenosyl-L-methionine  =  24-methylenecycloartenol + S-adenosyl-homocysteine	sterol biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.68	5-hydroxy-ferulic-acid + S-adenosyl-L-methionine  =  sinapate + S-adenosyl-homocysteine	phenylpropanoid biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	4.4.1.14	S-adenosyl-L-methionine  =  5'-methylthioadenosine + 1-aminocyclopropane-1-carboxylate	ethylene biosynthesis from methionine
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	4.4.1.14	S-adenosyl-L-methionine  =  5'-methylthioadenosine + 1-aminocyclopropane-1-carboxylate	methionine salvage pathway
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.103	N-dimethylethanolamine phosphate + S-adenosyl-L-methionine  =  phosphoryl-choline + S-adenosyl-homocysteine	choline biosynthesis I
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.103	N-methylethanolamine phosphate + S-adenosyl-L-methionine  =  N-dimethylethanolamine phosphate + S-adenosyl-homocysteine	choline biosynthesis I
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.79	oleate + S-adenosyl-L-methionine  =  dihydrosterculate + S-adenosyl-homocysteine	cyclopropane and cyclopropene fatty acid biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.143	24-methylenelophenol + S-adenosyl-L-methionine  =  24-ethylidenelophenol + S-adenosyl-homocysteine	sterol biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	RXN-5763	N-dimethylethanolamine + S-adenosyl-L-methionine  =  choline + S-adenosyl-homocysteine	choline biosynthesis II
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	RXN-5762	N-monomethylethanolamine + S-adenosyl-L-methionine  =  N-dimethylethanolamine + S-adenosyl-homocysteine	choline biosynthesis II
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	RXN-5761	ethanolamine + S-adenosyl-L-methionine  =  N-monomethylethanolamine + S-adenosyl-homocysteine	choline biosynthesis II
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	RXN-7569	demethylphylloquinone + S-adenosyl-L-methionine  =  phylloquinone + S-adenosyl-homocysteine	phylloquinone biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	RXN-6723	salicylate + S-adenosyl-L-methionine  =  methylsalicylate + S-adenosyl-homocysteine	volatile benzenoid ester biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	RXN-6722	benzoate + S-adenosyl-L-methionine  =  methylbenzoate + S-adenosyl-homocysteine	volatile benzenoid ester biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.-	S-adenosyl-L-methionine + methyl acceptor  =  S-adenosyl-homocysteine + N-methylated acceptor	SAM cycle
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.-	24-methylenecycloartenol + S-adenosyl-homocysteine  =  cycloeucalenol + S-adenosyl-L-methionine	sterol biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.1.1.-	24-methylenelophenol + S-adenosyl-homocysteine  =  episterol + S-adenosyl-L-methionine	sterol biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	SAM cycle
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	ethylene biosynthesis from methionine
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	adenosylmethionine biosynthesis
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine salvage pathway
S-adenosyl-L-methionine	<i>S</i>-adenosylmethionine*<i>S</i>-adenosyl-methionine*2-<i>S</i>-adenosyl-L-methionine*AdoMet*SAM*2-S-adenosyl-L-methionine*S-adenosyl-methionine*adenosylmethionine*S-adenosylmethionine	C15 H23 N6 O5 S1 	C(CC(N)C(O)=O)[S+1](C)CC1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00019*CAS:29908-03-0	2.5.1.6	ATP + L-methionine + H2O  =  phosphate + pyrophosphate + S-adenosyl-L-methionine	methionine degradation I
mannose-1-phosphate	D-mannose-1-phosphate*mannose-1-P*&alpha;-D-mannose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:27251-84-9	5.4.2.8	mannose-6-phosphate  =  mannose-1-phosphate	colanic acid building blocks biosynthesis
mannose-1-phosphate	D-mannose-1-phosphate*mannose-1-P*&alpha;-D-mannose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:27251-84-9	5.4.2.8	mannose-6-phosphate  =  mannose-1-phosphate	ascorbate biosynthesis
mannose-1-phosphate	D-mannose-1-phosphate*mannose-1-P*&alpha;-D-mannose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:27251-84-9	5.4.2.8	mannose-6-phosphate  =  mannose-1-phosphate	GDP-D-rhamnose biosynthesis
mannose-1-phosphate	D-mannose-1-phosphate*mannose-1-P*&alpha;-D-mannose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:27251-84-9	2.7.7.13	mannose-1-phosphate + GTP  =  GDP-mannose + pyrophosphate	ascorbate biosynthesis
mannose-1-phosphate	D-mannose-1-phosphate*mannose-1-P*&alpha;-D-mannose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:27251-84-9	2.7.7.22	mannose-1-phosphate + GDP  =  GDP-mannose + phosphate	colanic acid building blocks biosynthesis
mannose-1-phosphate	D-mannose-1-phosphate*mannose-1-P*&alpha;-D-mannose-1-phosphate	C6 H13 O9 P1 	C(O)C1(OC(OP(O)(=O)O)C(O)C(O)C(O)1)	CAS:27251-84-9	2.7.7.22	mannose-1-phosphate + GDP  =  GDP-mannose + phosphate	GDP-D-rhamnose biosynthesis
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	5.3.1.6	D-ribose-5-phosphate  =  D-ribulose-5-phosphate	Calvin cycle
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	5.3.1.6	D-ribose-5-phosphate  =  D-ribulose-5-phosphate	superpathway of gluconate degradation
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	5.3.1.6	D-ribose-5-phosphate  =  D-ribulose-5-phosphate	ribose degradation
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	5.3.1.6	D-ribose-5-phosphate  =  D-ribulose-5-phosphate	non-oxidative branch of the pentose phosphate pathway
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	2.7.6.1	ATP + D-ribose-5-phosphate  =  PRPP + AMP	PRPP biosynthesis
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	(deoxy)ribose phosphate degradation
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	ribose degradation
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	non-oxidative branch of the pentose phosphate pathway
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	5.4.2.7	ribose-1-phosphate  =  D-ribose-5-phosphate	(deoxy)ribose phosphate degradation
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	3.2.2.14	H2O + nicotinamide mononucleotide  =  D-ribose-5-phosphate + nicotinamide	pyridine nucleotide cycling
D-ribose-5-phosphate	D-ribose-5-phosphate*D-ribose-5-phosphoric acid*ribose-5-phosphoric acid*ribose-5P*D-ribose-5-P*ribose-5-P*ribose-5-phosphate	C5 H11 O8 P1 	C(=O)C(O)C(O)C(O)COP(O)(=O)O	CAS:3615-55-2	2.7.1.15	D-ribose + ATP  =  D-ribose-5-phosphate + ADP	ribose degradation
D-myo-inositol (3,4)-bisphosphate	1D-<i>myo</i>-inositol (3,4)-bisphosphate*inositol (3,4)-bisphosphate*(2,3,4,5)-tetrahydroxy-6-phosphonooxy-cyclohexoxy)phosphonic acid*Ins(3,4)P<sub>2</sub>*I(3,4)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7203	D-myo-inositol (3,4)-bisphosphate + ATP  =  D-myo-inositol (3,4,6)-trisphosphate + ADP	lipid-independent phytate biosynthesis
D-myo-inositol (3,4)-bisphosphate	1D-<i>myo</i>-inositol (3,4)-bisphosphate*inositol (3,4)-bisphosphate*(2,3,4,5)-tetrahydroxy-6-phosphonooxy-cyclohexoxy)phosphonic acid*Ins(3,4)P<sub>2</sub>*I(3,4)P<sub>2</sub>	C6 H12 O12 P2 	C1(C(OP(O)([O-1])=O)C(O)C(O)C(O)C(O)1)(OP(O)([O-1])=O)		RXN-7202	D-myo-inositol (3)-monophosphate + ATP  =  D-myo-inositol (3,4)-bisphosphate + ADP	lipid-independent phytate biosynthesis
quercetin		C15 H10 O7 	c1(cc(cc(O)c(O)1)c2(c(O)c(=O)c3(c(o2)cc(O)cc(O)3)))		2.4.1.91	quercetin + UDP-D-glucose  =  quercetin-3-glucoside + UDP	flavonol biosynthesis
quercetin		C15 H10 O7 	c1(cc(cc(O)c(O)1)c2(c(O)c(=O)c3(c(o2)cc(O)cc(O)3)))		RXN-527	dihydroquercetin + alpha-ketoglutarate + O2  =  quercetin + succinate + CO2 + H2O	flavonol biosynthesis
gamma-butyrobetainyl-CoA	&gamma;-butyrobetaine-CoA	C28 H50 N8 O17 P3 S1 	C(C(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CCC[N+1](C)(C)C)OP(=O)(O)OP(O)(=O)OCC1(OC(C(O)C1OP(=O)(O)O)n2(c3(c(nc2)c(N)ncn3)))		1.3.99.-	reduced acceptor + crotonobetainyl-CoA  =  acceptor + gamma-butyrobetainyl-CoA	carnitine degradation
chlorophyllide a	chlorophyllide a	C35 H34 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(n6c(c(c7C)CCC(=O)O)=C8[CH](C(=O)9)C(=O)OC)))))))		2.5.1.62	chlorophyllide a + phytyl pyrophosphate  =  chlorophyll a + pyrophosphate	chlorophyll cycle
chlorophyllide a	chlorophyllide a	C35 H34 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(n6c(c(c7C)CCC(=O)O)=C8[CH](C(=O)9)C(=O)OC)))))))		2.5.1.62	chlorophyllide a + phytyl pyrophosphate  =  chlorophyll a + pyrophosphate	chlorophyll a biosynthesis I
chlorophyllide a	chlorophyllide a	C35 H34 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(n6c(c(c7C)CCC(=O)O)=C8[CH](C(=O)9)C(=O)OC)))))))		2.5.1.-	chlorophyllide a + geranylgeranyl-PP  =  geranylgeranyl-chlorophyll a + pyrophosphate	chlorophyll a biosynthesis II
chlorophyllide a	chlorophyllide a	C35 H34 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(n6c(c(c7C)CCC(=O)O)=C8[CH](C(=O)9)C(=O)OC)))))))		RXN-7676	chlorophyllide a + O2 + NADPH  =  7-hydroxy-chlorophyllide a + H2O + NADP+	chlorophyll cycle
chlorophyllide a	chlorophyllide a	C35 H34 N4 O5 MG1 	Cc3(c9(c8(n2([Mg]56(n1(c(c(C)c(C=C)c1=Cc4(n(c(=Cc23)c(c4C)CC)5))=Cc7(n6c(c(c7C)CCC(=O)O)=C8[CH](C(=O)9)C(=O)OC)))))))		RXN1F-10	monovinyl protochlorophyllide a + NADPH  =  NADP+ + chlorophyllide a	chlorophyllide a biosynthesis
tRNAleu	TRNA(LEU)				6.1.1.4	L-leucine + tRNAleu + ATP  =  L-leucyl-tRNAleu + pyrophosphate + AMP	tRNA charging pathway
4-diphosphocytidyl-2-C-methylerythritol	4-diphosphocytidyl-2C-methyl-D-erythritol*CDP-methyl-D-erythritol*CDP-ME	C14 H25 N3 O14 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OCC(O)C(O)(C)CO))		2.7.-.-	4-diphosphocytidyl-2-C-methylerythritol + ATP  =  4-diphosphocytidyl-2-C-methylerythritol 2-phosphate + ADP	isopentenyl diphosphate biosynthesis -- mevalonate-independent
4-diphosphocytidyl-2-C-methylerythritol	4-diphosphocytidyl-2C-methyl-D-erythritol*CDP-methyl-D-erythritol*CDP-ME	C14 H25 N3 O14 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OCC(O)C(O)(C)CO))		RXN0-277	2-C-methyl-D-erythritol-4-phosphate + CTP  =  4-diphosphocytidyl-2-C-methylerythritol + pyrophosphate	isopentenyl diphosphate biosynthesis -- mevalonate-independent
4-diphosphocytidyl-2-C-methylerythritol 2-phosphate	4-diphosphocytidyl-2C-methyl-D-erythritol 2-phosphate*CDP-methyl-D-erylthritol 2-phosphate*CDP-ME-2P	C14 H26 N3 O17 P3 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OCC(O)C(CO)(C)OP(O)(=O)O))		RXN0-302	4-diphosphocytidyl-2-C-methylerythritol 2-phosphate  =  2-C-methyl-D-erythritol-2,4-cyclodiphosphate + CMP	isopentenyl diphosphate biosynthesis -- mevalonate-independent
4-diphosphocytidyl-2-C-methylerythritol 2-phosphate	4-diphosphocytidyl-2C-methyl-D-erythritol 2-phosphate*CDP-methyl-D-erylthritol 2-phosphate*CDP-ME-2P	C14 H26 N3 O17 P3 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OCC(O)C(CO)(C)OP(O)(=O)O))		2.7.-.-	4-diphosphocytidyl-2-C-methylerythritol + ATP  =  4-diphosphocytidyl-2-C-methylerythritol 2-phosphate + ADP	isopentenyl diphosphate biosynthesis -- mevalonate-independent
sinapaldehyde glucoside	sinapyl aldehyde-4-O-&beta;-D-glucopyranoside	C17 H22 O9 	C(=O)C=Cc1(cc(OC)c(c(c1)OC)OC2(OC(CO)C(O)C(O)C(O)2))		RXN-92	sinapaldehyde + UDP-D-glucose  =  sinapaldehyde glucoside + UDP	monolignol glucosides biosynthesis
orotidine-5'-phosphate		C10 H13 N2 O11 P1 	c1(=O)([nH]c(=O)n(c(c1)C(O)=O)[CH]2(O[CH]([CH](O)[CH]2O)COP(O)(=O)O))	CAS:2149-82-8	2.4.2.10	PRPP + orotate  =  orotidine-5'-phosphate + pyrophosphate	de novo biosynthesis of pyrimidine ribonucleotides
orotidine-5'-phosphate		C10 H13 N2 O11 P1 	c1(=O)([nH]c(=O)n(c(c1)C(O)=O)[CH]2(O[CH]([CH](O)[CH]2O)COP(O)(=O)O))	CAS:2149-82-8	4.1.1.23	orotidine-5'-phosphate  =  CO2 + UMP	de novo biosynthesis of pyrimidine ribonucleotides
cis-zeatin	(Z)-2-methyl-4-(1H-purin-6-ylamino)but-2-en-1-ol	C10 H13 N5 O1 	CC(CO)=CCNc2(c1(c([nH]cn1)ncn2))		2.4.1.215	cis-zeatin + UDP-D-glucose  =  cis-zeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
inositol 1,4,5-trisphosphate	I(1,4,5)P<sub>3</sub>*Ins(1,4,5)P<sub>3</sub>*1D-<i>myo</i>-inositol (1,4,5)-trisphosphate*inositol (1,4,5)-trisphosphate*D-myo-Inositol 1,4,5-trisphosphate*1D-myo-Inositol 1,4,5-trisphosphate	C6 H15 O15 P3 	C1(C(O)C(OP(=O)(O)O)C(OP(O)(=O)O)C(O)C(O)1)(OP(O)(=O)O)	CAS:85166-31-0*CAS:88269-39-0	2.7.1.151	inositol 1,4,5-trisphosphate + ATP  =  D-myo-inositol (1,4,5,6)-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
inositol 1,4,5-trisphosphate	I(1,4,5)P<sub>3</sub>*Ins(1,4,5)P<sub>3</sub>*1D-<i>myo</i>-inositol (1,4,5)-trisphosphate*inositol (1,4,5)-trisphosphate*D-myo-Inositol 1,4,5-trisphosphate*1D-myo-Inositol 1,4,5-trisphosphate	C6 H15 O15 P3 	C1(C(O)C(OP(=O)(O)O)C(OP(O)(=O)O)C(O)C(O)1)(OP(O)(=O)O)	CAS:85166-31-0*CAS:88269-39-0	3.1.4.11	phosphatidyl-myo-inositol 4,5-biphosphate + H2O  =  1,2-diacylglycerol + inositol 1,4,5-trisphosphate	lipases pathway
UDP-D-galacturonate	UDP-galacturonate	C15 H22 N2 O18 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)C(O)=O)))		RXN-3	alpha-D-galacturonate 1-phosphate + UTP  =  UDP-D-galacturonate + pyrophosphate	UDP-D-galacturonate biosynthesis II (from D-galacturonate)
UDP-D-galacturonate	UDP-galacturonate	C15 H22 N2 O18 P2 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OC3(C(O)C(O)C(O)C(O3)C(O)=O)))		5.1.3.6	UDP-D-glucuronate  =  UDP-D-galacturonate	UDP-D-galacturonate biosynthesis I (from UDP-D-glucuronate)
trehalose 6-phosphate	&alpha;,&alpha;-trehalose 6-phosphate	C12 H23 O14 P1 	C1(OC(COP(O)(=O)O)C(O)C(O)C(O)1)(OC2(OC(CO)C(O)C(O)C(O)2))	CAS:4484-88-2	3.1.3.12	trehalose 6-phosphate + H2O  =  trehalose + phosphate	trehalose biosynthesis
trehalose 6-phosphate	&alpha;,&alpha;-trehalose 6-phosphate	C12 H23 O14 P1 	C1(OC(COP(O)(=O)O)C(O)C(O)C(O)1)(OC2(OC(CO)C(O)C(O)C(O)2))	CAS:4484-88-2	2.4.1.15	UDP-D-glucose + alpha-D-glucose-6-phosphate  =  UDP + trehalose 6-phosphate	trehalose biosynthesis
octadec-9-ene-1,18-dioic-acid		C18 H32 O4 	C(=O)(O)CCCCCCCC=CCCCCCCCC(O)=O		1.1.1.-	18-oxooleate + NADP+ + H2O  =  octadec-9-ene-1,18-dioic-acid + NADPH	suberin biosynthesis
oxidized glutaredoxin	Grx*B0849*GrxA*glutaredoxin oxidized*protein-disulfide reductase (glutathione)*glutathione:protein-disulfide oxidoreductase				1.17.4.-	CDP + reduced glutaredoxin  =  dCDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
oxidized glutaredoxin	Grx*B0849*GrxA*glutaredoxin oxidized*protein-disulfide reductase (glutathione)*glutathione:protein-disulfide oxidoreductase				1.17.4.-	UDP + reduced glutaredoxin  =  dUDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
oxidized glutaredoxin	Grx*B0849*GrxA*glutaredoxin oxidized*protein-disulfide reductase (glutathione)*glutathione:protein-disulfide oxidoreductase				RXN0-747	ADP + reduced glutaredoxin  =  dADP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
oxidized glutaredoxin	Grx*B0849*GrxA*glutaredoxin oxidized*protein-disulfide reductase (glutathione)*glutathione:protein-disulfide oxidoreductase				RXN0-748	GDP + reduced glutaredoxin  =  dGDP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
indolylmethyl glucosinolate aglycone		C10 H10 N2 O4 S2 	c1(c(CC([SH])=NOS(O)(=O)=O)c2(c([nH]1)cccc2))		RXN-1444	indolylmethyl-glucosinolate + H2O  =  indolylmethyl glucosinolate aglycone + beta-D-glucose	glucosinolate biosynthesis from tryptophan
deoxyribose-5-phosphate	2-deoxy-D-ribose-5-phosphate*deoxyribose-5-P*2-deoxyribose-5-P*2-deoxyribose-5-phosphate*2-deoxy-&alpha;-D-ribose 5-phosphate	C5 H11 O7 P1 	C(OP(=O)(O)O)[CH]1([CH](O)[CH2][CH](O)O1)	CAS:102916-66-5	4.1.2.4	deoxyribose-5-phosphate  =  acetaldehyde + D-glyceraldehyde-3-phosphate	(deoxy)ribose phosphate degradation
deoxyribose-5-phosphate	2-deoxy-D-ribose-5-phosphate*deoxyribose-5-P*2-deoxyribose-5-P*2-deoxyribose-5-phosphate*2-deoxy-&alpha;-D-ribose 5-phosphate	C5 H11 O7 P1 	C(OP(=O)(O)O)[CH]1([CH](O)[CH2][CH](O)O1)	CAS:102916-66-5	5.4.2.7	deoxyribose-1-phosphate  =  deoxyribose-5-phosphate	(deoxy)ribose phosphate degradation
D-myo-inositol (1,2,4,5,6)-pentakisphosphate	1D-<i>myo</i>-inositol 1,2,4,5,6-penta<i>kis</i>phosphate*<i>myo</i>-inositol 1,2,4,5,6-penta<i>kis</i>phosphate*inositol 1,2,4,5,6-penta<i>kis</i>phosphate*Ins(1,2,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C1OP(O)([O-1])=O)(O)	CAS:20298-95-7	RXN-7243	D-myo-inositol (1,2,4,5,6)-pentakisphosphate + H2O  =  D-myo-inositol (1,2,5,6) tetrakisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,4,5,6)-pentakisphosphate	1D-<i>myo</i>-inositol 1,2,4,5,6-penta<i>kis</i>phosphate*<i>myo</i>-inositol 1,2,4,5,6-penta<i>kis</i>phosphate*inositol 1,2,4,5,6-penta<i>kis</i>phosphate*Ins(1,2,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C1OP(O)([O-1])=O)(O)	CAS:20298-95-7	3.1.3.8	phytate + H2O  =  D-myo-inositol (1,2,4,5,6)-pentakisphosphate + phosphate	phytate degradation I
D-myo-inositol (1,2,4,5,6)-pentakisphosphate	1D-<i>myo</i>-inositol 1,2,4,5,6-penta<i>kis</i>phosphate*<i>myo</i>-inositol 1,2,4,5,6-penta<i>kis</i>phosphate*inositol 1,2,4,5,6-penta<i>kis</i>phosphate*Ins(1,2,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C1OP(O)([O-1])=O)(O)	CAS:20298-95-7	2.7.1.-	D-myo-inositol (1,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,2,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
L-histidine	L-histidine*glyoxaline-5-alanine*&alpha;-amino-4-imidazoleproprionic acid*(S)-&alpha;-amino-1H-imidazole-4-propanoic acid*H*histidine*his	C6 H9 N3 O2 	C(O)(=O)[CH](N)Cc1(nc[nH]c1)	CAS:71-00-1*CAS:7006-35-1	6.1.1.21	tRNAhis + L-histidine + ATP  =  L-histidyl-tRNAhis + pyrophosphate + AMP	tRNA charging pathway
L-histidine	L-histidine*glyoxaline-5-alanine*&alpha;-amino-4-imidazoleproprionic acid*(S)-&alpha;-amino-1H-imidazole-4-propanoic acid*H*histidine*his	C6 H9 N3 O2 	C(O)(=O)[CH](N)Cc1(nc[nH]c1)	CAS:71-00-1*CAS:7006-35-1	1.1.1.23	histidinal + NAD+ + H2O  =  L-histidine + NADH	histidine biosynthesis
coniferaldehyde glucoside	coniferyl aldehyde-4-O-&beta;-D-glucopyranoside	C16 H20 O8 	C(=O)C=Cc1(cc(OC)c(cc1)OC2(OC(CO)C(O)C(O)C(O)2))		RXN-91	coniferyl aldehyde + UDP-D-glucose  =  coniferaldehyde glucoside + UDP	monolignol glucosides biosynthesis
dihydroconiferyl alcohol glucoside	dihydroconiferyl alcohol-4-O-&beta;-D-glucopyranoside	C16 H24 O8 	C1(C(O)C(O)C(O)C(O1)CO)Oc2(c(OC)cc(cc2)CCCO)		RXN-95	dihydroconiferyl alcohol + UDP-D-glucose  =  dihydroconiferyl alcohol glucoside + UDP	monolignol glucosides biosynthesis
2,3-diketo-5-methylthio-1-phosphopentane	DKM-1-P*1-phospho-2,3-diketo-5-methylthiopentane*1-phosphoryloxy-2,3-diketo-5-methylthiopentane	C6 H11 O6 P1 S1 	C(SC)CC(=O)C(=O)COP(O)(=O)O		R82-RXN	2,3-diketo-5-methylthio-1-phosphopentane  =  2-hydroxy-3-keto-5-methylthio-1-phosphopentene	methionine salvage pathway
2,3-diketo-5-methylthio-1-phosphopentane	DKM-1-P*1-phospho-2,3-diketo-5-methylthiopentane*1-phosphoryloxy-2,3-diketo-5-methylthiopentane	C6 H11 O6 P1 S1 	C(SC)CC(=O)C(=O)COP(O)(=O)O		R145-RXN	5-methylthioribulose-1-phosphate  =  2,3-diketo-5-methylthio-1-phosphopentane + H2O	methionine salvage pathway
1,2-dihydroxy-3-keto-5-methylthiopentene	1,2-dihydroxy-3-keto-5-methylthiopentene anion*1,2-dihydroxy-3-keto-5-methylthiopentane	C6 H10 O3 S1 	C(O)=C(O)C(=O)CCSC		R147-RXN	1,2-dihydroxy-3-keto-5-methylthiopentene + O2  =  2-oxo-4-methylthiobutanoic acid + formate	methionine salvage pathway
1,2-dihydroxy-3-keto-5-methylthiopentene	1,2-dihydroxy-3-keto-5-methylthiopentene anion*1,2-dihydroxy-3-keto-5-methylthiopentane	C6 H10 O3 S1 	C(O)=C(O)C(=O)CCSC		R83-RXN	2-hydroxy-3-keto-5-methylthio-1-phosphopentene + H2O  =  1,2-dihydroxy-3-keto-5-methylthiopentene + phosphate	methionine salvage pathway
mannitol-1-phosphate	D-mannitol-6-phosphate*mannitol-6-P*mannitol-1-P*D-mannitol-1-phosphate	C6 H15 O9 P1 	C(OP(O)(O)=O)C(O)C(O)C(O)C(O)CO	CAS:15806-48-1	1.1.1.224	NADPH + mannose-6-phosphate  =  NADP+ + mannitol-1-phosphate	mannitol biosynthesis
mannitol-1-phosphate	D-mannitol-6-phosphate*mannitol-6-P*mannitol-1-P*D-mannitol-1-phosphate	C6 H15 O9 P1 	C(OP(O)(O)=O)C(O)C(O)C(O)C(O)CO	CAS:15806-48-1	3.1.3.22	H2O + mannitol-1-phosphate  =  phosphate + mannitol	mannitol biosynthesis
N5-formyl-H4F	5-formyl-THF leucovorin*n5-formyltetrahydrofolate*n5-formyl-thf*5-formyltetrahydrofolate*5-formyl-H4F*5-formyl-THF*folinic acid*5-CHO-THF*folinate*formyl-H4F*citrovorum factor*N5-formyl-THF	C20 H23 N7 O7 	C([CH]1(N(C=O)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:58-05-9	6.3.3.2	N5-formyl-H4F + ATP  =  5,10-methenyl-THF + ADP + phosphate	formylTHF biosynthesis I
N5-formyl-H4F	5-formyl-THF leucovorin*n5-formyltetrahydrofolate*n5-formyl-thf*5-formyltetrahydrofolate*5-formyl-H4F*5-formyl-THF*folinic acid*5-CHO-THF*folinate*formyl-H4F*citrovorum factor*N5-formyl-THF	C20 H23 N7 O7 	C([CH]1(N(C=O)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	CAS:58-05-9	RXN-6321	5,10-methenyl-THF + H2O  =  N5-formyl-H4F	formylTHF biosynthesis I
L-seryl-tRNAser	L-SERYL-TRNA(SER)				6.1.1.11	tRNAser + L-serine + ATP  =  L-seryl-tRNAser + pyrophosphate + AMP	tRNA charging pathway
S-Methyl-L-methionine	S-methylmethionine	C6 H14 N1 O2 S1 	C(=O)(O)C(N)CC[S+1](C)C	CAS:4727-40-6	2.1.1.-	S-Methyl-L-methionine + homocysteine  =  2 L-methionine	methionine biosynthesis
alpha-D-glucose-6-phosphate	&alpha;-glucose-6-phosphate*&alpha;-D-glucose-6-P	C6 H13 O9 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00668*LIGAND:C00092*CAS:56-73-5	5.1.3.15	beta-D-glucose-6-phosphate  =  alpha-D-glucose-6-phosphate	starch biosynthesis
alpha-D-glucose-6-phosphate	&alpha;-glucose-6-phosphate*&alpha;-D-glucose-6-P	C6 H13 O9 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00668*LIGAND:C00092*CAS:56-73-5	5.1.3.15	beta-D-glucose-6-phosphate  =  alpha-D-glucose-6-phosphate	sucrose degradation
alpha-D-glucose-6-phosphate	&alpha;-glucose-6-phosphate*&alpha;-D-glucose-6-P	C6 H13 O9 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00668*LIGAND:C00092*CAS:56-73-5	2.4.1.15	UDP-D-glucose + alpha-D-glucose-6-phosphate  =  UDP + trehalose 6-phosphate	trehalose biosynthesis
alpha-D-glucose-6-phosphate	&alpha;-glucose-6-phosphate*&alpha;-D-glucose-6-P	C6 H13 O9 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00668*LIGAND:C00092*CAS:56-73-5	5.3.1.9	alpha-D-glucose-6-phosphate  =  D-fructose-6-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
alpha-D-glucose-6-phosphate	&alpha;-glucose-6-phosphate*&alpha;-D-glucose-6-P	C6 H13 O9 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00668*LIGAND:C00092*CAS:56-73-5	2.7.1.1	alpha-D-glucose + ATP  =  alpha-D-glucose-6-phosphate + ADP	sucrose degradation
alpha-D-glucose-6-phosphate	&alpha;-glucose-6-phosphate*&alpha;-D-glucose-6-P	C6 H13 O9 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00668*LIGAND:C00092*CAS:56-73-5	5.4.2.2	alpha-D-glucose-1-phosphate  =  alpha-D-glucose-6-phosphate	starch biosynthesis
alpha-D-glucose-6-phosphate	&alpha;-glucose-6-phosphate*&alpha;-D-glucose-6-P	C6 H13 O9 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00668*LIGAND:C00092*CAS:56-73-5	5.4.2.2	alpha-D-glucose-1-phosphate  =  alpha-D-glucose-6-phosphate	sucrose degradation
alpha-D-glucose-6-phosphate	&alpha;-glucose-6-phosphate*&alpha;-D-glucose-6-P	C6 H13 O9 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(O)C(O1)O)	LIGAND-CPD:C00668*LIGAND:C00092*CAS:56-73-5	5.4.2.2	alpha-D-glucose-1-phosphate  =  alpha-D-glucose-6-phosphate	sucrose degradation to ethanol and lactate (anaerobic)
4-(2'-carboxyphenyl)-4-oxobutyryl-CoA		C32 H44 N7 O20 P3 S1 	C(=O)(O)c1(c(cccc1)C(=O)CCC(=O)SCNC(=O)CCNC(=O)C(O)C(C)(C)COP(O)(=O)OP(O)(=O)OCC2(OC(C)(C(O)C2OP(O)(=O)O)n3(c4(c(nc3)c(N)ncn4))))		4.1.3.36	4-(2'-carboxyphenyl)-4-oxobutyryl-CoA  =  coenzyme A + 1,4-dihydroxy-2-naphthoate	phylloquinone biosynthesis
4-(2'-carboxyphenyl)-4-oxobutyryl-CoA		C32 H44 N7 O20 P3 S1 	C(=O)(O)c1(c(cccc1)C(=O)CCC(=O)SCNC(=O)CCNC(=O)C(O)C(C)(C)COP(O)(=O)OP(O)(=O)OCC2(OC(C)(C(O)C2OP(O)(=O)O)n3(c4(c(nc3)c(N)ncn4))))		6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  4-(2'-carboxyphenyl)-4-oxobutyryl-CoA + AMP + pyrophosphate	phylloquinone biosynthesis
12-oxo-cis-9-dodecenoate		C12 H20 O3 	C(=O)CC=CCCCCCCCC(O)=O		RXN-1349	12-oxo-cis-9-dodecenoate  =  12-oxo-trans-10-dodecenoate	lipoxygenase pathway
12-oxo-cis-9-dodecenoate		C12 H20 O3 	C(=O)CC=CCCCCCCCC(O)=O		RXN-1345	13(S)-hydroperoxylinolenate  =  12-oxo-cis-9-dodecenoate + cis-3-hexenal	lipoxygenase pathway
pyridoxal 5'-phosphate	PLP*pyridoxal phosphate*pyridoxal-5P*pyridoxal 5-phosphate*pyridoxal-P	C8 H10 N1 O6 P1 	c1(c(COP(O)(O)=O)c(C=O)c(O)c(C)n1)	LIGAND-CPD:C00018*CAS:54-47-7	2.7.1.35	ATP + pyridoxal  =  ADP + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
pyridoxal 5'-phosphate	PLP*pyridoxal phosphate*pyridoxal-5P*pyridoxal 5-phosphate*pyridoxal-P	C8 H10 N1 O6 P1 	c1(c(COP(O)(O)=O)c(C=O)c(O)c(C)n1)	LIGAND-CPD:C00018*CAS:54-47-7	PNPOXI-RXN	O2 + pyridoxine-5'-phosphate  =  H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
pyridoxal 5'-phosphate	PLP*pyridoxal phosphate*pyridoxal-5P*pyridoxal 5-phosphate*pyridoxal-P	C8 H10 N1 O6 P1 	c1(c(COP(O)(O)=O)c(C=O)c(O)c(C)n1)	LIGAND-CPD:C00018*CAS:54-47-7	1.4.3.5	O2 + H2O + pyridoxamine 5'-phosphate  =  NH3 + H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
cis-prenyl-tRNA					RXN-4545	cis-prenyl-tRNA  =  cis-zeatin riboside monophosphate	cis-zeatin biosynthesis
cis-prenyl-tRNA					RXN-4544	prenyl-tRNA  =  cis-prenyl-tRNA	cis-zeatin biosynthesis
5-methyl-THF	N5-methyltetrahydropteroyl mono-L-glutamate*5-methyl-tetrahydrofolate*5-methyl-5,6,7,8-tetrahydrofolate*n5-methyltetrahydrofolate*CH3-THF*n5-CH3-THF*n5-methyl-THF*methyl-THF*methyl-tetrahydrofolate*methyl-H4F	C20 H25 N7 O6 	C(C1(N(C)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	LIGAND-CPD:C00440*CAS:134-35-0	2.1.1.-	5-methyl-THF + [Co-E]  =  tetrahydrofolate + [Co-E-CH3]	carbon monoxide dehydrogenase pathway
5-methyl-THF	N5-methyltetrahydropteroyl mono-L-glutamate*5-methyl-tetrahydrofolate*5-methyl-5,6,7,8-tetrahydrofolate*n5-methyltetrahydrofolate*CH3-THF*n5-CH3-THF*n5-methyl-THF*methyl-THF*methyl-tetrahydrofolate*methyl-H4F	C20 H25 N7 O6 	C(C1(N(C)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	LIGAND-CPD:C00440*CAS:134-35-0	2.1.1.14	5-methyl-THF + homocysteine  =  tetrahydrofolate + L-methionine	SAM cycle
5-methyl-THF	N5-methyltetrahydropteroyl mono-L-glutamate*5-methyl-tetrahydrofolate*5-methyl-5,6,7,8-tetrahydrofolate*n5-methyltetrahydrofolate*CH3-THF*n5-CH3-THF*n5-methyl-THF*methyl-THF*methyl-tetrahydrofolate*methyl-H4F	C20 H25 N7 O6 	C(C1(N(C)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	LIGAND-CPD:C00440*CAS:134-35-0	2.1.1.14	5-methyl-THF + homocysteine  =  tetrahydrofolate + L-methionine	formylTHF biosynthesis I
5-methyl-THF	N5-methyltetrahydropteroyl mono-L-glutamate*5-methyl-tetrahydrofolate*5-methyl-5,6,7,8-tetrahydrofolate*n5-methyltetrahydrofolate*CH3-THF*n5-CH3-THF*n5-methyl-THF*methyl-THF*methyl-tetrahydrofolate*methyl-H4F	C20 H25 N7 O6 	C(C1(N(C)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	LIGAND-CPD:C00440*CAS:134-35-0	1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis
5-methyl-THF	N5-methyltetrahydropteroyl mono-L-glutamate*5-methyl-tetrahydrofolate*5-methyl-5,6,7,8-tetrahydrofolate*n5-methyltetrahydrofolate*CH3-THF*n5-CH3-THF*n5-methyl-THF*methyl-THF*methyl-tetrahydrofolate*methyl-H4F	C20 H25 N7 O6 	C(C1(N(C)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	LIGAND-CPD:C00440*CAS:134-35-0	1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis I
5-methyl-THF	N5-methyltetrahydropteroyl mono-L-glutamate*5-methyl-tetrahydrofolate*5-methyl-5,6,7,8-tetrahydrofolate*n5-methyltetrahydrofolate*CH3-THF*n5-CH3-THF*n5-methyl-THF*methyl-THF*methyl-tetrahydrofolate*methyl-H4F	C20 H25 N7 O6 	C(C1(N(C)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	LIGAND-CPD:C00440*CAS:134-35-0	2.1.1.13	homocysteine + 5-methyl-THF  =  L-methionine + tetrahydrofolate	formylTHF biosynthesis
5-methyl-THF	N5-methyltetrahydropteroyl mono-L-glutamate*5-methyl-tetrahydrofolate*5-methyl-5,6,7,8-tetrahydrofolate*n5-methyltetrahydrofolate*CH3-THF*n5-CH3-THF*n5-methyl-THF*methyl-THF*methyl-tetrahydrofolate*methyl-H4F	C20 H25 N7 O6 	C(C1(N(C)c2(c(NC1)nc(N)[nH]c2=O)))Nc3(ccc(cc3)C(=O)NC(C(O)=O)CCC(O)=O)	LIGAND-CPD:C00440*CAS:134-35-0	METLENETHFRED-FERRE-RXN	5,10-methylene-THF + reduced ferredoxin  =  5-methyl-THF + oxidized ferredoxin	carbon monoxide dehydrogenase pathway
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		2.4.1.46	1,2-diacylglycerol + UDP-galactose  =  mono-beta-D-galactosyldiacylglycerol + UDP	glycolipid biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		2.3.1.20	acyl-CoA + 1,2-diacylglycerol  =  triacylglycerol + coenzyme A	triacylglycerol biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		RXN-1224	UDP-sulfoquinovose + 1,2-diacylglycerol  =  sulfoquinovosyldiacylglycerol + UDP	sulfolipid biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		2.7.8.1	1,2-diacylglycerol + CDP-ethanolamine  =  L-1-phosphatidyl-ethanolamine + CMP	phospholipid biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		2.7.8.2	1,2-diacylglycerol + CDP-choline  =  a phosphatidylcholine + CMP	phospholipid biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		RXN-1641	a phosphatidylcholine + 1,2-diacylglycerol  =  triacylglycerol + 1-acyl-sn-glycero-3-phosphocholine	triacylglycerol biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		RXN-1602	1,2-diacylglycerol + H2O  =  2-acylglycerol + a fatty acid	triacylglycerol degradation
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		2.7.8.2	1,2-diacylglycerol + CDP-choline  =  a phosphatidylcholine + CMP	choline biosynthesis III
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		3.1.4.11	phosphatidyl-myo-inositol 4,5-biphosphate + H2O  =  1,2-diacylglycerol + inositol 1,4,5-trisphosphate	lipases pathway
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		2.4.1.184	2 mono-beta-D-galactosyldiacylglycerol  =  alpha-D-galactosyl-beta-D-galactosyldiacylglycerol + 1,2-diacylglycerol	glycolipid biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		3.1.3.4	H2O + L-phosphatidate  =  phosphate + 1,2-diacylglycerol	triacylglycerol biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		3.1.3.4	H2O + L-phosphatidate  =  phosphate + 1,2-diacylglycerol	phospholipid biosynthesis
1,2-diacylglycerol	1,2-diasylglycerol*1,2-diacyl-SN-glycerol*D-1,2-Diacylglycerol*DAG	C5 H6 O5 R11 R21 	C(O)C(OC(=O)[R2])COC(=O)[R1]		3.1.1.3	H2O + triacylglycerol  =  a fatty acid + 1,2-diacylglycerol	triacylglycerol degradation
lupeol	lupenol*farganasterol*clerodol*monogynol B	C30 H50 O1 	CC(=C)C1([CH]2(C(CC1)(C)CCC3(C4([CH](CC[CH]23)C5([CH](CC4)C(C)(C)C(O)CC5)(C))(C))(C)))		5.4.99.-	(S)-2,3-Epoxysqualene  =  lupeol	lupeol biosynthesis
tryptamine	3-(2-aminoethyl)indole	C10 H12 N2 	C(N)Cc1(c2(c([nH]c1)cccc2))	CAS:61-54-1	RXN-1405	tryptamine + O2 + NADPH  =  N-hydroxyl-tryptamine + H2O + NADP+	IAA biosynthesis I
tryptamine	3-(2-aminoethyl)indole	C10 H12 N2 	C(N)Cc1(c2(c([nH]c1)cccc2))	CAS:61-54-1	1.4.3.6	tryptamine + H2O + O2  =  NH3 + indole acetaldehyde + H2O2	IAA biosynthesis I
tryptamine	3-(2-aminoethyl)indole	C10 H12 N2 	C(N)Cc1(c2(c([nH]c1)cccc2))	CAS:61-54-1	4.1.1.28	L-tryptophan  =  CO2 + tryptamine	IAA biosynthesis I
dihydroconiferyl alcohol		C10 H14 O3 	C(O)CCc1(cc(OC)c(O)cc1)		RXN-95	dihydroconiferyl alcohol + UDP-D-glucose  =  dihydroconiferyl alcohol glucoside + UDP	monolignol glucosides biosynthesis
dTDP-D-glucose	dTDP-glucose	C16 H26 N2 O16 P2 	Cc1(cn(c(=O)[nH]c(=O)1)C2(OC(C(O)C2)COP(O)(=O)OP(O)(=O)OC3(OC(CO)C(O)C(O)C(O)3)))		4.2.1.46	dTDP-D-glucose  =  H2O + dTDP-4-dehydro-6-deoxy-D-glucose	dTDP-L-rhamnose biosynthesis
protoheme	haemin*heme*hemin*ferroprotoporphyrin*heme b*protoheme IX*hematin	C34 H32 N4 O4 FE1 	Cc8(c4(n7([Fe]35(n1(c(c(C)c(C=C)c1=CC2(C(C)=C(C(N=23)=C4)C=C))=CC6(=N5C(C(=C6C)CCC(=O)O)=Cc7c8CCC(=O)O))))))	CAS:14875-96-8	2.5.1.-	protoheme + trans, trans-farnesyl diphosphate + H2O  =  heme O + pyrophosphate	biosynthesis of proto- and siroheme
protoheme	haemin*heme*hemin*ferroprotoporphyrin*heme b*protoheme IX*hematin	C34 H32 N4 O4 FE1 	Cc8(c4(n7([Fe]35(n1(c(c(C)c(C=C)c1=CC2(C(C)=C(C(N=23)=C4)C=C))=CC6(=N5C(C(=C6C)CCC(=O)O)=Cc7c8CCC(=O)O))))))	CAS:14875-96-8	4.99.1.1	Fe2+ + protoporphyrin IX  =  2 H+ + protoheme	biosynthesis of proto- and siroheme
1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate	HMBDP	C5 H12 O8 P2 	CC(CO)=CCOP(=O)(O)OP(=O)(O)O		RXN0-884	1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + 2 H+  =  dimethylallyl-pyrophosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate	HMBDP	C5 H12 O8 P2 	CC(CO)=CCOP(=O)(O)OP(=O)(O)O		1.17.1.2	1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + 2 H+  =  delta3-isopentenyl-PP + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate	HMBDP	C5 H12 O8 P2 	CC(CO)=CCOP(=O)(O)OP(=O)(O)O		1.17.4.3	2-C-methyl-D-erythritol-2,4-cyclodiphosphate + e- + H+  =  1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
2-oxobutanoate	2-oxobutyrate*2-ketobutyrate*2-oxobutyric acid*&alpha;-oxobutyric acid*&alpha;-ketobutyrate*&alpha;-ketobutyric acid*2-oxo-butyrate*2-keto-butyrate*2-ketobutyric acid	C4 H6 O3 	C(O)(=O)C(=O)CC	CAS:600-18-0	ALPHA-KETOBUTYRATE-DEHYDROG-RXN	2-oxobutanoate + coenzyme A + NAD+  =  propionyl-CoA + CO2 + NADH	methionine degradation I
2-oxobutanoate	2-oxobutyrate*2-ketobutyrate*2-oxobutyric acid*&alpha;-oxobutyric acid*&alpha;-ketobutyrate*&alpha;-ketobutyric acid*2-oxo-butyrate*2-keto-butyrate*2-ketobutyric acid	C4 H6 O3 	C(O)(=O)C(=O)CC	CAS:600-18-0	2.2.1.6	pyruvate + 2-oxobutanoate  =  2-aceto-2-hydroxy-butyrate + CO2	isoleucine biosynthesis
2-oxobutanoate	2-oxobutyrate*2-ketobutyrate*2-oxobutyric acid*&alpha;-oxobutyric acid*&alpha;-ketobutyrate*&alpha;-ketobutyric acid*2-oxo-butyrate*2-keto-butyrate*2-ketobutyric acid	C4 H6 O3 	C(O)(=O)C(=O)CC	CAS:600-18-0	4.3.1.19	L-threonine  =  2-oxobutanoate + NH3	isoleucine biosynthesis
2-oxobutanoate	2-oxobutyrate*2-ketobutyrate*2-oxobutyric acid*&alpha;-oxobutyric acid*&alpha;-ketobutyrate*&alpha;-ketobutyric acid*2-oxo-butyrate*2-keto-butyrate*2-ketobutyric acid	C4 H6 O3 	C(O)(=O)C(=O)CC	CAS:600-18-0	4.4.1.-	homoserine + H2O  =  2-oxobutanoate + NH4+ + H2O	methionine degradation I
2-oxobutanoate	2-oxobutyrate*2-ketobutyrate*2-oxobutyric acid*&alpha;-oxobutyric acid*&alpha;-ketobutyrate*&alpha;-ketobutyric acid*2-oxo-butyrate*2-keto-butyrate*2-ketobutyric acid	C4 H6 O3 	C(O)(=O)C(=O)CC	CAS:600-18-0	4.4.1.1	cystathionine + H2O  =  NH3 + 2-oxobutanoate + L-cysteine	homocysteine and cysteine interconversion
2-oxobutanoate	2-oxobutyrate*2-ketobutyrate*2-oxobutyric acid*&alpha;-oxobutyric acid*&alpha;-ketobutyrate*&alpha;-ketobutyric acid*2-oxo-butyrate*2-keto-butyrate*2-ketobutyric acid	C4 H6 O3 	C(O)(=O)C(=O)CC	CAS:600-18-0	4.4.1.11	L-methionine + H2O  =  NH3 + 2-oxobutanoate + methanethiol	methionine degradation II
cis-zeatin	cZ	C10 H13 N5 O1 	c2(ncnc1(c(N=CN1)2))(NCC=C(C)CO)		2.4.1.-	cis-zeatin + UDP-D-glucose  =  cis-zeatin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
cis-zeatin	cZ	C10 H13 N5 O1 	c2(ncnc1(c(N=CN1)2))(NCC=C(C)CO)		2.4.1.-	cis-zeatin + UDP-D-glucose  =  cis-zeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
cis-zeatin	cZ	C10 H13 N5 O1 	c2(ncnc1(c(N=CN1)2))(NCC=C(C)CO)		1.5.99.12	cis-zeatin + H2O + FAD  =  3-methyl-4-cis-hydroxy-2-butenal + adenine + FADH2	cytokinins degradation
cis-zeatin	cZ	C10 H13 N5 O1 	c2(ncnc1(c(N=CN1)2))(NCC=C(C)CO)		RXN-4541	cis-zeatin riboside + H2O  =  cis-zeatin + D-ribose	cis-zeatin biosynthesis
shikimate-3-phosphate	shikimate-5-phosphate*shikimate-5-P*3-phosphoshikimate*5-phosphoshikimate*shikimate-3-P	C7 H11 O8 P1 	C(O)(=O)C1(=[CH][CH]([CH](O)[CH]([CH2]1)O)OP(O)(O)=O)		2.5.1.19	shikimate-3-phosphate + phosphoenolpyruvate  =  5-enolpyruvyl-shikimate-3-phosphate + phosphate	chorismate biosynthesis
shikimate-3-phosphate	shikimate-5-phosphate*shikimate-5-P*3-phosphoshikimate*5-phosphoshikimate*shikimate-3-P	C7 H11 O8 P1 	C(O)(=O)C1(=[CH][CH]([CH](O)[CH]([CH2]1)O)OP(O)(O)=O)		2.7.1.71	shikimate + ATP  =  shikimate-3-phosphate + ADP	chorismate biosynthesis
cis-zeatin riboside	cZR	C15 H21 N5 O5 	C1(O[CH](CO)C(O)C(O)1)N2(c3(c(N=C2)c(ncn3)NCC=C(C)CO))		RXN-4541	cis-zeatin riboside + H2O  =  cis-zeatin + D-ribose	cis-zeatin biosynthesis
cis-zeatin riboside	cZR	C15 H21 N5 O5 	C1(O[CH](CO)C(O)C(O)1)N2(c3(c(N=C2)c(ncn3)NCC=C(C)CO))		RXN-4542	cis-zeatin riboside monophosphate + H2O  =  cis-zeatin riboside + phosphate	cis-zeatin biosynthesis
(N-acetylglucosaminyl)2-diphosphodolichol	chitobiosyldiphosphodolichol*N,N'-diacetylchitobiosyldiphosphodolichol*{<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C96 H160 N2 O17 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(C(NC(C)=O)C(O)C(O)C(O2)CO))		2.4.1.142	(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
(N-acetylglucosaminyl)2-diphosphodolichol	chitobiosyldiphosphodolichol*N,N'-diacetylchitobiosyldiphosphodolichol*{<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C96 H160 N2 O17 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(C(NC(C)=O)C(O)C(O)C(O2)CO))		2.4.1.141	N-acetylglucosaminyl-diphosphodolichol + UDP-N-acetyl-D-glucosamine  =  (N-acetylglucosaminyl)2-diphosphodolichol + UDP	dolichyl-diphosphooligosaccharide biosynthesis
cis-zeatin riboside monophosphate	cZRMP	C15 H22 N5 O8 P1 	C1(O[CH](C(O)C(O)1)COP(O)(=O)O)N2(c3(c(N=C2)c(ncn3)NCC=C(C)CO))		RXN-4542	cis-zeatin riboside monophosphate + H2O  =  cis-zeatin riboside + phosphate	cis-zeatin biosynthesis
cis-zeatin riboside monophosphate	cZRMP	C15 H22 N5 O8 P1 	C1(O[CH](C(O)C(O)1)COP(O)(=O)O)N2(c3(c(N=C2)c(ncn3)NCC=C(C)CO))		RXN-4545	cis-prenyl-tRNA  =  cis-zeatin riboside monophosphate	cis-zeatin biosynthesis
1,2-bis-O-sinapoyl-beta-D-glucoside		C28 H34 O14 	C(O)C2(OC(OC(=O)CCc1(cc(OC)c(O)c(c1)OC))C(C(O)C2O)OC(=O)C=Cc3(cc(OC)c(O)c(c3)OC))	PUBCHEM:440280	2.3.1.103	2 1-O-sinapoyl-beta-D-glucose  =  1,2-bis-O-sinapoyl-beta-D-glucoside + beta-D-glucose	sinapate ester biosynthesis
1-acylglycerophosphocholine	1-lysolecithin*1-lysophosphatidylcholine*&alpha;'-acylglycerophosphocholine*L-1-lysolecithin	C9 H19 N1 O7 R1 P1 			3.1.1.4	a phosphatidylcholine + H2O  =  1-acylglycerophosphocholine + a carboxylate	lipases pathway
indole-3-acetyl-beta-1-D-glucose	1-O-indol-3-ylacetyl-&beta;-D-glucose	C16 H19 N1 O7 	c1(c(c2(c([nH]1)cccc2))CC(=O)OC3(C(O)C(O)C(O)C(O3)CO))		2.4.1.121	indole-3-acetate + UDP-D-glucose  =  indole-3-acetyl-beta-1-D-glucose + UDP	IAA conjugate biosynthesis
mevalonate	(R)-mevalonate*mevalonic acid	C6 H12 O4 	C(O)CC(C)(O)CC(O)=O	CAS:150-97-0	1.1.1.34	2 NADPH + 3-hydroxy-3-methyl-glutaryl-CoA  =  2 NADP+ + coenzyme A + mevalonate	mevalonate pathway
mevalonate	(R)-mevalonate*mevalonic acid	C6 H12 O4 	C(O)CC(C)(O)CC(O)=O	CAS:150-97-0	2.7.1.36	mevalonate + ATP  =  mevalonate-5P + ADP	mevalonate pathway
tRNAthr	TRNA(THR)				6.1.1.3	tRNAthr + L-threonine + ATP  =  L-threonyl-tRNAthr + pyrophosphate + AMP	tRNA charging pathway
oxidized ferredoxin	Fdx				1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	ammonia assimilation cycle
oxidized ferredoxin	Fdx				1.4.7.1	2 reduced ferredoxin + alpha-ketoglutarate + L-glutamine  =  2 oxidized ferredoxin + 2 L-glutamate	glutamate biosynthesis I
oxidized ferredoxin	Fdx				1.8.7.1	3 reduced ferredoxin + SO3-2  =  H2O + oxidized ferredoxin + H2S	sulfate assimilation
oxidized ferredoxin	Fdx				1.7.7.-	NO2- + reduced ferredoxin  =  NH3 + H2O + oxidized ferredoxin	nitrate assimilation pathway
oxidized ferredoxin	Fdx				METLENETHFRED-FERRE-RXN	5,10-methylene-THF + reduced ferredoxin  =  5-methyl-THF + oxidized ferredoxin	carbon monoxide dehydrogenase pathway
D-myo-inositol (1,3,4,5,6)-pentakisphosphate	Ins(1,3,4,5,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*I(1,3,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-independent phytate biosynthesis
D-myo-inositol (1,3,4,5,6)-pentakisphosphate	Ins(1,3,4,5,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*I(1,3,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
D-myo-inositol (1,3,4,5,6)-pentakisphosphate	Ins(1,3,4,5,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*I(1,3,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
D-myo-inositol (1,3,4,5,6)-pentakisphosphate	Ins(1,3,4,5,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*I(1,3,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.134	D-myo-inositol (3,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-independent phytate biosynthesis
D-myo-inositol (1,3,4,5,6)-pentakisphosphate	Ins(1,3,4,5,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*I(1,3,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.140	D-myo-inositol (1,3,4,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
D-myo-inositol (1,3,4,5,6)-pentakisphosphate	Ins(1,3,4,5,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*I(1,3,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.-	1D-myo-inositol 1,3,4,5-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
D-myo-inositol (1,3,4,5,6)-pentakisphosphate	Ins(1,3,4,5,6)P<sub>5</sub>*1D-<i>myo</i>-inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*inositol (1,3,4,5,6)-penta<i>kis</i>phosphate*I(1,3,4,5,6)P<sub>5</sub>	C6 H12 O21 P5 	C1(C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(OP(O)([O-1])=O)C(C(O)1)OP(O)([O-1])=O)(OP(O)([O-1])=O)		2.7.1.-	D-myo-inositol (1,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
N-acetylglutamyl-phosphate	<i>N</i>-acetyl-5-glutamyl phosphate*<i>N</i>-acetylglutamyl-P*<i>N</i>-acetyl-glutamyl-P*<i>N</i>-acetyl-L-glutamate-5-phosphate*N-acetyl-L-glutamate-5-phosphate*N-acetyl-glutamyl-P*N-acetylglutamyl-P*N-acetyl-5-glutamyl phosphate	C7 H12 N1 O8 P1 	CC(=O)NC(C(O)=O)CCC(=O)OP(O)(O)=O		1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis
N-acetylglutamyl-phosphate	<i>N</i>-acetyl-5-glutamyl phosphate*<i>N</i>-acetylglutamyl-P*<i>N</i>-acetyl-glutamyl-P*<i>N</i>-acetyl-L-glutamate-5-phosphate*N-acetyl-L-glutamate-5-phosphate*N-acetyl-glutamyl-P*N-acetylglutamyl-P*N-acetyl-5-glutamyl phosphate	C7 H12 N1 O8 P1 	CC(=O)NC(C(O)=O)CCC(=O)OP(O)(O)=O		1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis II (acetyl cycle)
N-acetylglutamyl-phosphate	<i>N</i>-acetyl-5-glutamyl phosphate*<i>N</i>-acetylglutamyl-P*<i>N</i>-acetyl-glutamyl-P*<i>N</i>-acetyl-L-glutamate-5-phosphate*N-acetyl-L-glutamate-5-phosphate*N-acetyl-glutamyl-P*N-acetylglutamyl-P*N-acetyl-5-glutamyl phosphate	C7 H12 N1 O8 P1 	CC(=O)NC(C(O)=O)CCC(=O)OP(O)(O)=O		2.7.2.8	N-acetyl-L-glutamate + ATP  =  N-acetylglutamyl-phosphate + ADP	arginine biosynthesis
N-acetylglutamyl-phosphate	<i>N</i>-acetyl-5-glutamyl phosphate*<i>N</i>-acetylglutamyl-P*<i>N</i>-acetyl-glutamyl-P*<i>N</i>-acetyl-L-glutamate-5-phosphate*N-acetyl-L-glutamate-5-phosphate*N-acetyl-glutamyl-P*N-acetylglutamyl-P*N-acetyl-5-glutamyl phosphate	C7 H12 N1 O8 P1 	CC(=O)NC(C(O)=O)CCC(=O)OP(O)(O)=O		2.7.2.8	N-acetyl-L-glutamate + ATP  =  N-acetylglutamyl-phosphate + ADP	arginine biosynthesis II (acetyl cycle)
sterculate	sterculic acid	C19 H34 O2 	CCCCCCCCC1(=C(C1)CCCCCCCC(O)=O)		RXN-7422	dihydrosterculate  =  sterculate	cyclopropane and cyclopropene fatty acid biosynthesis
galacturonate	D-galacturonate*D-galaturonate*galaturonate*D-galacturonic acid	C6 H10 O7 	C1(OC(C(=O)O)C(O)C(O)C(O)1)(O)	LIGAND-CPD:C00333*CAS:685-73-4	2.7.1.44	galacturonate + ATP  =  alpha-D-galacturonate 1-phosphate + ADP	UDP-D-galacturonate biosynthesis II (from D-galacturonate)
CDP-choline	citicoline*citicholine*cidifos*cyticholine*cytidine 5'-diphosphocholine*cytidine diphosphate choline	C14 H27 N4 O11 P2 	C(OP(O)(=O)OP(O)(=O)OCC[N+1](C)(C)C)C1(OC(C(O)C1O)n2(c(=O)nc(N)cc2))	CAS:987-78-0	2.7.8.2	1,2-diacylglycerol + CDP-choline  =  a phosphatidylcholine + CMP	phospholipid biosynthesis
CDP-choline	citicoline*citicholine*cidifos*cyticholine*cytidine 5'-diphosphocholine*cytidine diphosphate choline	C14 H27 N4 O11 P2 	C(OP(O)(=O)OP(O)(=O)OCC[N+1](C)(C)C)C1(OC(C(O)C1O)n2(c(=O)nc(N)cc2))	CAS:987-78-0	2.7.8.2	1,2-diacylglycerol + CDP-choline  =  a phosphatidylcholine + CMP	choline biosynthesis III
CDP-choline	citicoline*citicholine*cidifos*cyticholine*cytidine 5'-diphosphocholine*cytidine diphosphate choline	C14 H27 N4 O11 P2 	C(OP(O)(=O)OP(O)(=O)OCC[N+1](C)(C)C)C1(OC(C(O)C1O)n2(c(=O)nc(N)cc2))	CAS:987-78-0	2.7.7.15	phosphoryl-choline + CTP  =  CDP-choline + pyrophosphate	choline biosynthesis III
eriodictyol		C15 H12 O6 	c3(c2(OC(c1(ccc(O)c(O)c1))CC(=O)c2c(O)cc(O)3))		RXN-7653	eriodictyol + NADPH + O2  =  luteolin + NADP+ + 2 H2O	luteolin biosynthesis
eriodictyol		C15 H12 O6 	c3(c2(OC(c1(ccc(O)c(O)c1))CC(=O)c2c(O)cc(O)3))		1.14.11.22	eriodictyol + alpha-ketoglutarate + O2  =  luteolin + succinate + CO2 + H2O	luteolin biosynthesis
eriodictyol		C15 H12 O6 	c3(c2(OC(c1(ccc(O)c(O)c1))CC(=O)c2c(O)cc(O)3))		1.14.13.21	naringenin + NADPH + O2  =  eriodictyol + NADP+ + H2O	luteolin biosynthesis
indole-S-cysteine-adduct		C12 H14 N2 O3 S1 	c1(c(C([OH])SCC([NH2])C([OH])=O)c2(c([nH]1)cccc2))		RXN1F-14	indole-S-cysteine-adduct  =  indole carboxyl tetrahydro-thiazole + H2O	camalexin biosynthesis
indole-S-cysteine-adduct		C12 H14 N2 O3 S1 	c1(c(C([OH])SCC([NH2])C([OH])=O)c2(c([nH]1)cccc2))		RXN1F-13	indole-3-carboxaldehyde + L-cysteine  =  indole-S-cysteine-adduct	camalexin biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.7.4.6	UDP + ATP  =  UTP + ADP	de novo biosynthesis of pyrimidine ribonucleotides
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	1.17.4.-	UDP + reduced glutaredoxin  =  dUDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	1.17.4.1	Reduced Thioredoxin + UDP  =  Oxidized Thioredoxin + dUDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.111	coniferyl alcohol + UDP-D-glucose  =  coniferin + UDP	coniferin metabolism
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.111	sinapyl-alcohol + UDP-D-glucose  =  syringin + UDP	monolignol glucosides biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	RXN-91	coniferyl aldehyde + UDP-D-glucose  =  coniferaldehyde glucoside + UDP	monolignol glucosides biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	RXN-92	sinapaldehyde + UDP-D-glucose  =  sinapaldehyde glucoside + UDP	monolignol glucosides biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	RXN-95	dihydroconiferyl alcohol + UDP-D-glucose  =  dihydroconiferyl alcohol glucoside + UDP	monolignol glucosides biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.117	dolichyl-phosphate + UDP-D-glucose  =  dolichyl beta-D-glucosyl phosphate + UDP	dolichyl-diphosphooligosaccharide biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	RXN-6142	p-aminobenzoate + UDP-D-glucose  =  p-aminobenzoate-beta-D-glucopyranosyl ester + UDP	tetrahydrofolate biosynthesis I
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	RXN1F-444	kaempferol-3-glucoside-7-rhamnoside + UDP-D-glucose  =  kaempferol-3-O-gentiobioside-7-O-rhamnoside + UDP	flavonol biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.120	sinapate + UDP-D-glucose  =  1-O-sinapoyl-beta-D-glucose + UDP	sinapate ester biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	phenylacetothiohydroximate + UDP-D-glucose  =  benzyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from phenylalanine
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.203	trans-zeatin + UDP-D-glucose  =  trans-zeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.215	cis-zeatin + UDP-D-glucose  =  cis-zeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	dihydrozeatin-9-N-glucoside + UDP-D-glucose  =  dihydrozeatin-9-N-glucoside-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.91	quercetin + UDP-D-glucose  =  quercetin-3-glucoside + UDP	flavonol biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.91	kaempferol + UDP-D-glucose  =  kaempferol-3-glucoside + UDP	flavonol biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	RXN1F-775	cyanidin + UDP-D-glucose  =  cyanidin-3-glucoside + UDP	anthocyanin biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	pelargonidin + UDP-D-glucose  =  pelargonidin-3-glucoside + UDP	anthocyanin biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	trans-zeatin + UDP-D-glucose  =  trans-zeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	isopentenyladenine + UDP-D-glucose  =  isopentenyladenine-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	benzyladenine + UDP-D-glucose  =  benzyladenine-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	kinetin + UDP-D-glucose  =  kinetin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	cis-zeatin + UDP-D-glucose  =  cis-zeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	trans-zeatin + UDP-D-glucose  =  trans-zeatin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-7-N-dihydrozeatin + UDP	cytokinins 7-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	isopentenyladenine + UDP-D-glucose  =  isopentenyladenine-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	benzyladenine + UDP-D-glucose  =  benzyladenine-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	kinetin + UDP-D-glucose  =  kinetin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	cis-zeatin + UDP-D-glucose  =  cis-zeatin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	trans-zeatin-O-glucoside + UDP-D-glucose  =  trans-zeatin-O-glucoside-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	4-methylthiobutylhydroximate + UDP-D-glucose  =  3-methylthiopropyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from homomethionine
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.-	indolylmethylthiohydroximate + UDP-D-glucose  =  indolylmethyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from tryptophan
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.182	2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate + UDP-2,3-bis(3-hydroxymyristoyl)glucosamine  =  lipid A disaccharide + UDP	lipid-A-precursor biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.141	N-acetylglucosaminyl-diphosphodolichol + UDP-N-acetyl-D-glucosamine  =  (N-acetylglucosaminyl)2-diphosphodolichol + UDP	dolichyl-diphosphooligosaccharide biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	RXN-1224	UDP-sulfoquinovose + 1,2-diacylglycerol  =  sulfoquinovosyldiacylglycerol + UDP	sulfolipid biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	RXN-1225	mono-beta-D-galactosyldiacylglycerol + UDP-galactose  =  alpha-D-galactosyl-beta-D-galactosyldiacylglycerol + UDP	glycolipid biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.12	UDP-D-glucose + (1,4-beta-D-glucosyl)(n)  =  UDP + (1,4-beta-D-glucosyl)(n+1)	cellulose biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.7.4.-	ATP + UMP  =  ADP + UDP	de novo biosynthesis of pyrimidine ribonucleotides
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.121	indole-3-acetate + UDP-D-glucose  =  indole-3-acetyl-beta-1-D-glucose + UDP	IAA conjugate biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.46	1,2-diacylglycerol + UDP-galactose  =  mono-beta-D-galactosyldiacylglycerol + UDP	glycolipid biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.14	D-fructose-6-phosphate + UDP-D-glucose  =  sucrose-6'-phosphate + UDP	sucrose biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose degradation
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose degradation to ethanol and lactate (anaerobic)
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	galactose degradation I
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose biosynthesis
UDP	uridine-diphosphate*uridine-5'-diphosphate	C9 H14 N2 O12 P2 	c1(n(c(=O)[nH]c(=O)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	LIGAND-CPD:C00015*CAS:58-98-0	2.4.1.15	UDP-D-glucose + alpha-D-glucose-6-phosphate  =  UDP + trehalose 6-phosphate	trehalose biosynthesis
5-dehydro episterol		C28 H44 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC=3)CC(O)CC4)(C))))		1.3.1.21	5-dehydro episterol + 2 NADPH  =  24-methylenecholesterol + 2 NADP+	sterol biosynthesis
5-dehydro episterol		C28 H44 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC=3)CC(O)CC4)(C))))		1.3.3.-	episterol  =  5-dehydro episterol	sterol biosynthesis
3-hydroxy-isobutyryl-CoA	3-Hydroxy-2-methylpropanoyl-CoA*3-hydroxy-isobutyryl-coenzyme A*3-Hydroxy-2-methylpropionyl-CoA	C25 H42 N7 O18 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)CO)		3.1.2.4	H2O + 3-hydroxy-isobutyryl-CoA  =  3-hydroxy-isobutyrate + coenzyme A	valine degradation
3-hydroxy-isobutyryl-CoA	3-Hydroxy-2-methylpropanoyl-CoA*3-hydroxy-isobutyryl-coenzyme A*3-Hydroxy-2-methylpropionyl-CoA	C25 H42 N7 O18 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)CO)		4.2.1.17	methacrylyl-CoA + H2O  =  3-hydroxy-isobutyryl-CoA	valine degradation
tRNAasn	TRNA(ASN)				6.1.1.22	tRNAasn + L-asparagine + ATP  =  L-asparaginyl-tRNAasn + pyrophosphate + AMP	tRNA charging pathway
5-methylthioribose	S5-methyl-5-thio-D-ribose*5-methylthio-D-ribose*MTR	C6 H12 O4 S1 	C1(OC(CSC)C(O)C(O)1)(O)		2.7.1.100	5-methylthioribose + ATP  =  5-methylthioribose-1-phosphate + ADP	methionine salvage pathway
5-methylthioribose	S5-methyl-5-thio-D-ribose*5-methylthio-D-ribose*MTR	C6 H12 O4 S1 	C1(OC(CSC)C(O)C(O)1)(O)		3.2.2.16	H2O + 5'-methylthioadenosine  =  5-methylthioribose + adenine	methionine salvage pathway
24-methylenecholesterol		C28 H46 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4222	24-methylenecholesterol  =  24-methyldesmosterol	sterol biosynthesis
24-methylenecholesterol		C28 H46 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		1.3.1.21	5-dehydro episterol + 2 NADPH  =  24-methylenecholesterol + 2 NADP+	sterol biosynthesis
campesterol		C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		5.3.3.1	campesterol  =  campest-4-en-3beta-ol	brassinosteroid biosynthesis III
campesterol		C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		5.3.3.1	campesterol  =  campest-4-en-3beta-ol	brassinosteroid biosynthesis II
campesterol		C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		5.3.3.1	campesterol  =  campest-4-en-3beta-ol	brassinosteroid biosynthesis I
campesterol		C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-4242	campesterol  =  brassicasterol	sterol biosynthesis
campesterol		C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		1.1.1.51	campesterol + NAD(P)+  =  campest-4-en-3-one + NAD(P)H	brassinosteroid biosynthesis III
campesterol		C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		1.1.1.145	campesterol + NAD+  =  campest-5-en-3-one + NADH	brassinosteroid biosynthesis III
campesterol		C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		1.14.-.-	campesterol + O2 + reduced acceptor  =  (22alpha)-hydroxy-campesterol + H2O + acceptor	brassinosteroid biosynthesis II
campesterol		C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(=CC3)CC(O)CC4)(C))))		RXN-708	24-methyldesmosterol  =  campesterol	sterol biosynthesis
campest-4-en-3beta-ol	methylcholestenol*(24<i>R</i>)-24-methyl-cholest-4-en-3&beta;-ol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(O)CC4)(C))))		1.1.1.145	campest-4-en-3beta-ol  =  campest-4-en-3-one	brassinosteroid biosynthesis III
campest-4-en-3beta-ol	methylcholestenol*(24<i>R</i>)-24-methyl-cholest-4-en-3&beta;-ol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(O)CC4)(C))))		1.1.1.145	campest-4-en-3beta-ol  =  campest-4-en-3-one	brassinosteroid biosynthesis II
campest-4-en-3beta-ol	methylcholestenol*(24<i>R</i>)-24-methyl-cholest-4-en-3&beta;-ol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(O)CC4)(C))))		1.1.1.145	campest-4-en-3beta-ol  =  campest-4-en-3-one	brassinosteroid biosynthesis I
campest-4-en-3beta-ol	methylcholestenol*(24<i>R</i>)-24-methyl-cholest-4-en-3&beta;-ol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(O)CC4)(C))))		5.3.3.1	campesterol  =  campest-4-en-3beta-ol	brassinosteroid biosynthesis III
campest-4-en-3beta-ol	methylcholestenol*(24<i>R</i>)-24-methyl-cholest-4-en-3&beta;-ol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(O)CC4)(C))))		5.3.3.1	campesterol  =  campest-4-en-3beta-ol	brassinosteroid biosynthesis II
campest-4-en-3beta-ol	methylcholestenol*(24<i>R</i>)-24-methyl-cholest-4-en-3&beta;-ol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4(C(CC3)=CC(O)CC4)(C))))		5.3.3.1	campesterol  =  campest-4-en-3beta-ol	brassinosteroid biosynthesis I
5alpha-campestan-3-one	methylcholestanone*(24<i>R</i>)-24-methyl-5&alpha;-cholestan-3-one*3-dehydro-campestanol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		RXN-712	5alpha-campestan-3-one  =  campestanol	brassinosteroid biosynthesis II
5alpha-campestan-3-one	methylcholestanone*(24<i>R</i>)-24-methyl-5&alpha;-cholestan-3-one*3-dehydro-campestanol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		RXN-712	5alpha-campestan-3-one  =  campestanol	brassinosteroid biosynthesis I
5alpha-campestan-3-one	methylcholestanone*(24<i>R</i>)-24-methyl-5&alpha;-cholestan-3-one*3-dehydro-campestanol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		RXN-4230	5alpha-campestan-3-one + O2  =  22alpha-hydroxy-5alpha-campestan-3-one + H2O	brassinosteroid biosynthesis II
5alpha-campestan-3-one	methylcholestanone*(24<i>R</i>)-24-methyl-5&alpha;-cholestan-3-one*3-dehydro-campestanol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis III
5alpha-campestan-3-one	methylcholestanone*(24<i>R</i>)-24-methyl-5&alpha;-cholestan-3-one*3-dehydro-campestanol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis II
5alpha-campestan-3-one	methylcholestanone*(24<i>R</i>)-24-methyl-5&alpha;-cholestan-3-one*3-dehydro-campestanol	C28 H48 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		1.3.99.-	campest-4-en-3-one + NADPH  =  5alpha-campestan-3-one + NADP+	brassinosteroid biosynthesis I
D-lactate	(R)-2-hydroxypropanate*(R)-lactate*lactate	C3 H6 O3 	C(O)(=O)[CH](O)C	CAS:10326-41-7	3.1.2.6	S-lactoyl-glutathione + H2O  =  glutathione + D-lactate	threonine degradation
D-lactate	(R)-2-hydroxypropanate*(R)-lactate*lactate	C3 H6 O3 	C(O)(=O)[CH](O)C	CAS:10326-41-7	3.1.2.6	S-lactoyl-glutathione + H2O  =  glutathione + D-lactate	methylglyoxal degradation
L-tyrosyl-tRNAtyr	L-TYROSYL-TRNA(TYR)				6.1.1.1	L-tyrosine + tRNAtyr + ATP  =  L-tyrosyl-tRNAtyr + pyrophosphate + AMP	tRNA charging pathway
a ubiquinone	ubiquinones*coenzyme-Q<SUB>n</SUB>*ubiquinone				1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	aerobic respiration
a ubiquinone	ubiquinones*coenzyme-Q<SUB>n</SUB>*ubiquinone				1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	superpathway of glyoxylate cycle
a ubiquinone	ubiquinones*coenzyme-Q<SUB>n</SUB>*ubiquinone				1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	TCA cycle -- aerobic respiration
a ubiquinone	ubiquinones*coenzyme-Q<SUB>n</SUB>*ubiquinone				1.6.5.3	a ubiquinone + NADH  =  a ubiquinol + NAD+	aerobic respiration
a ubiquinone	ubiquinones*coenzyme-Q<SUB>n</SUB>*ubiquinone				1.10.2.2	2 ferricytochrome c + a ubiquinol  =  2 ferrocytochrome c + a ubiquinone	aerobic respiration
GA36	GA36*gibberellin A36*gibberellin A<sub>36</sub>	C20 H26 O6 	CC1([CH]4(C(CCC(O)1)(C=O)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA36 + O2 + alpha-ketoglutarate  =  GA4 + succinate + 2 CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
GA36	GA36*gibberellin A36*gibberellin A<sub>36</sub>	C20 H26 O6 	CC1([CH]4(C(CCC(O)1)(C=O)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA37 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2 + H2O	gibberellin biosynthesis II (early C-3 hydroxylation)
GA36	GA36*gibberellin A36*gibberellin A<sub>36</sub>	C20 H26 O6 	CC1([CH]4(C(CCC(O)1)(C=O)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
dihydrogeranylgeranyl-chlorophyll a	dihydrogeranylgeranyl-chl a*dihydroGG-chl a*dihydroGG-chlorophyll a	C55 H68 N4 O5 MG1 	CC(CCCC(C)CCC=C(C)CCC=C(C)C)=CCOC(=O)CCC6(C4(C1(C(C(=O)OC)C(=O)c2(c(C)c7(n(c=12)[Mg]58(n3(c(c(C=C)c(C)c3C=C(N=45)C(C)6)C=C9(C(C)=C(CC)C(C=7)=N89))))))))		1.3.1.-	dihydrogeranylgeranyl-chlorophyll a + NADPH  =  tetrahydrogeranylgeranyl-chlorophyll a + NADP+	chlorophyll a biosynthesis II
dihydrogeranylgeranyl-chlorophyll a	dihydrogeranylgeranyl-chl a*dihydroGG-chl a*dihydroGG-chlorophyll a	C55 H68 N4 O5 MG1 	CC(CCCC(C)CCC=C(C)CCC=C(C)C)=CCOC(=O)CCC6(C4(C1(C(C(=O)OC)C(=O)c2(c(C)c7(n(c=12)[Mg]58(n3(c(c(C=C)c(C)c3C=C(N=45)C(C)6)C=C9(C(C)=C(CC)C(C=7)=N89))))))))		1.3.1.-	geranylgeranyl-chlorophyll a + NADPH  =  dihydrogeranylgeranyl-chlorophyll a + NADP+	chlorophyll a biosynthesis II
GA37	GA37*gibberellin A37*gibberellin A<sub>37</sub>	C20 H28 O6 	CC1([CH]4(C(CCC(O)1)(CO)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA37 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2 + H2O	gibberellin biosynthesis II (early C-3 hydroxylation)
GA37	GA37*gibberellin A37*gibberellin A<sub>37</sub>	C20 H28 O6 	CC1([CH]4(C(CCC(O)1)(CO)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA14 + O2 + alpha-ketoglutarate  =  GA37 + CO2 + succinate	gibberellin biosynthesis II (early C-3 hydroxylation)
GA37	GA37*gibberellin A37*gibberellin A<sub>37</sub>	C20 H28 O6 	CC1([CH]4(C(CCC(O)1)(CO)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA15 + alpha-ketoglutarate + O2  =  GA37 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
geranylgeranyl-chlorophyll a	geranylgeranyl-chl <i>a</i>*GG-chl <i>a</i>*GG-chlorophyll <i>a</i>	C55 H66 N4 O5 MG1 	CC(CCC=C(C)CCC=C(C)CCC=C(C)C)=CCOC(=O)CCC6(C4(C1(C(C(=O)OC)C(=O)c2(c(C)c7(n(c=12)[Mg]58(n3(c(c(C=C)c(C)c3C=C(N=45)C(C)6)C=C9(C(C)=C(CC)C(C=7)=N89))))))))		1.3.1.-	geranylgeranyl-chlorophyll a + NADPH  =  dihydrogeranylgeranyl-chlorophyll a + NADP+	chlorophyll a biosynthesis II
geranylgeranyl-chlorophyll a	geranylgeranyl-chl <i>a</i>*GG-chl <i>a</i>*GG-chlorophyll <i>a</i>	C55 H66 N4 O5 MG1 	CC(CCC=C(C)CCC=C(C)CCC=C(C)C)=CCOC(=O)CCC6(C4(C1(C(C(=O)OC)C(=O)c2(c(C)c7(n(c=12)[Mg]58(n3(c(c(C=C)c(C)c3C=C(N=45)C(C)6)C=C9(C(C)=C(CC)C(C=7)=N89))))))))		2.5.1.-	chlorophyllide a + geranylgeranyl-PP  =  geranylgeranyl-chlorophyll a + pyrophosphate	chlorophyll a biosynthesis II
GA38	GA38*gibberellin A38*gibberellin A<sub>38</sub>	C20 H28 O7 	CC1([CH]4(C(CCC(O)1)(CO)[CH]3(C2(CC(C(=C)C2)(O)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA38 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
tetrahydrogeranylgeranyl-chlorophyll a	tetrahydroGG-chlorophyll <i>a</i>*tetrahydroGG-chl <i>a</i>*tetrahydrogeranylgeranyl-chl <i>a</i>	C55 H70 N4 O5 MG1 	CC(CCCC(C)CCCC(C)CCC=C(C)C)=CCOC(=O)CCC6(C4(C1(C(C(=O)OC)C(=O)c2(c(C)c7(n(c=12)[Mg]58(n3(c(c(C=C)c(C)c3C=C(N=45)C(C)6)C=C9(C(C)=C(CC)C(C=7)=N89))))))))		1.3.1.-	tetrahydrogeranylgeranyl-chlorophyll a + NADPH  =  chlorophyll a + NADP+	chlorophyll a biosynthesis II
tetrahydrogeranylgeranyl-chlorophyll a	tetrahydroGG-chlorophyll <i>a</i>*tetrahydroGG-chl <i>a</i>*tetrahydrogeranylgeranyl-chl <i>a</i>	C55 H70 N4 O5 MG1 	CC(CCCC(C)CCCC(C)CCC=C(C)C)=CCOC(=O)CCC6(C4(C1(C(C(=O)OC)C(=O)c2(c(C)c7(n(c=12)[Mg]58(n3(c(c(C=C)c(C)c3C=C(N=45)C(C)6)C=C9(C(C)=C(CC)C(C=7)=N89))))))))		1.3.1.-	dihydrogeranylgeranyl-chlorophyll a + NADPH  =  tetrahydrogeranylgeranyl-chlorophyll a + NADP+	chlorophyll a biosynthesis II
fructose	laevosan*levugen*laevoral*fructosteril*levulose*fru*fru-ring*D-fructose-ring*D-fructose	C6 H12 O6 	C(O)C1(OC(CO)(O)C(O)C(O)1)	CAS:30237-26-4	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose degradation
fructose	laevosan*levugen*laevoral*fructosteril*levulose*fru*fru-ring*D-fructose-ring*D-fructose	C6 H12 O6 	C(O)C1(OC(CO)(O)C(O)C(O)1)	CAS:30237-26-4	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose degradation to ethanol and lactate (anaerobic)
fructose	laevosan*levugen*laevoral*fructosteril*levulose*fru*fru-ring*D-fructose-ring*D-fructose	C6 H12 O6 	C(O)C1(OC(CO)(O)C(O)C(O)1)	CAS:30237-26-4	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	galactose degradation I
fructose	laevosan*levugen*laevoral*fructosteril*levulose*fru*fru-ring*D-fructose-ring*D-fructose	C6 H12 O6 	C(O)C1(OC(CO)(O)C(O)C(O)1)	CAS:30237-26-4	2.4.1.13	fructose + UDP-D-glucose  =  sucrose + UDP	sucrose biosynthesis
fructose	laevosan*levugen*laevoral*fructosteril*levulose*fru*fru-ring*D-fructose-ring*D-fructose	C6 H12 O6 	C(O)C1(OC(CO)(O)C(O)C(O)1)	CAS:30237-26-4	2.7.1.4	fructose + ATP  =  D-fructose-6-phosphate + ADP	sucrose degradation
fructose	laevosan*levugen*laevoral*fructosteril*levulose*fru*fru-ring*D-fructose-ring*D-fructose	C6 H12 O6 	C(O)C1(OC(CO)(O)C(O)C(O)1)	CAS:30237-26-4	2.7.1.4	fructose + ATP  =  D-fructose-6-phosphate + ADP	sucrose degradation to ethanol and lactate (anaerobic)
fructose	laevosan*levugen*laevoral*fructosteril*levulose*fru*fru-ring*D-fructose-ring*D-fructose	C6 H12 O6 	C(O)C1(OC(CO)(O)C(O)C(O)1)	CAS:30237-26-4	3.2.1.26	sucrose + H2O  =  alpha-D-glucose + fructose	sucrose degradation
isopentenyladenine-7-N-glucoside		C16 H23 N5 O5 	c2(c1(N(C=Nc1ncn2)C3(OC(CO)C(O)C(O)C(O)3)))(NCC=C(C)C)		2.4.1.-	isopentenyladenine + UDP-D-glucose  =  isopentenyladenine-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
isopentenyladenine-9-N-glucoside		C16 H23 N5 O5 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCC=C(C)C)		2.4.1.-	isopentenyladenine + UDP-D-glucose  =  isopentenyladenine-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
caffeoylshikimate		C16 H16 O8 	C(=O)(O)C1(CC(C(O)C(C=1)O)OC(=O)C=CC2(C=C(O)C(O)=CC=2))		2.3.1.133	caffeoylshikimate + coenzyme A  =  caffeoyl-CoA + shikimate	lignin biosynthesis
caffeoylshikimate		C16 H16 O8 	C(=O)(O)C1(CC(C(O)C(C=1)O)OC(=O)C=CC2(C=C(O)C(O)=CC=2))		1.14.13.36	4-coumaroylshikimate + NADPH + O2  =  caffeoylshikimate + NADP+ + H2O	lignin biosynthesis
benzyladenine		C12 H11 N5 	c2(ncnc1(c(N=CN1)2))(NCc3(ccccc3))		2.4.1.-	benzyladenine + UDP-D-glucose  =  benzyladenine-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
benzyladenine		C12 H11 N5 	c2(ncnc1(c(N=CN1)2))(NCc3(ccccc3))		2.4.1.-	benzyladenine + UDP-D-glucose  =  benzyladenine-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
beta-D-glucuronide	acceptor-&beta;-D-glucuronoside*&beta;-D-glucuronoside*acceptor &beta;-D-glucuronoside*glucuronide	C6 H9 O7 R1 			3.2.1.31	H2O + beta-D-glucuronide  =  glucuronate + an alcohol	beta-D-glucuronide degradation
benzyladenine-7-N-glucoside		C18 H21 N5 O5 	c2(c1(N(C=Nc1ncn2)C3(OC(CO)C(O)C(O)C(O)3)))(NCc4(ccccc4))		2.4.1.-	benzyladenine + UDP-D-glucose  =  benzyladenine-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
benzyladenine-9-N-glucoside		C18 H21 N5 O5 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCc4(ccccc4))		2.4.1.-	benzyladenine + UDP-D-glucose  =  benzyladenine-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
thymine	5-methyluracil*5-methyl-2,4(1H,3H)-pyrimidinedione	C5 H6 N2 O2 	c1(c(C)c(=O)[nH]c(=O)[nH]1)	LIGAND-CPD:C00178*CAS:65-71-4	2.4.2.4	phosphate + thymidine  =  deoxyribose-1-phosphate + thymine	(deoxy)ribose phosphate degradation
guanosine diphosphate fucose	guanosine 5'-(trihydrogen diphosphate), P'-(6-deoxy-&beta;-L- galactopyranosyl) ester*guanosine diphosphate fucose*GDP-L-fucose*guanosine 5'-(trihydrogen diphosphate), P'-(6-deoxy-beta-L- galactopyranosyl) ester*2-amino-9-[3,4-dihydroxy-5-[[hydroxy-[hydroxy-(3,4,5-trihydroxy- 6-methyl-tetrahydropyran-2-yl)oxy-phosphinoyl]oxy-phosphinoyl] oxymethyl]tetrahydrofuran-2-yl]-1,9-dihydropurin-6-one	C16 H25 N5 O15 P2 	C(OP(=O)(O)OP(=O)(O)OC1(C(O)C(O)C(O)C(O1)C))C2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N)))	CAS:15839-70-0	1.1.1.271	NADPH + GDP-4-dehydro-6-deoxy-D-mannose  =  NADP+ + guanosine diphosphate fucose	GDP-L-fucose biosynthesis I (from GDP-D-mannose)
guanosine diphosphate fucose	guanosine 5'-(trihydrogen diphosphate), P'-(6-deoxy-&beta;-L- galactopyranosyl) ester*guanosine diphosphate fucose*GDP-L-fucose*guanosine 5'-(trihydrogen diphosphate), P'-(6-deoxy-beta-L- galactopyranosyl) ester*2-amino-9-[3,4-dihydroxy-5-[[hydroxy-[hydroxy-(3,4,5-trihydroxy- 6-methyl-tetrahydropyran-2-yl)oxy-phosphinoyl]oxy-phosphinoyl] oxymethyl]tetrahydrofuran-2-yl]-1,9-dihydropurin-6-one	C16 H25 N5 O15 P2 	C(OP(=O)(O)OP(=O)(O)OC1(C(O)C(O)C(O)C(O1)C))C2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N)))	CAS:15839-70-0	2.7.7.30	beta-L-fucose 1-phosphate + GTP  =  guanosine diphosphate fucose + pyrophosphate	GDP-L-fucose biosynthesis II (from L-fucose)
guanosine diphosphate fucose	guanosine 5'-(trihydrogen diphosphate), P'-(6-deoxy-&beta;-L- galactopyranosyl) ester*guanosine diphosphate fucose*GDP-L-fucose*guanosine 5'-(trihydrogen diphosphate), P'-(6-deoxy-beta-L- galactopyranosyl) ester*2-amino-9-[3,4-dihydroxy-5-[[hydroxy-[hydroxy-(3,4,5-trihydroxy- 6-methyl-tetrahydropyran-2-yl)oxy-phosphinoyl]oxy-phosphinoyl] oxymethyl]tetrahydrofuran-2-yl]-1,9-dihydropurin-6-one	C16 H25 N5 O15 P2 	C(OP(=O)(O)OP(=O)(O)OC1(C(O)C(O)C(O)C(O1)C))C2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N)))	CAS:15839-70-0	1.-.-.-	GDP-4-dehydro-6-L-deoxygalactose + NADPH  =  guanosine diphosphate fucose + NADP+	colanic acid building blocks biosynthesis
kinetin		C10 H9 N5 O1 	c2(ncnc1(c(NC=N1)2))(NCc3(occc3))		2.4.1.-	kinetin + UDP-D-glucose  =  kinetin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
kinetin		C10 H9 N5 O1 	c2(ncnc1(c(NC=N1)2))(NCc3(occc3))		2.4.1.-	kinetin + UDP-D-glucose  =  kinetin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
Large-branched-glucans					3.2.1.41	Large-branched-glucans  =  Long-linear-glucans	starch degradation
Large-branched-glucans					3.2.1.1	Starch  =  Large-branched-glucans	starch degradation
D-glucosamine-6-phosphate	D-glucosamine phosphate*D-glucosamine 6-phosphate*D-glucosamine-6-P*glucosamine-6-P*glucosamine-6-phosphate	C6 H14 N1 O8 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(N)C(O1)O)	CAS:3616-42-0	PHOSGLUCOSAMINEMUT-RXN	D-glucosamine-6-phosphate  =  glucosamine-1P	UDP-N-acetyl-D-glucosamine biosynthesis
D-glucosamine-6-phosphate	D-glucosamine phosphate*D-glucosamine 6-phosphate*D-glucosamine-6-P*glucosamine-6-P*glucosamine-6-phosphate	C6 H14 N1 O8 P1 	C(OP(O)(O)=O)C1(C(O)C(O)C(N)C(O1)O)	CAS:3616-42-0	2.6.1.16	D-fructose-6-phosphate + L-glutamine  =  D-glucosamine-6-phosphate + L-glutamate	UDP-N-acetyl-D-glucosamine biosynthesis
acyl carrier protein	B1094*AcpP*holo-[acyl-carrier protein]*ACP-SH*ACP			SWISSPROT:P02901*ECOCYC:LIPOYL-ACP	2.3.1.39	acyl carrier protein + malonyl-CoA  =  malonyl-ACP + coenzyme A	fatty acid biosynthesis - initial steps
acyl carrier protein	B1094*AcpP*holo-[acyl-carrier protein]*ACP-SH*ACP			SWISSPROT:P02901*ECOCYC:LIPOYL-ACP	2.3.1.41	acyl-ACP + malonyl-ACP  =  acyl carrier protein + beta-ketoacyl-ACP + CO2	fatty acid elongation -- saturated
acyl carrier protein	B1094*AcpP*holo-[acyl-carrier protein]*ACP-SH*ACP			SWISSPROT:P02901*ECOCYC:LIPOYL-ACP	2.3.1.-	UDP-3-O-(3-hydroxymyristoyl)glucosamine + (R)-3-hydroxymyristoyl-ACP  =  UDP-2,3-bis(3-hydroxymyristoyl)glucosamine + acyl carrier protein	lipid-A-precursor biosynthesis
acyl carrier protein	B1094*AcpP*holo-[acyl-carrier protein]*ACP-SH*ACP			SWISSPROT:P02901*ECOCYC:LIPOYL-ACP	2.3.1.129	(R)-3-hydroxymyristoyl-ACP + UDP-N-acetyl-D-glucosamine  =  UDP-3-O-(3-hydroxymyristoyl)-N-acetylglucosamine + acyl carrier protein	lipid-A-precursor biosynthesis
campestanol	5&alpha;-campestanol	C28 H50 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-773	campestanol + O2  =  6-deoxocathasterone + H2O	brassinosteroid biosynthesis II
campestanol	5&alpha;-campestanol	C28 H50 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-773	campestanol + O2  =  6-deoxocathasterone + H2O	brassinosteroid biosynthesis I
campestanol	5&alpha;-campestanol	C28 H50 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		1.14.-.-	campestanol + O2 + reduced acceptor  =  (6alpha)-hydroxycampestanol + H2O + acceptor	brassinosteroid biosynthesis I
campestanol	5&alpha;-campestanol	C28 H50 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-712	5alpha-campestan-3-one  =  campestanol	brassinosteroid biosynthesis II
campestanol	5&alpha;-campestanol	C28 H50 O1 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-712	5alpha-campestan-3-one  =  campestanol	brassinosteroid biosynthesis I
(6alpha)-hydroxycampestanol	hydroxycampestanol	C28 H50 O2 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(O)C3)CC(O)CC4)(C))))		RXN-714	(6alpha)-hydroxycampestanol  =  6-oxocampestanol	brassinosteroid biosynthesis I
(6alpha)-hydroxycampestanol	hydroxycampestanol	C28 H50 O2 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(O)C3)CC(O)CC4)(C))))		1.14.-.-	campestanol + O2 + reduced acceptor  =  (6alpha)-hydroxycampestanol + H2O + acceptor	brassinosteroid biosynthesis I
6-deoxocathasterone	deoxocathasterone	C28 H50 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		1.14.-.-	6-deoxocathasterone + O2  =  6-deoxoteasterone + H2O	brassinosteroid biosynthesis II
6-deoxocathasterone	deoxocathasterone	C28 H50 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		1.14.-.-	6-deoxocathasterone + O2  =  6-deoxoteasterone + H2O	brassinosteroid biosynthesis I
6-deoxocathasterone	deoxocathasterone	C28 H50 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-4228	22alpha-hydroxy-5alpha-campestan-3-one  =  6-deoxocathasterone	brassinosteroid biosynthesis II
6-deoxocathasterone	deoxocathasterone	C28 H50 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-773	campestanol + O2  =  6-deoxocathasterone + H2O	brassinosteroid biosynthesis II
6-deoxocathasterone	deoxocathasterone	C28 H50 O2 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-773	campestanol + O2  =  6-deoxocathasterone + H2O	brassinosteroid biosynthesis I
4-methylthiobutanaldoxime		C5 H11 N1 O1 S1 	C(SC)CCC=NO		RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
4-methylthiobutanaldoxime		C5 H11 N1 O1 S1 	C(SC)CCC=NO		1.14.13.-	homomethionine + NADPH + O2  =  4-methylthiobutanaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from homomethionine
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	mannitol degradation
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	mannitol biosynthesis
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	colanic acid building blocks biosynthesis
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	ascorbate biosynthesis
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	5.3.1.8	mannose-6-phosphate  =  D-fructose-6-phosphate	GDP-D-rhamnose biosynthesis
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	1.1.1.224	NADPH + mannose-6-phosphate  =  NADP+ + mannitol-1-phosphate	mannitol biosynthesis
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	2.7.1.7	mannose + ATP  =  mannose-6-phosphate + ADP	mannitol degradation
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	5.4.2.8	mannose-6-phosphate  =  mannose-1-phosphate	colanic acid building blocks biosynthesis
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	5.4.2.8	mannose-6-phosphate  =  mannose-1-phosphate	ascorbate biosynthesis
mannose-6-phosphate	D-mannose-6-phosphate*&alpha;-D-mannose-6-phosphate*&alpha;-D-mannose-6-P	C6 H13 O9 P1 	C(OP(O)(=O)O)C1(C(O)C(O)C(O)C(O)O1)	CAS:3672-15-9	5.4.2.8	mannose-6-phosphate  =  mannose-1-phosphate	GDP-D-rhamnose biosynthesis
6-oxocampestanol	oxocampestanol	C28 H48 O2 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		1.14.-.-	6-oxocampestanol + O2 + reduced acceptor  =  cathasterone + H2O + acceptor	brassinosteroid biosynthesis I
6-oxocampestanol	oxocampestanol	C28 H48 O2 	CC(C)C(C)CCC(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		RXN-714	(6alpha)-hydroxycampestanol  =  6-oxocampestanol	brassinosteroid biosynthesis I
cathasterone		C28 H48 O3 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		1.14.-.-	cathasterone + O2 + reduced acceptor  =  teasterone + H2O + acceptor	brassinosteroid biosynthesis I
cathasterone		C28 H48 O3 	CC(C)C(C)CC(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		1.14.-.-	6-oxocampestanol + O2 + reduced acceptor  =  cathasterone + H2O + acceptor	brassinosteroid biosynthesis I
6-deoxoteasterone	deoxoteasterone	C28 H50 O3 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-775	6-deoxoteasterone  =  3-dehydro-6-deoxoteasterone	brassinosteroid biosynthesis I
6-deoxoteasterone	deoxoteasterone	C28 H50 O3 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		1.14.-.-	6-deoxocathasterone + O2  =  6-deoxoteasterone + H2O	brassinosteroid biosynthesis II
6-deoxoteasterone	deoxoteasterone	C28 H50 O3 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		1.14.-.-	6-deoxocathasterone + O2  =  6-deoxoteasterone + H2O	brassinosteroid biosynthesis I
teasterone		C28 H48 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		RXN-717	teasterone  =  3-dehydroteasterone	brassinosteroid biosynthesis I
teasterone		C28 H48 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		1.14.-.-	cathasterone + O2 + reduced acceptor  =  teasterone + H2O + acceptor	brassinosteroid biosynthesis I
3-dehydro-6-deoxoteasterone	dehydro-deoxoteasterone	C28 H48 O3 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		RXN-776	3-dehydro-6-deoxoteasterone  =  6-deoxotyphasterol	brassinosteroid biosynthesis I
3-dehydro-6-deoxoteasterone	dehydro-deoxoteasterone	C28 H48 O3 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(=O)CC4)(C))))		RXN-775	6-deoxoteasterone  =  3-dehydro-6-deoxoteasterone	brassinosteroid biosynthesis I
hydroxymethylpyrimidine	6-amino-5-hydroxymethyl-2-methylpyrimidine*4-amino-2-methyl-5-pyrimidinemethanol*pyramine*pyramin*Toxopyrimidine*HMP*4-amino-2-methyl-5-hydroxymethylpyrimidine*4-amino-5-hydroxymethyl-2-methylpyrimidine	C6 H9 N3 O1 	c1(c(CO)c(N)nc(C)n1)	CAS:73-67-6	2.7.1.49	ATP + hydroxymethylpyrimidine  =  ADP + hydroxymethylpyrimidine phosphate	thiamin biosynthesis
3-dehydroteasterone	dehydroteasterone	C28 H46 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(=O)CC4)(C))))		RXN-718	3-dehydroteasterone  =  typhasterol	brassinosteroid biosynthesis I
3-dehydroteasterone	dehydroteasterone	C28 H46 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(=O)CC4)(C))))		RXN-717	teasterone  =  3-dehydroteasterone	brassinosteroid biosynthesis I
typhasterol		C28 H48 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		1.14.-.-	typhasterol + O2 + reduced acceptor  =  castasterone + H2O + acceptor	brassinosteroid biosynthesis I
typhasterol		C28 H48 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		RXN-718	3-dehydroteasterone  =  typhasterol	brassinosteroid biosynthesis I
typhasterol		C28 H48 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(=O)C3)CC(O)CC4)(C))))		RXN-4241	6-deoxotyphasterol + O2  =  typhasterol + H2O	brassinosteroid biosynthesis I
hydroxymethylbilane		C40 H46 N4 O17 	C(O)c1([nH]c(c(CCC(=O)O)c1CC(O)=O)Cc2([nH]c(c(c2CC(=O)O)CCC(O)=O)Cc3([nH]c(c(CCC(=O)O)c3CC(O)=O)Cc4(c(CC(=O)O)c(c[nH]4)CCC(=O)O))))	CAS:73023-76-4	4.2.1.75	hydroxymethylbilane  =  uroporphyrinogen-III + H2O	chlorophyllide a biosynthesis
hydroxymethylbilane		C40 H46 N4 O17 	C(O)c1([nH]c(c(CCC(=O)O)c1CC(O)=O)Cc2([nH]c(c(c2CC(=O)O)CCC(O)=O)Cc3([nH]c(c(CCC(=O)O)c3CC(O)=O)Cc4(c(CC(=O)O)c(c[nH]4)CCC(=O)O))))	CAS:73023-76-4	4.2.1.75	hydroxymethylbilane  =  uroporphyrinogen-III + H2O	biosynthesis of proto- and siroheme
hydroxymethylbilane		C40 H46 N4 O17 	C(O)c1([nH]c(c(CCC(=O)O)c1CC(O)=O)Cc2([nH]c(c(c2CC(=O)O)CCC(O)=O)Cc3([nH]c(c(CCC(=O)O)c3CC(O)=O)Cc4(c(CC(=O)O)c(c[nH]4)CCC(=O)O))))	CAS:73023-76-4	2.5.1.61	H2O + 4 porphobilinogen  =  4 NH3 + hydroxymethylbilane	chlorophyllide a biosynthesis
hydroxymethylbilane		C40 H46 N4 O17 	C(O)c1([nH]c(c(CCC(=O)O)c1CC(O)=O)Cc2([nH]c(c(c2CC(=O)O)CCC(O)=O)Cc3([nH]c(c(CCC(=O)O)c3CC(O)=O)Cc4(c(CC(=O)O)c(c[nH]4)CCC(=O)O))))	CAS:73023-76-4	2.5.1.61	H2O + 4 porphobilinogen  =  4 NH3 + hydroxymethylbilane	biosynthesis of proto- and siroheme
Reduced Thioredoxin					1.17.4.1	Reduced Thioredoxin + GDP  =  Oxidized Thioredoxin + dGDP + H2O	de novo biosynthesis of purine nucleotides I
Reduced Thioredoxin					1.17.4.1	Reduced Thioredoxin + ADP  =  Oxidized Thioredoxin + dADP + H2O	de novo biosynthesis of purine nucleotides I
Reduced Thioredoxin					1.17.4.1	Reduced Thioredoxin + CDP  =  Oxidized Thioredoxin + dCDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
Reduced Thioredoxin					1.17.4.1	Reduced Thioredoxin + UDP  =  Oxidized Thioredoxin + dUDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
orotate	orotic acid	C5 H4 N2 O4 	C(O)(=O)c1([nH]c(=O)[nH]c(c1)=O)	CAS:65-86-1	1.3.3.1	O2 + dihydroorotate  =  H2O2 + orotate	de novo biosynthesis of pyrimidine ribonucleotides
orotate	orotic acid	C5 H4 N2 O4 	C(O)(=O)c1([nH]c(=O)[nH]c(c1)=O)	CAS:65-86-1	2.4.2.10	PRPP + orotate  =  orotidine-5'-phosphate + pyrophosphate	de novo biosynthesis of pyrimidine ribonucleotides
chlorophyllide b		C35 H32 N4 O6 MG1 	CCC9(C1(=N8([Mg]46(N5(=C(C2(C(C(=O)OC)C(=O)c3(c(C)c(=C1)n(c=23)4)))C(CCC(=O)O)C(C)C5=Cc7(n6c(c(C=C)c(C)7)C=C8C=9C=O))))))		2.5.1.-	chlorophyllide b + phytyl pyrophosphate  =  chlorophyll b + pyrophosphate	chlorophyll cycle
chlorophyllide b		C35 H32 N4 O6 MG1 	CCC9(C1(=N8([Mg]46(N5(=C(C2(C(C(=O)OC)C(=O)c3(c(C)c(=C1)n(c=23)4)))C(CCC(=O)O)C(C)C5=Cc7(n6c(c(C=C)c(C)7)C=C8C=9C=O))))))		RXN-7677	7-hydroxy-chlorophyllide a + O2 + NADPH  =  chlorophyllide b + 2 H2O + NADP+	chlorophyll cycle
7-hydroxy-chlorophyllide a	7-OH-chlorophyllide a	C35 H34 N4 O6 MG1 	CCC9(C1(=N8([Mg]46(N5(=C(C2(C(C(=O)OC)C(=O)c3(c(C)c(=C1)n(c=23)4)))C(CCC(=O)O)C(C)C5=Cc7(n6c(c(C=C)c(C)7)C=C8C=9CO))))))		RXN-7677	7-hydroxy-chlorophyllide a + O2 + NADPH  =  chlorophyllide b + 2 H2O + NADP+	chlorophyll cycle
7-hydroxy-chlorophyllide a	7-OH-chlorophyllide a	C35 H34 N4 O6 MG1 	CCC9(C1(=N8([Mg]46(N5(=C(C2(C(C(=O)OC)C(=O)c3(c(C)c(=C1)n(c=23)4)))C(CCC(=O)O)C(C)C5=Cc7(n6c(c(C=C)c(C)7)C=C8C=9CO))))))		RXN-7676	chlorophyllide a + O2 + NADPH  =  7-hydroxy-chlorophyllide a + H2O + NADP+	chlorophyll cycle
7-hydroxy-chlorophyll a	7-OH-chlorophyll a	C55 H72 N4 O6 MG1 	CC(CCCC(C)CCCC(C)CCCC(C)C)=CCOC(=O)CCC7(C6(C1(C(C(=O)OC)C(=O)c2(c(C)c3(n(c=12)[Mg]59(N4(C(C(CO)=C(CC)C(C=3)=4)=Cc8(n(c(C=C(N5=6)C(C)7)c(C)c8C=C)9))))))))		RXN-7679	7-hydroxy-chlorophyll a + H2O + NADP+  =  chlorophyll a + O2 + NADPH	chlorophyll cycle
7-hydroxy-chlorophyll a	7-OH-chlorophyll a	C55 H72 N4 O6 MG1 	CC(CCCC(C)CCCC(C)CCCC(C)C)=CCOC(=O)CCC7(C6(C1(C(C(=O)OC)C(=O)c2(c(C)c3(n(c=12)[Mg]59(N4(C(C(CO)=C(CC)C(C=3)=4)=Cc8(n(c(C=C(N5=6)C(C)7)c(C)c8C=C)9))))))))		RXN-7678	chlorophyll b + 2 H2O + NADP+  =  7-hydroxy-chlorophyll a + O2 + NADPH	chlorophyll cycle
tRNAcys	TRNA(CYS)				6.1.1.16	tRNAcys + L-cysteine + ATP  =  L-cysteinyl-tRNAcys + pyrophosphate + AMP	tRNA charging pathway
kinetin-7-N-glucoside		C16 H19 N5 O6 	c2(c1(N(C=Nc1ncn2)C3(OC(CO)C(O)C(O)C(O)3)))(NCc4(occc4))		2.4.1.-	kinetin + UDP-D-glucose  =  kinetin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
kinetin-9-N-glucoside		C16 H19 N5 O6 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCc4(occc4))		2.4.1.-	kinetin + UDP-D-glucose  =  kinetin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
1-18:3-2-18:3-sn-glycerol-phosphocholine		C44 H77 N1 O8 P1 	C(OP(O)(=O)OCC[N+1](C)(C)C)C(OC(=O)CCCCCCCC=CCC=CCC=CCC)COC(=O)CCCCCCCC=CCC=CCC=CCC		1.14.99.-	1-18:2-2-18:2-sn-glycerol-3-phosphocholine  =  1-18:3-2-18:3-sn-glycerol-phosphocholine	phospholipid desaturation pathway
trans-zeatin-7-N-glucoside		C16 H23 N5 O6 	c2(c1(N(C=Nc1ncn2)C3(OC(CO)C(O)C(O)C(O)3)))(NCC=C(C)CO)		2.4.1.-	trans-zeatin + UDP-D-glucose  =  trans-zeatin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
trans-zeatin-9-N-glucoside		C16 H23 N5 O6 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCC=C(C)CO)		2.4.1.-	trans-zeatin + UDP-D-glucose  =  trans-zeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
trans-zeatin-O-glucoside	O-&beta;-D-Glucosylzeatin	C16 H23 N5 O6 	c2(c1(c(NC=N1)ncn2))NCC=C(C)COC3(OC(CO)C(O)C(O)C(O)3)		2.4.1.-	trans-zeatin-O-glucoside + UDP-D-glucose  =  trans-zeatin-O-glucoside-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
trans-zeatin-O-glucoside	O-&beta;-D-Glucosylzeatin	C16 H23 N5 O6 	c2(c1(c(NC=N1)ncn2))NCC=C(C)COC3(OC(CO)C(O)C(O)C(O)3)		2.4.1.203	trans-zeatin + UDP-D-glucose  =  trans-zeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
dihydrozeatin-7-N-dihydrozeatin		C16 H25 N5 O6 	c2(c1(N(C=Nc1ncn2)C3(OC(CO)C(O)C(O)C(O)3)))(NCCC(C)CO)		2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-7-N-dihydrozeatin + UDP	cytokinins 7-N-glucoside biosynthesis
sinapyl-alcohol		C11 H14 O4 	C(O)C=Cc1(cc(OC)c(O)c(c1)OC)		2.4.1.111	sinapyl-alcohol + UDP-D-glucose  =  syringin + UDP	monolignol glucosides biosynthesis
sinapyl-alcohol		C11 H14 O4 	C(O)C=Cc1(cc(OC)c(O)c(c1)OC)		1.1.1.195	sinapaldehyde + NADPH  =  sinapyl-alcohol + NADP+	lignin biosynthesis
dihydrozeatin-9-N-glucoside		C16 H25 N5 O6 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCCC(C)CO)		2.4.1.-	dihydrozeatin-9-N-glucoside + UDP-D-glucose  =  dihydrozeatin-9-N-glucoside-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
dihydrozeatin-9-N-glucoside		C16 H25 N5 O6 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCCC(C)CO)		2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
dihydrozeatin-O-glucoside		C16 H25 N5 O6 	c2(c1(c(NC=N1)ncn2))NCCC(C)COC3(OC(CO)C(O)C(O)C(O)3)		2.4.1.-	dihydrozeatin + UDP-D-glucose  =  dihydrozeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
cis-zeatin-7-N-glucoside		C16 H23 N5 O6 	c2(c1(N(C=Nc1ncn2)C3(OC(CO)C(O)C(O)C(O)3)))(NCC=C(C)CO)		2.4.1.-	cis-zeatin + UDP-D-glucose  =  cis-zeatin-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
cis-zeatin-9-N-glucoside		C16 H23 N5 O6 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCC=C(C)CO)		2.4.1.-	cis-zeatin + UDP-D-glucose  =  cis-zeatin-9-N-glucoside + UDP	cytokinins 9-N-glucoside biosynthesis
N-acetylglutamate semialdehyde	N-acetylglutamate &gamma;-semialdehyde*N-acetyl-L-glutamate-5-semialdehyde*<i>N</i>-acetyl-L-glutamate semialdehyde*<i>N</i>-acetyl-L-glutamate-5-semialdehyde*<i>N</i>-acetylglutamate &gamma;-semialdehyde	C7 H11 N1 O4 	C(=O)CCC(C(=O)O)NC(C)=O		1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis
N-acetylglutamate semialdehyde	N-acetylglutamate &gamma;-semialdehyde*N-acetyl-L-glutamate-5-semialdehyde*<i>N</i>-acetyl-L-glutamate semialdehyde*<i>N</i>-acetyl-L-glutamate-5-semialdehyde*<i>N</i>-acetylglutamate &gamma;-semialdehyde	C7 H11 N1 O4 	C(=O)CCC(C(=O)O)NC(C)=O		1.2.1.38	N-acetylglutamyl-phosphate + NADPH  =  N-acetylglutamate semialdehyde + NADP+ + phosphate	arginine biosynthesis II (acetyl cycle)
N-acetylglutamate semialdehyde	N-acetylglutamate &gamma;-semialdehyde*N-acetyl-L-glutamate-5-semialdehyde*<i>N</i>-acetyl-L-glutamate semialdehyde*<i>N</i>-acetyl-L-glutamate-5-semialdehyde*<i>N</i>-acetylglutamate &gamma;-semialdehyde	C7 H11 N1 O4 	C(=O)CCC(C(=O)O)NC(C)=O		2.6.1.11	N-acetylglutamate semialdehyde + L-glutamate  =  N-alpha-acetylornithine + alpha-ketoglutarate	arginine biosynthesis
N-acetylglutamate semialdehyde	N-acetylglutamate &gamma;-semialdehyde*N-acetyl-L-glutamate-5-semialdehyde*<i>N</i>-acetyl-L-glutamate semialdehyde*<i>N</i>-acetyl-L-glutamate-5-semialdehyde*<i>N</i>-acetylglutamate &gamma;-semialdehyde	C7 H11 N1 O4 	C(=O)CCC(C(=O)O)NC(C)=O		2.6.1.11	N-acetylglutamate semialdehyde + L-glutamate  =  N-alpha-acetylornithine + alpha-ketoglutarate	arginine biosynthesis II (acetyl cycle)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	RXN0-747	ADP + reduced glutaredoxin  =  dADP + oxidized glutaredoxin + H2O	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	1.17.4.1	Reduced Thioredoxin + ADP  =  Oxidized Thioredoxin + dADP + H2O	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.5.1.-	dimethylallyl-pyrophosphate + ADP  =  isopentenyladenosine-5'-diphosphate + pyrophosphate	trans-zeatin biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.4.3	10-formyl-H4PteGlun + ADP + phosphate  =  THF polyglutamate + ATP + formate	tetrahydrofolate biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.73	guanosine + ATP  =  GMP + ADP	salvage pathways of purine nucleosides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.73	inosine + ATP  =  IMP + ADP	salvage pathways of purine nucleosides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.86	NADH + ATP  =  NADPH + ADP	NAD/NADH phosphorylation and dephosphorylation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.4.1.21	(1,4-alpha-D-glucosyl)(n) + ADP-D-glucose  =  ADP + (1,4-alpha-D-glucosyl)(n+1)	starch biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.52	L-fucose + ATP  =  beta-L-fucose 1-phosphate + ADP	GDP-L-fucose biosynthesis II (from L-fucose)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.46	L-arabinose + ATP  =  beta-L-arabinose 1-phosphate + ADP	UDP-L-arabinose biosynthesis II (from L-arabinose)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.43	glucuronate + ATP  =  alpha-D-glucuronate 1-phosphate + ADP	inositol oxidation pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.44	galacturonate + ATP  =  alpha-D-galacturonate 1-phosphate + ADP	UDP-D-galacturonate biosynthesis II (from D-galacturonate)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	RXN-7204	D-myo-inositol (3,4,6)-trisphosphate + ATP  =  D-myo-inositol (3,4,5,6)-tetrakisphosphate + ADP	lipid-independent phytate biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	RXN-7203	D-myo-inositol (3,4)-bisphosphate + ATP  =  D-myo-inositol (3,4,6)-trisphosphate + ADP	lipid-independent phytate biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.134	D-myo-inositol (3,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-independent phytate biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	RXN-7202	D-myo-inositol (3)-monophosphate + ATP  =  D-myo-inositol (3,4)-bisphosphate + ADP	lipid-independent phytate biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.64	myo-inositol + ATP  =  D-myo-inositol (3)-monophosphate + ADP	lipid-independent phytate biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.139	D-myo-inositol (1,3,4)-trisphosphate + ATP  =  1D-myo-inositol 1,3,4,5-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.140	D-myo-inositol (1,3,4,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.133	D-myo-inositol (1,3,4)-trisphosphate + ATP  =  D-myo-inositol (1,3,4,6)-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	1D-myo-inositol 1,3,4,5-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	D-myo-inositol (1,2,3,4,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	D-myo-inositol (1,3,4,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,2,3,4,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-independent phytate biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis II (via Ins(1,3,4)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ATP  =  phytate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	D-myo-inositol (1,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,3,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.151	inositol 1,4,5-trisphosphate + ATP  =  D-myo-inositol (1,4,5,6)-tetrakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	D-myo-inositol (1,4,5,6)-tetrakisphosphate + ATP  =  D-myo-inositol (1,2,4,5,6)-pentakisphosphate + ADP	lipid-dependent phytate biosynthesis I (via Ins(1,4,5)P3)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.12	ATP + gluconate  =  6-phospho-D-gluconate + ADP	superpathway of gluconate degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.6.1.1	ATP + protoporphyrin IX + Mg2+ + H2O  =  Mg-protoporphyrin + H+ + phosphate + ADP	chlorophyllide a biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	arginine biosynthesis III
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	PROLINE-MULTI	L-glutamate + ATP + NADPH  =  ADP + L-glutamate gamma-semialdehyde + NADP+ + phosphate	proline biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.100	5-methylthioribose + ATP  =  5-methylthioribose-1-phosphate + ADP	methionine salvage pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.17	tetrahydrofolate + L-glutamate + ATP  =  THF-L-glutamate + ADP + phosphate	tetrahydrofolate biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.82	ethanolamine + ATP  =  phosphoryl-ethanolamine + ADP	choline biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.1	alpha-D-glucose + ATP  =  alpha-D-glucose-6-phosphate + ADP	sucrose degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.17	xylulose + ATP  =  D-xylulose-5-phosphate + ADP	xylose degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	PYRAMKIN-RXN	ATP + pyridoxamine  =  ADP + pyridoxamine 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.35	ATP + pyridoxal  =  ADP + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.24	dephospho-CoA + ATP  =  coenzyme A + ADP	coenzyme A biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.130	lipid A disaccharide + ATP  =  lipid IV(A) + ADP	lipid-A-precursor biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.45	2-dehydro-3-deoxy-D-gluconate + ATP  =  2-keto-3-deoxy-6-phospho-gluconate + ADP	beta-D-glucuronide degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.6	dCDP + ATP  =  dCTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.6	dUDP + ATP  =  dUTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.6	dTDP + ATP  =  dTTP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.89	thiamine + ATP  =  thiamine-phosphate + ADP	thiamin biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.16	thiamine-phosphate + ATP  =  thiamin diphosphate + ADP	thiamin biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.49	ATP + hydroxymethylpyrimidine  =  ADP + hydroxymethylpyrimidine phosphate	thiamin biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.-.-	4-diphosphocytidyl-2-C-methylerythritol + ATP  =  4-diphosphocytidyl-2-C-methylerythritol 2-phosphate + ADP	isopentenyl diphosphate biosynthesis -- mevalonate-independent
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.4.1.4	HCO3- + 3-methylcrotonyl-CoA + ATP  =  phosphate + trans-3-methylglutaconyl-CoA + ADP	leucine degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	isoleucine degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	valine degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle variation I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle -- aerobic respiration
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	PROPIONYL-COA-CARBOXYLASE-RXN	propionyl-CoA + H2O + ATP + CO2  =  D-methylmalonyl-CoA + phosphate + ADP	methionine degradation I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.7	mannose + ATP  =  mannose-6-phosphate + ADP	mannitol degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.31	glycerate + ATP  =  3-phosphoglycerate + ADP	photorespiration
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.1	acetylphosphate + ADP  =  acetate + ATP	carbon monoxide dehydrogenase pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.17	10-formyl-H4PteGlun + L-glutamate + ATP  =  10-formyl-H4PteGlu(n+1) + ADP + phosphate	formylTHF biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.6	UDP + ATP  =  UTP + ADP	de novo biosynthesis of pyrimidine ribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.6	CTP + ADP  =  CDP + ATP	de novo biosynthesis of pyrimidine ribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.5.3	ATP + 5'-phosphoribosyl-N-formylglycineamide + L-glutamine + H2O  =  ADP + phosphate + 5-phosphoribosyl-n-formylglycineamidine + L-glutamate	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.1.2.-	5-phospho-ribosyl-glycineamide + formate + ATP  =  phosphate + 5'-phosphoribosyl-N-formylglycineamide + ADP	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	RXN0-742	5-aminoimidazole ribonucleotide + ATP + H2O + CO2  =  N5-carboxyaminoimidazole ribonucleotide + ADP + phosphate	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.6	dGDP + ATP  =  dGTP + ADP	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.6	dADP + ATP  =  dATP + ADP	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.4.1.2	HCO3- + H+ + acetyl-CoA + ATP  =  malonyl-CoA + phosphate + ADP	fatty acid biosynthesis - initial steps
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.3.2	N5-formyl-H4F + ATP  =  5,10-methenyl-THF + ADP + phosphate	formylTHF biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.3	glycine + L-gamma-glutamylcysteine + ATP  =  glutathione + phosphate + ADP	glutathione biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.-	ATP + pyridoxine  =  ADP + pyridoxine-5'-phosphate	pyridoxal 5'-phosphate salvage pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.3.3	CO2 + 7,8-diaminononanoate + ATP  =  dethiobiotin + phosphate + ADP	biotin biosynthesis II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.36	mevalonate + ATP  =  mevalonate-5P + ADP	mevalonate pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.26	riboflavin + ATP  =  FMN + ADP	riboflavin and FMN and FAD biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.2	L-cysteine + L-glutamate + ATP  =  L-gamma-glutamylcysteine + phosphate + ADP	glutathione biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.2	carbamoyl-phosphate + ADP  =  NH3 + CO2 + ATP	citrulline degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.6	GDP + ATP  =  GTP + ADP	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.3.1	ATP + 5-phosphoribosyl-n-formylglycineamidine  =  ADP + phosphate + 5-aminoimidazole ribonucleotide	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.50	ATP + 4-methyl-5-(beta-hydroxyethyl)thiazole  =  ADP + 4-methyl-5-(beta-hydroxyethyl)thiazole phosphate	thiamin biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.9	dTMP + ATP  =  dTDP + ADP	de novo biosynthesis of pyrimidine deoxyribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.20	adenosine + ATP  =  AMP + ADP	salvage pathways of purine nucleosides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.33	pantothenate + ATP  =  D-4'-phosphopantothenate + ADP	coenzyme A biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.-	ATP + UMP  =  ADP + UDP	de novo biosynthesis of pyrimidine ribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.8	GMP + ATP  =  GDP + ADP	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	superpathway of glyoxylate cycle
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	4.1.1.49	oxaloacetate + ATP  =  CO2 + phosphoenolpyruvate + ADP	gluconeogenesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.8	N-acetyl-L-glutamate + ATP  =  N-acetylglutamyl-phosphate + ADP	arginine biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.8	N-acetyl-L-glutamate + ATP  =  N-acetylglutamyl-phosphate + ADP	arginine biosynthesis II (acetyl cycle)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.4.2.11	nicotinate + H2O + PRPP + ATP  =  nicotinate nucleotide + pyrophosphate + phosphate + ADP	pyridine nucleotide cycling
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	4.1.1.21	5-aminoimidazole ribonucleotide + ATP + CO2 + H2O  =  phosphate + phosphoribosyl-carboxy-aminoimidazole + ADP	de novo biosynthesis of purine nucleotides II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.3	AMP + ATP  =  ADP + ADP	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	4.1.1.33	mevalonate-5-PP + ATP  =  phosphate + CO2 + delta3-isopentenyl-PP + ADP	mevalonate pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.4.13	ATP + 5-phospho-beta-D-ribosyl-amine + glycine  =  ADP + phosphate + 5-phospho-ribosyl-glycineamide	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.39	homoserine + ATP  =  O-phospho-L-homoserine + ADP	threonine biosynthesis from homoserine
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.39	homoserine + ATP  =  O-phospho-L-homoserine + ADP	methionine biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.7	hydroxymethylpyrimidine phosphate + ATP  =  4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate + ADP	thiamin biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.4	fructose + ATP  =  D-fructose-6-phosphate + ADP	sucrose degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.4	fructose + ATP  =  D-fructose-6-phosphate + ADP	sucrose degradation to ethanol and lactate (anaerobic)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.6	ATP + phosphoribosyl-carboxy-aminoimidazole + L-aspartate  =  ADP + phosphate + 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole	de novo biosynthesis of purine nucleotides I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.15	D-ribose + ATP  =  D-ribose-5-phosphate + ADP	ribose degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.4	L-aspartate + ATP  =  L-aspartyl-4-phosphate + ADP	homoserine biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.4	L-aspartate + ATP  =  L-aspartyl-4-phosphate + ADP	lysine biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	Calvin cycle
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	sucrose degradation to ethanol and lactate (anaerobic)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glycolysis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glycolysis II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	gluconeogenesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glyceraldehyde 3-phosphate degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.30	glycerol + ATP  =  glycerol-3-phosphate + ADP	glycerol degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	glutamine biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	ammonia assimilation cycle
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.1.2	NH3 + L-glutamate + ATP  =  ADP + phosphate + L-glutamine	nitrate assimilation pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.71	shikimate + ATP  =  shikimate-3-phosphate + ADP	chorismate biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	colanic acid building blocks biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	galactose degradation II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.6	alpha-D-galactose + ATP  =  alpha-D-galactose-1-phosphate + ADP	galactose degradation I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.23	NAD+ + ATP  =  NADP+ + ADP	NAD/NADH phosphorylation and dephosphorylation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	glycine degradation
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	formylTHF biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.4.3	ATP + formate + tetrahydrofolate  =  ADP + phosphate + N10-formyl-THF	carbon monoxide dehydrogenase pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.4.2	mevalonate-5P + ATP  =  mevalonate-5-PP + ADP	mevalonate pathway
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.4.2	L-glutamine + H2O + UTP + ATP  =  CTP + phosphate + ADP + L-glutamate	de novo biosynthesis of pyrimidine ribonucleotides
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	sucrose degradation to ethanol and lactate (anaerobic)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	sucrose degradation to ethanol and lactate (anaerobic)
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis II
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	2.7.1.19	D-ribulose-5-phosphate + ATP  =  D-ribulose-1,5-bisphosphate + ADP	Calvin cycle
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	formylTHF biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis I
ADP	adenosine pyrophosphate*adenosine 5'-pyrophosphate*adenosine-5'-diphosphate*adenosine-diphosphate*adenosine-5-diphosphate	C10 H15 N5 O10 P2 	C(OP(O)(=O)OP(O)(O)=O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00008*CAS:20398-34-9*CAS:58-64-0	6.3.2.17	L-glutamate + H4PteGlu(n) + ATP  =  H4PteGlu(n+1) + phosphate + ADP	tetrahydrofolate biosynthesis II
6-deoxotyphasterol	deoxotyphasterol	C28 H50 O3 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-4241	6-deoxotyphasterol + O2  =  typhasterol + H2O	brassinosteroid biosynthesis I
6-deoxotyphasterol	deoxotyphasterol	C28 H50 O3 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-777	6-deoxotyphasterol + O2  =  6-deoxocastasterone + H2O	brassinosteroid biosynthesis I
6-deoxotyphasterol	deoxotyphasterol	C28 H50 O3 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)CC4)(C))))		RXN-776	3-dehydro-6-deoxoteasterone  =  6-deoxotyphasterol	brassinosteroid biosynthesis I
(4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol		C29 H46 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(=CC1)C3(=C(CC2)C4([CH](CC3)C(C)C(O)CC4)(C))))	LIGAND-CPD:C11508	1.3.1.70	(4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol + 2 NADPH  =  4alpha-methylfecosterol + 2 NADP+	sterol biosynthesis
(4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol		C29 H46 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(=CC1)C3(=C(CC2)C4([CH](CC3)C(C)C(O)CC4)(C))))	LIGAND-CPD:C11508	1.14.13.70	3 NADPH + 3 O2 + obtusifoliol + 3 H+  =  4 H2O + 3 NADP+ + formate + (4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol	sterol biosynthesis
indole carboxyl tetrahydro-thiazole		C12 H12 N2 O2 S1 	c2(c(C1([NH]C(CS1)C(=O)[OH]))c3(c([nH]2)cccc3))		RXN1F-15	indole carboxyl tetrahydro-thiazole  =  indole carboxyl hydro-thiazole	camalexin biosynthesis
indole carboxyl tetrahydro-thiazole		C12 H12 N2 O2 S1 	c2(c(C1([NH]C(CS1)C(=O)[OH]))c3(c([nH]2)cccc3))		RXN1F-14	indole-S-cysteine-adduct  =  indole carboxyl tetrahydro-thiazole + H2O	camalexin biosynthesis
6-deoxocastasterone	deoxocastasterone	C28 H50 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)C(O)C4)(C))))		RXN-778	6-deoxocastasterone + O2  =  6alpha-hydroxy-castasterone + H2O	brassinosteroid biosynthesis I
6-deoxocastasterone	deoxocastasterone	C28 H50 O4 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](CC3)CC(O)C(O)C4)(C))))		RXN-777	6-deoxotyphasterol + O2  =  6-deoxocastasterone + H2O	brassinosteroid biosynthesis I
obtusifoliol	4&alpha;,14&alpha;-dimethyl-5&alpha;-ergosta-8,24(28)-dien-3&beta;-ol*4&alpha;,14&alpha;-dimethyl-24-methylene-5&alpha;-cholesta-8-en-3&beta;-ol	C30 H50 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(C)(CC1)C3(=C(CC2)C4([CH](CC3)C(C)C(O)CC4)(C))))	LIGAND-CPD:C01943	1.14.13.70	3 NADPH + 3 O2 + obtusifoliol + 3 H+  =  4 H2O + 3 NADP+ + formate + (4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol	sterol biosynthesis
obtusifoliol	4&alpha;,14&alpha;-dimethyl-5&alpha;-ergosta-8,24(28)-dien-3&beta;-ol*4&alpha;,14&alpha;-dimethyl-24-methylene-5&alpha;-cholesta-8-en-3&beta;-ol	C30 H50 O1 	CC(C)C(=C)CCC(C)C1(C2(C)(C(C)(CC1)C3(=C(CC2)C4([CH](CC3)C(C)C(O)CC4)(C))))	LIGAND-CPD:C01943	5.5.1.9	cycloeucalenol  =  obtusifoliol	sterol biosynthesis
6alpha-hydroxy-castasterone	hydroxydeoxocastasterone*6&alpha;-hydroxy-6-deoxocastasterone	C28 H50 O5 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(O)C3)CC(O)C(O)C4)(C))))		RXN-779	6alpha-hydroxy-castasterone  =  castasterone	brassinosteroid biosynthesis I
6alpha-hydroxy-castasterone	hydroxydeoxocastasterone*6&alpha;-hydroxy-6-deoxocastasterone	C28 H50 O5 	CC(C)C(C)C(O)C(O)C(C)C1(C2(C)(C(CC1)C3(C(CC2)C4([CH](C(O)C3)CC(O)C(O)C4)(C))))		RXN-778	6-deoxocastasterone + O2  =  6alpha-hydroxy-castasterone + H2O	brassinosteroid biosynthesis I
13(S)-hydroperoxylinolenate	13(S)-hydroperoxylinolenic acid*hydroperoxylinolenic acid*13S-hydroperoxy-9(Z),11(E),15(Z)-octadecatrienoic acid	C18 H30 O4 	CCC=CCC(OO)C=CC=CCCCCCCCC(=O)O		4.2.1.92	13(S)-hydroperoxylinolenate  =  H2O + 12,13(S)-epoxylinolenate	jasmonic acid biosynthesis
13(S)-hydroperoxylinolenate	13(S)-hydroperoxylinolenic acid*hydroperoxylinolenic acid*13S-hydroperoxy-9(Z),11(E),15(Z)-octadecatrienoic acid	C18 H30 O4 	CCC=CCC(OO)C=CC=CCCCCCCCC(=O)O		4.2.1.92	13(S)-hydroperoxylinolenate  =  H2O + 12,13(S)-epoxylinolenate	lipoxygenase pathway
13(S)-hydroperoxylinolenate	13(S)-hydroperoxylinolenic acid*hydroperoxylinolenic acid*13S-hydroperoxy-9(Z),11(E),15(Z)-octadecatrienoic acid	C18 H30 O4 	CCC=CCC(OO)C=CC=CCCCCCCCC(=O)O		RXN-1345	13(S)-hydroperoxylinolenate  =  12-oxo-cis-9-dodecenoate + cis-3-hexenal	lipoxygenase pathway
13(S)-hydroperoxylinolenate	13(S)-hydroperoxylinolenic acid*hydroperoxylinolenic acid*13S-hydroperoxy-9(Z),11(E),15(Z)-octadecatrienoic acid	C18 H30 O4 	CCC=CCC(OO)C=CC=CCCCCCCCC(=O)O		1.13.11.12	O2 + linolenate  =  13(S)-hydroperoxylinolenate	jasmonic acid biosynthesis
13(S)-hydroperoxylinolenate	13(S)-hydroperoxylinolenic acid*hydroperoxylinolenic acid*13S-hydroperoxy-9(Z),11(E),15(Z)-octadecatrienoic acid	C18 H30 O4 	CCC=CCC(OO)C=CC=CCCCCCCCC(=O)O		1.13.11.12	O2 + linolenate  =  13(S)-hydroperoxylinolenate	lipoxygenase pathway
a carboxylate	carboxylic acid*carboxylate	C1 H1 O2 R1 			3.1.1.4	a phosphatidylcholine + H2O  =  1-acylglycerophosphocholine + a carboxylate	lipases pathway
12,13(S)-epoxylinolenate	12,13(S)-epoxylinolenic acid*epoxylinolenic acid*12,13-epoxy-octadecatrienoic acid	C18 H28 O3 	CCC=CCC1(C(O1)=CC=CCCCCCCCC(O)=O)		5.3.99.6	12,13(S)-epoxylinolenate  =  12-oxo-cis-10,15-phytodienoate	jasmonic acid biosynthesis
12,13(S)-epoxylinolenate	12,13(S)-epoxylinolenic acid*epoxylinolenic acid*12,13-epoxy-octadecatrienoic acid	C18 H28 O3 	CCC=CCC1(C(O1)=CC=CCCCCCCCC(O)=O)		5.3.99.6	12,13(S)-epoxylinolenate  =  12-oxo-cis-10,15-phytodienoate	lipoxygenase pathway
12,13(S)-epoxylinolenate	12,13(S)-epoxylinolenic acid*epoxylinolenic acid*12,13-epoxy-octadecatrienoic acid	C18 H28 O3 	CCC=CCC1(C(O1)=CC=CCCCCCCCC(O)=O)		4.2.1.92	13(S)-hydroperoxylinolenate  =  H2O + 12,13(S)-epoxylinolenate	jasmonic acid biosynthesis
12,13(S)-epoxylinolenate	12,13(S)-epoxylinolenic acid*epoxylinolenic acid*12,13-epoxy-octadecatrienoic acid	C18 H28 O3 	CCC=CCC1(C(O1)=CC=CCCCCCCCC(O)=O)		4.2.1.92	13(S)-hydroperoxylinolenate  =  H2O + 12,13(S)-epoxylinolenate	lipoxygenase pathway
12-oxo-cis-10,15-phytodienoate	12-oxo-cis-10,15-phytodienoic acid*oxophytodienoic acid*(15Z)-12-oxophyto-10,15-dienoate*12-oxo-phytodienoic acid	C18 H28 O3 	C(O)(=O)CCCCCCCC1(C(C(=O)C=C1)CC=CCC)		5.3.99.6	12,13(S)-epoxylinolenate  =  12-oxo-cis-10,15-phytodienoate	jasmonic acid biosynthesis
12-oxo-cis-10,15-phytodienoate	12-oxo-cis-10,15-phytodienoic acid*oxophytodienoic acid*(15Z)-12-oxophyto-10,15-dienoate*12-oxo-phytodienoic acid	C18 H28 O3 	C(O)(=O)CCCCCCCC1(C(C(=O)C=C1)CC=CCC)		5.3.99.6	12,13(S)-epoxylinolenate  =  12-oxo-cis-10,15-phytodienoate	lipoxygenase pathway
12-oxo-cis-10,15-phytodienoate	12-oxo-cis-10,15-phytodienoic acid*oxophytodienoic acid*(15Z)-12-oxophyto-10,15-dienoate*12-oxo-phytodienoic acid	C18 H28 O3 	C(O)(=O)CCCCCCCC1(C(C(=O)C=C1)CC=CCC)		1.3.1.42	NADPH + 12-oxo-cis-10,15-phytodienoate  =  NADP+ + 3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate	jasmonic acid biosynthesis
D-4'-phosphopantothenate	4'-phosphopantothenate*4'-P-Pantothenate*(R)-4'-phosphopantothenate	C9 H18 N1 O8 P1 	C(OP(O)(=O)O)C(C)(C)C(O)C(=O)NCCC(O)=O		6.3.2.5	D-4'-phosphopantothenate + L-cysteine + CTP  =  R-4'-phosphopantothenoyl-L-cysteine + pyrophosphate + CMP	coenzyme A biosynthesis
D-4'-phosphopantothenate	4'-phosphopantothenate*4'-P-Pantothenate*(R)-4'-phosphopantothenate	C9 H18 N1 O8 P1 	C(OP(O)(=O)O)C(C)(C)C(O)C(=O)NCCC(O)=O		2.7.1.33	pantothenate + ATP  =  D-4'-phosphopantothenate + ADP	coenzyme A biosynthesis
glutathione disulfide	glutathione oxidized*glutathione ox*GSSG*glutathione*GSH*ox. glutathione*oxidized glutathione	C20 H32 N6 O12 S2 	C(=O)(CCC(N)C(O)=O)NC(C(=O)NCC(O)=O)CSSCC(C(=O)NCC(O)=O)NC(=O)CCC(N)C(=O)O	CAS:27025-41-8	1.8.1.7	glutathione disulfide + NADPH + H+  =  2 glutathione + NADP+	ascorbate glutathione cycle
glutathione disulfide	glutathione oxidized*glutathione ox*GSSG*glutathione*GSH*ox. glutathione*oxidized glutathione	C20 H32 N6 O12 S2 	C(=O)(CCC(N)C(O)=O)NC(C(=O)NCC(O)=O)CSSCC(C(=O)NCC(O)=O)NC(=O)CCC(N)C(=O)O	CAS:27025-41-8	1.8.5.1	L-dehydro-ascorbate + 2 glutathione  =  glutathione disulfide + L-ascorbate	ascorbate glutathione cycle
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	1.1.1.95	3-phosphoglycerate + NAD+  =  3-phospho-hydroxypyruvate + NADH	serine biosynthesis
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	sucrose degradation to ethanol and lactate (anaerobic)
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	glycolysis I
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	glycolysis II
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	gluconeogenesis
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	glyceraldehyde 3-phosphate degradation
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	Calvin cycle
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	sucrose degradation to ethanol and lactate (anaerobic)
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glycolysis I
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glycolysis II
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	gluconeogenesis
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	2.7.2.3	3-phosphoglycerate + ATP  =  1,3-diphosphateglycerate + ADP	glyceraldehyde 3-phosphate degradation
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	4.1.1.-	D-ribulose-1,5-bisphosphate + O2  =  2-phosphoglycolate + 3-phosphoglycerate + 2 H+	photorespiration
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	2.7.1.31	glycerate + ATP  =  3-phosphoglycerate + ADP	photorespiration
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	1.2.1.9	H2O + NADP+ + D-glyceraldehyde-3-phosphate  =  3-phosphoglycerate + NADPH	glycolysis I
3-phosphoglycerate	3-phospho-(R)-glycerate*3-phospho-glyceric acid*g3p*3-pg*3-P-glycerate*glycerate 3-phosphate*3-phospho-D-glycerate*3-P-D-glycerate*glycerate-3-P*D-Glycerate 3-phosphate*phosphoglycerate	C3 H7 O7 P1 	C(OP(O)(=O)O)C(O)C(=O)O	CAS:820-11-1	4.1.1.39	H2O + CO2 + D-ribulose-1,5-bisphosphate  =  2 3-phosphoglycerate	Calvin cycle
GA13	GA13*gibberellin A13*gibberellin A<sub>13</sub>	C20 H26 O7 	CC1([CH]4(C(CCC(O)1)(C(=O)O)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA25 + alpha-ketoglutarate + O2  =  GA13 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
coniferyl alcohol	4-hydroxy-3-methoxycinnamyl alcohol*coniferyl alcohol*4-hydroxy-3-methoxycinnamyl alcohol *3-(4-hydroxy-3-methoxyphenyl)-2-propen-1-ol*4-(3-hydroxy-1-propenyl)-2-methoxyphenol*&gamma;-hydroxyisoeugenol*coniferol	C10 H12 O3 	C(O)C=Cc1(cc(OC)c(O)cc1)	CAS:458-35-5	2.4.1.111	coniferyl alcohol + UDP-D-glucose  =  coniferin + UDP	coniferin metabolism
coniferyl alcohol	4-hydroxy-3-methoxycinnamyl alcohol*coniferyl alcohol*4-hydroxy-3-methoxycinnamyl alcohol *3-(4-hydroxy-3-methoxyphenyl)-2-propen-1-ol*4-(3-hydroxy-1-propenyl)-2-methoxyphenol*&gamma;-hydroxyisoeugenol*coniferol	C10 H12 O3 	C(O)C=Cc1(cc(OC)c(O)cc1)	CAS:458-35-5	3.2.1.126	H2O + coniferin  =  coniferyl alcohol + beta-D-glucose	coniferin metabolism
coniferyl alcohol	4-hydroxy-3-methoxycinnamyl alcohol*coniferyl alcohol*4-hydroxy-3-methoxycinnamyl alcohol *3-(4-hydroxy-3-methoxyphenyl)-2-propen-1-ol*4-(3-hydroxy-1-propenyl)-2-methoxyphenol*&gamma;-hydroxyisoeugenol*coniferol	C10 H12 O3 	C(O)C=Cc1(cc(OC)c(O)cc1)	CAS:458-35-5	1.1.1.195	coniferyl aldehyde + NADPH  =  coniferyl alcohol + NADP+	lignin biosynthesis
cis-zeatin-O-glucoside		C16 H23 N5 O6 	c2(c1(c(N=CN1)ncn2))NCC=C(C)COC3(OC(CO)C(O)C(O)C(O)3)		2.4.1.215	cis-zeatin + UDP-D-glucose  =  cis-zeatin-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
GA34	GA34*gibberellin A34*gibberellin A<sub>34</sub>	C19 H24 O6 	C=C1(C2(CC5(C1)([CH](CC2)C34(OC(=O)C(C(O)C(O)C3)(C)[CH]4C5C(=O)O))))		1.14.11.-	GA34 + alpha-ketoglutarate + O2  =  GA34-catabolite + succinate + CO2 + H2O	gibberellin inactivation
GA34	GA34*gibberellin A34*gibberellin A<sub>34</sub>	C19 H24 O6 	C=C1(C2(CC5(C1)([CH](CC2)C34(OC(=O)C(C(O)C(O)C3)(C)[CH]4C5C(=O)O))))		1.14.11.-	GA4 + alpha-ketoglutarate + O2  =  GA34 + succinate + CO2	gibberellin inactivation
dihydrozeatin-9-N-glucoside-O-glucoside		C22 H35 N5 O11 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCCC(C)COC4(OC(CO)C(O)C(O)C(O)4))		2.4.1.-	dihydrozeatin-9-N-glucoside + UDP-D-glucose  =  dihydrozeatin-9-N-glucoside-O-glucoside + UDP	cytokinins-O-glucoside biosynthesis
alpha-tocopherol		C29 H50 O2 	CC2(=C1(OC(CCC1=C(C)C(O)=C2C)(C)CCCC(C)CCCC(C)CCCC(C)C))	NCI:82623*CAS:2074-53-5	2.1.1.95	gamma-tocopherol + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + alpha-tocopherol	vitamin E biosynthesis
trans-zeatin-O-glucoside-7-N-glucoside		C22 H33 N5 O11 	c1(c2(c(ncn1)N(C=N2)C3(OC(CO)C(O)C(O)C(O)3)))(NCC=C(C)COC4(OC(CO)C(O)C(O)C(O)4))		2.4.1.-	trans-zeatin-O-glucoside + UDP-D-glucose  =  trans-zeatin-O-glucoside-7-N-glucoside + UDP	cytokinins 7-N-glucoside biosynthesis
oleate	octadecenoate (n-C18:1)*oleic acid*9-octadecenoic acid	C18 H34 O2 	CCCCCCCCC=CCCCCCCCC(=O)O	LIGAND-CPD:C00712*PUBCHEM:445639*CAS:112-80-1	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	suberin biosynthesis
oleate	octadecenoate (n-C18:1)*oleic acid*9-octadecenoic acid	C18 H34 O2 	CCCCCCCCC=CCCCCCCCC(=O)O	LIGAND-CPD:C00712*PUBCHEM:445639*CAS:112-80-1	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	cutin biosynthesis
oleate	octadecenoate (n-C18:1)*oleic acid*9-octadecenoic acid	C18 H34 O2 	CCCCCCCCC=CCCCCCCCC(=O)O	LIGAND-CPD:C00712*PUBCHEM:445639*CAS:112-80-1	2.1.1.79	oleate + S-adenosyl-L-methionine  =  dihydrosterculate + S-adenosyl-homocysteine	cyclopropane and cyclopropene fatty acid biosynthesis
3-aminopropionaldehyde	3-APA	C3 H7 N1 O1 	C(N)CC=O		1.2.1.3	3-aminopropionaldehyde + NAD(P)+ + H2O  =  beta-alanine + NAD(P)H	beta-alanine biosynthesis I
3-aminopropionaldehyde	3-APA	C3 H7 N1 O1 	C(N)CC=O		1.4.3.6	1,3-diaminopropane + H2O + O2  =  3-aminopropionaldehyde + NH3 + H2O2	beta-alanine biosynthesis I
GA14	GA14*gibberellin A14*gibberellin A<sub>14</sub>	C20 H28 O5 	CC1([CH]4(C(CCC(O)1)(C)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA14 + O2 + alpha-ketoglutarate  =  GA37 + CO2 + succinate	gibberellin biosynthesis II (early C-3 hydroxylation)
GA14	GA14*gibberellin A14*gibberellin A<sub>14</sub>	C20 H28 O5 	CC1([CH]4(C(CCC(O)1)(C)[CH]3(C2(CC(C(=C)C2)CC3)(C4C(=O)O))))(C(=O)O)		1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA14 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
pantothenate	(R)-pantothenate*vitamin B<SUB>5</SUB>*pantothenic acid*D-pantothenic acid	C9 H17 N1 O5 	CC(CO)(C)C(O)C(=O)NCCC(=O)O	CAS:79-83-4	2.7.1.33	pantothenate + ATP  =  D-4'-phosphopantothenate + ADP	coenzyme A biosynthesis
pantothenate	(R)-pantothenate*vitamin B<SUB>5</SUB>*pantothenic acid*D-pantothenic acid	C9 H17 N1 O5 	CC(CO)(C)C(O)C(=O)NCCC(=O)O	CAS:79-83-4	6.3.2.1	beta-alanine + L-pantoate + ATP  =  pantothenate + pyrophosphate + AMP	pantothenate biosynthesis
NO2-	NO<sub>2</sub>*nitrite	N1 O2 	N(=O)[O-1]	CAS:14797-65-0	1.7.1.1	NO3- + NADH  =  NO2- + H2O + NAD+	nitrate assimilation pathway
NO2-	NO<sub>2</sub>*nitrite	N1 O2 	N(=O)[O-1]	CAS:14797-65-0	1.7.7.-	NO2- + reduced ferredoxin  =  NH3 + H2O + oxidized ferredoxin	nitrate assimilation pathway
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	sucrose degradation to ethanol and lactate (anaerobic)
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glycolysis I
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glycolysis II
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	gluconeogenesis
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	4.2.1.11	2-phosphoglycerate  =  phosphoenolpyruvate + H2O	glyceraldehyde 3-phosphate degradation
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	sucrose degradation to ethanol and lactate (anaerobic)
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	glycolysis I
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	glycolysis II
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	gluconeogenesis
2-phosphoglycerate	phosphoglycerate*2-phosphoglyceric acid*2-pg*2-P-glycerate*glycerate 2-phosphate*2-phospho-D-glycerate*2-P-D-glycerate*D-Glycerate 2-phosphate	C3 H7 O7 P1 	C(O)C(C(=O)O)OP(O)(=O)O	CAS:2553-59-5	5.4.2.1	3-phosphoglycerate  =  2-phosphoglycerate	glyceraldehyde 3-phosphate degradation
3-methyl-4-cis-hydroxy-2-butenal		C5 H8 O2 	C(=O)C=C(C)CO		1.5.99.12	cis-zeatin + H2O + FAD  =  3-methyl-4-cis-hydroxy-2-butenal + adenine + FADH2	cytokinins degradation
3-methyl-4-trans-hydroxy-2-butenal		C5 H8 O2 	C(=O)C=C(C)CO		1.5.99.12	trans-zeatin riboside + H2O + FAD  =  adenosine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
3-methyl-4-trans-hydroxy-2-butenal		C5 H8 O2 	C(=O)C=C(C)CO		1.5.99.12	trans-zeatin + H2O + FAD  =  adenine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
7,8-dihydropteroate	dihydropterate*H2Pte*dihydropteroate	C14 H14 N6 O3 	C(Nc1(ccc(C(O)=O)cc1))C2(=Nc3(c(NC2)nc(N)[nH]c3=O))		6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis
7,8-dihydropteroate	dihydropterate*H2Pte*dihydropteroate	C14 H14 N6 O3 	C(Nc1(ccc(C(O)=O)cc1))C2(=Nc3(c(NC2)nc(N)[nH]c3=O))		6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	formylTHF biosynthesis I
7,8-dihydropteroate	dihydropterate*H2Pte*dihydropteroate	C14 H14 N6 O3 	C(Nc1(ccc(C(O)=O)cc1))C2(=Nc3(c(NC2)nc(N)[nH]c3=O))		6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis I
7,8-dihydropteroate	dihydropterate*H2Pte*dihydropteroate	C14 H14 N6 O3 	C(Nc1(ccc(C(O)=O)cc1))C2(=Nc3(c(NC2)nc(N)[nH]c3=O))		6.3.2.12	L-glutamate + 7,8-dihydropteroate + ATP  =  7,8-dihydrofolate + phosphate + ADP	tetrahydrofolate biosynthesis II
7,8-dihydropteroate	dihydropterate*H2Pte*dihydropteroate	C14 H14 N6 O3 	C(Nc1(ccc(C(O)=O)cc1))C2(=Nc3(c(NC2)nc(N)[nH]c3=O))		2.5.1.15	p-aminobenzoate + 2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate  =  7,8-dihydropteroate + pyrophosphate	tetrahydrofolate biosynthesis I
7,8-dihydropteroate	dihydropterate*H2Pte*dihydropteroate	C14 H14 N6 O3 	C(Nc1(ccc(C(O)=O)cc1))C2(=Nc3(c(NC2)nc(N)[nH]c3=O))		2.5.1.15	p-aminobenzoate + 2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate  =  7,8-dihydropteroate + pyrophosphate	tetrahydrofolate biosynthesis II
dihydrosirohydrochlorin	precorrin-2	C42 H48 N4 O16 	CC1(C5(=NC(C1CCC(O)=O)=Cc2(nc(c(CCC(O)=O)c2CC(=O)O)Cc3(nc(c(CC(O)=O)c3CCC(O)=O)C=C4(C(CC(O)=O)(C)C(C(N4)=C5)CCC(=O)O)))))(CC(O)=O)		DIMETHUROPORDEHYDROG-RXN	dihydrosirohydrochlorin + NAD+  =  sirohydrochlorin + NADH	biosynthesis of proto- and siroheme
dihydrosirohydrochlorin	precorrin-2	C42 H48 N4 O16 	CC1(C5(=NC(C1CCC(O)=O)=Cc2(nc(c(CCC(O)=O)c2CC(=O)O)Cc3(nc(c(CC(O)=O)c3CCC(O)=O)C=C4(C(CC(O)=O)(C)C(C(N4)=C5)CCC(=O)O)))))(CC(O)=O)		2.1.1.-	uroporphyrinogen-III + 2 S-adenosyl-L-methionine  =  2 S-adenosyl-homocysteine + dihydrosirohydrochlorin	biosynthesis of proto- and siroheme
feruloyl-CoA		C31 H44 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc4(cc(OC)c(O)cc4))		1.2.1.44	feruloyl-CoA + NADPH  =  coniferyl aldehyde + NADP+ + coenzyme A	lignin biosynthesis
feruloyl-CoA		C31 H44 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc4(cc(OC)c(O)cc4))		2.3.1.110	feruloyl-CoA + tyramine  =  N-feruloyltyramine + coenzyme A	suberin biosynthesis
feruloyl-CoA		C31 H44 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc4(cc(OC)c(O)cc4))		6.2.1.12	ferulate + coenzyme A + ATP  =  feruloyl-CoA + AMP + pyrophosphate	suberin biosynthesis
feruloyl-CoA		C31 H44 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc4(cc(OC)c(O)cc4))		2.1.1.104	caffeoyl-CoA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + feruloyl-CoA	lignin biosynthesis
feruloyl-CoA		C31 H44 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=Cc4(cc(OC)c(O)cc4))		2.1.1.104	caffeoyl-CoA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + feruloyl-CoA	suberin biosynthesis
L-delta1-pyrroline-5-carboxylate	pyrroline 5-carboxylate*(S)-1-pyrroline-5-carboxylate*1-pyrroline-5-carboxylate*L-1-pyrroline-5-carboxylate*&delta;-1-pyrroline-5-carboxylic acid*&delta;-1-pyrroline-5-carboxylate	C5 H7 N1 O2 	C1(=NC(C(O)=O)CC1)	CAS:2906-39-0	1.5.1.12	L-delta1-pyrroline-5-carboxylate + NAD(P)+ + H2O  =  L-glutamate + NAD(P)H + H+	proline degradation
L-delta1-pyrroline-5-carboxylate	pyrroline 5-carboxylate*(S)-1-pyrroline-5-carboxylate*1-pyrroline-5-carboxylate*L-1-pyrroline-5-carboxylate*&delta;-1-pyrroline-5-carboxylic acid*&delta;-1-pyrroline-5-carboxylate	C5 H7 N1 O2 	C1(=NC(C(O)=O)CC1)	CAS:2906-39-0	1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	proline biosynthesis
L-delta1-pyrroline-5-carboxylate	pyrroline 5-carboxylate*(S)-1-pyrroline-5-carboxylate*1-pyrroline-5-carboxylate*L-1-pyrroline-5-carboxylate*&delta;-1-pyrroline-5-carboxylic acid*&delta;-1-pyrroline-5-carboxylate	C5 H7 N1 O2 	C1(=NC(C(O)=O)CC1)	CAS:2906-39-0	1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	arginine degradation II
L-delta1-pyrroline-5-carboxylate	pyrroline 5-carboxylate*(S)-1-pyrroline-5-carboxylate*1-pyrroline-5-carboxylate*L-1-pyrroline-5-carboxylate*&delta;-1-pyrroline-5-carboxylic acid*&delta;-1-pyrroline-5-carboxylate	C5 H7 N1 O2 	C1(=NC(C(O)=O)CC1)	CAS:2906-39-0	1.5.99.8	L-proline + acceptor  =  L-delta1-pyrroline-5-carboxylate + reduced acceptor	proline degradation
L-delta1-pyrroline-5-carboxylate	pyrroline 5-carboxylate*(S)-1-pyrroline-5-carboxylate*1-pyrroline-5-carboxylate*L-1-pyrroline-5-carboxylate*&delta;-1-pyrroline-5-carboxylic acid*&delta;-1-pyrroline-5-carboxylate	C5 H7 N1 O2 	C1(=NC(C(O)=O)CC1)	CAS:2906-39-0	SPONTPRO-RXN	L-glutamate gamma-semialdehyde  =  H2O + L-delta1-pyrroline-5-carboxylate	proline biosynthesis
L-delta1-pyrroline-5-carboxylate	pyrroline 5-carboxylate*(S)-1-pyrroline-5-carboxylate*1-pyrroline-5-carboxylate*L-1-pyrroline-5-carboxylate*&delta;-1-pyrroline-5-carboxylic acid*&delta;-1-pyrroline-5-carboxylate	C5 H7 N1 O2 	C1(=NC(C(O)=O)CC1)	CAS:2906-39-0	SPONTPRO-RXN	L-glutamate gamma-semialdehyde  =  H2O + L-delta1-pyrroline-5-carboxylate	arginine degradation II
indole		C8 H7 N1 	c1([nH]c2(c(c1)cccc2))	CAS:120-72-9	RXN0-2382	indole + L-serine  =  L-tryptophan + H2O	tryptophan biosynthesis
indole		C8 H7 N1 	c1([nH]c2(c(c1)cccc2))	CAS:120-72-9	RXN-1408	indole + acetate  =  indole-3-acetate	IAA biosynthesis I
indole		C8 H7 N1 	c1([nH]c2(c(c1)cccc2))	CAS:120-72-9	RXN-1407	indole-3-glycerol-phosphate  =  indole + glycerol-3-phosphate	IAA biosynthesis I
indole		C8 H7 N1 	c1([nH]c2(c(c1)cccc2))	CAS:120-72-9	RXN0-2381	indole-3-glycerol-phosphate  =  indole + D-glyceraldehyde-3-phosphate	tryptophan biosynthesis
3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate	3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoic acid*oxopentenyl-cyclopentane-octanoic acid*8-[(1R,2R)-3-oxo-2-{(Z)-pent-2-enyl}cyclopentyl]octanoate	C18 H30 O3 	CCC=CCC1(C(CCC1=O)CCCCCCCC(=O)O)		1.3.1.42	NADPH + 12-oxo-cis-10,15-phytodienoate  =  NADP+ + 3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate	jasmonic acid biosynthesis
3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate	3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoic acid*oxopentenyl-cyclopentane-octanoic acid*8-[(1R,2R)-3-oxo-2-{(Z)-pent-2-enyl}cyclopentyl]octanoate	C18 H30 O3 	CCC=CCC1(C(CCC1=O)CCCCCCCC(=O)O)		RXN-744	3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate + 3 O2  =  (+)-7-isojasmonate + 3 acetate	jasmonic acid biosynthesis
(+)-7-isojasmonate	(+)-7-isojasmonic acid*isojasmonic acid*(3R,7S)-(+)-7-isojasmonate	C12 H18 O3 	CCC=CCC1(C(CC(=O)O)CCC1=O)		RXN-745	(+)-7-isojasmonate  =  (-)-jasmonate	jasmonic acid biosynthesis
(+)-7-isojasmonate	(+)-7-isojasmonic acid*isojasmonic acid*(3R,7S)-(+)-7-isojasmonate	C12 H18 O3 	CCC=CCC1(C(CC(=O)O)CCC1=O)		RXN-744	3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate + 3 O2  =  (+)-7-isojasmonate + 3 acetate	jasmonic acid biosynthesis
(-)-jasmonate	(-)-jasmonic acid*jasmonic acid*(3R,7R)-(-)-jasmonate	C12 H18 O3 	C(=O)(O)CC1(C(C(=O)CC1)CC=CCC)		2.1.1.141	(-)-jasmonate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + (-)-jasmonic acid methyl ester	jasmonic acid biosynthesis
(-)-jasmonate	(-)-jasmonic acid*jasmonic acid*(3R,7R)-(-)-jasmonate	C12 H18 O3 	C(=O)(O)CC1(C(C(=O)CC1)CC=CCC)		RXN-745	(+)-7-isojasmonate  =  (-)-jasmonate	jasmonic acid biosynthesis
leucocyanidin		C15 H14 O7 	c1(O)(c2(c(cc(c1)O)OC(C(O)C2O)c3(cc(O)c(O)cc3)))		1.14.11.19	leucocyanidin + alpha-ketoglutarate + O2  =  cyanidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
leucocyanidin		C15 H14 O7 	c1(O)(c2(c(cc(c1)O)OC(C(O)C2O)c3(cc(O)c(O)cc3)))		1.1.1.219	dihydroquercetin + NADPH  =  leucocyanidin + NADP+	anthocyanin biosynthesis
(KDO)-lipid IV(A)	3-Deoxy-D-manno-octulosonyl-lipid IV(A)	C76 H142 N2 O30 P2 	CCCCCCCCCCCC(O)CC(=O)NC1(C(OC(=O)CC(O)CCCCCCCCCCC)C(O)C(OC1OP(O)(O)=O)COC2(C(NC(=O)CC(O)CCCCCCCCCCC)C(C(OP(O)(O)=O)C(O2)COC3(OC(C(O)C(C3)O)C(O)CO)(C(O)=O))OC(=O)CC(O)CCCCCCCCCCC))		2.-.-.-	lipid IV(A) + CMP-3-deoxy-D-manno-octulosonate  =  (KDO)-lipid IV(A) + CMP	lipid-A-precursor biosynthesis
cyanidin		C15 H11 O6 	C3(=C(O)C(c1(ccc(O)c(c1)O))=Oc2(cc(O)cc(c23)O))		RXN1F-775	cyanidin + UDP-D-glucose  =  cyanidin-3-glucoside + UDP	anthocyanin biosynthesis
cyanidin		C15 H11 O6 	C3(=C(O)C(c1(ccc(O)c(c1)O))=Oc2(cc(O)cc(c23)O))		1.14.11.19	leucocyanidin + alpha-ketoglutarate + O2  =  cyanidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
crotono-betaine	4-(trimethylammonio)but-2-enoate	C7 H13 N1 O2 	C([N+1](C)(C)C)C=CC(=O)[O-1]		6.3.2.-	coenzyme A + crotono-betaine  =  crotonobetainyl-CoA + H2O	carnitine degradation
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	1.3.99.1	succinate + FAD  =  fumarate + FADH2	TCA cycle variation I
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.3.2.2	adenylo-succinate  =  fumarate + AMP	de novo biosynthesis of purine nucleotides II
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.3.2.2	adenylo-succinate  =  fumarate + AMP	de novo biosynthesis of purine nucleotides I
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis II (acetyl cycle)
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.3.2.1	L-arginino-succinate  =  L-arginine + fumarate	arginine biosynthesis III
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	aerobic respiration
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	superpathway of glyoxylate cycle
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	TCA cycle -- aerobic respiration
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	3.7.1.2	H2O + 4-fumaryl-acetoacetate  =  fumarate + acetoacetate	tyrosine degradation
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	3.7.1.2	H2O + 4-fumaryl-acetoacetate  =  fumarate + acetoacetate	phenylalanine degradation
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.3.2.2	5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole  =  fumarate + AICAR	de novo biosynthesis of purine nucleotides II
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.3.2.2	5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole  =  fumarate + AICAR	de novo biosynthesis of purine nucleotides I
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.2.1.2	fumarate + H2O  =  malate	TCA cycle variation I
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.2.1.2	fumarate + H2O  =  malate	superpathway of glyoxylate cycle
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.2.1.2	fumarate + H2O  =  malate	phenylalanine degradation
fumarate	fum*fumaric acid	C4 H4 O4 	C(O)(=O)C=CC(O)=O	CAS:110-17-8	4.2.1.2	fumarate + H2O  =  malate	TCA cycle -- aerobic respiration
N-carbamoylputrescine		C5 H13 N3 O1 	C(N)CCCNC(=O)N	CAS:6851-51-0	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	polyamine biosynthesis III
N-carbamoylputrescine		C5 H13 N3 O1 	C(N)CCCNC(=O)N	CAS:6851-51-0	3.5.1.53	H2O + N-carbamoylputrescine  =  NH3 + CO2 + putrescine	arginine degradation I
N-carbamoylputrescine		C5 H13 N3 O1 	C(N)CCCNC(=O)N	CAS:6851-51-0	3.5.3.12	H2O + agmatine  =  NH3 + N-carbamoylputrescine	polyamine biosynthesis III
N-carbamoylputrescine		C5 H13 N3 O1 	C(N)CCCNC(=O)N	CAS:6851-51-0	3.5.3.12	H2O + agmatine  =  NH3 + N-carbamoylputrescine	arginine degradation I
ferrocytochrome b1	reduced cytochrome <i>b</i><sub>1</sub>*cytochrome <i>b</i><sub>1</sub> reduced				1.2.2.1	ferricytochrome b1 + formate  =  ferrocytochrome b1 + CO2	glycine degradation
ureidoglycine		C3 H7 N3 O2 	C(N)C(=O)NC(=O)N		3.5.3.9	2 H2O + 2 allantoate  =  2 NH3 + O2 + 2 CO2 + 2 ureidoglycine	ureide degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.3.99.3	FAD + propionyl-CoA  =  FADH2 + acrylyl-CoA	beta-alanine biosynthesis II
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.1.99.5	glycerol-3-phosphate + FAD  =  dihydroxy-acetone-phosphate + FADH2	glycerol degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.5.99.12	isopentenyladenine + FAD + H2O  =  3-methyl-2-butenal + adenine + FADH2	cytokinins degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.5.99.12	isopentenyl adenosine + H2O + FAD  =  adenosine + 3-methyl-2-butenal + FADH2	cytokinins degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.5.99.12	trans-zeatin + H2O + FAD  =  adenine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.5.99.12	cis-zeatin + H2O + FAD  =  3-methyl-4-cis-hydroxy-2-butenal + adenine + FADH2	cytokinins degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.5.99.12	trans-zeatin riboside + H2O + FAD  =  adenosine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	GLUTARYL-COA-DEHYDROG-RXN	glutaryl-CoA + FAD  =  glutaconyl-CoA + FADH2	lysine degradation II
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	GLUTARYL-COA-DEHYDROG-RXN	glutaryl-CoA + FAD  =  glutaconyl-CoA + FADH2	tryptophan degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.3.99.10	isovaleryl-CoA + FAD  =  3-methylcrotonyl-CoA + FADH2	leucine degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.3.99.12	2-methylbutyryl-CoA + FAD  =  tiglyl-CoA + FADH2	isoleucine degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.3.99.12	isobutyryl-CoA + FAD  =  methacrylyl-CoA + FADH2	valine degradation
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.3.99.1	succinate + FAD  =  fumarate + FADH2	TCA cycle variation I
FADH2	flavin adenine dinucleotide reduced*1,5-dihydro-FAD	C27 H35 N9 O15 P2 	Cc3(cc2(N(c1(c(c(=O)[nH]c(=O)[nH]1)[NH]c2cc(C)3))CC(O)C(O)C(O)COP(=O)(O)OP(=O)(O)OCC4(O[CH]([CH](O)[CH]4O)n5(c6(c(nc5)c(N)ncn6)))))	CAS:1910-41-4	1.3.99.3	acyl-CoA + FAD  =  FADH2 + delta2-enoyl-CoA	fatty acid beta-oxidation
indole-3-acetaldoxime	3-indoleacetaldoxime*indole-3-acetaldehyde oxime	C10 H10 N2 O1 	c1(c(CC=NO)c2(c([nH]1)cccc2))		4.99.1.6	indole-3-acetaldoxime  =  3-indoleacetonitrile + H2O	IAA biosynthesis I
indole-3-acetaldoxime	3-indoleacetaldoxime*indole-3-acetaldehyde oxime	C10 H10 N2 O1 	c1(c(CC=NO)c2(c([nH]1)cccc2))		RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
indole-3-acetaldoxime	3-indoleacetaldoxime*indole-3-acetaldehyde oxime	C10 H10 N2 O1 	c1(c(CC=NO)c2(c([nH]1)cccc2))		RXN-1406	N-hydroxyl-tryptamine  =  indole-3-acetaldoxime	IAA biosynthesis I
indole-3-acetaldoxime	3-indoleacetaldoxime*indole-3-acetaldehyde oxime	C10 H10 N2 O1 	c1(c(CC=NO)c2(c([nH]1)cccc2))		1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	IAA biosynthesis I
indole-3-acetaldoxime	3-indoleacetaldoxime*indole-3-acetaldehyde oxime	C10 H10 N2 O1 	c1(c(CC=NO)c2(c([nH]1)cccc2))		1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	glucosinolate biosynthesis from tryptophan
isobutyryl-CoA	2-methylpropanoyl-CoA*isobutyryl-coenzyme A*2-methylpropionyl-CoA*<i>S</i>-(2-methylpropanoyl)-CoA	C25 H42 N7 O17 P3 S1 	c1(c2(c(ncn1)n(cn2)C3(OC(C(C(O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C)))(N)	CAS:15621-60-0	1.3.99.12	isobutyryl-CoA + FAD  =  methacrylyl-CoA + FADH2	valine degradation
isobutyryl-CoA	2-methylpropanoyl-CoA*isobutyryl-coenzyme A*2-methylpropionyl-CoA*<i>S</i>-(2-methylpropanoyl)-CoA	C25 H42 N7 O17 P3 S1 	c1(c2(c(ncn1)n(cn2)C3(OC(C(C(O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C)))(N)	CAS:15621-60-0	1.2.1.25	NAD+ + coenzyme A + 2-keto-isovalerate  =  NADH + CO2 + isobutyryl-CoA	valine degradation
histidinal	L-histidinal	C6 H9 N3 O1 	c1(c(nc[nH]1)C[CH](N)C=O)		1.1.1.23	histidinal + NAD+ + H2O  =  L-histidine + NADH	histidine biosynthesis
histidinal	L-histidinal	C6 H9 N3 O1 	c1(c(nc[nH]1)C[CH](N)C=O)		1.1.1.23	histidinol + NAD+  =  histidinal + NADH	histidine biosynthesis
R-4'-phosphopantothenoyl-L-cysteine	(R)-4'-phospho-N-pantothenoyl-L-cysteine*4-P-N-pantothenoylcysteine*4'-P-N-pantothenoylcysteine*N-((R)-4-phosphopantothenoyl)-L-cysteine*4'-phosphopantothenoylcysteine*4'-phospho-N-pantothenoylcysteine*(R)-4'-phosphopantothenoyl-L-cysteine*N-[(R)-4'-phosphopantothenoyl]-L-cysteine	C12 H23 N2 O9 P1 S1 	CC(C)(COP(O)(O)=O)C(O)C(=O)NCCC(=O)NC(C(O)=O)CS	LIGAND-CPD:C04352	4.1.1.36	R-4'-phosphopantothenoyl-L-cysteine  =  pantetheine 4'-phosphate + CO2	coenzyme A biosynthesis
R-4'-phosphopantothenoyl-L-cysteine	(R)-4'-phospho-N-pantothenoyl-L-cysteine*4-P-N-pantothenoylcysteine*4'-P-N-pantothenoylcysteine*N-((R)-4-phosphopantothenoyl)-L-cysteine*4'-phosphopantothenoylcysteine*4'-phospho-N-pantothenoylcysteine*(R)-4'-phosphopantothenoyl-L-cysteine*N-[(R)-4'-phosphopantothenoyl]-L-cysteine	C12 H23 N2 O9 P1 S1 	CC(C)(COP(O)(O)=O)C(O)C(=O)NCCC(=O)NC(C(O)=O)CS	LIGAND-CPD:C04352	6.3.2.5	D-4'-phosphopantothenate + L-cysteine + CTP  =  R-4'-phosphopantothenoyl-L-cysteine + pyrophosphate + CMP	coenzyme A biosynthesis
anthranilate	anthranilic acid*2-aminobenzoic acid*vitamin L1*o-aminobenzoic acid*2-aminobenzoate	C7 H7 N1 O2 	C(=O)(O)c1(c(N)cccc1)	CAS:118-92-3	2.4.2.18	anthranilate + PRPP  =  N-(5'-phosphoribosyl)-anthranilate + pyrophosphate	tryptophan biosynthesis
anthranilate	anthranilic acid*2-aminobenzoic acid*vitamin L1*o-aminobenzoic acid*2-aminobenzoate	C7 H7 N1 O2 	C(=O)(O)c1(c(N)cccc1)	CAS:118-92-3	4.1.3.27	chorismate + L-glutamine  =  anthranilate + pyruvate + L-glutamate	tryptophan biosynthesis
ethene	olefiant gas*elayl*ethylene	C2 H4 	C=C		1.14.17.4	L-ascorbate + 1-aminocyclopropane-1-carboxylate + O2  =  2 H2O + ethene + L-dehydro-ascorbate + hydrogen cyanide + CO2	ethylene biosynthesis from methionine
SO3-2	SO<SUB>3</SUB>*sulfite	O3 S1 	S([O-1])([O-1])=O		3.13.1.1	UDP-D-glucose + SO3-2  =  UDP-sulfoquinovose + H2O	sulfolipid biosynthesis
SO3-2	SO<SUB>3</SUB>*sulfite	O3 S1 	S([O-1])([O-1])=O		1.8.99.2	reduced acceptor + APS  =  AMP + acceptor + SO3-2	sulfate assimilation
SO3-2	SO<SUB>3</SUB>*sulfite	O3 S1 	S([O-1])([O-1])=O		SO3OXTFER-RXN	SO3-2 + 2 oxidized cytochrome c + H2O  =  SO42- + 2 reduced cytochrome c + 2 H+	sulfur oxidation
SO3-2	SO<SUB>3</SUB>*sulfite	O3 S1 	S([O-1])([O-1])=O		SULFOXTFER-RXN	polysulfide-glutathione complex + O2 + H2O  =  SO3-2 + polysulfide-glutathione complex + 2 H+	sulfur oxidation
SO3-2	SO<SUB>3</SUB>*sulfite	O3 S1 	S([O-1])([O-1])=O		1.8.7.1	3 reduced ferredoxin + SO3-2  =  H2O + oxidized ferredoxin + H2S	sulfate assimilation
methanethiol	methyl-mercaptan	C1 H4 S1 	CS		4.4.1.11	L-methionine + H2O  =  NH3 + 2-oxobutanoate + methanethiol	methionine degradation II
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	3.3.1.1	S-adenosyl-homocysteine + H2O  =  homocysteine + adenosine	SAM cycle
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	3.3.1.1	S-adenosyl-homocysteine + H2O  =  homocysteine + adenosine	methionine degradation I
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.-	24-methylenelophenol + S-adenosyl-homocysteine  =  episterol + S-adenosyl-L-methionine	sterol biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.-	24-methylenecycloartenol + S-adenosyl-homocysteine  =  cycloeucalenol + S-adenosyl-L-methionine	sterol biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.-	S-adenosyl-L-methionine + methyl acceptor  =  S-adenosyl-homocysteine + N-methylated acceptor	SAM cycle
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	RXN-6722	benzoate + S-adenosyl-L-methionine  =  methylbenzoate + S-adenosyl-homocysteine	volatile benzenoid ester biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	RXN-6723	salicylate + S-adenosyl-L-methionine  =  methylsalicylate + S-adenosyl-homocysteine	volatile benzenoid ester biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	RXN-7569	demethylphylloquinone + S-adenosyl-L-methionine  =  phylloquinone + S-adenosyl-homocysteine	phylloquinone biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	RXN-5761	ethanolamine + S-adenosyl-L-methionine  =  N-monomethylethanolamine + S-adenosyl-homocysteine	choline biosynthesis II
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	RXN-5762	N-monomethylethanolamine + S-adenosyl-L-methionine  =  N-dimethylethanolamine + S-adenosyl-homocysteine	choline biosynthesis II
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	RXN-5763	N-dimethylethanolamine + S-adenosyl-L-methionine  =  choline + S-adenosyl-homocysteine	choline biosynthesis II
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.143	24-methylenelophenol + S-adenosyl-L-methionine  =  24-ethylidenelophenol + S-adenosyl-homocysteine	sterol biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.79	oleate + S-adenosyl-L-methionine  =  dihydrosterculate + S-adenosyl-homocysteine	cyclopropane and cyclopropene fatty acid biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.103	N-methylethanolamine phosphate + S-adenosyl-L-methionine  =  N-dimethylethanolamine phosphate + S-adenosyl-homocysteine	choline biosynthesis I
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.103	N-dimethylethanolamine phosphate + S-adenosyl-L-methionine  =  phosphoryl-choline + S-adenosyl-homocysteine	choline biosynthesis I
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.68	5-hydroxy-ferulic-acid + S-adenosyl-L-methionine  =  sinapate + S-adenosyl-homocysteine	phenylpropanoid biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.41	cycloartenol + S-adenosyl-L-methionine  =  24-methylenecycloartenol + S-adenosyl-homocysteine	sterol biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.-	2-methyl-6-solanyl-1,4-benzoquinone + S-adenosyl-L-methionine  =  plastoquinone-9 + S-adenosyl-homocysteine	plastoquinone biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.37	DNA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + DNA CONTAINING 5-METHYLCYTOSINE	methionine degradation I
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.68	caffeate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + ferulate	phenylpropanoid biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.68	caffeate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + ferulate	suberin biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.141	(-)-jasmonate + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + (-)-jasmonic acid methyl ester	jasmonic acid biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	ADOMET-DMK-METHYLTRANSFER-RXN	demethylmenaquinone-8 + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + menaquinone-8	menaquinone biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.-	uroporphyrinogen-III + 2 S-adenosyl-L-methionine  =  2 S-adenosyl-homocysteine + dihydrosirohydrochlorin	biosynthesis of proto- and siroheme
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.68	5-hydroxy-coniferaldehyde + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + sinapaldehyde	lignin biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.-	2-methyl-6-phytyl-1,4-benzoquinone + S-adenosyl-L-methionine  =  2,3-dimethyl-6-phytyl-1,4-benzoquinone + S-adenosyl-homocysteine	vitamin E biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.95	delta-tocopherol + S-adenosyl-L-methionine  =  beta-tocopherol + S-adenosyl-homocysteine	vitamin E biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.11	Mg-protoporphyrin + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + Mg-protoporphyrin monomethyl ester	chlorophyllide a biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.10	homocysteine + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + L-methionine	methionine biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.104	caffeoyl-CoA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + feruloyl-CoA	lignin biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.104	caffeoyl-CoA + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + feruloyl-CoA	suberin biosynthesis
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.103	phosphoryl-ethanolamine + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + N-methylethanolamine phosphate	choline biosynthesis I
S-adenosyl-homocysteine	AdoHcy*2-S-adenosyl-L-homocysteine*S-adenosyl-L-homocysteine*S-adenosylhomocysteine*adenosyl-homo-cys*adenosylhomocysteine*adenosylhomo-cys*SAH	C14 H20 N6 O5 S1 	C(CC(N)C(O)=O)SC[CH]1(O[CH]([CH](O)[CH]1O)N2(c3(c(N=C2)c(N)ncn3)))	LIGAND-CPD:C00021*CAS:979-92-0	2.1.1.95	gamma-tocopherol + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + alpha-tocopherol	vitamin E biosynthesis
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	2.7.1.19	D-ribulose-5-phosphate + ATP  =  D-ribulose-1,5-bisphosphate + ADP	Calvin cycle
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	5.1.3.1	D-ribulose-5-phosphate  =  D-xylulose-5-phosphate	Calvin cycle
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	5.1.3.1	D-ribulose-5-phosphate  =  D-xylulose-5-phosphate	non-oxidative branch of the pentose phosphate pathway
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	DIOHBUTANONEPSYN-RXN	D-ribulose-5-phosphate  =  3,4-dihydroxy-2-butanone-4-P + formate	riboflavin and FMN and FAD biosynthesis
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	superpathway of gluconate degradation
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	1.1.1.44	6-phospho-D-gluconate + NAD(P)+  =  D-ribulose-5-phosphate + CO2 + NAD(P)H	oxidative branch of the pentose phosphate pathway
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	5.3.1.6	D-ribose-5-phosphate  =  D-ribulose-5-phosphate	Calvin cycle
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	5.3.1.6	D-ribose-5-phosphate  =  D-ribulose-5-phosphate	superpathway of gluconate degradation
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	5.3.1.6	D-ribose-5-phosphate  =  D-ribulose-5-phosphate	ribose degradation
D-ribulose-5-phosphate	ribulose-5P*D-ribulose-5-P*ribulose-5-P*ribulose-5-phosphate	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:4151-19-3	5.3.1.6	D-ribose-5-phosphate  =  D-ribulose-5-phosphate	non-oxidative branch of the pentose phosphate pathway
indole-3-acetyl-polypeptide					RXN-2942	indole-3-acetate + polypeptide  =  indole-3-acetyl-polypeptide	IAA conjugate biosynthesis
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	4.2.1.22	homocysteine + L-serine  =  H2O + cystathionine	homocysteine and cysteine interconversion
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	4.2.1.22	homocysteine + L-serine  =  H2O + cystathionine	methionine degradation I
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	2.1.1.10	homocysteine + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + L-methionine	methionine biosynthesis
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	2.1.1.14	5-methyltetrahydropteroyltri-L-glutamate + homocysteine  =  tetrahydropteroyltri-L-glutamate + L-methionine	methionine biosynthesis
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	2.1.1.14	5-methyltetrahydropteroyltri-L-glutamate + homocysteine  =  tetrahydropteroyltri-L-glutamate + L-methionine	sulfate assimilation
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	2.1.1.-	S-Methyl-L-methionine + homocysteine  =  2 L-methionine	methionine biosynthesis
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	2.1.1.14	5-methyl-THF + homocysteine  =  tetrahydrofolate + L-methionine	SAM cycle
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	2.1.1.14	5-methyl-THF + homocysteine  =  tetrahydrofolate + L-methionine	formylTHF biosynthesis I
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	2.1.1.13	homocysteine + 5-methyl-THF  =  L-methionine + tetrahydrofolate	formylTHF biosynthesis
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	3.3.1.1	S-adenosyl-homocysteine + H2O  =  homocysteine + adenosine	SAM cycle
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	3.3.1.1	S-adenosyl-homocysteine + H2O  =  homocysteine + adenosine	methionine degradation I
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	homocysteine and cysteine interconversion
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	methionine biosynthesis
homocysteine	homo-cys*L-Homocysteine	C4 H9 N1 O2 S1 	C(S)CC(N)C(=O)O	LIGAND-CPD:C00155*CAS:6027-13-0*CAS:454-28-4	4.4.1.8	cystathionine + H2O  =  NH3 + pyruvate + homocysteine	sulfate assimilation
sucrose-6'-phosphate	sucrose-6F-P	C12 H23 O14 P1 	C(O)C1(OC(C(O)C(O)C1O)OC2(CO)(OC(C(O)C2O)COP(O)(O)=O))		3.1.3.24	H2O + sucrose-6'-phosphate  =  sucrose + phosphate	sucrose biosynthesis
sucrose-6'-phosphate	sucrose-6F-P	C12 H23 O14 P1 	C(O)C1(OC(C(O)C(O)C1O)OC2(CO)(OC(C(O)C2O)COP(O)(O)=O))		2.4.1.14	D-fructose-6-phosphate + UDP-D-glucose  =  sucrose-6'-phosphate + UDP	sucrose biosynthesis
N-dimethylethanolamine phosphate	P-DME	C4 H12 N1 O4 P1 	C(CN(C)C)OP(=O)(O)O		2.1.1.103	N-dimethylethanolamine phosphate + S-adenosyl-L-methionine  =  phosphoryl-choline + S-adenosyl-homocysteine	choline biosynthesis I
N-dimethylethanolamine phosphate	P-DME	C4 H12 N1 O4 P1 	C(CN(C)C)OP(=O)(O)O		2.1.1.103	N-methylethanolamine phosphate + S-adenosyl-L-methionine  =  N-dimethylethanolamine phosphate + S-adenosyl-homocysteine	choline biosynthesis I
tetrahydropteroyltri-L-glutamate		C24 H34 N8 O12 	C(=O)(O)CCC(N)C(=O)OC2(C1(NC(=CNC=1N=C(N=2)N)C(OC(=O)C(N)CCC(=O)O)C(C)OC(=O)C(N)CCC(O)=O))	LIGAND-CPD:C04144	2.1.1.14	5-methyltetrahydropteroyltri-L-glutamate + homocysteine  =  tetrahydropteroyltri-L-glutamate + L-methionine	methionine biosynthesis
tetrahydropteroyltri-L-glutamate		C24 H34 N8 O12 	C(=O)(O)CCC(N)C(=O)OC2(C1(NC(=CNC=1N=C(N=2)N)C(OC(=O)C(N)CCC(=O)O)C(C)OC(=O)C(N)CCC(O)=O))	LIGAND-CPD:C04144	2.1.1.14	5-methyltetrahydropteroyltri-L-glutamate + homocysteine  =  tetrahydropteroyltri-L-glutamate + L-methionine	sulfate assimilation
5-methyltetrahydropteroyltri-L-glutamate		C25 H36 N8 O12 	C2(OC(=O)C(N)CCC(=O)O)(C1(N(C)C(=CNC=1N=C(N)N=2)C(OC(=O)C(N)CCC(=O)O)C(C)OC(=O)C(N)CCC(O)=O))	LIGAND-CPD:C04489	2.1.1.14	5-methyltetrahydropteroyltri-L-glutamate + homocysteine  =  tetrahydropteroyltri-L-glutamate + L-methionine	methionine biosynthesis
5-methyltetrahydropteroyltri-L-glutamate		C25 H36 N8 O12 	C2(OC(=O)C(N)CCC(=O)O)(C1(N(C)C(=CNC=1N=C(N)N=2)C(OC(=O)C(N)CCC(=O)O)C(C)OC(=O)C(N)CCC(O)=O))	LIGAND-CPD:C04489	2.1.1.14	5-methyltetrahydropteroyltri-L-glutamate + homocysteine  =  tetrahydropteroyltri-L-glutamate + L-methionine	sulfate assimilation
heme O		C49 H58 N4 O5 FE1 	Cc8(c3(n7([Fe]25(n4(c(=CC1(C(C)=C(C(N=12)=C3)C=C))c(c(C)c4=CC6(=N5C(C(=C6C)CCC(=O)O)=Cc7c8CCC(=O)O))C(O)CCC=C(C)CCC=C(C)CCC=C(C)C)))))		2.5.1.-	protoheme + trans, trans-farnesyl diphosphate + H2O  =  heme O + pyrophosphate	biosynthesis of proto- and siroheme
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	2.4.1.121	indole-3-acetate + UDP-D-glucose  =  indole-3-acetyl-beta-1-D-glucose + UDP	IAA conjugate biosynthesis
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	RXN-2947	indole-3-acetate + L-glutamate  =  indole-3-acetyl-glu + H2O	IAA conjugate biosynthesis
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	RXN-2946	indole-3-acetate + L-aspartate  =  indole-3-acetyl-asp + H2O	IAA conjugate biosynthesis
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	RXN-2945	indole-3-acetate + L-leucine  =  indole-3-acetyl-leu + H2O	IAA conjugate biosynthesis
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	RXN-2944	indole-3-acetate + L-alanine  =  indole-3-acetyl-ala + H2O	IAA conjugate biosynthesis
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	RXN-2942	indole-3-acetate + polypeptide  =  indole-3-acetyl-polypeptide	IAA conjugate biosynthesis
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	RXN-2948	indole-3-acetate + L-glutamine  =  indole-3-acetyl-gln + H2O	IAA conjugate biosynthesis
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	3.5.1.-	indole-3-acetyl-ala + H2O  =  indole-3-acetate + L-alanine	IAA biosynthesis II
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	3.5.1.-	indole-3-acetyl-leu + H2O  =  indole-3-acetate + L-leucine	IAA biosynthesis II
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	1.2.3.7	O2 + 2 indole acetaldehyde  =  2 indole-3-acetate	IAA biosynthesis I
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	3.5.5.1	3-indoleacetonitrile + 2 H2O  =  NH3 + indole-3-acetate	IAA biosynthesis I
indole-3-acetate	IAA*indole-3-acetic acid*indoleacetic acid*auxin*indoleacetate	C10 H9 N1 O2 	c1(c(CC(=O)O)c2(c([nH]1)cccc2))	CAS:87-51-4	RXN-1408	indole + acetate  =  indole-3-acetate	IAA biosynthesis I
L-leucine	(2S)-&alpha;-2-amino-4-methylvaleric acid*L*leu*leucine*2-amino-4-methylvaleric acid*(2S)-&alpha;-leucine	C6 H13 N1 O2 	CC(C)CC(N)C(=O)O	LIGAND:C00123*CAS:7005-03-0*NCI:46709*CAS:61-90-5	6.1.1.4	L-leucine + tRNAleu + ATP  =  L-leucyl-tRNAleu + pyrophosphate + AMP	tRNA charging pathway
L-leucine	(2S)-&alpha;-2-amino-4-methylvaleric acid*L*leu*leucine*2-amino-4-methylvaleric acid*(2S)-&alpha;-leucine	C6 H13 N1 O2 	CC(C)CC(N)C(=O)O	LIGAND:C00123*CAS:7005-03-0*NCI:46709*CAS:61-90-5	RXN-2945	indole-3-acetate + L-leucine  =  indole-3-acetyl-leu + H2O	IAA conjugate biosynthesis
L-leucine	(2S)-&alpha;-2-amino-4-methylvaleric acid*L*leu*leucine*2-amino-4-methylvaleric acid*(2S)-&alpha;-leucine	C6 H13 N1 O2 	CC(C)CC(N)C(=O)O	LIGAND:C00123*CAS:7005-03-0*NCI:46709*CAS:61-90-5	3.5.1.-	indole-3-acetyl-leu + H2O  =  indole-3-acetate + L-leucine	IAA biosynthesis II
L-leucine	(2S)-&alpha;-2-amino-4-methylvaleric acid*L*leu*leucine*2-amino-4-methylvaleric acid*(2S)-&alpha;-leucine	C6 H13 N1 O2 	CC(C)CC(N)C(=O)O	LIGAND:C00123*CAS:7005-03-0*NCI:46709*CAS:61-90-5	2.6.1.42	2-keto-4-methyl-pentanoate + L-glutamate  =  L-leucine + alpha-ketoglutarate	leucine biosynthesis
L-leucine	(2S)-&alpha;-2-amino-4-methylvaleric acid*L*leu*leucine*2-amino-4-methylvaleric acid*(2S)-&alpha;-leucine	C6 H13 N1 O2 	CC(C)CC(N)C(=O)O	LIGAND:C00123*CAS:7005-03-0*NCI:46709*CAS:61-90-5	2.6.1.42	2-keto-4-methyl-pentanoate + L-glutamate  =  L-leucine + alpha-ketoglutarate	leucine degradation
phosphoryl-choline	choline phosphate*phosphocholine*N-Trimethyl-2-aminoethylphosphonate*O-Phosphocholine	C5 H15 N1 O4 P1 	C([N+1](C)(C)C)COP(O)(=O)O	CAS:107-73-3	2.7.7.15	phosphoryl-choline + CTP  =  CDP-choline + pyrophosphate	choline biosynthesis III
phosphoryl-choline	choline phosphate*phosphocholine*N-Trimethyl-2-aminoethylphosphonate*O-Phosphocholine	C5 H15 N1 O4 P1 	C([N+1](C)(C)C)COP(O)(=O)O	CAS:107-73-3	RXN-5647	phosphoryl-choline + H2O  =  choline + phosphate	choline biosynthesis I
phosphoryl-choline	choline phosphate*phosphocholine*N-Trimethyl-2-aminoethylphosphonate*O-Phosphocholine	C5 H15 N1 O4 P1 	C([N+1](C)(C)C)COP(O)(=O)O	CAS:107-73-3	2.1.1.103	N-dimethylethanolamine phosphate + S-adenosyl-L-methionine  =  phosphoryl-choline + S-adenosyl-homocysteine	choline biosynthesis I
keto acid					2.6.1.5	2-oxo-4-methylthiobutanoic acid + an amino acid  =  L-methionine + keto acid	methionine salvage pathway
hydroxypyruvate	OH-pyruvate*OH-pyr*3-hydroxypyruvate	C3 H4 O4 	C(O)(=O)C(=O)CO	CAS:1113-60-6	RXN-974	L-serine + alpha-ketoglutarate  =  hydroxypyruvate + L-glutamate	photorespiration
hydroxypyruvate	OH-pyruvate*OH-pyr*3-hydroxypyruvate	C3 H4 O4 	C(O)(=O)C(=O)CO	CAS:1113-60-6	1.1.1.29	NADH + hydroxypyruvate  =  NAD+ + glycerate	photorespiration
O-phospho-L-homoserine	o-phosphohomoserine	C4 H10 N1 O6 P1 	C(O)(=O)C(N)CCOP(O)(=O)O		4.2.3.1	O-phospho-L-homoserine + H2O  =  phosphate + L-threonine	threonine biosynthesis from homoserine
O-phospho-L-homoserine	o-phosphohomoserine	C4 H10 N1 O6 P1 	C(O)(=O)C(N)CCOP(O)(=O)O		4.2.99.-	L-cysteine + O-phospho-L-homoserine  =  cystathionine + phosphate	methionine biosynthesis
O-phospho-L-homoserine	o-phosphohomoserine	C4 H10 N1 O6 P1 	C(O)(=O)C(N)CCOP(O)(=O)O		4.2.99.-	L-cysteine + O-phospho-L-homoserine  =  cystathionine + phosphate	sulfate assimilation
O-phospho-L-homoserine	o-phosphohomoserine	C4 H10 N1 O6 P1 	C(O)(=O)C(N)CCOP(O)(=O)O		2.7.1.39	homoserine + ATP  =  O-phospho-L-homoserine + ADP	threonine biosynthesis from homoserine
O-phospho-L-homoserine	o-phosphohomoserine	C4 H10 N1 O6 P1 	C(O)(=O)C(N)CCOP(O)(=O)O		2.7.1.39	homoserine + ATP  =  O-phospho-L-homoserine + ADP	methionine biosynthesis
CDP-ethanolamine	cytidine diphosphate ethanolamine	C11 H20 N4 O11 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)OCCN))	LIGAND-CPD:C00570*CAS:3036-18-8	2.7.8.1	1,2-diacylglycerol + CDP-ethanolamine  =  L-1-phosphatidyl-ethanolamine + CMP	phospholipid biosynthesis
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	(deoxy)ribose phosphate degradation
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	ribose degradation
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	non-oxidative branch of the pentose phosphate pathway
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	2TRANSKETO-RXN	D-erythrose-4-phosphate + D-xylulose-5-phosphate  =  D-fructose-6-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	2TRANSKETO-RXN	D-erythrose-4-phosphate + D-xylulose-5-phosphate  =  D-fructose-6-phosphate + D-glyceraldehyde-3-phosphate	non-oxidative branch of the pentose phosphate pathway
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	2.7.1.17	xylulose + ATP  =  D-xylulose-5-phosphate + ADP	xylose degradation
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	5.1.3.1	D-ribulose-5-phosphate  =  D-xylulose-5-phosphate	Calvin cycle
D-xylulose-5-phosphate	xylulose-5-phosphate*xylulose-phosphate*D-xylulose-5-P*xylulose-P	C5 H11 O8 P1 	C(O)C(=O)C(O)C(O)COP(O)(=O)O	CAS:60802-29-1	5.1.3.1	D-ribulose-5-phosphate  =  D-xylulose-5-phosphate	non-oxidative branch of the pentose phosphate pathway
4-amino-4-deoxychorismate		C10 H11 N1 O5 	C=C(C(O)=O)OC1(C(N)C=CC(=C1)C(O)=O)	CAS:97279-79-3	4.1.3.38	4-amino-4-deoxychorismate  =  p-aminobenzoate + pyruvate	tetrahydrofolate biosynthesis I
4-amino-4-deoxychorismate		C10 H11 N1 O5 	C=C(C(O)=O)OC1(C(N)C=CC(=C1)C(O)=O)	CAS:97279-79-3	4.1.3.38	4-amino-4-deoxychorismate  =  p-aminobenzoate + pyruvate	tetrahydrofolate biosynthesis II
4-amino-4-deoxychorismate		C10 H11 N1 O5 	C=C(C(O)=O)OC1(C(N)C=CC(=C1)C(O)=O)	CAS:97279-79-3	6.3.5.8	L-glutamine + chorismate  =  4-amino-4-deoxychorismate + L-glutamate	tetrahydrofolate biosynthesis I
4-amino-4-deoxychorismate		C10 H11 N1 O5 	C=C(C(O)=O)OC1(C(N)C=CC(=C1)C(O)=O)	CAS:97279-79-3	6.3.5.8	L-glutamine + chorismate  =  4-amino-4-deoxychorismate + L-glutamate	tetrahydrofolate biosynthesis II
a tRNA	tRNA				2.5.1.8	a tRNA + dimethylallyl-pyrophosphate  =  prenyl-tRNA + pyrophosphate	cis-zeatin biosynthesis
dGTP	2'-deoxyguanosine-5'-triphosphate*deoxy-GTP*deoxyguanosine-triphosphate	C10 H16 N5 O13 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(CC1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	CAS:2564-35-4	RXN0-746	GTP + reduced flavodoxin  =  dGTP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
dGTP	2'-deoxyguanosine-5'-triphosphate*deoxy-GTP*deoxyguanosine-triphosphate	C10 H16 N5 O13 P3 	C(OP(=O)(O)OP(=O)(O)OP(O)(O)=O)C1(OC(CC1O)n2(c3(c(nc2)c(=O)[nH]c(n3)N)))	CAS:2564-35-4	2.7.4.6	dGDP + ATP  =  dGTP + ADP	de novo biosynthesis of purine nucleotides I
pyridoxal		C8 H9 N1 O3 	C(=O)c1(c(CO)cnc(C)c(O)1)	CAS:66-72-8	2.7.1.35	ATP + pyridoxal  =  ADP + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
5-amino-levulinate	5-aminolevulinate*5-aminolevulinic acid*&gamma;-aminolevulinic acid*5-amino-4-oxopentanoic acid*5-amino-levulinic acid*5-amino-4-oxo-pentanoic acid*ALA*&delta;-aminolevulinic acid	C5 H9 N1 O3 	C(N)C(=O)CCC(=O)O	LIGAND-CPD:C00430*PUBCHEM:137*CAS:5451-09-2*CAS:106-60-5	4.2.1.24	2 5-amino-levulinate  =  2 H2O + porphobilinogen	chlorophyllide a biosynthesis
5-amino-levulinate	5-aminolevulinate*5-aminolevulinic acid*&gamma;-aminolevulinic acid*5-amino-4-oxopentanoic acid*5-amino-levulinic acid*5-amino-4-oxo-pentanoic acid*ALA*&delta;-aminolevulinic acid	C5 H9 N1 O3 	C(N)C(=O)CCC(=O)O	LIGAND-CPD:C00430*PUBCHEM:137*CAS:5451-09-2*CAS:106-60-5	4.2.1.24	2 5-amino-levulinate  =  2 H2O + porphobilinogen	biosynthesis of proto- and siroheme
5-amino-levulinate	5-aminolevulinate*5-aminolevulinic acid*&gamma;-aminolevulinic acid*5-amino-4-oxopentanoic acid*5-amino-levulinic acid*5-amino-4-oxo-pentanoic acid*ALA*&delta;-aminolevulinic acid	C5 H9 N1 O3 	C(N)C(=O)CCC(=O)O	LIGAND-CPD:C00430*PUBCHEM:137*CAS:5451-09-2*CAS:106-60-5	5.4.3.8	glutamate-1-semialdehyde  =  5-amino-levulinate	chlorophyllide a biosynthesis
5-amino-levulinate	5-aminolevulinate*5-aminolevulinic acid*&gamma;-aminolevulinic acid*5-amino-4-oxopentanoic acid*5-amino-levulinic acid*5-amino-4-oxo-pentanoic acid*ALA*&delta;-aminolevulinic acid	C5 H9 N1 O3 	C(N)C(=O)CCC(=O)O	LIGAND-CPD:C00430*PUBCHEM:137*CAS:5451-09-2*CAS:106-60-5	5.4.3.8	glutamate-1-semialdehyde  =  5-amino-levulinate	biosynthesis of proto- and siroheme
acetaldehyde	acetic aldehyde*ethanal*aldehyde*ethyl aldehyde	C2 H4 O1 	[CH](C)=O	UM-BBD-CPD:c0160*LIGAND-CPD:c00084*CAS:75-07-0	1.1.1.1	acetaldehyde + NADH  =  ethanol + NAD+	sucrose degradation to ethanol and lactate (anaerobic)
acetaldehyde	acetic aldehyde*ethanal*aldehyde*ethyl aldehyde	C2 H4 O1 	[CH](C)=O	UM-BBD-CPD:c0160*LIGAND-CPD:c00084*CAS:75-07-0	4.1.1.1	pyruvate  =  acetaldehyde + CO2	sucrose degradation to ethanol and lactate (anaerobic)
acetaldehyde	acetic aldehyde*ethanal*aldehyde*ethyl aldehyde	C2 H4 O1 	[CH](C)=O	UM-BBD-CPD:c0160*LIGAND-CPD:c00084*CAS:75-07-0	4.1.2.4	deoxyribose-5-phosphate  =  acetaldehyde + D-glyceraldehyde-3-phosphate	(deoxy)ribose phosphate degradation
phosphoribulosylformimino-AICAR-P	N-(5'-phospho-D-1'-ribulosylformimino)-5-amino-1-(5''-phosphoribosyl)-4-imidazolecarboxamide*phosphoribulosylformiminoAICAR-phosphate*phosphoribulosyl-formimino-5-aminoimidazole-4-carboxamide ribotide phosphate*phosphoribulosyl-formimino-5-aminoimidazole-4-carboxamide ribonucleotide phosphate*PRFAR*N-(5'phospho-D-1'-ribulosylformimino)-5-amino-1-(5-phosphoribosyl)-4-imidazolecarboxamide	C15 H25 N5 O15 P2 	C(N)(=O)c1(c(n(cn1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O))N=CNCC(=O)[CH](O)[CH](O)COP(O)(O)=O)		2.4.2.-	phosphoribulosylformimino-AICAR-P + L-glutamine  =  D-erythro-imidazole-glycerol-phosphate + AICAR + L-glutamate	histidine biosynthesis
phosphoribulosylformimino-AICAR-P	N-(5'-phospho-D-1'-ribulosylformimino)-5-amino-1-(5''-phosphoribosyl)-4-imidazolecarboxamide*phosphoribulosylformiminoAICAR-phosphate*phosphoribulosyl-formimino-5-aminoimidazole-4-carboxamide ribotide phosphate*phosphoribulosyl-formimino-5-aminoimidazole-4-carboxamide ribonucleotide phosphate*PRFAR*N-(5'phospho-D-1'-ribulosylformimino)-5-amino-1-(5-phosphoribosyl)-4-imidazolecarboxamide	C15 H25 N5 O15 P2 	C(N)(=O)c1(c(n(cn1)[CH]2(O[CH]([CH](O)[CH](O)2)COP(O)(=O)O))N=CNCC(=O)[CH](O)[CH](O)COP(O)(O)=O)		5.3.1.16	phosphoribosylformiminoAICAR-phosphate  =  phosphoribulosylformimino-AICAR-P	histidine biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.85	2-D-threo-hydroxy-3-carboxy-isocaproate + NAD+  =  2-keto-4-methyl-pentanoate + NADH + CO2	leucine biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.103	L-threonine + NAD+  =  2-amino-3-oxobutanoate + NADH	threonine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.7.1.1	NO3- + NADH  =  NO2- + H2O + NAD+	nitrate assimilation pathway
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	purine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	salvage pathways of purine nucleosides
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	ureide biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.205	H2O + NAD+ + IMP  =  xanthosine-5-phosphate + NADH	de novo biosynthesis of purine nucleotides I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	2.7.1.23	NAD+ + ATP  =  NADP+ + ADP	NAD/NADH phosphorylation and dephosphorylation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.95	3-phosphoglycerate + NAD+  =  3-phospho-hydroxypyruvate + NADH	serine biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.29	NADH + hydroxypyruvate  =  NAD+ + glycerate	photorespiration
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	sucrose degradation to ethanol and lactate (anaerobic)
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glycolysis II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	gluconeogenesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.12	D-glyceraldehyde-3-phosphate + phosphate + NAD+  =  1,3-diphosphateglycerate + NADH	glyceraldehyde 3-phosphate degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	UDP-D-xylose biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	colanic acid building blocks biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.22	H2O + 2 NAD+ + UDP-D-glucose  =  2 NADH + UDP-D-glucuronate	galactose degradation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.3.1.9	NADH + trans-delta2-enoyl-acyl-ACP  =  acyl-ACP + NAD+	fatty acid elongation -- saturated
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.27	NADH + pyruvate  =  NAD+ + lactate	sucrose degradation to ethanol and lactate (anaerobic)
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.31	NAD+ + 3-hydroxy-isobutyrate  =  NADH + methylmalonate-semialdehyde	valine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	purine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	ureide biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	ammonia assimilation cycle
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.4.1.14	NADH + alpha-ketoglutarate + L-glutamine  =  NAD+ + 2 L-glutamate	glutamate biosynthesis II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.23	histidinal + NAD+ + H2O  =  L-histidine + NADH	histidine biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	3.2.2.5	H2O + NAD+  =  adenosine diphosphate ribose + nicotinamide	pyridine nucleotide cycling
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	3.6.1.22	H2O + NAD+  =  nicotinamide mononucleotide + AMP	pyridine nucleotide cycling
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	photorespiration
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.5.1.15	5,10-methylene-THF + NAD+  =  5,10-methenyl-THF + NADH	glycine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	DIMETHUROPORDEHYDROG-RXN	dihydrosirohydrochlorin + NAD+  =  sirohydrochlorin + NADH	biosynthesis of proto- and siroheme
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	TCA cycle variation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.38	NAD+ + malate  =  NADH + CO2 + pyruvate	gluconeogenesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	TCA cycle variation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	superpathway of glyoxylate cycle
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	glyoxylate cycle
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	phenylalanine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	TCA cycle -- aerobic respiration
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.37	malate + NAD+  =  oxaloacetate + NADH	gluconeogenesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.-	L-galactose + NAD+  =  L-galactono-1,4-lactone + NADH	ascorbate biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	ALPHA-KETOBUTYRATE-DEHYDROG-RXN	2-oxobutanoate + coenzyme A + NAD+  =  propionyl-CoA + CO2 + NADH	methionine degradation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle variation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	2OXOGLUTARATEDEH-RXN	alpha-ketoglutarate + coenzyme A + NAD+  =  succinyl-CoA + CO2 + NADH	TCA cycle -- aerobic respiration
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	TCA cycle variation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	superpathway of glycolysis, pyruvate dehydrogenase, TCA, and glyoxylate bypass
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.35	NAD+ + L-3-hydroxyacyl-CoA  =  NADH + beta-ketoacyl-CoA	fatty acid beta-oxidation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.25	NAD+ + coenzyme A + 2-keto-isovalerate  =  NADH + CO2 + isobutyryl-CoA	valine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.27	NAD+ + coenzyme A + methylmalonate-semialdehyde  =  NADH + CO2 + propionyl-CoA	valine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.23	histidinol + NAD+  =  histidinal + NADH	histidine biosynthesis
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.57	NADH + fructuronate  =  NAD+ + D-mannonate	beta-D-glucuronide degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	2KETO-3METHYLVALERATE-RXN	2-keto-3-methyl-valerate + NAD+ + coenzyme A  =  2-methylbutyryl-CoA + NADH + CO2	isoleucine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.178	NAD+ + 2-methyl-3-hydroxybutyryl-CoA  =  NADH + 2-methylaceto-acetyl-CoA	isoleucine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.255	NAD+ + mannitol  =  NADH + mannose	mannitol degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	2KETO-4METHYL-PENTANOATE-DEHYDROG-RXN	2-keto-4-methyl-pentanoate + coenzyme A + NAD+  =  isovaleryl-CoA + CO2 + NADH	leucine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	glutamate degradation II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	arginine degradation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.19	4-amino-butyraldehyde + NAD+ + H2O  =  4-aminobutyrate + NADH	arginine degradation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.3.1.12	prephenate + NAD+  =  p-hydroxyphenylpyruvate + CO2 + NADH	tyrosine biosynthesis I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	lysine degradation II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	2-KETO-ADIPATE-DEHYDROG-RXN	alpha-ketoadipate + NAD+ + coenzyme A  =  CO2 + NADH + glutaryl-CoA	tryptophan degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.32	H2O + NAD+ + 2-aminomuconate semialdehyde  =  NADH + 2-amino-muconate	tryptophan degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.145	campesterol + NAD+  =  campest-5-en-3-one + NADH	brassinosteroid biosynthesis III
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid omega-oxidation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.2.1.3	a fatty aldehyde + NAD+ + H2O  =  a fatty acidn-1 + NADH	fatty acid alpha-oxidation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	RXN-4466	a omega-oxo fatty acid + H2O + NAD+  =  a dicarboxylate + NADH	fatty acid omega-oxidation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	ALLYSINE-DEHYDROG-RXN	H2O + allysine + NAD+  =  alpha-aminoadipate + NADH	lysine degradation II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.5.1.9	H2O + NAD+ + saccharopine  =  NADH + allysine + L-glutamate	lysine degradation II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.3.1.43	NAD+ + L-arogenate  =  L-tyrosine + CO2 + NADH	tyrosine biosynthesis II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.4.1.2	H2O + NAD+ + L-glutamate  =  NH3 + NADH + alpha-ketoglutarate	glutamate degradation I
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.59	NAD+ + 3-hydroxy-propionate  =  NADH + malonate semialdehyde	beta-alanine biosynthesis II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.6.1.1	NAD+ + NADPH  =  NADH + NADP+	NAD/NADH phosphorylation and dephosphorylation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	purine degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	salvage pathways of purine nucleosides
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	3.1.3.-	H2O + NADP+  =  NAD+ + phosphate	NAD/NADH phosphorylation and dephosphorylation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.6.5.3	a ubiquinone + NADH  =  a ubiquinol + NAD+	aerobic respiration
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	2-AMINOMUCONATE-REDUCTASE-RXN	2-amino-muconate + 2 H2O + NADH  =  NH(4)OH + alpha-ketoadipate + NAD+	tryptophan degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.-	3-hydroxybutyryl-CoA + NAD+  =  acetoacetyl-CoA + NADH	lysine degradation II
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.-	3-hydroxybutyryl-CoA + NAD+  =  acetoacetyl-CoA + NADH	tryptophan degradation
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.1.1.1	acetaldehyde + NADH  =  ethanol + NAD+	sucrose degradation to ethanol and lactate (anaerobic)
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	NAD biosynthesis I (from aspartate)
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	pyridine nucleotide cycling
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis II (from tryptophan)
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis I (from aspartate)
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	pyridine nucleotide cycling
NAD+	&beta;-nicotinamide adenine dinucleotide*coenzyme I*diphosphopyridine nucleotide*diphosphopyridine nucleotide oxidized*nicotinamide adenine dinucleotide*nicotinamide adenine dinucleotide oxidized*NAD-oxidized*NAD-ox*NAD+*DPN+*DPN-ox*DPN*beta-nicotinamide adenine dinucleotide*NAD	C21 H28 N7 O14 P2 	c1([n+1](cc(C(=O)N)cc1)C2(OC(C(O)C2O)COP(=O)(O)OP(=O)(O)OCC3(OC(C(O)C3O)n4(c5(c(nc4)c(N)ncn5)))))	LIGAND-CPD:C00003*CAS:53-84-9	1.6.5.3	ubiquinol-8 + NAD+  =  ubiquinone-8 + NADH	NAD/NADH phosphorylation and dephosphorylation
N-monomethylethanolamine		C3 H9 N1 O1 	C(CO)[NH]C		RXN-5762	N-monomethylethanolamine + S-adenosyl-L-methionine  =  N-dimethylethanolamine + S-adenosyl-homocysteine	choline biosynthesis II
N-monomethylethanolamine		C3 H9 N1 O1 	C(CO)[NH]C		RXN-5761	ethanolamine + S-adenosyl-L-methionine  =  N-monomethylethanolamine + S-adenosyl-homocysteine	choline biosynthesis II
N-dimethylethanolamine		C4 H11 N1 O1 	C(CO)N(C)C		RXN-5763	N-dimethylethanolamine + S-adenosyl-L-methionine  =  choline + S-adenosyl-homocysteine	choline biosynthesis II
N-dimethylethanolamine		C4 H11 N1 O1 	C(CO)N(C)C		RXN-5762	N-monomethylethanolamine + S-adenosyl-L-methionine  =  N-dimethylethanolamine + S-adenosyl-homocysteine	choline biosynthesis II
N-succinyl-L,L-2,6-diaminopimelate	<i>N</i>-succinyl-L-2,6-diaminoheptanedioate*<i>N</i>-succinyl-LL-2,6-diaminoheptanedioate*L,L-SDAP	C11 H18 N2 O7 	C(O)(=O)C(N)CCCC(C(=O)O)NC(=O)CCC(=O)O	CAS:26605-36-7	3.5.1.18	H2O + N-succinyl-L,L-2,6-diaminopimelate  =  L,L-diaminopimelate + succinate	lysine biosynthesis
N-succinyl-L,L-2,6-diaminopimelate	<i>N</i>-succinyl-L-2,6-diaminoheptanedioate*<i>N</i>-succinyl-LL-2,6-diaminoheptanedioate*L,L-SDAP	C11 H18 N2 O7 	C(O)(=O)C(N)CCCC(C(=O)O)NC(=O)CCC(=O)O	CAS:26605-36-7	2.6.1.17	L-glutamate + N-succinyl-2-amino-6-ketopimelate  =  alpha-ketoglutarate + N-succinyl-L,L-2,6-diaminopimelate	lysine biosynthesis
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.30	L-serine + acetyl-CoA  =  O-acetyl-L-serine + coenzyme A	cysteine biosynthesis
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.30	L-serine + acetyl-CoA  =  O-acetyl-L-serine + coenzyme A	sulfate assimilation
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.1	L-glutamate + acetyl-CoA  =  N-acetyl-L-glutamate + coenzyme A	arginine biosynthesis
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.1	L-glutamate + acetyl-CoA  =  N-acetyl-L-glutamate + coenzyme A	arginine biosynthesis II (acetyl cycle)
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	lysine degradation II
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	tryptophan degradation
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.9	2 acetyl-CoA  =  acetoacetyl-CoA + coenzyme A	mevalonate pathway
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.3.-	2-oxo-4-methylthiobutanoic acid + acetyl-CoA + H2O  =  2-(2'-methylthio)ethylmalic-acid + coenzyme A	homomethionine biosynthesis
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	6.4.1.2	HCO3- + H+ + acetyl-CoA + ATP  =  malonyl-CoA + phosphate + ADP	fatty acid biosynthesis - initial steps
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	3-OXOACYL-ACP-COA-SYNTHIII-RXN	acetyl-CoA + malonyl-ACP  =  acetoacetyl-ACP + coenzyme A + CO2	fatty acid biosynthesis - initial steps
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.8	phosphate + acetyl-CoA  =  acetylphosphate + coenzyme A	carbon monoxide dehydrogenase pathway
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	GLUCOSAMINE1PACETYL-RXN	glucosamine-1P + acetyl-CoA  =  N-acetyl-glucosamine-1-phosphate + coenzyme A	UDP-N-acetyl-D-glucosamine biosynthesis
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.84	benzyl alcohol + acetyl-CoA  =  benzylacetate + coenzyme A	volatile benzenoid ester biosynthesis
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.16	coenzyme A + beta-ketoacyl-CoA  =  acyl-CoA + acetyl-CoA	fatty acid beta-oxidation
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	TCA cycle variation I
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	1.2.1.-	pyruvate + coenzyme A + NAD+  =  acetyl-CoA + CO2 + NADH	superpathway of glycolysis, pyruvate dehydrogenase, TCA, and glyoxylate bypass
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	RXN-2006	oxocinnamoyl-CoA + coenzyme A  =  benzoyl-CoA + acetyl-CoA	salicylic acid biosynthesis
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	ACETYLSYNCLTH-RXN	CO + [Co-E-CH3] + coenzyme A  =  acetyl-CoA + [Co-E]	carbon monoxide dehydrogenase pathway
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.3.9	acetyl-CoA + H2O + glyoxylate  =  malate + coenzyme A	glyoxylate cycle
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	4.1.3.5	acetoacetyl-CoA + H2O + acetyl-CoA  =  coenzyme A + 3-hydroxy-3-methyl-glutaryl-CoA	mevalonate pathway
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	4.1.3.4	3-hydroxy-3-methyl-glutaryl-CoA  =  acetoacetate + acetyl-CoA	leucine degradation
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle variation I
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	glyoxylate cycle
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle -- aerobic respiration
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	2.3.1.16	2-methylaceto-acetyl-CoA + coenzyme A  =  propionyl-CoA + acetyl-CoA	isoleucine degradation
acetyl-CoA	ac-<i>S</i>-CoA*acetyl-<i>S</i>-CoA*acetyl coenzyme-A*ac-CoA*acetylcoenzyme-A*acetyl-S-CoA*ac-S-CoA	C23 H38 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(O)(=O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(C)=O)	CAS:72-89-9*UM-BBD-CPD:c0031*LIGAND-CPD:C00024	4.1.3.12	2-keto-isovalerate + acetyl-CoA + H2O  =  3-carboxy-3-hydroxy-isocaproate + coenzyme A	leucine biosynthesis
a ubiquinol	ubiquinols*ubiquinol*dihydroubiquinone*reduced ubiquinone				1.10.2.2	2 ferricytochrome c + a ubiquinol  =  2 ferrocytochrome c + a ubiquinone	aerobic respiration
a ubiquinol	ubiquinols*ubiquinol*dihydroubiquinone*reduced ubiquinone				1.6.5.3	a ubiquinone + NADH  =  a ubiquinol + NAD+	aerobic respiration
a ubiquinol	ubiquinols*ubiquinol*dihydroubiquinone*reduced ubiquinone				1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	aerobic respiration
a ubiquinol	ubiquinols*ubiquinol*dihydroubiquinone*reduced ubiquinone				1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	superpathway of glyoxylate cycle
a ubiquinol	ubiquinols*ubiquinol*dihydroubiquinone*reduced ubiquinone				1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	TCA cycle -- aerobic respiration
L-isoleucyl-tRNAile	L-ISOLEUCYL-TRNA(ILE)				6.1.1.5	tRNAile + L-isoleucine + ATP  =  L-isoleucyl-tRNAile + pyrophosphate + AMP	tRNA charging pathway
2-D-threo-hydroxy-3-carboxy-isocaproate	2-isopropylmalate*3-carboxy-2-hydroxy-4-methylpentanoate*&beta;-isopropylmalate	C7 H12 O5 	C(O)(=O)C(O)C(C(C)C)C(=O)O		1.1.1.85	2-D-threo-hydroxy-3-carboxy-isocaproate + NAD+  =  2-keto-4-methyl-pentanoate + NADH + CO2	leucine biosynthesis
2-D-threo-hydroxy-3-carboxy-isocaproate	2-isopropylmalate*3-carboxy-2-hydroxy-4-methylpentanoate*&beta;-isopropylmalate	C7 H12 O5 	C(O)(=O)C(O)C(C(C)C)C(=O)O		4.2.1.33	3-carboxy-3-hydroxy-isocaproate  =  2-D-threo-hydroxy-3-carboxy-isocaproate	leucine biosynthesis
hydroxymethylpyrimidine phosphate	4-amino-2-methyl-5-phosphomethylpyrimidine*4-amino-5-phosphomethyl-2-methylpyrimidine*HMP-P*4-amino-5-hydroxymethyl-2-methylpyrimidine-P*4-amino-5-hydroxymethyl-2-methylpyrimidine-phosphate	C6 H10 N3 O4 P1 	Cc1(nc(N)c(cn1)COP(O)(O)=O)		2.7.4.7	hydroxymethylpyrimidine phosphate + ATP  =  4-amino-5-hydroxymethyl-2-methylpyrimidine-pyrophosphate + ADP	thiamin biosynthesis
hydroxymethylpyrimidine phosphate	4-amino-2-methyl-5-phosphomethylpyrimidine*4-amino-5-phosphomethyl-2-methylpyrimidine*HMP-P*4-amino-5-hydroxymethyl-2-methylpyrimidine-P*4-amino-5-hydroxymethyl-2-methylpyrimidine-phosphate	C6 H10 N3 O4 P1 	Cc1(nc(N)c(cn1)COP(O)(O)=O)		PYRIMSYN1-RXN	5-aminoimidazole ribonucleotide  =  hydroxymethylpyrimidine phosphate	thiamin biosynthesis
hydroxymethylpyrimidine phosphate	4-amino-2-methyl-5-phosphomethylpyrimidine*4-amino-5-phosphomethyl-2-methylpyrimidine*HMP-P*4-amino-5-hydroxymethyl-2-methylpyrimidine-P*4-amino-5-hydroxymethyl-2-methylpyrimidine-phosphate	C6 H10 N3 O4 P1 	Cc1(nc(N)c(cn1)COP(O)(O)=O)		2.7.1.49	ATP + hydroxymethylpyrimidine  =  ADP + hydroxymethylpyrimidine phosphate	thiamin biosynthesis
4-hydroxybenzyl alcohol		C7 H8 O2 	C(O)C1(=CC=C(O)C=C1)	NCI:227926*CAS:623-05-2	THIAZOLSYN2-RXN	L-tyrosine + 1-deoxy-D-xylulose 5-phosphate + ThiS-COSH  =  4-methyl-5-(beta-hydroxyethyl)thiazole phosphate + 4-hydroxybenzyl alcohol + C1 of tyrosine + ThiS protein	thiamin biosynthesis
GDP-L-galactose		C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C(O)1)OP(O)(=O)OP(O)(=O)OCC2(OC(C(O)C(O)2)n3(c4(c(nc3)c(=O)[nH]c(N)n4))))		RXN-1883	GDP-L-galactose + 2 H2O  =  L-galactose + GMP + phosphate	ascorbate biosynthesis
GDP-L-galactose		C16 H25 N5 O16 P2 	C(O)C1(OC(C(O)C(O)C(O)1)OP(O)(=O)OP(O)(=O)OCC2(OC(C(O)C(O)2)n3(c4(c(nc3)c(=O)[nH]c(N)n4))))		5.1.3.18	GDP-mannose  =  GDP-L-galactose	ascorbate biosynthesis
mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol	&alpha;-D-mannosylchitobiosyldiphosphodolichol*{&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C102 H170 N2 O22 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(OC(CO)C(O)C(O)C(O)3)))		2.4.1.132	mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  (mannosyl)2-(N-acetylglucosaminyl)2-diphosphodolichol   + GDP	dolichyl-diphosphooligosaccharide biosynthesis
mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol	&alpha;-D-mannosylchitobiosyldiphosphodolichol*{&beta;-D-mannosyl-(1->4)-<i>N</i>-acetyl-&beta;-D-glucosaminyl-(1->4)-<i>N</i>-acetyl-D-glucosaminyl}diphosphodolichol	C102 H170 N2 O22 P2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)CCOP(=O)(O)OP(=O)(O)OC1(C(NC(=O)C)C(O)C(C(O1)CO)OC2(OC(CO)C(C(O)C2NC(C)=O)OC3(OC(CO)C(O)C(O)C(O)3)))		2.4.1.142	(N-acetylglucosaminyl)2-diphosphodolichol + GDP-mannose  =  mannosyl-(N-acetylglucosaminyl)2-diphosphodolichol + GDP	dolichyl-diphosphooligosaccharide biosynthesis
caffeoylquinate	chlorogenate*chlorogenic acid	C16 H18 O9 	C(=O)(OC1(C(O)C(O)CC(O)(C1)C(O)=O))C=Cc2(cc(O)c(O)cc2)		2.3.1.133	caffeoylquinate + coenzyme A  =  caffeoyl-CoA + quinate	lignin biosynthesis
caffeoylquinate	chlorogenate*chlorogenic acid	C16 H18 O9 	C(=O)(OC1(C(O)C(O)CC(O)(C1)C(O)=O))C=Cc2(cc(O)c(O)cc2)		1.14.13.36	4-coumaroylquinate + NADPH + O2  =  caffeoylquinate + NADP+ + H2O	lignin biosynthesis
D-methylmalonyl-CoA	(S)-methyl-malonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.1.99.1	D-methylmalonyl-CoA  =  L-methylmalonyl-CoA	isoleucine degradation
D-methylmalonyl-CoA	(S)-methyl-malonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.1.99.1	D-methylmalonyl-CoA  =  L-methylmalonyl-CoA	valine degradation
D-methylmalonyl-CoA	(S)-methyl-malonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	5.1.99.1	D-methylmalonyl-CoA  =  L-methylmalonyl-CoA	methionine degradation I
D-methylmalonyl-CoA	(S)-methyl-malonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	isoleucine degradation
D-methylmalonyl-CoA	(S)-methyl-malonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	valine degradation
D-methylmalonyl-CoA	(S)-methyl-malonyl-CoA*methyl-malonyl-coenzyme A*CH3-malonyl-CoA	C25 H40 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(O)(=O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)C(O)=O)	CAS:104809-02-1	PROPIONYL-COA-CARBOXYLASE-RXN	propionyl-CoA + H2O + ATP + CO2  =  D-methylmalonyl-CoA + phosphate + ADP	methionine degradation I
L-1-phosphatidylglycerol-phosphate	3-(3-phosphatidyl)-glycerol-1-phosphate*phosphatidyl-glycerol-phosphate*3-(3-phosphatidyl)-sn-glycerol-1-phosphate*(3-sn-phosphatidyl)-sn-glycerol-1-phosphate*phosphatidylglycerophosphate*1-phosphatidyl-glycerol-P*L-1-phosphatidylglycerol-P*3(3-sn-Phosphatidyl)-sn-glycerol 1-phosphate*3(3-Phosphatidyl-)L-glycerol 1-phosphate	C8 H14 O13 P2 R2 			3.1.3.27	L-1-phosphatidylglycerol-phosphate + H2O  =  L-1-phosphatidyl-glycerol + phosphate	phospholipid biosynthesis
L-1-phosphatidylglycerol-phosphate	3-(3-phosphatidyl)-glycerol-1-phosphate*phosphatidyl-glycerol-phosphate*3-(3-phosphatidyl)-sn-glycerol-1-phosphate*(3-sn-phosphatidyl)-sn-glycerol-1-phosphate*phosphatidylglycerophosphate*1-phosphatidyl-glycerol-P*L-1-phosphatidylglycerol-P*3(3-sn-Phosphatidyl)-sn-glycerol 1-phosphate*3(3-Phosphatidyl-)L-glycerol 1-phosphate	C8 H14 O13 P2 R2 			2.7.8.5	CDP-diacylglycerol + glycerol-3-phosphate  =  L-1-phosphatidylglycerol-phosphate + CMP	phospholipid biosynthesis
L-histidinol-phosphate	L-histidinol-phosphate*histidinol-P*L-histidinol-p*histidinol-phosphate	C6 H12 N3 O4 P1 	c1(c(nc[nH]1)CC(N)COP(O)(O)=O)	CAS:25679-93-0	3.1.3.15	L-histidinol-phosphate + H2O  =  histidinol + phosphate	histidine biosynthesis
L-histidinol-phosphate	L-histidinol-phosphate*histidinol-P*L-histidinol-p*histidinol-phosphate	C6 H12 N3 O4 P1 	c1(c(nc[nH]1)CC(N)COP(O)(O)=O)	CAS:25679-93-0	2.6.1.9	imidazole acetol-phosphate + L-glutamate  =  L-histidinol-phosphate + alpha-ketoglutarate	histidine biosynthesis
[Co-E]	corrinoid/Fe-S protein, unmethylated				2.1.1.-	5-methyl-THF + [Co-E]  =  tetrahydrofolate + [Co-E-CH3]	carbon monoxide dehydrogenase pathway
[Co-E]	corrinoid/Fe-S protein, unmethylated				ACETYLSYNCLTH-RXN	CO + [Co-E-CH3] + coenzyme A  =  acetyl-CoA + [Co-E]	carbon monoxide dehydrogenase pathway
sinapate		C11 H12 O5 	C(O)(=O)C=CC1(=CC(OC)=C(O)C(=C1)OC)	NCI:59261*CAS:530-59-6	2.4.1.120	sinapate + UDP-D-glucose  =  1-O-sinapoyl-beta-D-glucose + UDP	sinapate ester biosynthesis
sinapate		C11 H12 O5 	C(O)(=O)C=CC1(=CC(OC)=C(O)C(=C1)OC)	NCI:59261*CAS:530-59-6	3.1.1.49	H2O + O-sinapoylcholine  =  choline + sinapate	sinapate ester biosynthesis
sinapate		C11 H12 O5 	C(O)(=O)C=CC1(=CC(OC)=C(O)C(=C1)OC)	NCI:59261*CAS:530-59-6	2.1.1.68	5-hydroxy-ferulic-acid + S-adenosyl-L-methionine  =  sinapate + S-adenosyl-homocysteine	phenylpropanoid biosynthesis
[Co-E-CH3]	corrinoid/Fe-S protein, methylated				ACETYLSYNCLTH-RXN	CO + [Co-E-CH3] + coenzyme A  =  acetyl-CoA + [Co-E]	carbon monoxide dehydrogenase pathway
[Co-E-CH3]	corrinoid/Fe-S protein, methylated				2.1.1.-	5-methyl-THF + [Co-E]  =  tetrahydrofolate + [Co-E-CH3]	carbon monoxide dehydrogenase pathway
GDP-4-dehydro-6-L-deoxygalactose	GDP-4-keto-6-L-deoxygalactose	C16 H23 N5 O15 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		1.-.-.-	GDP-4-dehydro-6-L-deoxygalactose + NADPH  =  guanosine diphosphate fucose + NADP+	colanic acid building blocks biosynthesis
GDP-4-dehydro-6-L-deoxygalactose	GDP-4-keto-6-L-deoxygalactose	C16 H23 N5 O15 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		5.-.-.-	GDP-4-dehydro-6-deoxy-D-mannose  =  GDP-4-dehydro-6-L-deoxygalactose	colanic acid building blocks biosynthesis
O-sinapoylcholine	sinapoylcholine*sinapine	C16 H24 N1 O5 	C(C[N+1](C)(C)C)OC(=O)C=Cc1(cc(OC)c(O)c(c1)OC)	PUBCHEM:89287	3.1.1.49	H2O + O-sinapoylcholine  =  choline + sinapate	sinapate ester biosynthesis
O-sinapoylcholine	sinapoylcholine*sinapine	C16 H24 N1 O5 	C(C[N+1](C)(C)C)OC(=O)C=Cc1(cc(OC)c(O)c(c1)OC)	PUBCHEM:89287	2.3.1.91	1-O-sinapoyl-beta-D-glucose + choline  =  O-sinapoylcholine + beta-D-glucose	sinapate ester biosynthesis
trans-3-methylglutaconyl-CoA	3-Methylglutaconyl-CoA	C27 H42 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=C(C)CC(O)=O)		6.4.1.4	HCO3- + 3-methylcrotonyl-CoA + ATP  =  phosphate + trans-3-methylglutaconyl-CoA + ADP	leucine degradation
trans-3-methylglutaconyl-CoA	3-Methylglutaconyl-CoA	C27 H42 N7 O19 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(O)(=O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C=C(C)CC(O)=O)		4.2.1.18	H2O + trans-3-methylglutaconyl-CoA  =  3-hydroxy-3-methyl-glutaryl-CoA	leucine degradation
3-methylthiopropyl-desulfoglucosinolate		C11 H21 N1 O6 S2 	C1(OC(C(CO)C(O)C(O)1)SC(=NO)CCCSC)(O)		2.8.2.-	3-methylthiopropyl-desulfoglucosinolate + PAPS  =  3-methylthiopropyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from homomethionine
3-methylthiopropyl-desulfoglucosinolate		C11 H21 N1 O6 S2 	C1(OC(C(CO)C(O)C(O)1)SC(=NO)CCCSC)(O)		2.4.1.-	4-methylthiobutylhydroximate + UDP-D-glucose  =  3-methylthiopropyl-desulfoglucosinolate + UDP	glucosinolate biosynthesis from homomethionine
CDP	cytidine-diphosphate*cytidine-5'-diphosphate	C9 H15 N3 O11 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	CAS:63-38-7	2.7.4.6	CTP + ADP  =  CDP + ATP	de novo biosynthesis of pyrimidine ribonucleotides
CDP	cytidine-diphosphate*cytidine-5'-diphosphate	C9 H15 N3 O11 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	CAS:63-38-7	1.17.4.1	Reduced Thioredoxin + CDP  =  Oxidized Thioredoxin + dCDP + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
CDP	cytidine-diphosphate*cytidine-5'-diphosphate	C9 H15 N3 O11 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	CAS:63-38-7	2.7.1.108	dolichol + CTP  =  dolichyl-phosphate + CDP	dolichyl-diphosphooligosaccharide biosynthesis
CDP	cytidine-diphosphate*cytidine-5'-diphosphate	C9 H15 N3 O11 P2 	c1(n(c(=O)nc(N)c1)C2(OC(C(O)C(O)2)COP(O)(=O)OP(O)(=O)O))	CAS:63-38-7	1.17.4.-	CDP + reduced glutaredoxin  =  dCDP + oxidized glutaredoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
malonate semialdehyde	3-oxopropanoate*malonate-S-ald	C3 H4 O3 	C(O)(=O)C[CH]=O	CAS:926-61-4	2.6.1.18	malonate semialdehyde + L-alanine  =  beta-alanine + pyruvate	beta-alanine biosynthesis II
malonate semialdehyde	3-oxopropanoate*malonate-S-ald	C3 H4 O3 	C(O)(=O)C[CH]=O	CAS:926-61-4	1.1.1.59	NAD+ + 3-hydroxy-propionate  =  NADH + malonate semialdehyde	beta-alanine biosynthesis II
5-enolpyruvyl-shikimate-3-phosphate	EPSP*3-enolpyruvyl-shikimate-5-phosphate*3-enolpyruvyl-shikimate-5-P*5-O-(1-carboxyvinyl)-3-phosphoshikimate	C10 H13 O10 P1 	C(=O)(O)C1([CH2][CH](OC(=C)C(=O)O)[CH](O)[CH]([CH]=1)OP(O)(O)=O)		4.2.3.5	5-enolpyruvyl-shikimate-3-phosphate  =  phosphate + chorismate	chorismate biosynthesis
5-enolpyruvyl-shikimate-3-phosphate	EPSP*3-enolpyruvyl-shikimate-5-phosphate*3-enolpyruvyl-shikimate-5-P*5-O-(1-carboxyvinyl)-3-phosphoshikimate	C10 H13 O10 P1 	C(=O)(O)C1([CH2][CH](OC(=C)C(=O)O)[CH](O)[CH]([CH]=1)OP(O)(O)=O)		2.5.1.19	shikimate-3-phosphate + phosphoenolpyruvate  =  5-enolpyruvyl-shikimate-3-phosphate + phosphate	chorismate biosynthesis
cycloartenol	9&beta;,19-cyclo-24-lanosten-3&beta;-ol	C30 H50 O1 	CC(C)=CCCC(C)C1(C5(C)(C(C)(CC1)C2(C4(C3([CH](CC2)C(C)(C)C(O)CC3)(C4))(CC5))))	CAS:469-38-5	2.1.1.41	cycloartenol + S-adenosyl-L-methionine  =  24-methylenecycloartenol + S-adenosyl-homocysteine	sterol biosynthesis
cycloartenol	9&beta;,19-cyclo-24-lanosten-3&beta;-ol	C30 H50 O1 	CC(C)=CCCC(C)C1(C5(C)(C(C)(CC1)C2(C4(C3([CH](CC2)C(C)(C)C(O)CC3)(C4))(CC5))))	CAS:469-38-5	5.4.99.8	(S)-2,3-Epoxysqualene  =  cycloartenol	sterol biosynthesis
tRNAgly	TRNA(GLY)				6.1.1.14	tRNAgly + glycine + ATP  =  glycyl-tRNAgly + pyrophosphate + AMP	tRNA charging pathway
L-dehydro-ascorbate	dehydroascorbate	C6 H6 O6 	C1(OC(C(O)CO)C(=O)C(=O)1)(=O)		1.8.5.1	L-dehydro-ascorbate + 2 glutathione  =  glutathione disulfide + L-ascorbate	ascorbate glutathione cycle
L-dehydro-ascorbate	dehydroascorbate	C6 H6 O6 	C1(OC(C(O)CO)C(=O)C(=O)1)(=O)		1.14.17.4	L-ascorbate + 1-aminocyclopropane-1-carboxylate + O2  =  2 H2O + ethene + L-dehydro-ascorbate + hydrogen cyanide + CO2	ethylene biosynthesis from methionine
L-dehydro-ascorbate	dehydroascorbate	C6 H6 O6 	C1(OC(C(O)CO)C(=O)C(=O)1)(=O)		RXN-3523	2 monodehydroascorbate  =  L-ascorbate + L-dehydro-ascorbate	ascorbate glutathione cycle
18-oxooleate	18-oxooctadec-9-enoic acid	C18 H32 O3 	C(=O)CCCCCCCC=CCCCCCCCC(O)=O		1.1.1.-	18-oxooleate + NADP+ + H2O  =  octadec-9-ene-1,18-dioic-acid + NADPH	suberin biosynthesis
18-oxooleate	18-oxooctadec-9-enoic acid	C18 H32 O3 	C(=O)CCCCCCCC=CCCCCCCCC(O)=O		1.1.1.-	18-hydroxyoleate + NADP+  =  18-oxooleate + NADPH	suberin biosynthesis
2-C-methyl-D-erythritol-2,4-cyclodiphosphate	ME-2,4cPP	C5 H12 O9 P2 	CC1(CO)(C(O)COP(=O)(O)OP(O)(O1)=O)		1.17.4.3	2-C-methyl-D-erythritol-2,4-cyclodiphosphate + e- + H+  =  1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
2-C-methyl-D-erythritol-2,4-cyclodiphosphate	ME-2,4cPP	C5 H12 O9 P2 	CC1(CO)(C(O)COP(=O)(O)OP(O)(O1)=O)		RXN0-302	4-diphosphocytidyl-2-C-methylerythritol 2-phosphate  =  2-C-methyl-D-erythritol-2,4-cyclodiphosphate + CMP	isopentenyl diphosphate biosynthesis -- mevalonate-independent
1-acyl-sn-glycerol-3P	1-acyl-sn-glycerol-3-phosphate*acyl-sn-glycerol-3P*acyl-sn-glycerol-3-phosphate	C4 H8 O7 R1 P1 			2.3.1.51	fatty-acyl-CoA + 1-acyl-sn-glycerol-3P  =  L-phosphatidate + coenzyme A	triacylglycerol biosynthesis
1-acyl-sn-glycerol-3P	1-acyl-sn-glycerol-3-phosphate*acyl-sn-glycerol-3P*acyl-sn-glycerol-3-phosphate	C4 H8 O7 R1 P1 			2.3.1.15	fatty-acyl-CoA + glycerol-3-phosphate  =  1-acyl-sn-glycerol-3P + coenzyme A	triacylglycerol biosynthesis
3-phospho-hydroxypyruvate	3-phosphonooxypyruvate*3-P-hydroxypyruvate*3-p-OH-pyr*3-phosphohydroxypyruvate*3-p-OH-pyruvate*3-p-hydroxy-pyr*3-phosphohydroxy-pyr*phosphohydroxypyruate	C3 H5 O7 P1 	C(C(=O)C(O)=O)OP(=O)(O)O	CAS:3913-50-6	2.6.1.52	3-phospho-hydroxypyruvate + L-glutamate  =  3-phospho-serine + alpha-ketoglutarate	serine biosynthesis
3-phospho-hydroxypyruvate	3-phosphonooxypyruvate*3-P-hydroxypyruvate*3-p-OH-pyr*3-phosphohydroxypyruvate*3-p-OH-pyruvate*3-p-hydroxy-pyr*3-phosphohydroxy-pyr*phosphohydroxypyruate	C3 H5 O7 P1 	C(C(=O)C(O)=O)OP(=O)(O)O	CAS:3913-50-6	1.1.1.95	3-phosphoglycerate + NAD+  =  3-phospho-hydroxypyruvate + NADH	serine biosynthesis
N-acetyl-glucosamine-1-phosphate	N-acetyl-D-glucosamine 1-phosphate*N-acetyl-&alpha;-D-glucosamine 1-phosphate	C8 H16 N1 O9 P1 	CC(=O)NC1(C(OP(O)(O)=O)OC(CO)C(O)C1O)		2.7.7.23	N-acetyl-glucosamine-1-phosphate + UTP  =  UDP-N-acetyl-D-glucosamine + pyrophosphate	UDP-N-acetyl-D-glucosamine biosynthesis
N-acetyl-glucosamine-1-phosphate	N-acetyl-D-glucosamine 1-phosphate*N-acetyl-&alpha;-D-glucosamine 1-phosphate	C8 H16 N1 O9 P1 	CC(=O)NC1(C(OP(O)(O)=O)OC(CO)C(O)C1O)		GLUCOSAMINE1PACETYL-RXN	glucosamine-1P + acetyl-CoA  =  N-acetyl-glucosamine-1-phosphate + coenzyme A	UDP-N-acetyl-D-glucosamine biosynthesis
squalene		C30 H50 	CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C	CAS:111-02-4	1.14.99.7	O2 + reduced acceptor + squalene  =  (S)-2,3-Epoxysqualene + H2O + acceptor	sterol biosynthesis
squalene		C30 H50 	CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C	CAS:111-02-4	2.5.1.21	presqualene diphosphate + NAD(P)H  =  squalene + NAD(P)+ + pyrophosphate	sterol biosynthesis
cadaverine	1,5-pentanediamine*pentamethylenediamine*BioDex 1-*cadaverine	C5 H14 N2 	C(N)CCCCN	CAS:462-94-2	4.1.1.18	L-lysine  =  CO2 + cadaverine	lysine degradation I
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis II (acetyl cycle)
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	arginine biosynthesis III
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	2.1.3.3	L-ornithine + carbamoyl-phosphate  =  citrulline + phosphate	citrulline degradation
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	2.1.3.2	L-aspartate + carbamoyl-phosphate  =  carbamoyl-L-aspartate + phosphate	de novo biosynthesis of pyrimidine ribonucleotides
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	2.7.2.2	carbamoyl-phosphate + ADP  =  NH3 + CO2 + ATP	citrulline degradation
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
carbamoyl-phosphate	carbamoyl-P*carbamyl-phosphate	C1 H4 N1 O5 P1 	C(N)(=O)OP(=O)(O)O	CAS:590-55-6	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
propionate	propionic acid*ethylformic acid*methylacetic acid*propanoate	C3 H6 O2 	C(=O)(O)CC	LIGAND-CPD:C00163*CAS:79-09-4	6.2.1.17	coenzyme A + propionate + ATP  =  propionyl-CoA + pyrophosphate + AMP	beta-alanine biosynthesis II
oxidized flavodoxin					RXN0-724	UTP + reduced flavodoxin  =  dUTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
oxidized flavodoxin					RXN0-723	CTP + reduced flavodoxin  =  dCTP + oxidized flavodoxin + H2O	de novo biosynthesis of pyrimidine deoxyribonucleotides
oxidized flavodoxin					RXN0-745	ATP + reduced flavodoxin  =  dATP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
oxidized flavodoxin					RXN0-746	GTP + reduced flavodoxin  =  dGTP + oxidized flavodoxin + H2O	de novo biosynthesis of purine nucleotides I
glutamate-1-semialdehyde	(S)-4-amino-5-oxopentanoate*L-Glutamate 1-semialdehyde	C5 H9 N1 O3 	[CH](=O)C(N)CCC(=O)O		5.4.3.8	glutamate-1-semialdehyde  =  5-amino-levulinate	chlorophyllide a biosynthesis
glutamate-1-semialdehyde	(S)-4-amino-5-oxopentanoate*L-Glutamate 1-semialdehyde	C5 H9 N1 O3 	[CH](=O)C(N)CCC(=O)O		5.4.3.8	glutamate-1-semialdehyde  =  5-amino-levulinate	biosynthesis of proto- and siroheme
glutamate-1-semialdehyde	(S)-4-amino-5-oxopentanoate*L-Glutamate 1-semialdehyde	C5 H9 N1 O3 	[CH](=O)C(N)CCC(=O)O		1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	chlorophyllide a biosynthesis
glutamate-1-semialdehyde	(S)-4-amino-5-oxopentanoate*L-Glutamate 1-semialdehyde	C5 H9 N1 O3 	[CH](=O)C(N)CCC(=O)O		1.2.1.70	L-glutamyl-tRNAglt + NADPH  =  glutamate-1-semialdehyde + NADP+ + tRNAglt	biosynthesis of proto- and siroheme
UMP	uridylate*5'-UMP*U*uridine-5'-monophosphate*5'-uridylic acid (8CI)(9CI)*uridine-monophosphate*uridine-5'-phosphate*uridine-phosphate	C9 H13 N2 O9 P1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(O)(O)=O))	LIGAND-CPD:C00105*CAS:58-97-9	2.7.4.-	ATP + UMP  =  ADP + UDP	de novo biosynthesis of pyrimidine ribonucleotides
UMP	uridylate*5'-UMP*U*uridine-5'-monophosphate*5'-uridylic acid (8CI)(9CI)*uridine-monophosphate*uridine-5'-phosphate*uridine-phosphate	C9 H13 N2 O9 P1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(O)(O)=O))	LIGAND-CPD:C00105*CAS:58-97-9	LIPIDXSYNTHESIS-RXN	H2O + UDP-2,3-bis(3-hydroxymyristoyl)glucosamine  =  2,3-bis(3-hydroxymyristoyl)-beta-D-glucosaminyl 1-phosphate + UMP	lipid-A-precursor biosynthesis
UMP	uridylate*5'-UMP*U*uridine-5'-monophosphate*5'-uridylic acid (8CI)(9CI)*uridine-monophosphate*uridine-5'-phosphate*uridine-phosphate	C9 H13 N2 O9 P1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(O)(O)=O))	LIGAND-CPD:C00105*CAS:58-97-9	4.1.1.23	orotidine-5'-phosphate  =  CO2 + UMP	de novo biosynthesis of pyrimidine ribonucleotides
UMP	uridylate*5'-UMP*U*uridine-5'-monophosphate*5'-uridylic acid (8CI)(9CI)*uridine-monophosphate*uridine-5'-phosphate*uridine-phosphate	C9 H13 N2 O9 P1 	c1(n(c(=O)[nH]c(c1)=O)C2(OC(C(O)C2O)COP(O)(O)=O))	LIGAND-CPD:C00105*CAS:58-97-9	2.7.8.15	dolichyl-phosphate + UDP-N-acetyl-D-glucosamine  =  N-acetylglucosaminyl-diphosphodolichol + UMP	dolichyl-diphosphooligosaccharide biosynthesis
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.3.99.-	reduced acceptor + crotonobetainyl-CoA  =  acceptor + gamma-butyrobetainyl-CoA	carnitine degradation
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.14.99.7	O2 + reduced acceptor + squalene  =  (S)-2,3-Epoxysqualene + H2O + acceptor	sterol biosynthesis
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.14.-.-	typhasterol + O2 + reduced acceptor  =  castasterone + H2O + acceptor	brassinosteroid biosynthesis I
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.14.-.-	cathasterone + O2 + reduced acceptor  =  teasterone + H2O + acceptor	brassinosteroid biosynthesis I
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.14.-.-	6-oxocampestanol + O2 + reduced acceptor  =  cathasterone + H2O + acceptor	brassinosteroid biosynthesis I
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.14.-.-	campestanol + O2 + reduced acceptor  =  (6alpha)-hydroxycampestanol + H2O + acceptor	brassinosteroid biosynthesis I
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.14.-.-	campesterol + O2 + reduced acceptor  =  (22alpha)-hydroxy-campesterol + H2O + acceptor	brassinosteroid biosynthesis II
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.5.99.8	L-proline + acceptor  =  L-delta1-pyrroline-5-carboxylate + reduced acceptor	proline degradation
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.5.99.6	H2O + acceptor + spermidine  =  reduced acceptor + 4-amino-butyraldehyde + 1,3-diaminopropane	beta-alanine biosynthesis I
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.1.99.16	acceptor + malate  =  reduced acceptor + oxaloacetate	TCA cycle -- aerobic respiration
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.2.99.2	reduced acceptor + CO2  =  acceptor + H2O + CO	carbon monoxide dehydrogenase pathway
reduced acceptor	reduced electron acceptor*donor*A(H2)	H2 			1.8.99.2	reduced acceptor + APS  =  AMP + acceptor + SO3-2	sulfate assimilation
phenylacetaldoxime		C8 H9 N1 O1 	C(=NO)Cc1(ccccc1)		RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
phenylacetaldoxime		C8 H9 N1 O1 	C(=NO)Cc1(ccccc1)		1.14.13.-	L-phenylalanine + NADPH + O2  =  phenylacetaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from phenylalanine
L-tryptophanyl-tRNAtrp	L-TRYPTOPHANYL-TRNA(TRP)				6.1.1.2	tRNAtrp + L-tryptophan + ATP  =  L-tryptophanyl-tRNAtrp + pyrophosphate + AMP	tRNA charging pathway
GDP-4-dehydro-6-deoxy-D-mannose	GDP-4-keto-6-deoxymannose*GDP-4-keto-6-deoxy-D-mannose*GDP-4-dehydro-6-deoxy-D-talose*GDP-4-oxo-6-deoxy-D-mannose*GDP-4-oxo-6-deoxymannose	C16 H23 N5 O15 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		5.-.-.-	GDP-4-dehydro-6-deoxy-D-mannose  =  GDP-4-dehydro-6-L-deoxygalactose	colanic acid building blocks biosynthesis
GDP-4-dehydro-6-deoxy-D-mannose	GDP-4-keto-6-deoxymannose*GDP-4-keto-6-deoxy-D-mannose*GDP-4-dehydro-6-deoxy-D-talose*GDP-4-oxo-6-deoxy-D-mannose*GDP-4-oxo-6-deoxymannose	C16 H23 N5 O15 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		1.1.1.187	NADPH + GDP-4-dehydro-6-deoxy-D-mannose  =  NADP+ + GDP-D-rhamnose	GDP-D-rhamnose biosynthesis
GDP-4-dehydro-6-deoxy-D-mannose	GDP-4-keto-6-deoxymannose*GDP-4-keto-6-deoxy-D-mannose*GDP-4-dehydro-6-deoxy-D-talose*GDP-4-oxo-6-deoxy-D-mannose*GDP-4-oxo-6-deoxymannose	C16 H23 N5 O15 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		1.1.1.271	NADPH + GDP-4-dehydro-6-deoxy-D-mannose  =  NADP+ + guanosine diphosphate fucose	GDP-L-fucose biosynthesis I (from GDP-D-mannose)
GDP-4-dehydro-6-deoxy-D-mannose	GDP-4-keto-6-deoxymannose*GDP-4-keto-6-deoxy-D-mannose*GDP-4-dehydro-6-deoxy-D-talose*GDP-4-oxo-6-deoxy-D-mannose*GDP-4-oxo-6-deoxymannose	C16 H23 N5 O15 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	GDP-L-fucose biosynthesis I (from GDP-D-mannose)
GDP-4-dehydro-6-deoxy-D-mannose	GDP-4-keto-6-deoxymannose*GDP-4-keto-6-deoxy-D-mannose*GDP-4-dehydro-6-deoxy-D-talose*GDP-4-oxo-6-deoxy-D-mannose*GDP-4-oxo-6-deoxymannose	C16 H23 N5 O15 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	colanic acid building blocks biosynthesis
GDP-4-dehydro-6-deoxy-D-mannose	GDP-4-keto-6-deoxymannose*GDP-4-keto-6-deoxy-D-mannose*GDP-4-dehydro-6-deoxy-D-talose*GDP-4-oxo-6-deoxy-D-mannose*GDP-4-oxo-6-deoxymannose	C16 H23 N5 O15 P2 	CC1(OC(C(O)C(O)C1=O)OP(=O)(O)OP(=O)(O)OCC2(OC(C(O)C2O)n3(c4(c(nc3)c(=O)[nH]c(n4)N))))		4.2.1.47	GDP-mannose  =  H2O + GDP-4-dehydro-6-deoxy-D-mannose	GDP-D-rhamnose biosynthesis
3-methylthiopropyl-glucosinolate	glucoiberverin	C11 H21 N1 O9 S3 	C1(SC(=NOS(O)(=O)=O)CCCSC)(C(CO)C(O)C(O)C(O1)O)		RXN-2221	3-methylthiopropyl-glucosinolate  =  3-methylsulfinylpropyl-glucosinolate	glucosinolate biosynthesis from homomethionine
3-methylthiopropyl-glucosinolate	glucoiberverin	C11 H21 N1 O9 S3 	C1(SC(=NOS(O)(=O)=O)CCCSC)(C(CO)C(O)C(O)C(O1)O)		2.8.2.-	3-methylthiopropyl-desulfoglucosinolate + PAPS  =  3-methylthiopropyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from homomethionine
benzoate	benzoic acid*benzenecarboxylic acid*phenylformic acid	C7 H5 O2 	C([O-1])(=O)c1(ccccc1)	CAS:65-85-0	1.14.13.-	benzoate + NADPH + O2  =  salicylate + NADP+ + H2O	salicylic acid biosynthesis
benzoate	benzoic acid*benzenecarboxylic acid*phenylformic acid	C7 H5 O2 	C([O-1])(=O)c1(ccccc1)	CAS:65-85-0	RXN-6722	benzoate + S-adenosyl-L-methionine  =  methylbenzoate + S-adenosyl-homocysteine	volatile benzenoid ester biosynthesis
benzoate	benzoic acid*benzenecarboxylic acid*phenylformic acid	C7 H5 O2 	C([O-1])(=O)c1(ccccc1)	CAS:65-85-0	RXN-2005	benzoyl-CoA + H2O  =  benzoate + coenzyme A	salicylic acid biosynthesis
beta-tocopherol		C28 H48 O2 	CC(C)CCCC(C)CCCC(C)CCCC1(C)(OC2(C(CC1)=C(C)C(O)=CC=2C))		2.1.1.95	delta-tocopherol + S-adenosyl-L-methionine  =  beta-tocopherol + S-adenosyl-homocysteine	vitamin E biosynthesis
L-valyl-tRNAval	L-VALYL-TRNA(VAL)				6.1.1.9	tRNAval + L-valine + ATP  =  L-valyl-tRNAval + pyrophosphate + AMP	tRNA charging pathway
methylbenzoate		C8 H8 O2 	C(OC)(=O)c1(ccccc1)		RXN-6722	benzoate + S-adenosyl-L-methionine  =  methylbenzoate + S-adenosyl-homocysteine	volatile benzenoid ester biosynthesis
glycerol-3-phosphate	&alpha;-glycerophosphoric acid*glycerol-3-P*<i>sn</i>-glycerol-3-phosphate*&alpha;-glycerophosphate*D-glycerol-3-phosphate*rac-Glycerol 3-phosphate	C3 H9 O6 P1 	C(O)C(O)COP(O)(O)=O	CAS:57-03-4	2.7.8.5	CDP-diacylglycerol + glycerol-3-phosphate  =  L-1-phosphatidylglycerol-phosphate + CMP	phospholipid biosynthesis
glycerol-3-phosphate	&alpha;-glycerophosphoric acid*glycerol-3-P*<i>sn</i>-glycerol-3-phosphate*&alpha;-glycerophosphate*D-glycerol-3-phosphate*rac-Glycerol 3-phosphate	C3 H9 O6 P1 	C(O)C(O)COP(O)(O)=O	CAS:57-03-4	2.3.1.15	fatty-acyl-CoA + glycerol-3-phosphate  =  1-acyl-sn-glycerol-3P + coenzyme A	triacylglycerol biosynthesis
glycerol-3-phosphate	&alpha;-glycerophosphoric acid*glycerol-3-P*<i>sn</i>-glycerol-3-phosphate*&alpha;-glycerophosphate*D-glycerol-3-phosphate*rac-Glycerol 3-phosphate	C3 H9 O6 P1 	C(O)C(O)COP(O)(O)=O	CAS:57-03-4	1.1.99.5	glycerol-3-phosphate + FAD  =  dihydroxy-acetone-phosphate + FADH2	glycerol degradation
glycerol-3-phosphate	&alpha;-glycerophosphoric acid*glycerol-3-P*<i>sn</i>-glycerol-3-phosphate*&alpha;-glycerophosphate*D-glycerol-3-phosphate*rac-Glycerol 3-phosphate	C3 H9 O6 P1 	C(O)C(O)COP(O)(O)=O	CAS:57-03-4	RXN-1407	indole-3-glycerol-phosphate  =  indole + glycerol-3-phosphate	IAA biosynthesis I
glycerol-3-phosphate	&alpha;-glycerophosphoric acid*glycerol-3-P*<i>sn</i>-glycerol-3-phosphate*&alpha;-glycerophosphate*D-glycerol-3-phosphate*rac-Glycerol 3-phosphate	C3 H9 O6 P1 	C(O)C(O)COP(O)(O)=O	CAS:57-03-4	2.7.1.30	glycerol + ATP  =  glycerol-3-phosphate + ADP	glycerol degradation
ethanolamine	2-aminoethanol*monoethanolamine*colamine*ethanol-amine	C2 H7 N1 O1 	C(O)CN	LIGAND-CPD:C00189*LIGAND:C00189*CAS:141-43-5	2.7.1.82	ethanolamine + ATP  =  phosphoryl-ethanolamine + ADP	choline biosynthesis I
ethanolamine	2-aminoethanol*monoethanolamine*colamine*ethanol-amine	C2 H7 N1 O1 	C(O)CN	LIGAND-CPD:C00189*LIGAND:C00189*CAS:141-43-5	RXN-5761	ethanolamine + S-adenosyl-L-methionine  =  N-monomethylethanolamine + S-adenosyl-homocysteine	choline biosynthesis II
ethanolamine	2-aminoethanol*monoethanolamine*colamine*ethanol-amine	C2 H7 N1 O1 	C(O)CN	LIGAND-CPD:C00189*LIGAND:C00189*CAS:141-43-5	RXN-5641	L-serine  =  ethanolamine + CO2	choline biosynthesis I
ethanolamine	2-aminoethanol*monoethanolamine*colamine*ethanol-amine	C2 H7 N1 O1 	C(O)CN	LIGAND-CPD:C00189*LIGAND:C00189*CAS:141-43-5	RXN-1382	L-1-phosphatidyl-ethanolamine + L-serine  =  L-1-phosphatidylserine + ethanolamine	phospholipid biosynthesis
methylsalicylate		C8 H8 O3 	C(OC)(=O)c1(c(O)cccc1)		RXN-6723	salicylate + S-adenosyl-L-methionine  =  methylsalicylate + S-adenosyl-homocysteine	volatile benzenoid ester biosynthesis
benzylbenzoate		C14 H12 O2 	C(c1(ccccc1))(=O)OCc2(ccccc2)		RXN-6724	benzyl alcohol + benzoyl-CoA  =  benzylbenzoate + coenzyme A	volatile benzenoid ester biosynthesis
2-C-methyl-D-erythritol-4-phosphate	MEP	C5 H13 O7 P1 	C(OP(O)(=O)O)C(O)C(O)(C)CO		1.1.1.267	1-deoxy-D-xylulose 5-phosphate + NADPH  =  2-C-methyl-D-erythritol-4-phosphate + NADP+	isopentenyl diphosphate biosynthesis -- mevalonate-independent
2-C-methyl-D-erythritol-4-phosphate	MEP	C5 H13 O7 P1 	C(OP(O)(=O)O)C(O)C(O)(C)CO		RXN0-277	2-C-methyl-D-erythritol-4-phosphate + CTP  =  4-diphosphocytidyl-2-C-methylerythritol + pyrophosphate	isopentenyl diphosphate biosynthesis -- mevalonate-independent
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	formylTHF biosynthesis I
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	photorespiration
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.2.1	5,10-methylene-THF + glycine + H2O  =  L-serine + tetrahydrofolate	glycine biosynthesis
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.2.11	H2O + 2-keto-isovalerate + 5,10-methylene-THF  =  2-dehydropantoate + tetrahydrofolate	pantothenate biosynthesis
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	formylTHF biosynthesis
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	formylTHF biosynthesis I
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.1.45	5,10-methylene-THF + dUMP  =  dTMP + 7,8-dihydrofolate	de novo biosynthesis of pyrimidine deoxyribonucleotides
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		METLENETHFRED-FERRE-RXN	5,10-methylene-THF + reduced ferredoxin  =  5-methyl-THF + oxidized ferredoxin	carbon monoxide dehydrogenase pathway
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	formylTHF biosynthesis
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	formylTHF biosynthesis I
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		1.5.1.5	5,10-methylene-THF + NADP+  =  NADPH + 5,10-methenyl-THF	carbon monoxide dehydrogenase pathway
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		1.5.1.15	5,10-methylene-THF + NAD+  =  5,10-methenyl-THF + NADH	glycine degradation
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis I
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	formylTHF biosynthesis I
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		GCVMULTI-RXN	glycine + tetrahydrofolate + NAD+  =  NH3 + 5,10-methylene-THF + CO2 + NADH	photorespiration
5,10-methylene-THF	5,10-methylenetetrahydrofolate*N<SUP>5</SUP>,N<SUP>10</SUP>-methylenetetrahydrofolate	C20 H23 N7 O6 	C(=O)(NC(C(O)=O)CCC(=O)O)c1(ccc(cc1)N2(CN4([CH](C2)[CH2]Nc3(nc(N)[nH]c(c34)=O))))		2.1.2.10	S-aminomethyldihydrolipoyl-GcvH-protein + tetrahydrofolate  =  NH3 + dihydrolipoyl-GcvH-protein + 5,10-methylene-THF	glycine degradation
methylmalonate-semialdehyde	2-methyl-3-oxopropanoate*CH3-malonate-S-ald*ch3-malonate-semialdehyde	C4 H6 O3 	C(=O)(O)C(C)C=O	CAS:6236-08-4	1.2.1.27	NAD+ + coenzyme A + methylmalonate-semialdehyde  =  NADH + CO2 + propionyl-CoA	valine degradation
methylmalonate-semialdehyde	2-methyl-3-oxopropanoate*CH3-malonate-S-ald*ch3-malonate-semialdehyde	C4 H6 O3 	C(=O)(O)C(C)C=O	CAS:6236-08-4	1.1.1.31	NAD+ + 3-hydroxy-isobutyrate  =  NADH + methylmalonate-semialdehyde	valine degradation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	aerobic respiration
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	superpathway of glyoxylate cycle
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.3.5.1	a ubiquinone + succinate  =  a ubiquinol + fumarate	TCA cycle -- aerobic respiration
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle variation I
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	6.2.1.5	succinyl-CoA + ADP + phosphate  =  succinate + coenzyme A + ATP	TCA cycle -- aerobic respiration
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.3.99.1	succinate + FAD  =  fumarate + FADH2	TCA cycle variation I
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.22	naringenin + alpha-ketoglutarate + O2  =  apigenin + succinate + CO2 + H2O	luteolin biosynthesis
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.22	eriodictyol + alpha-ketoglutarate + O2  =  luteolin + succinate + CO2 + H2O	luteolin biosynthesis
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA20 + alpha-ketoglutarate + O2  =  GA29 + succinate + CO2	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA8 + alpha-ketoglutarate + O2  =  GA8-catabolite + succinate + CO2 + H2O	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.13	GA1 + alpha-ketoglutarate + O2  =  GA8 + succinate + CO2	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA29 + alpha-ketoglutarate + O2  =  GA29-catabolite + succinate + CO2 + H2O	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA51 + succinate + CO2	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA51 + alpha-ketoglutarate + O2  =  GA51-catabolite + succinate + CO2 + H2O	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA34 + alpha-ketoglutarate + O2  =  GA34-catabolite + succinate + CO2 + H2O	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA110 + succinate + CO2	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA97 + succinate + CO2	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA98 + succinate + CO2	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA17 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA20 + succinate + 2 CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA44 + CO2 + succinate	gibberellin biosynthesis III (early C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA14 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA37 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2 + H2O	gibberellin biosynthesis II (early C-3 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA14 + O2 + alpha-ketoglutarate  =  GA37 + CO2 + succinate	gibberellin biosynthesis II (early C-3 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA36 + O2 + alpha-ketoglutarate  =  GA4 + succinate + 2 CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA25 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA9 + succinate + 2 CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA15 + O2 + alpha-ketoglutarate  =  GA24 + H2O + CO2 + succinate	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA15 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.19	leucocyanidin + alpha-ketoglutarate + O2  =  cyanidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	RXN-527	dihydroquercetin + alpha-ketoglutarate + O2  =  quercetin + succinate + CO2 + H2O	flavonol biosynthesis
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	RXN1F-93	dihydrokaempferol + alpha-ketoglutarate + O2  =  kaempferol + succinate + CO2 + H2O	flavonol biosynthesis
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA4 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.12	GA44 + alpha-ketoglutarate + O2  =  GA19 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.15	GA20 + alpha-ketoglutarate + O2  =  GA1 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA38 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA15 + alpha-ketoglutarate + O2  =  GA37 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA25 + alpha-ketoglutarate + O2  =  GA13 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.-	GA4 + alpha-ketoglutarate + O2  =  GA34 + succinate + CO2	gibberellin inactivation
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.19	leucopelargonidin + alpha-ketoglutarate + O2  =  pelargonidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.14.11.9	naringenin + O2 + alpha-ketoglutarate  =  CO2 + succinate + dihydrokaempferol	flavonoid biosynthesis
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	glutamate degradation II
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.2.1.24	H2O + NAD+ + succinate semialdehyde  =  NADH + succinate	arginine degradation I
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	1.2.1.16	succinate semialdehyde + NADP+ + H2O  =  NADPH + succinate	arginine degradation I
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	4.1.3.1	isocitrate  =  glyoxylate + succinate	glyoxylate cycle
succinate	succinic acid*suc*succ*butanedioic acid*ethylenesuccinic acid	C4 H6 O4 	C(=O)(O)CCC(O)=O	LIGAND-CPD:C00042*CAS:110-15-6*CAS:110-15-6	3.5.1.18	H2O + N-succinyl-L,L-2,6-diaminopimelate  =  L,L-diaminopimelate + succinate	lysine biosynthesis
D-sedoheptulose-7-phosphate	D-Sedoheptulose-7-P*sedoheptulose-7-phosphate*heptulose-7-phosphate*sedoheptulose-7-P	C7 H15 O10 P1 	C(OP(O)(O)=O)C(O)C(O)C(O)C(O)C(=O)CO	CAS:2646-35-7	2.2.1.2	D-glyceraldehyde-3-phosphate + D-sedoheptulose-7-phosphate  =  D-fructose-6-phosphate + D-erythrose-4-phosphate	non-oxidative branch of the pentose phosphate pathway
D-sedoheptulose-7-phosphate	D-Sedoheptulose-7-P*sedoheptulose-7-phosphate*heptulose-7-phosphate*sedoheptulose-7-P	C7 H15 O10 P1 	C(OP(O)(O)=O)C(O)C(O)C(O)C(O)C(=O)CO	CAS:2646-35-7	3.1.3.37	H2O + D-sedoheptulose-1,7-bisphosphate  =  phosphate + D-sedoheptulose-7-phosphate	Calvin cycle
D-sedoheptulose-7-phosphate	D-Sedoheptulose-7-P*sedoheptulose-7-phosphate*heptulose-7-phosphate*sedoheptulose-7-P	C7 H15 O10 P1 	C(OP(O)(O)=O)C(O)C(O)C(O)C(O)C(=O)CO	CAS:2646-35-7	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	Calvin cycle
D-sedoheptulose-7-phosphate	D-Sedoheptulose-7-P*sedoheptulose-7-phosphate*heptulose-7-phosphate*sedoheptulose-7-P	C7 H15 O10 P1 	C(OP(O)(O)=O)C(O)C(O)C(O)C(O)C(=O)CO	CAS:2646-35-7	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	(deoxy)ribose phosphate degradation
D-sedoheptulose-7-phosphate	D-Sedoheptulose-7-P*sedoheptulose-7-phosphate*heptulose-7-phosphate*sedoheptulose-7-P	C7 H15 O10 P1 	C(OP(O)(O)=O)C(O)C(O)C(O)C(O)C(=O)CO	CAS:2646-35-7	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	ribose degradation
D-sedoheptulose-7-phosphate	D-Sedoheptulose-7-P*sedoheptulose-7-phosphate*heptulose-7-phosphate*sedoheptulose-7-P	C7 H15 O10 P1 	C(OP(O)(O)=O)C(O)C(O)C(O)C(O)C(=O)CO	CAS:2646-35-7	2.2.1.1	D-ribose-5-phosphate + D-xylulose-5-phosphate  =  D-sedoheptulose-7-phosphate + D-glyceraldehyde-3-phosphate	non-oxidative branch of the pentose phosphate pathway
2-keto-isovalerate	2-oxo-3-methylbutanoate*3-methyl-2-oxobutanoate*&alpha;-keto-isovaleric acid*&alpha;-ketoisopentanoic acid*&alpha;-keto-isovalerate*&alpha;-oxoisovalerate*&alpha;-ketovaline*2-oxoisovalerate*2-ketovaline*&alpha;-keto-valine*2-oxoisopentanoate*2-keto-3-methylbutyric acid	C5 H8 O3 	CC(C)C(=O)C(=O)O	CAS:759-05-7	2.1.2.11	H2O + 2-keto-isovalerate + 5,10-methylene-THF  =  2-dehydropantoate + tetrahydrofolate	pantothenate biosynthesis
2-keto-isovalerate	2-oxo-3-methylbutanoate*3-methyl-2-oxobutanoate*&alpha;-keto-isovaleric acid*&alpha;-ketoisopentanoic acid*&alpha;-keto-isovalerate*&alpha;-oxoisovalerate*&alpha;-ketovaline*2-oxoisovalerate*2-ketovaline*&alpha;-keto-valine*2-oxoisopentanoate*2-keto-3-methylbutyric acid	C5 H8 O3 	CC(C)C(=O)C(=O)O	CAS:759-05-7	1.2.1.25	NAD+ + coenzyme A + 2-keto-isovalerate  =  NADH + CO2 + isobutyryl-CoA	valine degradation
2-keto-isovalerate	2-oxo-3-methylbutanoate*3-methyl-2-oxobutanoate*&alpha;-keto-isovaleric acid*&alpha;-ketoisopentanoic acid*&alpha;-keto-isovalerate*&alpha;-oxoisovalerate*&alpha;-ketovaline*2-oxoisovalerate*2-ketovaline*&alpha;-keto-valine*2-oxoisopentanoate*2-keto-3-methylbutyric acid	C5 H8 O3 	CC(C)C(=O)C(=O)O	CAS:759-05-7	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	pantothenate biosynthesis
2-keto-isovalerate	2-oxo-3-methylbutanoate*3-methyl-2-oxobutanoate*&alpha;-keto-isovaleric acid*&alpha;-ketoisopentanoic acid*&alpha;-keto-isovalerate*&alpha;-oxoisovalerate*&alpha;-ketovaline*2-oxoisovalerate*2-ketovaline*&alpha;-keto-valine*2-oxoisopentanoate*2-keto-3-methylbutyric acid	C5 H8 O3 	CC(C)C(=O)C(=O)O	CAS:759-05-7	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	valine biosynthesis
2-keto-isovalerate	2-oxo-3-methylbutanoate*3-methyl-2-oxobutanoate*&alpha;-keto-isovaleric acid*&alpha;-ketoisopentanoic acid*&alpha;-keto-isovalerate*&alpha;-oxoisovalerate*&alpha;-ketovaline*2-oxoisovalerate*2-ketovaline*&alpha;-keto-valine*2-oxoisopentanoate*2-keto-3-methylbutyric acid	C5 H8 O3 	CC(C)C(=O)C(=O)O	CAS:759-05-7	2.6.1.42	2-keto-isovalerate + L-glutamate  =  L-valine + alpha-ketoglutarate	valine degradation
2-keto-isovalerate	2-oxo-3-methylbutanoate*3-methyl-2-oxobutanoate*&alpha;-keto-isovaleric acid*&alpha;-ketoisopentanoic acid*&alpha;-keto-isovalerate*&alpha;-oxoisovalerate*&alpha;-ketovaline*2-oxoisovalerate*2-ketovaline*&alpha;-keto-valine*2-oxoisopentanoate*2-keto-3-methylbutyric acid	C5 H8 O3 	CC(C)C(=O)C(=O)O	CAS:759-05-7	4.2.1.9	2,3-dihydroxy-isovalerate  =  2-keto-isovalerate + H2O	valine biosynthesis
2-keto-isovalerate	2-oxo-3-methylbutanoate*3-methyl-2-oxobutanoate*&alpha;-keto-isovaleric acid*&alpha;-ketoisopentanoic acid*&alpha;-keto-isovalerate*&alpha;-oxoisovalerate*&alpha;-ketovaline*2-oxoisovalerate*2-ketovaline*&alpha;-keto-valine*2-oxoisopentanoate*2-keto-3-methylbutyric acid	C5 H8 O3 	CC(C)C(=O)C(=O)O	CAS:759-05-7	4.1.3.12	2-keto-isovalerate + acetyl-CoA + H2O  =  3-carboxy-3-hydroxy-isocaproate + coenzyme A	leucine biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.4.2.7	PRPP + adenine  =  AMP + pyrophosphate	salvage pathways of purine nucleosides
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	3.5.4.6	AMP + H2O  =  IMP + NH3	purine degradation
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	3.5.4.6	AMP + H2O  =  IMP + NH3	salvage pathways of purine nucleosides
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.7.4.3	AMP + ATP  =  ADP + ADP	de novo biosynthesis of purine nucleotides I
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	1.8.99.2	reduced acceptor + APS  =  AMP + acceptor + SO3-2	sulfate assimilation
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.5.1.27	dimethylallyl-pyrophosphate + AMP  =  isopentenyladenosine-5'-monophosphate + pyrophosphate	trans-zeatin biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	3.1.3.5	AMP + H2O  =  adenosine + phosphate	salvage pathways of purine nucleosides
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  4-(2'-carboxyphenyl)-4-oxobutyryl-CoA + AMP + pyrophosphate	phylloquinone biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.2.1.17	coenzyme A + propionate + ATP  =  propionyl-CoA + pyrophosphate + AMP	beta-alanine biosynthesis II
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.5.4	H2O + L-glutamine + L-aspartate + ATP  =  L-glutamate + L-asparagine + pyrophosphate + AMP	asparagine biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	GDPPYPHOSKIN-RXN	ATP + GDP  =  AMP + guanosine 5'-diphosphate,3'-diphosphate	ppGpp biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.2.1.3	coenzyme A + a fatty acid + ATP  =  acyl-CoA + pyrophosphate + AMP	fatty acid beta-oxidation
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.2.1.12	ferulate + coenzyme A + ATP  =  feruloyl-CoA + AMP + pyrophosphate	suberin biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.2.1.12	caffeate + coenzyme A + ATP  =  caffeoyl-CoA + AMP + pyrophosphate	suberin biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.2.1.26	ATP + O-succinylbenzoate + coenzyme A  =  AMP + pyrophosphate + O-succinylbenzoyl-CoA	menaquinone biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.7.6.3	6-hydroxymethyl-dehydropterin + ATP  =  2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate + AMP	tetrahydrofolate biosynthesis I
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.7.6.3	6-hydroxymethyl-dehydropterin + ATP  =  2-amino-4-hydroxy-6-hydroxymethyl-7,8-dihydropteridine diphosphate + AMP	tetrahydrofolate biosynthesis II
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	3.6.1.22	H2O + NAD+  =  nicotinamide mononucleotide + AMP	pyridine nucleotide cycling
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	salvage pathways of purine nucleosides
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.4.1	NH3 + xanthosine-5-phosphate + ATP  =  AMP + pyrophosphate + GMP	de novo biosynthesis of purine nucleotides I
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	NAD biosynthesis I (from aspartate)
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.1.5	NH3 + ATP + deamido-NAD  =  AMP + pyrophosphate + NAD+	pyridine nucleotide cycling
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	4.3.2.2	adenylo-succinate  =  fumarate + AMP	de novo biosynthesis of purine nucleotides II
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	4.3.2.2	adenylo-succinate  =  fumarate + AMP	de novo biosynthesis of purine nucleotides I
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	chlorophyllide a biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	biosynthesis of proto- and siroheme
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.17	tRNAglt + L-glutamate + ATP  =  L-glutamyl-tRNAglt + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.2.1	beta-alanine + L-pantoate + ATP  =  pantothenate + pyrophosphate + AMP	pantothenate biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis II (acetyl cycle)
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.4.5	L-aspartate + citrulline + ATP  =  L-arginino-succinate + pyrophosphate + AMP	arginine biosynthesis III
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.12	tRNAasp + L-aspartate + ATP  =  L-aspartyl-tRNAasp + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.21	tRNAhis + L-histidine + ATP  =  L-histidyl-tRNAhis + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.6	tRNAlys + L-lysine + ATP  =  L-lysyl-tRNAlys + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.7.6.5	GTP + ATP  =  guanosine 3'-diphosphate 5'-triphosphate + AMP	ppGpp biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.7.1.20	adenosine + ATP  =  AMP + ADP	salvage pathways of purine nucleosides
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.16	tRNAcys + L-cysteine + ATP  =  L-cysteinyl-tRNAcys + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis II (from tryptophan)
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	NAD biosynthesis I (from aspartate)
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.5.1	ATP + deamido-NAD + L-glutamine + H2O  =  AMP + pyrophosphate + NAD+ + L-glutamate	pyridine nucleotide cycling
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.2	tRNAtrp + L-tryptophan + ATP  =  L-tryptophanyl-tRNAtrp + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.1	L-tyrosine + tRNAtyr + ATP  =  L-tyrosyl-tRNAtyr + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.7.6.1	ATP + D-ribose-5-phosphate  =  PRPP + AMP	PRPP biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	gluconeogenesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	2.7.9.2	H2O + pyruvate + ATP  =  phosphate + phosphoenolpyruvate + AMP	glyceraldehyde 3-phosphate degradation
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.3	tRNAthr + L-threonine + ATP  =  L-threonyl-tRNAthr + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.20	tRNAphe + L-phenylalanine + ATP  =  L-phenylalanyl-tRNAphe + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.11	tRNAser + L-serine + ATP  =  L-seryl-tRNAser + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.18	tRNAgln + L-glutamine + ATP  =  L-glutaminyl-tRNAgln + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.5	tRNAile + L-isoleucine + ATP  =  L-isoleucyl-tRNAile + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.4	L-leucine + tRNAleu + ATP  =  L-leucyl-tRNAleu + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.10	tRNAmet + L-methionine + ATP  =  L-methionyl-tRNAmet + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.9	tRNAval + L-valine + ATP  =  L-valyl-tRNAval + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.14	tRNAgly + glycine + ATP  =  glycyl-tRNAgly + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.15	L-proline + tRNApro + ATP  =  L-prolyl-tRNApro + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.7	tRNAala + L-alanine + ATP  =  L-alanyl-tRNAala + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.19	tRNAarg + L-arginine + ATP  =  L-arginyl-tRNAarg + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.1.1.22	tRNAasn + L-asparagine + ATP  =  L-asparaginyl-tRNAasn + pyrophosphate + AMP	tRNA charging pathway
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	flavonoid biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.2.1.12	coenzyme A + 4-coumarate + ATP  =  coumaroyl-CoA + pyrophosphate + AMP	lignin biosynthesis
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides II
AMP	adenosine-5'-phosphate*adenosine-phosphate*5'-AMP*adenosine-monophosphate*adenylic acid*A*AMP*adenosine 5'-monophosphate*adenylate*5'-adenylic acid*5'-adenosine monophosphate*adenosine 5'-phosphate	C10 H14 N5 O7 P1 	C(OP(O)(=O)O)C1(OC(C(O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	LIGAND-CPD:C00020*CAS:61-19-8*NCI:20264	6.3.5.2	xanthosine-5-phosphate + H2O + L-glutamine + ATP  =  L-glutamate + GMP + pyrophosphate + AMP	de novo biosynthesis of purine nucleotides I
Mg-protoporphyrin monomethyl ester	MgPMME*magnesium-protoporphyrin IX 13-monomethyl ester*Mg-protoporphyrin monomethyl ester*magnesium protoporphyrin monomethyl ester	C35 H36 N4 O4 MG1 	Cc7(c(CCC(=O)OC)c3(n6([Mg]25(n4(c(=Cc1(c(C)c(c(n12)=C3)CCC(=O)O))c(C)c(C=C)c4=Cc8(n5c(=Cc67)c(c8C)C=C))))))		1.14.13.81	Mg-protoporphyrin monomethyl ester + NADPH + H+ + O2  =  131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + H2O	chlorophyllide a biosynthesis
Mg-protoporphyrin monomethyl ester	MgPMME*magnesium-protoporphyrin IX 13-monomethyl ester*Mg-protoporphyrin monomethyl ester*magnesium protoporphyrin monomethyl ester	C35 H36 N4 O4 MG1 	Cc7(c(CCC(=O)OC)c3(n6([Mg]25(n4(c(=Cc1(c(C)c(c(n12)=C3)CCC(=O)O))c(C)c(C=C)c4=Cc8(n5c(=Cc67)c(c8C)C=C))))))		2.1.1.11	Mg-protoporphyrin + S-adenosyl-L-methionine  =  S-adenosyl-homocysteine + Mg-protoporphyrin monomethyl ester	chlorophyllide a biosynthesis
adenine	2-aminopurine	C5 H5 N5 	c1(ncnc2(c1N=CN2))(N)	LIGAND-CPD:C00147*CAS:73-24-5	3.2.2.7	H2O + adenosine  =  D-ribose + adenine	salvage pathways of purine nucleosides
adenine	2-aminopurine	C5 H5 N5 	c1(ncnc2(c1N=CN2))(N)	LIGAND-CPD:C00147*CAS:73-24-5	3.2.2.16	H2O + 5'-methylthioadenosine  =  5-methylthioribose + adenine	methionine salvage pathway
adenine	2-aminopurine	C5 H5 N5 	c1(ncnc2(c1N=CN2))(N)	LIGAND-CPD:C00147*CAS:73-24-5	1.5.99.12	isopentenyladenine + FAD + H2O  =  3-methyl-2-butenal + adenine + FADH2	cytokinins degradation
adenine	2-aminopurine	C5 H5 N5 	c1(ncnc2(c1N=CN2))(N)	LIGAND-CPD:C00147*CAS:73-24-5	1.5.99.12	trans-zeatin + H2O + FAD  =  adenine + 3-methyl-4-trans-hydroxy-2-butenal + FADH2	cytokinins degradation
adenine	2-aminopurine	C5 H5 N5 	c1(ncnc2(c1N=CN2))(N)	LIGAND-CPD:C00147*CAS:73-24-5	1.5.99.12	cis-zeatin + H2O + FAD  =  3-methyl-4-cis-hydroxy-2-butenal + adenine + FADH2	cytokinins degradation
adenine	2-aminopurine	C5 H5 N5 	c1(ncnc2(c1N=CN2))(N)	LIGAND-CPD:C00147*CAS:73-24-5	2.4.2.7	PRPP + adenine  =  AMP + pyrophosphate	salvage pathways of purine nucleosides
HCO3-	HCO<SUB>3</SUB>*bicarbonate*CO<SUB>3</SUB><SUP>2-</SUP>*CO<SUB>3</SUB><SUP>-2</SUP>*carbonate	C1 H1 O3 	C(=O)(O)[O-1]	CAS:144-55-8	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
HCO3-	HCO<SUB>3</SUB>*bicarbonate*CO<SUB>3</SUB><SUP>2-</SUP>*CO<SUB>3</SUB><SUP>-2</SUP>*carbonate	C1 H1 O3 	C(=O)(O)[O-1]	CAS:144-55-8	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
HCO3-	HCO<SUB>3</SUB>*bicarbonate*CO<SUB>3</SUB><SUP>2-</SUP>*CO<SUB>3</SUB><SUP>-2</SUP>*carbonate	C1 H1 O3 	C(=O)(O)[O-1]	CAS:144-55-8	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
HCO3-	HCO<SUB>3</SUB>*bicarbonate*CO<SUB>3</SUB><SUP>2-</SUP>*CO<SUB>3</SUB><SUP>-2</SUP>*carbonate	C1 H1 O3 	C(=O)(O)[O-1]	CAS:144-55-8	6.4.1.2	HCO3- + H+ + acetyl-CoA + ATP  =  malonyl-CoA + phosphate + ADP	fatty acid biosynthesis - initial steps
HCO3-	HCO<SUB>3</SUB>*bicarbonate*CO<SUB>3</SUB><SUP>2-</SUP>*CO<SUB>3</SUB><SUP>-2</SUP>*carbonate	C1 H1 O3 	C(=O)(O)[O-1]	CAS:144-55-8	4.3.99.1	HCO3- + cyanate  =  carbamate + CO2	cyanate degradation
HCO3-	HCO<SUB>3</SUB>*bicarbonate*CO<SUB>3</SUB><SUP>2-</SUP>*CO<SUB>3</SUB><SUP>-2</SUP>*carbonate	C1 H1 O3 	C(=O)(O)[O-1]	CAS:144-55-8	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	isoleucine degradation
HCO3-	HCO<SUB>3</SUB>*bicarbonate*CO<SUB>3</SUB><SUP>2-</SUP>*CO<SUB>3</SUB><SUP>-2</SUP>*carbonate	C1 H1 O3 	C(=O)(O)[O-1]	CAS:144-55-8	6.4.1.3	ATP + HCO3- + propionyl-CoA  =  ADP + phosphate + D-methylmalonyl-CoA	valine degradation
HCO3-	HCO<SUB>3</SUB>*bicarbonate*CO<SUB>3</SUB><SUP>2-</SUP>*CO<SUB>3</SUB><SUP>-2</SUP>*carbonate	C1 H1 O3 	C(=O)(O)[O-1]	CAS:144-55-8	6.4.1.4	HCO3- + 3-methylcrotonyl-CoA + ATP  =  phosphate + trans-3-methylglutaconyl-CoA + ADP	leucine degradation
cyanidin-3-glucoside	cyanidin-3-O-glucoside	C21 H21 O11 	C(O)C1(OC(C(O)C(O)C1O)Oc3(c(c2(cc(O)c(O)cc2))[o+1]c4(c(c3)c(O)cc(c4)O)))		RXN1F-775	cyanidin + UDP-D-glucose  =  cyanidin-3-glucoside + UDP	anthocyanin biosynthesis
tiglyl-CoA	2-methylbut-2-enoyl-CoA*trans-2-methylbut-2-enoyl-CoA*tigloyl-CoA*tiglyl-CoA*methylcrotonyl-CoA	C26 H42 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)=CC)	CAS:6247-62-7	4.2.1.17	tiglyl-CoA + H2O  =  2-methyl-3-hydroxybutyryl-CoA	isoleucine degradation
tiglyl-CoA	2-methylbut-2-enoyl-CoA*trans-2-methylbut-2-enoyl-CoA*tigloyl-CoA*tiglyl-CoA*methylcrotonyl-CoA	C26 H42 N7 O17 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(=O)(O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)C(C)=CC)	CAS:6247-62-7	1.3.99.12	2-methylbutyryl-CoA + FAD  =  tiglyl-CoA + FADH2	isoleucine degradation
cytidine		C9 H13 N3 O5 	[CH]1(O[CH](CO)[CH](O)[CH](O)1)n2(c(=O)nc(N)cc2)	CAS:65-46-3	3.5.4.5	H2O + cytidine  =  NH3 + uridine	(deoxy)ribose phosphate degradation
fructuronate	D-fructuronate	C6 H10 O7 	C(O)C1(O)(C(O)C(O)C(O1)C(O)=O)		1.1.1.57	NADH + fructuronate  =  NAD+ + D-mannonate	beta-D-glucuronide degradation
fructuronate	D-fructuronate	C6 H10 O7 	C(O)C1(O)(C(O)C(O)C(O1)C(O)=O)		5.3.1.12	glucuronate  =  fructuronate	beta-D-glucuronide degradation
choline		C5 H14 N1 O1 	C(O)C[N+1](C)(C)C	LIGAND-CPD:C00114*CAS:62-49-7	2.3.1.91	1-O-sinapoyl-beta-D-glucose + choline  =  O-sinapoylcholine + beta-D-glucose	sinapate ester biosynthesis
choline		C5 H14 N1 O1 	C(O)C[N+1](C)(C)C	LIGAND-CPD:C00114*CAS:62-49-7	RXN-5763	N-dimethylethanolamine + S-adenosyl-L-methionine  =  choline + S-adenosyl-homocysteine	choline biosynthesis II
choline		C5 H14 N1 O1 	C(O)C[N+1](C)(C)C	LIGAND-CPD:C00114*CAS:62-49-7	RXN-5647	phosphoryl-choline + H2O  =  choline + phosphate	choline biosynthesis I
choline		C5 H14 N1 O1 	C(O)C[N+1](C)(C)C	LIGAND-CPD:C00114*CAS:62-49-7	3.1.1.49	H2O + O-sinapoylcholine  =  choline + sinapate	sinapate ester biosynthesis
choline		C5 H14 N1 O1 	C(O)C[N+1](C)(C)C	LIGAND-CPD:C00114*CAS:62-49-7	3.1.4.4	a phosphatidylcholine + H2O  =  L-phosphatidate + choline	choline biosynthesis III
choline		C5 H14 N1 O1 	C(O)C[N+1](C)(C)C	LIGAND-CPD:C00114*CAS:62-49-7	3.1.4.4	a phosphatidylcholine + H2O  =  L-phosphatidate + choline	lipases pathway
beta-D-galactose	galactose*galactopyranoside*galactopyranose*D-galactose*cerebrose*6-(hydroxymethyl)tetrahydropyran-2,3,4,5-tetraol	C6 H12 O6 	C(O)C1(C(O)C(O)C(O)C(O)O1)	LIGAND:C00124*CAS:59-23-4	5.1.3.3	beta-D-galactose  =  alpha-D-galactose	galactose degradation II
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	6.4.1.2	HCO3- + H+ + acetyl-CoA + ATP  =  malonyl-CoA + phosphate + ADP	fatty acid biosynthesis - initial steps
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.17.4.3	2-C-methyl-D-erythritol-2,4-cyclodiphosphate + e- + H+  =  1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.15.1.1	2 O2- + 2 H+  =  H2O2 + O2	removal of superoxide radicals
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.14.13.70	3 NADPH + 3 O2 + obtusifoliol + 3 H+  =  4 H2O + 3 NADP+ + formate + (4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol	sterol biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.14.13.79	ent-7-alpha-hydroxykaurenoate + NADPH + H+ + O2  =  GA12-aldehyde + NADP+ + 2 H2O	GA12 biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	arginine biosynthesis II (acetyl cycle)
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	6.3.5.5	H2O + HCO3- + L-glutamine + 2 ATP + H+  =  carbamoyl-phosphate + L-glutamate + phosphate + 2 ADP	de novo biosynthesis of pyrimidine ribonucleotides
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	RXN0-884	1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + 2 H+  =  dimethylallyl-pyrophosphate + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	RXN-924	2 NAD(P)+ + 2 H+ + 4 e-  =  2 NAD(P)H	photosynthesis, light reaction
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.17.1.2	1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate + 2 H+  =  delta3-isopentenyl-PP + H2O	isopentenyl diphosphate biosynthesis -- mevalonate-independent
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.14.13.78	ent-kaur-16-en-19-ol + NADPH + H+ + O2  =  ent-kaur-16-en-19-al + NADP+ + 2 H2O	GA12 biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.14.13.78	ent-kaur-16-en-19-al + NADPH + H+ + O2  =  ent-kaurenoate + NADP+ + H2O	GA12 biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.14.13.81	Mg-protoporphyrin monomethyl ester + NADPH + H+ + O2  =  131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + H2O	chlorophyllide a biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.14.13.81	131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + 2 H2O	chlorophyllide a biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.14.13.81	131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  divinyl protochlorophyllide a + NADP+ + 2 H2O	chlorophyllide a biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	purine degradation
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	salvage pathways of purine nucleosides
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.3.1.26	L-2,3-dihydrodipicolinate + NAD(P)H + H+  =  L-2,3,4,5-tetrahydrodipicolinate + NAD(P)+	lysine biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.5.1.20	5,10-methylene-THF + NAD(P)H + H+  =  5-methyl-THF + NAD(P)+	formylTHF biosynthesis I
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	proline biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.5.1.2	L-delta1-pyrroline-5-carboxylate + NAD(P)H + H+  =  L-proline + NAD(P)+	arginine degradation II
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.8.1.7	glutathione disulfide + NADPH + H+  =  2 glutathione + NADP+	ascorbate glutathione cycle
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	6.6.1.1	ATP + protoporphyrin IX + Mg2+ + H2O  =  Mg-protoporphyrin + H+ + phosphate + ADP	chlorophyllide a biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	1.5.1.12	L-delta1-pyrroline-5-carboxylate + NAD(P)+ + H2O  =  L-glutamate + NAD(P)H + H+	proline degradation
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	RXN-4316	isopentenyl adenosine + H2O  =  trans-zeatin riboside + 2 H+	trans-zeatin biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	RXN-4317	isopentenyladenine + H2O  =  trans-zeatin + 2 H+	trans-zeatin biosynthesis
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	SO3OXTFER-RXN	SO3-2 + 2 oxidized cytochrome c + H2O  =  SO42- + 2 reduced cytochrome c + 2 H+	sulfur oxidation
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	SULFOXTFER-RXN	polysulfide-glutathione complex + O2 + H2O  =  SO3-2 + polysulfide-glutathione complex + 2 H+	sulfur oxidation
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	PSII-RXN	2 H2O  =  4 H+ + 4 e- + O2	photosynthesis, light reaction
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	3.5.1.4	acrylamide + H2O  =  NH3 + acrylate + H+	acrylonitrile degradation
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	4.1.1.-	D-ribulose-1,5-bisphosphate + O2  =  2-phosphoglycolate + 3-phosphoglycerate + 2 H+	photorespiration
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	4.99.1.4	sirohydrochlorin + Fe2+  =  siroheme  + 2 H+	biosynthesis of proto- and siroheme
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	4.99.1.1	Fe2+ + protoporphyrin IX  =  2 H+ + protoheme	biosynthesis of proto- and siroheme
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	sucrose degradation to ethanol and lactate (anaerobic)
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis I
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	2.7.1.40	phosphoenolpyruvate + ADP + H+  =  pyruvate + ATP	glycolysis II
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	sucrose degradation to ethanol and lactate (anaerobic)
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis I
H+	hydrogen ion*proton*H	H1 	[H+1]	LIGAND-CPD:C00080*CAS:12408-02-5	2.7.1.11	ATP + D-fructose-6-phosphate  =  fructose-1,6-bisphosphate + ADP + H+	glycolysis II
linolenate	linolenic acid	C18 H30 O2 	C(O)(=O)CCCCCCCC=CCC=CCC=CCC	CAS:463-40-1	1.13.11.12	O2 + linolenate  =  13(S)-hydroperoxylinolenate	jasmonic acid biosynthesis
linolenate	linolenic acid	C18 H30 O2 	C(O)(=O)CCCCCCCC=CCC=CCC=CCC	CAS:463-40-1	1.13.11.12	O2 + linolenate  =  13(S)-hydroperoxylinolenate	lipoxygenase pathway
linolenate	linolenic acid	C18 H30 O2 	C(O)(=O)CCCCCCCC=CCC=CCC=CCC	CAS:463-40-1	3.1.1.4	a phosphatidylcholine + H2O  =  linolenate + a lysophosphatidylcholine	jasmonic acid biosynthesis
plastoquinone-9		C53 H80 O2 	CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCC1(C(=O)C(C)=C(C)C(C=1)=O)		2.1.1.-	2-methyl-6-solanyl-1,4-benzoquinone + S-adenosyl-L-methionine  =  plastoquinone-9 + S-adenosyl-homocysteine	plastoquinone biosynthesis
3-dehydroquinate	3-dehydroquinic acid*5-dehydroquinic acid*5-dehydroquinate*5-de-H-quinate	C7 H10 O6 	C(O)(=O)C1([CH2]C(=O)[CH](O)[CH]([CH2]1)O)(O)	CAS:10534-44-8	4.2.1.10	3-dehydroquinate  =  H2O + 3-dehydro-shikimate	chorismate biosynthesis
3-dehydroquinate	3-dehydroquinic acid*5-dehydroquinic acid*5-dehydroquinate*5-de-H-quinate	C7 H10 O6 	C(O)(=O)C1([CH2]C(=O)[CH](O)[CH]([CH2]1)O)(O)	CAS:10534-44-8	4.2.3.4	3-deoxy-D-arabino-heptulosonate-7-phosphate  =  phosphate + 3-dehydroquinate	chorismate biosynthesis
acyl-CoA	fatty acyl thioester-CoA*an acyl-CoA*RCH2CH2CO-CoA*acyl-Coenzyme A	C22 H35 N7 O17 R1 P3 S1 			1.3.99.3	acyl-CoA + FAD  =  FADH2 + delta2-enoyl-CoA	fatty acid beta-oxidation
acyl-CoA	fatty acyl thioester-CoA*an acyl-CoA*RCH2CH2CO-CoA*acyl-Coenzyme A	C22 H35 N7 O17 R1 P3 S1 			2.3.1.20	acyl-CoA + 1,2-diacylglycerol  =  triacylglycerol + coenzyme A	triacylglycerol biosynthesis
acyl-CoA	fatty acyl thioester-CoA*an acyl-CoA*RCH2CH2CO-CoA*acyl-Coenzyme A	C22 H35 N7 O17 R1 P3 S1 			2.3.1.16	coenzyme A + beta-ketoacyl-CoA  =  acyl-CoA + acetyl-CoA	fatty acid beta-oxidation
acyl-CoA	fatty acyl thioester-CoA*an acyl-CoA*RCH2CH2CO-CoA*acyl-Coenzyme A	C22 H35 N7 O17 R1 P3 S1 			6.2.1.3	coenzyme A + a fatty acid + ATP  =  acyl-CoA + pyrophosphate + AMP	fatty acid beta-oxidation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.9.3.1	O2 + 4 ferrocytochrome c  =  2 H2O + 4 ferricytochrome c	aerobic respiration
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	IAA biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.-	L-tryptophan + NADPH + O2  =  indole-3-acetaldoxime + CO2 + NADP+ + H2O	glucosinolate biosynthesis from tryptophan
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	vitamin E biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	tyrosine degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	plastoquinone biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.27	p-hydroxyphenylpyruvate + O2  =  CO2 + homogentisate	phenylalanine degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	chlorophyllide a biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.3.3.3	coproporphyrinogen III + 2 O2  =  protoporphyrinogen + 2 CO2 + 2 H2O2	biosynthesis of proto- and siroheme
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.4.3.5	O2 + H2O + pyridoxamine 5'-phosphate  =  NH3 + H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	phenylpropanoid biosynthesis, initial reactions
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.11	O2 + NADPH + trans-cinnamate  =  H2O + NADP+ + 4-coumarate	suberin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.3.3.1	O2 + dihydroorotate  =  H2O2 + orotate	de novo biosynthesis of pyrimidine ribonucleotides
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-1121	ferulate + NADPH + O2  =  5-hydroxy-ferulic-acid + H2O + NADP+	phenylpropanoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.4.3.-	O2 + L-aspartate  =  H2O2 + iminoaspartate	NAD biosynthesis I (from aspartate)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.5	O2 + homogentisate  =  4-maleyl-acetoacetate	tyrosine degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.5	O2 + homogentisate  =  4-maleyl-acetoacetate	phenylalanine degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	carotenoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN1F-153	zeaxanthin + NADPH + O2  =  antheraxanthin + NADP+ + H2O	xanthophyll cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.36	4-coumaroylquinate + NADPH + O2  =  caffeoylquinate + NADP+ + H2O	lignin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.36	4-coumaroylshikimate + NADPH + O2  =  caffeoylshikimate + NADP+ + H2O	lignin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-1142	coniferyl aldehyde + NADPH + O2  =  5-hydroxy-coniferaldehyde + NADP+ + H2O	lignin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.-	benzoate + NADPH + O2  =  salicylate + NADP+ + H2O	salicylic acid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-744	3-oxo-2-(cis-2'-pentenyl)-cyclopentane-1-octanoate + 3 O2  =  (+)-7-isojasmonate + 3 acetate	jasmonic acid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.12	O2 + linolenate  =  13(S)-hydroperoxylinolenate	jasmonic acid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.12	O2 + linolenate  =  13(S)-hydroperoxylinolenate	lipoxygenase pathway
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	AMACETOXID-RXN	aminoacetone + H2O + O2  =  NH3 + methylglyoxal + H2O2	threonine degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	suberin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.-	oleate + 2 NADPH + O2  =  18-hydroxyoleate + 2 NADP+ + H2O	cutin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	phenylpropanoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-1103	4-coumarate + NADPH + O2  =  H2O + caffeate + NADP+	suberin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.16.1	O2 + tetrahydrobiopterin + L-phenylalanine  =  L-tyrosine + 4alpha-hydroxy-5,6,7,8-tetrahydrobiopterin	phenylalanine degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	PNPOXI-RXN	O2 + pyridoxine-5'-phosphate  =  H2O2 + pyridoxal 5'-phosphate	pyridoxal 5'-phosphate salvage pathway
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.1.3.15	glycolate + O2  =  glyoxylate + H2O2	photorespiration
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	4.1.1.-	D-ribulose-1,5-bisphosphate + O2  =  2-phosphoglycolate + 3-phosphoglycerate + 2 H+	photorespiration
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-1405	tryptamine + O2 + NADPH  =  N-hydroxyl-tryptamine + H2O + NADP+	IAA biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.4.3.6	tryptamine + H2O + O2  =  NH3 + indole acetaldehyde + H2O2	IAA biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.2.3.7	O2 + 2 indole acetaldehyde  =  2 indole-3-acetate	IAA biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.4.3.10	O2 + H2O + putrescine  =  NH3 + H2O2 + 4-amino-butyraldehyde	arginine degradation I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-1441	indole-3-acetaldoxime + NADPH + O2 + L-cysteine  =  indolylmethylthiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from tryptophan
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-2207	4-methylthiobutanaldoxime + NADPH + O2 + L-cysteine  =  4-methylthiobutylhydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from homomethionine
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.-	homomethionine + NADPH + O2  =  4-methylthiobutanaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from homomethionine
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-1064	18-hydroxyoleate + NADPH + O2  =  9,10-epoxy-18-hydroxystearate + NADP+ + H2O	cutin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-1062	16-hydroxypalmitate + NADPH + O2  =  10,16-dihydroxypalmitate + NADP+ + H2O	cutin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.-	palmitate + NADPH + O2  =  16-hydroxypalmitate + NADP+ + H2O	cutin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-698	neoxanthin + O2  =  xanthoxin + C25-allenic-apo-aldehyde	abscisic acid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	SULFOXTFER-RXN	polysulfide-glutathione complex + O2 + H2O  =  SO3-2 + polysulfide-glutathione complex + 2 H+	sulfur oxidation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.6	O2 + 3-hydroxy-anthranilate  =  2-amino-3-carboxymuconate semialdehyde	NAD biosynthesis II (from tryptophan)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.6	O2 + 3-hydroxy-anthranilate  =  2-amino-3-carboxymuconate semialdehyde	tryptophan degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	NAD biosynthesis II (from tryptophan)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.9	O2 + NADPH + kynurenine  =  H2O + NADP+ + 3-hydroxy-L-kynurenine	tryptophan degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.11	O2 + L-tryptophan  =  N-formylkynurenine	NAD biosynthesis II (from tryptophan)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.11	O2 + L-tryptophan  =  N-formylkynurenine	tryptophan degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-4241	6-deoxotyphasterol + O2  =  typhasterol + H2O	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-778	6-deoxocastasterone + O2  =  6alpha-hydroxy-castasterone + H2O	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-777	6-deoxotyphasterol + O2  =  6-deoxocastasterone + H2O	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.-.-	6-deoxocathasterone + O2  =  6-deoxoteasterone + H2O	brassinosteroid biosynthesis II
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.-.-	6-deoxocathasterone + O2  =  6-deoxoteasterone + H2O	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-773	campestanol + O2  =  6-deoxocathasterone + H2O	brassinosteroid biosynthesis II
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-773	campestanol + O2  =  6-deoxocathasterone + H2O	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.70	3 NADPH + 3 O2 + obtusifoliol + 3 H+  =  4 H2O + 3 NADP+ + formate + (4alpha)-methyl-(5alpha)-ergosta-8,14,24(28)-trien-3beta-ol	sterol biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.99.7	O2 + reduced acceptor + squalene  =  (S)-2,3-Epoxysqualene + H2O + acceptor	sterol biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-4230	5alpha-campestan-3-one + O2  =  22alpha-hydroxy-5alpha-campestan-3-one + H2O	brassinosteroid biosynthesis II
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-4231	campest-4-en-3-one + O2  =  22alpha-hydroxy-campest-4-en-3-one + H2O	brassinosteroid biosynthesis II
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.9	naringenin + O2 + alpha-ketoglutarate  =  CO2 + succinate + dihydrokaempferol	flavonoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.21	dihydrokaempferol + O2  =  dihydroquercetin + H2O	flavonol biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.21	dihydrokaempferol + O2  =  dihydroquercetin + H2O	anthocyanin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.19	leucopelargonidin + alpha-ketoglutarate + O2  =  pelargonidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.19	leucocyanidin + alpha-ketoglutarate + O2  =  cyanidin + succinate + CO2 + 2 H2O	anthocyanin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.10.3.3	L-ascorbate + O2  =  monodehydroascorbate + 2 H2O	ascorbate glutathione cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.11.-	a fatty acid + O2  =  a 2(R)-hydroperoxy fatty acid	fatty acid alpha-oxidation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-4465	a omega-hydroxy fatty acid + O2  =  a omega-oxo fatty acid + H2O2	fatty acid omega-oxidation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-4444	a fatty alcohol + O2  =  a fatty aldehyde + H2O2	fatty acid omega-oxidation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-4603	phenylacetaldoxime + NADPH + O2 + L-cysteine  =  phenylacetothiohydroximate + NADP+ + H2O + pyruvate + NH3	glucosinolate biosynthesis from phenylalanine
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.-	L-phenylalanine + NADPH + O2  =  phenylacetaldoxime + NADP+ + H2O + CO2	glucosinolate biosynthesis from phenylalanine
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.5.3.11	spermine + O2 + H2O  =  1-(3-aminopropyl)-4-aminobutanal + 1,3-diaminopropane + H2O2	beta-alanine biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.4.3.6	1,3-diaminopropane + H2O + O2  =  3-aminopropionaldehyde + NH3 + H2O2	beta-alanine biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA4 + alpha-ketoglutarate + O2  =  GA34 + succinate + CO2	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA25 + alpha-ketoglutarate + O2  =  GA13 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA15 + alpha-ketoglutarate + O2  =  GA37 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA38 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.15	GA20 + alpha-ketoglutarate + O2  =  GA1 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.12	GA44 + alpha-ketoglutarate + O2  =  GA19 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN1F-143	GA12 + O2  =  GA53 + H2O	gibberellin biosynthesis III (early C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA4 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.79	GA12-aldehyde + NADPH + O2  =  GA12 + NADP+ + H2O	GA12 biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.79	ent-7-alpha-hydroxykaurenoate + NADPH + H+ + O2  =  GA12-aldehyde + NADP+ + 2 H2O	GA12 biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN1F-93	dihydrokaempferol + alpha-ketoglutarate + O2  =  kaempferol + succinate + CO2 + H2O	flavonol biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-527	dihydroquercetin + alpha-ketoglutarate + O2  =  quercetin + succinate + CO2 + H2O	flavonol biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	R147-RXN	1,2-dihydroxy-3-keto-5-methylthiopentene + O2  =  2-oxo-4-methylthiobutanoic acid + formate	methionine salvage pathway
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.78	ent-kaur-16-ene + O2 + NADPH  =  H2O + NADP+ + ent-kaur-16-en-19-ol	GA12 biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	carotenoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN1F-154	antheraxanthin + NADPH + O2  =  violaxanthin + NADP+ + H2O	xanthophyll cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.3.3.4	1.5 O2 + protoporphyrinogen  =  3 H2O + protoporphyrin IX	chlorophyllide a biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.3.3.4	1.5 O2 + protoporphyrinogen  =  3 H2O + protoporphyrin IX	biosynthesis of proto- and siroheme
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.-.-	typhasterol + O2 + reduced acceptor  =  castasterone + H2O + acceptor	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.-.-	cathasterone + O2 + reduced acceptor  =  teasterone + H2O + acceptor	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.-.-	6-oxocampestanol + O2 + reduced acceptor  =  cathasterone + H2O + acceptor	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.-.-	campestanol + O2 + reduced acceptor  =  (6alpha)-hydroxycampestanol + H2O + acceptor	brassinosteroid biosynthesis I
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.-.-	campesterol + O2 + reduced acceptor  =  (22alpha)-hydroxy-campesterol + H2O + acceptor	brassinosteroid biosynthesis II
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-5962	zeinoxanthin + NADPH + O2  =  lutein + NADP+ + H2O	carotenoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-5961	alpha-carotene + NADPH + O2  =  zeinoxanthin + NADP+ + H2O	carotenoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.13.99.1	O2 + myo-inositol  ->  H2O + glucuronate	inositol oxidation pathway
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.79	ent-kaurenoate + O2 + NADPH  =  ent-7-alpha-hydroxykaurenoate + H2O + NADP+	GA12 biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.78	ent-kaur-16-en-19-ol + NADPH + H+ + O2  =  ent-kaur-16-en-19-al + NADP+ + 2 H2O	GA12 biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.78	ent-kaur-16-en-19-al + NADPH + H+ + O2  =  ent-kaurenoate + NADP+ + H2O	GA12 biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA15 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA15 + O2 + alpha-ketoglutarate  =  GA24 + H2O + CO2 + succinate	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA9 + succinate + 2 CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA24 + alpha-ketoglutarate + O2  =  GA25 + succinate + CO2	gibberellin biosynthesis I (non C-3, non C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA36 + O2 + alpha-ketoglutarate  =  GA4 + succinate + 2 CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA14 + O2 + alpha-ketoglutarate  =  GA37 + CO2 + succinate	gibberellin biosynthesis II (early C-3 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA37 + alpha-ketoglutarate + O2  =  GA36 + succinate + CO2 + H2O	gibberellin biosynthesis II (early C-3 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA14 + succinate + CO2	gibberellin biosynthesis II (early C-3 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA44 + CO2 + succinate	gibberellin biosynthesis III (early C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA20 + succinate + 2 CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA19 + alpha-ketoglutarate + O2  =  GA17 + succinate + CO2	gibberellin biosynthesis III (early C-13 hydroxylation)
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA44 + alpha-ketoglutarate + O2  =  GA98 + succinate + CO2	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA53 + alpha-ketoglutarate + O2  =  GA97 + succinate + CO2	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA12 + alpha-ketoglutarate + O2  =  GA110 + succinate + CO2	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA34 + alpha-ketoglutarate + O2  =  GA34-catabolite + succinate + CO2 + H2O	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA51 + alpha-ketoglutarate + O2  =  GA51-catabolite + succinate + CO2 + H2O	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA9 + alpha-ketoglutarate + O2  =  GA51 + succinate + CO2	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA29 + alpha-ketoglutarate + O2  =  GA29-catabolite + succinate + CO2 + H2O	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.13	GA1 + alpha-ketoglutarate + O2  =  GA8 + succinate + CO2	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA8 + alpha-ketoglutarate + O2  =  GA8-catabolite + succinate + CO2 + H2O	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.-	GA20 + alpha-ketoglutarate + O2  =  GA29 + succinate + CO2	gibberellin inactivation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.17.4	L-ascorbate + 1-aminocyclopropane-1-carboxylate + O2  =  2 H2O + ethene + L-dehydro-ascorbate + hydrogen cyanide + CO2	ethylene biosynthesis from methionine
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.81	Mg-protoporphyrin monomethyl ester + NADPH + H+ + O2  =  131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + H2O	chlorophyllide a biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.81	131-hydroxy-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADP+ + 2 H2O	chlorophyllide a biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.81	131-oxo-magnesium-protoporphyrin IX 13-monomethyl ester + NADPH + H+ + O2  =  divinyl protochlorophyllide a + NADP+ + 2 H2O	chlorophyllide a biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.22	eriodictyol + alpha-ketoglutarate + O2  =  luteolin + succinate + CO2 + H2O	luteolin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.11.22	naringenin + alpha-ketoglutarate + O2  =  apigenin + succinate + CO2 + H2O	luteolin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-7653	eriodictyol + NADPH + O2  =  luteolin + NADP+ + 2 H2O	luteolin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.21	naringenin + NADPH + O2  =  eriodictyol + NADP+ + H2O	luteolin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.14.13.21	apigenin + NADPH + O2  =  luteolin + NADP+ + H2O	luteolin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-7650	naringenin + NADPH + O2  =  apigenin + NADP+ + 2 H2O	luteolin biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.7.3.3	urate + O2  =  allantoin + CO2 + H2O2	purine degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-7677	7-hydroxy-chlorophyllide a + O2 + NADPH  =  chlorophyllide b + 2 H2O + NADP+	chlorophyll cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-7676	chlorophyllide a + O2 + NADPH  =  7-hydroxy-chlorophyllide a + H2O + NADP+	chlorophyll cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-7678	chlorophyll b + 2 H2O + NADP+  =  7-hydroxy-chlorophyll a + O2 + NADPH	chlorophyll cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-7679	7-hydroxy-chlorophyll a + H2O + NADP+  =  chlorophyll a + O2 + NADPH	chlorophyll cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	LUMAZINESYN-RXN	5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione + 3,4-dihydroxy-2-butanone-4-P  =  6,7-dimethyl-8-(1-D-ribityl)lumazine + phosphate + O2	riboflavin and FMN and FAD biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	carotenoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-314	violaxanthin + NADP+ + H2O  =  antheraxanthin + NADPH + O2	xanthophyll cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	carotenoid biosynthesis
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	RXN-325	antheraxanthin + NADP+ + H2O  =  zeaxanthin + NADPH + O2	xanthophyll cycle
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	PSII-RXN	2 H2O  =  4 H+ + 4 e- + O2	photosynthesis, light reaction
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.15.1.1	2 O2- + 2 H+  =  H2O2 + O2	removal of superoxide radicals
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	3.5.3.9	2 H2O + 2 allantoate  =  2 NH3 + O2 + 2 CO2 + 2 ureidoglycine	ureide degradation
O2	oxygen*oxygen molecule	O2 	O=O	LIGAND-CPD:C00007*CAS:7782-44-7	1.11.1.6	2 H2O2  =  2 H2O + O2	removal of superoxide radicals
p-aminobenzoate-beta-D-glucopyranosyl ester	p-PAPA-Glc	C13 H17 N1 O7 	C(=O)(c1(ccc(N)cc1))OC2(OC(CO)C(O)C(O)C2O)		RXN-6142	p-aminobenzoate + UDP-D-glucose  =  p-aminobenzoate-beta-D-glucopyranosyl ester + UDP	tetrahydrofolate biosynthesis I
3-hydroxy-3-methyl-glutaryl-CoA	(S)-3-hydroxy-3-methylglutaryl-CoA*HMG-CoA*hydroxymethylglutaryl-CoA*3-hydroxy-3-methylglutaryl-coenzyme A*3-Hydroxy-3-methylglutaryl-CoA	C27 H44 N7 O20 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(C)(O)CC(O)=O)	CAS:1553-55-5	4.1.3.4	3-hydroxy-3-methyl-glutaryl-CoA  =  acetoacetate + acetyl-CoA	leucine degradation
3-hydroxy-3-methyl-glutaryl-CoA	(S)-3-hydroxy-3-methylglutaryl-CoA*HMG-CoA*hydroxymethylglutaryl-CoA*3-hydroxy-3-methylglutaryl-coenzyme A*3-Hydroxy-3-methylglutaryl-CoA	C27 H44 N7 O20 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(C)(O)CC(O)=O)	CAS:1553-55-5	4.1.3.5	acetoacetyl-CoA + H2O + acetyl-CoA  =  coenzyme A + 3-hydroxy-3-methyl-glutaryl-CoA	mevalonate pathway
3-hydroxy-3-methyl-glutaryl-CoA	(S)-3-hydroxy-3-methylglutaryl-CoA*HMG-CoA*hydroxymethylglutaryl-CoA*3-hydroxy-3-methylglutaryl-coenzyme A*3-Hydroxy-3-methylglutaryl-CoA	C27 H44 N7 O20 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(C)(O)CC(O)=O)	CAS:1553-55-5	4.2.1.18	H2O + trans-3-methylglutaconyl-CoA  =  3-hydroxy-3-methyl-glutaryl-CoA	leucine degradation
3-hydroxy-3-methyl-glutaryl-CoA	(S)-3-hydroxy-3-methylglutaryl-CoA*HMG-CoA*hydroxymethylglutaryl-CoA*3-hydroxy-3-methylglutaryl-coenzyme A*3-Hydroxy-3-methylglutaryl-CoA	C27 H44 N7 O20 P3 S1 	[CH]3(n1(c2(c(nc1)c(N)ncn2)))(O[CH]([CH]([CH](O)3)OP(=O)(O)O)COP(=O)(O)OP(O)(=O)OCC(C)(C)C(O)C(=O)NCCC(=O)NCCSC(=O)CC(C)(O)CC(O)=O)	CAS:1553-55-5	1.1.1.34	2 NADPH + 3-hydroxy-3-methyl-glutaryl-CoA  =  2 NADP+ + coenzyme A + mevalonate	mevalonate pathway
zeinoxanthin	&beta;,&epsilon;-carotene-3-ol	C40 H56 O1 	CC1(C(=C(C)CC(O)C1)C=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CCC=C(C)2))(C)		RXN-5962	zeinoxanthin + NADPH + O2  =  lutein + NADP+ + H2O	carotenoid biosynthesis
zeinoxanthin	&beta;,&epsilon;-carotene-3-ol	C40 H56 O1 	CC1(C(=C(C)CC(O)C1)C=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC2(C(C)(C)CCC=C(C)2))(C)		RXN-5961	alpha-carotene + NADPH + O2  =  zeinoxanthin + NADP+ + H2O	carotenoid biosynthesis
9-mercaptodethiobiotin	9-mercaptodesthiobiotin	C10 H18 N2 O3 S1 	C(=O)(O)CCCCCC1(C(CS)NC(=O)N1)		RXN-5985	9-mercaptodethiobiotin  =  biotin	biotin biosynthesis II
9-mercaptodethiobiotin	9-mercaptodesthiobiotin	C10 H18 N2 O3 S1 	C(=O)(O)CCCCCC1(C(CS)NC(=O)N1)		2.8.1.6	dethiobiotin + sulfur donor  =  9-mercaptodethiobiotin	biotin biosynthesis II
L-2,3-dihydrodipicolinate	2,3-dihydrodipicolinate*dihydrodipicolinate*2,3-di-H-dipicolinate	C7 H7 N1 O4 	C(=O)(O)C1(=NC(C(O)=O)CC=C1)		1.3.1.26	L-2,3-dihydrodipicolinate + NAD(P)H + H+  =  L-2,3,4,5-tetrahydrodipicolinate + NAD(P)+	lysine biosynthesis
L-2,3-dihydrodipicolinate	2,3-dihydrodipicolinate*dihydrodipicolinate*2,3-di-H-dipicolinate	C7 H7 N1 O4 	C(=O)(O)C1(=NC(C(O)=O)CC=C1)		4.2.1.52	pyruvate + L-aspartate-semialdehyde  =  2 H2O + L-2,3-dihydrodipicolinate	lysine biosynthesis
N5-carboxyaminoimidazole ribonucleotide	N<sup>5</sup>-CAIR	C9 H13 N3 O9 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c(N)c(C([O-1])=O)nc2))		RXN0-743	N5-carboxyaminoimidazole ribonucleotide  =  phosphoribosyl-carboxy-aminoimidazole	de novo biosynthesis of purine nucleotides I
N5-carboxyaminoimidazole ribonucleotide	N<sup>5</sup>-CAIR	C9 H13 N3 O9 P1 	C(OP(O)(O)=O)C1(OC(C(O)C1O)n2(c(N)c(C([O-1])=O)nc2))		RXN0-742	5-aminoimidazole ribonucleotide + ATP + H2O + CO2  =  N5-carboxyaminoimidazole ribonucleotide + ADP + phosphate	de novo biosynthesis of purine nucleotides I
adenosine 3',5'-bisphosphate	PAP*phosphoadenosine phosphate	C10 H15 N5 O10 P2 	C(OP(=O)(O)O)[CH]1(O[CH](C(O)C1OP(=O)(O)O)n2(c3(c(nc2)c(N)ncn3)))		2.8.2.-	benzyl-desulfoglucosinolate + PAPS  =  benzyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from phenylalanine
adenosine 3',5'-bisphosphate	PAP*phosphoadenosine phosphate	C10 H15 N5 O10 P2 	C(OP(=O)(O)O)[CH]1(O[CH](C(O)C1OP(=O)(O)O)n2(c3(c(nc2)c(N)ncn3)))		2.8.2.-	3-methylthiopropyl-desulfoglucosinolate + PAPS  =  3-methylthiopropyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from homomethionine
adenosine 3',5'-bisphosphate	PAP*phosphoadenosine phosphate	C10 H15 N5 O10 P2 	C(OP(=O)(O)O)[CH]1(O[CH](C(O)C1OP(=O)(O)O)n2(c3(c(nc2)c(N)ncn3)))		2.8.2.-	indolylmethyl-desulfoglucosinolate + PAPS  =  indolylmethyl-glucosinolate + adenosine 3',5'-bisphosphate	glucosinolate biosynthesis from tryptophan
tRNAmet	TRNA(MET)				6.1.1.10	tRNAmet + L-methionine + ATP  =  L-methionyl-tRNAmet + pyrophosphate + AMP	tRNA charging pathway
1-18:1-2-18:1-sn-glycerol-3-phosphocholine		C44 H85 N1 O8 P1 	C(OP(O)(=O)OCC[N+1](C)(C)C)C(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC		1.14.99.-	1-18:1-2-18:1-sn-glycerol-3-phosphocholine  =  1-18:2-2-18:2-sn-glycerol-3-phosphocholine	phospholipid desaturation pathway
1-18:2-2-18:2-sn-glycerol-3-phosphocholine		C44 H81 N1 O8 P1 	C(OP(O)(=O)OCC[N+1](C)(C)C)C(OC(=O)CCCCCCCC=CCC=CCCCCC)COC(=O)CCCCCCCC=CCC=CCCCCC		1.14.99.-	1-18:2-2-18:2-sn-glycerol-3-phosphocholine  =  1-18:3-2-18:3-sn-glycerol-phosphocholine	phospholipid desaturation pathway
1-18:2-2-18:2-sn-glycerol-3-phosphocholine		C44 H81 N1 O8 P1 	C(OP(O)(=O)OCC[N+1](C)(C)C)C(OC(=O)CCCCCCCC=CCC=CCCCCC)COC(=O)CCCCCCCC=CCC=CCCCCC		1.14.99.-	1-18:1-2-18:1-sn-glycerol-3-phosphocholine  =  1-18:2-2-18:2-sn-glycerol-3-phosphocholine	phospholipid desaturation pathway
1-18:1-2-16:0-sn-glycerol-3-phosphate		C37 H71 O8 P1 	C(OP(O)(=O)O)C(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC		1.14.99.-	1-18:1-2-16:0-sn-glycerol-3-phosphate  =  1-18:1-2-trans-16:1-sn-glycerol-3-phosphate	phospholipid desaturation pathway
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	purine degradation
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	1.17.1.4	H2O + NAD+ + xanthine  =  NADH + urate	ureide biosynthesis
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	3.2.2.1	xanthosine + H2O  =  xanthine + D-ribose	purine degradation
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	3.2.2.1	xanthosine + H2O  =  xanthine + D-ribose	salvage pathways of purine nucleosides
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	3.5.4.3	H2O + guanine  =  NH3 + xanthine	purine degradation
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	3.5.4.3	H2O + guanine  =  NH3 + xanthine	salvage pathways of purine nucleosides
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	purine degradation
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	1.17.1.4	hypoxanthine + NAD+ + H2O  =  xanthine + NADH + H+	salvage pathways of purine nucleosides
xanthine	2,6-dioxopurine	C5 H4 N4 O2 	c12(c([nH]cn1)c(=O)[nH]c(=O)[nH]2)	LIGAND-CPD:C00385*CAS:69-89-6	XANTHOSINEPHOSPHORY-RXN	xanthosine + phosphate  =  ribose-1-phosphate + xanthine	ureide biosynthesis
L-3-hydroxyacyl-CoA	(S)-3-hydroxyacyl-CoA*trans-3-hydroxyacyl-CoA*RCHOHCH2CO-CoA*3-OH-acyl-CoA*3-hydroxyacyl-CoA*(3S)-3-hydroxyacyl-CoA	C24 H39 N7 O18 R1 P3 S1 			1.1.1.35	NAD+ + L-3-hydroxyacyl-CoA  =  NADH + beta-ketoacyl-CoA	fatty acid beta-oxidation
L-3-hydroxyacyl-CoA	(S)-3-hydroxyacyl-CoA*trans-3-hydroxyacyl-CoA*RCHOHCH2CO-CoA*3-OH-acyl-CoA*3-hydroxyacyl-CoA*(3S)-3-hydroxyacyl-CoA	C24 H39 N7 O18 R1 P3 S1 			5.1.2.3	D-3-hydroxyacyl-CoA  =  L-3-hydroxyacyl-CoA	fatty acid beta-oxidation
L-3-hydroxyacyl-CoA	(S)-3-hydroxyacyl-CoA*trans-3-hydroxyacyl-CoA*RCHOHCH2CO-CoA*3-OH-acyl-CoA*3-hydroxyacyl-CoA*(3S)-3-hydroxyacyl-CoA	C24 H39 N7 O18 R1 P3 S1 			4.2.1.17	H2O + trans-delta2-enoyl-CoA  =  L-3-hydroxyacyl-CoA	fatty acid beta-oxidation
D-erythro-imidazole-glycerol-phosphate	D-erythro-1-(imidazol-4-yl)-glycerol-3-phosphate*D-erythro-imidazole-glycerol-P*erythro-imidazole-glycerol-P*erythro-imidazole-glycerol-phosphate*imidazole glycerol phosphate*IGP	C6 H11 N2 O6 P1 	C(OP(O)(=O)O)C(O)C(O)c1(c[nH]cn1)		4.2.1.19	D-erythro-imidazole-glycerol-phosphate  =  imidazole acetol-phosphate + H2O	histidine biosynthesis
D-erythro-imidazole-glycerol-phosphate	D-erythro-1-(imidazol-4-yl)-glycerol-3-phosphate*D-erythro-imidazole-glycerol-P*erythro-imidazole-glycerol-P*erythro-imidazole-glycerol-phosphate*imidazole glycerol phosphate*IGP	C6 H11 N2 O6 P1 	C(OP(O)(=O)O)C(O)C(O)c1(c[nH]cn1)		2.4.2.-	phosphoribulosylformimino-AICAR-P + L-glutamine  =  D-erythro-imidazole-glycerol-phosphate + AICAR + L-glutamate	histidine biosynthesis
1-18:1-2-trans-16:1-sn-glycerol-3-phosphate		C37 H69 O8 P1 	C(OP(O)(=O)O)C(OC(=O)CC=CCCCCCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC		1.14.99.-	1-18:1-2-trans-16:1-sn-glycerol-3-phosphate  =  1-18:2-2-trans-16:1-sn-glycerol-3-phosphate	phospholipid desaturation pathway
1-18:1-2-trans-16:1-sn-glycerol-3-phosphate		C37 H69 O8 P1 	C(OP(O)(=O)O)C(OC(=O)CC=CCCCCCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC		1.14.99.-	1-18:1-2-16:0-sn-glycerol-3-phosphate  =  1-18:1-2-trans-16:1-sn-glycerol-3-phosphate	phospholipid desaturation pathway
1-18:2-2-trans-16:1-sn-glycerol-3-phosphate		C37 H67 O8 P1 	C(OP(O)(=O)O)C(OC(=O)CC=CCCCCCCCCCCCC)COC(=O)CCCCCCCC=CCC=CCCCCC		1.14.99.-	1-18:2-2-trans-16:1-sn-glycerol-3-phosphate  =  1-18:3-2-trans-16:1-sn-glycerol-3-phosphate	phospholipid desaturation pathway
1-18:2-2-trans-16:1-sn-glycerol-3-phosphate		C37 H67 O8 P1 	C(OP(O)(=O)O)C(OC(=O)CC=CCCCCCCCCCCCC)COC(=O)CCCCCCCC=CCC=CCCCCC		1.14.99.-	1-18:1-2-trans-16:1-sn-glycerol-3-phosphate  =  1-18:2-2-trans-16:1-sn-glycerol-3-phosphate	phospholipid desaturation pathway
dihydrolipoyl-GcvH-protein	B2904*Gcv*GcvH*dihydrolipoylprotein				2.1.2.10	S-aminomethyldihydrolipoyl-GcvH-protein + tetrahydrofolate  =  NH3 + dihydrolipoyl-GcvH-protein + 5,10-methylene-THF	glycine degradation
a 2(R)-hydroxy fatty acid		C2 H3 O3 R1 			RXN-4141	a 2(R)-hydroperoxy fatty acid  =  a 2(R)-hydroxy fatty acid	fatty acid alpha-oxidation
trans, trans-farnesyl diphosphate	FPP*farnesyl pyrophosphate*farnesyl-PP*farnesyl diphosphate*2-trans,6-trans-farnesyl diphosphate	C15 H28 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(=O)(O)O	LIGAND-CPD:C00448*CAS:146-14-5*CAS:13058-04-3	2.5.1.29	delta3-isopentenyl-PP + trans, trans-farnesyl diphosphate  =  geranylgeranyl-PP + pyrophosphate	ent-kaurene biosynthesis
trans, trans-farnesyl diphosphate	FPP*farnesyl pyrophosphate*farnesyl-PP*farnesyl diphosphate*2-trans,6-trans-farnesyl diphosphate	C15 H28 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(=O)(O)O	LIGAND-CPD:C00448*CAS:146-14-5*CAS:13058-04-3	2.5.1.21	2 trans, trans-farnesyl diphosphate  =  presqualene diphosphate + pyrophosphate	sterol biosynthesis
trans, trans-farnesyl diphosphate	FPP*farnesyl pyrophosphate*farnesyl-PP*farnesyl diphosphate*2-trans,6-trans-farnesyl diphosphate	C15 H28 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(=O)(O)O	LIGAND-CPD:C00448*CAS:146-14-5*CAS:13058-04-3	2.5.1.-	protoheme + trans, trans-farnesyl diphosphate + H2O  =  heme O + pyrophosphate	biosynthesis of proto- and siroheme
trans, trans-farnesyl diphosphate	FPP*farnesyl pyrophosphate*farnesyl-PP*farnesyl diphosphate*2-trans,6-trans-farnesyl diphosphate	C15 H28 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(=O)(O)O	LIGAND-CPD:C00448*CAS:146-14-5*CAS:13058-04-3	2.5.1.10	geranyl-PP + delta3-isopentenyl-PP  =  pyrophosphate + trans, trans-farnesyl diphosphate	polyisoprenoid biosynthesis
trans, trans-farnesyl diphosphate	FPP*farnesyl pyrophosphate*farnesyl-PP*farnesyl diphosphate*2-trans,6-trans-farnesyl diphosphate	C15 H28 O7 P2 	CC(C)=CCCC(C)=CCCC(C)=CCOP(=O)(O)OP(=O)(O)O	LIGAND-CPD:C00448*CAS:146-14-5*CAS:13058-04-3	2.5.1.10	geranyl-PP + delta3-isopentenyl-PP  =  pyrophosphate + trans, trans-farnesyl diphosphate	mevalonate pathway
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.18	anthranilate + PRPP  =  N-(5'-phosphoribosyl)-anthranilate + pyrophosphate	tryptophan biosynthesis
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.-	guanine + PRPP  =  pyrophosphate + GMP	salvage pathways of purine nucleosides
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.11	nicotinate + H2O + PRPP + ATP  =  nicotinate nucleotide + pyrophosphate + phosphate + ADP	pyridine nucleotide cycling
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides II
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.14	L-glutamine + PRPP + H2O  =  5-phospho-beta-D-ribosyl-amine + pyrophosphate + L-glutamate	de novo biosynthesis of purine nucleotides I
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.8	PRPP + hypoxanthine  =  pyrophosphate + IMP	salvage pathways of purine nucleosides
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis II (from tryptophan)
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.19	PRPP + quinolinate  =  CO2 + pyrophosphate + nicotinate nucleotide	NAD biosynthesis I (from aspartate)
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.10	PRPP + orotate  =  orotidine-5'-phosphate + pyrophosphate	de novo biosynthesis of pyrimidine ribonucleotides
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.7.6.1	ATP + D-ribose-5-phosphate  =  PRPP + AMP	PRPP biosynthesis
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.17	ATP + PRPP  =  phosphoribosyl-ATP + pyrophosphate	histidine biosynthesis
PRPP	5-phosphoribosyl diphosphate*5-phospho-&alpha;-D-ribose 1-diphosphate*PRPP*5-phosphoribosyl-1-PP*5-phosphoribosyl-PP*5-phosphoribosyl-1-pyrophosphate*5-phosphoribosylpyrophosphate*phosphoribosylpyrophosphate*5-phospho-ribosyl-pyrophosphate*&alpha;-D-5-phosphoribosylPP*&alpha;-D-5-P-RibosylPP*5-phospho-&alpha;-D-ribose-1-diphosphate	C5 H13 O14 P3 	[CH]1(O[CH]([CH](O)[CH](O)1)COP(=O)(O)O)(OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C00119*CAS:13270-65-0	2.4.2.7	PRPP + adenine  =  AMP + pyrophosphate	salvage pathways of purine nucleosides
1-18:3-2-trans-16:1-sn-glycerol-3-phosphate		C37 H65 O8 P1 	C(OP(O)(=O)O)C(OC(=O)CC=CCCCCCCCCCCCC)COC(=O)CCCCCCCC=CCC=CCC=CCC		1.14.99.-	1-18:2-2-trans-16:1-sn-glycerol-3-phosphate  =  1-18:3-2-trans-16:1-sn-glycerol-3-phosphate	phospholipid desaturation pathway
1-18:1-2-16:0-monogalactosyldiacylglycerol		C43 H80 O10 	C1(OC(CO)C(O)C(O)C(O)1)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC		1.14.99.-	1-18:1-2-16:0-monogalactosyldiacylglycerol  =  1-18:1-2-16:1-monogalactosyldiacylglycerol	glycolipid desaturation pathway
1-18:1-2-16:1-monogalactosyldiacylglycerol		C43 H78 O10 	C1(OC(CO)C(O)C(O)C(O)1)OCC(OC(=O)CCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC		1.14.99.-	1-18:1-2-16:1-monogalactosyldiacylglycerol  =  1-18:2-2-16:2-monogalactosyldiacylglycerol	glycolipid desaturation pathway
1-18:1-2-16:1-monogalactosyldiacylglycerol		C43 H78 O10 	C1(OC(CO)C(O)C(O)C(O)1)OCC(OC(=O)CCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC		1.14.99.-	1-18:1-2-16:0-monogalactosyldiacylglycerol  =  1-18:1-2-16:1-monogalactosyldiacylglycerol	glycolipid desaturation pathway
dephospho-CoA	dephosphocoenzyme A	C21 H35 N7 O13 P2 S1 	C(=O)(NCCS)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	CAS:3633-59-8	2.7.1.24	dephospho-CoA + ATP  =  coenzyme A + ADP	coenzyme A biosynthesis
dephospho-CoA	dephosphocoenzyme A	C21 H35 N7 O13 P2 S1 	C(=O)(NCCS)CCNC(=O)C(O)C(C)(C)COP(=O)(O)OP(=O)(O)OC[CH]1(O[CH]([CH](O)C(O)1)n2(c3(c(nc2)c(N)ncn3)))	CAS:3633-59-8	2.7.7.3	pantetheine 4'-phosphate + ATP  =  dephospho-CoA + pyrophosphate	coenzyme A biosynthesis
1-18:2-2-16:2-monogalactosyldiacylglycerol		C43 H74 O10 	C1(OC(CO)C(O)C(O)C(O)1)OCC(OC(=O)CCCCCC=CCC=CCCCCC)COC(=O)CCCCCCCC=CCC=CCCCCC		1.14.99.-	1-18:2-2-16:2-monogalactosyldiacylglycerol  =  1-18:3-2-16:3-monogalactosyldiacylglycerol	glycolipid desaturation pathway
1-18:2-2-16:2-monogalactosyldiacylglycerol		C43 H74 O10 	C1(OC(CO)C(O)C(O)C(O)1)OCC(OC(=O)CCCCCC=CCC=CCCCCC)COC(=O)CCCCCCCC=CCC=CCCCCC		1.14.99.-	1-18:1-2-16:1-monogalactosyldiacylglycerol  =  1-18:2-2-16:2-monogalactosyldiacylglycerol	glycolipid desaturation pathway
citrate	citr*cit*citric acid*2-hydroxy-1,2,3-propanetricarboxylic acid	C6 H8 O7 	C(=O)(O)CC(C(O)=O)(O)CC(O)=O	CAS:77-92-9	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle variation I
citrate	citr*cit*citric acid*2-hydroxy-1,2,3-propanetricarboxylic acid	C6 H8 O7 	C(=O)(O)CC(C(O)=O)(O)CC(O)=O	CAS:77-92-9	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	glyoxylate cycle
citrate	citr*cit*citric acid*2-hydroxy-1,2,3-propanetricarboxylic acid	C6 H8 O7 	C(=O)(O)CC(C(O)=O)(O)CC(O)=O	CAS:77-92-9	2.3.3.1	oxaloacetate + acetyl-CoA + H2O  =  citrate + coenzyme A	TCA cycle -- aerobic respiration
citrate	citr*cit*citric acid*2-hydroxy-1,2,3-propanetricarboxylic acid	C6 H8 O7 	C(=O)(O)CC(C(O)=O)(O)CC(O)=O	CAS:77-92-9	4.2.1.3	citrate  =  cis-aconitate + H2O	TCA cycle variation I
citrate	citr*cit*citric acid*2-hydroxy-1,2,3-propanetricarboxylic acid	C6 H8 O7 	C(=O)(O)CC(C(O)=O)(O)CC(O)=O	CAS:77-92-9	4.2.1.3	citrate  =  cis-aconitate + H2O	glyoxylate cycle
citrate	citr*cit*citric acid*2-hydroxy-1,2,3-propanetricarboxylic acid	C6 H8 O7 	C(=O)(O)CC(C(O)=O)(O)CC(O)=O	CAS:77-92-9	4.2.1.3	citrate  =  cis-aconitate + H2O	TCA cycle -- aerobic respiration
D-3-hydroxy-acyl-ACP	(3R)-3-hydroxyacyl-[acyl-carrier protein]*CH3(CH2)xCHOHCH2CO-S-ACP*beta-OH-acyl-ACP*beta-hydroxy-acyl-ACP				1.1.1.100	NADPH + beta-ketoacyl-ACP  =  D-3-hydroxy-acyl-ACP + NADP+	fatty acid elongation -- saturated
D-3-hydroxy-acyl-ACP	(3R)-3-hydroxyacyl-[acyl-carrier protein]*CH3(CH2)xCHOHCH2CO-S-ACP*beta-OH-acyl-ACP*beta-hydroxy-acyl-ACP				4.2.1.60	D-3-hydroxy-acyl-ACP  =  trans-delta2-enoyl-acyl-ACP + H2O	fatty acid elongation -- saturated
dihydroneopterin triphosphate	6-(D-<I>erythro</I>-1',2',3'-trihydroxypropyl)-7,8-dihydropterin-3'-triphosphate*H<SUB>2</SUB>NTP*2-amino-4-hydroxy-6-(<I>erythro</I>-1,2,3-trihydroxypropyl)dihydropteridine triphosphate	C9 H16 N5 O13 P3 	C2(C(=Nc1(c(=O)[nH]c(N)nc1N2))C(O)C(O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C04895	3.6.1.-	dihydroneopterin triphosphate + H2O  =  dihydroneopterin phosphate + pyrophosphate	tetrahydrofolate biosynthesis I
dihydroneopterin triphosphate	6-(D-<I>erythro</I>-1',2',3'-trihydroxypropyl)-7,8-dihydropterin-3'-triphosphate*H<SUB>2</SUB>NTP*2-amino-4-hydroxy-6-(<I>erythro</I>-1,2,3-trihydroxypropyl)dihydropteridine triphosphate	C9 H16 N5 O13 P3 	C2(C(=Nc1(c(=O)[nH]c(N)nc1N2))C(O)C(O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C04895	3.6.1.-	dihydroneopterin triphosphate + H2O  =  dihydroneopterin phosphate + pyrophosphate	tetrahydrofolate biosynthesis II
dihydroneopterin triphosphate	6-(D-<I>erythro</I>-1',2',3'-trihydroxypropyl)-7,8-dihydropterin-3'-triphosphate*H<SUB>2</SUB>NTP*2-amino-4-hydroxy-6-(<I>erythro</I>-1,2,3-trihydroxypropyl)dihydropteridine triphosphate	C9 H16 N5 O13 P3 	C2(C(=Nc1(c(=O)[nH]c(N)nc1N2))C(O)C(O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C04895	3.5.4.16	2 H2O + GTP  =  dihydroneopterin triphosphate + formate + H2O	tetrahydrofolate biosynthesis I
dihydroneopterin triphosphate	6-(D-<I>erythro</I>-1',2',3'-trihydroxypropyl)-7,8-dihydropterin-3'-triphosphate*H<SUB>2</SUB>NTP*2-amino-4-hydroxy-6-(<I>erythro</I>-1,2,3-trihydroxypropyl)dihydropteridine triphosphate	C9 H16 N5 O13 P3 	C2(C(=Nc1(c(=O)[nH]c(N)nc1N2))C(O)C(O)COP(=O)(O)OP(=O)(O)OP(O)(O)=O)	LIGAND-CPD:C04895	3.5.4.16	2 H2O + GTP  =  dihydroneopterin triphosphate + formate + H2O	tetrahydrofolate biosynthesis II